JP2003081804A - Fragrant composition for bathing and bathing agent comprising the same fragrant composition for bathing - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a fragrant composition for bathing comprising a functionally classified synthetic perfume material used as a material of the fragrant composition for bathing and a natural essential oil, a method for producing the fragrant composition and a bathing agent comprising the fragrant composition for bathing and/or a crude drug ingredient. SOLUTION: This fragrant composition for bathing is obtained by functionally classifying one thousand and several hundreds of synthetic perfumes usually used as the material of the fragrant composition for bathing into (A) a top note ingredient, (B) a middle note ingredient and (C) a base note ingredient, providing a group consisting of the ingredients (A) to (C) and further (D) the natural essential oil and suitably formulating at least one or more kinds of natural or synthetic perfumes selected from the group. Thereby, the desired resultant fragrant composition for bathing can more readily be prepared than conventional compositions. Furthermore, the fragrant composition for bathing can be combined with (E) the crude drug ingredient to thereby readily prepare the composition for bathing in which the odor peculiar to the crude drug ingredient is masked or enhanced and the medicinal effects of the crude drug can be expected.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to at least one selected from the group consisting of (A) top note component, (B) middle note component, (C) base note component and (D) natural essential oil.
The present invention relates to a bath fragrance composition containing one or more fragrances, a method for producing the same, and a bath agent containing the bath fragrance composition.

Further, the present invention relates to a bath agent composition comprising the above-mentioned bath fragrance composition and (E) a galenical component, a method for producing the same, and a bath agent containing the bath agent composition.

[0003]

2. Description of the Related Art The effects of bathing are generally said to be such as washing the body, promoting recovery from fatigue by improving blood circulation, and obtaining mental comfort through a feeling of openness.

On the other hand, the bath agents used during bathing are cleansed and protected by the chemical, physical, physiological and pharmacological actions of the bases contained in the bath agents, and also the diseases caused by the promotion of metabolism. Prevention, treatment, health maintenance, improvement, and even color,
It is said that there are effects such as providing a comfortable bathing atmosphere with sensory elements such as scent and skin feel, and easily enabling effects close to those of hot springs at home and the like.

In such a bath agent, the aroma composition used (hereinafter sometimes referred to as "bath aroma composition") makes the bathing rich and enjoyable due to the scent of taste, It is used for the purpose of relaxing, giving spiritual comfort, masking body odors such as sweat odor, and masking unpleasant odors derived from a combination base.

Therefore, the fragrance composition for bath is basically required to have various scents such as a scent that gives a relaxing or refreshing sensation, such as a scent with a refreshing sensation, a scent with a fresh sensation, and a warm scent. In addition, a highly diffused scent that spreads throughout the bathroom, and a fragrance with a residual fragrance (prepared fragrance) that can maintain the same fragrance or aroma for several hours after being put in the bathtub and maintain its strength is required. . This residual aroma is also effective for masking body odors such as sweat odors and axillary odors, and the compounding base.

[0007] Further, by using the aroma composition in combination with a crude drug having a medicinal effect, it is expected that the unique scent masking of the crude drug or the like and the synergistic effect of the efficacy effects of both will be obtained.

In response to such a demand, for example, JP-A-60-215617, JP-A-5-148130, JP-A-8-188529, JP-A-8-231376 and JP-A-9-
-2937, JP-A-9-2938, JP-A-9-2064
6, JP-A-9-110674, JP-A-9-241151
Although such proposals have been made, they are not always satisfactory, and development of an excellent bath fragrance composition having the above-mentioned function is desired. The relationship between the scent and the volatility is extremely important, and the basis of the aroma composition (hereinafter, also referred to as a compounded fragrance) is generally performed based on this volatility. As a property of the natural and synthetic fragrances used as materials, it is necessary to recognize what volatility each material has.

Observing the volatility is an effective means for preparing a fragrance composition. The natural and synthetic fragrances used for the preparation are usually classified into top notes (A) with high volatility, middle notes (B) with moderate volatility, and base notes (C) with low volatility. Although it is possible to express the volatility of natural and synthetic flavors used as flavor materials by vapor pressure,
In general, a method of sensing volatility sensorially described below is adopted. For the selection of the material of the aroma composition mainly composed of sensuality, the aroma composition is usually assembled based on the above-mentioned top note, middle note and base note.

However, about 200 kinds of natural and synthetic fragrances used as the material of the fragrance composition are classified into top notes, middle notes or base notes [Fragrance No. 97, pp. 17-24 (1970)]. Therefore, it is not satisfactory in practice.

Further, to the inventor's knowledge, of course, no examples have been known to which the prepared perfume assembled based on the above-mentioned top note, middle note, and base note is applied to a bath agent composition.

[0012]

An object of the present invention is to use a synthetic perfume material used as a material for a bath fragrance composition in a sensory manner (A) top note component, (B) middle note component,
(C) a base note component, and a bath fragrance composition comprising this and (D) at least one natural or synthetic fragrance selected from natural essential oils, a process for producing the same, and a bath containing the bath fragrance composition To provide the agent.

Another object of the present invention is to provide a bath preparation composition in which the above bath fragrance composition and (E) a galenical component are combined.

[0014]

In order to solve the above-mentioned problems, the present inventor organoleptically (A) a top note component of a thousand or more synthetic fragrances that are usually used as a raw material of a bath fragrance composition, (B) Middle note component and (C) base note component are each classified, and (D) natural essential oils are provided in the groups (A) to (D), and at least one or more selected from these groups. The present invention has been completed by finding that a desired bath fragrance composition can be prepared more easily than in the past by appropriately blending the natural or synthetic fragrance.

Further, the bath fragrance composition of the present invention and (E)
The present invention has been completed by discovering that a unique odor of a crude drug component can be masked or enhanced by combining the crude drug components, and further, an excellent bath preparation composition expected to have the medicinal effect of the crude drug can be easily prepared.

The volatility of the synthetic fragrance can be measured by diluting the raw material with ethyl alcohol to about 10%, attaching it to odor paper and leaving it at room temperature to observe how long the fragrance lasts. It can be classified into the following three types. 1. Top note (A); Top note A synthetic fragrance that has a high volatility, and if it is applied to scented paper, all or main part of it will evaporate within about 2 hours. Part needed to give. 2. Middle note (B); Middle note A synthetic fragrance that has a moderate volatility, and when applied to odor paper, the whole or main part of the fragrance lasts for about 2 to 6 hours. The part that makes up. 3. Base note (C); Base note A synthetic fragrance that has a low volatility and rich retention properties, and leaves an odor on the odor paper for about 6 hours or longer, and is a part showing the characteristics of the aroma composition.

The fragrance composition of the present invention is selected from the group of a large number of synthetic fragrances having different volatility and (D) natural essential oils shown in the above-mentioned Top Note (A), Middle Note (B) and Base Note (C). By mixing at least one or more selected fragrances, a predetermined fragrance or aroma required for each aroma composition (for example, citrus, fruity, green,
Fragrance compositions having floral, aldehyde, spicy, woody, sweet, mossy, musky, amber, animal, herbal, marine, mint notes, etc.) can be readily prepared.

The blending ratio of the note component of the synthetic fragrance in the formulation of the fragrance composition of the present invention is, for example, 0 to 100% by weight of the top note component (A) and 0 to 100% by weight of the middle note component (B). (C) Base note component is 0
-100% by weight, (D) the natural essential oil is used in the range of 0 to 100% by weight, but (A) the top note component is 5 to 80% by weight, and (B) the middle note component is 10 to 50% by weight.
% By weight, 10 to 50% by weight of (C) base note component,
(D) Natural essential oils are often used in the range of 5-80% by weight.

The synthetic perfume classified as the top note component (A) used in the bath fragrance composition is, for example, limonene, p-cymene, α-pinene, β-pinene, terpinolene, cis-3-hexene-1. -Ol, trans-2-hexenol, 1-penten-3-ol, 1-
Octene-3-ol, 2,6-dimethylheptane-2
-Ol, myrcenol, dihydromyrcenol, l-
Menthol, p-cresyl methyl ether, hexanal, trans-2-hexenal, octanal, nonanal, sinensal, methylheptenone, 1,4-cineole, 1,8-cineole, limonene oxide,
Ethyl 2-methylbutyrate, ethyl propionate, cis-3-hexenyl propionate, ethyl acetate, butyl acetate,
Isoamyl acetate, cis-3-hexenyl acetate, trans-2-hexenyl acetate, hexyl acetate, myrcenyl acetate, prenyl acetate, methyl benzoate, amyl acetate, ethyl butyrate, isoamyl butyrate, amyl butyrate, allyl butyrate, ethyl acetoacetate, yoshi Ethyl herbate, isovaleric acid cis-3-
Examples thereof include hexenyl, ethyl caproate, allyl caproate, ethyl heptanoate, ethyl octanoate, 8-mercaptomenthone and the like. Fragrances classified into the above top note ingredients are liquid, paste, solid, etc.
Any known state can be used.

Further, it is classified into (B) middle note component
Examples of synthetic fragrances include 3-phenylpropyl acetate.
Rucor, α-fencon, 9-decen-1-ol,
Dimethyl octanol, citronellol, geranio
Le, tetrahydromugol, linalool, tetrahydro
Linalool, nerol, ethyl linalool, terpineo
, Tetrahydrogeraniol, tetrahydromyrce
Nole, α-phenalkyl alcohol, eugenol, di
Methylbenzylcarbinol, dimethylphenylethyl
Carbinol, diphenyl oxide, Dupicer
Le^*, Citronellyl formate, geranyl formate, jasmar
^*, Benzyl acetate, dimethyl benzyl carbyl acetate,
Linalyl acetate, neryl acetate, o-tert butylcyclohexyl acetate
Xyl, p-tert-butylcyclohexyl acetate, cyclohexyl
Allyl siloxyacetate, fenkill acetate, citrone acetate
Ril, geranyl acetate, tetrahydrogeranyl acetate, acetic acid
Terpenyl, dihydroterpenyl acetate, isobornyl acetate
, L-menthyl acetate, nonyl acetate, tricyclode acetate
Cenyl, p-cresyl acetate, 2-phenylethyl acetate,
3-phenylpropyl acetate, styralyl acetate, dimethy acetate
Tylphenylethylcarbinyl acetate 1-ethynylsic
Lohexyl, allyl heptanoate, isobutyric propionate
, 2-phenylethyl propionate, sodium propionate
Tronellyl, benzyl propionate, tripropionate
Cyclodecenyl, cis-3-hexenyl butyrate, Cyclic butyrate
Rohexyl, 3-phenylpropyl isobutyrate, Dimethy butyrate
Cylbenzylcarbinyl, geranyl propionate, pro
Allyl pionate, Cyclohexyl butyrate, Anthra
Cis-3-hexenyl nitrate, phenylacetic acid isobutyrate
, Isobutyl salicylate, 2-phenyl ether salicylate
Chill, methyl heptine carboxylate, octyne carboxylic acid
Methyl, p-cresyl octanoate, cis-3-benzoic acid
Hexenyl, allyl amyl glycolate, cyclogalva
Nate^*, Β-phenylethyl alcohol, aferma
Out^*, Benzyl alcohol, anise alcohol, galley
Nyar, citral, neral, decanal, unde
Canal, 10-Undecenal, Dodecanal, Chiku
Rocitral, isocyclocitral, anisaldeh
De, phenylacetaldehyde, hydratrop arde
Hido, hydroxy citronellal, mirac aldehi
De, homomilac aldehyde, 2-methyl-3- (p
-Methoxyphenyl) -propanal, lilial, co
Avon ^*, Triplar^*, Limetor^*, Flora Rozo
The^*, 2-pentylcyclopentanone, l-carvone,
Menthone, geranylacetone, p-methylacetopheno
, Citronellal, citronellyl oxyacetoaldehyde
Hydrate, ethyl methylphenylglycidate, hydroxy
Troneral dimethyl acetal, phenyl acetal
Dehydr dimethyl acetal, methyl nonyl acetaldehyde
Hyddimethyl acetal, acetaldehyde 2-phenyl
Le-2,4-pentanediol acetal, acetoacetic acid
Ethyl propylene glycol acetal, hydratropa
Aldehyde Dimethyl acetal, Hydratropa aldehi
Ethylene glycol acetal, estragal^*,
Guaiacol, anethole, p-cresol, geranyl
Nitrile, citronellyl nitrile, indole, Lvov
Six^*Can include thiogeraniol, etc.
It Fragrances classified as the above middle note ingredients are liquid,
It is in any known state such as paste or solid.
Can also be used.

Trade names marked with * represent the following compounds. Dupical (Quest); 4- (Tricyclo [5.2.1.
0 ^2,6 ] decylidene-8) butanal Jasmal; 3-Pe
ntyltetrahydropyran-4-yl acetate Aphermate (IFF); α, 3,3-Trimethylcycl
ohexanemethyl formate Floralozon (IFF); p-Ethyl-α, α-dimethy
lhydrocinnamic aldehyde Cyclogalbanate (Dragoco); Allyl c
yclohexyloxy acetate Estragol; Methyl chavicol Rhubofix, Firmenich; Spiro [1,4-metha
nonaphthalene-2 (1H), 2'-oxirane], 3,4,4a, 5,8,8a, -he
xahydro-3 ′, 7-dimethyl (1), Spiro [1,4-methanonaphtha
lene- (2H), 2′-Oxiran], 3,4,4a, 5,8,8a-hexahydro-3 ′,
Mixture of 6-dimethyl (2) isomers Tripral (IFF); Dimethyl tetrahydrobenz
Aldehyde corebon (Koavone, IFF); 4-Methylene-3,5,6,6-tetrame
thyl-2-heptanone Limetol; 2,2,6-Trimethyl-6-vinyl tetra
hydropyran In addition, as the synthetic perfume showing the (C) base note component, for example, patchouli alcohol, p-tert-butylcyclohexanol, cinnamic alcohol, β-caryophyllene, guaiac acetate, cinnamyl acetate, geranyl butyrate, citronellyl butyrate, phenylacetic acid. , Amyl salicylate, isoamyl salicylate, benzyl salicylate, cis-3-hexenyl salicylate, hexyl salicylate,
Methyl anthranilate, methyl N-methylanthranilate, benzyl benzoate, diethyl phthalate, phenoxyethyl isobutyrate, geranyl isobutyrate, geranyl isovalerate, cinnamyl cinnamate, ethyl cinnamate, citronellyl phenylacetate, phenylacetate p -Cresyl, phenylethyl phenylacetate, eugenyl phenylacetate, isoeugenyl phenylacetate, isolongiforanone, methyl atralate, tetradecanal, α-amylcinnamic aldehyde, hydrocinnamic aldehyde, cyclamenaldehyde, lilal, raspberry ketone, iso jasmonate, Shisujasumon, damascones class ^*, damascenone class ^*, vanillin, ethyl vanillin, ocean propanal, heliotropin, α-n- hexyl cinnamic aldehyde, Oranchi Lumpur, alpha-Dainasukon ^*, ionones ^*, methyl ionone such ^*, nylon such ^*, acetyl cedrene, isoeugenol, methyl eugenol,
Methylisoeugenol, benzylisoeugenol,
β-methyl naphthyl ketone, β-naphthyl methyl ether, β-naphthyl ethyl ether, 2-methyl undecanal dimethyl acetal, 2-methyl-3- (p-methoxyphenyl) propanol, nerolidol, maltol, ethyl maltol, synthetic sandals ^* , Synthetic musk
^* , Γ-octalactone, γ-undecalactone, γ-
Decalactone, .gamma. nonyl lactone, .delta.-dodecalactone, methyl dihydro jasmonate, iso -E- super, cedryl methyl ether, isobutyl quinoline, ambroxan ^*, Chinberoru ^*, rose oxide, rose phenone, illustrate like longifolene be able to. Fragrances classified as the above middle note ingredients are liquid,
Any known state such as paste or solid can be used.

The above-mentioned product names and inclusive names marked with * represent the following compounds. Ambroxan; Ambroxan (Henkel) Damascus; α-Damascone, β-Damascone, γ-Dama
scone, δ-Damascone damacenones; α-Damascenone, β-Damascenone, γ-
Damascenone Ionones; α-Ionone, β-Ionone, γ-Ionone, δ-I
onone Methylionones; α-n-Methylionone, β-n-Methylion
one, γ-n-Methylionone, δ−n-Methylionone, α-iso-Me
thylionone, β-iso-Methylionone, γ-iso-Methylionone synthetic sandals; Bacdanol (IFF); 2-Ethyl-4- (2,2,3-trimethyl-3-cyclop
enten-1-yl) -2-buten-1-ol Brahamanol (Dragoco) ； 2-Methyl-4- (2,2,3-trimethyl-3
-cyclopenten-1-yl) butanol Madranol (Dragoco) ； β-2,2,3-Tetramethyl-3-cyclopen
tenyl-2-butenol Sandalore (Givaudan) ； 3-Methyl-5- (2,2,3-trimethylcy
clopent-3-en-1-yl) -pentan-2-ol 3,3-Dimethyl-5- (2,2,3-trimethyl cyclopenten-1-yl)-
Synthetic musks such as pent-4-en-2-ol, Methylsadeflor (TPC), Sandeol (MS); Cashmeran (IFF), Galaxolide (IFF), Tonali
de (PFW), Phantolide, Versalide, Exaltolide, Exaltone,
Oxalide, 12-Oxahexadecanolide, Ethylene brassylate, M
usk ketone, Celestolide (IFF), Traseolide (Quest), Ethy
lenedodecanedioate, 5-Cyclohexadecen-1-one etc. Iso-E-Super; Iso-E-Super (IFF): 7-Acetyl-1,
2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl-naphth
alene timbelol; Timberol (Dragoco): 1- (2,2,6-Trimethy
lcyclohexan-1-yl) -hexan-3-ol Irons; α-Irone, β-Irone, γ-Irone, δ-Irone α-Dynascon; α-Dynascone (Firmenich): 1- (5,5-
Dimethyl cyclohexen-1-yl) -4-penten-1-one (D) Natural essential oils include, for example, lemon oil, orange oil, lime oil, bergamot oil, eucalyptus oil, mandarin oil, wintergreen oil, camphor oil, Borax oil, oak moss oil, opoponax oil, copaiba oil,
Sandalwood oil, cedarwood oil, troy balsam oil, Peruvian balsam oil, benzoin oil, vanilla oil, abies fa oil, almond oil, columbus oil, chamomile oil, cardamom oil, galbanum oil, caraway oil, cumin oil, coriander oil , Juniper berry oil, spearmint oil, sage oil, celery oil, thyme oil, tarragon oil, nut meg oil, basil oil, hyssop oil, petitgrain oil, butchu oil, penny royal oil, peppermint oil, mace oil, lavender oil, rosemary Oil, lovage oil,
Laurel oil, Millis oil, Elemi oil, Cassia oil, Guayak oil, Clove oil, Styrax oil, Geranium oil,
Tangerine oil, patchouli oil, vetiver oil, labdanum oil, lemongrass oil, angelica oil, cypress oil, hiba oil, citronella oil, anise seed oil, ylang ylang oil,
Mention may be made of natural essential oils such as clary sage oil, cinnamon oil, star anise oil, cananga oil and black currant oil. The essential oil may be in the form of absolute, concrete, tincture, resinoid or the like. Further, the natural essential oil can be used in any shape such as liquid, solid or paste.

(A) Top note component and / or (B)
Middle note component and / or (C) base note component,
And / or (D) a bath aroma composition of the present invention comprising at least one or more fragrances selected from natural essential oils, and (E) a bath agent composition further containing a galenical component are bath salts, bath tablets, It can be used for bath agents such as bubble bath, foam bath, bath liquid, bath capsule and the like.

Predetermined fragrance or aroma required for each compounded fragrance (eg, citrus, fruity, green, floral, aldehyde, spicy, woody,
Sweet, mossy, musky, amber, animal,
Herbal, marine, and mint notes, etc.) have a bath fragrance composition of the present invention, which is harmonious with a pleasant scent, moderately preceding, moderately strong aroma, and characterized by diffusive and persistent. Having a bath salt, a bath tablet, a bubble bath, a foam bath containing this mixed fragrance,
Bath liquids, bath capsules, etc. have a pleasant scent when used, and the persistence that continues to smell for a while even after use,
It has a residual scent with a scent attached to the body after bathing, and it has an excellent effect on masking body odor due to the masking function of perfume.It also masks the unique odor of the base material used in bath agents and herbal medicines. It is possible, and it is possible to exert excellent effects such as aromatherapy effect due to fragrance, stress relieving effect, and antibacterial property.

In addition to the above-mentioned fragrances, as synthetic fragrances that can be used as the ingredients of the compounded fragrance of the present invention (A) top note component, (B) middle note component, (C) base note component, for example, Those listed in -1, Table-2 and Table-3 are listed. Further, examples of the fragrance that can be used as the (D) natural essential oil include the fragrances shown in Table 4. The synthetic and natural fragrances listed in Tables 1 to 4 are appropriately selected for each scent, and
Replace with the fragrance listed in each group described in 7,
Alternatively, a compounded fragrance having a desired aroma or aroma (eg, citrus, fruity, green, floral, aldehyde, spicy, woody, sweet, mossy, musky, amber, animal, herbal, marine, and mint note) added. Can be prepared. Table-1 (A) Top note dihydromyrcenyl acetate, 2,6-dimethyl-5
-Hepten-1-al, ethyl formate, 2-ethylhexanol, ethyl isoamyl ketone, ethyl isobutyrate, ethyl isovalerate, ethyl lactate, ethyl laurate, benzaldehyde, n-heptanal, cis-3-hexenal, β , Γ-hexenol, trans-3-hexen-1-ol, isobutyl acetate, octanal dimethyl acetal, n-propyl acetate and the like.

Table-2 (B) Middle note Acetaldehyde ethyl linalyl acetal, acetaldehyde phenylethyl n-propyl acetal, acetophenone, 4-tert amylcyclohexanone, benzyl butyrate, benzyl formate, benzyl isobutyrate, butyl butyryl lactate, 2-butyl-
4,6-Dimethyl-dihydropyran, ethyl 2-methyl-6-pentyl-4-oxocyclohexe-2-enecarboxylate, carbyl acetate, citral dimethyl acetal, 2,2-dimethyl-5- (1-methyl -1-propenyl) -tetrahydrofuran, cumin aldehyde, cumin alcohol, 1-decanol, trans-2-decen-1-al, cis-4-decenal,
Trans-4-decenal, decyl acetate, dihydroeugenol, dihydrojasmon, dihydrolinalool, 2,4-dimethyl-4,4a, 5,9a tetrahydroindeno [1,2d] -1,3-dioxin, 3,
7-dimethyl-1-octanal, dodecanal dimethyl acetal, dodecane nitrile, dodecanol, trans-2-dodecenal, ethyl acetoacetate ethylene glycol ketal, ethyl benzoate, ethyl 2-tert-butylcyclohexyl carbonate, ethyl geranoate, ethyl re Brinate, ethyl phenylacetate, ethyl salicylate, hexyl butyrate, hydroxycitronellal diethyl acetal, isoborneol, isobornyl propionate, 4-isopropylcyclohexanol, lavandulol, lavandulyl acetate, 1-methyl- 1-methoxycyclododecane (Madorox; Givaudan),
Methyl salicylate, nerol oxide, cis-6-
Nonen-1-ol, nopyr acetate, octahydro-4,7-methano-1H-indenecarboxaldehyde (Vertral), octyl acetate, octanol, perilla alcohol, perilla aldehyde, α-phenylethyl alcohol, 2-phenylethylpho Mate, 2-phenylethyl tiglate, piperiton, 9-
Decenol (ROSALVA; IFF), 5-methyl-
3-heptanone oxime (Stemone; Givau)
dan), tricyclodecenyl acetate, toccyclodecenyl isobutyrate, tricyclodecenyl propionate (Florocyclene), 1-methyl-4
-(4-Methylpentyl) -3-cyclohexenecarboxaldehyde (Vernaldehyde; Giva
udan), 2-Sec-butylcyclohexanone, terpinen-4-ol, sweet fennel and the like.

Table 3 (C) Base note Allyl α-ionone, Ambretride (Ambrett
oxide), anis alcohol, anisyl acetate, anisyl acetone, anisyl formate, isoamyl phenyl ethyl ether (Anther), benzophenone, benzyl cinnamate, benziphenyl acetate, bicyclo [3,2,1] -octane-8- on,
1,5-Dimethyloxime (Buccoxime; Dr)
agoco), 2-tert-butylcyclohexanol, 7-methyl-3,5-dihydro-2H-benzodioxepin-3-one (Calone; Pfizer),
Cedryl acetate, α-cedrene epoxide, propylidenephthalide, cinnamic acid, cinnamic aldehyde, cinnamyl nitrile, cyclohexyl salicylate, cyclopentadecanone, decyl alcohol, dibenzyl ether, ethyl laurate, ethylmethylphenylglycy Date, farnesol, geranyl benzoate, geranyl phenylacetate, heliotropyl acetone, γ-hexalactone, hexyl benzoate, indole-hydroxy citronellal Schiff base, isoamyl benzoate, jasmine lactone,
Tetrahydro-6- (3-pentenyl) -2H-pyran-2-one (Jasmolactone; Firmen
ich), methyl- (3,5-dimethyl-3-cyclohexenyl) -methylene anthranilate (Herbat
iol; IFF), methyl jasmonate, muscone,
δ-nonalactone, δ-octalactone, 2-phenylethylbenzoate, 2-phenylethylcaprylate, 2-phenylethylisoamyl ether, 2-phenylethylpivalate, phytol, santalol,
2,6,10-trimethyl-1-acetyl-2,5,9
-Cyclododecatriene (Trimofix O; IF
F), δ-undecalactone, vetiverol, vetiveryl acetate, cedrenol and the like.

Table-4 (D) Natural essential oils Cypress oil, Lavandin oil, Verbena, Elemi oil, Cascailla oil, Ginger grass oil, Pine oil, Bitter almond oil, Bitter fennel oil, Horwood oil, Melissa oil,
Bay Oil, Rose De May, Pimento Berry Oil, Pepper Oil, Cassie Absolute, Oris Absolute, Incense Oil, Cubeva Oil, Savory Oil, Dill Oil, Parsley Oil, Valerian Oil, Marjoram Oil, Linaroe Oil, Sassafras Oil, Amblet Seed Oil, Ajowan Oil , Iris oil, turmeric oil, costus oil, palmarosa oil, arnica oil, boad rose oil, mill oil, bloom oil, helicopterum oil, marigold oil, mimosa oil, narciss oil, orange flower oil, juni oil, honeysuckle Oil, Cassie oil, champaca oil,
Gardenia oil, hyacinth oil, jasmine oil, linden blossom oil, magnolia oil, osmanthus oil, rose oil, tuberose oil, violet oil, john kill oil, etc.

The perfumes listed in Tables 1-4 above may be in any known shape such as liquid, powder, paste and solid.

Furthermore, in addition to the above-mentioned perfume ingredients, examples of synthetic perfume (A) top note ingredient, (B) middle note ingredient, (C) base note ingredient which can be used as a blending material of the present invention are shown in Table 5 below. , 6 and 7. Table-5
The synthetic fragrance described in 7 is appropriately selected for each fragrance, and is replaced with or added to the fragrance described in each group of claims 5 to 7 to obtain a desired fragrance or aroma (citrus, fruity). , Green, floral, aldehyde,
Formulated perfumes having spicy, woody, sweet, mossy, musky, amber, animal, herbal, marine, and mint notes, etc. can be prepared.

Table-5 (A) Top notes Acetaldehyde, acetaldehyde diethyl acetal, acetaldehyde ethylhexyl acetal, acetaldehyde ethyl cis-3-hexenyl acetal,
Acetoin, 3-acetyl-2,5-dimethylfuran,
2-acetylfuran, acetylisovaleryl, 2-acetyl-5-methylfuran, 2-acetylpyridine, 3-
Acetylpyridine, 2-acetylpyrrole, pentanal, cis-3-hexenyl formate, heptanal,
Hexanal dimethyl acetal, heptanal dimethyl acetal, octanal dimethyl acetal, allyl caprate, alloocimene, alloocimenol, 4-
Allyl anisole, allyl benzoate, allyl caprylate, allyl 2-ethyl butyrate, allyl isothiocyanate, allyl isovalerate, allyl mercaptan, allyl propionate, amyl valerate, butyl formate, butyl butyrate, butyl isobutyrate. , Butyl isovalerate, butyl propionate, butyl valerate, Δ ³ -calene, 2,6-nonadienal, cyclohexyl acetate, diacetyl, diallyl disulfide, diallyl sulfide, dibutyl sulfide, diethyl malonate, dimethyl disulfide, 2,
6-dimethylheptan-2-one, 2,5-dimethyl-
4-hydroxy-3- (2H) -furanone, dihydrolinalool, dipentene, dimethylvinylcarbinol,
Dimethyl sulfide, ethyl 3-hydroxyhexanoate, ethyl acrylate, 2-ethylbenzenethiol, ethyl decanoate, ethyl crotonate, ethyl 2-ethylhexanoate, 2-ethylfuroate, ethyl trans-2-hexanoate, ethyl Trans-3-hexanoate, 2-ethylhexyl acetate, ethyl 2-hexyl acetoacetate, ethyl 3-
Hydroxybutyrate, 5-ethyl-3-hydroxy-
4-methyl-2 [5H] -furanone, ethylpyruvate, ethyl tiglate, furaneol, furfural,
Furfural acetone, furfuryl acetate, furfuryl alcohol, furfuryl acrolein, heptanal dimethytyl acetal, 2,3-heptanedione, heptanol, 2-heptanol, 3-heptanol, 2
-Heptanone, 3-heptanone, 4-heptanone, 4-
Heptanal, trans-2-heptanal, 3-hepten-2-one, heptyl acetate, 2,4-hexadienal, hexanal dimethyl acetal, 2,3
-Hexadione, 3,4-hexadione, 3-hexanone, cis-3-hexenyl hexanoate, cis-3-
Hexenyl formate, trans-2-hexenyl hexanoate, cis-3-hexenyl isovalerate, cis-3-hexenyl valerate, cis-3-hexenyl lactate, cis-3-hexenyl 2-methylbutyrate, cis- 4-hexen-1-ol, hexyl formate, hexyl isobutyrate, hexyl propionate, 3-hydroxy-2-butanone, 5-hydroxy-
4-octanone, isoamyl formate, isoamyl butyrate, isoamyl isovalerate, isoamyl mercaptan, isoamyl propionate, isobutyl crotonate, isobutyl 2-furan propionate, isobutyl hexanoate, isobutyl isobutyrate, isobutyl isovaleate Rate, isobutyl valerate, isopropyl acetate, isopropyl butyrate, isopropyl hexanoate, isopropyl isobutyrate,
Isopropyl isovalerate, isopropyl mercaptan, isopulegol, isopregyl acetate, isovaleraldehyde, linalyl formate, 1- (p-menthen-6-yl) -1-propanone, methoxybenzene, methylbenzyl ether, 2-methyl- 3-buten-2-ol, 3-methyl-2-buten-1-ol,
2-methylbutanal, 2-methylbutyl acetate,
Methyl butyrate, methyl caprynate, methyl caproate, methyl caprylate, methyl octyl carbonate, methyl cyclopentenolone, methyl cyclopentylidene acetate, 5-methyl furfural, methyl 2
-Furoate, methyl α-furyl ketone, 5-methyl-
3-heptenone, methylhexanoate, 5-methyl-
2,3-hexanedione, methyl trans-2-hexanoate, methyl trans-3-hexanoate,
Methyl hexyl ether, methyl isobutyrate, methyl isohexanoate, methyl isopropyl ketone, methyl isovalerate, methyl lactate, methyl 2-methyl butyrate, methyl pelargonate, 3-methyl-
1-pentanol, 4-methyl-3-pentene-2-
On, methyl valerate, myrtenal, myrcene, myrtenyl acetate, 2,4-nonadienal, 2,6
-Nonadienal, 2,6-nonadien-1-ol,
Cis-6-nonenal, trans-2-nonenal, ocimene, ocimene epoxide, ocimenol, 2-octanone, 3-octanone, trans-2-octenal, 1-octen-3-ol, 1-octen-3-yl acetate, 2,3-pentanedione, 2-pentenone, 1-penten-3-ol, trans-2-pentenal, α-ferrandrene, phenoxyacetaldehyde, 2-or4- (2-pinen-10-ylmethyl)
Pyridine, piperidine, prenol, prenyl angelate, prenyl benzoate, propiophenone, propyl butyrate, propyl formate, propyl-2-
Furan acrylate, propyl hexanoate, propyl isobutyrate, propyl isovalerate, propyl pupionate, rose furan, terpinene, tetrahydrofurfuryl acetate, 3-thiophene carboxaldehyde, tiglic acid, 2,5,6-trimethyl- 4-
Heptenal, 3,5,5-trimethylhexanal,
3,5,5-Trimethyl-1-hexanol, trithioacetone, valeraldehyde, benzaldehyde diethyl acetal, valeric acid, etc.

Table 6 (B) Middle note Acetaldehyde citronellyl methyl acetal, acetaldehyde ethyl isoeugenyl acetal, acetaldehyde ethyl phenylethyl acetal, acetaldehyde 2-phenyl-2,4-pentanediol acetal, acetoketal, 2'-acetonaphthone, Cis-2-acetonyl-4-methyltetrahydropyran,
Acetophenone neopentyl glycol ketal, 1-
Acetoxy-2-sec-butyl-1-vinylcyclohexane, 1-acetyl-3,3-dimethyl-1-cyclohexene, 2-acetyl-3,3-dimethylnorbornane, acetyldimethyltetrahydrobenzindane, acetyleugenol, acetylisoeugenol. Four
(5) -Acetyl-7,7,9 (7,9,9) -trimethylbicyclo [4.3.0] -1-nonene, heptanal diethyl acetal, octanal diethyl acetal, nonanal diethyl acetal, hexanal P ．
G. Acetal, ethyl p-methyl-β-phenylglycidate, 2-n-heptylcycloheptanone, allyl cinnamate, allyl cyclohexyl acetate, allyl octanoate, p-allyl phenol, allyl phenyl ethyl ether, 4,7- Dihydro-2-isopentyl-2-methyl-1,3-dioxepin, 1- (2,
2,6-trimethylcyclohexyl) -4-hexanol, amyl caproate, amyl caprylate, ot
ert-amyl cyclohexyl acetate, amyl cyclopentanone, 2-amyl pyridine, α-angelica lactone, anisylidene acetone, 4-isopropyl-
5,5-dimethyl-1,3-dioxane, benzaldehyde dimethyl acetal, benzyl cyanide, benzyl hexanoate, benzyl isovalerate, benzyl 2-methylbutyrate, benzyl valerate, α-methylene citronellal, 1- Bornyl propionate, β
-Bromostyrene, o-tert-butylcyclohexanone, tert-butylcyclohexanone, 2-butyl-1,4-dioxaspiro [4,4] nonane, butylhexanoate, butylideneacetone, tert-butylhydroquinone dimethyl ether, butyl lactate, Butyl levulinate, butyl octanoate, butyl sulfide, 2-butyl-4,4,6-trimethyl-1,3
-Dioxane, γ-butyrolactone, α, 3,3-trimethyl-2-norbornane-2-methanol, α-camphorenic aldehyde, camphor, carvacrol,
Carveol, 1-carbyl propionate, chabicol, citral diethyl acetal, citral P.I.
G. Acetal, citronellal cyclomonoglycol acetal, citronellyl E. G. Acetal, citronellyl ethyl ether, citronellyl hexanoate,
Citronellyl isobutyrate, citronellyl isovalerate, citronellyl methyl acetal, citryl acetate, o-tert-amyl cyclohexyl acetate, p-cresyl isobutyrate, 4-isopropyl-
2-cyclohexanone, cuminic acetate, cuminyl nitrile, cyclododecyl methyl ether, allylcyclohexyloxyacetate, l-cyclohexe-1
-Ene isopropyl acetate, 2- (1-cyclohexen-1-yl) cyclohexanone, cyclohexyl butyrate, cyclohexyl crotonate, cyclohexyl ethyl acetate, cyclohexyl ethyl alcohol, cyclohexyl isovalerate, cyclohexyl lactone, 4-cyclohexyl-4-methyl- 2-pentanone, 2,4-decadienol, decahydro-β-naphthol, trans-decahydro-β-naphthyl acetate, decahydro-β-naphthyl formate, trans-
Decahydro-β-naphthyl isobutyrate, decanal diethyl acetal, decanal dimethyl acetal,
Decanoic acid, 2-decenoic acid, 9-decenyl acetate, 9-decenyl propionate, decyl methyl ether, decyl vinyl ether, diethyl succinate, 4,7-dihydro-2-isopentyl-2
-Methyl-1,3-dioxepin, dihydrocarvone,
Dihydrocitronellol, diethyl adipate, dihydrocuminyl acetate, dihydromyrcene, dihydro-
α-terpineol, 3,4-dimethoxybenzaldehyde, 1,2-dimethoxybenzene, m-dimethoxybenzene, 2,6-dimethoxyphenol, 2,4-dimethylbenzyl acetate, p, α-dimethylbenzyl alcohol, 1,3- Dimethyl-3-butenyl isobutyrate, 2,4-dimethyl-3-cyclohexene-1-methanol, γ-4-dimethyl-3-cyclohexene-1
-Propanol, 2,4-dimethyl-3-cyclohexenylmethyl acetate, 3,3-dimethylcyclohexyl methyl ketone, 3,4-dimethyl-1,2-cyclopentanedione, 3,5-dimethyl-1,2-cyclo Pentanedione, 5,9-dimethyl-4,9-dimethyl-
4,9-decadienal, 3,7-dimethyl-7-methoxyoctane-2-ol, 2,2-dimethyl-5-
(1-methyl-1-propenyl) -tetrahydrofuran, 3,7-dimethyl-2,6-nonadienonitrile,
6,8-Dimethyl-2-nonanol, 3,3-dimethyl-Δ ² , β-norbornane-2-ethanol, 3,6-
Dimethyloctane-3-ol, 3,7-dimethyl-
1,3,6-octatriene, dimethyloctenone,
α, α-dimethylphenylethyl alcohol, dimethyl phthalate, dimethyl succinate, dimethyl tetrahydrobenzaldehyde, dimethyl trisulfide, 6,
10-dimethyl-5,9-undecadiene-2-yl acetate, 2-hydroxy-6-isopropyl-3-methyl-2-cyclohexanone, 2,4-dioxa-3-
Methyl-7,10-methanospiro [5.5] -undecane, dipropyl disulfide, dithiospirofuran,
2,4-dodecadienal, 3-dodecanaal, dodecyl acetate, ethyl-2-benzyl acetoacetate, ethyl cyclogeranate, ethyl decadienoate,
Ethyl decanoate, ethyl 2-decenoate, ethyl dehydrocyclogeranate, 3-ethyl-8 (9), 1
1-dimethyl-2,4-dioxaspiro- [5.5] undec-8-ene, 3-ethyl-2,4-dioxaspiro [5.5] -undec-8-ene, ethyl dodecanoate, E.I. G. Diacetate, E. G. Monobutyl ether, 4-ethylguaiacol, ethylheptine carbonate, ethyl 3-hydroxy-3-phenylpropionate, ethylisoeugenol, acetaldehyde ethyllinalyl acetal, ethyllinalyl acetate, ethyl o-methoxybenzoate, ethyl 2-methoxybenzyl ether, Ethyl nonanoate, ethyl octanoate, ethyl 2-octanoate, ethyl octocarbonate, ethyl 3-phenylpropionate, ethyl 3,5,5-trimethylhexanoate, eugenyl formate, formaldehyde cyclododecyl ethyl acetal, formaldehyde (Indan-1-
All-2-hydroxymethyl) acetal, formylethyltetramethyltetralin, 4 (5) formyl-
7,7,9 (7,9,9) -trimethylbicyclo [4.
3.0] -1-Nonene, gellan acid, geranyl ethyl ether, gingerol, 2,4-heptadienal, α-
Furfuryl valerate, heptanal diethyl acetal, heptanal E.I. G. Acetal, heptanoic acid, heptyl butyrate, 2-heptyl cyclopentanone, 2
-Heptyltetrahydrofuran, 1-ethynylcyclohexyl acetate, 2,4-hexadienyl isobutyrate, 2,4-hexadiene-1-ol, hexanal diethyl acetal, hexanal P.I. G. Acetal, hexanoic acid, cis-3-hexenal diethyl acetal, trans-2-hexenal diethyl acetal, cis-3-hexenyl angelate, trans-2
-Hexenyl butyrate, cis-3-hexenyl caproate, cis-3-hexenyl tiglate, cis-3-
Hexenyl valerate, 2-hexyl cyclopentanone, hexyl hexanoate, hexyl isovalerate, hexyl 2-methylbutyrate, 2-hexyl-5
-Methyl-1,3-dioxolane, hexyl tiglate, homofuraneol, hydratropic alcohol,
Hydratropic acetate, hydroquinone dimethyl ether, 3-hydroxy-4,5-dimethyl-2- (5
H) -furanone, 5- (hydroxymethyl) -2-furfural, 3-hydroxymethyl-2-nonanone, isoamyl angelate, isoamyl heptine carbonate, isoamyl lactate, isoamyl levulinate,
Isobornyl methyl ether, isobutyl angelate, isobutyl benzoate, isobutylbenzyl carbinol, 2-isobutyl-4-hydroxy-4-methyltetrahydropyran, p-isobutyl-α-methylhydrocinnamic aldehyde, α-isobutylphenylethyl Alcohol, 2-isobutyl pyridine, 3-isobutyl pyridine, isocyclogeraniol, isodamascon, isodihydrolavandulol, isodihydrolavandryl acetate, isononyl alcohol, 5-
Isopropenyl-methyl-2-vinyltetrahydrofuran, 4-isopropylbenzaldehyde, isopropylbenzoate, P-isopropylcyclohexyl acetate, cis-p-isopropylcyclohexylmethanol, isopropyldecanoate, 4-isopropyl-
5,5-dimethyl-1,3-dioxane, p-isopropylhydrotropic aldehyde, 4-isopropyl-
1-methyl-2-propenylbenzene, isopropylphenylacetate, 2-ethylidene-6-isopropoxybicyclo [2.2.1] heptane, isoquinoline, isosaflor, methylcyclooctyl carbonate, 5
-Methyl-3-butyltetrahydropyran-4-yl acetate, 4,7-dihydro-2- (3-pentanyl)
-1,3-dioxepin, limonenethiol, linalyl butyrate, linalyl hexanoate, linalyl isobutyrate, linalyl isovalerate, linalyl octanoate, linalyl propionate, menthalactone, l
-Menthyl isovalerate, 1-menthyl propionate, mercaptoacetic acid, mesityl oxide, p-methoxyacetophenone, o-methoxybenzaldehyde, p-methoxybenzaldehyde, o-methoxycinnamic aldehyde, methoxycitronellal, methoxy Dicyclopentadienecarboxaldehyde, p-methoxyphenylacetone, 4- (4-methoxyphenyl) -3-butan-2-one, 2-methoxy-
2-phenylethyl alcohol, 1- (4-methoxyphenyl) -1-penten-3-one, p-methylanisole, methyl angelate, α-methylanisylacetone, methyl anisate, 2-methylbenzoxazole,
α-methylbenzyl acetate, 4-methylbenzyl acetate, 2-methyl-2-butenyl phenyl ethyl ether, 2-methylbutyl isovalerate, 5-methyl-3-butyltetrahydropyran-4-yl acetate, 1-methyl Cyclododecyl methyl ether, methyl cyclogeranate, 4- (4-methyl-3-cyclohexenylidene-1) pentanal, 2-methyl decanal, methyl decanal, methyl decanoate, 4-methyl-3-decene- 5-ol, methyldecyne carbonate, 7-methyl-3,5-dihydro-2H-benzodioxepin, methyldodecanoate, α-methylene citronellal, 4-methylene-3,5,6,6-tetra Methyl-2-heptanone, methylgeranate, 4-methylguaiacol, 6-methyl Le-3,5-heptadiene-2
-One, 2-methylheptanoic acid, p-methylhydratropic aldehyde, β-methylhydrocinnamic aldehyde, methylhydroxyhexanoate,
p-Methylisopropylbenzene, methyl-o-methoxybenzoate, 2-methyl-3- (p-methoxyphenyl) propanal, methyl 1-methyl-3-cyclohexenecarboxylate, 7-methyl-3-methylene-1,6 -Octadiene, 1-methyl-4- (4-methyl-3-pentenyl) -3-cyclohexene-1-carboxaldehyde, 2-methylpentylvalerate, 2
-Methyl-3- (4-methylphenyl) propanal,
2-methyl-5- (methylthio) furan, methyl 3-
(Methylthio) propionate, methyl (methylthio)
Acetate, methylnicotinate, methylnonanoate, methyl 2-nonenoate, methyl 3-nonenoate, 2-methyloctanal, methyloctanoate,
4-methylpentanoic acid, trans-2-methyl-2-pentenoic acid, 3-methyl-pentyl angelate, p-methylphenoxyacetaldehyde, p-methylphenylacetaldehyde, methylphenylacetate, 3-methyl- 4-phenyl-3-buten-2-one, methylphenylglycidate, 5-methyl-2-phenyl-2-hexanol, 3-methyl-1
-Phenyl-3-propanal, 3-methyl-5-phenylpentanol, 4-methyl-4-phenyl-2-pentanone, 4-methyl-2-phenyl-2-pentenal, 3-methyl-5-phenyl Barrel aldehyde, 3-
Methyl-5-propyl-2-cyclohexen-1-one, 5-methyl-5-propyl-2- (1-methylbutyl) -1,3-dioxane, 2-methyl-4-propyl-1,3-oxathiane, Methylpropyl trisulfide, 1-methylpyrrole, p-methylquinoline, 5-methylquinoline, methyltetrahydrofuranone, 2-methylundecanaal, 2-methylundecanaal dimethylacetal, methyl 9-undecenoate, mentlactone, muguet alcohol, Miraldyl acetate, neryl butyrate, neryl formate, neryl isobutyrate, neryl propionate, nonanal diethyl acetal, nonanal dimethyl acetal, nonanediol-1,3-diacetate, nonanoic acid, 2-nonanol, 2 -Nonnan 3-nonanone, 1-nonene -3
-Ol, nonyl alcohol, sec-nonyl alcohol, nopol, ocimenyl acetate, 2,4-octadienal, octanal diethyl acetal, octanoic acid, 2-octanol, 3-octanol, 3-octyl acetate, octyl alcohol , Sec-octyl alcohol, octyl butyrate, octyl formate, octyl isobutyrate, 4-oxophorone, oxyoctaline formate, 3,4,5,6,6-pentamethyl-2-heptanol, 4-pentenoic acid, 2-pentyl-2-cyclopenten-1-one, 2-pentylpyridine, peryl acetate, phenoxyethyl alcohol, phenylacetaldehyde P.I. G. Acetal,
2-phenylethyl angelate, 2-phenylethyl isovalerate, 2-phenylethyl 2-methylbutyrate, 5-phenyl-5-methyl-3-hexanone, 3
-Phenylpropionaldehyde dimethyl acetal,
3-phenylpropylisobutyrate, 3-phenylpropylpropionate, pinocarveol, piperitenone, 4-methyltricyclo [6.2.1.0 ^2,7 ] undecan-5-one, 5-propenylguetol , Propyl benzoate, 3-propyl bicyclo [2.2.
1] hept-5-ene-2-carboxaldehyde,
P. G. Dibutyrate, P.I. G. Dipropionate, propylheptanoate, propyloctanoate, α-
Propylphenylethyl alcohol, propylphenylacetate, propyl trans-2, cis-4-decadienoate, pseudoionone, d-pregon, quinoline, rosinyl formate, rosinyl acetate, rosinyl butyrate, rosinyl propionate, sabinen Hydrate, safranal, safrole, salicylaldehyde, 3-hydroxy-4,5-dimethyl-2 (5
H) -Furanone, styralyl alcohol, styrylyl isobutyrate, styrylyl propionate, styrylyl diacetate, styryl cyanide, terpenyl butyrate, terpenyl formate, terpenyl isobutyrate, terpenylyl ester. Sovalerate, α-terpenyl methyl ether, terpenyl propionate, tetrahydroaroosimenol, tetrahydrocitral, tetrahydrofurfuryl butyrate, tetrahydrolinalyl acetate, tetrahydromugyl acetate, tetrahydropyrrole, 2,2,5 , 5-Tetramethyl-4-isopropyl-1,3-dioxane, thiogeraniol, 3-tunanol, 4-tunanol, β-tsuyapricin, thymol, theaspirane, p-tolylaldehyde, triacetin, tricyclodeceni. -Methyl ether, tricyclodecyl acetate, 4-tricyclodecylidene butanal, tridecanaal, 2-tridecanone, trans-2
-Tridecanol, tridecene-2-nitrile, 1-
(2,2,6-trimethylcyclohexan-1-yl)
-Hexan-3-ol, 4- (2,2,6-trimethyl-2 (1) -cyclohexene) -2-methylbutanal, 2,6,6-trimethyl-2-cyclohexene-
1,4-dione, 2,3,5-trimethyl-2-cyclohexen-4-yl-1-methyl ketone, 3,3,5-
Trimethylcyclohexyl ethyl ether, trimethyldecadienal, 9-ethylidene-3-oxatricyclo [6.2.1.0 ^2,7 ] undecane, α, 3,3-
Trimethylcyclohexane-1-methyl acetate,
3,5,5-trimethylhexyl acetate, α-3,
3-trimethyl-2-norbornanemethanol, 2,
2,5-trimethyl-5-pentylcyclopentanone,
2,5,5-trimethyl-2-phenyl-1,3-dioxane, α, α, p-trimethylphenylethyl alcohol, 4,6,6 (4,4,6) -trimethyltetrahydropyran-2-one, 2,2,10-trimethyl-
5,9-Undecadienal, Trimethylundecanal, 2,2,6-Trimethyl-6-vinyltetrahydropyran, 2,4-Undecadienal, 1-Undecanal, 2-Undecanol, 2-Undecanone , 1,
3,5-undecatriene, trans-2-undecenal, 10-undecen-1-ol, undecyl alcohol, undecylenic acid, sec-undecyl alcohol, valencene, γ-valerolactone, 4-methyl-4-phenyl- 2-pentyl acetate, 3-methyl-4-octanolide, verdyl acetate, verdyl propionate and the like.

* In the table, E. G. Is Ethylene
glycol, P.G. G. Is Propyrene G
Indicates lycol.

Table 7 (C) Base note Acetyl caryophyllene, acetyl vanillin, tridecanal, hexanal diethyl acetal, allylphenoxyacetate, 5-cyclohexadecen-1-one, 2,5,5-trimethyloctahydronaphthol,
α-n-amyl cinnamic alcohol, α-amyl cinnamic aldehyde diethyl acetal, α-amyl cinnamic aldehyde-methyl anthranilate (Schiff base), α-amyl cinnamic aldehyde dimethyl acetal, α-amyl cinnamyl acetate,
Anisyl propionate, 4 (5) -acetyl-7,
7,9 (7,9,9) -trimethylbicyclo [4,3,
0] Non-1-ene, benzyl tiglate, benzaldehyde glyceryl acetal, benzaldehyde P.I.
G. Acetal, benzyl caprylate, 8,9-epoxy cedrene, benzyl dodecanoate, benzyl eugenol, benzylidene acetophenone, benzyl isothiocyanate, benzyl laurate, benzyl octanoate, biphenyl, visabolene, α-visabol,
Butyl anthranilate, butyl decanoate, butyl dodecanoate, p-tert butyl hydrocinnamic aldehyde, 3-n-butylidenephthalide, 2-n-
Butylidene-3,5,5 (3,3,5) -trimethylcyclohexanone, p-tertbutyl-α-methylhydrocinnamic aldehyde, butylphenylacetate, 3-n-butylphthalide, 2-tertbutylquinoline, 6 (p ) -Tert-Butylquinoline, 6-se
c-Butylquinoline, 8-sec-butylquinoline, butyl salicylate, butyl stearate, butyl-10
-Undecenoate, caryophyllene acetate, β-
Caryophyllene alcohol, caryophyllene aldehyde, caryophyllene formate, β-caryophyllene oxide, cedranone, cedrenone, cedryl formate, cedrol methyl ether, cinnamyl anthranilate, cinnamyl benzoate, cinnamyl butyrate, cinnamyl formate, cinnamyl Isobutyrate, cinnamyl isovalerate, cinnamyl propionate, cinnamyl tiglate, citronellyl tiglate, civetone, p-cresyl octanoate, p-cresyl salicylate, cyclumber (Henkel), cyclohexadecanolide , 5-cyclohexadecene-1
-One, cyclohexyl phenyl ethyl ether, cyclomethylene citronellol, 2-cyclopentyl cyclopentadecanone, cyclotene, 2,4-di-tert-
Butylcyclohexanone, decahydrocyclododecaxazole, δ-decalactone, ε-decalactone, δ-
2-decenolactone, dibenzyl ketone, diethyl sebacate, diethyl tartrate, dihydrocarbeol, dihydrocarbyl acetate, dihydrocoumarin,
Dihydroindenyl-2,4-dioxane, dihydrojasmon lactone, 1,4-dimethoxy-2-tert
-Butylbenzene, dimethylbenzylcarbinylpropionate, dimethylbenzylcarbinylisobutyrate, 1,1-dimethyl-3-phenylpropanol,
2,2-Dimethyl-3-phenylpropanol, diphenyl, diphenylamine, ε-dodecalactone, ethyl-p-anisicate, ethylanthranilate, ethylcitronellyl oxalate, ethyl 2-methyl-6-pentyl-4-oxocyclohexyl See-2-encarboxylate, ethyl p-methyl-β-phenylglycidate, ethylmethyl p-tolylglycidate, ethyl myristate, ethyl oleate, ethyl palmitate, ethyl 3-phenylglycidate, ethyl safranate,
Ethyl stearate, farnesene, farnesyl acetone, geranyl benzoate, geranyl linalool, geranyl oxyacetaldehyde, guaien, heliotropin diethyl acetal, heliotropin dimethyl acetal, heliotropin acetate, γ-heptalactone, heptyl hexanoate, heptyl octanoate, δ-hexalactone, cis-3-hexenylphenyl acetate, hexyl octanoate, hinokitiol, hexyl phenyl acetate, hydrocinnamic alcohol, hydroxycitronellol, 2-hydroxy-6-isopropyl-3-methyl-2-cyclohexanone, 4- (4-hydroxy-3-methoxyphenyl)
-2-butanone, p-hydroxyphenylbutanone, isoamyl benzyl ether, isoamyl caprylate,
Isoamyl cinnamate, isoamyl decanoate, isoamyl decanoate, isoamyl hexanoate,
Isoamyl laurate, isoamyl octanoate, isoamyl phenyl ethyl ether, isoamyl undecylenate, isobutyl cinnamate, isobutyl phenyl ethyl acetate, 2-isobutyl quinoline, isoeugenyl ethyl ether, isoeugenyl phenyl acetate, isohexenyl cyclohexene carboxaldehyde , Isolongifolene epoxide, isophytol, isopropyl cinnamate, isopropyl myristate, 6-isopropyl quinoline, γ-jasmolactone, δ-jasmolactone, linalyl benzoate, linalyl cinnamate, p-isopropylcyclohexylmethanol, 1- Menthyl phenylacetate, methyl cinnamate, α-methyl trans-cinnamic aldehyde, 6-methyl Coumarin, methyl γ-decalactone, methyl dihydrojasmonate, p-methyldimethylbenzylcarbinol, 3-methylindole, 3
-Methyl-4- (2,4,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2-one, methyl laurate, α-methyl 3,4-methylenedioxyhydrocinnamic aldehyde, Methyl N-2'-methylpentylidene anthranilate, methyl myristate, methyl oleate, N-methyl-N-phenyl-2-methylbutyramide, 4-methyl-4-phenyl-2-pentyl acetate, methylpropyl Acetaldehyde-methylanthranilate-Schiff base, methyltetradecanoate, 2-methyl-4- (2,2,6-trimethyl-1 (2) -cyclohexenyl) -3-butene-1-
Earl, 3-methyl-5- (2,2,3-trimethyl-
3-Cyclopenten-1-yl) -3-pentene-2-
On, methyl vanillin, 1,1,3,3,5-pentamethacyl-4,6-dinitroindane, musk ambrette, musk tibetan, β-naphthyl isobutyl ether, nootkatone, octyl heptanoate, octyl octanoate, oleic Acid, 13-oxabicyclo [10.3.0] pentadecane, 3-oxabicyclo [10.3.0] pentadec-6-ene, 2-oxaspiro [4.7] dodecane, oxocedrane, pentylsalicylate, 2-phenoxy. Ethyl propionate,
Phenylacetaldehyde 2,3-butylene glycol acetal, phenylacetaldehyde diisobutyl acetal, 2-phenylethyl anthranilate, 2-
Phenylethyl cinnamate, 2-phenylethyl methacrylate, 2-phenylethyl methyl ether, 2
-Phenylethylmethylethylcarbinol, 2-phenylethylmethylethylcarbinyl acetate, 2-phenylethylnonanoate, phenylethyloctanoate, 2-phenylethylvalerate, phenylglycol diacetate, 3-phenylpropylisovalerate , Phenyl salicylate, piperonal, piperonyl acetate, piperonyl acetone, propyl cinnamate, 3-propylidene phthalide, raspberry aldehyde, resorcinol dimethyl ether, rosinyl isobutyrate, rosinyl phenyl acetate, α (β) santalyl Acetate, squalene, sclareol, skatole, stearic acid, δ-tetradecalactone, tetrahydro-p-methylquinoline, 5,6,7,8-tetrahydroquinoxaline δ-tridecalactone, triethyl citrate, 2,6,10-trimethyl-1-acetyl-2,5,9-cyclododecatriene, trimethylcyclodecatriene epoxide, 2,5,5-trimethyl-2-octahydro- 2-naphthol, dimethylbenzaldehyde-methylanthranilate Schiff base,
Vanillic acid, vanillin propylene glycol acetal, vanillyl alcohol, 5-propenyl guetol,
1- (2,3,5,6,7,8-hexahydro-1,1
-Dimethyl-1H-benzindan-4-yl) -ethanone and the like. * In the table, P. G. Is a Propylen G
represents lycol.

Further, the synthetic perfume and natural essential oil material of the bath aroma composition of the present invention can be used by adopting various refining / processing means if desired [well-known and conventional techniques collection (perfume) Part 1 Fragrances in general 2.3 Fragrance refining and processing technology issued on January 29, 2011].

Further, the above (A), (B) and (C)
When the synthetic fragrance described in 1) contains geometric isomers or optical isomers, these are included, and a natural essential oil containing the synthetic fragrance can also be used.

By adding a galenical component to the bath fragrance composition of the present invention, it can be used as a bath agent composition. By using the bath aroma composition and the galenical component in combination, it is possible to expect a unique odor masking of the galenical component and a synergistic effect of the efficacy effect of the bath aroma composition and the efficacy effect of the galenical component. Herbal medicines that can be used include aloe, apricot, nettle, fennel, mussel, mussels, hollyhock, erika, rye, orange, chamomile, kayapte, licorice, raspberry, cabbage, ginkgo biloba, camphoraceae, cabbage, keihi, gentian, Kouka, Kobokoku, Burdock, Rice, Salvia, Yamazushi, Sanshin, Sikon, Peonies, Jasmine, Ginger, Iris, Birch, Violet, Carrot, Sawtooth, Stinkweed, Stinkweed, Thyme, thyme, thyme, thyme, Onions, tea, cloves, chomps, capsicum, spruce, spruce, dodami, carrots, garlic, noibara, parsley, peppermint, poppy, loquat, loofah, rose, verbena, horse chestnut Melissa, Mokutou, Peach, Yokuinin, Yuzu, Eucalyptus, Wormwood, Lavender, Reishi, Lettuce, Lemon, Rosemary, etc., one or more of these herbal medicines cut, dried, etc. and known methods It is possible to utilize the one extracted by the method as a crude drug component.

In addition to the above galenical ingredients, examples of the herbal ingredient materials of the present invention include the herbal ingredient materials shown in Table-8.

Table 8 (E) Crude drug ingredients Ai, Aoki, Aokiba, Aojizo, Aodamo, Aochirimijiso, Aotsutsurafuji, Akagashi, Akachinoki, Akaza, Akajiso, Akashoma, Akane, Akabeakumokusaijo, Akamatsu, Akamitampo, Akamegashiwa, Akamegashiwa, Akamegashiwa , Aki larch, Akita tabuki,
Akebobi, Akebonofuji, Asa, Morning glory, Morning glory, Hydrangea, Thistle, Ashitaba, Atsumikan mallow, Amaki, Amagya maccha, Amakusa elephant, Ama, Amacha, Amachazul, Amaranthus, Amaranthus, Amaranthus, Amaranthus, Amaranthus, Akasagi Alexandria Senna, Rumex,
Abalone, Scion, Knotweed, Yew, Taxus, Ichiha, Ichigefuuro, Fig, Ichiakuso, Ginkgo, Itohimehagi, Inusafuran, Inushousho, Inusugina, Inudokusa, Rice, Inokozuchi, Inondo, Ibuukinobukou
Centella asiatica, Prickly Tobacco, Strawberry, Rhododendron japonicus, Ukogi, Turmeric, Ushinohakobore, Ushihakobe,
Pleurotus ostreatus, oleander, syringa, nepenthes, udo, unohana, ubashiraga, ubamekashi, horse squid, ume, urasimasou, urajiraikarisou,
White-tailed oak, Unshiu-kan, Ezo plantain, Ezo gall, Ezo grandiflorum, Ezo gentian, Ebisugusa, Enju, Engosaku, Ougi, Ooha, Oobaraki, Obana, Obaruma, Ootsuhaji, Otsuwabuki, Owabuki, Omanagi, Otsurakuji, Otsuwabaki, Omanagi, Ootsurafuji
Steller's wreath, barberry, Okuna grass, Okina yabaran, Ogyo, Okera, Ozekohone, Panax ginseng, Hypericum perforatum, Otokoeshi, Onamomi, Oniudo,
Onik, Onigurumi, Onidokoro, Oninagara, Onibasu, Onibishi, Oniyuri, Onoitatori, Obako,
Obashi Raga, Ominae, Omoto, Olive Tree, Onco, Ombaco, Kaikaisou, Kaininsou, Kaeloppa, Potato, Cacao, Oyster, Kagizura, Kakidooshi, Kakinoki, Katakuri, Scutellariae, Kamenopa, Kasou, Kanotsuka, Kasoposhi, Kasoposhi, Kasoposhi, Kasuga , Kaminari Cowpea, Kaya, Karitesou, Karagua, mustard, mustard, crow urchin, mustard mulberry, karaya muwa, karin, kawaraketsumei, kawara cowpea, kawarachigo, kawaranadeshiko,
Kawaranobasan, kawara mugwort, kawaribafuji, kansoi, kansai dandelion, licorice, kanzuwabuki,
Kanto dandelion, citrus trifoliate, citrus lily, kyoto, chrysanthemum, chrysanthemum, cowpea, beetle, Rumex, crocodile, yellow moss, yellow croaker, yellow croaker, yellow croaker, yellow croaker, yellow croaker, yellow croaker, yellow croaker. Oleander,
Kiransu, kumquat, cane sesame, buttercup, knotweed, kinreika, swordfish, wolfberry, hare, kusagikazura, kusaboke, kakushujifuji, kujo leeks, kudzu, camphor tree, gardenia, kumazasa, kumisumukutin, clara, chestnut, black sesame , Black squirrel, black slug, black lily, mulberry, mulberry, kei, swordfish,
Keito, geroppa, poppy, bay, zebra, zelkova, gentiai, genocho, corn, kobocha, kohone, koume, koyakanoi, korai pepper (koraigogoshi), kogaebane, kogaeikona, kogaekonagianagikona, kogaekonagina, koutanegagiana. , Coconut, gosaiba, koshinobaimo, goshuyu, pepper, cosmile, koselibaouren, kotorisuwaraz, kotoritomarazu, konotegawa,
Kochacobe, Kobano Tonoko, Kohitotsuba, Kofuuro, Kobushi, Sesame, Goyo Akebi, Konjac, Comfrey,
Psychic, Psyllium, Saotomebana, Prunus densiflora, Sakura, Pomegranate, Prickly pear, Sasayuri, Sagimoda, Sazensou, Saffron, Sabonsou, Sala cinnabarum, Sartoi rose, Sawweed, Strawberry, Steller's squirrel, Steller's squirrel, Steller's squirrel, Steller's squirrel, Steller's squirrel, Steller's squirrel, Steller's squirrel, Steller's squirrel Jigokunokamanofuta, Shikokufuuro, Shishiudo, Chili pepper, Perilla,
Pleurotus cornucopiae, Coccinella japonica, Coccinella vulgaris, Jingenjo, Shihai violets, Shimaten Nansho, potatoes, mustache, Juzudama, palm, ginger,
Shougunboku, Shoujou, Choppinoki, White Oak, White birch, Silane, White sesame, White azalea, White sycamore, White Oleander, White silane, White dandelion, White squirrel, White squirrel, White squirrel, White squid, White squid, White squid, White squid, White squirrel Stevia,
Strophanthus, Slonoki, Seikonoyoshi, Akane Akane, Oleander, Dandelion,
Horse chestnut, garlic, garlic, broomweed, ginkgo, senega, seri, ceriba lauren, sendan, senna, chinensis, senburi, soshin roubai, cycad, buckwheat, yoshino cherry, sycamore, radish daisaw, daidai, takatsuran, hawkweed, moss, rice field hawkweed Zeri, Tachitubosomire, Tachibana, Tachibana, Tachibana, Tachifuuro, Tateyamatsubogusa, Tanyutsugi, Tobacco, Tamasakitsuduraji, Tamaboki, Tamushigusa, Tamshiba, Taranoki, Tamaboshi, Tanbouren, Bamboo Ginseng, Takebushi Ninja, Ginseng Ginseng, Takebushi Ninja (Ginseng). Chimakiza, Chimegusa, Champagiku, Chugakuza, Azaleas, Ginseng, Gypsophila,
Chili Menjiso, Chinney Berry Senna, Tsukisuibara,
Black-breasted beetle, black-winged beetle, black-and-white widow, tutucholine senna, tsubos millet, black-winged psyllium, communis vulgaris, periwinkle, carrot, periwinkle, periwinkle, periwinkle, periwinkle, black-and-white, periwinkle, black-and-white, periwinkle, black-and-white, black-and-white, black-and-white, black-and-white, black-and-white
Delice, Terili Hanoi Barra, Tendaiyaku, Tennansho, Tanashi Carrot, German Thistle, Psyllium, Pepper, Toucan, Cowpea, Tokyo Leek, Castor bean, Tousendan, Dokudami, Tojuro, Astragalus serrata, Spicy corn, Ascendaceae, Tokiwadoki, Tokiwadoki, Tokiwadoki, Tokiwadoki, Tokiwadoki, Tokiwadoki, Tokiwadoki, Tokiwadoki, Tokiwadoki, Tokiwadoki, Tokiwa. , Syringa, horsetail, mackerel, carrot, horse chestnut, eucommia, ash,
Tobikosa, Tobikoma, Tobishago, Trish,
Aconitum, Toranoo, Trolo mallow, Chinese yam, Nagakinkan, Nagami Pepper, Naginatakouju, Namatame, Summer (Natsudai), Summer orange (Natsuto), Natsumikan, Date, Nadeshiko, Narukoyuri, Nankinto, Nangokushi Nanako, Nanakokushi, Nanakokushi Nankobi), nanban pepper, Nambu tosou, Nambutoranoo, scented squirrel, scented eucalyptus, nigaki, nigana, sagebrush, nutmeg, euglena, periwinkle, nikkei, nikkoza, leek,
Elderberry, garlic, nindou, nurude, Neiha kumquat, leek, cat flea, mouse, rat, rat,
Rodentia, Nemble, Nuphar, Neisseria sinensis, Aedes chinensis, Noxinob, Nobile, Baixalis, Baikauren, Hakusanobaku, Hakusanomieshi, Bakuchinoki, Hakubea, Hakubea, Hakobe, Hakobera, Hashihaduna, Hakudoha, Hakobori, Hakobera , Anemone japonicus, Anemone japonicus, Anemone japonicus, Vanilla, Anemone japonicum, Anemone japonicum, Habosothis, Thistle, Hamoud, Hamago, Hamagisha, Hamagesue, Hamachia, Hamanama,
Hamana, Hermanus, Hamaboufu, Rose, Balun, Harukoganebana, Harutlanoo, Harlindo, Pansy,
Bansho, Bell pepper, Hyogi, Hizagenokozuchi, Higanbana, Hikiokoshi, Hishi, Hizengusa, Hitahakihadada, Hitsuba, Hinako nokozuchi,
Binankazura (Sunflower), sunflower, Himeaoki,
Little Umegi, Himegashima, Himekin Mizuki, Himebishi,
Himefuro, sandalwood, sandalwood, sandalwood, hiyos, hiyoridorigogo, hiroha, hirohasenega, hirohahebinoboraz, loquat, areca, filisilane, butterbur, dandelion, wisteria, wisteria thiver, juvenile, burdock, fudaku, fudexhabuku, fuderin dow, burdock , Safflower,
Safflower, safflower, peony, snake novora, plantain, plantain, belladonna,
Crassulaceae, Henggodama, Henruda, Balsam,
Physalis, honoki, bokeh, prickly pear, prickly pear, buckwheat okera, prickly pear, button, honsekkokku, maou, masaki, matabi, matsurika, matecha, makushigusa, mamecha, malkincan, markova, witch hazel, citrus reeds Mishigawa, Mishima Psycho, Mizujeri, Mizudokusa, Mizumizusho, Mitsugashiwa, Mitsuba, Mitsuba Akkebi, Mitsuba Ouren, Mitsumata, Midorihakobe, Miyakoza, Miyogousou Meikyumaku, Miyokomaki Oyako, Miyoma Gyaku, Oyster, Miyoma Nagomi Oyako, Miyoma Gyaku, Oyster, Miyoma Nagomi Umami, Oyster, Miyoma Gyaku, Oyster, Miyoma Nagomi, Oysters ,
Swordfish, Japanese pine, magnolia, Mori thistle, yaitobana, greengrocer's windbreak (yaoyabofu), yakchi, yachisugina, azalea, mistletoe, willow foxtail, yabkoji, yaburayama, yamago, yamago, yamagogi, yamagoyaku, yamagogi, yamagogi, yamagogi, yakochi. Yamayakujo, Yamayakuyaku, Yamateri Hanoi Rose, Yamato Pepper, Yamatonadeshiko, Yamatorenkyo, Yamanoimo, Yamanokami Ryukyu, Yakuryuukayoryu, Yoryokura, Yakuroyaku, Yakurinoshi, Yuki-no-Toshi, Yoroida, Yakuroyaku, Yuki-no-Uta Koji sansho, gentian, lemongrass, lemon verbena, litchi, forsythia, laurel, waxy, rossaw, wasabi, Modulo, cotton, burnet, Woshizuri like.

The amount of the galenical component used in the bath agent is
Although it cannot be generally specified depending on the effective concentration of the crude drug component, it may be used in the bath agent so that it is used at a concentration of 0.001 to 99.9% by weight in the bath agent.

The method of mixing (preparing) the bath aroma composition and the herbal medicine component can be carried out by a conventionally known method, for example, a physical mixing method such as stirring is used.

In order to prevent deterioration of the bath fragrance composition and the bath agent composition produced as described above, known natural or synthetic antioxidants and photodegradation inhibitors can be added, if necessary. Well-known and common technique collection (fragrance) Part 1 General fragrance 2.4 Preservation technology of fragrance Page 141, November 1, 1999
29. Issue].

If necessary, a solvent (ethanol, ethylene glycol, propylene glycol, etc.), a known natural / synthetic dye, a known emulsifier, a solubilizer, a holding agent, etc.
Perfumes, cooling / warming agents, enhancers, enzymes and the like can be added as appropriate [Collection of well-known and common techniques (perfume) No. 1
Part General fragrance 2,3,8 Emulsification, solubilization, 2,6,11
Retention agent / fragrance agent, 2.6.12 enhancer, 2.6.
13 Cooling and Warming Agents Issued on January 29, 1999].

The bath fragrance composition and bath agent composition of the present invention can be used in various bath agents. A bath agent is used by putting it in bath water or bath water when taking a bath. It is used for the purpose of masking axillary odors and body odors and imparting odors.

Examples of bath agents in which the bath fragrance composition and bath agent composition of the present invention are used include bath salts, bath tablets, galenical bath agents, bubble baths, foam baths,
Examples include bath liquid, bath capsule, bath oil, milk bath, bath perfume, bath jelly and the like.

In addition to the bath fragrance composition and bath agent composition, the bath agent of the present invention may be, for example, sodium sulfate, magnesium sulfate, sodium chloride, ammonium chloride, sodium nitrate, potassium nitrate, depending on its efficacy and form. , Calcium nitrate, iron sulfate, aluminum sulfate, sodium thiosulfate, potassium chloride, potassium sulfide, alum, inorganic salts such as anhydrous silicic acid, sodium carbonate, sodium hydrogencarbonate, potassium carbonate, potassium hydrogencarbonate and the like, soybean oil , Natural oils and fats such as oils of succulent oil, jojoba oil, avocado oil, almond oil, olive oil, cacao butter, sesame oil, persic oil, castor oil, coconut oil, mink oil, beef tallow, lard, and these natural oils and fats are hydrogenated. The resulting hardened oil, myristic acid glyceride, 2-ethylhexanoic acid glyceride, etc. Glycerides, fats and oils such as diglycerides, carnauba, spermaceti, beeswax, waxes and lanolin, liquid paraffin, vaseline, paraffin, microcrystalline wax, ceresin, squalane, hydrocarbons such as pristane, lauric acid, myristic acid,
Palmitic acid, stearic acid, behenic acid, oleic acid,
Higher fatty acids such as linoleic acid, linolenic acid, lanolinic acid, isostearic acid, lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol,
Cholesterol, higher alcohols such as 2-hexyldecanol, cetyl octanoate, myristyl lactate, cetyl lactate, myristyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate,
Esters of decyl oleate, cholesterol isostearate, etc., benzoic acid, succinic acid, malic acid, fumaric acid, tartaric acid, citric acid, pyrrolidonecarboxylic acid, glycine, alanine, valine, leucine, isoleucine, serine, threonine, phenylalanine, tyrosine Organic acids such as tryptophan, cystine, cysteine, methionine, proline, hydroxyproline, aspartic acid, glutamic acid, arginine, histidine, lysine, kojic acid and its derivatives, glycerin fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, polyoxy Ethylene sorbitan fatty acid ester, tetraoleic acid polyoxyethylene sorbitan fatty acid ester, tetraoleic acid polyoxyethylene sorbit, polio Shi ethylene alkyl ether, nonionic surfactants such as polyglycerol fatty acid esters, alpha
-Anionic surfactants such as sodium olefin sulfonate, sodium lauryl sulfate, sodium cetyl sulfate, sodium polyoxyethylene lauryl sulfate, disodium lauryl sulfosuccinate, amphoteric surfactants such as carboxybetaine type, aminocarboxylic acid, sulfobetaine type Agents, cationic surfactants, polyhydric alcohols, gelatin, agar, guar gum, xanthan gum, gellan gum, native gellan gum, carrageenan (κ, ι,
λ), curdlan, thickeners such as alginic acid and its salts,
Vitamin A, vitamin B, vitamin C, vitamin D, vitamin E, vitamin F, vitamin K, vitamin P, vitamin U, carnitine, ferulic acid, γ-oryzanol,
Vitamins such as lipoic acid, orotic acid and its salts, fluorescent dyes such as fluorescein, pigments, enzymes such as pepsin, trypsin, papain and bromelain, sulfur, iron, mineral sand, gold,
Examples thereof include metals such as silver, Yunohana, water-soluble sulfide, neutral clay, egg yolk powder, iris bran, mica powder, seaweed extract, skim milk powder and the like.

The method of blending the bath fragrance composition and the bath agent composition into the bath agent can be carried out by a method commonly used in the art. [Collection of well-known and commonly used technologies (cosmetics and similar products) 5. Bath agent pages 174 to 178, issued on August 21, 1984] The blending ratio of the bath aroma composition and the bath agent composition to the bath agent depends on the intended effect and the form of the bath agent. Of the total weight of the bath agent, for example, powder (granular) type 0.0001 to 10% by weight, preferably 0.01 to 5% by weight, liquid type 0.01 to 100%
It may be used in a weight percentage, preferably 0.1 to 50 wt%.

The bath preparation of the present invention is not limited to liquid, paste, powder, granules, tablets and liquid.

The dose of the bath preparation of the present invention to be administered per administration is appropriately selected depending on the kind and concentration of the active ingredient used in the bath preparation, the dosage form of the bath preparation, the bath temperature and the like. For example, about 0.0 per 200 liters of bath water
001 to 200 g, preferably 0.01 to 100 g, but not necessarily limited to this.

Examples will be shown below, but these do not limit the present invention in any way.

[0051]

EFFECTS OF THE INVENTION Synthetic fragrances are sensually classified into (A) top note components, (B) middle note components, (C) base note components, and these and (D) natural essential oils, and these fragrances. Furthermore, the herbal medicine ingredients are mixed in a specific ratio. According to this method, it is possible to easily prepare a bath fragrance composition and a bath agent composition having a pleasant fragrance and capable of masking the unpleasant odor of the base, sweat odor, armpit odor, and the like. it can.

[0052]

EXAMPLES Next, the present invention will be described more specifically with reference to examples.

The units of the numerical values in the formulation examples in the examples are parts, and the total amount is 100 parts.
Further, the galenical components shown in the present example and the reference examples are extracts. Examples 1 to 290: Preparation examples of bath fragrance composition Reference Examples 291 to 300: Prescription examples of crude drug Examples 301 to 320: Preparation examples of bath agent composition /
A bath agent composition was prepared. The prepared aroma composition for bath /
The bath agent composition had a pleasant fragrance, masked unpleasant odors such as base and body odor, and was very effective because it could be widely applied to the general public. Further, the bath preparation composition was masked for the odor of the herbal medicine component, and was a very effective bath preparation composition that could be widely applied to the general public.

[0054]

[Table 1]

[0055]

[Table 2]

[0056]

[Table 3]

[0057]

[Table 4]

[0058]

[Table 5]

[0059]

[Table 6]

[0060]

[Table 7]

[0061]

[Table 8]

[0062]

[Table 9]

[0063]

[Table 10]

[0064]

[Table 11]

[0065]

[Table 12]

[0066]

[Table 13]

[0067]

[Table 14]

[0068]

[Table 15]

[0069]

[Table 16]

[0070]

[Table 17]

[0071]

[Table 18]

[0072]

[Table 19]

[0073]

[Table 20]

[0074]

[Table 21]

[0075]

[Table 22]

[0076]

[Table 23]

[0077]

[Table 24]

[0078]

[Table 25]

[0079]

[Table 26]

[0080]

[Table 27]

[0081]

[Table 28]

[0082]

[Table 29]

[0083]

[Table 30]

[0084]

[Table 31]

[0085]

[Table 32]

The following is an example of blending the bath fragrance composition / bath agent composition. Formulation Examples 321 to 630: Bath agent (bath salt) Formulation example (bath salt) Sodium sesquicarbonate 40 Sodium salt 10 Sodium sulfate 40 Liquid lanolin 0.4 Colorant 0.1 Bath aroma composition / bath agent composition 9.5 Above According to the formulation example, sodium sesquicarbonate, sodium chloride, sodium sulfate, liquid lanolin, colorant and Examples 1-290, 30
The aroma compositions for baths or the bath agent compositions prepared in 1 to 320 were mixed and evaluated when used as bath agents (bath salt). Evaluation is done by professional panelists,
"◎ ◎: highly preferred fragrance as a bath agent ＞ ◎ ＞ ○ ＞ △
> ×: Smell that is not very desirable as a bath agent ”was evaluated by 5 grades.

As a result of the evaluation, it was a preferable bath salt in any of the examples.

[0088]

[Table 33]

[0089]

[Table 34]

[0090]

[Table 35]

[0091]

[Table 36]

Formulation Examples 631 to 940: Evaluation of Bath Agent (Bath Oil) Bath Oil Hexadecyl Alcohol 30 Polyethylene Glycol 20 Polyoxylene Castor Oil 5 Ethyl Alcohol 40 Bath Aroma Composition / Bath Agent Composition 5 According to the above formulation example Hexadecyl alcohol, polyethylene glycol, polyoxylene hydrogenated castor oil, ethyl alcohol and the bath aroma composition or bath agent composition prepared in Examples 1 to 290 and 301 to 320 were mixed and used as a bath agent (bath oil). The time was evaluated. The evaluation was carried out by a five-level evaluation by a professional panelist, "◎ ◎: fragrance very preferable as a bath agent >>◎>○>△> x: fragrance not very preferable as a bath agent".

As a result of the evaluation, it was a preferable bath oil in all the examples.

[0094]

[Table 37]

[0095]

[Table 38]

[0096]

[Table 39]

[0097]

[Table 40]

   ─────────────────────────────────────────────────── ─── Continued front page    F term (reference) 4C083 AA111 AA112 AA121 AA122                       AB102 AB312 AB352 AC061                       AC062 AC151 AC152 AC171                       AC172 AC211 AC212 AC241                       AC242 AC351 AC352 AC731                       AC732 AC841 AC842 AC851                       AC852 AD512 AD531 AD532                       BB41 CC25 EE41                 4H059 BC23 DA09 DA30 EA31

Claims (12)

[Claims] 1. A top note component (A) and / or (B)
At least one selected from the group of middle note ingredients and / or (C) base note ingredients and / or (D) natural essential oils
A bath fragrance composition comprising one or more perfumes. 2. A top note component (A) is 0 to 100% by weight, a middle note component (B) is 0 to 100% by weight,
The bath aroma composition according to claim 1, wherein the base note component (C) is contained in an amount of 0 to 100% by weight, and the natural essential oil (D) is contained in an amount of 0 to 100% by weight. 3. A top note component (A) is 5 to 80% by weight, a middle note component (B) is 10 to 50% by weight,
The aromatic composition for bath according to claim 1 or 2, wherein the base note component (C) is contained in an amount of 10 to 50% by weight and the natural essential oil (D) is contained in an amount of 5 to 80% by weight. 4. A perfume (A) a top note component that volatilizes within about 2 hours, (B) a perfume that a middle note component volatilizes within about 2 to 6 hours, and (C) a base note component for about 6 hours or longer. The fragrance composition for bath according to claim 1, which is a fragrance having a persistent scent. 5. (A) The top note component is limonene, p-
Cymen, α-pinene, β-pinene, terpinolene,
Cis-3-hexen-1-ol, trans-2-hexenol, 1-penten-3-ol, 1-octene-
3-ol, 2,6-dimethylheptan-2-ol,
Myrcenol, dihydromyrcenol, 1-menthol, p-cresyl methyl ether, hexanal, trans-2-hexenal, octanal, nonanal,
Synensal, methylheptenone, 1,4-cineole, 1,8-cineol, limonene oxide, ethyl 2-methylbutyrate, ethyl propionate, cis-3-hexenyl propionate, ethyl acetate, butyl acetate, isoamyl acetate, cis-3 acetate -Hexenyl, acetic acid trans-
2-hexenyl, hexyl acetate, myrcenyl acetate, prenyl acetate, methyl benzoate, amyl acetate, ethyl butyrate,
At least selected from isoamyl butyrate, amyl butyrate, allyl butyrate, ethyl acetoacetate, ethyl valerate, cis-3-hexenyl isovalerate, ethyl caproate, allyl caproate, ethyl heptanoate, ethyl octanoate, 8-mercaptomentone. Claim 1 which consists of 1 or more types of perfume.
~ 4 bath fragrance composition. 6. The middle note component (B) is 3-phenylpropyl alcohol, α-phencon, 9-decene-1-.
All, dimethyl octanol, citronellol, geraniol, tetrahydromugol, linalool, tetrahydrolinalool, nerol, ethyl linalool, terpineol, tetrahydrogeraniol, tetrahydromyrcenol, α-phenalkyl alcohol, eugenol, dimethylbenzylcarbinol, dimethylphenylethylcarbyl. Nole, diphenyl oxide, dupicar, citronellyl formate, geranyl formate, jasmar, benzyl acetate, dimethylbenzyl carbyl acetate,
Linalyl acetate, neryl acetate, o-tert-butylcyclohexyl acetate, p-tert-butylcyclohexyl acetate, allyl cyclohexyloxyacetate, phenalkyl acetate, citronellyl acetate, geranyl acetate, tetrahydrogeranyl acetate, terpenyl acetate, dihydroterpenyl acetate, isobornyl acetate, L-menthyl acetate, nonyl acetate, tricyclodecenyl acetate, p-cresyl acetate, 2-phenylethyl acetate, 3-phenylpropyl acetate, styrylyl acetate, dimethylphenylethylcarbinyl acetate,
1-ethynylcyclohexyl acetate, allyl heptanoate,
Isobutyl propionate, 2-phenylethyl propionate, citronellyl propionate, benzyl propionate, tricyclodecenyl propionate, cis-3-butyrate.
Hexenyl, cyclohexyl butyrate, 3-phenylpropyl isobutyrate, dimethylbenzylcarbinyl butyrate, geranyl propionate, allyl propionate, allyl cyclohexylbutyrate, cis-3-hexenyl anthranilate, isobutyl phenylacetate, isobutyl salicylate, 2-phenylethyl salicylate. , Methyl heptine carboxylate,
Methyl octynecarboxylate, p-cresyl octanoate,
Cis-3-hexenyl benzoate, allyl amyl glycolate, cyclogalvanate, β-phenylethyl alcohol, afermate, benzyl alcohol, anis alcohol, geranial, citral, neral, decanal, undecanal, 10-undecenal, dodecanal, cyclocitral , Isocyclocitral,
Anisaldehyde, phenylacetaldehyde, hydratropaldehyde, hydroxycitronellal, mylacaldehyde, homomylacaldehyde, 2-methyl-3- (p-methoxyphenyl) -propanal,
Lilyal, Coabon, Tripral, Limitol, Florarozone, 2-Pentylcyclopentanone, l-Carvone, Mentone, Geranylacetone, p-Methylacetophenone, Citronellal, Citronellyloxyacetaldehyde, Ethylmethylphenylglycidate, Hydroxycitronellal dimethyl Acetal, phenylacetaldehyde dimethyl acetal, methylnonyl acetaldehyde dimethyl acetal, acetaldehyde 2-
Phenyl-2,4-pentanediol acetal, acetoacetate ethyl propylene glycol acetal, hydratropaldehyde dimethyl acetal, hydratropaldehyde alkane glycol acetal, estragal, guaiacol, anethole, p-cresol, geranyl nitrile, citronellyl nitrile, The aroma composition for bath according to any one of claims 1 to 4, comprising at least one fragrance selected from the group consisting of indole, lubofix, thiogeraniol and acetylcedrene. 7. The base note component (C) is patchouli alcohol, p-tert-butylcyclohexanol, cinnamic alcohol, β-caryophyllene, guaiac acetate, cinnamyl acetate, geranyl butyrate, citronellyl butyrate, phenylacetic acid, amyl salicylate, salicylic acid. Isoamyl, benzyl salicylate, cis-3-hexenyl salicylate, hexyl salicylate, methyl anthranilate, methyl N-methylanthranilate, benzyl benzoate, diethyl phthalate, phenoxyethyl isobutyrate,
Geranyl isobutyrate, geranyl isovalerate, cinnamyl cinnamate, ethyl cinnamate, citronellyl phenylacetate,
P-Cresyl phenylacetate, phenylethyl phenylacetate, eugenyl phenylacetate, isoeugenyl phenylacetate, isolongiforanone, methyl atralate, tetradecanal, α-amylcinnamic aldehyde, hydrocinnamic aldehyde, cyclamenaldehyde, linal, Raspberry Ketone, Isojasmon, Cisjasmon, Damascon, Damacenone, Vanillin, Ethylvanillin, Helional, Heliotropin,
α-n-hexylcinnamic aldehyde, auranthiol, α-dynascon, ionones, methylionones, irons, isoeugenol, methyleugenol, methylisoeugenol, benzylisoeugenol, β-methylnaphthylketone, β-naphthylmethyl Ether, β-naphthylethyl ether, 2-methylundecanal dimethyl acetal, 2-methyl-3- (p
-Methoxyphenyl) propanol, nerolidol, maltol, ethylmaltol, synthetic sandals, synthetic musk, γ-octalactone, γ-undecalactone, γ-
Decalactone, γ-nonyl lactone, δ-dodecalactone, methyl dihydrojasmonate, iso-E-super, ceryl methyl ether, isobutyl quinoline, ambroxane, timberol, rose oxide, rose phenone, longifolene, cedrol The aroma composition for bath according to claim 1, which comprises at least one or more fragrances. 8. The natural essential oil (D) is lemon oil, orange oil, lime oil, bergamot oil, eucalyptus oil, mandarin oil, wintergreen oil, camphor oil, borax oil, oak moss oil, opoponax oil, copaiba oil,
Sandalwood oil, cedarwood oil, troy balsam oil, Peruvian balsam oil, benzoin oil, vanilla oil, abies fa oil, almond oil, columbus oil, chamomile oil, cardamom oil, galbanum oil, caraway oil, cumin oil, coriander oil , Juniper berry oil, spearmint oil, sage oil, celery oil, thyme oil, tarragon oil, nut meg oil, basil oil, hyssop oil, petitgrain oil, butchu oil, penny royal oil, peppermint oil, mace oil, lavender oil, rosemary Oil, lovage oil,
Laurel oil, amiris oil, elemi oil, cassia oil, guaiac oil, clove oil, styrax oil, geranium oil, tangerine oil, patchouli oil, vetiver oil, labdanum oil, lemongrass oil, angelica oil, cypress oil, hiba oil, citronella. Oil, aniseed oil, ylang-ylang oil, clary sage oil, cinnamon oil, star anise oil,
The aroma composition for bath according to claim 1, which comprises at least one natural essential oil selected from the group consisting of cananga oil and black currant oil. 9. A bath fragrance composition according to any one of claims 1-8.
A bath agent containing 001 to 10% by weight. 10. A bath agent composition comprising the bath fragrance composition according to any one of claims 1 to 8 and (E) a galenical component. (E) The crude drug component (E) is aloe, apricot, nettle, fennel, euglena, euglena, enishida, erica, saccharum, orange, chamomile, kayapte, licorice, raspberry, cabbage, ginkgo biloba, camphoraceae, cabbage, Keihi, Gentian, Kouka, Koboku, Burdock, Rice, Salvia, Yamashiko, Sanshin, Sikon, Peonies, Jasmine, Shoikyo, Iris, Birch, Violet, Carrots, Astragalus vulgaris, Gypsophila, Gypsophila, Gypsophila Thyme, red pepper, onion, tea, clove, cock, pepper,
Touki, spruce, dokudami, carrot, garlic, Neubara, parsley, peppermint, corn poppy, loquat, loofah, rose, verbena, horse chestnut, melissa, mokutsu, peach,
11. The bath preparation composition according to claim 10, which is at least one crude drug selected from the group consisting of Yokuinin, citron, eucalyptus, mugwort, lavender, ganoderma, lettuce, lemon, and rosemary. 12. A bath agent containing 0.001 to 90% by weight of the bath agent composition according to claim 10.