JP2002252426A - Optical communication system using long-waveband surface light-emitting laser device - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an easy and high-reliability optical communications system. SOLUTION: A surface light-emitting semiconductor laser device chip whose operating voltage, lasing threshold current and the like can be reduced is used as a light-emitting light source. An optical connector is mounted on an optical fiber which is led out from the chip or a module package accommodating the chip.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a semiconductor laser used for optical communication and the like and an optical communication system therefor, and more particularly to a so-called surface which emits light in a direction perpendicular to the surface of a semiconductor substrate used for manufacturing the semiconductor laser. The present invention relates to an optical communication system in which a plurality of laser elements are formed using a light emitting laser to enable large-capacity communication.

[0002]

2. Description of the Related Art A surface emitting semiconductor laser emits laser light in a vertical direction from the surface of a substrate, so that two-dimensional parallel integration is possible, and the spread angle of the output light is relatively narrow (about 10 degrees). Therefore, it is easy to couple with an optical fiber and easy to inspect the element.
Therefore, in particular, development as an element suitable for configuring an optical transmission module (optical interconnection device) of a parallel transmission type has been actively conducted. The immediate application of the optical interconnection device is parallel connection between housings of computers and the like and between boards, as well as short-distance optical fiber communication, but large-scale computer networks and long distances are expected applications in the future. There is a trunk system for distance and large-capacity communication.

Generally, a surface emitting semiconductor laser is made of GaAs.
Or, it is common to comprise an active layer made of GaInAs, and an optical resonator consisting of an upper semiconductor distributed Bragg reflector disposed above and below the active layer and a lower semiconductor distributed Bragg reflector on the substrate side. However, since the length of the optical resonator is significantly shorter than that of the edge emitting semiconductor laser, it is necessary to set the reflectivity of the reflecting mirror to an extremely high value (99% or more) so as to easily cause laser oscillation. There is. For this reason, a semiconductor distributed Bragg reflector formed by alternately laminating a low-refractive-index material made of AlAs and a high-refractive-index material made of GaAs with a period of 1/4 wavelength is usually used.

By the way, as described above, a long wavelength band laser having a laser wavelength of 1.1 μm or more used for optical communication, for example, a long wavelength band having a laser wavelength of 1.3 μm or 1.55 μm. In the laser, InP is used for the production substrate and InGaAsP is used for the active layer. However, the lattice constant of InP of the substrate is large, and a large difference in the refractive index cannot be obtained with a reflecting mirror material that matches the substrate. Must be more than pairs. Another problem with the semiconductor laser formed on the InP substrate is that the characteristics greatly change with temperature. For this reason, it is necessary to add a device for keeping the temperature constant, and it is difficult to use the device for general purposes such as consumer use. Light emitting semiconductors have not yet been put to practical use.

As an invention made to solve such a problem, one disclosed in Japanese Patent Application Laid-Open No. 9-237942 is known. According to this, a GaAs substrate is used as a production substrate, and a semiconductor layer made of AlInP that can be lattice-matched with the substrate is used as a low refractive index layer of at least one of the semiconductor distributed Bragg reflectors in the lower part on the substrate side. A semiconductor layer made of GaInNAs is used as a high refractive index layer of at least one of the lower and upper semiconductor distributed Bragg reflecting mirrors so that a larger refractive index difference is obtained than in the prior art. It is to realize a mirror.

Further, GaInNAs is used as a material for the active layer. This is because the band gap (forbidden band width) is increased from 1.4 eV to 0 eV by increasing the N composition.
0.85 μm
This is because it can be used as a material that emits a longer wavelength. In addition, since lattice matching with the GaAs substrate is possible, the semiconductor layer made of GaInNAs is 1.3 μm.
Reference is also made to the fact that it is preferable as a material for long-wavelength surface emitting semiconductor lasers in the m-band and 1.55 μm band.

[0007] However, conventionally, this only suggests the possibility of realizing a surface emitting semiconductor laser in a wavelength band longer than 0.85 µm, and such a device is not actually realized. This is because the basic configuration is almost theoretically determined, but a more specific configuration for realizing stable laser emission is still unknown.

As an example, a semiconductor distributed Bragg reflector formed by alternately laminating a low-refractive-index material made of AlAs and a high-refractive-index material made of GaAs at a period of 1/4 wavelength as described above is used. Or a device using a semiconductor layer made of AlInP, which is lattice-matched to the same substrate as the low refractive index layer of the semiconductor distributed Bragg reflector, as disclosed in JP-A-9-237942. The laser element does not emit light at all,
Alternatively, even if light is emitted, the light emission efficiency is low, which is far from a practical level. This is because the material containing Al is chemically very active, and crystal defects due to Al are likely to occur. In order to solve this problem, it is necessary to use a GaInNP containing no Al as disclosed in Japanese Patent Application Laid-Open Nos. 8-340146 and 7-307525.
There is a proposal for forming a semiconductor distributed Bragg reflector from GaAs and GaAs. However, the refractive index difference between GaInNP and GaAs is about half of the refractive index difference between AlAs and GaAs, and the number of stacked reflectors is very large, making it difficult to manufacture.

That is, at present, optical fiber communication is expected in a computer network or the like. However, a long wavelength band surface emitting semiconductor laser having a laser wavelength of 1.1 μm to 1.7 μm and a communication system using the same can be used. It does not exist and its appearance is longing for.

[0010]

According to the present invention, a laser oscillation wavelength used for such optical communication or the like is 1.1 μm or more.
1. Field of the Invention The present invention relates to a long-wavelength surface emitting semiconductor laser having a wavelength of 1.7 μm and an optical communication system using the same. By mounting an optical connector on the surface emitting semiconductor laser device chip or an optical fiber drawn from a module package for picking up the chip, an easy and reliable optical communication system can be constructed, and the oscillation wavelength can be reduced. An object of the present invention is to propose an optical communication system that enables a human body to perform safer wiring work by setting it outside the visible region (wavelength range of 0.4 μm to 0.7 μm).

A second object of the present invention is to use a long-wavelength surface emitting semiconductor laser device chip having a laser oscillation wavelength of 1.1 μm to 1.7 μm, which can be used stably, as a light emitting light source. An easy and reliable optical communication system can be constructed by attaching an optical connector to a chip or an optical fiber drawn from a module package that picks up the chip, and the oscillation wavelength can be set in the visible region (wavelength 0.4 μm to 0.7 μm). The scope of the present invention is to propose an optical communication system that enables a safer wiring construction by the human body by setting it outside the range.

[0012]

According to the present invention, in order to achieve the above object, first, in a laser chip and an optical communication system connected to the laser chip, the laser chip has an oscillation wavelength of 1.1 μm to 1 μm. 0.7 μm, and the light-generating active layer is a layer whose main element is Ga, In, N, As or a layer consisting of Ga, In, As. What is claimed is: 1. A surface-emitting type semiconductor laser device chip having a resonator structure including a reflecting mirror provided at a lower portion, wherein the reflecting mirror periodically changes the refractive index of a material layer constituting the reflecting mirror to be small / large and is incident. A semiconductor distributed Bragg reflector for reflecting light by light wave interference, and the material layer having a small refractive index is made of Al _x Ga _{1 -x} As.
(0 <x ≦ 1) and then, the material layer of the refractive index is large is Al _y
A reflecting mirror having Ga _1-y As (0 ≦ y <x ≦ 1),
And a material layer Al _z Ga _{1 -z} As (0 ≦ y <z) in which the refractive index takes a value between small and large between the material layers with small and large refractive indexes.
<X ≦ 1) is used as a light emitting light source, and the optical communication system has an optical connector for tightly connecting two optical fibers, and the optical connector is The optical fiber comprises a member for covering the optical fiber with the connecting portion and a member for holding the outside of the member.

Secondly, in a laser chip and an optical communication system connected to the laser chip, the laser chip has an oscillation wavelength of 1.1 μm to 1.7 μm, and an active layer for generating light includes a main element. Is Ga, In, N, As
Or a layer made of Ga, In, As, and a surface emitting semiconductor laser device chip having a resonator structure including reflectors provided above and below the active layer in order to obtain a laser beam. The reflector is a semiconductor distributed Bragg reflector in which the refractive index of the material constituting the reflector changes periodically as small / large and reflects incident light by light wave interference. Al _x Ga _1-x
As (0 <x ≦ 1), the material having a large refractive index is Al
a reflecting mirror with _y Ga _1-y As (0 ≦ y <x ≦ 1),
GaInP or Ga between the active layer and the reflector.
A surface-emitting type semiconductor laser device chip provided with a non-light-emitting recombination preventing layer made of InPAs is used as a light-emitting source. The optical communication system has an optical connector for closely connecting two optical fibers and the optical connector. Is made up of a member for covering the two optical fibers with a connecting portion and a member for holding the outside of the member.

[0014]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS First, an example of a long-wavelength surface emitting semiconductor laser having a small laser oscillation wavelength of 1.1 to 1.7 .mu.m, which is a light emitting element applied to the optical communication system of the present invention, having a small transmission loss. This will be described with reference to FIG.

As described above, a long-wavelength surface emitting semiconductor laser with a laser oscillation wavelength of 1.1 μm to 1.7 μm to which the present invention is applied is conventionally realized only with the suggestion of the possibility. The materials for the use, as well as the more specific and detailed composition, were unknown. In the present invention, a material such as GaInNAs is used for the active layer, and a more specific configuration is clarified. The details are described below.

In the present invention, n-Ga having a plane orientation of (100) is used.
On the As substrate, n-Al _x Ga _{1 -x} A with a thickness (thickness of λ / 4) of 発 振 of the oscillation wavelength λ in each medium.
s (x = 1.0) (low refractive index layer to low refractive index layer) and n−
An n-semiconductor distributed Bragg reflector (AlAs / GaAs lower semiconductor distributed Bragg reflector) in which 35 cycles of Al _y Ga _1-y As (y = 0) (high refractive index layer to high refractive index layer) are alternately stacked. And n-Ga _x In _1-x P _{y having} a thickness of λ / 4 is formed thereon.
As _1-y (x = 0.5, y = 1) layers were laminated. In this example _{n-Ga x In 1-x} P y As 1-y (x = 0.5, y =
1) The layer is also a part of the lower reflecting mirror and is a low refractive index layer (a layer having a small refractive index).

An undoped lower GaAs spacer layer, an active layer (quantum well active layer), which is a three-layer Ga _x In _1-x As quantum well layer, and a GaAs barrier layer (20 n
m) and an undoped upper G layer
The aAs spacer layer is laminated to form a resonator having a thickness of one oscillation wavelength λ (thickness of λ) in the medium.

In addition, C (carbon) doped p-
Ga _x In _{1-x Py} As _1-y (x = 0.5, y = 1) layer and Z
A periodic structure (one cycle) in which n-doped p-Al _x Ga _1-x As (x = 0) is alternately stacked with a thickness of １ ／ times the oscillation wavelength λ in each medium is stacked. C-doped p-Al _x Ga _{1 -x} As (x = 0.9) and Zn-doped p
A semiconductor distributed Bragg reflector (a periodic structure (25 periods) in which -Al _x Ga _{1 -x} As (x = 0) is alternately stacked with a thickness of １ ／ times the oscillation wavelength λ in each medium; Al _0.9 Ga _0.1 As / GaAs upper semiconductor distributed Bragg reflector)
Is formed. In this example _{p-Ga x In 1-x} P y As
_{The 1-y} (x = 0.5, y = 1) layer is also a part of the upper reflecting mirror and is a low refractive index layer (a layer having a small refractive index).

Here, both the upper and lower reflectors are formed by alternately laminating a low refractive index layer (a layer having a low refractive index) / a high refractive index layer (a layer having a high refractive index). Between these, the material layer Al _z G whose refractive index takes a value between small and large
a _1-z As (0 ≦ y <z <x ≦ 1) is provided. FIG.
Is a material layer Al _z Ga _{1 -z} As having a refractive index between small and large between a low refractive index layer (a layer with a small refractive index) and a high refractive index layer (a layer with a large refractive index). 1 shows a part of a semiconductor distributed Bragg reflector provided with (0 ≦ y <z <x ≦ 1) (FIG. 1)
Then, the illustration is omitted because the figure becomes complicated).

Conventionally, it has been studied to provide such a material layer for a semiconductor laser having a laser wavelength of 0.85 μm band, but it is still in the study stage, and the material and its thickness are not described in detail. Not considered. Further, the laser oscillation wavelength as in the present invention is 1.1 μm to 1.7 μm.
No consideration has been given to a long-wavelength surface emitting semiconductor laser having a wavelength of m. The reason for this is that this field (a long-wavelength surface emitting semiconductor laser having a laser oscillation wavelength of 1.1 μm to 1.7 μm) is a new field, and little research has yet been made.

The present inventor has quickly noticed the usefulness of this field (a long-wavelength surface emitting semiconductor laser having a laser oscillation wavelength of 1.1 μm to 1.7 μm and optical communication using the same).
In order to realize it, we studied diligently.

In such a material layer, the refractive index of the material layer is changed continuously or stepwise by controlling the gas flow rate at the time of formation and changing the Al composition continuously or stepwise. And formed.

More specifically, Al _z Ga _{1 -z} As (0 ≦
(y <z <x ≦ 1) The layer is formed so that the value of z of the layer changes from 0 to 1.0, that is, the ratio of Al to Ga gradually changes, such as GaAs to AlGaAs to AlAs. This is created by controlling the gas flow during layer formation as described above. Al and G
The ratio a may be formed so as to change continuously as described above, or the same effect can be obtained even if the ratio changes stepwise.

The reason for providing such a material layer is to solve the problem that the electrical resistance of the p-semiconductor distributed Bragg reflector, which is one of the problems of the distributed Bragg reflector, is high. This is due to the hetero barrier generated at the interface between the two types of semiconductor layers constituting the semiconductor distributed Bragg reflector. However, as in the present invention, the interface between the low refractive index layer and the high refractive index layer is changed from one composition to the other. It is possible to suppress the generation of the hetero barrier by changing the Al composition gradually to the composition and changing the refractive index.

Further lasing wavelength, such as such a refractive index takes a value between the small and large material layer _{Al z Ga 1-z As (} 0 ≦ y <z <x ≦ 1) the invention is 1 .1 μm to 1.7 μ
5 nm to 50 nm in the case of a long-wavelength surface emitting semiconductor laser
It is preferable that the thickness is less than 10 nm. If the thickness is smaller than this, there is a problem that the resistance becomes large and the current hardly flows, and the element generates heat and the driving energy becomes high. In addition, when the thickness is large, the resistance becomes small, which is advantageous in terms of heat generation of the element and driving energy, but there is a problem that the reflectance cannot be obtained this time,
As described above, it is necessary to select an optimum range (thickness of 5 nm to 50 nm).

As described above, it has been considered to provide such a material layer for a conventional semiconductor laser having a laser wavelength of 0.85 μm band. In the case of a long-wavelength surface emitting semiconductor laser having a wavelength of 1.7 μm, it is more effective. This is because, for example, in order to obtain the same reflectance (for example, 99.5% or more), the band from 1.1 μm to 1.0 μm is more than 0.85 μm.
In the case of the 7 μm band, such a material layer can be approximately doubled, so that the resistance value of the semiconductor distributed Bragg reflector can be reduced, the operating voltage, the oscillation threshold current, and the like are reduced, and the laser device This is advantageous in terms of preventing heat generation, stable oscillation, and low energy driving.

In other words, providing such a material layer on a semiconductor distributed Bragg reflector is particularly effective for a long-wavelength surface emitting semiconductor laser having a laser oscillation wavelength of 1.1 μm to 1.7 μm as in the present invention. It can be said that it is a device.

As an example of a more detailed examination result for obtaining an effective reflectance, for example, in a 1.3 μm band surface emitting laser device, Al _x Ga _{1 -x} As (x = 1.0)
(Low refractive index layer to low refractive index layer) and Al _y Ga _1-y As (y
= 0) (in the case of a high refractive index layer-refractive index large layer) 20 period stacking, the reflectance of the semiconductor distributed Bragg reflector is 99.7% or less _{Al z Ga 1-z As (} 0 ≦ y <z
<X ≦ 1) The thickness of the layer is 30 nm. The wavelength band in which the reflectance is 99.5% or more is 53 nm. When the reflectance is designed to be 99.5% or more, it is only necessary to control the film thickness by ± 2%. Therefore, when prototypes of 10 nm, 20 nm, and 30 nm which are equivalent to and thinner than this were prototyped, the reflectivity could be kept to a practically acceptable level, and the resistance value of the semiconductor distributed Bragg reflector could be reduced. A 1.3 μm band surface emitting laser device was realized, and laser oscillation was successful. Other configurations of the prototyped laser element are as described below.

In the multilayer reflector, there is a band having a high reflectance including the design wavelength (assuming that the film thickness can be completely controlled). It is referred to as a high-reflectance band (including a region where the reflectivity is equal to or more than a required value for a target wavelength). This is the region where the reflectance at the design wavelength is the highest and decreases very little as the wavelength increases. It drops off sharply from some area. Originally, it is necessary to completely control the film thickness of the multilayer mirror at the atomic layer level so that the reflectance is higher than the required reflectance for the target wavelength. But actually ± 1
Since a film thickness error of about% occurs, the target wavelength deviates from the wavelength having the highest reflectance. For example, if the target wavelength is 1.3
In the case of μm, when the film thickness control is shifted by 1%, the wavelength having the highest reflectance is shifted by 13 nm. Therefore, it is desirable that the band of the high reflectance (here, the region where the reflectance is equal to or more than a required value with respect to a target wavelength) is wide. However, thickening the intermediate layer tends to narrow this band.

As described above, in a long-wavelength surface emitting semiconductor laser having a laser oscillation wavelength of 1.1 μm to 1.7 μm as in the present invention, the configuration of such a semiconductor distributed Bragg reflector is devised and optimized. Since the resistance value can be reduced while maintaining a high reflectance, the operating voltage, the oscillation threshold current, and the like can be reduced, so that heat generation of the laser element, stable oscillation, and low-energy driving can be achieved.

Referring again to FIG. 1, the uppermost p-Al _x G
The a _1-x As (x = 0) layer also has a role as a contact layer (p-contact layer) for making contact with the electrode.

Here, the In composition x of the quantum well active layer is 3
9% (Ga0.61In0.39As). The thickness of the quantum well active layer was 7 nm. The quantum well active layer is made of GaAs.
It had a compression strain of about 2.8% with respect to the substrate.

The whole surface-emitting type semiconductor laser was grown by MOCVD. In this case, no lattice relaxation was observed. The materials constituting each layer of the semiconductor laser include TMA (trimethylaluminum), TMG (trimethylgallium), TMI (trimethylindium),
AsH ₃ (arsine) and PH ₃ (phosphine) were used. H ₂ was used as a carrier gas. In the case where the strain is large as in the active layer (quantum well active layer) of the device shown in FIG. here,
The GaInAs layer (quantum well active layer) is grown at 550 ° C. The MOCVD method used here has a high degree of supersaturation and is suitable for crystal growth of a high strain active layer. In addition, high vacuum is not required as in the MBE method, and the supply flow rate and supply time of the source gas may be controlled.

In this example, the portion outside the current path was irradiated with protons (H ⁺ ) to form an insulating layer (high resistance portion) to form a current narrowing portion.

In this example, a p-side electrode is formed on the p-contact layer which is the uppermost layer of the upper reflecting mirror and is a part of the upper reflecting mirror except for the light emitting portion, and is formed on the back surface of the substrate. An n-side electrode was formed.

In this example, the active region (in this embodiment, a resonator composed of the upper and lower spacer layers and the multiple quantum well active layer) sandwiched between the upper and lower reflecting mirrors and into which carriers are injected and recombined is used. In the material containing Al (II
The ratio of the low refractive index layer of the lower and upper reflectors closest to the active layer is G.
It is set to _{a x In 1-x P y} As 1-y (0 <x <1,0 <y ≦ 1) non-radiative recombination preventing layer. Since the carriers are confined between the low-refractive index layers of the upper and lower reflectors, which are closest to the active layer and have a wide gap, only the active region is constituted by a layer containing no Al (the percentage of group III is 1% or less). However, if the low-refractive index layer (wide gap layer) of the reflector in contact with the active region has a structure including Al, when carriers are injected and recombined, non-radiative recombination occurs at this interface, and the luminous efficiency is reduced. Will drop. Therefore, it is desirable that the active region be formed of a layer containing no Al.

The Ga _x In _{1-x Py} As _1-y (0 <x
The non-radiative recombination preventing layer composed of <1, 0 <y ≦ 1)
Its lattice constant is smaller than that of a GaAs substrate and has tensile strain.

In the epitaxial growth, since the growth is performed by reflecting the information of the base, if there is a defect on the surface of the substrate, it goes up to the growth layer. However, it is known that the presence of a strained layer is effective in preventing such defects from climbing.

When the above defects reach the active layer, the luminous efficiency is reduced. In the case of an active layer having a strain, there arises a problem that the critical thickness is reduced and a layer having a required thickness cannot be grown. In particular, when the amount of compressive strain of the active layer is large, for example, 2% or more, or when the thickness of the strained layer is larger than the critical thickness, even if non-equilibrium growth such as low-temperature growth is performed, growth cannot be performed due to the presence of defects. This is particularly problematic. If a strained layer is present, such a defect can be prevented from climbing up, so that the luminous efficiency can be improved, a layer having a compressive strain of 2% or more of the active layer can be grown, or the thickness of the strained layer can be reduced to a critical film. It becomes possible to grow thicker than thick.

This Ga _x In _{1-x Py} As _1-y (0 <x <
1,0 <y ≦ 1) layer also has the role of carrier confinement in which the active region in contact with the active region but, Ga _x an In
_{The 1-x Py} As _1-y (0 <x <1, 0 <y ≦ 1) layer can have a larger band gap energy as the lattice constant decreases. For example, in the case of Ga _x In _1-x P (when y = 1), as x increases and approaches x GaP, the lattice constant increases and the band gap increases. Band gap E
g is a direct transition, Eg (Γ) = 1.351 + 0.643x + 0.786
x ² , and Eg (X) = 2.24 + 0.02x in the indirect transition. Therefore, the active region and Ga _x In _{1-x Py} As _1-y (0
<X <1, 0 <y ≦ 1) The hetero barrier in the layer is large, so that the carrier confinement is good, the threshold current is reduced,
This has the effect of improving temperature characteristics.

Further, the Ga _x In _{1-x Py} As _1-y (0 <
x <1, 0 <y ≦ 1) The non-radiative recombination preventing layer has a larger lattice constant than the GaAs substrate, has a compressive strain, and has a lattice constant of the active layer of Ga _x.
It has a larger compressive strain than the In _{1-x Py} As _1-y (0 <x <1, 0 <y ≦ 1) layer.

The Ga _x In _{1-x Py} As _1-y (0 <x
<1, 0 <y ≦ 1) Since the direction of strain of the layer is the same as that of the active layer, it acts in the direction of reducing the substantial amount of compressive strain felt by the active layer. The larger the strain is, the more easily affected by external factors. Therefore, it is particularly effective when the amount of compressive strain of the active layer is as large as 2% or more, or when it exceeds the critical film thickness.

For example, a surface emitting laser having an oscillation wavelength of 1.3 μm band is preferably formed on a GaAs substrate, and a semiconductor multilayer mirror is often used as a resonator, and the total thickness is 5 to 8 μm. It is necessary to grow 50 to 80 semiconductor layers before growing the active layer. (On the other hand, in the case of an edge-emitting laser, the total thickness before growing the active layer is about 2 μm, and it is only necessary to grow about three semiconductor layers.) In this case, even if a high-quality GaAs substrate is used, various methods are used. Due to the cause (defects once generated basically creep up in the crystal growth direction and defects are generated at the hetero interface).
The defect density on the surface immediately before the active layer growth is inevitably higher than the defect density on the s substrate surface. If the insertion of a strained layer or the substantial amount of compressive strain felt by the active layer is reduced before the growth of the active layer, the influence of defects on the surface immediately before the growth of the active layer can be reduced.

In this example, since Al is not contained in the active region and at the interface between the reflector and the active region, non-radiative recombination caused by crystal defects caused by Al at the time of carrier injection is eliminated. And non-radiative recombination was reduced.

As described above, it is preferable to apply a structure that does not contain Al at the interface between the reflector and the active region, that is, to provide a non-radiative recombination preventing layer for both the upper and lower reflectors. It is effective even when applied to a reflector. In this example, both the upper and lower reflecting mirrors are semiconductor distributed Bragg reflecting mirrors, but one reflecting mirror may be a semiconductor distributed Bragg reflecting mirror and the other reflecting mirror may be a dielectric reflecting mirror. In the above-described example, only the layer closest to the active layer in the low-refractive index layer of the reflector is Ga _x In _{1-x Py} As _1-y (0 <x <1,
Although a non-radiative recombination prevention layer of 0 <y ≦ 1) is used, a plurality of layers of Ga _x In _{1-x Py} As _1-y (0 <x <1, 0 <y ≦
1) may be a non-radiative recombination preventing layer.

Further, in this example, this idea is applied to the lower reflector between the GaAs substrate and the active layer, and a crystal defect caused by Al, which is a problem at the time of growing the active layer, rises into the active layer. The adverse effect is suppressed, and the active layer can be crystal-grown with high quality. As a result, a surface-emitting type semiconductor laser having high luminous efficiency and sufficient reliability for practical use was obtained. In addition, not all of the low refractive index layers of the semiconductor distributed Bragg reflector but at least a portion closest to the active region is Ga _x In _{1 -x Py} As _{1 -y} (0 <x <
Since only 1, 0 <y ≦ 1) layers, the above-described effect can be obtained without particularly increasing the number of stacked reflectors.

The oscillation wavelength of the surface emitting semiconductor laser manufactured in this manner was about 1.2 μm. GaInAs on a GaAs substrate has a longer wavelength due to an increase in the In composition, but with an increase in the amount of strain. Conventionally, up to 1.1 μm has been considered to be the limit of a longer wavelength (see the document “IEEE Photo”).
onics. Technol. Lett. Vol. 9
(1997) p. 1319-1321 ").

However, as manufactured by the present inventors, a highly strained GaInAs quantum well active layer can be coherently grown thicker than before by a growth method with a high degree of non-equilibrium, such as growth at a low temperature of 600 ° C. or less. Reached 1.2 μm. This wavelength is transparent to the Si semiconductor substrate. Therefore, light transmission through the Si substrate becomes possible in a circuit chip in which an electronic element and an optical element are integrated on the Si substrate.

As apparent from the above description, it was found that a long-wavelength surface-emitting type semiconductor laser can be formed on a GaAs substrate by using GaInAs having a large In composition and a high compression strain for the active layer.

As described above, such a surface emitting semiconductor laser can be grown by MOCVD, but other growth methods such as MBE can also be used.
In addition, a triple quantum well structure (TQ
Although the example of W) is shown, a structure (SQW, MQW) using a quantum well of another number of wells or the like can be used.

The structure of the laser may be another structure. Although the length of the resonator is set to the thickness of λ, it can be set to an integral multiple of λ / 2. Desirably, it is an integral multiple of λ. Also, an example in which GaAs is used as the semiconductor substrate has been described.
The above concept can be applied even when another semiconductor substrate such as P is used. The period of the reflecting mirror may be another period.

In this example, as the active layer, a layer whose main element is Ga, In, or As, that is, Ga _x In _{1 -x}
Although an example of As (GaInAs active layer) has been described, in order to perform laser oscillation of a longer wavelength, a layer (GaInNAs active layer) in which N is added and the main element is Ga, In, N, and As is used. Good.

By actually changing the composition of the GaInNAs active layer, it was possible to perform laser oscillation in each of the 1.3 μm band and the 1.55 μm band. By studying the composition, a longer wavelength, for example, 1.7
A surface emitting laser in the μm band is also possible.

Also, when GaAsSb is used for the active layer,
A 1.3 μm band surface emitting laser can be realized on an aAs substrate. As described above, a semiconductor laser having a wavelength of 1.1 μm to 1.7 μm has not conventionally been available with a suitable material.
By using aInAs, GaInNAs, and GaAsSb, and providing a non-radiative recombination preventing layer, a high-performance surface emitting laser in a long wavelength region of the 1.1 μm to 1.7 μm band where stable oscillation has been difficult in the past. Can be realized.

Next, another configuration of a long wavelength band surface emitting semiconductor laser which is a light emitting element applied to the optical transmitting / receiving system of the present invention will be described with reference to FIG.

In this case as well, as in the case of FIG.
00) is used. N-Al _x Ga _{1 -x} As (x = 0.9) and n-A at a thickness of 1/4 (λ / 4 thickness) of the oscillation wavelength λ in each medium.
n in which l _x Ga _1-x As (x = 0) are alternately stacked for 35 periods
Forming a semiconductor distributed Bragg reflector (Al _0.9 Ga _0.1 As / GaAs lower reflector) on which a λ / 4 thick n-Ga _{x
In 1-x P y As 1} -y (x = 0.5, y = 1) was laminated layer. In this example _{n-Ga x In 1-x} P y As 1-y (x = 0.
5, y = 1) layer is also a part of the lower reflecting mirror and is a low refractive index layer.

On top of that, undoped lower GaAs
A multi-quantum well active layer (a quantum well active layer) composed of a spacer layer, an active layer (quantum well active layer) which is a three-layer Ga _x In _1-x N _y As _1-y quantum well layer, and a GaAs barrier layer (15 nm). In the example, triple quantum well (TQW)) and undoped upper Ga
An As spacer layer is laminated to form a resonator having a thickness (λ thickness) of one oscillation wavelength in the medium.

Further, a p-semiconductor distributed Bragg reflector (upper reflector) is formed thereon.

The upper reflecting mirror is made of AlA to be a selectively oxidized layer.
s layer is sandwiched between a GaInP layer and an AlGaAs layer by 3λ /
4 low refractive index layer (thickness of (λ / 4-15 nm)
C-doped p-Ga_xIn_1-xP_yAs_1-y(X = 0.5, y
= 1) layer, C-doped p-Al _zGa_1-zAs (z = 1)
Selective oxidation layer (thickness 30 nm), thickness (2λ / 4-15)
nm) C-doped p-Al_xGa_1-xAs layer (x = 0.
9)), a GaAs layer having a thickness of λ / 4 (one period), and C
Doped p-Al_xGa_1-xAs layer (x = 0.9) and p-
Al_xGa_1-xAs (x = 0) layer in each medium
Periodic structure laminated alternately with a thickness of 1/4 times the oscillation wavelength
Structure (22 cycles)
Reflector (Al_0.9Ga_0.1As / GaAs upper reflector).

Also in this example, although not shown in FIG. 3 because it becomes complicated in FIG. 3, the structure of the semiconductor distributed Bragg reflector has a low refractive index layer (low refractive index layer) as shown in FIG. Layer) and a high refractive index layer (high refractive index layer), a material layer Al _z Ga _1-z having a refractive index between low and high
As (0 ≦ y <z <x ≦ 1) is provided.

The uppermost p-Al _x Ga _{1 -x} As
The (x = 0) layer also serves as a contact layer (p-contact layer) for making contact with the electrode.

Here, the In composition x of the quantum well active layer is 37
%, And the N (nitrogen) composition was 0.5%. The thickness of the quantum well active layer was 7 nm.

The surface-emitting type semiconductor laser was grown by MOCVD. The materials constituting each layer of the semiconductor laser include TMA (trimethylaluminum), TM
G (trimethyl gallium), TMI (trimethyl indium), AsH ₃ (arsine), PH ₃ (phosphine), and DMHy (dimethylhydrazine) were used as raw materials for nitrogen. DMHy decomposes at low temperature, so 600
It is suitable for low-temperature growth at a temperature of less than or equal to ° C., and is particularly preferable when growing a quantum well layer having a large strain that requires low-temperature growth. Note that H ₂ was used as a carrier gas.

In this example, the GaInNAs layer (quantum well active layer) was grown at 540 ° C. The MOCVD method has a high degree of supersaturation and is suitable for crystal growth of a material containing N and another V group simultaneously. In addition, high vacuum is not required as in the MBE method, and the supply flow rate and supply time of the source gas may be controlled.

[0065] Further in this example, the predetermined size mesa portion of the _{p-Ga x In 1-x} P y As 1-y (x = 0.5, y =
Until reaching 1) _{layer, p-Al z Ga 1-} z As (z = 1)
The selective oxidation layer is formed by exposing the side surface, and the Al _x Ga _{1 -z} As (z = 1) layer on the side surface is oxidized from the side surface with water vapor to form an Al _x O _y current narrowing layer. .

Finally, the portion removed by mesa etching with polyimide (insulating film) is buried and flattened, the polyimide on the upper reflecting mirror is removed, and a p-side electrode is formed on the p-contact layer except for the light emitting portion. And n on the back surface of the GaAs substrate.
Side electrodes were formed.

In this example, the lower part of the selectively oxidized layer
Ga as part of the top reflector_xIn_{1 -x}P_yAs_1-y(0 <
x <1, 0 <y ≦ 1) layers are inserted. For example
In the case of etching, a sulfuric acid-based etchant is used.
For example, the GaInPAs system is an etch to the AlGaAs system.
Ga can be used as a stopping layer._xIn
_1-xP_yAs_1-y(0 <x <1, 0 <y ≦ 1) layer inserted
The high mesa etching for selective oxidation.
Can be strictly controlled. Therefore, uniformity and reproducibility are improved.
Cost can be reduced.

When the surface-emitting type semiconductor laser (element) of this example is integrated one-dimensionally or two-dimensionally, the controllability at the time of element production is improved, and the uniformity of the element characteristics of each element in the array is improved. In addition, there is an effect that reproducibility becomes extremely good.

In this example, Ga _x In _{1-x Py} As _1-y (0 <x <1, 0 <y ≦
1) Although the layer is provided on the upper reflecting mirror side, it may be provided on the lower reflecting mirror side.

Also in this example, in an active region (in this embodiment, a resonator composed of upper and lower spacer layers and a multiple quantum well active layer) sandwiched between the upper and lower reflectors and into which carriers are injected and recombined, No material containing Al is used in the active region, and the lower refractive index layers of the lower and upper mirrors, which are closest to the active layer, are formed of Ga _x In _{1-x Py} As _1-y (0
<X <1, 0 <y ≦ 1). That is, in this example, Al is not included in the active region and at the interface between the reflecting mirror and the active region, so that non-radiative recombination caused by crystal defects caused by Al during carrier injection is reduced. Can be done.

It is preferable to apply a structure in which Al is not contained at the interface between the reflecting mirror and the active region to the upper and lower reflecting mirrors as in this example, but it is effective to apply it to only one of the reflecting mirrors. . In this example, both the upper and lower reflecting mirrors are semiconductor distributed Bragg reflecting mirrors, but one reflecting mirror may be a semiconductor distributed Bragg reflecting mirror and the other reflecting mirror may be a dielectric reflecting mirror.

Further, also in this example, the same idea as in the case of the example of FIG. 1 is applied to the lower reflector between the GaAs substrate and the active layer, so that crystal defects caused by Al which are problematic at the time of growing the active layer. Of the active layer is suppressed, and crystal growth of the active layer with high quality can be achieved.

Note that such a non-radiative recombination preventing layer is
1 and 3, a part of the semiconductor distributed Bragg reflector is formed, and its thickness is 、 of the oscillation wavelength λ in the medium (thickness of λ / 4). ). Alternatively, a plurality of layers may be provided.

As is clear from the above description, a surface emitting semiconductor laser having high luminous efficiency and sufficient reliability for practical use was obtained by such a configuration. Also, not all of the low refractive index layers of the semiconductor distributed Bragg reflector, but at least the portion closest to the active region is Ga _x In containing no Al.
_{1-x Py} As _1-y (0 <x <1, 0 <y ≦ 1) is used only as a non-radiative recombination prevention layer, so that the above-described effect can be obtained without particularly increasing the number of stacked reflectors. I was able to.

In addition, even in such a configuration, since the polyimide can be easily embedded, the wiring (p-side electrode in this example) is hardly disconnected, and a device having high reliability can be obtained.

The oscillation wavelength of the surface emitting semiconductor laser manufactured as described above was about 1.3 μm.

In this example, the main elements are Ga, In,
A layer composed of N and As was used as an active layer (GaInNAs
As a result, a long-wavelength surface emitting semiconductor laser could be formed on the GaAs substrate. Further, the current was narrowed by selective oxidation of the selectively oxidized layer containing Al and As as main components, so that the threshold current was low.

According to the current narrowing structure using the current narrowing layer made of the Al oxide film in which the selectively oxidized layer is selectively oxidized,
By forming the current narrowing layer close to the active layer, the spread of current can be suppressed, and carriers can be efficiently confined in a minute region that is not exposed to the atmosphere. Further oxidized to Al
By forming an oxide film, the refractive index is reduced, and light can be efficiently confined in a minute region in which carriers are confined by the effect of the convex lens, and the efficiency is extremely improved, and the threshold current can be reduced. In addition, since the current narrowing structure can be easily formed, the manufacturing cost can be reduced.

As is apparent from the above description, a 1.3 μm band surface emitting semiconductor laser can be realized in the configuration as shown in FIG. 3 as in the case of FIG. Is obtained.

The surface-emitting type semiconductor laser shown in FIG.
The growth can be performed by the MOCVD method as in the case of the above, but another growth method such as the MBE method can also be used.
Although DMHy is used as a nitrogen source, activated nitrogen and other nitrogen compounds such as NH ₃ can be used.

Further, although an example of a triple quantum well structure (TQW) is shown as the laminated structure of the active layer, a structure using other quantum wells (SQW, DQW, MQW) or the like may be used. The structure of the laser may be another structure.

In the surface-emitting type semiconductor laser shown in FIG. 3, by changing the composition of the GaInNAs active layer, 1.
A surface emitting semiconductor laser in the 55 μm band, and even in the longer wavelength 1.7 μm band, is also possible. The GaInNAs active layer may contain other III-V elements such as Tl, Sb, and P. Also, even if GaAsSb is used for the active layer, a 1.3 μm band surface emitting semiconductor laser can be realized on a GaAs substrate.

When GaInAs is used for the active layer,
Conventionally, up to 1.1 μm has been considered to be the limit of increasing the wavelength.
The quantum well active layer can be grown thicker than before, and the wavelength can reach up to 1.2 μm. in this way,
Conventionally, there is no suitable material for the semiconductor laser having a wavelength of 1.1 μm to 1.7 μm, but GaInAs, G
By using aInNAs and GaAsSb and providing a non-radiative recombination prevention layer, a high-performance surface-emitting laser can be realized in the long wavelength region of the 1.1 μm to 1.7 μm wavelength band where stable oscillation has conventionally been difficult. As a result, application to optical communication systems has become possible.

FIG. 4 shows an example in which such a long-wavelength band surface emitting semiconductor laser device is formed as a number of chips on an n-GaAs wafer having a plane orientation of (100), and a laser device chip. 1 to n laser elements are formed in the laser element chip shown here, and the number n and the arrangement method are determined according to the application.

FIG. 5 shows an example of a communication system using a long-wavelength band surface emitting semiconductor laser. The optical fiber is connected to the surface emitting semiconductor laser device chip or a module package accommodating the chip and an optical fiber connected thereto. 1 shows an optical fiber for use and an optical connector for connecting each optical fiber. The optical fiber drawn from the module package and the communication optical fiber connected thereto are generally joined by an optical connector. In an optical connector, if there is an air layer at the joint, reflection occurs because the air layer has a different refractive index from the optical fiber. For this reason, a method of injecting a gel-like refractive index matching agent to suppress the fluctuation of the refractive index of the bonding portion and a PC for completely bringing the optical fibers into close contact with each other.
(Physical Contact) connection, but in this embodiment PC
Perform with connection. In the figure, the optical connector is bonded and fixed to a ferrule for preventing breakage. Generally, a ferrule is made of a cylindrical high-strength zirconia ceramic and adhesively fixes an optical fiber in a hollow portion. FIG. 6 shows the positional relationship between the optical fiber, the ferrule, and the split sleeve. The split sleeve has the shape of a cylinder divided in the axial direction as shown in the figure.
As a material, phosphor bronze is generally used. As shown in the figure, the ferrules butt against each other with a split sleeve. Both ferrules are pressed down by a certain pressure by both springs, and PC connection can be performed. This has made it possible to easily construct an optical communication system. Also, the joints were solid and highly reliable.

In general, a laser device has safety standards from the viewpoint of safety to the human body. However, the oscillation wavelength of the surface-emitting type semiconductor laser element chip is 1.1 μm to 1.7 μm, and the oscillation wavelength is in a visible region (wavelength). It is possible to meet safety standards even with a larger output than devices with a range of 0.4 μm to 0.7 μm).

[0087]

According to the first aspect, the present invention operates in the field where the laser oscillation wavelength is expected to be 1.1 μm to 1.7 μm in optical fiber communication such as a computer network and a trunk system of long-distance large-capacity communication. A surface-emitting type semiconductor laser and a communication system using the same that can reduce voltage, oscillation threshold current and the like, generate less heat from the laser element, and perform stable oscillation did not exist. By devising the method, the operating voltage, the oscillation threshold current, and the like can be lowered, the laser element generates less heat, stable oscillation can be achieved, and a low-cost practical optical communication system can be realized.

Further, since there has been no practical optical communication system in the field where the laser oscillation wavelength is in the 1.1 μm band to 1.7 μm band, the surface emitting semiconductor laser device chip used for this has not been available. Or how to connect the optical fiber drawn from the module package accommodating the chip has not been studied, but an optical connector for connecting the optical fiber as in the present invention is added. This has made it possible to easily construct an optical communication system. And the joint became strong and reliable.

Further, since the laser oscillation wavelength of the chip is in the 1.1 μm band to 1.7 μm band, the oscillation wavelength is out of the visible region (wavelength range of 0.4 μm to 0.7 μm), so that more secure wiring for the human body. The construction was realized.

Advantages Corresponding to Claim 2 In fields where the laser oscillation wavelength is expected to be in the 1.1 μm to 1.7 μm band for optical fiber communication, such as in computer networks and trunk systems for long-distance and large-capacity communication, it is stable. Although there was no usable long-wavelength band surface emitting semiconductor laser and a communication system using the same, as in the present invention, a surface emitting semiconductor laser device chip provided with a non-radiative recombination preventing layer is used. Stable oscillation was made possible, and a practical optical communication system using this as a light emitting light source was realized.

Furthermore, since there has been no practical optical communication system in the field where the laser oscillation wavelength is in the 1.1 μm band to 1.7 μm band, the surface emitting type semiconductor laser device chip used for this has been known. Or how to connect the optical fiber drawn from the module package accommodating the chip has not been studied, but an optical connector for connecting the optical fiber as in the present invention is added. This has made it possible to easily construct an optical communication system. And the joint became strong and reliable.

Further, since the laser oscillation wavelength of the chip is in the 1.1 μm band to 1.7 μm band, the oscillation wavelength is out of the visible region (wavelength range of 0.4 μm to 0.7 μm), so that more secure wiring for the human body. The construction was realized.

[Brief description of the drawings]

FIG. 1 is a sectional view of an element part of a long-wavelength band surface emitting semiconductor laser according to an embodiment of the present invention.

FIG. 2 is a partial cross-sectional view of a configuration of a semiconductor distributed Bragg reflector of a long wavelength band surface emitting semiconductor laser according to an embodiment of the present invention.

FIG. 3 is a sectional view of an element portion of another configuration of a long-wavelength band surface emitting semiconductor laser according to an embodiment of the present invention.

FIG. 4 is a plan view showing a wafer substrate and a laser element chip on which a long wavelength band surface emitting semiconductor laser element according to one embodiment of the present invention is formed.

FIG. 5 is a configuration diagram of an optical communication system including a long wavelength band surface emitting semiconductor laser, an optical fiber, and an optical connector according to an embodiment of the present invention.

FIG. 6 is a configuration diagram illustrating a positional relationship among an optical fiber, a ferrule, and a split sleeve according to an embodiment of the present invention.

 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Teruyuki Furuta 1-3-6 Nakamagome, Ota-ku, Tokyo Inside Ricoh Co., Ltd. (72) Inventor Kazuya Miyagaki 1-3-6 Nakamagome, Ota-ku, Tokyo Inside Ricoh Co., Ltd. (72) Inventor Atsuyuki Watada 1-3-6 Nakamagome, Ota-ku, Tokyo Inside Ricoh Co., Ltd. (72) Shun Sato 1-3-6 Nakamagome, Ota-ku, Tokyo Ricoh Co., Ltd. (72) Inventor Yukie Suzuki 1-3-6 Nakamagome, Ota-ku, Tokyo Inside Ricoh Co., Ltd. (72) Inventor Satoru Sugahara 1-3-6 Nakamagome, Ota-ku, Tokyo Ricoh Co., Ltd. (72) Invention Person Shinji Sato 1-3-6 Nakamagome, Ota-ku, Tokyo Inside Ricoh Company (72) Inventor Shuichi Hikichi 1-3-6 Nakamagome, Ota-ku, Tokyo Stock Association (72) Inventor Takuro Sekiya 1-3-6 Nakamagome, Ota-ku, Tokyo F-term (reference) 5R073 AA11 AA51 AA53 AA74 AB02 AB17 AB19 AB27 AB28 BA02 CA07 CB02 DA05 DA23 EA12 EA23 EA29 FA07

Claims (2)

[Claims] In a laser chip and an optical communication system connected to the laser chip, the laser chip has an oscillation wavelength of 1.1 μm to 1.7 μm, and an active layer for generating light includes a main element of Ga, A surface emitting type having a layer structure of In, N, and As or a layer of Ga, In, and As and having a resonator structure including reflectors provided above and below the active layer to obtain a laser beam. A semiconductor laser element chip, wherein the reflecting mirror is a semiconductor distributed Bragg reflecting mirror that periodically changes a refractive index of a material layer constituting the reflecting mirror to small / large and reflects incident light by light wave interference; The material layer having a small ratio is Al _x Ga _{1 -x} As.
(0 <x ≦ 1) and then, the material layer of the refractive index is large is Al _y
A reflecting mirror having Ga _1-y As (0 ≦ y <x ≦ 1),
And a material layer Al _z Ga _{1 -z} As (0 ≦ y <z) in which the refractive index takes a value between small and large between the material layers with small and large refractive indexes.
<X ≦ 1) is used as a light emitting light source, and the optical communication system has an optical connector for tightly connecting two optical fibers, and the optical connector is An optical communication system, comprising: a member that covers an optical fiber with a connection portion; and a member that holds the outside of the member. 2. In a laser chip and an optical communication system connected to the laser chip, the laser chip has an oscillation wavelength of 1.1 μm to 1.7 μm, and has an active layer for generating light, wherein the main element is Ga, A surface emitting type having a layer structure of In, N, and As or a layer of Ga, In, and As and having a resonator structure including reflectors provided above and below the active layer to obtain a laser beam. A semiconductor laser device chip, wherein the reflecting mirror is a semiconductor distributed Bragg reflecting mirror that periodically changes the refractive index of a material forming the reflecting mirror to small / large and reflects incident light by light wave interference; Is smaller than that of Al _x Ga _{1 -x} As (0 <
x ≦ 1), and the material having a large refractive index is Al _y Ga _1-y A
s (0 ≦ y <x ≦ 1), wherein GaInP or GaInPAs is provided between the active layer and the reflector.
A surface emitting semiconductor laser element chip provided with a non-radiative recombination preventing layer comprising a light emitting light source, wherein the optical communication system has an optical connector for closely connecting two optical fibers, and the optical connector is An optical communication system, comprising: a member for covering the two optical fibers with a connecting portion; and a member for holding the outside of the member.