GB848671A - Improvements in or relating to the manufacture of polymeric materials - Google Patents

Improvements in or relating to the manufacture of polymeric materials

Info

Publication number
GB848671A
GB848671A GB35082/56A GB3508256A GB848671A GB 848671 A GB848671 A GB 848671A GB 35082/56 A GB35082/56 A GB 35082/56A GB 3508256 A GB3508256 A GB 3508256A GB 848671 A GB848671 A GB 848671A
Authority
GB
United Kingdom
Prior art keywords
polyisocyanate
diphenylmethane diisocyanate
derivatives
isocyanate groups
diphenylmethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB35082/56A
Inventor
William Abbotson
Harold France
Reginald Hurd
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE562425D priority Critical patent/BE562425A/xx
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB35082/56A priority patent/GB848671A/en
Priority to DEI13987A priority patent/DE1108904B/en
Priority to FR1190066D priority patent/FR1190066A/en
Publication of GB848671A publication Critical patent/GB848671A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/794—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aromatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
    • C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
    • C08G18/8022—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with polyols having at least three hydroxy groups
    • C08G18/8029—Masked aromatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2350/00—Acoustic or vibration damping material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

A process for the manufacture of cellular materials by interacting polyesters and organic polyisocyanates is characterised in that the polyisocyanate used is a polyisocyanate composition comprising more than 50% by weight of diphenylmethane diisocyanate and at least 5% by weight of polyisocyanate containing more than two isocyanate groups, sufficient of said diisocyanate and polyisocyanate being present as carbamyl chloride derivatives to provide an ionisable chlorine content of 0,01% to 3,0%, preferably 0,1% to 1,0% by weight of the polyisocyanate composition. The polyisocyanate containing more than two isocyanate groups can be (1) added directly to the diphenylmethane diisocyanate, e.g. as benzene, toluene, diphenylmethane, diphenyl or diphenyl ether triisocyanates; (2) formed by interaction of some of the diphenylmethane diisocyanate with a polyhydric alcohol; (3) formed by partial polymerisation of the diphenylmethane diisocyanate to form isocyanurate derivatives; (4) present as the result of the manufacture of the diphenylmethane diisocyanate from a crude diaminodiphenylmethane containing triamines and other polyamines. The carbomyl chloride derivatives comprise di- and polyisocyanate compounds in which some or all the isocyanate groups have been converted to N-substituted carbamyl chloride groups, for example by direct addition of hydrogen chloride. In a typical example (1) a mixture is prepared of a polyester (from pentacrythritol, butylene glycol, adipic acid and phthalic anhydride), and alkylphenolethylene oxide condensate and water. To produce a foam there is then added a diphenylmethane diisocyanate composition. This is obtained by phosgenation and heating of an aniline-formaldehyde condensation product and contains about 30% of derivatives of triamines and also isocyanurate polymers and has an ionisable chlorine content of 0,5%.ALSO:A polysocyanate composition for use in the preparation of cellular polyurethanes comprises more than 50% by weight of diphenylmethane diisocyanate and at least 5% by weight of polyisocyanate containing more than two isocyanate groups, sufficient of said diisocyanate and polyisocyanate being present as carbamyl chloride derivatives to provide an ionisable chlorine content of 0,01% to 3% of the polyisocyanate composition. The polyisocyanate containing more than two isocyanate groups can be (1) added directly; (2) formed by interaction of some of the diphenylmethane diisocyanate with a polyhydric alcohol, e.g. with trimethylol propane to give C2H5,C (CH2OCONHR,NCO)3 (3) formed by partial polymerisation of the diphenylmethane diisoyanate to give isocyanurate derivatives, suitable catalysts being sodium methoxide or phenate, alkali metal salts of weak acids, alkali metal oxides and hydroxides or soluble metal salts such as lead 2-ethyl hexoate or zinc naphthenate; (4) formed during the manufacture of the diphenylmethane diisocyanate from crude diaminodiphenylmethane containing triand other polyamines. The carbamyl chloride derivatives are the di- and polyisocyanates of which some or all the isocyanate groups have been converted to N-substituted carbamyl chloride derivatives, for example by direct addition of hydrogen chloride or result during the phosgenation of the amines. In specific processes (a) Diphenyl methane diisocyanate is heated with sodium methoxide to give a product containing 18% of an isocyanurate derivative. The product is treated with dry hydrogen chloride to convert some of the isocyanate groups to carbamyl chloride groups;(b) a trimethylolpropane-amodi-fied diphenylmethane diisocyanate is prepared; (c) a crude reaction product of aniline and formaldehyde containing 2, 41-and 4:41-diamino-diphenylmethane and about 15% triamine is phosgenated first at 0 degree, then with heating to give a product containing the di- and polyisocyanates, and isocyanurate polymers, and also having a carbamyl chloride content.ALSO:A process for the manufacture of cellular materials by interacting polyesters and organic polyisocyanates is characterised in that the polyisocyanate used is a polyisocyanate composition comprising more than 50% by weight of diphenylmethane diisocyanate and at least 5% by weight of polyisocyanate containing more than two isocyanate groups, sufficient of said diisocyanate and polyisocyanate being present as carbamyl chloride derivatives to provide an ionisable chlorine content of 0,01% to 3,0%, preferably 0,1% to 1,0% by weight of the polyisocyanate composition. The polyisocyanate containing more than two isocyanate groups can be (1) added directly to the diphenylmethane diisocyanate, e.g. as benzene, toluene, diphenylmethane, diphenyl or diphenyl ether triisocyanates; (2) formed by interaction of some of the diphenylmethane diisocyanate with a polyhydric alcohol; (3) formed by partial polymerisation of the diphenylmethane diisocyanate to form isocyanurate derivatives; (4) present as the result of the manufacture of the diphenylmethane diisocyanate from a crude diamino-diphenylmethane containing triamines and other polyamines. The carbomyl chloride derivatives comprise di-and polyisocyanate compounds in which some or all the isocyanate groups have been converted to N-substituted carbamyl chloride groups, for example by direct addition of hydrogen chloride. In a typical example (1) a mixture is prepared of a polyester (from pentaerythritol, butylene glycol, adipic acid and phthalic anhydride), an alkylphenolethylene oxide condensate and water. To produce a foam there is then added a diphenylmethane diisocyanate composition. This is obtained by phosgenation and heating of an aniline-formaldehyde condensation product and contains derivatives of triamines present in the mixture and also isocyanurate polymers, and has an ionisable chlorine content of 0,5%.
GB35082/56A 1956-11-16 1956-11-16 Improvements in or relating to the manufacture of polymeric materials Expired GB848671A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BE562425D BE562425A (en) 1956-11-16
GB35082/56A GB848671A (en) 1956-11-16 1956-11-16 Improvements in or relating to the manufacture of polymeric materials
DEI13987A DE1108904B (en) 1956-11-16 1957-11-16 Process for the production of foams containing urethane groups
FR1190066D FR1190066A (en) 1956-11-16 1957-11-16 Manufacture of polymeric materials from organic polyesters and polyisocyanates

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB35082/56A GB848671A (en) 1956-11-16 1956-11-16 Improvements in or relating to the manufacture of polymeric materials

Publications (1)

Publication Number Publication Date
GB848671A true GB848671A (en) 1960-09-21

Family

ID=10373584

Family Applications (1)

Application Number Title Priority Date Filing Date
GB35082/56A Expired GB848671A (en) 1956-11-16 1956-11-16 Improvements in or relating to the manufacture of polymeric materials

Country Status (4)

Country Link
BE (1) BE562425A (en)
DE (1) DE1108904B (en)
FR (1) FR1190066A (en)
GB (1) GB848671A (en)

Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4163830A (en) 1975-12-24 1979-08-07 Bayer Aktiengesellschaft Process for the production of new polysiloxane-polyoxyalkylene copolymers with reduced burning properties
US4525590A (en) * 1981-07-29 1985-06-25 Bayer Aktiengesellschaft Simplified process for the production of polyamines by the alkaline hydrolysis of compounds containing NCO-groups
US4888124A (en) * 1985-05-14 1989-12-19 Basf Aktiengesellschaft Preparation of stable dispersions of finely divided polyisocyanates and preparation of heat-crosslinkable isocyanate systems
US5294445A (en) * 1991-08-21 1994-03-15 Bayer Aktiengesellschaft Pesticidal shaped articles
US5314588A (en) * 1991-08-20 1994-05-24 Bayer Aktiengesellschaft Process for recovering polysocyanates from the distillation residues obtained in the production of tolylene diisocyanate
US5965256A (en) * 1997-10-14 1999-10-12 Minnesota Mining And Manufacturing Company Protective films and coatings
US6001936A (en) * 1997-10-24 1999-12-14 3M Innovative Properties Company Dye enhanced durability through controlled dye environment
US6582771B1 (en) 2002-05-03 2003-06-24 Bayer Corporation Method for producing a polyurethane/geofabric composite
US6773756B2 (en) 2002-03-20 2004-08-10 Bayer Polymers Llc Process to manufacture three dimensionally shaped substrate for sound abatement
DE102007046187A1 (en) 2007-09-26 2009-04-09 Bayer Materialscience Ag roof module
EP2177555A2 (en) 2008-10-16 2010-04-21 Bayer MaterialScience AG Method for manufacturing polyether ester polyols
EP2202256A1 (en) 2008-12-23 2010-06-30 Bayer MaterialScience LLC Polymer polyols comprising a natural oil base polyol, polyurethane foams comprising these polymer polyols and processes for their preparation
WO2012080185A1 (en) 2010-12-15 2012-06-21 Bayer Materialscience Ag Foams of high thermal stability
WO2012084760A1 (en) 2010-12-20 2012-06-28 Bayer Materialscience Ag Method for producing polyether ester polyols
WO2012150201A2 (en) 2011-05-02 2012-11-08 Bayer Intellectual Property Gmbh High-temperature-resistant foams having low thermal conductivity
WO2013127850A1 (en) 2012-02-29 2013-09-06 Bayer Intellectual Property Gmbh 2-k pultrusion formulation and process
DE102012209598A1 (en) 2012-06-06 2013-12-12 Cht R. Beitlich Gmbh Textile auxiliaries and thus refined textile product
DE102012222045A1 (en) 2012-12-03 2014-06-05 Cht R. Beitlich Gmbh Coating of luminophores
WO2014086797A1 (en) 2012-12-04 2014-06-12 Purbond Ag Adhesive system for preparing lignocellulosic composites
EP2762508A1 (en) 2007-07-23 2014-08-06 Dow Global Technologies LLC Two part polyurethane curable composition having substantially consistent G-modulus across the range of use temperatures
EP2848638A1 (en) 2013-09-11 2015-03-18 Purbond AG Adhesive system for lignocellulosic substrates having high levels of extractives
WO2015100128A1 (en) 2013-12-23 2015-07-02 Dow Global Technologies Llc Adhesive containing high solid copolymer polyol polyurethane prepolymer
EP2894180A1 (en) 2014-01-08 2015-07-15 Bayer MaterialScience AG Polymer Polyols comprising a Polyether Carbonate Polyol as the Base Polyol
EP3034534A1 (en) 2014-12-17 2016-06-22 PURAC Biochem BV Substrates coated or bonded with a composition comprising a polyurethane
WO2016097002A1 (en) 2014-12-17 2016-06-23 Purac Biochem Bv Substrates coated or bonded with a composition comprising a polyurethane
US9649826B2 (en) 2013-08-15 2017-05-16 Henkel Ag & Co. Kgaa Adhesive system for preparing lignocellulosic composites
WO2017112012A2 (en) 2015-09-17 2017-06-29 Jerez Roberto Velozzi Load-bearing composite panels, materials, products, and processes to make and use same
EP3363840A1 (en) 2017-02-17 2018-08-22 Henkel AG & Co. KGaA Two-component polyurethane composition comprising a latent catalyst
WO2019149672A2 (en) 2018-02-02 2019-08-08 Basf Se Simultaneous optimization of fiber sizing in-line with the pultrusion process
US10526463B2 (en) 2015-02-20 2020-01-07 Covestro Deutschland Ag Foam materials resistant to high temperatures
EP3741788A1 (en) 2019-05-24 2020-11-25 Covestro Deutschland AG Method for the preparation of polyoxyalkylenpolyol mixtures
WO2021004624A1 (en) 2019-07-09 2021-01-14 Henkel Ag & Co. Kgaa Two component (2k) composition based on modified epoxy resins
EP3798246A1 (en) 2019-09-27 2021-03-31 Henkel AG & Co. KGaA One component (1k) composition based on modified epoxy resin
EP3838963A1 (en) 2019-12-17 2021-06-23 Covestro Deutschland AG Method for producing polyoxyalkylene polyesterpolyols
WO2022043160A1 (en) 2020-08-27 2022-03-03 Henkel Ag & Co. Kgaa Electrically conductive one component (1k) epoxy formulation
WO2022096390A1 (en) 2020-11-06 2022-05-12 Covestro Deutschland Ag Method for producing a polyol mixture
WO2023280560A1 (en) 2021-07-05 2023-01-12 Henkel Ag & Co. Kgaa High performance silicone-epoxy composition
WO2023057328A1 (en) 2021-10-07 2023-04-13 Covestro Deutschland Ag Process for preparing polyoxyalkylene polyester polyols

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE581667A (en) * 1958-08-15
CH537633A (en) * 1971-10-29 1973-05-31 Bbc Brown Boveri & Cie Electrical insulating body made of porous foam plastic
AT332863B (en) 1973-01-02 1976-10-25 Gerot Pharmazeutika PROCESS FOR THE PREPARATION OF NEW 2-AMINOMETHYL-4,6-DIHALOGENPHENOL DERIVATIVES AND THEIR ADDITIONAL SALTS WITH ACIDS

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2620349A (en) * 1950-12-06 1952-12-02 Monsanto Chemicals Compositions comprising organic isocyanates and method for preparing same
DE929507C (en) * 1951-07-26 1955-06-27 Bayer Ag Process for the production of foams
BE516512A (en) * 1951-12-24

Cited By (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4163830A (en) 1975-12-24 1979-08-07 Bayer Aktiengesellschaft Process for the production of new polysiloxane-polyoxyalkylene copolymers with reduced burning properties
US4525590A (en) * 1981-07-29 1985-06-25 Bayer Aktiengesellschaft Simplified process for the production of polyamines by the alkaline hydrolysis of compounds containing NCO-groups
US4888124A (en) * 1985-05-14 1989-12-19 Basf Aktiengesellschaft Preparation of stable dispersions of finely divided polyisocyanates and preparation of heat-crosslinkable isocyanate systems
US5314588A (en) * 1991-08-20 1994-05-24 Bayer Aktiengesellschaft Process for recovering polysocyanates from the distillation residues obtained in the production of tolylene diisocyanate
US5294445A (en) * 1991-08-21 1994-03-15 Bayer Aktiengesellschaft Pesticidal shaped articles
US5965256A (en) * 1997-10-14 1999-10-12 Minnesota Mining And Manufacturing Company Protective films and coatings
US6001936A (en) * 1997-10-24 1999-12-14 3M Innovative Properties Company Dye enhanced durability through controlled dye environment
US6395844B1 (en) 1997-10-24 2002-05-28 3M Innovative Properties Company Enhanced dye durability through controlled dye environment
US6498218B2 (en) 1997-10-24 2002-12-24 3M Innovative Properties Co Enhanced dye durability through controlled dye environment
US6773756B2 (en) 2002-03-20 2004-08-10 Bayer Polymers Llc Process to manufacture three dimensionally shaped substrate for sound abatement
US7285316B2 (en) 2002-03-20 2007-10-23 Bayer Materialscience Llc Process to manufacture three dimensionally shaped substrate for sound abatement
US6582771B1 (en) 2002-05-03 2003-06-24 Bayer Corporation Method for producing a polyurethane/geofabric composite
EP2762508A1 (en) 2007-07-23 2014-08-06 Dow Global Technologies LLC Two part polyurethane curable composition having substantially consistent G-modulus across the range of use temperatures
DE102007046187A1 (en) 2007-09-26 2009-04-09 Bayer Materialscience Ag roof module
US8042864B2 (en) 2007-09-26 2011-10-25 Bayer Materialscience Ag Roof module for a motor vehicle
EP2177555A2 (en) 2008-10-16 2010-04-21 Bayer MaterialScience AG Method for manufacturing polyether ester polyols
DE102008051882A1 (en) 2008-10-16 2010-04-29 Bayer Materialscience Ag Process for the preparation of polyetherester polyols
EP2202256A1 (en) 2008-12-23 2010-06-30 Bayer MaterialScience LLC Polymer polyols comprising a natural oil base polyol, polyurethane foams comprising these polymer polyols and processes for their preparation
WO2012080185A1 (en) 2010-12-15 2012-06-21 Bayer Materialscience Ag Foams of high thermal stability
US9481776B2 (en) 2010-12-15 2016-11-01 Covestro Deutschland Ag Foams of high thermal stability
WO2012084760A1 (en) 2010-12-20 2012-06-28 Bayer Materialscience Ag Method for producing polyether ester polyols
WO2012150201A2 (en) 2011-05-02 2012-11-08 Bayer Intellectual Property Gmbh High-temperature-resistant foams having low thermal conductivity
WO2013127850A1 (en) 2012-02-29 2013-09-06 Bayer Intellectual Property Gmbh 2-k pultrusion formulation and process
WO2013182568A2 (en) 2012-06-06 2013-12-12 Cht R. Beitlich Gmbh Textile auxiliary agent and textile product finished therewith
DE102012209598A1 (en) 2012-06-06 2013-12-12 Cht R. Beitlich Gmbh Textile auxiliaries and thus refined textile product
DE102012222045A1 (en) 2012-12-03 2014-06-05 Cht R. Beitlich Gmbh Coating of luminophores
WO2014086579A1 (en) 2012-12-03 2014-06-12 Cht R. Beitlich Gmbh Luminophore coating
WO2014086797A1 (en) 2012-12-04 2014-06-12 Purbond Ag Adhesive system for preparing lignocellulosic composites
EP2928977B1 (en) 2012-12-04 2020-10-28 Henkel AG & Co. KGaA Adhesive system for preparing lignocellulosic composites
US9649826B2 (en) 2013-08-15 2017-05-16 Henkel Ag & Co. Kgaa Adhesive system for preparing lignocellulosic composites
EP2848638A1 (en) 2013-09-11 2015-03-18 Purbond AG Adhesive system for lignocellulosic substrates having high levels of extractives
WO2015100128A1 (en) 2013-12-23 2015-07-02 Dow Global Technologies Llc Adhesive containing high solid copolymer polyol polyurethane prepolymer
EP2894180A1 (en) 2014-01-08 2015-07-15 Bayer MaterialScience AG Polymer Polyols comprising a Polyether Carbonate Polyol as the Base Polyol
EP3034534A1 (en) 2014-12-17 2016-06-22 PURAC Biochem BV Substrates coated or bonded with a composition comprising a polyurethane
WO2016097002A1 (en) 2014-12-17 2016-06-23 Purac Biochem Bv Substrates coated or bonded with a composition comprising a polyurethane
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