GB781289A - Improvements in or relating to linear polyamides - Google Patents

Improvements in or relating to linear polyamides

Info

Publication number
GB781289A
GB781289A GB3500153A GB3500153A GB781289A GB 781289 A GB781289 A GB 781289A GB 3500153 A GB3500153 A GB 3500153A GB 3500153 A GB3500153 A GB 3500153A GB 781289 A GB781289 A GB 781289A
Authority
GB
United Kingdom
Prior art keywords
methyl
hexamethylene diamine
diamines
diamine
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3500153A
Inventor
Denis Coleman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE534108D priority Critical patent/BE534108A/xx
Priority to NL204155D priority patent/NL204155A/xx
Priority to BE545090D priority patent/BE545090A/xx
Priority to DENDAT1165265D priority patent/DE1165265B/en
Priority to NL91517D priority patent/NL91517C/xx
Priority to NL99874D priority patent/NL99874C/xx
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3500153A priority patent/GB781289A/en
Priority to FR1115493D priority patent/FR1115493A/en
Priority to DEI9492A priority patent/DE1157393B/en
Priority to ES0218983A priority patent/ES218983A1/en
Priority to CH335082D priority patent/CH335082A/en
Priority to GB3826/55A priority patent/GB793451A/en
Priority to US563178A priority patent/US2880197A/en
Priority to CH341312D priority patent/CH341312A/en
Priority to FR69275D priority patent/FR69275E/en
Publication of GB781289A publication Critical patent/GB781289A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/40—Polyamides containing oxygen in the form of ether groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyamides (AREA)
  • Artificial Filaments (AREA)

Abstract

Linear polyamides are formed from oxalic acid and a di-methyl hexamethylene diamine or a mixture of two diamines at least one of which is mono-methyl hexamethylene diamine. In the substituted hexamethylene diamines the methyl groups are in 2, 3, 4 or 5 position. Minor amounts of conventional diamines, dibasic acids, monoaminomonocarboxylic acids or caprolactam may be included in the reaction mixture. Ingredients may be present as amideforming ingredients, e.g. as oxamic esters of the diamines or as diamine-dibasic acid salts. Monofunctional amide forming ingredients may be included as described in Specification 495,790, [Group IV]. Preferably lower alkyl or aryl esters of oxalic acid are used and mixed with the diamine in the cold preferably with a solvent. When the initial reaction ceases, heat is applied to drive off solvent and alcohol formed in the reaction. Final heating may be at 300 DEG C. under reduced pressure. Conventional reaction techniques may be employed. Examples are given employing (1) 3,4-dimethyl hexamethylene diamine; (2) a mixture of 3-methyl-hexamethylene diamine with hexamethylene diamine; and (3) a mixture of 2-methyl and 3-methyl hexamethylene diamine. Physical properties of fibres spun from the polymers are given.
GB3500153A 1953-12-16 1953-12-16 Improvements in or relating to linear polyamides Expired GB781289A (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
BE534108D BE534108A (en) 1953-12-16
NL204155D NL204155A (en) 1953-12-16
BE545090D BE545090A (en) 1953-12-16
DENDAT1165265D DE1165265B (en) 1953-12-16 Process for the production of polyamides
NL91517D NL91517C (en) 1953-12-16
NL99874D NL99874C (en) 1953-12-16
GB3500153A GB781289A (en) 1953-12-16 1953-12-16 Improvements in or relating to linear polyamides
FR1115493D FR1115493A (en) 1953-12-16 1954-12-11 Polyamides
DEI9492A DE1157393B (en) 1953-12-16 1954-12-14 Process for the production of polyamides
ES0218983A ES218983A1 (en) 1953-12-16 1954-12-14 Improvements in or relating to linear polyamides
CH335082D CH335082A (en) 1953-12-16 1954-12-15 Process for the production of new polyamides
GB3826/55A GB793451A (en) 1953-12-16 1955-02-09 Improved polyamides by copolymerising polyethers with certain polyamide-forming ingredients
US563178A US2880197A (en) 1953-12-16 1956-02-03 Polyoxamides
CH341312D CH341312A (en) 1953-12-16 1956-02-08 Process for the production of new polyamides
FR69275D FR69275E (en) 1953-12-16 1956-02-09 Polyamides

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3500153A GB781289A (en) 1953-12-16 1953-12-16 Improvements in or relating to linear polyamides

Publications (1)

Publication Number Publication Date
GB781289A true GB781289A (en) 1957-08-14

Family

ID=10372631

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3500153A Expired GB781289A (en) 1953-12-16 1953-12-16 Improvements in or relating to linear polyamides

Country Status (2)

Country Link
ES (1) ES218983A1 (en)
GB (1) GB781289A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2977340A (en) * 1958-04-04 1961-03-28 Du Pont Preparation of polyoxamides with trioxides and trihalides of as, sb and bi as catalysts
EP2130852A1 (en) * 2007-03-27 2009-12-09 Ube Industries, Ltd. Method for production of polyamide resin

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2977340A (en) * 1958-04-04 1961-03-28 Du Pont Preparation of polyoxamides with trioxides and trihalides of as, sb and bi as catalysts
EP2130852A1 (en) * 2007-03-27 2009-12-09 Ube Industries, Ltd. Method for production of polyamide resin
EP2130852A4 (en) * 2007-03-27 2012-09-05 Ube Industries Method for production of polyamide resin
US9090738B2 (en) 2007-03-27 2015-07-28 Ube Industries, Ltd. Production method of polyamide resin

Also Published As

Publication number Publication date
ES218983A1 (en) 1955-02-01

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