GB574818A - Cyclical process for the manufacture of titanium dioxide pigments - Google Patents
Cyclical process for the manufacture of titanium dioxide pigmentsInfo
- Publication number
- GB574818A GB574818A GB12506/43A GB1250643A GB574818A GB 574818 A GB574818 A GB 574818A GB 12506/43 A GB12506/43 A GB 12506/43A GB 1250643 A GB1250643 A GB 1250643A GB 574818 A GB574818 A GB 574818A
- Authority
- GB
- United Kingdom
- Prior art keywords
- iron
- solution
- titanium
- hydrochloric acid
- chloride solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title abstract 7
- 239000004408 titanium dioxide Substances 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000000049 pigment Substances 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 6
- 229910052742 iron Inorganic materials 0.000 abstract 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 3
- 239000012141 concentrate Substances 0.000 abstract 3
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 abstract 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 3
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 2
- 238000005868 electrolysis reaction Methods 0.000 abstract 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000003575 carbonaceous material Substances 0.000 abstract 1
- 238000005660 chlorination reaction Methods 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000003792 electrolyte Substances 0.000 abstract 1
- 229960002089 ferrous chloride Drugs 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 abstract 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 abstract 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/02—Roasting processes
- C22B1/08—Chloridising roasting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1204—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 preliminary treatment of ores or scrap to eliminate non- titanium constituents, e.g. iron, without attacking the titanium constituent
- C22B34/1209—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 preliminary treatment of ores or scrap to eliminate non- titanium constituents, e.g. iron, without attacking the titanium constituent by dry processes, e.g. with selective chlorination of iron or with formation of a titanium bearing slag
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1218—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by dry processes
- C22B34/1222—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by dry processes using a halogen containing agent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1236—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching
- C22B34/1259—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching treatment or purification of titanium containing solutions or liquors or slurries
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
574,818. Treating iron-bearing titanium ores. BRITISH TITAN PRODUCTS CO., Ltd. Aug. 3, 1943, No. 12506. Convention date, Aug. 1, 1942. Drawings to Specification. [Class 1 (iii)] [Also in Group XXXVI] Iron-bearing titanium ores such as ilmenite are treated with hydrochloric acid to bring the bulk of the iron into solution and leave a titanium dioxide concentrate, the latter is chlorinated to form and volatilise titanium tetrachloride, which is brought into solution and hydrolized to obtain hydrated titanium oxide which is calcined and hydrochloric acid for treating fresh ore; whilst the iron chloride solution is reduced and electrolysed to obtain metallic iron and chlorine which is used for chlorinating fresh titanium dioxide concentrate. In the first step elevated temperatures and relatively concentrated hydrochloric acid are used. In the chlorination step, the concentrate is preferably briquetted with carbonaceous material and a binder and ferric chloride passing off with the titanium tetrachloride is separated therefrom and added to the iron chloride solution to be electrolysed. The latter is usually acid and is neutralized before or during the reduction of ferric chloride present to ferrous chloride. Spent electrolyte from the electrolysis step may be used to form the titanium tetrachloride solution, and hydrolysis of the latter be effected in the presence of nuclei. Electrolysis may take place in a diaphragm cell having a carbon anode and iron cathode, using the iron chloride solution as catholyte and calcium chloride solution as anolyte, and current densities of 2-10 amps. per sq. decimetre. Specification 421,308 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US574818XA | 1942-08-01 | 1942-08-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB574818A true GB574818A (en) | 1946-01-22 |
Family
ID=22010824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB12506/43A Expired GB574818A (en) | 1942-08-01 | 1943-08-03 | Cyclical process for the manufacture of titanium dioxide pigments |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB574818A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014008586A1 (en) * | 2012-07-12 | 2014-01-16 | Orbite Aluminae Inc. | Processes for preparing titanium oxide and various other products |
| US9023301B2 (en) | 2012-01-10 | 2015-05-05 | Orbite Aluminae Inc. | Processes for treating red mud |
| US9181603B2 (en) | 2012-03-29 | 2015-11-10 | Orbite Technologies Inc. | Processes for treating fly ashes |
| US9260767B2 (en) | 2011-03-18 | 2016-02-16 | Orbite Technologies Inc. | Processes for recovering rare earth elements from aluminum-bearing materials |
| US9353425B2 (en) | 2012-09-26 | 2016-05-31 | Orbite Technologies Inc. | Processes for preparing alumina and magnesium chloride by HCl leaching of various materials |
| US9382600B2 (en) | 2011-09-16 | 2016-07-05 | Orbite Technologies Inc. | Processes for preparing alumina and various other products |
| US9410227B2 (en) | 2011-05-04 | 2016-08-09 | Orbite Technologies Inc. | Processes for recovering rare earth elements from various ores |
| US9534274B2 (en) | 2012-11-14 | 2017-01-03 | Orbite Technologies Inc. | Methods for purifying aluminium ions |
-
1943
- 1943-08-03 GB GB12506/43A patent/GB574818A/en not_active Expired
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9260767B2 (en) | 2011-03-18 | 2016-02-16 | Orbite Technologies Inc. | Processes for recovering rare earth elements from aluminum-bearing materials |
| US9945009B2 (en) | 2011-03-18 | 2018-04-17 | Orbite Technologies Inc. | Processes for recovering rare earth elements from aluminum-bearing materials |
| US9410227B2 (en) | 2011-05-04 | 2016-08-09 | Orbite Technologies Inc. | Processes for recovering rare earth elements from various ores |
| US9382600B2 (en) | 2011-09-16 | 2016-07-05 | Orbite Technologies Inc. | Processes for preparing alumina and various other products |
| US10174402B2 (en) | 2011-09-16 | 2019-01-08 | Orbite Technologies Inc. | Processes for preparing alumina and various other products |
| US9023301B2 (en) | 2012-01-10 | 2015-05-05 | Orbite Aluminae Inc. | Processes for treating red mud |
| US9556500B2 (en) | 2012-01-10 | 2017-01-31 | Orbite Technologies Inc. | Processes for treating red mud |
| US9181603B2 (en) | 2012-03-29 | 2015-11-10 | Orbite Technologies Inc. | Processes for treating fly ashes |
| WO2014008586A1 (en) * | 2012-07-12 | 2014-01-16 | Orbite Aluminae Inc. | Processes for preparing titanium oxide and various other products |
| US9290828B2 (en) | 2012-07-12 | 2016-03-22 | Orbite Technologies Inc. | Processes for preparing titanium oxide and various other products |
| US9353425B2 (en) | 2012-09-26 | 2016-05-31 | Orbite Technologies Inc. | Processes for preparing alumina and magnesium chloride by HCl leaching of various materials |
| US9534274B2 (en) | 2012-11-14 | 2017-01-03 | Orbite Technologies Inc. | Methods for purifying aluminium ions |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9963796B2 (en) | Method of producing titanium metal with titanium-containing material | |
| CN108251866B (en) | A kind of preparation method of metallic titanium powder | |
| SE8401357D0 (en) | SET TO MAKE ALUMINUM BY CHLORING ALUMINUM CHLORIDE HEXHYDRATE | |
| GB972938A (en) | Process for decomposing minerals | |
| ES478138A1 (en) | Process for the production of pigmentary titanium dioxide by the sulphuric acid method | |
| GB574818A (en) | Cyclical process for the manufacture of titanium dioxide pigments | |
| CH365096A (en) | Process for the extraction of iron from materials containing iron and titanium oxide | |
| US2441856A (en) | Cyclical process for the manufacture of titanium dioxide | |
| US3193376A (en) | Beneficiation of ilmenite | |
| CN104294040B (en) | Method for synchronously extracting vanadium and chrome in electrochemical reinforced vanadium slag decomposition of sodium hydroxide solution | |
| US1432544A (en) | Art of making electrolytic iron | |
| US2766197A (en) | Production of manganese | |
| GB1300973A (en) | Production of titanium dioxide concentrate | |
| US6340423B1 (en) | Hydrometallurgical processing of lead materials using fluotitanate | |
| US4272343A (en) | Process for the electrolytic reductive leaching of ilmenite ore | |
| US2396570A (en) | Methods for purifying manganese in metal state | |
| US2410242A (en) | Electrochemical process of treating chromite ore | |
| GB572866A (en) | Electrolytic methods for utilising iron chloride liquors | |
| US3787555A (en) | Process for recovering chromium values from chrome ore | |
| US3766026A (en) | Electrolytic process for the recovery of nickel, cobalt and iron from their sulfides | |
| US1235638A (en) | Process for obtaining oxid of titanium from materials incorporating other substances. | |
| US1201541A (en) | Method of obtaining titanic oxid. | |
| GB868717A (en) | Improvements in the treatment of ferro-titanium ores | |
| US1380711A (en) | Arthur e | |
| GB969680A (en) | Reduction of titanium dioxide to metallic titanium |