GB409336A - Improvements in stripping dyeings prepared with vat dyestuffs - Google Patents

Improvements in stripping dyeings prepared with vat dyestuffs

Info

Publication number
GB409336A
GB409336A GB2957732A GB2957732A GB409336A GB 409336 A GB409336 A GB 409336A GB 2957732 A GB2957732 A GB 2957732A GB 2957732 A GB2957732 A GB 2957732A GB 409336 A GB409336 A GB 409336A
Authority
GB
United Kingdom
Prior art keywords
hour
ethylene oxide
dyed
products
fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2957732A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB2957732A priority Critical patent/GB409336A/en
Publication of GB409336A publication Critical patent/GB409336A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/13Fugitive dyeing or stripping dyes

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

Protective colloids for addition to a dyestripping bath are inspissated sulphite waste liquor, glue, gelatine, soft roe, lysalbinic or protalbinic acid or the products of their reaction with stearic, oleic or other fatty acid chlorides, sericin, boiled-off soap, waxy polymerization products obtained from ethylene oxide, e.g. as described in Specification 346,550, [Group IV], and condensation products of ethylene oxide, an ethylene halohydrin, polyglycerol or an epihalohydrin with water-insoluble or difficulty soluble organic compounds containing at least six carbon atoms and at least one reactive hydrogen atom (cf. Specifications 368,530 and 380,431, [both in Group IV]). Such organic compounds are, for example, (a) lauric, palmitic, oleic, linoleic, ricinoleic, montanic, naphthenic or abietic acid or mixtures of fatty acids contained in coconut oil or palm kernel oil, or fatty acids obtainable by blowing paraffin wax with oxygen-containing gases at about 160 DEG C.; (b) the alkyl, hydroxy-alkyl or hydroxy-amino-alkyl esters or the amides of such acids; (c) the products of reaction of higher fatty acid chlorides with aminocarboxylic acids such as glycocoll or sarcosine; (d) alcohols containing at least ten carbon atoms, e.g. oleic or lauric alcohol or montanol; (e) alkylamines or their arylated derivatives, octadecylamine, oleylamine, hydroxyethyldodecylaniline or octadecyl--a --naphthylamine; (f) aromatic hydroxy compounds containing at least ten carbon atoms, e.g. b -naphthol; (g) aromatic amines, e.g. a -- or b -naphthylamine; (h) natural products of high molecular weight, such as casein, gelatine, glue, starch or cellulose.ALSO:The colour is stripped from vat-dyed textile materials by heating in an aqueous bath containing an alkaline reducing agent and adding a magnesium compound to the bath toward the end of the treatment. Specified magnesium compounds are the sulphate, chloride, sulphide, nitrate, acetate and hydroxide. Specified reducing agents are sodium and potassium hydrosulphites, sodium or zinc formaldehyde-sulphoxylates, glucose, and sodium sulphide. A protective colloid is preferably present in the bath, such as inspissated sulphite waste liquor, glue, gelatine, soft roe, lysalbinic or protalbinic acid or the products of their reaction with stearic, oleic or other fatty acid chlorides, sericin, boiled-off soap, and condensation products of ethylene oxide, an ethylene halohydrin, polyglycerol or an epihalohydrin with water-insoluble or difficulty soluble organic compounds containing at least six carbon atoms and at least one reactive hydrogen atom (cf. Specifications 368,530 and 380,431). Such organic compounds are, for example, (a) lauric, palmitic, oleic, linoleic, ricinoleic, montanic, naphthenic or abietic acid or mixtures of fatty acids contained in coconut oil or palm kernel oil, or fatty acids obtainable by blowing paraffin wax with oxygen-containing gases at about 160 DEG C.; (b) the alkyl, hydroxyalkyl or hydroxy-amino-alkyl esters or the amides of such acids; (c) the products of reaction of higher fatty acid chlorides with aminocarboxylic acids such as glycocoll or sarcosine; (d) alcohols containing at least ten carbon atoms, e.g. oleic or lauric alcohol or montanol; (e) alkylamines or their arylated derivatives, e.g. octadecylamine, oleylamine, hydroxyethyl-dodecylaniline or octadecyl-a -naphthylamine; (f) aromatic hydroxy compounds containing at least ten carbon atoms, e.g. b -naphthol; (g) aromatic amines, e.g. a - or b -naphthylamine; (h) natural products of high molecular weight, such as casein, gelatine, glue, starch or cellulose. Instead of or in addition to such protective colloids, waxy polymerisation products obtained from ethylene oxide, e.g. as described in Specification 346,550 may be employed to prevent the re-absorption of the vat dyestuffs by the fibre (cf. Specification 367,420). The following examples are specified: (1) A cotton fabric, dyed with Indanthrene blue 5G is treated for \ba1/2\be hour in a boiling aqueous solution containing caustic soda and sodium hydrosulphite; magnesium sulphate is then added, the boiling is continued for \ba1/2\be hour, and the fabric is rinsed, preferably with water containing some sodium hydrosulphite, and dried. (2) A cotton fabric, dyed with Indanthrene brilliant green B, is treated for \ba1/2\be hour in an aqueous solution at 90--95 DEG C. containing caustic soda, sodium hydrosulphite and a product obtained, as described in example 1 of Specification 346,550, by polymerisation of ethylene oxide in presence of alkali; magnesium chloride is then added and the treatment is continued for \ba1/2\be hour; the stripping effect may be improved by a further treatment for \ba1/2\be hour in an aqueous solution at 95 DEG C. containing the calcium salt of the sulphonic acid of dimethylphenyl-benzyl-ammonium sulphonic anhydride (cf. Example 3 of Specification 15722/10, [Class 2 (iii)]), caustic soda and sodium hydrosulphite. (3) A fabric, dyed with Indanthrene brilliant violet RR, is treated for \ba1/2\be hour in an aqueous solution at 90--95 DEG C. containing caustic soda, sodium hydrosulphite and a condensation product from ethylene oxide and octadecyl alcohol; magnesium sulphate is then added and the treatment is continued for \ba1/2\be hour; indigo dyeings on wool may be similarly stripped and artificial silk, dyed with Indanthrene blue RS may be stripped by treatment for \ba1/2\be hour in a similar solution at 60 DEG C. with an addition of magnesium sulphate 10 minutes before the end. (4) A fabric, dyed with Indanthrene blue RS, is treated for 1 hour in an aqueous solution at 90--95 DEG C. containing caustic soda, sodium hydrosulphite and a condensation product from ethylene oxide and either oleyl alcohol or a coconut oil acid ethanolamide; magnesium sulphate is then added, the treatment is continued for \ba1/2\be hour, and the fabric is rinsed with water which may contain some hydrosulphite. (5) A cotton fabric, dyed with Indanthrene brilliant green B, is treated for \ba1/2\be hour in an aqueous solution at 90 DEG C. containing caustic soda, sodium hydrosulphite and a product obtainable by the action of ethylene oxide on casein as described in Specification 368,530; magnesium hydroxide is then added and the treatment is continued for \ba1/2\be hour. (6) A calico fabric, dyed with Indanthrene yellow G, is treated for \ba1/2\be hour in an aqueous solution at 90 DEG C. containing caustic soda, sodium sulphide and a condensation product from ethylene oxide and oleyl alcohol; magnesium sulphide is then added, the treatment is continued for \ba1/2\be hour and the fabric is rinsed with water which may contain some hydrosulphite. Hydroxyethyl-dodecyl-aniline is obtainable by condensation of hydroxyethyl-aniline with dodecyl bromide. Octadecyl-a -naphthylamine is obtainable by condensation of a -naphthylamine with octadecyl bromide.
GB2957732A 1932-10-22 1932-10-22 Improvements in stripping dyeings prepared with vat dyestuffs Expired GB409336A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2957732A GB409336A (en) 1932-10-22 1932-10-22 Improvements in stripping dyeings prepared with vat dyestuffs

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2957732A GB409336A (en) 1932-10-22 1932-10-22 Improvements in stripping dyeings prepared with vat dyestuffs

Publications (1)

Publication Number Publication Date
GB409336A true GB409336A (en) 1934-04-23

Family

ID=10293720

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2957732A Expired GB409336A (en) 1932-10-22 1932-10-22 Improvements in stripping dyeings prepared with vat dyestuffs

Country Status (1)

Country Link
GB (1) GB409336A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3193465A (en) * 1961-04-21 1965-07-06 Lever Brothers Ltd Hair dyeing method using gelatin as a dye resist
EP0101989A1 (en) * 1982-08-26 1984-03-07 BASF Aktiengesellschaft Process for the production of discharge prints on textile materials made of wool, silk and polyamide

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3193465A (en) * 1961-04-21 1965-07-06 Lever Brothers Ltd Hair dyeing method using gelatin as a dye resist
EP0101989A1 (en) * 1982-08-26 1984-03-07 BASF Aktiengesellschaft Process for the production of discharge prints on textile materials made of wool, silk and polyamide

Similar Documents

Publication Publication Date Title
GB409336A (en) Improvements in stripping dyeings prepared with vat dyestuffs
US2019124A (en) Stripping agent
GB398258A (en) Improvements in the production and treatment of artificial filaments, threads, yarns, ribbons and the like
GB343901A (en) Improvements in the manufacture and production of wetting, cleansing and dispersing agents
US2144202A (en) Saponifying cellulose esters
US2248128A (en) Production of pattern effects on textile materials
Dorée The action of sea water on cotton and other textile fibres
GB500960A (en) Improvements in the treatment of textile materials
GB448272A (en) Improvements in dyeing with vat dyestuffs
GB403049A (en) A process for manufacturing coloured cellulose material
US2036932A (en) Condensation products and process of making same
US2206535A (en) Stripping dyed textile
US2064130A (en) Process for degumming textile fibers
US2681845A (en) Acid vat dyeing of animal fibers
GB500013A (en) Improvements in or relating to the treatment of casein fibres
US1897691A (en) Partial saponification of material containing organic esters of cellulose
US1963121A (en) Treatment of materials made of or containing cellulose esters
US2204932A (en) Process for producing dyeings
GB804056A (en) Process for the production of discharge printed textile or knitted fabrics of regenerated cellulose
GB396050A (en) Protecting agents for acid and alkaline treatment of animal fibres
US1532427A (en) Treatment of cellulose esters for dyeing
US1897794A (en) Dyeing or otherwise coloring of materials made with or containing cellulose esters or ethers
DE679768C (en) Process for the production of ice colors using the printing or padding process
GB582895A (en) Improvements in the dyeing of textile materials
GB482181A (en) Process for the production on textile fabrics of wash-resistant decorations simulating die-stamp printing