GB2204609A - Liquid detergent/softener compositions - Google Patents
Liquid detergent/softener compositions Download PDFInfo
- Publication number
- GB2204609A GB2204609A GB08810901A GB8810901A GB2204609A GB 2204609 A GB2204609 A GB 2204609A GB 08810901 A GB08810901 A GB 08810901A GB 8810901 A GB8810901 A GB 8810901A GB 2204609 A GB2204609 A GB 2204609A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition according
- component
- formula
- softener
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims description 39
- 239000003599 detergent Substances 0.000 title claims description 14
- 239000007788 liquid Substances 0.000 title claims description 13
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 15
- 239000000194 fatty acid Substances 0.000 claims description 15
- 229930195729 fatty acid Natural products 0.000 claims description 15
- 150000004665 fatty acids Chemical class 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 10
- -1 ethylsulphate anion Chemical class 0.000 claims description 10
- 239000003945 anionic surfactant Substances 0.000 claims description 8
- 239000002736 nonionic surfactant Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 230000003287 optical effect Effects 0.000 claims description 6
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 4
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical group C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 3
- 239000003352 sequestering agent Substances 0.000 claims description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 230000010933 acylation Effects 0.000 claims description 2
- 238000005917 acylation reaction Methods 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims description 2
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 239000003752 hydrotrope Substances 0.000 claims description 2
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 2
- 229920001281 polyalkylene Polymers 0.000 claims description 2
- 229920000768 polyamine Polymers 0.000 claims description 2
- 238000005956 quaternization reaction Methods 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 1
- 238000005406 washing Methods 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 239000000872 buffer Substances 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229940093476 ethylene glycol Drugs 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 150000003839 salts Chemical group 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 108010011222 cyclo(Arg-Pro) Proteins 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000001516 effect on protein Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
1 2204609 IMPROVEMENTS IN OR RELATING TO ORGANIC COMPOUNDS This invention
relates to liquid laundry detergent compositions for use in domestic and industrial laundering.
Such liquid detergents mostly consist of a mixture of anionic and nonionic surfactants, but no builders,.so that their washing power for fatty stains is only moderate despite their high surfactant content Qv 40 %). For good washing effect on protein-containing stains it is also necessary to include enzymes in the formulation.
It has also been attempted to include softeners in liquid detergent compositions, to avoid the need for aftertreatment with a solution or dispersion of a softener. It has however been found that conventional softeners tend to be incompatible with the anionic surfactants which are present so that the composition does not remain as a stable solution, but separates into two phases. When phase separation occurs, the composition must be shaken each time before use, and measurement of the correct dosage becomes unreliable. For this reason, liquid detergent compositions containing softeners have so far been made only on the basis of non-ionic surfactants, which tend to have inadequate washing power.
It has now been found that stable liquid detergent compositions based on anionic surfactants having excellent washing power can be made containing a selected group of softeners. Accordingly, the 1 present invention provides a stable liquid detergent composition based on one or more anionic surfactants, and containing a softener which is the product of acylation and quaternization of a polyalkylene polyamine. Preferred softeners are of formula I R Q 1 R CONH-+ CH J1 N CH 1 NHCOR 1 2 n 1 2/n 1 R xe in which each RI, independently, is C12-19 alkyl or C12-le alkenyl; each n, independently, is 2 or 3; R2 is C1-4 alkyl, C1-4 hydroxyalkyl, or C1-4 hydroxyalkyl etherified with 1-10 ethylene oxide groups; R3 is CI-4 alkyl or benzyl; and XG is a halide, methylsulphate or ethylsulphate anion.
Preferred liquid detergent compositions according to the invention contain I (A) 1-15 X, preferably 3-10% of softener of formula I (B) 0-25 %, preferably 4-20% of a partially carboxymethylated or carboxyethylated ethylene oxide adduct of a fatty alcohol or an alkylphenol (C) 5-30 X, preferably 10-25%, of one or more fatty acids (D) 2-20 %, preferably 5-15% of one or more other anionic surfactants.
All percentages are by weight based on the total weight of the composition, including water. Preferably the active components (A)-(D) together make up 20-50%, preferably 30-50% of the total compositi on.
The composition also contains sufficient alkali to neutralise the anionic components. In.addition the composition may contain other conventional components for example nonionic surfactants, hydrotropes, v 1 sequestering agents, buffers, enzymes and optical brighteners.
The softeners of formula I may be prepared in conventional manner by the reaction of a dialkylene triamine with a fatty acid or a functional derivative thereof, followed by alkylation and quaternisation with an alkyl, hydroxyalkyl or benzyl derivative. Preferred softeners contain at least one hydroxyalkyl group, more preferably a 0-hydroxyethyl group which may be etherified with ethylene oxide groups (preferably 1-5 EO groups), and at least one unsaturated fatty acid residue, for example an oleyl group. Preferably both groups R, are identical, or represent the same average mixture of groups, for example a mixture of 85% oleyl and 15 % stearyl groups.
Component (B) is preferably a compound of formula II R- 0---+ CH2CH20). A - COOH-7 II in which R is the residue of a C8-22 fatty alcohol or of an alkylphenol having 10-24 C atoms; A is a methylene or ethylene group; m is a number from 1-20; and X is an average value from 0.1 to 1.
Compounds of formula II are k,own or may be prepared by conven tional methods from available starting materials. The most preferred component (B) is a compound of formula II obtained by reacting a synthetic lauryl alcohol (C12-15) with 4-5 moles ethylene oxide and subsequently with 0.8 mole chloracetic acid. The compounds are normally used in the form of their alkali metal salts, particularly sodium salts.
The fatty acids of component (C) are preferably saturated and unsaturated CS-22 carboxylic acids, more preferably C12-18. The fatty acids, for example coco fatty acid or oleic acid are added a such and converted to the salt form by addition of alkali e.g. NaOH, KOH or an organic base e.g. triethanolamine.
4 - The further anionic surfactants of component (D) may be any of the following conventional types:
a) sulphates and sulphonates of fatty acids, fatty acid esters and fatty acid amides b) linear or branched C5-18 alkyl sulphates and sulphonates c) sulphated ethoxylated compounds, particularly sulphated forms of any non-ionic surfactants which may be present d) polycarboxylic acid ester sulphates e) C5-18 alkylbenzenesulphonates and C1-4 alkyl and dialkylnaphthalene sulphonates.
These compounds may be added in acid form and converted to their salt forms by addition of alkali.
Nonionic surfactants which may be present include ethylene oxide (E0) 1 propylene oxide (PO) block copolymers (Pluronics), and the addition products of EO or PO, preferably EO, to fatty alcohols, fatty amines, fatty acids, fatty acid alkanolamides and alkylphenols. Such non-ionic surfactants are conventional and commercially available.
Hydrotropic compounds which may be present include for example urea, dicyandiamide and its derivatives, alcohols, water-soluble glycols, glycol ethers and glycol esters and C1-4 alkylbenzenesulphonates, provided that the compounds display no cloud point in distilled water up to 1001. They act so as to prevent phase separation, that is to stabilize the liquid composition.
Sequestering agents include citric acid, nitrilotriacetic acid and other complex formers. Buffers may be used to stabilise the pH of the wash liquor in the neutral or alkali region. Buffer substances include sodium bicarbonate, sodium carbonate and sodium silicate.
By selection of these additional components, and optionally by use of enzymes and optical brighteners, the washing effect of the liquid detergent can be adjusted according to the desired field of use. The liquid detergent compositions of the invention are primarily useful as domestic laundry detergents. Not only do they display good washing power, they also produce a soft handle on laundered cotton goods. Being phosphate-free, they are ecologically acceptable. When used in conjunction with optical brighteners they do not cause quenching of the brightener so that acceptable grades of whiteness are obtained. The liquid compositions are stable and do not separate into two phases on storage.
The following Examples, in which all percentages are percentages by weight of the entire composition, illustrate the invention:
Examples 1-7
In the following examples, component (A) is a compound of the formula CH 2CH 2 OH 1 0 R 1 CONHCH 2CH 2 - N- CH 2 CH 2 NHCOR 1 1 CH 3 CH 3 OSO 3 0 in which R, is a mixture of 85% oleyl groups and 15% stearyl groups, Component (B) is of the formula RO(CH2CH204.5 - (CH2COONa)o.8 in which R is C12-15 alkyl, used in the form of a 67% aqueous paste. The components are added to demineralised water at room temperature, stirring until a homogenous solution is obtained. The final pH of the product is approx. 7. 5. The components.are in the proportions shown in the following Table.
7 - Table
Percentage by weight Example 1 2 3 4 5 6 7 Component Demineralised water 12.5 16.0 13.5 14.0 (A) softener 5.0 7.0 7.0 5.0 (B) Carboxymethylated adduct (67%) coco fatty acid oleic acid (C) (C) (C) dodecylbenzene sulphonic acid (D) lauryl ether sulphate lauryl alcoholpoly (7)ethylene-glycol ether (SANDOXYLATE A 25-7) triethanolamine 10.0 diethanolamine - caustic soda (30% aq)15.0 isopropanol 12.0 ethylene glycol - optical brightener 1.0 citric acid 2.5 10.0 10.0 - 10.0 20.0 15.0 15.0 20.0 5.0 5.0 5.0 5.0 7.0 8.0 11.0 3.5 3.5 7.0 27.8 34.5 7.0 5.0 10.0 8.0 15.0 10.0 5.0 8.0 6.0 3.5 3.0 33.5 6.0 5.0 6.0 4.0 6.0 3.0 7.5 - - 3.0 10.0 10.0 5.0 12.5 14.5 12.0 12.0 10.7 14.0 14.0 18.5 12.0 12.0 810 8.0 0.5 3.0 1.0 1.0 1.0 1.0 2,5 8.0 8.0 0.5 3.0 Application Example A The compositions of Examples 1-7 are tested on cotton samples bleached without optical brightener. The washing tests are carried out with 2 kg polyester as ballast in a Schulthess Super 45 (Trade Mark) washing machine on programme 4. The washing conditions are as follows:
1 - 8 cylinder volume 43 1 amount of wate 17 1 amount of detergent 8 g11 temperature 600C heating time about 11 min.
washing time about 15 min.
water hardness 18dH pH of the wash liquor 7.
After washing the effect of the detergent composition on the cotton samples is measured by means of a spectrophotometer (Datacolor Type 7080) and expressed as the CIE whiteness degree (CIE publication No. 15.2).
il 1 1 J e
Claims (14)
1. A stable liquid detergent composition based on one or more anionic surfactants, and containing a softener which is the product of acylation and quaternization of a polyalkylene polyamine.
2. A composition according to Claim 1 in which the softener is of formula I R 01 R CONH---+ CH N -----+ CH2,--NHCOR 1 1 n R 3 xe in which each R,, independently, is C12-1e alkyl Or C12-18 alkenyl; each n, independently, is 2 or 3; R2 is C1-4 alkyl, C1-4 hydroxyalkyl, or C1-4 hydroxyalkyl etherified with 1-10 ethylene oxide groups; R3 is C1-4 alkyl or benzyl; and X- is a halide, methylsulphate or ethylsulphate anion.
3. A composition according to Claim 2 containing I (A) 1-15 % of softener of formula I (B) 0-25 % of a partially carboxymethylated or carboxyethylated ethylene oxide adduct of a fatty alcohol or an alkylphenol (C) 5-30 % of one or more fatty acids (D) 2-20 % of one or more other anionic surfactants, by weight based on the total weight of the compos.ition, including water.
4. A composition according to Claim 3 containing 3-10 % of component 4-20 % of component 10-25 % of component (A) (B) (C) and 5-15 % of component (D) by weight based on the total weight of the composition, including water.
5. A composition according to Claim 4 in which the active components (A)(D) together make up 30-50% by weight of the composition.
6. A composition according to any one of Claims 2-5 in which the softener (A) is a compound of formula I in which R2 is a 0-hydroxyethyl group or a 0-hydroxyethyl group etherified with 1-5 ethylene oxide groups.
7. A composition according to Claim 6 in which the softener (A) is a compound of the formula CH 2 CH 2 OH R CONHCH CH 0 CH CH NHCOR 1 2 2_ N 2 2 1 1 CH 3 CH 3 OSO 3 c) in which R, is a mixture of 85% oleyl groups and 15% stearyl groups.
8. A composition according to any one of the Claims 3-7 in which component B is a compound of formula II R - 0 __C CII 2 CH 2 0) m ( A - COOH II in which R is the residue of a C8-22 fatty alcohol or of an alkylphenol having 10-24 C atoms; A is a methylene or ethylene group; m is a number from 1-20; X is an average value from 0.1 to 1.
and
9. A compound according to Claim 8 in which component (B) is a compound of formula II obtained by reacting a synthetic lauryl alcohol (C1215) with 4-5 moles ethylene oxide and subsequently with 0.8 mole chloracetic acid.
10. A composition according to any one of Claims 3-9 in which component (C) is a saturated or unsaturated C12-18 carboxylic acid.
11. A composition according to any one of Claims 3-10 in which component (D) is selected from a) sulphates and sulphonates of fatty acids, fatty acid esters and fatty acid amides b) linear or branched C5-18 alkyl sulphates and sulphonates c) sulphated ethoxylated compounds, d) polycarboxylic acid ester sulphates and e) C5-18 alkylbenzenesulphonates and C1-4 alkyland dialkylnaphthalene sulphonates.
12. A composition according to any one of the preceding claims containing additionally one or more components selected from non-ionic surfactants, hydrotropes and sequestering agents.
13. A composition according to any one of the preceding claims containing an optical brightener. j
14. A composition as described in any one of the Examples.
Published 1988 at The Patent Office, State House, 66."71 High Holborn, London WCIR 4TP. Further copies may be obtained from The Patent Office, Wes Branch, St Mary Cray, Orpington, Kent BR5 3RD. Printed by Multiplex techniques ltd, St Mary Cray, Kent. Con. 1/87.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3715636 | 1987-05-11 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB8810901D0 GB8810901D0 (en) | 1988-06-15 |
| GB2204609A true GB2204609A (en) | 1988-11-16 |
| GB2204609B GB2204609B (en) | 1991-03-06 |
Family
ID=6327260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8810901A Expired - Lifetime GB2204609B (en) | 1987-05-11 | 1988-05-09 | Liquid detergent/ softener compositions |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS63292000A (en) |
| CH (1) | CH676007A5 (en) |
| FR (1) | FR2615202B1 (en) |
| GB (1) | GB2204609B (en) |
| IT (1) | IT1234993B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1989009204A1 (en) * | 1988-04-02 | 1989-10-05 | Henkel Kommanditgesellschaft Auf Aktien | Quaternary ammonium compounds |
| EP0376893A2 (en) * | 1988-12-30 | 1990-07-04 | Sandoz Ag | Liquid laundry detergent compositions containing optical brighteners |
| WO1995029217A1 (en) * | 1994-04-25 | 1995-11-02 | The Procter & Gamble Company | Stable, aqueous laundry detergent composition having improved softening properties |
| WO1997012020A1 (en) * | 1995-09-29 | 1997-04-03 | The Procter & Gamble Company | Liquid laundry detergents containing selected alkyl amidoalkoyl quaternary ammonium compounds |
| WO2012172367A1 (en) * | 2011-06-17 | 2012-12-20 | Reckitt Benckiser N.V. | Composition |
| WO2013087285A1 (en) * | 2011-12-12 | 2013-06-20 | Unilever Plc | Laundry compositions and uses |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH540071D (en) * | 1971-04-14 | |||
| US4460485A (en) * | 1983-07-15 | 1984-07-17 | Lever Brothers Company | Polyester fabric conditioning and whitening composition |
| GB8430301D0 (en) * | 1984-11-30 | 1985-01-09 | Swan Thomas & Co Ltd | Compositions of matter for fabric softeners |
| US4622173A (en) * | 1984-12-31 | 1986-11-11 | Colgate-Palmolive Co. | Non-aqueous liquid laundry detergents containing three surfactants including a polycarboxylic acid ester of a non-ionic |
-
1988
- 1988-05-03 IT IT8847907A patent/IT1234993B/en active
- 1988-05-04 FR FR8806089A patent/FR2615202B1/en not_active Expired - Fee Related
- 1988-05-09 GB GB8810901A patent/GB2204609B/en not_active Expired - Lifetime
- 1988-05-09 CH CH1759/88A patent/CH676007A5/de not_active IP Right Cessation
- 1988-05-10 JP JP63111747A patent/JPS63292000A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1989009204A1 (en) * | 1988-04-02 | 1989-10-05 | Henkel Kommanditgesellschaft Auf Aktien | Quaternary ammonium compounds |
| EP0336267A2 (en) * | 1988-04-02 | 1989-10-11 | Henkel Kommanditgesellschaft auf Aktien | Quaternary ammonium compounds |
| EP0336267A3 (en) * | 1988-04-02 | 1989-10-25 | Henkel Kommanditgesellschaft auf Aktien | Quaternary ammonium compounds |
| EP0376893A2 (en) * | 1988-12-30 | 1990-07-04 | Sandoz Ag | Liquid laundry detergent compositions containing optical brighteners |
| EP0376893A3 (en) * | 1988-12-30 | 1991-08-07 | Sandoz Ag | Liquid laundry detergent compositions containing optical brighteners |
| WO1995029217A1 (en) * | 1994-04-25 | 1995-11-02 | The Procter & Gamble Company | Stable, aqueous laundry detergent composition having improved softening properties |
| US5622925A (en) * | 1994-04-25 | 1997-04-22 | The Procter & Gamble Company | Stable, aqueous laundry detergent composition having improved softening properties |
| WO1997012020A1 (en) * | 1995-09-29 | 1997-04-03 | The Procter & Gamble Company | Liquid laundry detergents containing selected alkyl amidoalkoyl quaternary ammonium compounds |
| WO2012172367A1 (en) * | 2011-06-17 | 2012-12-20 | Reckitt Benckiser N.V. | Composition |
| WO2013087285A1 (en) * | 2011-12-12 | 2013-06-20 | Unilever Plc | Laundry compositions and uses |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2204609B (en) | 1991-03-06 |
| FR2615202A1 (en) | 1988-11-18 |
| IT8847907A0 (en) | 1988-05-03 |
| JPS63292000A (en) | 1988-11-29 |
| GB8810901D0 (en) | 1988-06-15 |
| FR2615202B1 (en) | 1994-03-11 |
| IT1234993B (en) | 1992-06-16 |
| CH676007A5 (en) | 1990-11-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19940509 |