GB1512751A - Preparation of 1,4-butanediol - Google Patents

Preparation of 1,4-butanediol

Info

Publication number
GB1512751A
GB1512751A GB134676A GB134676A GB1512751A GB 1512751 A GB1512751 A GB 1512751A GB 134676 A GB134676 A GB 134676A GB 134676 A GB134676 A GB 134676A GB 1512751 A GB1512751 A GB 1512751A
Authority
GB
United Kingdom
Prior art keywords
catalyst
butanediol
hydrogenolysis
present
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB134676A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of GB1512751A publication Critical patent/GB1512751A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1512751 1,4-Butanediol HOECHST AG 14 Jan 1976 [16 Jan 1975] 01346/76 Heading C2C 1,4-Butanediol is preapared by the hydrogenolysis of γ-butyrolactone in the presence of a copper oxide/chromium oxide catalyst which has been pretreated with hydrogen outside the hydrogenolysis zone. The catalyst is for example an Adkins catalyst which has been pretreated at 50-250‹ C. for 15 minutes to 6 hours; a mixture of hydrogen with nitrogen may be used, and a secondary treatment with carbon dioxide may take place. Rhenium or manganese in elementary or bound form may be present in the catalyst. Water (e.g. up to 20%) and carboxylic acids (e.g. up to 25%) may be present in the γ-butyrolactone. The hydrogenolysis may be carried out for example at 50-300‹ C. under a hydrogen pressure of 50-300 bars, and a solvent, e.g. dioxan, ether or methylcyclohexane, may be present.
GB134676A 1975-01-16 1976-01-14 Preparation of 1,4-butanediol Expired GB1512751A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19752501499 DE2501499A1 (en) 1975-01-16 1975-01-16 PROCESS FOR THE PRODUCTION OF BUTANDIOL- (1.4)

Publications (1)

Publication Number Publication Date
GB1512751A true GB1512751A (en) 1978-06-01

Family

ID=5936534

Family Applications (1)

Application Number Title Priority Date Filing Date
GB134676A Expired GB1512751A (en) 1975-01-16 1976-01-14 Preparation of 1,4-butanediol

Country Status (3)

Country Link
JP (1) JPS5198204A (en)
DE (1) DE2501499A1 (en)
GB (1) GB1512751A (en)

Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4652685A (en) * 1985-11-15 1987-03-24 General Electric Company Hydrogenation of lactones to glycols
US4656297A (en) * 1985-03-11 1987-04-07 Amoco Corporation Coproduction of butanediol and tetrahydrofuran and their subsequent separation from the reaction product mixture
FR2874377A1 (en) * 2004-08-20 2006-02-24 Cognis Deutschland Gmbh PROCESS FOR THE PREPARATION OF ALCOHOLS
US7154011B2 (en) 2002-06-11 2006-12-26 Basf Aktiengesellschaft Method for the production of 1,4- butanediol
US7169958B2 (en) 2002-06-11 2007-01-30 Basf Aktiengesellschaft Method for the production of 1,4- butane-diol by combined gas-phase and liquid-phase hydrogenation
US7271299B2 (en) 2002-06-11 2007-09-18 Basf Aktiengesellschaft Two-stage method for producing butanediol with intermediated separation of succinic anhydride
WO2010030711A2 (en) 2008-09-10 2010-03-18 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol
US7799545B2 (en) 2008-03-27 2010-09-21 Genomatica, Inc. Microorganisms for the production of adipic acid and other compounds
US7803589B2 (en) 2008-01-22 2010-09-28 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
WO2010141920A2 (en) 2009-06-04 2010-12-09 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol and related methods
US7947483B2 (en) 2007-08-10 2011-05-24 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
US7977084B2 (en) 2008-03-05 2011-07-12 Genomatica, Inc. Primary alcohol producing organisms
US8026386B2 (en) 2007-08-10 2011-09-27 Genomatica, Inc. Methods for the synthesis of olefins and derivatives
US8048661B2 (en) 2010-02-23 2011-11-01 Genomatica, Inc. Microbial organisms comprising exogenous nucleic acids encoding reductive TCA pathway enzymes
US8067214B2 (en) 2007-03-16 2011-11-29 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US8129155B2 (en) 2008-12-16 2012-03-06 Genomatica, Inc. Microorganisms and methods for conversion of syngas and other carbon sources to useful products
US8129154B2 (en) 2008-06-17 2012-03-06 Genomatica, Inc. Microorganisms and methods for the biosynthesis of fumarate, malate, and acrylate
US8241877B2 (en) 2008-05-01 2012-08-14 Genomatica, Inc. Microorganisms for the production of methacrylic acid
US8377666B2 (en) 2009-10-13 2013-02-19 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol, 4-hydroxybutanal, 4-hydroxybutyryl-coa, putrescine and related compounds, and methods related thereto
US8377680B2 (en) 2009-05-07 2013-02-19 Genomatica, Inc. Microorganisms and methods for the biosynthesis of adipate, hexamethylenediamine and 6-aminocaproic acid
US8420375B2 (en) 2009-06-10 2013-04-16 Genomatica, Inc. Microorganisms and methods for carbon-efficient biosynthesis of MEK and 2-butanol
US8445244B2 (en) 2010-02-23 2013-05-21 Genomatica, Inc. Methods for increasing product yields
US8530210B2 (en) 2009-11-25 2013-09-10 Genomatica, Inc. Microorganisms and methods for the coproduction 1,4-butanediol and gamma-butyrolactone
US8580543B2 (en) 2010-05-05 2013-11-12 Genomatica, Inc. Microorganisms and methods for the biosynthesis of butadiene
US8597918B2 (en) 2009-06-04 2013-12-03 Genomatica, Inc. Process of separating components of a fermentation broth
WO2013184602A2 (en) 2012-06-04 2013-12-12 Genomatica, Inc. Microorganisms and methods for production of 4-hydroxybutyrate, 1,4-butanediol and related compounds
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US8673601B2 (en) 2007-01-22 2014-03-18 Genomatica, Inc. Methods and organisms for growth-coupled production of 3-hydroxypropionic acid
US8715971B2 (en) 2009-09-09 2014-05-06 Genomatica, Inc. Microorganisms and methods for the co-production of isopropanol and 1,4-butanediol
US8715957B2 (en) 2010-07-26 2014-05-06 Genomatica, Inc. Microorganisms and methods for the biosynthesis of aromatics, 2,4-pentadienoate and 1,3-butadiene
WO2014176514A2 (en) 2013-04-26 2014-10-30 Genomatica, Inc. Microorganisms and methods for production of 4-hydroxybutyrate, 1,4-butanediol and related compounds
US8993285B2 (en) 2009-04-30 2015-03-31 Genomatica, Inc. Organisms for the production of isopropanol, n-butanol, and isobutanol
US9017983B2 (en) 2009-04-30 2015-04-28 Genomatica, Inc. Organisms for the production of 1,3-butanediol
US9023636B2 (en) 2010-04-30 2015-05-05 Genomatica, Inc. Microorganisms and methods for the biosynthesis of propylene
US9562241B2 (en) 2009-08-05 2017-02-07 Genomatica, Inc. Semi-synthetic terephthalic acid via microorganisms that produce muconic acid
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US10385344B2 (en) 2010-01-29 2019-08-20 Genomatica, Inc. Microorganisms and methods for the biosynthesis of (2-hydroxy-3methyl-4-oxobutoxy) phosphonate

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2715666A1 (en) * 1977-04-07 1978-10-12 Hoechst Ag PROCESS FOR THE MANUFACTURING OF ETHYLENE GLYCOL
DE2845905C3 (en) * 1978-10-21 1983-05-26 Chemische Werke Hüls AG, 4370 Marl Process for the continuous production of 1,4-butanediol
JP2596604B2 (en) * 1988-12-14 1997-04-02 東燃株式会社 Method for producing 1,4-butanediol and tetrahydrofuran
JP2666151B2 (en) * 1988-12-14 1997-10-22 東燃株式会社 Method for producing 1,4-butanediol
CN101619014B (en) * 2008-06-30 2013-05-01 上海焦化有限公司 Method for preparing 1,4-butanediol-coproduced tetrahydro furan and gamma-butyrolactone

Cited By (87)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4656297A (en) * 1985-03-11 1987-04-07 Amoco Corporation Coproduction of butanediol and tetrahydrofuran and their subsequent separation from the reaction product mixture
US4652685A (en) * 1985-11-15 1987-03-24 General Electric Company Hydrogenation of lactones to glycols
US7154011B2 (en) 2002-06-11 2006-12-26 Basf Aktiengesellschaft Method for the production of 1,4- butanediol
US7169958B2 (en) 2002-06-11 2007-01-30 Basf Aktiengesellschaft Method for the production of 1,4- butane-diol by combined gas-phase and liquid-phase hydrogenation
US7271299B2 (en) 2002-06-11 2007-09-18 Basf Aktiengesellschaft Two-stage method for producing butanediol with intermediated separation of succinic anhydride
FR2874377A1 (en) * 2004-08-20 2006-02-24 Cognis Deutschland Gmbh PROCESS FOR THE PREPARATION OF ALCOHOLS
WO2006021328A1 (en) * 2004-08-20 2006-03-02 Cognis Ip Management Gmbh Method for producing alcohols
US8673601B2 (en) 2007-01-22 2014-03-18 Genomatica, Inc. Methods and organisms for growth-coupled production of 3-hydroxypropionic acid
US8889399B2 (en) 2007-03-16 2014-11-18 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US8357520B2 (en) 2007-03-16 2013-01-22 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
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US11371046B2 (en) 2007-03-16 2022-06-28 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US9487803B2 (en) 2007-03-16 2016-11-08 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US8067214B2 (en) 2007-03-16 2011-11-29 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US8969054B2 (en) 2007-03-16 2015-03-03 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
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US8026386B2 (en) 2007-08-10 2011-09-27 Genomatica, Inc. Methods for the synthesis of olefins and derivatives
EP3447133A1 (en) 2007-08-10 2019-02-27 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
US7947483B2 (en) 2007-08-10 2011-05-24 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
EP2679685A1 (en) 2007-08-10 2014-01-01 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
EP2679684A1 (en) 2007-08-10 2014-01-01 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
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US8470582B2 (en) 2007-08-10 2013-06-25 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
US9885064B2 (en) 2008-01-22 2018-02-06 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US7803589B2 (en) 2008-01-22 2010-09-28 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US8697421B2 (en) 2008-01-22 2014-04-15 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US9051552B2 (en) 2008-01-22 2015-06-09 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
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US10550411B2 (en) 2008-01-22 2020-02-04 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US8323950B2 (en) 2008-01-22 2012-12-04 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
US9260729B2 (en) 2008-03-05 2016-02-16 Genomatica, Inc. Primary alcohol producing organisms
US10208320B2 (en) 2008-03-05 2019-02-19 Genomatica, Inc. Primary alcohol producing organisms
US7977084B2 (en) 2008-03-05 2011-07-12 Genomatica, Inc. Primary alcohol producing organisms
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US9175297B2 (en) 2008-09-10 2015-11-03 Genomatica, Inc. Microorganisms for the production of 1,4-Butanediol
US8129155B2 (en) 2008-12-16 2012-03-06 Genomatica, Inc. Microorganisms and methods for conversion of syngas and other carbon sources to useful products
US8993285B2 (en) 2009-04-30 2015-03-31 Genomatica, Inc. Organisms for the production of isopropanol, n-butanol, and isobutanol
US9017983B2 (en) 2009-04-30 2015-04-28 Genomatica, Inc. Organisms for the production of 1,3-butanediol
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Also Published As

Publication number Publication date
JPS5198204A (en) 1976-08-30
DE2501499A1 (en) 1976-07-22

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