GB1505028A - Preparation of gamma-pyrones - Google Patents

Preparation of gamma-pyrones

Info

Publication number
GB1505028A
GB1505028A GB30470/76A GB3047076A GB1505028A GB 1505028 A GB1505028 A GB 1505028A GB 30470/76 A GB30470/76 A GB 30470/76A GB 3047076 A GB3047076 A GB 3047076A GB 1505028 A GB1505028 A GB 1505028A
Authority
GB
United Kingdom
Prior art keywords
pyrones
gamma
preparation
formula
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30470/76A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pfizer Inc
Original Assignee
Pfizer Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pfizer Inc filed Critical Pfizer Inc
Publication of GB1505028A publication Critical patent/GB1505028A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32Oxygen atoms
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/20Synthetic spices, flavouring agents or condiments
    • A23L27/205Heterocyclic compounds
    • A23L27/2052Heterocyclic compounds having oxygen or sulfur as the only hetero atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/60Two oxygen atoms, e.g. succinic anhydride
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D309/00Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/32Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D309/00Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/34Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D309/36Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms
    • C07D309/40Oxygen atoms attached in positions 3 and 4, e.g. maltol
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D493/00Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04Ortho-condensed systems
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/0069Heterocyclic compounds
    • C11B9/0073Heterocyclic compounds containing only O or S as heteroatoms
    • C11B9/008Heterocyclic compounds containing only O or S as heteroatoms the hetero rings containing six atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Nutrition Science (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Saccharide Compounds (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pyrane Compounds (AREA)
  • Electroluminescent Light Sources (AREA)
  • Transforming Electric Information Into Light Information (AREA)
  • Picture Signal Circuits (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pyridine Compounds (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

gamma -Pyrones, for example maltol which can be used as a perfumery agent, are obtained by a rearrangement reaction of epoxybeta -pyrones of formula II, in which R and R' have the meaning given in Claim 1, with an acid. It is possible to synthesise the compound of formula II by reaction of a compound of formula III (which can be obtained from furfural) with an acid anhydride having a pKa of </= 4, and subsequent epoxidation. <IMAGE>
GB30470/76A 1975-08-28 1976-07-21 Preparation of gamma-pyrones Expired GB1505028A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US60845275A 1975-08-28 1975-08-28

Publications (1)

Publication Number Publication Date
GB1505028A true GB1505028A (en) 1978-03-22

Family

ID=24436571

Family Applications (2)

Application Number Title Priority Date Filing Date
GB30470/76A Expired GB1505028A (en) 1975-08-28 1976-07-21 Preparation of gamma-pyrones
GB43608/76A Expired GB1505029A (en) 1975-08-28 1976-07-21 2-ethyl-6-alkoxy - 2,3 - dihydro - 6h - pyran - 3- ones

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB43608/76A Expired GB1505029A (en) 1975-08-28 1976-07-21 2-ethyl-6-alkoxy - 2,3 - dihydro - 6h - pyran - 3- ones

Country Status (36)

Country Link
JP (1) JPS5231077A (en)
AR (2) AR214976A1 (en)
AT (1) AT347455B (en)
BE (1) BE843953A (en)
BG (1) BG27373A3 (en)
BR (1) BR7604541A (en)
CA (1) CA1077501A (en)
CH (1) CH620917A5 (en)
CS (2) CS193595B2 (en)
DD (2) DD131857A5 (en)
DE (1) DE2630837C3 (en)
DK (1) DK148020C (en)
ES (3) ES449938A1 (en)
FI (1) FI71316C (en)
FR (1) FR2322146A1 (en)
GB (2) GB1505028A (en)
GR (1) GR60430B (en)
HK (2) HK30081A (en)
HU (2) HU177367B (en)
IE (1) IE42789B1 (en)
IN (1) IN144978B (en)
IT (1) IT1065604B (en)
LU (1) LU75380A1 (en)
MX (1) MX3627E (en)
MY (2) MY8100265A (en)
NL (2) NL166260C (en)
NO (3) NO145952C (en)
PH (2) PH13217A (en)
PL (3) PL110369B1 (en)
PT (1) PT65357B (en)
RO (1) RO71275B (en)
SE (3) SE426592B (en)
SU (2) SU942596A3 (en)
TR (1) TR19310A (en)
YU (2) YU39355B (en)
ZA (1) ZA763902B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52153967A (en) * 1976-06-15 1977-12-21 Otsuka Chem Co Ltd 5,6-dihydro-2h-pyran-5-one derivatives
CA1095921A (en) * 1976-08-02 1981-02-17 Thomas M. Brennan Preparation of gamma-pyrones

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE225446C (en) *
US3159652A (en) * 1962-06-13 1964-12-01 Pfizer & Co C Preparation of gamma-pyrones
US3476778A (en) * 1966-05-16 1969-11-04 Monsanto Co Gamma-pyrone synthesis
US3491122A (en) * 1966-09-14 1970-01-20 Monsanto Co Synthesis of 4-pyrones
JPS5145565B1 (en) * 1968-10-12 1976-12-04
JPS5212166A (en) * 1975-07-17 1977-01-29 Tatsuya Shono Process for preparation of 4-pyron derivatives

Also Published As

Publication number Publication date
ATA517276A (en) 1978-05-15
NO147245B (en) 1982-11-22
MY8100265A (en) 1981-12-31
RO71275A (en) 1984-03-15
ES461253A1 (en) 1978-08-16
ES461252A1 (en) 1978-08-16
CS193595B2 (en) 1979-10-31
MX3627E (en) 1981-04-03
PT65357A (en) 1976-07-31
CH620917A5 (en) 1980-12-31
NO803831L (en) 1977-03-01
SE7910631L (en) 1979-12-21
NL7607730A (en) 1977-03-02
RO71275B (en) 1984-03-31
SE433078B (en) 1984-05-07
FI71316B (en) 1986-09-09
IE42789B1 (en) 1980-10-22
MY8100273A (en) 1981-12-31
FR2322146B1 (en) 1978-10-20
BE843953A (en) 1977-01-10
PL110241B1 (en) 1980-07-31
DE2630837B2 (en) 1980-08-21
PH13217A (en) 1980-02-07
YU103182A (en) 1982-08-31
ZA763902B (en) 1977-05-25
BR7604541A (en) 1977-08-02
PL110369B1 (en) 1980-07-31
CS193557B2 (en) 1979-10-31
IE42789L (en) 1977-02-28
SU942596A3 (en) 1982-07-07
PL104612B1 (en) 1979-08-31
FI71316C (en) 1986-12-19
PH14410A (en) 1981-06-25
IT1065604B (en) 1985-03-04
NO803832L (en) 1977-03-01
NL166260B (en) 1981-02-16
PT65357B (en) 1978-01-09
HU177367B (en) 1981-09-28
AU1578376A (en) 1978-01-12
YU39577B (en) 1984-12-31
NO145952B (en) 1982-03-22
DD131857A5 (en) 1978-07-26
LU75380A1 (en) 1977-04-04
TR19310A (en) 1978-11-28
NO145952C (en) 1982-06-30
FR2322146A1 (en) 1977-03-25
NO147245C (en) 1983-03-02
BG27373A3 (en) 1979-10-12
AR215618A1 (en) 1979-10-31
HU187762B (en) 1986-02-28
DE2630837C3 (en) 1981-07-09
IN144978B (en) 1978-08-05
SU1169540A3 (en) 1985-07-23
CA1077501A (en) 1980-05-13
DK148020B (en) 1985-02-04
HK29981A (en) 1981-07-10
SE7910630L (en) 1979-12-21
DK315576A (en) 1976-02-29
SE432929B (en) 1984-04-30
AT347455B (en) 1978-12-27
DE2630837A1 (en) 1977-03-03
HK30081A (en) 1981-07-10
SE7607321L (en) 1977-03-01
JPS5231077A (en) 1977-03-09
ES449938A1 (en) 1978-03-16
NO146572C (en) 1982-10-27
NO146572B (en) 1982-07-19
DD127201A5 (en) 1977-09-14
SE426592B (en) 1983-01-31
GR60430B (en) 1978-05-26
YU160476A (en) 1982-08-31
GB1505029A (en) 1978-03-22
NL8004974A (en) 1980-11-28
NO762449L (en) 1977-03-01
DK148020C (en) 1985-10-07
YU39355B (en) 1984-10-31
NL166260C (en) 1981-07-15
AR214976A1 (en) 1979-08-31
FI762039A (en) 1977-03-01

Similar Documents

Publication Publication Date Title
JPS5368770A (en) Preparation of dicarboxylic acid amide
GB1505028A (en) Preparation of gamma-pyrones
ES449817A1 (en) Substituted 2-phenylimino-thiazolines a process for their preparation and their use as ectoparasiticides
JPS51136615A (en) Process for preparation of methacrylic acid
JPS52211A (en) Process for preparatiopn of epoxides
JPS5285163A (en) Preparation of malenimide derivatives
JPS5281396A (en) Preparation of curable resins
JPS5225710A (en) Process for preparation of isopropyl acetate
JPS51131522A (en) A process for preparing perinone dyes
JPS51136658A (en) Process for preparation of 2-naphthoic acid derivatives
GB1123891A (en) Imidazolidine derivatives
JPS51113809A (en) Process for preparation of 1,3-propanediols
JPS51143645A (en) Process for preparation of 3,3-dimethyl- 2-(2,2-dihalo)cyclopropanecar boxylic acid ester
JPS5283434A (en) Preparation of cyclopropylcarbinol derivatives
JPS525708A (en) Process for preparation of gamma-unsaturated carboxylic acid ester
JPS51127014A (en) Process for preparation of terpenealcoholacetates
JPS51133226A (en) Process for preparation of 1,12-dodecane dicarboxylic acid diesters
JPS5283344A (en) Synthesis of 3-chloro-4-allyloxyphenyl-acetic acid
JPS5251308A (en) Process for preparation of cysteamines
JPS51141814A (en) Process for preparation of 4-oxopentadecane dicarboxylic acid or its e sters
JPS51138681A (en) Process for preparing 1-carboxybenzopyrans
BE607551A (en) Process for the preparation of new isophthalic acid derivatives.
JPS5231089A (en) Preparation of 3-acyloxy-3- methylcephalosporins derivatives
JPS5233616A (en) Process for preparation of methacrylic acid
JPS5231093A (en) Preparation of 3- methylenecephalosporanic acid derivatives

Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years

Effective date: 19960720