GB1422056A - Polyurethane foams - Google Patents

Polyurethane foams

Info

Publication number
GB1422056A
GB1422056A GB2536873A GB2536873A GB1422056A GB 1422056 A GB1422056 A GB 1422056A GB 2536873 A GB2536873 A GB 2536873A GB 2536873 A GB2536873 A GB 2536873A GB 1422056 A GB1422056 A GB 1422056A
Authority
GB
United Kingdom
Prior art keywords
isomer
diphenylmethane diisocyanate
composition
prepared
glycerol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2536873A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2536873A priority Critical patent/GB1422056A/en
Priority to BE144740A priority patent/BE815523A/en
Priority to FR7418422A priority patent/FR2231705B3/fr
Priority to IT2327474A priority patent/IT1012895B/en
Priority to DE19742425657 priority patent/DE2425657C2/en
Priority to ES426729A priority patent/ES426729A1/en
Publication of GB1422056A publication Critical patent/GB1422056A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

1422056 Polyurethane foams IMPERIAL CHEMICAL INDUSTRIES Ltd 10 May 1974 [29 May 1973] 25368/73 Heading C3R A flexible polyurethane foam is prepared by reacting in the presence of a blowing agent, a polyether having at least 2 hydroxyl end groups and a diphenylmethane diisocyanate composition which has an average isocyanate functionality of less than 2À4 contains not more than 60% wt. of 4,4<SP>1</SP>-diphenylmethane diisocyanate and wherein at least 15% wt. of the content of diphenylmethane diisocyanate isomers consists of 2,4<SP>1</SP>-diphenylmethane diisocyanate. The diphenylmethane composition may consist wholly of the 2,4<SP>1</SP>-isomer, or it may be a retined composition containing 40-80% wt. of the 2,41-isomer, the remainder being substantially the 4, 4<SP>1</SP>-isomer, or it may be a crude composition prepared by phosgenation of crude mixtures of polyamine obtained by the catalytic condensation of aniline and formaldehyde. Suitable polyethers are polyoxyalkylene polyols of M.Wt. 2000-10,000 preferably containing both ethylene oxide and 1,2-propylene oxide units in random or block polymer chains. Preferred polyols is a mixture of a diol and triol based on a diethylene glycol/glycerol initiator containing blocks of oxypropylene units terminated with oxyethylene units and having a M.Wt. of 3000- 6500 with from 50-80% of the OH groups being primary. Suitable foaming agents includes water alone or together with a halogenated hydrocarbon. Optional ingredients include catalysts particularly a mixture of a tertiary amine and a tin compound; chain extenders, e.g. glycerol, trimethylol propane and triethanolamine and other conventional additives. In the examples foams are prepared from a polyoxyalkylene polyol (diol/triol mixture based on diethylene glycol/glycerol plus propylene oxide) tipped with ethylene oxide, having 80% primary OH groups, and M.Wt. of 4850; water alone and together with trichlorofluoromethane; bis - (3 - dimethylaminopropyl) urea and stannous octoate as catalysts; and diisocyanato diphenyl methane containing 40% 2,41-isomer and 60% 4,4<SP>1</SP>-isomer alone or together with a crude diphenylmethane diisocyanate composition of functionality 2À6. Other similar examples are described with varying percentages of the 2,4<SP>1</SP>- and 4,4<SP>1</SP>-isomers.
GB2536873A 1973-05-29 1973-05-29 Polyurethane foams Expired GB1422056A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
GB2536873A GB1422056A (en) 1973-05-29 1973-05-29 Polyurethane foams
BE144740A BE815523A (en) 1973-05-29 1974-05-24 EXPANDED POLYURETHANES
FR7418422A FR2231705B3 (en) 1973-05-29 1974-05-28
IT2327474A IT1012895B (en) 1973-05-29 1974-05-28 EXPANDED POLYURETHANE
DE19742425657 DE2425657C2 (en) 1973-05-29 1974-05-28 Process for the production of a flexible polyurethane foam
ES426729A ES426729A1 (en) 1973-05-29 1974-05-29 Polyurethane foams

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2536873A GB1422056A (en) 1973-05-29 1973-05-29 Polyurethane foams

Publications (1)

Publication Number Publication Date
GB1422056A true GB1422056A (en) 1976-01-21

Family

ID=10226542

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2536873A Expired GB1422056A (en) 1973-05-29 1973-05-29 Polyurethane foams

Country Status (6)

Country Link
BE (1) BE815523A (en)
DE (1) DE2425657C2 (en)
ES (1) ES426729A1 (en)
FR (1) FR2231705B3 (en)
GB (1) GB1422056A (en)
IT (1) IT1012895B (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2537775A1 (en) * 1974-09-09 1976-04-08 Upjohn Co THERMOPLASTIC, REUSABLE POLYURETHANE ELASTOMERS
US5314588A (en) * 1991-08-20 1994-05-24 Bayer Aktiengesellschaft Process for recovering polysocyanates from the distillation residues obtained in the production of tolylene diisocyanate
US5621016A (en) * 1992-04-16 1997-04-15 Imperial Chemical Industries Plc Polyisocyanate compositions and low density flexible polyurethane foams produced therewith
US6417241B1 (en) 1998-08-07 2002-07-09 Huntsman Ici Chemicals Llc Process for preparing a flexible polyurethane foam
US6770684B2 (en) 2001-03-13 2004-08-03 Basf Aktiengesellschaft Production of flexible polyurethane foams
DE102009033710A1 (en) 2009-07-18 2011-01-20 Evonik Goldschmidt Gmbh Use of metal salts of a carboxylic acid in the production of polyurethane systems
DE102010003672A1 (en) 2010-04-07 2011-10-13 Evonik Goldschmidt Gmbh Preparation and Use of Metal Salts of Alkyl Oxide and / or Aryl Alkoxylate Oligomers and Acid Terminated Polymers in the Preparation of Polyurethane Systems
EP2557101A1 (en) 2011-08-11 2013-02-13 Evonik Goldschmidt GmbH Formula containing tin and/or zinc salts of ricinoleic acid, urea, polyethylene glycol and sugar alcohol and use of the formula in the production of polyurethane systems
EP2557100A1 (en) 2011-08-11 2013-02-13 Evonik Goldschmidt GmbH Compound containing tin and/or zinc salts of ricinoleic acid, urea and at least one other tin carboxylate and use of the compound in the production of polyurethane systems
EP2752243A1 (en) 2013-01-04 2014-07-09 Evonik Industries AG Use of tin salts of neodecanoic acid in the production of polyurethane systems
EP2762509A1 (en) 2013-02-05 2014-08-06 Evonik Industries AG Composition for use in the production of polyurethane systems
JP2017110113A (en) * 2015-12-16 2017-06-22 株式会社ブリヂストン Flexible polyurethane foam, and pad for sheet
CN108368228A (en) * 2015-12-16 2018-08-03 株式会社普利司通 Flexible polyurethane foams and seat cushion

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4256849A (en) 1976-10-21 1981-03-17 Bayer Aktiengesellschaft Process for the production of cold setting foams which contain urethane groups prepared from a mixture of 4,4-diphenyl methane diisocyanate and 2,4-diphenyl methane diisocyanate
DE2647482A1 (en) * 1976-10-21 1978-04-27 Bayer Ag PROCESS FOR THE MANUFACTURING OF COLD-CARDING FOAMS CONTAINING URETHANE GROUPS
DE2717653C2 (en) * 1977-04-21 1988-05-26 Bayer Ag, 5090 Leverkusen Process for the production of cold-curing, flexible foams containing urethane groups
EP0031650B1 (en) * 1979-12-14 1984-10-03 Imperial Chemical Industries Plc Process for preparing liquid polyisocyanate compositions, and their use
US4603076A (en) * 1985-03-04 1986-07-29 Norwood Industries, Inc. Hydrophilic foam
DE3934098C1 (en) * 1989-10-12 1991-05-23 Bayer Ag, 5090 Leverkusen, De
DE3942329A1 (en) * 1989-12-21 1991-06-27 Basf Ag METHOD FOR PRODUCING POLYURETHANOUS FUEL GRAINS WITH LOW STERILIZED HAIR AND BLOCKPOLYOXYPROPYLENE POLYOXYETHYLENE POLYOL MIXTURES USES THEREOF

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3362979A (en) * 1964-01-02 1968-01-09 Jefferson Chem Co Inc Mixtures of methylene-bridged polyphenyl polyisocyanates
GB1240708A (en) * 1967-07-31 1971-07-28 Upjohn Co Polyurethane foams

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2537775A1 (en) * 1974-09-09 1976-04-08 Upjohn Co THERMOPLASTIC, REUSABLE POLYURETHANE ELASTOMERS
US5314588A (en) * 1991-08-20 1994-05-24 Bayer Aktiengesellschaft Process for recovering polysocyanates from the distillation residues obtained in the production of tolylene diisocyanate
US5621016A (en) * 1992-04-16 1997-04-15 Imperial Chemical Industries Plc Polyisocyanate compositions and low density flexible polyurethane foams produced therewith
US6417241B1 (en) 1998-08-07 2002-07-09 Huntsman Ici Chemicals Llc Process for preparing a flexible polyurethane foam
US6770684B2 (en) 2001-03-13 2004-08-03 Basf Aktiengesellschaft Production of flexible polyurethane foams
EP2770001A1 (en) 2009-07-18 2014-08-27 Evonik Degussa GmbH Use of tin salts of a carboxylic acid in the production of polyurethane systems
DE102009033710A1 (en) 2009-07-18 2011-01-20 Evonik Goldschmidt Gmbh Use of metal salts of a carboxylic acid in the production of polyurethane systems
EP2289960A1 (en) 2009-07-18 2011-03-02 Evonik Goldschmidt GmbH Use of metallic salts of a carboxylic acid in the production of polyurethane systems
US9096706B2 (en) 2010-04-07 2015-08-04 Evonik Degussa Gmbh Production and use of metal salts of alkyl oxide and/or aryl alkyl oxide oligomers and polymers with acid end groups in the production of polyurethane systems
WO2011124432A1 (en) 2010-04-07 2011-10-13 Evonik Goldschmidt Gmbh Production and use of metal salts of alkyl oxide and/or aryl alkyl oxide oligomers and polymers with acid end groups in the production of polyurethane systems
DE102010003672A1 (en) 2010-04-07 2011-10-13 Evonik Goldschmidt Gmbh Preparation and Use of Metal Salts of Alkyl Oxide and / or Aryl Alkoxylate Oligomers and Acid Terminated Polymers in the Preparation of Polyurethane Systems
DE102011110020A1 (en) 2011-08-11 2013-02-14 Evonik Goldschmidt Gmbh Formulation containing tin and / or zinc salts of ricinoleic acid, urea, polyethylene glycol and sugar alcohol and use of the formulation in the preparation of polyurethane systems
EP2557101A1 (en) 2011-08-11 2013-02-13 Evonik Goldschmidt GmbH Formula containing tin and/or zinc salts of ricinoleic acid, urea, polyethylene glycol and sugar alcohol and use of the formula in the production of polyurethane systems
DE102011110016A1 (en) 2011-08-11 2013-02-14 Evonik Goldschmidt Gmbh Composition comprising tin and / or zinc salts of ricinoleic acid and at least one further tin carboxylate and use of the composition in the production of polyurethane systems
EP2557100A1 (en) 2011-08-11 2013-02-13 Evonik Goldschmidt GmbH Compound containing tin and/or zinc salts of ricinoleic acid, urea and at least one other tin carboxylate and use of the compound in the production of polyurethane systems
EP2752243A1 (en) 2013-01-04 2014-07-09 Evonik Industries AG Use of tin salts of neodecanoic acid in the production of polyurethane systems
WO2014106642A1 (en) 2013-01-04 2014-07-10 Evonik Industries Ag Use of tin salts of neodecanoic acid in the production of polyurethane systems
EP2762509A1 (en) 2013-02-05 2014-08-06 Evonik Industries AG Composition for use in the production of polyurethane systems
DE102013201825A1 (en) 2013-02-05 2014-08-07 Evonik Industries Ag Composition for use in the manufacture of polyurethane systems
JP2017110113A (en) * 2015-12-16 2017-06-22 株式会社ブリヂストン Flexible polyurethane foam, and pad for sheet
CN108368236A (en) * 2015-12-16 2018-08-03 株式会社普利司通 Flexible polyurethane foams and seat cushion
CN108368228A (en) * 2015-12-16 2018-08-03 株式会社普利司通 Flexible polyurethane foams and seat cushion
EP3392283A4 (en) * 2015-12-16 2018-10-24 Bridgestone Corporation Soft polyurethane foam and seat pad
EP3392282A4 (en) * 2015-12-16 2018-10-24 Bridgestone Corporation Soft polyurethane foam and seat pad

Also Published As

Publication number Publication date
FR2231705A1 (en) 1974-12-27
DE2425657C2 (en) 1983-08-25
FR2231705B3 (en) 1977-03-25
ES426729A1 (en) 1976-07-01
IT1012895B (en) 1977-03-10
DE2425657A1 (en) 1974-12-19
BE815523A (en) 1974-11-25

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19930510