GB1396062A - Rechargeable solid state electro-chemical cell having a lithium anode and a method of manufacturing the same - Google Patents

Rechargeable solid state electro-chemical cell having a lithium anode and a method of manufacturing the same

Info

Publication number
GB1396062A
GB1396062A GB3172273A GB3172273A GB1396062A GB 1396062 A GB1396062 A GB 1396062A GB 3172273 A GB3172273 A GB 3172273A GB 3172273 A GB3172273 A GB 3172273A GB 1396062 A GB1396062 A GB 1396062A
Authority
GB
United Kingdom
Prior art keywords
lithium
separator
cell
sulphide
catholyte
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3172273A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alcatel Lucent SAS
Original Assignee
Compagnie Generale dElectricite SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie Generale dElectricite SA filed Critical Compagnie Generale dElectricite SA
Priority to GB3172273A priority Critical patent/GB1396062A/en
Publication of GB1396062A publication Critical patent/GB1396062A/en
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Primary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

1396062 Solid state cell with lithium anode COMPAGNIE GENERALE D'ELECTRICITE 12 July 1973 31722/73 Addition to 1383447 Heading H1B A rechargeable cell comprises the following thin solid layers:-cathodic collector 6, catholyte 8 for supplying anions capable of forming a salt with lithium, separator 10 comprising a porous layer impregnated with a mixture of an organic bonding agent, viz polyvinyl formal, with a lithium salt at least partially solvated by a solvent constituted by propylene carbonate, and a lithium anode 12. These layers are held under pressure in a sealed housing 2 which pressure may be applied by a spring 14 acting between a stainless steel plate 13 and a terminal plate 4. The plates 4, 6 may be of steel. In the instance where a number of cells are stacked in succession in a common housing, the plate 6 comprises a copper grid disposed on a copper sheet. The catholyte 8 is in the form of a pulp or gel and comprises cupric sulphide powder mixed with a solvent, viz propylene carbonate, and a binder, viz polyvinyl formal. The impregnated porous layer of the separator 10 may be constituted by asbestos or filter paper. The solvated lithium salt in the separator is lithium iodide or lithium perchlorate. During discharge of the cell, the cupric sulphide is converted to cuprous sulphide and lithium sulphide is formed at the anode. Methods of making the catholyte 8, separator 10 and assembling the cell, are described.
GB3172273A 1973-07-12 1973-07-12 Rechargeable solid state electro-chemical cell having a lithium anode and a method of manufacturing the same Expired GB1396062A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3172273A GB1396062A (en) 1973-07-12 1973-07-12 Rechargeable solid state electro-chemical cell having a lithium anode and a method of manufacturing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3172273A GB1396062A (en) 1973-07-12 1973-07-12 Rechargeable solid state electro-chemical cell having a lithium anode and a method of manufacturing the same

Publications (1)

Publication Number Publication Date
GB1396062A true GB1396062A (en) 1975-05-29

Family

ID=10327409

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3172273A Expired GB1396062A (en) 1973-07-12 1973-07-12 Rechargeable solid state electro-chemical cell having a lithium anode and a method of manufacturing the same

Country Status (1)

Country Link
GB (1) GB1396062A (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2511547A1 (en) * 1981-08-13 1983-02-18 Moli Energy Ltd Electrode assembly for sec. cell - esp. using lithium anode and lithium:molybdenum sulphide cathodes pressed together to increase total working output of cell
US5114804A (en) * 1981-08-13 1992-05-19 Moli Energy Limited Battery and method of making the battery
EP0606533A2 (en) * 1992-11-19 1994-07-20 Sanyo Electric Co., Ltd Secondary battery
EP2409349A2 (en) * 2009-03-19 2012-01-25 Sion Power Corporation Cathode for lithium battery
US8936870B2 (en) 2011-10-13 2015-01-20 Sion Power Corporation Electrode structure and method for making the same
US9005809B2 (en) 2009-08-28 2015-04-14 Sion Power Corporation Electrochemical cells comprising porous structures comprising sulfur
US9034421B2 (en) 2008-01-08 2015-05-19 Sion Power Corporation Method of forming electrodes comprising sulfur and porous material comprising carbon
US9077041B2 (en) 2012-02-14 2015-07-07 Sion Power Corporation Electrode structure for electrochemical cell
US9548492B2 (en) 2011-06-17 2017-01-17 Sion Power Corporation Plating technique for electrode
US9577267B2 (en) 2012-12-19 2017-02-21 Sion Power Corporation Electrode structure and method for making same
CZ306913B6 (en) * 2016-09-15 2017-09-06 Jaroslav PolĂ­vka A lithium accumulator with high capacity and increased safety
US10319988B2 (en) 2014-05-01 2019-06-11 Sion Power Corporation Electrode fabrication methods and associated systems and articles
US10629947B2 (en) 2008-08-05 2020-04-21 Sion Power Corporation Electrochemical cell

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5114804A (en) * 1981-08-13 1992-05-19 Moli Energy Limited Battery and method of making the battery
FR2511547A1 (en) * 1981-08-13 1983-02-18 Moli Energy Ltd Electrode assembly for sec. cell - esp. using lithium anode and lithium:molybdenum sulphide cathodes pressed together to increase total working output of cell
EP0606533A2 (en) * 1992-11-19 1994-07-20 Sanyo Electric Co., Ltd Secondary battery
EP0606533A3 (en) * 1992-11-19 1996-05-08 Sanyo Electric Co Secondary battery.
US9034421B2 (en) 2008-01-08 2015-05-19 Sion Power Corporation Method of forming electrodes comprising sulfur and porous material comprising carbon
US10629947B2 (en) 2008-08-05 2020-04-21 Sion Power Corporation Electrochemical cell
EP2409349A2 (en) * 2009-03-19 2012-01-25 Sion Power Corporation Cathode for lithium battery
EP2409349A4 (en) * 2009-03-19 2013-05-01 Sion Power Corp Cathode for lithium battery
US9005809B2 (en) 2009-08-28 2015-04-14 Sion Power Corporation Electrochemical cells comprising porous structures comprising sulfur
US9419274B2 (en) 2009-08-28 2016-08-16 Sion Power Corporation Electrochemical cells comprising porous structures comprising sulfur
US9548492B2 (en) 2011-06-17 2017-01-17 Sion Power Corporation Plating technique for electrode
US11456459B2 (en) 2011-06-17 2022-09-27 Sion Power Corporation Plating technique for electrode
US8936870B2 (en) 2011-10-13 2015-01-20 Sion Power Corporation Electrode structure and method for making the same
US9040197B2 (en) 2011-10-13 2015-05-26 Sion Power Corporation Electrode structure and method for making the same
US9077041B2 (en) 2012-02-14 2015-07-07 Sion Power Corporation Electrode structure for electrochemical cell
US9577267B2 (en) 2012-12-19 2017-02-21 Sion Power Corporation Electrode structure and method for making same
US10319988B2 (en) 2014-05-01 2019-06-11 Sion Power Corporation Electrode fabrication methods and associated systems and articles
CZ306913B6 (en) * 2016-09-15 2017-09-06 Jaroslav PolĂ­vka A lithium accumulator with high capacity and increased safety

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee