GB1325715A - Bimetallic catalyst manufacture and use in ethylene oxidation - Google Patents

Bimetallic catalyst manufacture and use in ethylene oxidation

Info

Publication number
GB1325715A
GB1325715A GB5794770A GB5794770A GB1325715A GB 1325715 A GB1325715 A GB 1325715A GB 5794770 A GB5794770 A GB 5794770A GB 5794770 A GB5794770 A GB 5794770A GB 1325715 A GB1325715 A GB 1325715A
Authority
GB
United Kingdom
Prior art keywords
silver
derivative
ethylene oxide
dec
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5794770A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1325715A publication Critical patent/GB1325715A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1325715 Ethylene oxide ESSO RESEARCH & ENG CO 7 Dec 1970 [23 Dec 1969] 57947/70 Heading C2C [Also in Division C7] Ethylene oxide is obtained by the oxidation of ethylene with oxygen or an oxygen-containing gas in the presence of a bimetallic catalyst consisting of a major proportion (by weight) of silver and a minor proportion of one metal from Groups IB, IIIB at the iron sub group of Group VIII of the Periodic Table (Fisher Scientific Co 1953) and which is prepared by contacting a high surface area derivative of silver with an aqueous solution of a soluble salt of the second metal, drying the impregnated silver derivative, reducing it, and some barium peroxide may be added to the initial silver derivative to prevent wasting the reduced material. Some barium peroxide may be added to the initial silver derivative to prevent long-term deactivation of the catalyst. Examples describe the preparation of ethylene oxide using Ag/Au, Ag/Re, Ag/Cu, Ag/Mn, Ag/Fe and Ag/Ru catalysts.
GB5794770A 1969-12-23 1970-12-07 Bimetallic catalyst manufacture and use in ethylene oxidation Expired GB1325715A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US88774769A 1969-12-23 1969-12-23

Publications (1)

Publication Number Publication Date
GB1325715A true GB1325715A (en) 1973-08-08

Family

ID=25391783

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5794770A Expired GB1325715A (en) 1969-12-23 1970-12-07 Bimetallic catalyst manufacture and use in ethylene oxidation

Country Status (6)

Country Link
JP (1) JPS515357B1 (en)
BE (1) BE760686A (en)
DE (1) DE2062190A1 (en)
FR (1) FR2074187A5 (en)
GB (1) GB1325715A (en)
NL (1) NL7018651A (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0266015A1 (en) 1986-10-31 1988-05-04 Shell Internationale Researchmaatschappij B.V. Ethylene oxide catalyst and process for the catalytic production of ethylene oxide
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4808738A (en) * 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
US4820675A (en) * 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
US4833261A (en) * 1986-10-31 1989-05-23 Shell Oil Company Ethylene oxide process
US5364826A (en) * 1993-09-13 1994-11-15 Shell Oil Company Process for preparing ethylene oxide catalysts
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5486628A (en) * 1993-05-17 1996-01-23 Kemp; Richard A. Ethylene oxide catalyst and process
US5545603A (en) * 1994-11-01 1996-08-13 Shell Oil Company Ethylene oxide catalyst and process
US5739075A (en) * 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
US5801259A (en) * 1996-04-30 1998-09-01 Shell Oil Company Ethylene oxide catalyst and process

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2938245A1 (en) * 1979-09-21 1981-04-09 Hoechst Ag, 6000 Frankfurt METHOD FOR IMPROVING THE EFFECTIVENESS OF SILVER CARRIER CATALYSTS
KR100255480B1 (en) * 1996-03-21 2000-05-01 사또 다께오 Catalysts for partial oxidation of hydrocarbons and method of partial oxidation of hydrocarbon

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB434011A (en) * 1934-04-26 1935-08-23 Bataafsche Petroleum A process for manufacturing ethylene oxide
US2615899A (en) * 1949-06-23 1952-10-28 Du Pont Catalyst and process for ethylene oxide manufacture
US2593156A (en) * 1950-12-09 1952-04-15 Ethyl Corp Ethylene oxidation and silver on magnetite as catalyst therefor
US2985668A (en) * 1957-01-30 1961-05-23 Shingu Haruo Preparation of olefin oxides
GB1129190A (en) * 1966-01-13 1968-10-02 Engelhard Min & Chem Silver catalysts

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0266015A1 (en) 1986-10-31 1988-05-04 Shell Internationale Researchmaatschappij B.V. Ethylene oxide catalyst and process for the catalytic production of ethylene oxide
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4808738A (en) * 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
US4820675A (en) * 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
US4833261A (en) * 1986-10-31 1989-05-23 Shell Oil Company Ethylene oxide process
US5486628A (en) * 1993-05-17 1996-01-23 Kemp; Richard A. Ethylene oxide catalyst and process
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5380885A (en) * 1993-09-13 1995-01-10 Shell Oil Company Process for preparing ethylene oxide
US5364826A (en) * 1993-09-13 1994-11-15 Shell Oil Company Process for preparing ethylene oxide catalysts
US5545603A (en) * 1994-11-01 1996-08-13 Shell Oil Company Ethylene oxide catalyst and process
US5739075A (en) * 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
US5801259A (en) * 1996-04-30 1998-09-01 Shell Oil Company Ethylene oxide catalyst and process

Also Published As

Publication number Publication date
JPS515357B1 (en) 1976-02-19
NL7018651A (en) 1971-06-25
FR2074187A5 (en) 1971-10-01
DE2062190A1 (en) 1971-07-08
BE760686A (en) 1971-06-22

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee