GB1260269A - Novel acrylic monomers, their preparation and treatment - Google Patents

Novel acrylic monomers, their preparation and treatment

Info

Publication number
GB1260269A
GB1260269A GB2057070A GB2057070A GB1260269A GB 1260269 A GB1260269 A GB 1260269A GB 2057070 A GB2057070 A GB 2057070A GB 2057070 A GB2057070 A GB 2057070A GB 1260269 A GB1260269 A GB 1260269A
Authority
GB
United Kingdom
Prior art keywords
unsubstituted
formula
acid
aryl
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2057070A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Inc
Original Assignee
PPG Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PPG Industries Inc filed Critical PPG Industries Inc
Publication of GB1260269A publication Critical patent/GB1260269A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/20—Esters of polyhydric alcohols or polyhydric phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Paints Or Removers (AREA)

Abstract

1,260,269. Acrylic monomers. PPG INDUSTRIES Inc. 29 April, 1970 [30 April, 1969; 26 May, 1969], No. 20570/70. Heading C2C. A novel mixture of acrylic monomers comprising (i) a compound having the general formula wherein one of R 11 and R 12 is an unsubstituted or substituted alkyl, aryl or cycloalkyl group and the other of R 11 and R 12 is a radical of the formula wherein R 21 is a hydrogen or halogen atom, or an unsubstituted or halosubstituted methyl or ethyl group, R 13 , R 14 , R 19 and R 20 are hydrogen atoms or unsubstituted or substituted alkyl, aryl or cycloalkyl groups, R 15 , R 16 , R 17 and R 18 are hydrogen atoms or alkyl, aryl or cycloalkyl groups and k, l, m, n, p and q are integers of from 0 to 5; (ii) a compound of the first general formula given above in which both of R 11 and R 12 are unsubstituted or substituted alkyl, aryl or cycloalkyl groups, and (iii) a compound of the formula wherein both R 22 and R 23 are radicals of the formula wherein R 24 is a hydrogen or halogen atom or an unsubstituted or halo-substituted methyl or ethyl radical, is prepared by reacting a compound of the formula with (a) acrylic acid, methacrylic acid or an acid anhydride or acid chloride thereof and (b) an aliphatic, alicyclic or aromatic monofunctional acid which is not polymerizable in itself such as acetic, butyric, benzoic and 2-ethylhexoic acids. The compounds (i), (ii) and (iii) are also claimed per se. The reaction is preferably carried out at a temperature of from 50‹ 150‹ C. in the presence of an acid catalyst and an inhibitor.
GB2057070A 1969-04-30 1970-04-29 Novel acrylic monomers, their preparation and treatment Expired GB1260269A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US82067269A 1969-04-30 1969-04-30
US82797469A 1969-05-26 1969-05-26

Publications (1)

Publication Number Publication Date
GB1260269A true GB1260269A (en) 1972-01-12

Family

ID=27124476

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2057070A Expired GB1260269A (en) 1969-04-30 1970-04-29 Novel acrylic monomers, their preparation and treatment

Country Status (5)

Country Link
DE (1) DE2020419C3 (en)
DK (1) DK146047C (en)
FR (1) FR2056170A5 (en)
GB (1) GB1260269A (en)
SE (2) SE393371B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5243069A (en) * 1981-12-11 1993-09-07 Rohm And Haas Company Ester of Michael addition homopolymers of acrylic acid

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE793646A (en) * 1972-01-03 1973-05-02 Gaf Corp STABLE SIZE COVER SLABS
DE3204504A1 (en) * 1982-02-10 1983-08-18 Henkel KGaA, 4000 Düsseldorf NEW SERIOUS MONO AND / OR BIS (METH) ACRYLATES AND THEIR USE
US4775732A (en) * 1988-01-11 1988-10-04 Allied-Signal Inc. Vinyl ether terminated ester and urethane resins from bis(hydroxyalkyl)cycloalkanes

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3320336A (en) * 1963-11-14 1967-05-16 Eastman Kodak Co Unsaturated polyesters having branched structures
GB1135647A (en) * 1965-06-29 1968-12-04 Grace W R & Co New esters
US3470079A (en) * 1966-05-18 1969-09-30 Ppg Industries Inc Highly radiation-sensitive telomerized polyamides

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5243069A (en) * 1981-12-11 1993-09-07 Rohm And Haas Company Ester of Michael addition homopolymers of acrylic acid

Also Published As

Publication number Publication date
DK146047C (en) 1983-11-07
FR2056170A5 (en) 1971-05-14
DE2020419A1 (en) 1971-01-14
SE396757B (en) 1977-10-03
SE393371B (en) 1977-05-09
DE2020419C3 (en) 1982-07-22
DK146047B (en) 1983-06-13
DE2020419B2 (en) 1977-06-30

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee