GB1235062A - Preparation of alkene polymers and activated catalyst compositions therefor - Google Patents

Preparation of alkene polymers and activated catalyst compositions therefor

Info

Publication number
GB1235062A
GB1235062A GB2466269A GB2466269A GB1235062A GB 1235062 A GB1235062 A GB 1235062A GB 2466269 A GB2466269 A GB 2466269A GB 2466269 A GB2466269 A GB 2466269A GB 1235062 A GB1235062 A GB 1235062A
Authority
GB
United Kingdom
Prior art keywords
preparation
ticl
activator
component
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2466269A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stamicarbon BV
Original Assignee
Stamicarbon BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stamicarbon BV filed Critical Stamicarbon BV
Publication of GB1235062A publication Critical patent/GB1235062A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1,235,062. Polymerization of alkenes. STAMICARBON N.V. 14 May, 1969 [15 May, 1968], No. 24662/69. Heading C3P. Solutions of alkene polymers are prepared by polymerization of one or more alkenes at above 110‹ C. in a liquid dispersing agent using a catalyst obtained by mixing an Al-halogen compound, a Ti compound and an organo-Mg compound, and incorporating an activator into the catalyst during and/or after the preparation and/or mixing of the catalyst components, the activator being an alkanol, alkenol, alkanolate, alkenolate, carboxylic acid or salt or ester thereof, ketone or aldehyde. In the examples ethylene or propylene is polymerized using AlEt 2 Cl, AlEt 1À5 Cl 1À5 or AlCl 3 as Al-halogen component; Ph 2 Mg, C 4 H 9 (C 10 H 21 O)Mg, (C 4 H 9 ) 2 Mg, C 4 H 9 - (C 3 H 7 O)Mg, C 4 H 9 MgCl and 2(C 4 H 9 O) 2 .O(C 4 H 9 ) 2 - Mg as organo-Mg component; TiCl 4 , TiCl 3 Ti(OC 4 H 9 ) 4 or TiCl 3 /VOCl 3 as Ti component; decanol, cyclohexanone, benzoic acid, butylacrylate, benzaldehyde, Al(OEt) 3 , and Mgstearate as activator and pentamethylheptane and hexane as diluent.
GB2466269A 1968-05-15 1969-05-14 Preparation of alkene polymers and activated catalyst compositions therefor Expired GB1235062A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL6806890A NL153555B (en) 1968-05-15 1968-05-15 PROCESS FOR PREPARING ALKIN POLYMERS.

Publications (1)

Publication Number Publication Date
GB1235062A true GB1235062A (en) 1971-06-09

Family

ID=19803638

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2466269A Expired GB1235062A (en) 1968-05-15 1969-05-14 Preparation of alkene polymers and activated catalyst compositions therefor

Country Status (14)

Country Link
AT (1) AT296598B (en)
BE (1) BE733064A (en)
BG (1) BG17815A3 (en)
BR (1) BR6908842D0 (en)
CS (1) CS171205B2 (en)
DE (1) DE1924709A1 (en)
ES (1) ES367250A1 (en)
FR (1) FR2008619A1 (en)
GB (1) GB1235062A (en)
HU (1) HU164120B (en)
NL (1) NL153555B (en)
PL (1) PL79992B1 (en)
SE (1) SE381879B (en)
SU (1) SU400109A3 (en)

Cited By (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2259516A1 (en) * 1971-12-08 1973-06-14 Solvay METHOD OF POLYMERIZATION OF OLEFINS
US4069169A (en) 1975-11-24 1978-01-17 Mitsui Petrochemical Industries Ltd. Process for preparation of catalyst component supported on high performance carrier
US4076926A (en) 1975-05-14 1978-02-28 Imperial Chemical Industries Limited Polymerization catalyst comprising aluminum halide and an alcohol or ether
US4163831A (en) 1974-04-22 1979-08-07 The Dow Chemical Company High efficiency titanate catalyst for polymerizing olefins
US4172050A (en) * 1974-04-22 1979-10-23 The Dow Chemical Company High efficiency titanate catalyst for polymerizing olefins
US4189554A (en) * 1976-05-14 1980-02-19 Phillips Petroleum Company Magnesium reducing agent prepared in absence of complexing diluent milled with organoaluminum
US4194075A (en) * 1976-05-14 1980-03-18 Phillips Petroleum Company Magnesium reducing agent-hydrocarbylaluminum halide cocatalyst for titanium tetrahalide
EP0008595A1 (en) * 1978-09-13 1980-03-19 The Dow Chemical Company Organomagnesium catalyst compositions and their use for polymerizing olefins
US4199473A (en) * 1976-12-29 1980-04-22 The International Synthetic Rubber Co. Ltd. Olefin polymerization
US4229558A (en) * 1976-12-13 1980-10-21 Mitsubishi Chemical Industries Limited Process for preparing polyolefin
US4243785A (en) * 1978-09-05 1981-01-06 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
US4244838A (en) 1979-06-25 1981-01-13 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
US4246383A (en) 1979-06-25 1981-01-20 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from an organomagnesium component which does not reduce TiCl4
US4250288A (en) 1977-02-03 1981-02-10 The Dow Chemical Company High efficiency, high temperature catalyst for polymerizing olefins
US4263168A (en) 1979-01-10 1981-04-21 Imperial Chemical Industries Limited Olefine polymerization catalyst
EP0032309A2 (en) * 1980-01-10 1981-07-22 Imperial Chemical Industries Plc Production of catalyst component, catalyst and use thereof
EP0032308A2 (en) * 1980-01-10 1981-07-22 Imperial Chemical Industries Plc Ethylene polymerisation process
US4301029A (en) 1979-01-10 1981-11-17 Imperial Chemical Industries Limited Olefin polymerization catalyst and the production and use thereof
US4311816A (en) * 1977-04-27 1982-01-19 E. I. Du Pont De Nemours And Company Process for the preparation of polymers of α-olefins
US4312783A (en) * 1979-07-24 1982-01-26 Asahi Kasei Kogyo Kabushiki Kaisha Catalyst for polymerization of olefins
EP0044665A1 (en) * 1980-07-14 1982-01-27 Imperial Chemical Industries Plc Transition metal composition, production and use
US4314912A (en) 1977-02-03 1982-02-09 The Dow Chemical Company High efficiency, high temperature catalyst for polymerizing olefins
US4319010A (en) 1970-12-02 1982-03-09 Stamicarbon, B.V. Process for the polymerization of alkenes
US4328328A (en) * 1978-12-11 1982-05-04 Mitsui Petrochemical Industries Ltd. Continuous process for production of olefin polymers or copolymers
US4380508A (en) 1981-10-22 1983-04-19 The Dow Chemical Company Ultra high efficiency catalyst for polymerizing olefins
US4381253A (en) 1981-10-22 1983-04-26 The Dow Chemical Company Ultra high efficiency catalyst for polymerizing olefins
US4383938A (en) 1977-02-11 1983-05-17 Exxon Research And Engineering Co. Catalyst system for olefinic polymerization
US4391738A (en) * 1977-04-25 1983-07-05 Exxon Research And Engineering Co. Catalyst for olefinic polymerization
US4426316A (en) 1982-09-10 1984-01-17 The Dow Chemical Company Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4434282A (en) 1982-10-04 1984-02-28 The Dow Chemical Company Process for polymerizing olefins
US4456547A (en) * 1982-10-21 1984-06-26 Fuentes Jr Ricardo Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and complex formed from admixture of a transition metal compound and an organozinc compound
EP0114526A1 (en) * 1982-12-24 1984-08-01 Mitsui Petrochemical Industries, Ltd. Titanium catalyst composition for use in the polymerization of olefins
US4468477A (en) * 1980-01-10 1984-08-28 Imperial Chemical Industries Plc Production of catalyst component, catalyst and use thereof
EP0126515A1 (en) * 1983-05-21 1984-11-28 Dsm N.V. Process for the (co)polymerization of ethylene
US4496661A (en) * 1983-10-24 1985-01-29 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
US4496660A (en) * 1980-10-01 1985-01-29 The Dow Chemical Company Catalyst prepared from organo-magnesium compound; oxygen- or nitrogen-containing compound; halide source; transition metal compound and reducing agent
US4529715A (en) * 1983-10-17 1985-07-16 The Dow Chemical Company Catalyst prepared from organomagnesium compound, carbon dioxide, reducing aluminum source, transition metal compound and zinc compound
US4544647A (en) * 1982-07-29 1985-10-01 The Dow Chemical Company Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4604374A (en) * 1982-09-20 1986-08-05 The Dow Chemical Company Catalyst prepared from organomagnesium compound, epihalohydrin reducing halide source and transition metal compound
US4605715A (en) * 1982-09-20 1986-08-12 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from organomagnesium compound, epihalohydrin reducing halide source and transition metal compound
US4661465A (en) * 1985-10-31 1987-04-28 The Dow Chemical Company Method for preparing transition metal component of Ziegler-Natta catalysts
US4820471A (en) * 1985-08-06 1989-04-11 Stamicarbon B.V. Process for the preparation of blown film
US5045612A (en) * 1990-04-18 1991-09-03 The Dow Chemical Company Catalyst and process for polymerizing olefins
US5114897A (en) * 1990-04-18 1992-05-19 The Dow Chemical Company Catalyst and process for polymerizing olefins
US6218331B1 (en) * 1995-03-29 2001-04-17 Equistar Chemicals, L.P. Polymer-supported catalyst for olefin polymerization
US20150038660A1 (en) * 2012-02-22 2015-02-05 Saudi Basic Industries Corporation Catalyst component for the polymerization of olefins

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3995098A (en) 1971-04-23 1976-11-30 Naphtachimie Method of polymerizing olefins
JPS603324B2 (en) * 1978-12-28 1985-01-28 三井化学株式会社 Method for producing ethylene copolymer
US4252670A (en) * 1979-01-10 1981-02-24 Imperial Chemical Industries Limited Olefine polymerization catalyst
US4235746A (en) * 1979-01-17 1980-11-25 Phillips Petroleum Company Polymerization of olefins
AT397262B (en) * 1992-07-31 1994-03-25 Escher Wyss Gmbh SUCTION ROLLER

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1180135B (en) * 1956-04-18 1964-10-22 Du Pont Process for the catalytic polymerization of alkenes
US2898328A (en) * 1956-07-10 1959-08-04 Ici Ltd Polymerisation of olefins
BE557561A (en) * 1956-08-02
BE559727A (en) * 1956-08-02
FR1299295A (en) * 1960-09-07 1962-07-20 Phillips Petroleum Co Process for the production of olefinic polymers
NL130788C (en) * 1963-12-23
FR1425247A (en) * 1964-02-26 1966-01-14 Hoechst Ag Alpha-olefin polymerization process
US3445443A (en) * 1964-03-24 1969-05-20 Mitsui Petrochemical Ind Process for the preparation of polyolefins with a transition metal halide-organo aluminum compound catalyst

Cited By (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4319010A (en) 1970-12-02 1982-03-09 Stamicarbon, B.V. Process for the polymerization of alkenes
DE2259516A1 (en) * 1971-12-08 1973-06-14 Solvay METHOD OF POLYMERIZATION OF OLEFINS
US4163831A (en) 1974-04-22 1979-08-07 The Dow Chemical Company High efficiency titanate catalyst for polymerizing olefins
US4172050A (en) * 1974-04-22 1979-10-23 The Dow Chemical Company High efficiency titanate catalyst for polymerizing olefins
US4076926A (en) 1975-05-14 1978-02-28 Imperial Chemical Industries Limited Polymerization catalyst comprising aluminum halide and an alcohol or ether
US4069169A (en) 1975-11-24 1978-01-17 Mitsui Petrochemical Industries Ltd. Process for preparation of catalyst component supported on high performance carrier
US4189554A (en) * 1976-05-14 1980-02-19 Phillips Petroleum Company Magnesium reducing agent prepared in absence of complexing diluent milled with organoaluminum
US4194075A (en) * 1976-05-14 1980-03-18 Phillips Petroleum Company Magnesium reducing agent-hydrocarbylaluminum halide cocatalyst for titanium tetrahalide
US4229558A (en) * 1976-12-13 1980-10-21 Mitsubishi Chemical Industries Limited Process for preparing polyolefin
US4199473A (en) * 1976-12-29 1980-04-22 The International Synthetic Rubber Co. Ltd. Olefin polymerization
US4250288A (en) 1977-02-03 1981-02-10 The Dow Chemical Company High efficiency, high temperature catalyst for polymerizing olefins
US4314912A (en) 1977-02-03 1982-02-09 The Dow Chemical Company High efficiency, high temperature catalyst for polymerizing olefins
US4383938A (en) 1977-02-11 1983-05-17 Exxon Research And Engineering Co. Catalyst system for olefinic polymerization
US4391738A (en) * 1977-04-25 1983-07-05 Exxon Research And Engineering Co. Catalyst for olefinic polymerization
US4311816A (en) * 1977-04-27 1982-01-19 E. I. Du Pont De Nemours And Company Process for the preparation of polymers of α-olefins
US4243785A (en) * 1978-09-05 1981-01-06 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
EP0008595A1 (en) * 1978-09-13 1980-03-19 The Dow Chemical Company Organomagnesium catalyst compositions and their use for polymerizing olefins
US4328328A (en) * 1978-12-11 1982-05-04 Mitsui Petrochemical Industries Ltd. Continuous process for production of olefin polymers or copolymers
US4263168A (en) 1979-01-10 1981-04-21 Imperial Chemical Industries Limited Olefine polymerization catalyst
US4329252A (en) 1979-01-10 1982-05-11 Imperial Chemical Industries Limited Olefine polymerization catalyst and the production and use thereof
US4301029A (en) 1979-01-10 1981-11-17 Imperial Chemical Industries Limited Olefin polymerization catalyst and the production and use thereof
US4244838A (en) 1979-06-25 1981-01-13 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
US4246383A (en) 1979-06-25 1981-01-20 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from an organomagnesium component which does not reduce TiCl4
US4312783A (en) * 1979-07-24 1982-01-26 Asahi Kasei Kogyo Kabushiki Kaisha Catalyst for polymerization of olefins
US4468477A (en) * 1980-01-10 1984-08-28 Imperial Chemical Industries Plc Production of catalyst component, catalyst and use thereof
EP0032308A2 (en) * 1980-01-10 1981-07-22 Imperial Chemical Industries Plc Ethylene polymerisation process
EP0032309A2 (en) * 1980-01-10 1981-07-22 Imperial Chemical Industries Plc Production of catalyst component, catalyst and use thereof
EP0032308A3 (en) * 1980-01-10 1981-08-05 Imperial Chemical Industries Plc Ethylene polymerisation process
EP0032309A3 (en) * 1980-01-10 1981-08-05 Imperial Chemical Industries Plc Production of catalyst component, catalyst and use thereof
EP0044665A1 (en) * 1980-07-14 1982-01-27 Imperial Chemical Industries Plc Transition metal composition, production and use
US4388220A (en) 1980-07-14 1983-06-14 Imperial Chemical Industries Limited Transition metal composition, production and use
US4496660A (en) * 1980-10-01 1985-01-29 The Dow Chemical Company Catalyst prepared from organo-magnesium compound; oxygen- or nitrogen-containing compound; halide source; transition metal compound and reducing agent
US4380508A (en) 1981-10-22 1983-04-19 The Dow Chemical Company Ultra high efficiency catalyst for polymerizing olefins
US4381253A (en) 1981-10-22 1983-04-26 The Dow Chemical Company Ultra high efficiency catalyst for polymerizing olefins
US4544647A (en) * 1982-07-29 1985-10-01 The Dow Chemical Company Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4426316A (en) 1982-09-10 1984-01-17 The Dow Chemical Company Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4605715A (en) * 1982-09-20 1986-08-12 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from organomagnesium compound, epihalohydrin reducing halide source and transition metal compound
US4604374A (en) * 1982-09-20 1986-08-05 The Dow Chemical Company Catalyst prepared from organomagnesium compound, epihalohydrin reducing halide source and transition metal compound
US4434282A (en) 1982-10-04 1984-02-28 The Dow Chemical Company Process for polymerizing olefins
US4456547A (en) * 1982-10-21 1984-06-26 Fuentes Jr Ricardo Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and complex formed from admixture of a transition metal compound and an organozinc compound
EP0114526A1 (en) * 1982-12-24 1984-08-01 Mitsui Petrochemical Industries, Ltd. Titanium catalyst composition for use in the polymerization of olefins
EP0126515A1 (en) * 1983-05-21 1984-11-28 Dsm N.V. Process for the (co)polymerization of ethylene
US4529715A (en) * 1983-10-17 1985-07-16 The Dow Chemical Company Catalyst prepared from organomagnesium compound, carbon dioxide, reducing aluminum source, transition metal compound and zinc compound
US4496661A (en) * 1983-10-24 1985-01-29 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
US4820471A (en) * 1985-08-06 1989-04-11 Stamicarbon B.V. Process for the preparation of blown film
US4661465A (en) * 1985-10-31 1987-04-28 The Dow Chemical Company Method for preparing transition metal component of Ziegler-Natta catalysts
US5045612A (en) * 1990-04-18 1991-09-03 The Dow Chemical Company Catalyst and process for polymerizing olefins
US5114897A (en) * 1990-04-18 1992-05-19 The Dow Chemical Company Catalyst and process for polymerizing olefins
US6218331B1 (en) * 1995-03-29 2001-04-17 Equistar Chemicals, L.P. Polymer-supported catalyst for olefin polymerization
US9587049B2 (en) * 2012-02-22 2017-03-07 Saudi Basic Industries Corporation Catalyst component for the polymerization of olefins
US20150038660A1 (en) * 2012-02-22 2015-02-05 Saudi Basic Industries Corporation Catalyst component for the polymerization of olefins

Also Published As

Publication number Publication date
SE381879B (en) 1975-12-22
ES367250A1 (en) 1971-05-16
NL153555B (en) 1977-06-15
CS171205B2 (en) 1976-10-29
NL6806890A (en) 1969-11-18
FR2008619A1 (en) 1970-01-23
BR6908842D0 (en) 1973-01-11
PL79992B1 (en) 1975-08-30
BE733064A (en) 1969-11-14
SU400109A3 (en) 1973-10-03
DE1924709A1 (en) 1970-06-04
AT296598B (en) 1972-02-25
HU164120B (en) 1973-12-28
BG17815A3 (en) 1973-12-25

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