FR3109899B1 - Catalyseur d’hydrogénation comprenant un support et un ratio NiMo spécifique - Google Patents

Catalyseur d’hydrogénation comprenant un support et un ratio NiMo spécifique Download PDF

Info

Publication number
FR3109899B1
FR3109899B1 FR2004517A FR2004517A FR3109899B1 FR 3109899 B1 FR3109899 B1 FR 3109899B1 FR 2004517 A FR2004517 A FR 2004517A FR 2004517 A FR2004517 A FR 2004517A FR 3109899 B1 FR3109899 B1 FR 3109899B1
Authority
FR
France
Prior art keywords
hydrogenation catalyst
nimo
ratio
support
specific
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2004517A
Other languages
English (en)
Other versions
FR3109899A1 (fr
Inventor
Antoine Fecant
Philibert Leflaive
Etienne Girard
Ledezma Juan Jose Sossa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR2004517A priority Critical patent/FR3109899B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to EP21721952.6A priority patent/EP4146383A1/fr
Priority to PCT/EP2021/061555 priority patent/WO2021224172A1/fr
Priority to BR112022020367A priority patent/BR112022020367A2/pt
Priority to US17/922,130 priority patent/US20230173470A1/en
Priority to CN202180033526.8A priority patent/CN115443187A/zh
Priority to JP2022567457A priority patent/JP2023524798A/ja
Publication of FR3109899A1 publication Critical patent/FR3109899A1/fr
Priority to SA522441214A priority patent/SA522441214B1/ar
Application granted granted Critical
Publication of FR3109899B1 publication Critical patent/FR3109899B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/883Molybdenum and nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005Spinels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/755Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/394Metal dispersion value, e.g. percentage or fraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0207Pretreatment of the support
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0209Impregnation involving a reaction between the support and a fluid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0236Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/088Decomposition of a metal salt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12Oxidising
    • B01J37/14Oxidising with gases containing free oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20Sulfiding
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/36Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/38Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum or tungsten metals, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/06Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a selective hydrogenation of the diolefins
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1037Hydrocarbon fractions
    • C10G2300/104Light gasoline having a boiling range of about 20 - 100 °C
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/30Physical properties of feedstocks or products
    • C10G2300/301Boiling range
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Dispersion Chemistry (AREA)

Abstract

Catalyseur d’hydrogénation sélective comprenant une phase active à base de nickel et de molybdène, et un support poreux constitué d’alumine et/ou d’aluminate de nickel, caractérisé en ce que le ratio molaire entre le nickel et le molybdène est supérieur à 2,5 mol/mol et inférieur à 3,0 mol/mol.
FR2004517A 2020-05-07 2020-05-07 Catalyseur d’hydrogénation comprenant un support et un ratio NiMo spécifique Active FR3109899B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR2004517A FR3109899B1 (fr) 2020-05-07 2020-05-07 Catalyseur d’hydrogénation comprenant un support et un ratio NiMo spécifique
PCT/EP2021/061555 WO2021224172A1 (fr) 2020-05-07 2021-05-03 Catalyseur d'hydrogenation comprenant un support et un ratio nimo specifique
BR112022020367A BR112022020367A2 (pt) 2020-05-07 2021-05-03 Catalisador de hidrogenação compreendendo um suporte e uma razão específica de nimo
US17/922,130 US20230173470A1 (en) 2020-05-07 2021-05-03 Hydrogenation catalyst comprising a carrier and a specific nickel molybdenum ratio
EP21721952.6A EP4146383A1 (fr) 2020-05-07 2021-05-03 Catalyseur d'hydrogenation comprenant un support et un ratio nimo specifique
CN202180033526.8A CN115443187A (zh) 2020-05-07 2021-05-03 包含载体和特定镍钼比的加氢催化剂
JP2022567457A JP2023524798A (ja) 2020-05-07 2021-05-03 担体と特定の比率のニッケル・モリブデンとを含む水素化触媒
SA522441214A SA522441214B1 (ar) 2020-05-07 2022-11-07 محفز هدرجة مشتمل على ناقل ونسبة موليبيدنيوم ونيكل محددة

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2004517 2020-05-07
FR2004517A FR3109899B1 (fr) 2020-05-07 2020-05-07 Catalyseur d’hydrogénation comprenant un support et un ratio NiMo spécifique

Publications (2)

Publication Number Publication Date
FR3109899A1 FR3109899A1 (fr) 2021-11-12
FR3109899B1 true FR3109899B1 (fr) 2023-11-24

Family

ID=71894958

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2004517A Active FR3109899B1 (fr) 2020-05-07 2020-05-07 Catalyseur d’hydrogénation comprenant un support et un ratio NiMo spécifique

Country Status (8)

Country Link
US (1) US20230173470A1 (fr)
EP (1) EP4146383A1 (fr)
JP (1) JP2023524798A (fr)
CN (1) CN115443187A (fr)
BR (1) BR112022020367A2 (fr)
FR (1) FR3109899B1 (fr)
SA (1) SA522441214B1 (fr)
WO (1) WO2021224172A1 (fr)

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2118309A5 (fr) 1970-12-16 1972-07-28 Inst Francais Du Petrole
FR2689420B1 (fr) 1992-04-01 1994-06-17 Eurecat Europ Retrait Catalys Procede de presulfuration de catalyseur de traitement d'hydrocarbures.
FR2708597B1 (fr) 1993-07-30 1995-09-29 Inst Francais Du Petrole Procédé d'isomérisation d'oléfines sur des catalyseurs métalliques imprégnés de composés organiques soufrés avant chargement dans le réacteur.
FR2708596B1 (fr) 1993-07-30 1995-09-29 Inst Francais Du Petrole Procédé d'isomérisation d'oléfines externes en oléfines internes conjointement à l'hydrogénation des dioléfines.
US5525211A (en) * 1994-10-06 1996-06-11 Texaco Inc. Selective hydrodesulfurization of naphtha using selectively poisoned hydroprocessing catalyst
FR2725381B1 (fr) 1994-10-07 1996-12-13 Eurecat Europ Retrait Catalys Procede de pretraitement hors site d'un catalyseur de traitement d'hydrocarbures
US5958816A (en) 1997-02-28 1999-09-28 Tricat, Inc. Method of presulfiding and passivating a hydrocarbon conversion catalyst
FR2797639B1 (fr) 1999-08-19 2001-09-21 Inst Francais Du Petrole Procede de production d'essences a faible teneur en soufre
US6759364B2 (en) 2001-12-17 2004-07-06 Shell Oil Company Arsenic removal catalyst and method for making same
FR2895415B1 (fr) * 2005-12-22 2011-07-15 Inst Francais Du Petrole Procede d'hydrogenation selective mettant en oeuvre un catalyseur presentant un support specifique
FR2935389B1 (fr) * 2008-09-04 2012-05-11 Inst Francais Du Petrole Procede d'hydrogenation selective mettant en oeuvre un catalyseur sulfure de composition specifique
CN101869839A (zh) 2009-04-27 2010-10-27 北京海顺德钛催化剂有限公司 一种催化裂化汽油选择性加氢催化剂及其制备方法
CN103145516B (zh) 2011-12-06 2015-01-21 中国石油天然气股份有限公司 一种使不饱和化合物选择加氢的方法
FR2988732B1 (fr) * 2012-03-29 2015-02-06 IFP Energies Nouvelles Procede d'hydrogenation selective d'une essence
FR3007416B1 (fr) * 2013-06-19 2018-03-23 IFP Energies Nouvelles Procede de production d'une essence a basse teneur en soufre et en mercaptans
CN111097438A (zh) * 2018-10-29 2020-05-05 中国石油化工股份有限公司 一种重油加氢处理催化剂及其制备方法和应用

Also Published As

Publication number Publication date
US20230173470A1 (en) 2023-06-08
BR112022020367A2 (pt) 2022-11-29
SA522441214B1 (ar) 2024-06-06
FR3109899A1 (fr) 2021-11-12
EP4146383A1 (fr) 2023-03-15
CN115443187A (zh) 2022-12-06
WO2021224172A1 (fr) 2021-11-11
JP2023524798A (ja) 2023-06-13

Similar Documents

Publication Publication Date Title
AR037013A1 (es) Sintesis de poli-alfa olefinas y uso de las mismas
FR3109899B1 (fr) Catalyseur d’hydrogénation comprenant un support et un ratio NiMo spécifique
EP4231532A3 (fr) Procédé et dispositif de codage et procédé et dispositif de décodage pour code ldpc structuré
US20110149807A1 (en) Techniques to provide physical resource allocation using a tree-based structure and communicate a channel quality indicator
FI972273A0 (fi) Foerfarande foer framstaellning av dieselbraensle med hoeg kvalitet
NO20075133L (no) Bruk av tilleggstildelinger for a redusere ressurser
FR3050659B1 (fr) Catalyseur de cobalt a base d'un support contenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare par l'utilisation d'un compose ester
BR112022017402A2 (pt) Composições para substituição de surfactantes químicos
US9398598B2 (en) Overall MU-MIMO capacity for users with unequal packet lengths in an MU-MIMO frame
Basten Redefining “old age” and “dependency” in East Asia: Is “prospective aging” a more helpful concept?
US20040178317A1 (en) Document holder for computer workstation
DE602004031053D1 (de) Azeotropartige zusammensetzungen, die hexafluorpropylendimer enthalten, und verwendung davon
EA200702472A1 (ru) Катализатор оксихлорирования и способ, использующий такой катализатор
DK4171806T3 (da) Trimetallisk katalysator på basis af nikkel, molybdæn og wolfram og anvendelse heraf i en fremgangsmåde til hydrogenbehandling og/eller hydrokrakning
SA522431911B1 (ar) عملية نزع الهيدروجين حفزية من هيدروكربون
FR3109898B1 (fr) Catalyseur d’hydrogénation sélective comprenant une répartition particulière du nickel et du molybdène
BR112023025739A2 (pt) Política de seleção de rede de acesso com informações de assistência à seleção de fatia de rede
Батыкова et al. GEOGRAPHIC INFORMATION SYSTEMS (GIS)-IN LAND MANAGEMENT
CN219718294U (zh) 一种手机托及平板支架
JP5097580B2 (ja) 無線リソース割当装置、無線リソース割当方法、無線装置及びコンピュータプログラム
CN203847946U (zh) 一种手持设备固定器
Kim If you are interested in writing a review of one of the books listed below, or any relevant medical law title, please contact the Book Reviews Editor Professor Beverley Clough: b. clough@ mmu. ac. uk. Reviews are usually about 2–4000 words long, but shorter reviews will be considered with the agreement of the Reviews Editor.
Carpenter Avoiding the Pitfalls of Web Design.
Thompson et al. Cultural borderlands: Cultural dissonance in the international school Reprinted in memory of Michael Allen................................................ 27 From Ancient Greece to Mayan temples to Arabian souqs; bringing music and mathematics alive through interdisciplinary learning
Hirotsu On an optimal design for an isotonic inference

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Publication of the preliminary search report

Effective date: 20211112

PLFP Fee payment

Year of fee payment: 3

PLFP Fee payment

Year of fee payment: 4

PLFP Fee payment

Year of fee payment: 5