FR3058573B1 - ELECTROCHEMICAL CELL FOR LITHIUM ION BATTERY COMPRISING A SPECIFIC POSITIVE ELECTRODE ON ALUMINUM COLLECTOR AND A SPECIFIC ELECTROLYTE - Google Patents

ELECTROCHEMICAL CELL FOR LITHIUM ION BATTERY COMPRISING A SPECIFIC POSITIVE ELECTRODE ON ALUMINUM COLLECTOR AND A SPECIFIC ELECTROLYTE Download PDF

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Publication number
FR3058573B1
FR3058573B1 FR1660796A FR1660796A FR3058573B1 FR 3058573 B1 FR3058573 B1 FR 3058573B1 FR 1660796 A FR1660796 A FR 1660796A FR 1660796 A FR1660796 A FR 1660796A FR 3058573 B1 FR3058573 B1 FR 3058573B1
Authority
FR
France
Prior art keywords
positive electrode
specific
ion battery
electrochemical cell
electrolyte
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1660796A
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French (fr)
Other versions
FR3058573A1 (en
Inventor
Jean-Frederic Martin
Helene Rouault
Olivier Buisine
Marc-David BRAIDA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Operations SAS
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Rhodia Operations SAS
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Rhodia Operations SAS, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR1660796A priority Critical patent/FR3058573B1/en
Priority to PCT/FR2017/053047 priority patent/WO2018087473A1/en
Publication of FR3058573A1 publication Critical patent/FR3058573A1/en
Application granted granted Critical
Publication of FR3058573B1 publication Critical patent/FR3058573B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0028—Organic electrolyte characterised by the solvent
    • H01M2300/0034—Fluorinated solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

L'invention a trait à une cellule électrochimique pour batterie lithium-ion comprenant : -une électrode négative ; -une électrode positive comprenant, comme matériau actif, un composé oxyde répondant à la formule générale LIMO2, dans laquelle M est un élément choisi parmi Ni, Co, Mn, Al, Mg et les mélanges de ceux-ci, ladite électrode positive étant associée à un collecteur de courant en aluminium; et -un électrolyte disposé entre ladite électrode négative et ladite électrode positive, ledit électrolyte comprenant, comme sel de lithium, du bis(trifluorométhylsulfonyl)imidure de lithium, et comprenant, comme solvant organique, du carbonate de trifluoropropylène.The invention relates to an electrochemical cell for a lithium-ion battery comprising: a negative electrode; a positive electrode comprising, as active material, an oxide compound having the general formula LIMO 2, in which M is a member selected from Ni, Co, Mn, Al, Mg and mixtures thereof, said positive electrode being associated an aluminum current collector; and an electrolyte disposed between said negative electrode and said positive electrode, said electrolyte comprising, as lithium salt, lithium bis (trifluoromethylsulfonyl) imide, and comprising, as organic solvent, trifluoropropylene carbonate.

FR1660796A 2016-11-08 2016-11-08 ELECTROCHEMICAL CELL FOR LITHIUM ION BATTERY COMPRISING A SPECIFIC POSITIVE ELECTRODE ON ALUMINUM COLLECTOR AND A SPECIFIC ELECTROLYTE Expired - Fee Related FR3058573B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR1660796A FR3058573B1 (en) 2016-11-08 2016-11-08 ELECTROCHEMICAL CELL FOR LITHIUM ION BATTERY COMPRISING A SPECIFIC POSITIVE ELECTRODE ON ALUMINUM COLLECTOR AND A SPECIFIC ELECTROLYTE
PCT/FR2017/053047 WO2018087473A1 (en) 2016-11-08 2017-11-08 Electrochemical cell for lithium-ion battery comprising a specific positive electrode on aluminium collector and a specific electrolyte

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1660796A FR3058573B1 (en) 2016-11-08 2016-11-08 ELECTROCHEMICAL CELL FOR LITHIUM ION BATTERY COMPRISING A SPECIFIC POSITIVE ELECTRODE ON ALUMINUM COLLECTOR AND A SPECIFIC ELECTROLYTE
FR1660796 2016-11-08

Publications (2)

Publication Number Publication Date
FR3058573A1 FR3058573A1 (en) 2018-05-11
FR3058573B1 true FR3058573B1 (en) 2019-05-10

Family

ID=57590687

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1660796A Expired - Fee Related FR3058573B1 (en) 2016-11-08 2016-11-08 ELECTROCHEMICAL CELL FOR LITHIUM ION BATTERY COMPRISING A SPECIFIC POSITIVE ELECTRODE ON ALUMINUM COLLECTOR AND A SPECIFIC ELECTROLYTE

Country Status (2)

Country Link
FR (1) FR3058573B1 (en)
WO (1) WO2018087473A1 (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005340223A (en) * 1998-02-20 2005-12-08 Hitachi Ltd Lithium secondary battery, its electrolytic liquid, and electric equipment
WO2012056765A1 (en) * 2010-10-29 2012-05-03 日本電気株式会社 Secondary battery and method for manufacturing same
EP2800197B1 (en) * 2013-05-02 2017-03-22 Westfälische Wilhelms-Universität Münster Fluorinated carbonates as solvent for lithium sulfonimide-based electrolytes

Also Published As

Publication number Publication date
FR3058573A1 (en) 2018-05-11
WO2018087473A1 (en) 2018-05-17

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