EP2073975B1 - System for forming reinforcement layers having cross-directionally oriented fibers - Google Patents

System for forming reinforcement layers having cross-directionally oriented fibers Download PDF

Info

Publication number
EP2073975B1
EP2073975B1 EP07836959A EP07836959A EP2073975B1 EP 2073975 B1 EP2073975 B1 EP 2073975B1 EP 07836959 A EP07836959 A EP 07836959A EP 07836959 A EP07836959 A EP 07836959A EP 2073975 B1 EP2073975 B1 EP 2073975B1
Authority
EP
European Patent Office
Prior art keywords
fibers
chopped
array
continuous fibers
nozzle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP07836959A
Other languages
German (de)
French (fr)
Other versions
EP2073975A2 (en
Inventor
Michael Jander
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Owens Corning Intellectual Capital LLC
Original Assignee
OCV Intellectual Capital LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by OCV Intellectual Capital LLC filed Critical OCV Intellectual Capital LLC
Priority to PL07836959T priority Critical patent/PL2073975T3/en
Publication of EP2073975A2 publication Critical patent/EP2073975A2/en
Application granted granted Critical
Publication of EP2073975B1 publication Critical patent/EP2073975B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/12Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of short length, e.g. in the form of a mat
    • B29C70/14Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of short length, e.g. in the form of a mat oriented
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/20Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in a single direction, e.g. roofing or other parallel fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/20Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in a single direction, e.g. roofing or other parallel fibres
    • B29C70/202Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in a single direction, e.g. roofing or other parallel fibres arranged in parallel planes or structures of fibres crossing at substantial angles, e.g. cross-moulding compound [XMC]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/06Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/18Handling of layers or the laminate
    • B32B2038/1891Using a robot for handling the layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24058Structurally defined web or sheet [e.g., overall dimension, etc.] including grain, strips, or filamentary elements in respective layers or components in angular relation
    • Y10T428/24124Fibers

Definitions

  • the present invention relates generally to a system for forming reinforcement layers having cross-directionally oriented fibers, and, particularly, to a system for the dispensing of both continuous fibers and chopped reinforcement fibers to form the reinforcement layers.
  • the present invention has industrial applicability for making fiber reinforced articles, mats or preforms that are suitable for reinforcing molded articles, such as structural composites, pipes and the like.
  • Structural composites and other reinforced molded articles are commonly made using manufacturing processes such as resin transfer molding and structural resin injection molding. These molding processes have been made more efficient by using reinforcement fibers that arc used to make a reinforcement layer or mat.
  • the preformed fiber reinforced layers or mat "preforms" or filament winding prepregs have the approximate shape and size of the molded article.
  • US 2005/008804 describes a method of making a fibrous material bv providing a first longitudinal layer of glass fibers, applying an intermediate layer of reinforcing fibers onto the first layer (at least same of which include at least portions thereof which extend in the transverse direction), and covering the intermediate layer with a second longitudinal layer of glass fibers.
  • US 2002/124936 describes a method of making composite sheets using two bundles of composite parallel threads and a lap of composite threads deposited transversely in the form of a mat having continuous threads.
  • WO 03/038331 describes a reinforcement liner made of a fabric material and methods of making the liner and fabric material. The fabric material is formed as a continuous strip of materials by providing at first longitudinal layer of glass fibers and applying a second layer comprising chopped fibers extending in a direction substantially perpendicular to the fibers in the first layer.
  • reinforcement fibers As the technical requirements for reinforcement products increases, new methods for dispensing and laying down reinforcement fibers are required. One requirement is that the reinforcement fibers be delivered at faster speeds than used previously. Another requirement is that the reinforcement fibers be laid down in varying degrees of thickness or density to achieve the desired reinforcement result. Another requirement is that the reinforcement fibers be laid down in a predetermined orientation.
  • the preforms When preforms are made with specific amounts and specific orientations of the reinforcement fibers, the preforms provide improved strength to the molded product precisely at the weakest or most stressed locations. Because of this new design requirement, there often is a requirement that the fibers be dispensed in a very controlled manner.
  • the appartus includes a feeder that supplies an array of continuous fibers in a first orientation.
  • a chopped fiber dispenser distributes the chopped fibers onto the array of continuous fibers in a second, and cross-directional, orientation with respect to the first orientation of the array of continuous fibers.
  • the second orientation is defined as an angle ⁇ between about 0° to about 90° with respect to the first orientation of the array of continuous fibers; where the angle ⁇ is defined as an angle between x and z axes, where the x axis is defined by a top surface of the array of continuous fibers and the z axis is defined by a width of the array of continuous fibers.
  • a process for making a fibrous reinforcement layer which includes directing a supply of continuous fibers, and dispensing a supply of chopped fibrous material onto the continuous fibers.
  • the continuous fibers are directed in a first orientation and the chopped fibrous materials are dispensed in a second, and cross-directional orientation, with respect to the first orientation of the continuous fibers.
  • FIG. 1 shows a system 10 having a chopped fiber dispenser 12 for dispensing chopped fibers 14 onto an array of continuous fibers 16 in order to form a fibrous reinforcement layer 17.
  • the chopped fiber dispenser 12 is positioned adjacent to the array of the continuous fibers 16.
  • the chopped fiber dispenser 12 distributes the chopped fibers 14 onto the continuous fibers 16 in one or more desired cross-directional orientations with respect to the orientation of the continuous fibers 16.
  • the array of continuous fibers 16 is oriented in a longitudinal direction and the chopped fibers 14 are dispensed in a cross-direction orientation with respect to the longitudinal direction of the array of continuous fibers 16.
  • the chopped fibers 14 are dispensed from the fiber dispenser 12 in a generally aligned, closely spaced fashion such that the dispensed chopped fibers 14 are in substantially the same orientation.
  • the chopped fibers 14 can be aligned in a substantially parallel fashion.
  • the chopped fibers 14 can have substantially the same lengths.
  • the chopped fiber dispenser 12 can be substantially as shown in U.S. Pat No. 5,806,387 , U.S. Pat No. 5,819,614 , U.S. Pat No. 6,029,897 , U.S. Pat No. 6,038,949 , and/or U.S. Pat No. 6,182,332 issued to the inventor herein, Jander.
  • the chopped fibers 14 can be glass fibers having a weight within the range of from about 300 to about 4800 g/km, and a diameter within the range of from about 8 to about 30 microns, although other weights and diameters can be used.
  • the chopped fiber output would range from about 0.1 to about 5 kg glass fibers per minute, with a total output (resin and glass) within the range of from about 0.2 to about 15 kg per minute.
  • the chopped reinforcement fibers 14 can be any material suitable for reinforcement purposes.
  • One preferred material is Type 30 ® glass fibers, available from Owens Coming, Toledo, Ohio, although other mineral fibers and organic fibers, such as polyester, Kevlar® and carbon fibers, can be used with the invention. It is to be understood that the chopped reinforcement fibers can be a single filament (monofilament) or a strand comprised of numerous filaments.
  • the continuous fibers 16 can be any material suitable for reinforcement purposes.
  • One suitable material is Type 30 ® glass fibers, available from Owens Coming, Toledo, Ohio, although other mineral fibers and organic fibers, such as polyester, aramid fibers such as Kevlar ® type fibers, and carbon fibers, can be used.
  • the continuous fiber can be a single filament (monofilament) or a strand comprised of numerous filaments.
  • the continuous fibers 16 comprise a glass fiber roving having from about 2200 to about 4800 tex, where a tex is defined as one gram per 1000 meters of filament. Usually the roving is formed by combining a plurality of strands, with each strand being about 25 to about 100 tex.
  • a supply of reinforcement fibers (not shown) is transported to the fiber dispenser 12 where the reinforcement fibers are chopped or cut to produce the chopped fibers 14.
  • the chopped fiber dispenser 12 has a nozzle 30 mounted at the end of an articulation arm 32. As shown in FIGS. 1 and 1A , the nozzle 30 has a nozzle chamber 34 with an outlet 36 for dispensing the chopped fibers 14. In certain embodiments, the nozzle chamber 34 has a tapered shape which helps to disperse the chopped fibers 14 exiting the nozzle 30 in a wider flow of chopped fibers 14 onto the continuous fibers 16.
  • the nozzle 30 contains a fluid directing device 38 (schematically shown in phantom in FIG. 1 ) that directs a fluid into the nozzle 30 to aid in spreading out, or flaring, a dispersed stream of the chopped fibers 14 in the nozzle 30.
  • the dispersed stream of chopped fibers 14 can thus have any desired width.
  • the fluid can be delivered to the nozzle 30 by any suitable means such as a conduit 39.
  • the fluid can be any material suitable for affecting the path of travel of the chopped fibers 14 in the nozzle 30.
  • One suitable fluid is air, but other gases or even liquids can also be used.
  • Some of the alternate fluids can be adapted to provide surface treatments or other fiber quality-affecting enhancements or bonding capability of the fibers to the resin material to be reinforced. In such embodiments, the temperature and moisture content of the fluid can be set to positively affect the fiber quality and properties.
  • the flow rate, the amount and/or the width of the dispersed stream of the chopped fibers 14 being dispensed from the nozzle 30 is controlled by controlling the fluid entering the nozzle 30.
  • the deposition of chopped fibers 14 on the continuous fibers 16 is precisely controlled, even while being deposited at a rapid rate.
  • FIG. 1A shows the chopped fiber dispenser 12 positioned at an angle ⁇ with respect to a top, or planar, surface 16t of the array of continuous fibers 16.
  • the top surface 16t is oriented along the x-axis and z-axis, where the x axis is defined by a longitudinally extending length of the continuous fibers 16.
  • the chopped fibers 14 are dispersed at an angle ⁇ , where the angle ⁇ is defined as the angle between the x and y axes, where the y axis is defined as being in a vertical perpendicular relationship to the x axis.
  • the angle ⁇ at which the chopped fiber dispenser 12 is oriented can be varied between about 0° to about 90° to control the amount and the pattern of the chopped fibers 14 being dispensed onto the continuous fibers 16.
  • the chopped fiber dispenser 12 is also movable with respect to the continuous fibers 16.
  • the chopped fiber dispenser 12 can include, for example, a hydraulic system (not shown) or other suitable system can be used to enable the chopped fiber dispenser 12 to be moved to a position adjacent or above any portion of the continuous fibers 16.
  • the chopped fiber dispenser 12 can be moved to different positions so that the angle of the chopped fibers 14 being deposited on the continuous fibers 16 can be varied.
  • the angle ⁇ is varied by moving the chopped fiber dispenser 12 itself with respect to the top surface 16t of the continuous fibers 16 and/or by adjusting the rate of flow of chopped fibers 14 from the chopped fiber dispenser 12.
  • the movement of the chopped fiber dispenser 12 with respect to the continuous fibers 16 can be controlled in any suitable manner.
  • the chopped fiber dispenser 12 can be controlled by a computer (not shown) according to predetermined desired parameters so that one or more desired orientations of chopped fibers 14 are laid down on the continuous fibers 16.
  • the nozzle outlet 36 of the chopped fiber dispenser 12 can be oriented along the z-axis by moving a first end 36a of the nozzle outlet 36 at an angle ⁇ with respect to a second end 36b of the nozzle outlet 36, where angle ⁇ is defined as the angle between the x and z axes.
  • the angle ⁇ can be varied between about 0° to about ⁇ 90°.
  • the nozzle outlet 36 can be also oriented along the z-axis by moving the nozzle outlet 36 at an angle ⁇ , where angle ⁇ is defined as the angle between the y and z axes, where the z axis is defined as a width of the array of continuous fibers 16. In this manner, the nozzle outlet 36 sweeps across the width of the array of continuous fibers 16.
  • the rate of fiber deposition can be changed by adjusting (reducing/increasing) the fluid flow into the nozzle 30 during the time the nozzle 30 is directing the chopped fibers 14 to that particular area, thereby reducing/increasing the.angle of flow ( ⁇ ) and increasing/decreasing the concentration of the chopped fibers 14 on the specific area of the continuous fibers 16.
  • a further level of control can be achieved by coordinating the flow of fluid into the nozzle 30 with the movement of the chopped fiber dispenser 12.
  • the rate, amount and/or orientation of the chopped fiber deposition can be changed by adjusting (reducing/increasing) one or more of: 1) the rate of fluid flow into the nozzle 30; 2) the amount of fluid flow into the nozzle 30; and/or, 3) the angles of ⁇ , ⁇ , and/or ⁇ of the chopped fibers 14 being dispersed.
  • This adjustment can be made during the time when the nozzle 30 is directing the chopped fibers 14 to that particular area, thereby reducing/increasing the angle of flow ( ⁇ ) and increasing/decreasing the concentration of the chopped fibers 14 on the specific area of the continuous fibers 16.
  • FIG. 1B is a top plan schematic view of the top surface 16t of the continuous fibers 16 showing different orientations of chopped fibers 14.
  • the chopped fibers 14 are oriented at an angle ⁇ (as shown in FIG. 1 A) , where ⁇ is defined as an angle between the x and z axes.
  • the angle ⁇ can range anywhere from 0° to ⁇ 90°. For example, in FIG.
  • the chopped fibers 14a are oriented at a 90° angle ⁇ ; the chopped fibers 14b are oriented at a +45° angle ⁇ ; the chopped fibers 14c are oriented at a -45° angle ⁇ ; the chopped fibers 14d are oriented at a +60° ⁇ ; and, the chopped fibers 14e are oriented at a -60° angle ⁇ .
  • the deposition angle ⁇ of the chopped fibers 14 can be varied, depending on the desired parameters for the fiber reinforcement layer 17.
  • the nozzle 30 need not have any particular dimensions, but in certain embodiments, the width from the first end 36a to the second end 36b of the nozzle 30 can be within the range of from about 15 to about 90 mm, and sometimes within the range of from about 25 to about 50 mm.
  • the length of the nozzle 30 can be within the range of from about 40 to about 200 mm, and sometimes, within the range of from about 50 to about 90 mm.
  • the flow angle ⁇ i.e., width of the dispensed chopped fibers
  • a typical ratio of distance-to-width is within the range of from about 5:1 to about 1:1, and preferably within the range of from about 5:1 to about 2:1.
  • the continuous fibers 16 are supplied from a suitable feeder 18.
  • the feeder 18 can be any suitable device for supplying continuous fibers 16.
  • the feeder 18 can comprise one or more packages of rovings.
  • the feeder 18 can be a fiber forming operation where the continuous fibers 16 are supplied from bushings and are directed into the system 10.
  • the continuous fibers 16 can be coated with a binder type material supplied by a suitable dispenser 24.
  • the continuous fibers 16 are fed onto a collection surface 20 in a suitable manner.
  • the collection surface 20 is shown as a rotating drum, but it should be understood that other collection surfaces can also be used with the system described herein.
  • the collection surface can be, for example, a rotating drum, a mandrel for forming pipe, a conveyor, or a spool for a fabric material.
  • the continuous fibers 16 are longitudinally supplied along an outer surface of the drum 20.
  • the rotating drum 20 can be mounted along an axis A-A for rotation by any suitable means, such as by motor (not shown).
  • the feeder 18 can be configured to move along the axis A-A of the collection surface 20 and to supply the continuous fibers 16 in a desired pattern on the collection surface 20.
  • both the feeder 18 and the chopped fiber dispenser 12 can be configured to move axially along the axis A-A with respect to the collection surface 20.
  • the chopped fibers 14 can be dispensed onto a first supply 16a of continuous fibers.
  • a second supply 16b of continuous fibers is then supplied on top of the chopped fibers 14.
  • the second supply 16b can be supplied at the same or a different orientation with respect to the orientation of the first supply 16a.
  • FIG. 3 shows a system (not according to the present invention) for making a preform 40.
  • the chopped fibers 14 are dispensed onto a mat 42.
  • the mat 42 can be comprised of any suitable combination, such as randomly dispersed materials, woven materials, and/or nonwoven materials.
  • the continuous fibers 16 are deposited onto the chopped fibers 14 that are covering the mat 42 so that the perform 40 is formed.
  • the preform 40 can be impregnated with a suitable impregnation material from any suitable dispenser 46.
  • the chopped fibers 14 can be impregnated with a suitable material such as a binder or resin material before the chopped fibers 14 are dispensed onto the continuous fibers 16.
  • the continuous fibers 16 can be impregnated with a suitable material such as a binder or resin material before the continuous fibers 16 are dispensed onto the collection surface 20.
  • both the chopped fibers 14 and the continuous fibers 16 can be impregnated with a suitable material.
  • the impregnating material can be supplied in any suitable manner so that the fibers are substantially coated with the material.
  • the material can be a thermoset resin, such as a polyester, epoxy, phenolic or polyurethane resin.
  • the material can be a thermoplastic such as block copolymer of caprolactam polymer and elastomer Nyrim® resin or other suitable materials.
  • FIG. 4 shows a system where a first supply of continuous fibers 16a receives a supply of chopped fibers 14. A second supply of continuous fibers 16b is deposited on the chopped fibers 14 to form a multilayer reinforcement layer 50. Thereafter, the multi-layer reinforcement layer 50 can be formed into a fabric 52 by being subjected to a needling or stitching process, generally shown by the needling apparatus 60.
  • FIG. 5 shows another system having a reinforcement dispenser 112 which is positioned to deposit chopped reinforcement fibers 14 onto an array of continuous fibers 16.
  • the reinforcement dispenser 112 need not be robotized or automated, and could even be stationary with the array of continuous fibers 16 being moveable.
  • a source 118 of vacuum can be positioned beneath the array of continuous fibers 16 to facilitate the deposition process.
  • a compaction device 122 can be used to debulk the chopped reinforcement fibers 14.
  • Reinforcement fibers 14s supplied from a source not shown, are transported to a nozzle 130 in the fiber dispenser 112 where the reinforcement fibers 14s are chopped or cut to produce the discrete length reinforcement fibers 14.
  • the chopped fiber dispenser 112 has a nozzle 130 that has a nozzle chamber 134 with an outlet 136 for dispensing the chopped fibers 14.
  • the nozzle chamber 134 has a tapered shape which helps to disperse the chopped fibers 14 exiting the nozzle 130 in a wider flow of chopped fibers 14 onto the continuous fibers 16. It is to be understood that, in certain embodiments, the dispersed stream of chopped fibers 14 can thus have any desired width.
  • the nozzle 130 need not have any particular dimensions, but in certain embodiments, the width of the nozzle 130 can be within the range of from about 15 to about 90 mm, and sometimes within the range of from about 25 to about 50 mm.
  • the length of the nozzle 130 can be within the range of from about 40 to about 200 mm, and sometimes, within the range of from about 50 to about 90 mm.
  • the flow angle ⁇ i.e., width of the dispensed chopped fibers
  • a typical ratio of distance-to-width is within the range of from about 5:1 to about 1:1, and preferably within the range of from about 5:1 to about 2:1.
  • the reinforcement fibers 14s are wound in the nozzle 130 into a series of generally parallel loops or coils 14c.
  • the coils 14c are moved down stream axially of the nozzle 130.
  • the cutter 140 can be of any type capable of severing the coil 14c into discrete lengths of chopped fibers 14. Examples of cutters include heating devices and lasers.
  • FIG. 5 after the coils 14c are cut by the cutter 140, they travel downwardly as discrete lengths of chopped fibers 14. The discrete lengths of fibers are laid down in a generally parallel, closely spaced fashion on the array of continuous fibers 16.
  • the flow rate, the amount and/or the width of the dispersed stream of the chopped fibers 14 being dispensed from the nozzle 130 can be controlled so that the deposition of chopped fibers 14 on the continuous fibers 16 is precisely controlled, even while being deposited at a rapid rate.
  • FIG. 5 shows the chopped fiber dispenser 112 positioned at an angle ⁇ with respect to the top, or planar, surface 16t of the array of continuous fibers 16.
  • the top surface 16t is oriented along the x-axis and z-axis, where the x axis is defined by a longitudinally extending length of the continuous fibers 16.
  • the chopped fibers 14 are dispersed at an angle ⁇ , where the angle ⁇ is defined as the angle between the x and y axes, where the y axis is defined as being in a vertical perpendicular relationship to the x axis.
  • the angle ⁇ at which the chopped fiber dispenser 112 is oriented can be varied between about 0° to about 90° to control the amount and the pattern of the chopped fibers 14 being dispensed onto the continuous fibers 16.
  • the chopped fiber dispenser 112 is also movable with respect to the continuous fibers 16.
  • the chopped fiber dispenser 112 can be, for example, a hydraulic system (not shown) or other suitable systems can be used to enable the chopped fiber dispenser 112 to be moved to a position adjacent or above any portion of the continuous fibers 16.
  • the chopped fiber dispenser 112 can be moved to different positions so that the angle of the chopped fibers 14 being deposited on the continuous fibers 16 can be varied.
  • the angle ⁇ is varied by moving the chopped fiber dispenser 112 itself with respect to the top surface 16t of the continuous fibers 16 and/or by adjusting the rate of flow of chopped fibers 14 from the chopped fiber dispenser 112.
  • the nozzle outlet 136 of the chopped fiber dispenser 112 can be oriented along the z-axis by adjusting a first end of the nozzle outlet 136 at an angle ⁇ with respect to a second end of the nozzle outlet 136, where angle ⁇ is defined as the angle between the x and z axes.
  • the angle ⁇ can be varied between about 0° to about ⁇ 90°.
  • the nozzle outlet 136 can be also oriented along the z-axis by moving the nozzle outlet 136 at an angle ⁇ , where angle ⁇ is defined as the angle between the y and z axes, where the z axis is defined as a width of the array of continuous fibers 16. In this manner, the nozzle outlet 136 sweeps across the width of the array of continuous fibers 16.
  • the rate of fiber deposition can be changed by adjusting (reducing/increasing) the flow of chopped fibers 14 from the nozzle 130 during the time the nozzle 130 is directing the chopped fibers 14 to that particular area, thereby reducing/increasing the angle of flow ( ⁇ ) and increasing/decreasing the concentration of the chopped fibers 14 on the specific area of the array of continuous fibers 16.
  • a further level of control can be achieved by coordinating the flow of chopped fibers 14 from the chopped fiber dispenser 112.
  • the rate, amount and/or orientation of the chopped fiber deposition can be changed by adjusting (reducing/increasing) one or more of: 1) the rate of chopped fiber flow from the nozzle 130; and/or 2) the angles of ⁇ , ⁇ , and/or ⁇ of the chopped fibers 14 being dispersed.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Reinforced Plastic Materials (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Moulding By Coating Moulds (AREA)
  • Preliminary Treatment Of Fibers (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Description

    TECHNICAL FIELD AND INDUSTRIAL APPLICABILITY
  • The present invention relates generally to a system for forming reinforcement layers having cross-directionally oriented fibers, and, particularly, to a system for the dispensing of both continuous fibers and chopped reinforcement fibers to form the reinforcement layers.
  • The present invention has industrial applicability for making fiber reinforced articles, mats or preforms that are suitable for reinforcing molded articles, such as structural composites, pipes and the like.
  • BACKGROUND OF THE INVENTION
  • Structural composites and other reinforced molded articles are commonly made using manufacturing processes such as resin transfer molding and structural resin injection molding. These molding processes have been made more efficient by using reinforcement fibers that arc used to make a reinforcement layer or mat. The preformed fiber reinforced layers or mat "preforms" or filament winding prepregs have the approximate shape and size of the molded article.
  • US 2005/008804 describes a method of making a fibrous material bv providing a first longitudinal layer of glass fibers, applying an intermediate layer of reinforcing fibers onto the first layer (at least same of which include at least portions thereof which extend in the transverse direction), and covering the intermediate layer with a second longitudinal layer of glass fibers. US 2002/124936 describes a method of making composite sheets using two bundles of composite parallel threads and a lap of composite threads deposited transversely in the form of a mat having continuous threads. WO 03/038331 describes a reinforcement liner made of a fabric material and methods of making the liner and fabric material. The fabric material is formed as a continuous strip of materials by providing at first longitudinal layer of glass fibers and applying a second layer comprising chopped fibers extending in a direction substantially perpendicular to the fibers in the first layer.
  • As the technical requirements for reinforcement products increases, new methods for dispensing and laying down reinforcement fibers are required. One requirement is that the reinforcement fibers be delivered at faster speeds than used previously. Another requirement is that the reinforcement fibers be laid down in varying degrees of thickness or density to achieve the desired reinforcement result. Another requirement is that the reinforcement fibers be laid down in a predetermined orientation.
  • When preforms are made with specific amounts and specific orientations of the reinforcement fibers, the preforms provide improved strength to the molded product precisely at the weakest or most stressed locations. Because of this new design requirement, there often is a requirement that the fibers be dispensed in a very controlled manner.
  • Efforts to control the orientation of the fibers have not been entirely successful, especially at the high speeds necessary for commercially successful operations. When typical fiber dispensers are operated at a faster speed, the fibers cannot be successfully laid down in a pattern that is as controlled as is desired.
  • It is clear that improvements in dispensing precisely oriented fibers in a controlled manner, enabling a more precise distribution of fibers, would be desirable.
  • SUMMARY OF THE INVENTION
  • There has now been developed a system for rapidly and precisely dispensing chopped fibers in a cross-directional orientation onto an array of continuous fibers.
  • The appartus includes a feeder that supplies an array of continuous fibers in a first orientation. A chopped fiber dispenser distributes the chopped fibers onto the array of continuous fibers in a second, and cross-directional, orientation with respect to the first orientation of the array of continuous fibers.
  • In one aspect, the second orientation is defined as an angle θ between about 0° to about 90° with respect to the first orientation of the array of continuous fibers; where the angle θ is defined as an angle between x and z axes, where the x axis is defined by a top surface of the array of continuous fibers and the z axis is defined by a width of the array of continuous fibers.
  • There has also been developed a process for making a fibrous reinforcement layer which includes directing a supply of continuous fibers, and dispensing a supply of chopped fibrous material onto the continuous fibers. The continuous fibers are directed in a first orientation and the chopped fibrous materials are dispensed in a second, and cross-directional orientation, with respect to the first orientation of the continuous fibers.
  • Various objects and advantages of this invention will become apparent to those skilled in the art from the following detailed description of the preferred embodiment, when read in light of the accompanying drawings.
  • BRIEF DESCRIPTION OF THE DRAWINGS
    • FIG. 1 is a schematic perspective illustration of one system for dispensing chopped fibers onto an array of continuous fibers so that the chopped fibers and continuous fibers are oriented in a cross-directional manner with respect to each other.
    • FIG. 1A is a schematic perspective illustration of one part of a system for dispensing chopped fibers onto an array of continuous fibers so that the chopped fibers and the array of continuous fibers are oriented in a cross-directional manner with respect to each other.
    • FIG. 1 B is a top, or plan, view showing different cross-directional orientations of chopped fibers on the array of continuous fibers.
    • FIG. 2 is a schematic perspective illustration of another system for dispensing chopped fibers onto an array of continuous fibers so that the chopped fibers and the array of continuous fibers arc oriented in a cross-directional manner with respect to each other, showing two layers of arrays of continuous fibers.
    • FIG. 3 is a schematic perspective illustration of a system (not according to the present invention) for dispensing chopped fibers onto an array of continuous fibers so that the chopped fibers and the array of continuous fibers are oriented in a cross-directional manner with respect to each other, where a binder material is applied to the fibers.
    • FIG. 4 is a schematic perspective illustration of one system for dispensing chopped fibers onto an array of continuous fibers so that the chopped fibers and the array of continuous fibers are oriented in a cross-directional manner with respect to each other, where the fibrous reinforcement layer is subjected to a needling process.
    • FIG. 5 is a schematic perspective illustration of another system for dispensing chopped fibers onto an array of continuous fibers so that the chopped fibers and the array of continuous fibers are oriented in a cross-directional manner with respect to each other.
    DETAILED DESCRIPTION AND PREFERRED EMBODIMENTS
  • Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the invention belongs. Although any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present invention, the preferred methods and materials are described herein. It is to be noted that like numbers found throughout the figures refer to like elements.
  • FIG. 1 shows a system 10 having a chopped fiber dispenser 12 for dispensing chopped fibers 14 onto an array of continuous fibers 16 in order to form a fibrous reinforcement layer 17. The chopped fiber dispenser 12 is positioned adjacent to the array of the continuous fibers 16. The chopped fiber dispenser 12 distributes the chopped fibers 14 onto the continuous fibers 16 in one or more desired cross-directional orientations with respect to the orientation of the continuous fibers 16.
  • In the embodiments shown in the FIGURES, the array of continuous fibers 16 is oriented in a longitudinal direction and the chopped fibers 14 are dispensed in a cross-direction orientation with respect to the longitudinal direction of the array of continuous fibers 16.
  • In the embodiments, the chopped fibers 14 are dispensed from the fiber dispenser 12 in a generally aligned, closely spaced fashion such that the dispensed chopped fibers 14 are in substantially the same orientation. In certain embodiments, the chopped fibers 14 can be aligned in a substantially parallel fashion. Also, in certain embodiments, the chopped fibers 14 can have substantially the same lengths.
  • The system 10, in certain embodiments, as shown in FIG. 1, can include one or more additional dispensers 12' and 12" to provide a desired higher output and/or to achieve other orientations of chopped fibers, as schematically shown in FIG. 1B and further discussed below.
  • In certain embodiments, the chopped fiber dispenser 12 can be substantially as shown in U.S. Pat No. 5,806,387 , U.S. Pat No. 5,819,614 , U.S. Pat No. 6,029,897 , U.S. Pat No. 6,038,949 , and/or U.S. Pat No. 6,182,332 issued to the inventor herein, Jander.
  • The chopped fibers 14 can be glass fibers having a weight within the range of from about 300 to about 4800 g/km, and a diameter within the range of from about 8 to about 30 microns, although other weights and diameters can be used. For example, in a roving of 2400 g/km having fibers with a diameter of 17 microns, the chopped fiber output would range from about 0.1 to about 5 kg glass fibers per minute, with a total output (resin and glass) within the range of from about 0.2 to about 15 kg per minute.
  • The chopped reinforcement fibers 14 can be any material suitable for reinforcement purposes. One preferred material is Type 30 ® glass fibers, available from Owens Coming, Toledo, Ohio, although other mineral fibers and organic fibers, such as polyester, Kevlar® and carbon fibers, can be used with the invention. It is to be understood that the chopped reinforcement fibers can be a single filament (monofilament) or a strand comprised of numerous filaments.
  • The continuous fibers 16 can be any material suitable for reinforcement purposes. One suitable material is Type 30 ® glass fibers, available from Owens Coming, Toledo, Ohio, although other mineral fibers and organic fibers, such as polyester, aramid fibers such as Kevlar ® type fibers, and carbon fibers, can be used. It is to be understood that the continuous fiber can be a single filament (monofilament) or a strand comprised of numerous filaments. In certain embodiments, the continuous fibers 16 comprise a glass fiber roving having from about 2200 to about 4800 tex, where a tex is defined as one gram per 1000 meters of filament. Usually the roving is formed by combining a plurality of strands, with each strand being about 25 to about 100 tex.
  • In operation, a supply of reinforcement fibers (not shown) is transported to the fiber dispenser 12 where the reinforcement fibers are chopped or cut to produce the chopped fibers 14.
  • In the embodiments, the chopped fiber dispenser 12 has a nozzle 30 mounted at the end of an articulation arm 32. As shown in FIGS. 1 and 1A, the nozzle 30 has a nozzle chamber 34 with an outlet 36 for dispensing the chopped fibers 14. In certain embodiments, the nozzle chamber 34 has a tapered shape which helps to disperse the chopped fibers 14 exiting the nozzle 30 in a wider flow of chopped fibers 14 onto the continuous fibers 16.
  • It is to be understood that the nozzle 30 contains a fluid directing device 38 (schematically shown in phantom in FIG. 1) that directs a fluid into the nozzle 30 to aid in spreading out, or flaring, a dispersed stream of the chopped fibers 14 in the nozzle 30. The dispersed stream of chopped fibers 14 can thus have any desired width.
  • The fluid can be delivered to the nozzle 30 by any suitable means such as a conduit 39. The fluid can be any material suitable for affecting the path of travel of the chopped fibers 14 in the nozzle 30. One suitable fluid is air, but other gases or even liquids can also be used. Some of the alternate fluids can be adapted to provide surface treatments or other fiber quality-affecting enhancements or bonding capability of the fibers to the resin material to be reinforced. In such embodiments, the temperature and moisture content of the fluid can be set to positively affect the fiber quality and properties.
  • The flow rate, the amount and/or the width of the dispersed stream of the chopped fibers 14 being dispensed from the nozzle 30 is controlled by controlling the fluid entering the nozzle 30. By varying the introduction of fluid into the nozzle 30, the deposition of chopped fibers 14 on the continuous fibers 16 is precisely controlled, even while being deposited at a rapid rate.
  • A further level of control can be achieved by controlling the movement of the chopped fiber dispenser 12. FIG. 1A shows the chopped fiber dispenser 12 positioned at an angle α with respect to a top, or planar, surface 16t of the array of continuous fibers 16. In the embodiment shown in FIG. 1A, the top surface 16t is oriented along the x-axis and z-axis, where the x axis is defined by a longitudinally extending length of the continuous fibers 16. The chopped fibers 14 are dispersed at an angle α, where the angle α is defined as the angle between the x and y axes, where the y axis is defined as being in a vertical perpendicular relationship to the x axis. The angle α at which the chopped fiber dispenser 12 is oriented can be varied between about 0° to about 90° to control the amount and the pattern of the chopped fibers 14 being dispensed onto the continuous fibers 16.
  • The chopped fiber dispenser 12 is also movable with respect to the continuous fibers 16. The chopped fiber dispenser 12 can include, for example, a hydraulic system (not shown) or other suitable system can be used to enable the chopped fiber dispenser 12 to be moved to a position adjacent or above any portion of the continuous fibers 16. The chopped fiber dispenser 12 can be moved to different positions so that the angle of the chopped fibers 14 being deposited on the continuous fibers 16 can be varied.
  • In certain embodiments, the angle α is varied by moving the chopped fiber dispenser 12 itself with respect to the top surface 16t of the continuous fibers 16 and/or by adjusting the rate of flow of chopped fibers 14 from the chopped fiber dispenser 12.
  • The movement of the chopped fiber dispenser 12 with respect to the continuous fibers 16 can be controlled in any suitable manner. In certain embodiments, the chopped fiber dispenser 12 can be controlled by a computer (not shown) according to predetermined desired parameters so that one or more desired orientations of chopped fibers 14 are laid down on the continuous fibers 16.
  • Also, as shown in FIG. 1A, the nozzle outlet 36 of the chopped fiber dispenser 12 can be oriented along the z-axis by moving a first end 36a of the nozzle outlet 36 at an angle θ with respect to a second end 36b of the nozzle outlet 36, where angle θ is defined as the angle between the x and z axes. The angle θ can be varied between about 0° to about ± 90°.
  • In certain embodiments, the nozzle outlet 36 can be also oriented along the z-axis by moving the nozzle outlet 36 at an angle β, where angle β is defined as the angle between the y and z axes, where the z axis is defined as a width of the array of continuous fibers 16. In this manner, the nozzle outlet 36 sweeps across the width of the array of continuous fibers 16.
  • As an example, if a particular area of the continuous fibers 16 requires a higher/lower than normal concentration of chopped fibers 14, the rate of fiber deposition can be changed by adjusting (reducing/increasing) the fluid flow into the nozzle 30 during the time the nozzle 30 is directing the chopped fibers 14 to that particular area, thereby reducing/increasing the.angle of flow (α) and increasing/decreasing the concentration of the chopped fibers 14 on the specific area of the continuous fibers 16.
  • A further level of control can be achieved by coordinating the flow of fluid into the nozzle 30 with the movement of the chopped fiber dispenser 12. In another example, if a particular area of the continuous fibers 16 requires a higher/lower than normal concentration of chopped fibers 14, the rate, amount and/or orientation of the chopped fiber deposition can be changed by adjusting (reducing/increasing) one or more of: 1) the rate of fluid flow into the nozzle 30; 2) the amount of fluid flow into the nozzle 30; and/or, 3) the angles of α, β, and/or θ of the chopped fibers 14 being dispersed.
  • This adjustment can be made during the time when the nozzle 30 is directing the chopped fibers 14 to that particular area, thereby reducing/increasing the angle of flow (α) and increasing/decreasing the concentration of the chopped fibers 14 on the specific area of the continuous fibers 16.
  • FIG. 1B is a top plan schematic view of the top surface 16t of the continuous fibers 16 showing different orientations of chopped fibers 14. The chopped fibers 14 are oriented at an angle θ (as shown in FIG. 1 A), where θ is defined as an angle between the x and z axes. The angle θ can range anywhere from 0° to ± 90°. For example, in FIG. 1B, the chopped fibers 14a are oriented at a 90° angle θ; the chopped fibers 14b are oriented at a +45° angle θ; the chopped fibers 14c are oriented at a -45° angle θ; the chopped fibers 14d are oriented at a +60° θ; and, the chopped fibers 14e are oriented at a -60° angle θ. It is to be understood that the deposition angle θ of the chopped fibers 14 can be varied, depending on the desired parameters for the fiber reinforcement layer 17.
  • The nozzle 30 need not have any particular dimensions, but in certain embodiments, the width from the first end 36a to the second end 36b of the nozzle 30 can be within the range of from about 15 to about 90 mm, and sometimes within the range of from about 25 to about 50 mm. The length of the nozzle 30 can be within the range of from about 40 to about 200 mm, and sometimes, within the range of from about 50 to about 90 mm. The flow angle β (i.e., width of the dispensed chopped fibers) can be measured by determining the diameter or spray pattern width of the chopped fiber flow at a specific distance from the nozzle outlet 36. A typical ratio of distance-to-width is within the range of from about 5:1 to about 1:1, and preferably within the range of from about 5:1 to about 2:1.
  • In the schematic illustration shown in FIG. 1, the continuous fibers 16 are supplied from a suitable feeder 18. The feeder 18 can be any suitable device for supplying continuous fibers 16. In certain embodiments, the feeder 18 can comprise one or more packages of rovings. In other embodiments, the feeder 18 can be a fiber forming operation where the continuous fibers 16 are supplied from bushings and are directed into the system 10.
  • In certain embodiments, the continuous fibers 16 can be coated with a binder type material supplied by a suitable dispenser 24.
  • Also, in certain embodiments, the continuous fibers 16 are fed onto a collection surface 20 in a suitable manner. For ease of illustration herein, the collection surface 20 is shown as a rotating drum, but it should be understood that other collection surfaces can also be used with the system described herein. The collection surface can be, for example, a rotating drum, a mandrel for forming pipe, a conveyor, or a spool for a fabric material.
  • In embodiments where the collection surface 20 is a rotating drum, the continuous fibers 16 are longitudinally supplied along an outer surface of the drum 20. The rotating drum 20 can be mounted along an axis A-A for rotation by any suitable means, such as by motor (not shown). Also, in certain embodiments, the feeder 18 can be configured to move along the axis A-A of the collection surface 20 and to supply the continuous fibers 16 in a desired pattern on the collection surface 20. In certain embodiments, both the feeder 18 and the chopped fiber dispenser 12 can be configured to move axially along the axis A-A with respect to the collection surface 20.
  • In another embodiment, as shown in FIG. 2, the chopped fibers 14 can be dispensed onto a first supply 16a of continuous fibers. A second supply 16b of continuous fibers is then supplied on top of the chopped fibers 14. The second supply 16b can be supplied at the same or a different orientation with respect to the orientation of the first supply 16a.
  • FIG. 3 shows a system (not according to the present invention) for making a preform 40. The chopped fibers 14 are dispensed onto a mat 42. The mat 42 can be comprised of any suitable combination, such as randomly dispersed materials, woven materials, and/or nonwoven materials. The continuous fibers 16 are deposited onto the chopped fibers 14 that are covering the mat 42 so that the perform 40 is formed.
  • The preform 40 can be impregnated with a suitable impregnation material from any suitable dispenser 46.
  • Also, in certain embodiments, the chopped fibers 14 can be impregnated with a suitable material such as a binder or resin material before the chopped fibers 14 are dispensed onto the continuous fibers 16. In other embodiments, the continuous fibers 16 can be impregnated with a suitable material such as a binder or resin material before the continuous fibers 16 are dispensed onto the collection surface 20. In still other embodiments, both the chopped fibers 14 and the continuous fibers 16 can be impregnated with a suitable material. The impregnating material can be supplied in any suitable manner so that the fibers are substantially coated with the material. In certain embodiments, the material can be a thermoset resin, such as a polyester, epoxy, phenolic or polyurethane resin. In other embodiments, the material can be a thermoplastic such as block copolymer of caprolactam polymer and elastomer Nyrim® resin or other suitable materials.
  • FIG. 4 shows a system where a first supply of continuous fibers 16a receives a supply of chopped fibers 14. A second supply of continuous fibers 16b is deposited on the chopped fibers 14 to form a multilayer reinforcement layer 50. Thereafter, the multi-layer reinforcement layer 50 can be formed into a fabric 52 by being subjected to a needling or stitching process, generally shown by the needling apparatus 60.
  • FIG. 5 shows another system having a reinforcement dispenser 112 which is positioned to deposit chopped reinforcement fibers 14 onto an array of continuous fibers 16. The reinforcement dispenser 112 need not be robotized or automated, and could even be stationary with the array of continuous fibers 16 being moveable. In certain embodiments, a source 118 of vacuum can be positioned beneath the array of continuous fibers 16 to facilitate the deposition process. Also, in certain embodiments, a compaction device 122 can be used to debulk the chopped reinforcement fibers 14.
  • Reinforcement fibers 14s, supplied from a source not shown, are transported to a nozzle 130 in the fiber dispenser 112 where the reinforcement fibers 14s are chopped or cut to produce the discrete length reinforcement fibers 14.
  • The chopped fiber dispenser 112 has a nozzle 130 that has a nozzle chamber 134 with an outlet 136 for dispensing the chopped fibers 14. In certain embodiments, the nozzle chamber 134 has a tapered shape which helps to disperse the chopped fibers 14 exiting the nozzle 130 in a wider flow of chopped fibers 14 onto the continuous fibers 16. It is to be understood that, in certain embodiments, the dispersed stream of chopped fibers 14 can thus have any desired width.
  • The nozzle 130 need not have any particular dimensions, but in certain embodiments, the width of the nozzle 130 can be within the range of from about 15 to about 90 mm, and sometimes within the range of from about 25 to about 50 mm. The length of the nozzle 130 can be within the range of from about 40 to about 200 mm, and sometimes, within the range of from about 50 to about 90 mm. The flow angle β (i.e., width of the dispensed chopped fibers) can be measured by determining the diameter or spray pattern width of the chopped fiber flow at a specific distance from the nozzle outlet 136. A typical ratio of distance-to-width is within the range of from about 5:1 to about 1:1, and preferably within the range of from about 5:1 to about 2:1.
  • In the embodiment shown in FIG. 5, the reinforcement fibers 14s are wound in the nozzle 130 into a series of generally parallel loops or coils 14c. The coils 14c are moved down stream axially of the nozzle 130. As the coils 14c are moved axially, they are engaged by a cutter 140 which makes one or more cuts in each loop or coil 14c. The cutter 140 can be of any type capable of severing the coil 14c into discrete lengths of chopped fibers 14. Examples of cutters include heating devices and lasers. As shown in FIG. 5, after the coils 14c are cut by the cutter 140, they travel downwardly as discrete lengths of chopped fibers 14. The discrete lengths of fibers are laid down in a generally parallel, closely spaced fashion on the array of continuous fibers 16.
  • As stated above, the flow rate, the amount and/or the width of the dispersed stream of the chopped fibers 14 being dispensed from the nozzle 130 can be controlled so that the deposition of chopped fibers 14 on the continuous fibers 16 is precisely controlled, even while being deposited at a rapid rate.
  • A further level of control can be achieved by controlling the movement of the chopped fiber dispenser 112. FIG. 5 shows the chopped fiber dispenser 112 positioned at an angle α with respect to the top, or planar, surface 16t of the array of continuous fibers 16. In the embodiment shown in FIG. 5, the top surface 16t is oriented along the x-axis and z-axis, where the x axis is defined by a longitudinally extending length of the continuous fibers 16. The chopped fibers 14 are dispersed at an angle α, where the angle α is defined as the angle between the x and y axes, where the y axis is defined as being in a vertical perpendicular relationship to the x axis. The angle α at which the chopped fiber dispenser 112 is oriented can be varied between about 0° to about 90° to control the amount and the pattern of the chopped fibers 14 being dispensed onto the continuous fibers 16.
  • The chopped fiber dispenser 112 is also movable with respect to the continuous fibers 16. The chopped fiber dispenser 112 can be, for example, a hydraulic system (not shown) or other suitable systems can be used to enable the chopped fiber dispenser 112 to be moved to a position adjacent or above any portion of the continuous fibers 16. The chopped fiber dispenser 112 can be moved to different positions so that the angle of the chopped fibers 14 being deposited on the continuous fibers 16 can be varied.
  • In certain embodiments, the angle α is varied by moving the chopped fiber dispenser 112 itself with respect to the top surface 16t of the continuous fibers 16 and/or by adjusting the rate of flow of chopped fibers 14 from the chopped fiber dispenser 112.
  • Also, as shown in FIG. 5, the nozzle outlet 136 of the chopped fiber dispenser 112 can be oriented along the z-axis by adjusting a first end of the nozzle outlet 136 at an angle θ with respect to a second end of the nozzle outlet 136, where angle θ is defined as the angle between the x and z axes. The angle θ can be varied between about 0° to about ± 90°.
  • In certain embodiments, the nozzle outlet 136 can be also oriented along the z-axis by moving the nozzle outlet 136 at an angle β, where angle β is defined as the angle between the y and z axes, where the z axis is defined as a width of the array of continuous fibers 16. In this manner, the nozzle outlet 136 sweeps across the width of the array of continuous fibers 16.
  • As an example, if a particular area of the continuous fibers 16 requires a higher/lower than normal concentration of chopped fibers 14, the rate of fiber deposition can be changed by adjusting (reducing/increasing) the flow of chopped fibers 14 from the nozzle 130 during the time the nozzle 130 is directing the chopped fibers 14 to that particular area, thereby reducing/increasing the angle of flow (α) and increasing/decreasing the concentration of the chopped fibers 14 on the specific area of the array of continuous fibers 16.
  • A further level of control can be achieved by coordinating the flow of chopped fibers 14 from the chopped fiber dispenser 112. In another example, if a particular area of the continuous fibers 16 requires a higher/lower than normal concentration of chopped fibers 14, the rate, amount and/or orientation of the chopped fiber deposition can be changed by adjusting (reducing/increasing) one or more of: 1) the rate of chopped fiber flow from the nozzle 130; and/or 2) the angles of α, β, and/or θ of the chopped fibers 14 being dispersed.

Claims (14)

  1. An apparatus (10) for forming a fibrous reinforcement layer (17) having cross-directionally oriented fibers, the apparatus comprising ; a feeder (18) for feeding an array of continuous fibers (16;16a) in a first orientation; and a chopped fiber dispenser (12) including a nozzle (30) to dispense generally aligned chopped fibers (14) onto the array of continuous fibers in at least a second orientation with respect to the first orientation of the array of continuous fibers to form the fibrous reinforcement layer (17), characterized in that:
    said chopped fiber dispenser (12) is selectively movable relative to said array of continuous fibers (16) to vary a positional relationship of said chopped fibers placed on said array of continuous fibers, and
    said nozzle (30) includes a fluid directing device (38) for directing a fluid into the nozzle to control a flow rate, an amount, and/or a dispersion width of the chopped fibers exiting the nozzle by controlling the fluid entering the nozzle (30).
  2. The apparatus of claim 1, wherein said chopped fiber dispenser is movable relative to said array of continuous fibers which moves along a longitudinal direction so as to vary the pattern of the placement of said chopped fibers on said array of continuous fibers.
  3. The apparatus of claim 1, wherein the chopped fiber dispenser is positioned at an angle α with respect to the top surface (16t) of the array of continuous fibers. Said angle α being defined between an x - axis defined by a longitudinally extending Length of the array of continuous fibers and a y-axis which is in a vertical perpendicular relationship to the x-axis, said chopped fiber dispenser being movable to vary said angle α so as to control an amount and a pattern of the placement of said chopped fibers on said array of continuous fibers.
  4. The apparatus of claim 1, wherein the feeder is configured to feed at least a second supply (16b) of continuous fibers onto the chopped fibers.
  5. The apparatus of claim 1, further including a collection surface (20) configured to receive the fibrous reinforcement layer (17).
  6. The apparatus of claim 5, wherein the collection surface is a rotating drum, a mandrel for forming pipe, or spool for a fabric material.
  7. A process for making a fibrous reinforcement layer (17) having cross-directionally oriented fibers, the process comprising directing a supply of an array of continuous fibers (16;16a) from a feeder (18) in a first orientation; and dispensing through a nozzle (30) of a chopped fiber dispenser (12) a supply of generally aligned chopped fibers (14) onto the array of continuous fibers in at least a second orientation with respect to the first orientation of the array of continuous fibers to form the fibrous reinforcement layer (17); characterized in that
    said chopped fiber dispenser (12) is selectively movable relative to said array of continuous fibers to vary a positional relationship of said chopped fibers placed on said array of continuous fibers, and
    said nozzle (30) includes a fluid directing device (38) for directing a fluid into the nozzle to control a flow rate, an amount, and/or a dispersion width of the chopped fibers exiting the nozzle by controlling the fluid entering the nozzle (30).
  8. The process of claim 7, wherein a rate, amount and/or orientation of the chopped fiber deposition is changed by adjusting
    an angle at which the chopped fibers are dispensed from the chopped fiber dispenser.
  9. The process of claim 7, including directing a second supply of an array of continuous fibers (16b) onto the chopped fibers.
  10. The process of claim 7, including selecting a desired deposition pattern for the chopped fibers being dispensed onto the array of continuous fibers.
  11. The process of claim 7, including coating at least one of the continuous fibers and the chopped fibers with a binder material.
  12. The process of claim 7, including directing the fibrous reinforcement layer (17) onto a collection surface (20).
  13. The process of claim 12, wherein the collection surface is a rotating drum, a mandrel for forming pipe, a conveyor system, or spool for a fabric material.
  14. The process of claim 12, including moving the feeder (18) with respect to the collection surface.
EP07836959A 2006-08-25 2007-08-16 System for forming reinforcement layers having cross-directionally oriented fibers Not-in-force EP2073975B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL07836959T PL2073975T3 (en) 2006-08-25 2007-08-16 System for forming reinforcement layers having cross-directionally oriented fibers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/510,221 US8028736B2 (en) 2006-08-25 2006-08-25 System for forming reinforcement layers having cross-directionally oriented fibers
PCT/US2007/018217 WO2008027206A2 (en) 2006-08-25 2007-08-16 System for forming reinforcement layers having cross-directionally oriented fibers

Publications (2)

Publication Number Publication Date
EP2073975A2 EP2073975A2 (en) 2009-07-01
EP2073975B1 true EP2073975B1 (en) 2013-03-13

Family

ID=39025918

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07836959A Not-in-force EP2073975B1 (en) 2006-08-25 2007-08-16 System for forming reinforcement layers having cross-directionally oriented fibers

Country Status (8)

Country Link
US (1) US8028736B2 (en)
EP (1) EP2073975B1 (en)
DK (1) DK2073975T3 (en)
EA (1) EA017245B1 (en)
ES (1) ES2408229T3 (en)
PL (1) PL2073975T3 (en)
PT (1) PT2073975E (en)
WO (1) WO2008027206A2 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8028736B2 (en) 2006-08-25 2011-10-04 Ocv Intellectual Capital, Llc System for forming reinforcement layers having cross-directionally oriented fibers
NL1036355C2 (en) * 2008-12-22 2009-10-27 Willem Frans Van Der Mast Reinforcement fiber supplying method for pipe producing machine, involves limiting distance between location where fiber are issued and surface of object such that fiber retain on specific orientation while drop down
US8992711B2 (en) * 2010-09-21 2015-03-31 The Boeing Company Method and apparatus for making fiber reinforced composite tubes
BR112013011577B1 (en) 2010-12-02 2020-12-08 Teijin Carbon Europe Gmbh fiber preform and composite component
AT511349B1 (en) * 2011-09-21 2012-11-15 Kapsch Group Beteiligungs Gmbh FIBER MIDDLE, FIBER COMPOSITE AND METHOD FOR THE PRODUCTION THEREOF
WO2013071449A1 (en) 2011-11-16 2013-05-23 Flexpipe Systems Inc. Flexible reinforced pipe and reinforcement tape
DK2780619T3 (en) 2011-11-16 2018-11-19 Shawcor Ltd PIPE CONNECTION DEVICE AND PROCEDURE
CA3040163C (en) 2012-02-17 2021-02-16 Core Linepipe Inc. Pipe electro-fusion assembly
DE102012203388A1 (en) * 2012-03-05 2013-09-05 Voith Patent Gmbh Cross filing of fibers
EP2909026A1 (en) * 2012-10-16 2015-08-26 OCV Intellectual Capital, LLC Liner for reinforcing a pipe and method of making the same
WO2015187879A1 (en) 2014-06-04 2015-12-10 Bright Lite Structures Llc Composite structure exhibiting energy absorption and/or including a defect free surface
EP3277868B1 (en) * 2015-04-03 2021-11-24 Bright Lite Structures LLC Apparatus for controllably cutting fibers and related methods
US10160004B2 (en) 2015-07-07 2018-12-25 Palo Alto Research Center Incorporated Creating aligned and oriented fiber reinforced polymer composites
US10625486B2 (en) * 2016-06-20 2020-04-21 Johns Manville Methods of producing thermoplastic composites using fabric-based thermoplastic prepregs
KR102253104B1 (en) * 2017-05-19 2021-05-14 (주)엘지하우시스 Fiber reinforced composite material and method of manufacturing the same
CN109228399A (en) * 2018-10-16 2019-01-18 深圳市创旭腾新材料科技有限公司 A kind of integral formation method of same with thermosetting compound material chopped strand and continuous fiber
JP7208390B2 (en) 2018-11-19 2023-01-18 ブライト ライト ストラクチャーズ エルエルシー High-strength composite with low heat release

Family Cites Families (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2215150A (en) * 1936-12-28 1940-09-17 Hannen Clemens Process for treating mineral fibrous substances, such as glass wool, slag wool, or the like
US2882673A (en) * 1953-04-30 1959-04-21 Buddecke Heinrich Coiling head for yarn packs
US2892307A (en) * 1955-11-17 1959-06-30 Westinghouse Electric Corp "hot streak" ignition arrangement for afterburner fuel control system
US2954817A (en) * 1957-10-11 1960-10-04 St Regis Paper Co Apparatus and method for forming and applying strand reinforcement and product produced thereby
US3170197A (en) * 1961-01-12 1965-02-23 Ivan G Brenner Apparatus for producing a fibrous glass preform
US3377233A (en) * 1964-04-08 1968-04-09 John G. Jackson Coated glass thread
DE1560007A1 (en) 1966-05-27 1969-07-17 Heinrich Buddecke Winding head for the production of a yarn tape that consists of transverse yarn turns
FR1584056A (en) * 1968-07-29 1969-12-12
US3728195A (en) 1969-02-10 1973-04-17 Deering Milliken Res Corp Apparatus for the production of non-woven net fabrics
US3728189A (en) * 1969-06-06 1973-04-17 Johns Manville Method and apparatus for fabricating a plurality of filaments into a helix
US3831879A (en) * 1970-03-11 1974-08-27 Us Navy Wire dispenser
US3719540A (en) * 1970-05-04 1973-03-06 Hercules Inc Preparation of transversely fibrillated film
US3864443A (en) * 1970-05-27 1975-02-04 Arthur Hopkins Method of making light-weight concrete aggregate
US3892307A (en) * 1972-09-05 1975-07-01 American Air Filter Co Conveyor having adjustable flights
JPS4986638A (en) * 1972-12-25 1974-08-20
JPS5040185B2 (en) * 1973-01-18 1975-12-22
US4018964A (en) * 1973-07-27 1977-04-19 Nippon Asbestos Company, Ltd. Method for preparing glassy fiber having protuberances studded on the surface useful for reinforcement and resulting product
US3977069A (en) * 1974-12-18 1976-08-31 Brunswick Corporation Process and apparatus for production of precision cut lengths of metal wires and fibers
US4001935A (en) * 1975-06-12 1977-01-11 Binks Manufacturing Company Roving cutter
NL7802576A (en) * 1977-05-13 1978-11-15 Neumuenster Masch App METHOD AND DEVICE FOR TREATING FIBER TIRES.
JPS5431533A (en) 1977-08-15 1979-03-08 Hitachi Ltd High voltage thyristor device
CA1110817A (en) * 1978-02-23 1981-10-20 Giorgio A. Escher Fibre reinforced plastic structures and method and apparatus for producing same
US4178670A (en) * 1978-06-22 1979-12-18 Crystal Systems, Inc. Process of forming a wire pack
US4352769A (en) * 1980-05-27 1982-10-05 Victor United, Inc. Method for simultaneously molding a plurality of products
JPS5913423A (en) 1982-07-14 1984-01-24 Matsushita Electric Ind Co Ltd Gate turn off thyristor
US4519281A (en) * 1983-03-07 1985-05-28 Eastman Kodak Company Package wind cutter
GB2158471B (en) 1984-05-04 1988-03-16 Budd Co Fiberous armor material
US4750960A (en) * 1984-09-10 1988-06-14 Rensselaer Polytechnic Institute Robotic winding system and method
FR2581631B1 (en) * 1985-05-07 1987-07-10 Superba Sa SCREW DEVICE FOR FORMING FLAT LOOPS OF TEXTILE THREADS
US4630515A (en) * 1985-10-15 1986-12-23 Eastman Kodak Company Apparatus for cutting continuous strand
US4780432A (en) * 1986-09-02 1988-10-25 United Technologies Corporation Controlled fiber distribution technique for glass matrix composites
US4752313A (en) * 1986-12-16 1988-06-21 Corning Glass Works Pultrusion process for fiber-reinforced composites
US4854990A (en) * 1987-04-13 1989-08-08 David Constant V Method for fabricating and inserting reinforcing spikes in a 3-D reinforced structure
US5192390A (en) * 1987-11-13 1993-03-09 Bridgestone/Firestone Inc. Mandrel means
JP2547238B2 (en) * 1988-03-29 1996-10-23 株式会社日本触媒 Method for producing fiber-reinforced resin molding material
US4921518A (en) * 1988-12-23 1990-05-01 Corning Incorporated Method of making short fiber reinforced glass and glass-ceramic matrix composites
US4973440A (en) * 1989-03-15 1990-11-27 Nippon Shokubai Kagaku Kogyo Co., Ltd. Method for production of fiber-reinforced thermosetting resin molding material
US5432000A (en) * 1989-03-20 1995-07-11 Weyerhaeuser Company Binder coated discontinuous fibers with adhered particulate materials
US5020403A (en) * 1989-06-20 1991-06-04 Angelo Joseph J D Web feeding, cutting and dispensing machine
SU1694724A1 (en) 1989-08-02 1991-11-30 Предприятие П/Я А-7317 Device for cutting threads to size
US4944446A (en) * 1989-11-02 1990-07-31 Micron Technology, Inc. Automatic preform dispenser
US5229052A (en) * 1990-02-23 1993-07-20 Wellman Machinery Of Michigan, Inc. Apparatus and method for applying multiple type fibers to a foraminous surface
US5084035A (en) * 1990-03-27 1992-01-28 The Kendall Company Drainage device
JPH0452106A (en) * 1990-06-20 1992-02-20 Japan Steel Works Ltd:The Production of fiber reinforced plastic molded form
CA2057201C (en) * 1990-12-19 1998-05-19 Vernon M. Benson Multiple axes fiber placement machine
US5158631A (en) * 1991-01-15 1992-10-27 United Technologies Corporation Method of manufacturing a dog-leg shaped ply of composite material and the tool used in carrying out the method
US5204033A (en) * 1991-10-21 1993-04-20 Brunswick Corporation Method of fabricating a preform in a resin transfer molding process
US5463919A (en) * 1991-11-02 1995-11-07 Zortech International Limited Apparatus for cutting wound coils
US5262106A (en) * 1992-02-06 1993-11-16 The United States Of America As Represented By The United States Department Of Energy Anisotropic fiber alignment in composite structures
RO118129B1 (en) 1993-07-06 2003-02-28 Aplicator System Ab Device supplying reinforcing fibres for manufacturing heat-settable plastic products
EP0634265A1 (en) 1993-07-14 1995-01-18 General Electric Company Thermoforming process
JPH07107205A (en) 1993-10-05 1995-04-21 Matsushita Electric Ind Co Ltd Image communication terminal equipment
US5484641A (en) * 1993-11-01 1996-01-16 Rotter; Martin J. Process for fixing plastic reinforcing pins into non-woven filamentary material and product produced by the process
JPH07215587A (en) 1994-01-26 1995-08-15 Furukawa Electric Co Ltd:The Cutting and dividing device for filament
US5806387A (en) * 1995-04-10 1998-09-15 N.V. Owens-Corning S.A. Method for dispensing resinated reinforcement fibers
JPH11507104A (en) 1995-04-10 1999-06-22 ナムローゼ フェンノートシャップ オウェンス コーニング ソシエテ アノニム Reinforcement fiber distribution method
US5826812A (en) * 1997-01-08 1998-10-27 Belmont Textile Machinery Co., Inc. Coiler apparatus and method
FR2760596B1 (en) * 1997-03-14 1999-04-02 Speed France COMPOSITE CUTTING WIRE FOR TRIMMERS AND TRIMMERS
FR2761380B1 (en) * 1997-03-28 1999-07-02 Europ Propulsion METHOD AND MACHINE FOR PRODUCING MULTIAXIAL FIBROUS MATS
US6949289B1 (en) 1998-03-03 2005-09-27 Ppg Industries Ohio, Inc. Impregnated glass fiber strands and products including the same
US6029897A (en) * 1998-03-19 2000-02-29 N.V. Owens-Corning S.A. Method of dispensing chopped reinforcement strand using a vortex nozzle
US6038949A (en) * 1998-09-14 2000-03-21 Nv Owens-Corning S.A. Method for dispensing reinforcement fibers
US6325605B1 (en) 1998-11-02 2001-12-04 Owens Corning Canada Inc. Apparatus to control the dispersion and deposition of chopped fibrous strands
US6182332B1 (en) * 1999-07-30 2001-02-06 Owens Corning Composites Sprl Method of forming discrete length fibers
FR2797892B1 (en) * 1999-08-27 2002-08-30 Vetrotex France Sa PROCESS AND DEVICE FOR MANUFACTURING COMPOSITE PLATES
US6615875B2 (en) 2000-08-30 2003-09-09 Owens Corning Composites Sprl. Liner for reinforcing a pipe and method of making the same
US7514135B2 (en) * 2001-06-14 2009-04-07 Omniglass Ltd. Pultruded part reinforced by longitudinal and transverse fibers and a method of manufacturing thereof
US6527211B1 (en) * 2001-08-07 2003-03-04 Masco Corporation Blade and spring fiber chopper
US7353853B2 (en) * 2005-05-03 2008-04-08 Cincinnati Machine, Llc Fiber placement machine
US8028736B2 (en) 2006-08-25 2011-10-04 Ocv Intellectual Capital, Llc System for forming reinforcement layers having cross-directionally oriented fibers

Also Published As

Publication number Publication date
US8028736B2 (en) 2011-10-04
PT2073975E (en) 2013-05-06
DK2073975T3 (en) 2013-06-17
EA017245B1 (en) 2012-11-30
WO2008027206A3 (en) 2008-04-24
EP2073975A2 (en) 2009-07-01
ES2408229T3 (en) 2013-06-19
WO2008027206A2 (en) 2008-03-06
PL2073975T3 (en) 2013-08-30
US20080047657A1 (en) 2008-02-28
EA200970225A1 (en) 2009-08-28

Similar Documents

Publication Publication Date Title
EP2073975B1 (en) System for forming reinforcement layers having cross-directionally oriented fibers
CA2680470C (en) Method and device for producing a preform for a fibre composite structure suitable for power flows
CN111163921B (en) Method for manufacturing an article made of composite material by 3D printing
KR102091993B1 (en) Method for producing fibre preforms
CA2680457A1 (en) Spreading device for spreading out fibre filament bundles, and spreading method carried out using same
EP0907475B1 (en) Method for dispensing resinated reinforcement fibers
JPH02196637A (en) Glass-fiber-reinforced themoplastic sheet
US5819614A (en) Method for dispensing reinforcement fibers
CA1130713A (en) High strength composite of resin, helically wound fibers and swirled continuous fibers and method of its formation
EP1077805B1 (en) Method of dispensing chopped reinforcement strand using a vortex nozzle
CA3010092A1 (en) Method and apparatus for producing a reinforcement mesh
EP1144288B1 (en) Method for dispensing reinforcement fibers
CA1121705A (en) High strength composite of resin, helically wound fibers and chopped fibers and method of its formation
KR102082632B1 (en) Depositing device for the controlled deposition of reinforcing fibre bundles
KR101078713B1 (en) Fiber supplying apparatus for axial reinforcement of continuous pipe
US20050118390A1 (en) Continuous strand mats, methods of producing continuous strand mats, and systems for producing continuous strand mats
MXPA00009148A (en) Method of dispensing chopped reinforcement strand using a vortex nozzle

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20090325

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR MK RS

RIN1 Information on inventor provided before grant (corrected)

Inventor name: JANDER, MICHAEL

17Q First examination report despatched

Effective date: 20090720

DAX Request for extension of the european patent (deleted)
GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 600536

Country of ref document: AT

Kind code of ref document: T

Effective date: 20130315

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: PT

Ref legal event code: SC4A

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20130424

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602007029104

Country of ref document: DE

Effective date: 20130508

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2408229

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20130619

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130313

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130613

REG Reference to a national code

Ref country code: NL

Ref legal event code: T3

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130313

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130614

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130313

REG Reference to a national code

Ref country code: PL

Ref legal event code: T3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130313

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130713

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130313

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130313

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FI

Payment date: 20130813

Year of fee payment: 7

Ref country code: SE

Payment date: 20130821

Year of fee payment: 7

Ref country code: AT

Payment date: 20130813

Year of fee payment: 7

Ref country code: PT

Payment date: 20130424

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130313

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20131216

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602007029104

Country of ref document: DE

Effective date: 20131216

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130831

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130831

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130313

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130816

REG Reference to a national code

Ref country code: PT

Ref legal event code: MM4A

Free format text: LAPSE DUE TO NON-PAYMENT OF FEES

Effective date: 20150216

REG Reference to a national code

Ref country code: SE

Ref legal event code: EUG

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 600536

Country of ref document: AT

Kind code of ref document: T

Effective date: 20140816

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150216

Ref country code: FI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140816

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140817

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140816

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130313

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130816

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20070816

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 10

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20170826

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20170825

Year of fee payment: 11

Ref country code: ES

Payment date: 20170901

Year of fee payment: 11

Ref country code: IT

Payment date: 20170823

Year of fee payment: 11

Ref country code: CZ

Payment date: 20170803

Year of fee payment: 11

Ref country code: DE

Payment date: 20170829

Year of fee payment: 11

Ref country code: GB

Payment date: 20170829

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PL

Payment date: 20170802

Year of fee payment: 11

Ref country code: BE

Payment date: 20170828

Year of fee payment: 11

Ref country code: DK

Payment date: 20170825

Year of fee payment: 11

Ref country code: TR

Payment date: 20170802

Year of fee payment: 11

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602007029104

Country of ref document: DE

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

Effective date: 20180831

REG Reference to a national code

Ref country code: NL

Ref legal event code: MM

Effective date: 20180901

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20180816

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180816

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20180831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180901

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180816

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180831

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190301

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180831

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180831

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20190918

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180816

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180817

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180816

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180816