EP1125517B1 - Device for storing and applying comprising an intermediate storage element - Google Patents

Device for storing and applying comprising an intermediate storage element Download PDF

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Publication number
EP1125517B1
EP1125517B1 EP01400400A EP01400400A EP1125517B1 EP 1125517 B1 EP1125517 B1 EP 1125517B1 EP 01400400 A EP01400400 A EP 01400400A EP 01400400 A EP01400400 A EP 01400400A EP 1125517 B1 EP1125517 B1 EP 1125517B1
Authority
EP
European Patent Office
Prior art keywords
applicator
fact
intermediate reservoir
forming element
receptacle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01400400A
Other languages
German (de)
French (fr)
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EP1125517A1 (en
Inventor
Jean-François Delage
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
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Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Publication of EP1125517A1 publication Critical patent/EP1125517A1/en
Application granted granted Critical
Publication of EP1125517B1 publication Critical patent/EP1125517B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D34/04Appliances specially adapted for applying liquid, e.g. using roller or ball
    • A45D34/042Appliances specially adapted for applying liquid, e.g. using roller or ball using a brush or the like
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00Details not otherwise provided for in A45D
    • A45D2200/10Details of applicators
    • A45D2200/1009Applicators comprising a pad, tissue, sponge, or the like
    • A45D2200/1018Applicators comprising a pad, tissue, sponge, or the like comprising a pad, i.e. a cushion-like mass of soft material, with or without gripping means

Definitions

  • the present invention relates to a packaging device and for applying a product, in particular a cosmetic or care product, comprising a container to contain the product, this container being provided at the top with an applicator permeable to the product, comprising an internal face supplied with the product from of the container.
  • the product contained in the container gains the face inside of the applicator and flows towards its outside face through the material constituting the applicator, to come into contact with the skin of the user.
  • the user can feed the applicator by pressing it.
  • the user is faced with an autonomy problem if he uses the device head up or when he does not only a small amount of product remains in the container and the device is used horizontally.
  • the product may have difficulty diffusing through the applicator due to of its consistency.
  • the preamble of claim 1 is known from EP-A-0 678 458 and US-A-5 454 658.
  • the new packaging and application device according to the invention includes the features of claim 1.
  • the autonomy of the device is increased since the latter can be used longer in the head-up position without recharging the applicator by inverting the container.
  • the intermediate reservoir element makes it possible to supply the applicator when the device is used horizontally or substantially horizontally and that the quantity of product in the container is insufficient to directly gain the applicator.
  • the element forming the intermediate reservoir and the applicator are arranged in such a way that the latter comes into contact with the product retained by the intermediate reservoir element when sufficient pressure is exerted on the applicator during use.
  • the applicator is made of a cellular material elastically deformable, with open cells, for example a foam or a sponge.
  • the element forming an intermediate reservoir has a concave cup towards the applicator, in order to retain a certain amount of product when the device is turned over and then brought upside down.
  • the reservoir element intermediate has partitions tending to oppose the return of the product retained by the intermediate reservoir element towards the bottom of the container when the device is tilted relative to the vertical from an initial head-up position.
  • partitions are advantageously cylindrical, with the same axis as the container.
  • the partitions are provided with passages allowing the product to flow between them.
  • the distribution of the product in the intermediate reservoir element can thus be more homogeneous.
  • the applicator has an outer face having a dome shape and an inner face defining a recess in which the intermediate reservoir element is at least partially engaged.
  • the applicator is subjected at its periphery to a support piece made of a non-cellular material, for example a material semi-rigid plastic.
  • This support piece helps to facilitate the mounting of the applicator and its replacement, if applicable.
  • the container has a lower body and an upper part used for mounting a closure cover, constituted by a patch on this body.
  • the lower body is preferably made of a rigid plastic material, for aesthetic reasons.
  • the upper part of the container has a neck on which the closing cover is screwed.
  • the upper part of the container comprises fixing means capable of cooperating by snap-fastening with the piece of applicator support.
  • the latter comprises two fixing lugs diametrically opposite and arranged to allow, by being pressed inwards, to separate the applicator from the container, in order to clean it or replacement for example.
  • the intermediate reservoir element and the rest of the upper part of the container are advantageously made in one piece by molding of material plastic.
  • the element forming an intermediate reservoir is supported by an openwork wall having lateral passages allowing the product contained in the container to gain the space between the tank member intermediate and the inner face of the applicator when the container is inverted.
  • the aforementioned perforated wall is connected to the element forming intermediate tank without forming a projecting edge.
  • the region of the inner face of the applicator directly opposite the element forming the intermediate reservoir can be planar or convex towards the latter, so as to facilitate the contact of the applicator with the product retained in the element forming an intermediate reservoir.
  • the applicator occupies substantially all of the interior volume of the intermediate reservoir element, said interior volume being that in which the product retained by the reservoir element can accumulate intermediate.
  • the reservoir element comprises a rigid wall.
  • Another subject of the invention is the use of a packaging device and application as defined above, to apply a product to the body cosmetic or skincare.
  • the packaging and application device 1 shown in the figures comprises a container 2 formed by the assembly of a lower body 3 and a part upper 4, both made of rigid plastic.
  • the lower body 3 has a cylindrical lateral wall of axis revolution X, extended upwards by a collar 5 of axis X externally provided with a bead ring finger 6.
  • the upper part 4 has an externally threaded neck 7, intended for receive a closing cover 8.
  • the neck 7 is extended below by shaped fixing lugs 9 to snap onto the annular bead 6.
  • the upper part 4 also includes an outer skirt 10 surrounding the fixing lugs 9 and coming to be positioned in the extension of the side wall of the body 3 and an annular sealing lip 11 which is applied in a sealed manner on the radially inner surface 13 of the neck 5.
  • the upper part 4 of the container also has a stepped wall 14 which extends generally perpendicular to the X axis, radially inward, and which serves as a support for an element forming an intermediate reservoir 15 whose role will be specified further.
  • the stepped wall 14 has a first annular part 17 which is connected to the base of the threaded neck 7 and which serves to support a symmetrical mounting skirt 19 of revolution around the X axis and directed upwards, this mounting skirt 19 being provided on its radially inner surface with an annular groove 20 in the vicinity of its upper end.
  • the first annular part 17 is extended inward by a second annular part 21 extending parallel to the axis X at its connection to the first annular part 17 to form an annular groove 60 then perpendicular to the X axis.
  • the intermediate reservoir element 15 is connected to the second part annular 21 by a curved wall 23 provided with openings 24, four in number in the embodiment described, these openings 24 being equally distributed around the axis X.
  • the container 2 is filled with a product P, cosmetic or care.
  • the closure cover 8 has an annular sealing lip 26 which applies tightly to the radially inner surface of the neck 7, as can see it in figure 1.
  • the packaging and application device 1 comprises an applicator 30 made of an open cell plastic foam material such as by example a foam or a sponge.
  • the applicator 30 is fixed on its periphery to an annular support piece 31 made of a rigid or semi-rigid plastic material.
  • This support piece 31 has a base wall 32 which bears on the second annular part 21 of the stepped wall 14.
  • the base wall 32 is connected at its outer periphery on the one hand to a lip sealing ring 33 which extends downwards and is applied in a sealed manner to the radially inner surface of the mounting skirt 19 under the annular groove 20 and on the other hand with two diametrically opposite fixing lugs 34 extending upwards in the extension of the annular sealing lip 33.
  • the fixing lugs 34 are each provided with a boss 35 coming from snap into the annular groove 20 of the mounting skirt 19.
  • the applicator 30 does not rest not directly on the base wall 32 but is fixed by its end edge lower on ribs 37, annular, projecting upwards on the wall of base 32, being fixed on the ribs 37 by any known means, for example by welding or collage.
  • the applicator 30 has at rest an outer face 40 in the form of a dome and an inner face 41 comprising a central region 42 directly facing in the axis X to the intermediate reservoir element 15, planar and perpendicular to the axis X, and a rounded peripheral region 43, concave towards the container, of larger radius of curvature than the curved wall 23.
  • the intermediate reservoir element 15 comprises a cup 45 concave towards the applicator 30, this cup 45 connecting to the curved wall 23 by its peripheral edge 55 without forming a projecting edge and supporting, in the example of realization described, two partitions 47 and 48, cylindrical of revolution around the axis X.
  • the partitions 47 and 48 have a height chosen so that their upper end lies substantially in the same plane as the peripheral edge 55 of the cup 45, this plane being perpendicular to the axis X.
  • all the constituent elements of the part upper of the container 4 are made in one piece by plastic molding.
  • the device 1 is used in the following manner.
  • the product P gains by crossing the openings 24 the space 50 between the intermediate reservoir element 15 and the inner face 41 of the applicator and diffuses from the latter towards the external surface 40, by capillarity and / or gravity through the porous material constituting the applicator 30.
  • the partitions 47 and 48 participate in the retention of the product in the element forming an intermediate reservoir 15.
  • the volume of the quantity of product retained in the intermediate reservoir element is for example between 0.5 and 3 cm 3 .
  • the applicator 30 impregnated with product P can then be moved on the skin S as illustrated in FIG. 4, the X axis being able to take various orientations and in particular be horizontal or substantially horizontal.
  • the product P contained in the applicator 30 is deposited on the skin S during the moving the device 1.
  • the pressure exerted during use on the applicator 30 by the skin S has for effect of deforming the latter and bringing its inner surface 41 into contact with the element forming an intermediate reservoir 15, as can be seen in FIG. 4.
  • the product is thus forced to diffuse into the applicator 30.
  • the radius of curvature of the region peripheral 43 of the inner face 41 of the applicator 30 is chosen so that when the applicator 30 comes to bear on the partitions 47 and 48 and the peripheral edge 55 of the cup 45, the peripheral region 43 extends substantially parallel to the curved wall 23.
  • the element forming intermediate reservoir 15 enables the applicator 30 to be supplied with the product retained at inside the cup 45 when the level N of the product is insufficient for this feeds the applicator 30 directly through the openings 24.
  • the invention makes it possible to increase the autonomy of the applicator 30, since under the pressure exerted on the latter at at the time of application to the skin S, the inner face 41 can come into contact with the product retained in the element forming the intermediate reservoir 15.
  • the applicator 30 is then powered by capillary action.
  • the applicator 30 tends to penetrate between the partitions 47 and 48 to compress the product P contained in the intermediate reservoir element which is thus driven into the applicator 30.
  • the applicator can be easily separated from the upper part 4 of the container 2 by deforming the fixing lugs 34 inwards, which makes it possible to disengage the bosses 35 of the annular groove 20 of the mounting skirt 19.
  • FIG. 6 shows an alternative embodiment which differs from the device previously described by the fact that the element forming an intermediate reservoir 15 is replaced by an intermediate reservoir element 15 'which no longer comprises partitions 47 and 48.
  • the device is identical for the rest.
  • FIG. 7 A variant has been illustrated in FIG. 7 in which the partitions 47 and 48 are replaced by partitions 47 'and 48' provided with passages 62 which allow the product to circulate between the rings formed by the partitions 47 'and 48'.
  • the distribution of product is thus more homogeneous in the element forming the intermediate reservoir.
  • the partitions 47 'and 48' constitute staves against which the applicator comes to bear at the time of use.
  • the device shown in Figure 8 differs from that shown in Figure 6 by the fact that the applicator 30 is replaced by an applicator 30 'comprising a part central unit 64 which follows the shape of the concavity of the reservoir element intermediate 15 '.
  • the cellular material constituting the applicator 30 ' occupies all of the internal volume of the intermediate reservoir element 15 '.
  • the product accumulates in the intermediate reservoir element 15 'at within the cellular material constituting the applicator 30 '.
  • the element forming the intermediate reservoir can be produced with a shape or a different structure.

Landscapes

  • Closures For Containers (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Coating Apparatus (AREA)
  • Cosmetics (AREA)
  • Massaging Devices (AREA)

Description

La présente invention concerne un dispositif de conditionnement et d'application d'un produit, notamment cosmétique ou de soin, comportant un récipient pour contenir le produit, ce récipient étant muni en partie supérieure d'un applicateur perméable au produit, comportant une face intérieure alimentée par le produit provenant du récipient.The present invention relates to a packaging device and for applying a product, in particular a cosmetic or care product, comprising a container to contain the product, this container being provided at the top with an applicator permeable to the product, comprising an internal face supplied with the product from of the container.

On connaít de nombreux dispositifs de ce type.We know many devices of this type.

Lors de l'utilisation, le produit contenu dans le récipient gagne la face intérieure de l'applicateur et circule vers sa face extérieure à travers le matériau constituant l'applicateur, pour venir au contact de la peau de l'utilisateur.During use, the product contained in the container gains the face inside of the applicator and flows towards its outside face through the material constituting the applicator, to come into contact with the skin of the user.

Lorsque le récipient présente une paroi souple, l'utilisateur peut alimenter l'applicateur en pressant celle-ci.When the container has a flexible wall, the user can feed the applicator by pressing it.

Par contre, lorsque le récipient présente une paroi rigide, l'utilisateur se trouve confronté à un problème d'autonomie s'il utilise le dispositif tête en haut ou lorsqu'il ne reste qu'une faible quantité de produit dans le récipient et que le dispositif est utilisé horizontalement.On the other hand, when the container has a rigid wall, the user is faced with an autonomy problem if he uses the device head up or when he does not only a small amount of product remains in the container and the device is used horizontally.

De plus, le produit peut avoir du mal à diffuser à travers l'applicateur en raison de sa consistance.In addition, the product may have difficulty diffusing through the applicator due to of its consistency.

Il existe ainsi un besoin pour disposer d'un dispositif présentant une autonomie et un confort d'utilisation accrus.There is thus a need to have a device having autonomy and increased user comfort.

Le préambule de la revendication 1 est connu de EP-A-0 678 458 et US-A-5 454 658.The preamble of claim 1 is known from EP-A-0 678 458 and US-A-5 454 658.

Le nouveau dispositif de conditionnement et d'application selon l'invention comporte les caractéristiques de la revendication 1.The new packaging and application device according to the invention includes the features of claim 1.

Grâce à l'invention, l'autonomie du dispositif est augmentée puisque ce dernier peut être utilisé plus longtemps dans la position tête en haut sans avoir à recharger l'applicateur en retournant le récipient.Thanks to the invention, the autonomy of the device is increased since the latter can be used longer in the head-up position without recharging the applicator by inverting the container.

De plus, l'élément formant réservoir intermédiaire permet d'alimenter l'applicateur lorsque le dispositif est utilisé horizontalement ou sensiblement horizontalement et que la quantité de produit dans le récipient est insuffisante pour gagner directement l'applicateur.In addition, the intermediate reservoir element makes it possible to supply the applicator when the device is used horizontally or substantially horizontally and that the quantity of product in the container is insufficient to directly gain the applicator.

Avantageusement, l'élément formant réservoir intermédiaire et l'applicateur sont agencés de telle sorte que ce dernier vienne au contact du produit retenu par l'élément formant réservoir intermédiaire lorsqu'une pression suffisante est exercée sur l'applicateur lors de l'utilisation.Advantageously, the element forming the intermediate reservoir and the applicator are arranged in such a way that the latter comes into contact with the product retained by the intermediate reservoir element when sufficient pressure is exerted on the applicator during use.

On peut également favoriser le passage du produit à travers l'applicateur en donnant à l'élément formant réservoir intermédiaire une forme choisie de telle sorte que le produit contenu dans l'élément formant réservoir intermédiaire se trouve comprimé par l'applicateur lorsque ce dernier est pressé contre l'élément formant réservoir intermédiaire et donc forcé à traverser l'applicateur.We can also encourage the passage of the product through the applicator by giving the element forming the intermediate reservoir a shape chosen so that the product contained in the intermediate tank element is compressed by the applicator when the latter is pressed against the reservoir element intermediate and therefore forced to pass through the applicator.

Avantageusement, l'applicateur est réalisé dans un matériau alvéolaire élastiquement déformable, à cellules ouvertes, par exemple une mousse ou une éponge.Advantageously, the applicator is made of a cellular material elastically deformable, with open cells, for example a foam or a sponge.

Dans une réalisation particulière, l'élément formant réservoir intermédiaire comporte une coupelle concave vers l'applicateur, afin de retenir une certaine quantité de produit lorsque le dispositif est retourné puis ramené tête en haut.In a particular embodiment, the element forming an intermediate reservoir has a concave cup towards the applicator, in order to retain a certain amount of product when the device is turned over and then brought upside down.

Toujours dans une réalisation particulière, l'élément formant réservoir intermédiaire comporte des cloisons tendant à s'opposer au retour du produit retenu par l'élément formant réservoir intermédiaire vers le fond du récipient lorsque le dispositif est basculé par rapport à la verticale depuis une position initiale tête en haut.Still in a particular embodiment, the reservoir element intermediate has partitions tending to oppose the return of the product retained by the intermediate reservoir element towards the bottom of the container when the device is tilted relative to the vertical from an initial head-up position.

Ces cloisons sont avantageusement cylindriques, de même axe que le récipient.These partitions are advantageously cylindrical, with the same axis as the container.

En variante, les cloisons sont pourvues de passages permettant au produit de s'écouler entre elles.Alternatively, the partitions are provided with passages allowing the product to flow between them.

La répartition du produit dans l'élément formant réservoir intermédiaire peut ainsi être plus homogène.The distribution of the product in the intermediate reservoir element can thus be more homogeneous.

Dans une réalisation particulière, l'applicateur comporte une face extérieure ayant une forme de dôme et une face intérieure définissant un renfoncement dans lequel l'élément formant réservoir intermédiaire est au moins partiellement engagé. In a particular embodiment, the applicator has an outer face having a dome shape and an inner face defining a recess in which the intermediate reservoir element is at least partially engaged.

Ainsi, une faible déformation de l'applicateur au moment de l'utilisation suffit pour que le produit retenu dans l'élément formant réservoir intermédiaire vienne au contact de l'applicateur.Thus, a slight deformation of the applicator at the time of use is sufficient so that the product retained in the intermediate reservoir element comes to the contact of the applicator.

Dans une réalisation particulière, l'applicateur est assujetti à sa périphérie à une pièce de support réalisée dans un matériau non alvéolaire, par exemple une matière plastique semi-rigide.In a particular embodiment, the applicator is subjected at its periphery to a support piece made of a non-cellular material, for example a material semi-rigid plastic.

Cette pièce de support contribue à faciliter le montage de l'applicateur et son remplacement, le cas échéant.This support piece helps to facilitate the mounting of the applicator and its replacement, if applicable.

Dans une réalisation particulière, le récipient comporte un corps inférieur et une partie supérieure servant au montage d'un capot de fermeture, constituée par une pièce rapportée sur ce corps.In a particular embodiment, the container has a lower body and an upper part used for mounting a closure cover, constituted by a patch on this body.

Le corps inférieur est de préférence réalisé dans une matière plastique rigide, pour des raisons esthétiques.The lower body is preferably made of a rigid plastic material, for aesthetic reasons.

Dans une réalisation particulière, la partie supérieure du récipient comporte un col sur lequel se visse le capot de fermeture.In a particular embodiment, the upper part of the container has a neck on which the closing cover is screwed.

Toujours dans une réalisation particulière, la partie supérieure du récipient comporte des moyens de fixation aptes à coopérer par encliquetage avec la pièce de support de l'applicateur.Still in a particular embodiment, the upper part of the container comprises fixing means capable of cooperating by snap-fastening with the piece of applicator support.

Avantageusement, cette dernière comporte deux pattes de fixation diamétralement opposées et agencées pour permettre, en étant pressées vers l'intérieur, de désolidariser l'applicateur du récipient, afin de procéder à son nettoyage ou à son remplacement par exemple.Advantageously, the latter comprises two fixing lugs diametrically opposite and arranged to allow, by being pressed inwards, to separate the applicator from the container, in order to clean it or replacement for example.

L'élément formant réservoir intermédiaire et le reste de la partie supérieure du récipient sont avantageusement réalisés d'un seul tenant par moulage de matière plastique.The intermediate reservoir element and the rest of the upper part of the container are advantageously made in one piece by molding of material plastic.

Dans une réalisation particulière, l'élément formant réservoir intermédiaire est supporté par une paroi ajourée comportant des passages latéraux permettant au produit contenu dans le récipient de gagner l'espace compris entre l'élément formant réservoir intermédiaire et la face intérieure de l'applicateur lorsque le récipient est retourné.In a particular embodiment, the element forming an intermediate reservoir is supported by an openwork wall having lateral passages allowing the product contained in the container to gain the space between the tank member intermediate and the inner face of the applicator when the container is inverted.

Avantageusement, la paroi ajourée précitée se raccorde à l'élément formant réservoir intermédiaire sans former d'arête saillante.Advantageously, the aforementioned perforated wall is connected to the element forming intermediate tank without forming a projecting edge.

On réduit ainsi le risque d'endommagement de l'applicateur au cours de l'utilisation, lorsque celui-ci est pressé contre l'élément formant réservoir intermédiaire.This reduces the risk of damage to the applicator during use, when the latter is pressed against the intermediate reservoir element.

La région de la face intérieure de l'applicateur directement en regard de l'élément formant réservoir intermédiaire peut être plane ou convexe vers ce dernier, de manière à faciliter le contact de l'applicateur avec le produit retenu dans l'élément formant réservoir intermédiaire.The region of the inner face of the applicator directly opposite the element forming the intermediate reservoir can be planar or convex towards the latter, so as to facilitate the contact of the applicator with the product retained in the element forming an intermediate reservoir.

Dans une variante de réalisation, l'applicateur occupe sensiblement tout le volume intérieur de l'élément formant réservoir intermédiaire, ledit volume intérieur étant celui dans lequel peut s'accumuler le produit retenu par l'élément formant réservoir intermédiaire.In an alternative embodiment, the applicator occupies substantially all of the interior volume of the intermediate reservoir element, said interior volume being that in which the product retained by the reservoir element can accumulate intermediate.

Dans une réalisation particulière, l'élément formant réservoir comporte une paroi rigide.In a particular embodiment, the reservoir element comprises a rigid wall.

L'invention a encore pour objet l'utilisation d'un dispositif de conditionnement et d'application tel que défini plus haut, pour appliquer sur le corps un produit cosmétique ou de soin.Another subject of the invention is the use of a packaging device and application as defined above, to apply a product to the body cosmetic or skincare.

L'invention sera mieux comprise à la lecture de la description détaillée qui va suivre, d'exemples de réalisation non limitatifs, et à l'examen du dessin annexé sur lequel :

  • la figure 1 est une vue schématique en coupe axiale d'un dispositif de conditionnement et d'application conforme à l'invention,
  • la figure 2 représente le dispositif de la figure 1 après enlèvement du capot de fermeture et retournement du récipient pour imbiber l'applicateur,
  • la figure 3 illustre la rétention du produit par l'élément formant réservoir intermédiaire lorsque le récipient est basculé,
  • les figures 4 et 5 représentent le dispositif dans certaines conditions d'utilisation,
  • la figure 6 est une vue analogue à la figure 5 illustrant une variante de réalisation,
  • la figure 7 est une vue de dessus d'une variante de réalisation de l'élément formant réservoir intermédiaire, et
  • la figure 8 est une vue analogue à la figure 5 d'une autre variante de réalisation.
The invention will be better understood on reading the detailed description which follows, of nonlimiting exemplary embodiments, and on examining the appended drawing in which:
  • FIG. 1 is a schematic view in axial section of a packaging and application device according to the invention,
  • FIG. 2 represents the device of FIG. 1 after removing the closure cover and inverting the container to soak the applicator,
  • FIG. 3 illustrates the retention of the product by the element forming an intermediate reservoir when the container is tilted,
  • FIGS. 4 and 5 represent the device under certain conditions of use,
  • FIG. 6 is a view similar to FIG. 5 illustrating an alternative embodiment,
  • FIG. 7 is a top view of an alternative embodiment of the element forming an intermediate reservoir, and
  • Figure 8 is a view similar to Figure 5 of another alternative embodiment.

Le dispositif de conditionnement et d'application 1 représenté sur les figures comporte un récipient 2 formé par l'assemblage d'un corps inférieur 3 et d'une partie supérieure 4, tous deux réalisés dans une matière plastique rigide.The packaging and application device 1 shown in the figures comprises a container 2 formed by the assembly of a lower body 3 and a part upper 4, both made of rigid plastic.

Le corps inférieur 3 comporte une paroi latérale cylindrique de révolution d'axe X, prolongée vers le haut par un col 5 d'axe X pourvu extérieurement d'un bourrelet annulaire 6.The lower body 3 has a cylindrical lateral wall of axis revolution X, extended upwards by a collar 5 of axis X externally provided with a bead ring finger 6.

La partie supérieure 4 comporte un col 7 fileté extérieurement, destiné à recevoir un capot de fermeture 8.The upper part 4 has an externally threaded neck 7, intended for receive a closing cover 8.

Le col 7 est prolongé inférieurement par des pattes de fixation 9 conformées pour s'encliqueter sur le bourrelet annulaire 6.The neck 7 is extended below by shaped fixing lugs 9 to snap onto the annular bead 6.

La partie supérieure 4 comporte également une jupe extérieure 10 entourant les pattes de fixation 9 et venant se positionner dans le prolongement de la paroi latérale du corps 3 et une lèvre annulaire d'étanchéité 11 venant s'appliquer de manière étanche sur la surface radialement intérieure 13 du col 5.The upper part 4 also includes an outer skirt 10 surrounding the fixing lugs 9 and coming to be positioned in the extension of the side wall of the body 3 and an annular sealing lip 11 which is applied in a sealed manner on the radially inner surface 13 of the neck 5.

La partie supérieure 4 du récipient comporte encore une paroi étagée 14 qui s'étend globalement perpendiculairement à l'axe X, radialement vers l'intérieur, et qui sert de support à un élément formant réservoir intermédiaire 15 dont le rôle sera précisé plus loin.The upper part 4 of the container also has a stepped wall 14 which extends generally perpendicular to the X axis, radially inward, and which serves as a support for an element forming an intermediate reservoir 15 whose role will be specified further.

La paroi étagée 14 comporte une première partie annulaire 17 qui se raccorde à la base du col fileté 7 et qui sert de support à une jupe de montage 19 symétrique de révolution autour de l'axe X et dirigée vers le haut, cette jupe de montage 19 étant pourvue sur sa surface radialement intérieure d'une gorge annulaire 20 au voisinage de son extrémité supérieure.The stepped wall 14 has a first annular part 17 which is connected to the base of the threaded neck 7 and which serves to support a symmetrical mounting skirt 19 of revolution around the X axis and directed upwards, this mounting skirt 19 being provided on its radially inner surface with an annular groove 20 in the vicinity of its upper end.

La première partie annulaire 17 est prolongée vers l'intérieur par une deuxième partie annulaire 21 s'étendant parallèlement à l'axe X au niveau de son raccordement à la première partie annulaire 17 pour former une gorge annulaire 60 puis perpendiculairement à l'axe X.The first annular part 17 is extended inward by a second annular part 21 extending parallel to the axis X at its connection to the first annular part 17 to form an annular groove 60 then perpendicular to the X axis.

L'élément formant réservoir intermédiaire 15 se raccorde à la deuxième partie annulaire 21 par une paroi incurvée 23 pourvue d'ouvertures 24, au nombre de quatre dans l'exemple de réalisation décrit, ces ouvertures 24 étant équiréparties autour de l'axe X.The intermediate reservoir element 15 is connected to the second part annular 21 by a curved wall 23 provided with openings 24, four in number in the embodiment described, these openings 24 being equally distributed around the axis X.

Le récipient 2 est rempli d'un produit P, cosmétique ou de soin.The container 2 is filled with a product P, cosmetic or care.

Le capot de fermeture 8 comporte une lèvre annulaire d'étanchéité 26 qui s'applique de manière étanche sur la surface radialement intérieure du col 7, comme on peut le voir sur la figure 1.The closure cover 8 has an annular sealing lip 26 which applies tightly to the radially inner surface of the neck 7, as can see it in figure 1.

Le dispositif de conditionnement et d'application 1 comporte un applicateur 30 réalisé dans un matériau alvéolaire en matière plastique à cellules ouvertes tel que par exemple une mousse ou une éponge.The packaging and application device 1 comprises an applicator 30 made of an open cell plastic foam material such as by example a foam or a sponge.

L'applicateur 30 est assujetti sur sa périphérie à une pièce annulaire de support 31 réalisée dans une matière plastique rigide ou semi-rigide.The applicator 30 is fixed on its periphery to an annular support piece 31 made of a rigid or semi-rigid plastic material.

Cette pièce de support 31 comporte une paroi de base 32 qui vient en appui sur la deuxième partie annulaire 21 de la paroi étagée 14.This support piece 31 has a base wall 32 which bears on the second annular part 21 of the stepped wall 14.

La paroi de base 32 se raccorde à sa périphérie extérieure d'une part à une lèvre annulaire d'étanchéité 33 qui s'étend vers le bas et s'applique de manière étanche sur la surface radialement intérieure de la jupe de montage 19 sous la gorge annulaire 20 et d'autre part à deux pattes de fixation 34 diamétralement opposées s'étendant vers le haut dans le prolongement de la lèvre annulaire d'étanchéité 33.The base wall 32 is connected at its outer periphery on the one hand to a lip sealing ring 33 which extends downwards and is applied in a sealed manner to the radially inner surface of the mounting skirt 19 under the annular groove 20 and on the other hand with two diametrically opposite fixing lugs 34 extending upwards in the extension of the annular sealing lip 33.

Les pattes de fixation 34 sont munies chacune d'un bossage 35 venant s'encliqueter dans la gorge annulaire 20 de la jupe de montage 19.The fixing lugs 34 are each provided with a boss 35 coming from snap into the annular groove 20 of the mounting skirt 19.

On notera que dans l'exemple de réalisation décrit, l'applicateur 30 ne repose pas directement sur la paroi de base 32 mais est fixé par sa tranche d'extrémité inférieure sur des nervures 37, annulaires, formant saillie vers le haut sur la paroi de base 32, étant fixé sur les nervures 37 par tout moyen connu, par exemple par soudure ou collage.It will be noted that in the embodiment described, the applicator 30 does not rest not directly on the base wall 32 but is fixed by its end edge lower on ribs 37, annular, projecting upwards on the wall of base 32, being fixed on the ribs 37 by any known means, for example by welding or collage.

L'applicateur 30 présente au repos une face extérieure 40 en forme de dôme et une face intérieure 41 comportant une région centrale 42 faisant directement face dans l'axe X à l'élément formant réservoir intermédiaire 15, plane et perpendiculaire à l'axe X, et une région périphérique 43 arrondie, concave vers le récipient, de plus grand rayon de courbure que la paroi incurvée 23.The applicator 30 has at rest an outer face 40 in the form of a dome and an inner face 41 comprising a central region 42 directly facing in the axis X to the intermediate reservoir element 15, planar and perpendicular to the axis X, and a rounded peripheral region 43, concave towards the container, of larger radius of curvature than the curved wall 23.

L'élément formant réservoir intermédiaire 15 comporte une coupelle 45 concave vers l'applicateur 30, cette coupelle 45 se raccordant à la paroi incurvée 23 par son bord périphérique 55 sans former d'arête saillante et supportant, dans l'exemple de réalisation décrit, deux cloisons 47 et 48, cylindriques de révolution autour de l'axe X.The intermediate reservoir element 15 comprises a cup 45 concave towards the applicator 30, this cup 45 connecting to the curved wall 23 by its peripheral edge 55 without forming a projecting edge and supporting, in the example of realization described, two partitions 47 and 48, cylindrical of revolution around the axis X.

Les cloisons 47 et 48 présentent une hauteur choisie de telle sorte que leur extrémité supérieure se situe sensiblement dans un même plan que le bord périphérique 55 de la coupelle 45, ce plan étant perpendiculaire à l'axe X.The partitions 47 and 48 have a height chosen so that their upper end lies substantially in the same plane as the peripheral edge 55 of the cup 45, this plane being perpendicular to the axis X.

Dans l'exemple de réalisation décrit, tous les éléments constitutifs de la partie supérieure du récipient 4 sont réalisés d'un seul tenant par moulage de matière plastique.In the example of embodiment described, all the constituent elements of the part upper of the container 4 are made in one piece by plastic molding.

Le dispositif 1 s'utilise de la manière suivante.The device 1 is used in the following manner.

Le capot de fermeture 6 étant retiré, l'utilisateur bascule le récipient 2 dans une position tête en bas, comme illustré sur la figure 2, pour imbiber l'applicateur 30 de produit P.With the closure cover 6 removed, the user tilts the container 2 into a upside down position, as illustrated in Figure 2, to soak the applicator 30 with product P.

Le produit P gagne en traversant les ouvertures 24 l'espace 50 compris entre l'élément formant réservoir intermédiaire 15 et la face intérieure 41 de l'applicateur et diffuse à partir de cette dernière vers la surface extérieure 40, par capillarité et/ou gravité à travers le matériau poreux constituant l'applicateur 30.The product P gains by crossing the openings 24 the space 50 between the intermediate reservoir element 15 and the inner face 41 of the applicator and diffuses from the latter towards the external surface 40, by capillarity and / or gravity through the porous material constituting the applicator 30.

Lorsque le récipient 2 est ramené dans une position tête en haut comme illustré sur la figure 3, le produit P regagne le fond du corps 3 du récipient à l'exception de la quantité qui est retenue par l'élément formant réservoir intermédiaire 15.When container 2 is returned to a head-up position as shown in FIG. 3, the product P returns to the bottom of the body 3 of the container with the exception of the quantity which is retained by the intermediate reservoir element 15.

Les cloisons 47 et 48 participent à la rétention du produit dans l'élément formant réservoir intermédiaire 15.The partitions 47 and 48 participate in the retention of the product in the element forming an intermediate reservoir 15.

Le volume de la quantité de produit retenue dans l'élément formant réservoir intermédiaire est par exemple compris entre 0,5 et 3 cm3.The volume of the quantity of product retained in the intermediate reservoir element is for example between 0.5 and 3 cm 3 .

L'applicateur 30 imprégné de produit P peut alors être déplacé sur la peau S comme illustré sur la figure 4, l'axe X pouvant prendre diverses orientations et notamment être horizontal ou sensiblement horizontal.The applicator 30 impregnated with product P can then be moved on the skin S as illustrated in FIG. 4, the X axis being able to take various orientations and in particular be horizontal or substantially horizontal.

Le produit P contenu dans l'applicateur 30 se dépose sur la peau S lors du déplacement du dispositif 1.The product P contained in the applicator 30 is deposited on the skin S during the moving the device 1.

La pression exercée lors de l'utilisation sur l'applicateur 30 par la peau S a pour effet de déformer ce dernier et d'amener sa surface intérieure 41 au contact de l'élément formant réservoir intermédiaire 15, comme on peut le voir sur la figure 4.The pressure exerted during use on the applicator 30 by the skin S has for effect of deforming the latter and bringing its inner surface 41 into contact with the element forming an intermediate reservoir 15, as can be seen in FIG. 4.

Il en résulte que le produit P retenu par l'élément formant réservoir intermédiaire 15 peut diffuser par capillarité et/ou gravité dans l'applicateur 30 et ainsi accroítre son autonomie.It follows that the product P retained by the reservoir element intermediate 15 can diffuse by capillarity and / or gravity in the applicator 30 and thus increase their autonomy.

On remarquera également que par le fait que l'élément formant réservoir intermédiaire 15 est pratiquement engagé en totalité dans le renfoncement défini par la face intérieure 41 de l'applicateur 30, une faible pression sur l'applicateur 30 est suffisante pour amener sa face intérieure 41 au contact du bord périphérique 55 de la coupelle 45, ce qui empêche le produit retenu dans la coupelle 45 de s'écouler par les ouvertures 24 et de retourner dans le fond du récipient 2.It will also be noted that by the fact that the reservoir element intermediate 15 is practically fully engaged in the recess defined by the inner face 41 of the applicator 30, a slight pressure on the applicator 30 is sufficient to bring its inner face 41 into contact with the peripheral edge 55 of the cup 45, which prevents the product retained in the cup 45 from flowing through the openings 24 and return to the bottom of the container 2.

Le produit est ainsi obligé de diffuser dans l'applicateur 30.The product is thus forced to diffuse into the applicator 30.

La venue en appui de la face intérieure 41 sur les cloisons 47 et 48 force de manière similaire le produit P à s'écouler dans l'applicateur 30 plutôt que de regagner le fond du récipient.The coming into abutment of the inner face 41 on the partitions 47 and 48 force of similarly the product P to flow into the applicator 30 rather than returning to the bottom of container.

On remarquera à l'examen de la figure 4 que le rayon de courbure de la région périphérique 43 de la face intérieure 41 de l'applicateur 30 est choisi de telle sorte que lorsque l'applicateur 30 vient en appui sur les cloisons 47 et 48 et le bord périphérique 55 de la coupelle 45, la région périphérique 43 s'étend sensiblement parallèlement à la paroi incurvée 23.It will be noted on examining FIG. 4 that the radius of curvature of the region peripheral 43 of the inner face 41 of the applicator 30 is chosen so that when the applicator 30 comes to bear on the partitions 47 and 48 and the peripheral edge 55 of the cup 45, the peripheral region 43 extends substantially parallel to the curved wall 23.

On remarquera également à l'examen de la figure 4 que l'élément formant réservoir intermédiaire 15 permet d'alimenter l'applicateur 30 grâce au produit retenu à l'intérieur de la coupelle 45 lorsque le niveau N du produit est insuffisant pour que celui-ci alimente l'applicateur 30 directement au travers des ouvertures 24.It will also be noted on examining FIG. 4 that the element forming intermediate reservoir 15 enables the applicator 30 to be supplied with the product retained at inside the cup 45 when the level N of the product is insufficient for this feeds the applicator 30 directly through the openings 24.

On a représenté sur la figure 5 le récipient 2 utilisé tête en haut, l'élément formant réservoir intermédiaire 15 étant pratiquement rempli en totalité.There is shown in Figure 5 the container 2 used head up, the element forming intermediate reservoir 15 being almost completely filled.

On comprend à l'examen de cette figure que l'invention permet d'accroítre l'autonomie de l'applicateur 30, puisque sous la pression exercée sur ce dernier au moment de l'application sur la peau S, la face intérieure 41 peut venir au contact du produit retenu dans l'élément formant réservoir intermédiaire 15. L'applicateur 30 est alors alimenté par capillarité.It will be understood on examining this figure that the invention makes it possible to increase the autonomy of the applicator 30, since under the pressure exerted on the latter at at the time of application to the skin S, the inner face 41 can come into contact with the product retained in the element forming the intermediate reservoir 15. The applicator 30 is then powered by capillary action.

En outre, lorsque la quantité de produit dans l'élément formant réservoir intermédiaire 15 est suffisante, l'applicateur 30 tend en pénétrant entre les cloisons 47 et 48 à comprimer le produit P contenu dans l'élément formant réservoir intermédiaire qui se trouve ainsi chassé dans l'applicateur 30.In addition, when the amount of product in the reservoir member intermediate 15 is sufficient, the applicator 30 tends to penetrate between the partitions 47 and 48 to compress the product P contained in the intermediate reservoir element which is thus driven into the applicator 30.

L'applicateur peut être aisément séparé de la partie supérieure 4 du récipient 2 en déformant les pattes de fixation 34 vers l'intérieur, ce qui permet de désengager les bossages 35 de la gorge annulaire 20 de la jupe de montage 19.The applicator can be easily separated from the upper part 4 of the container 2 by deforming the fixing lugs 34 inwards, which makes it possible to disengage the bosses 35 of the annular groove 20 of the mounting skirt 19.

Bien entendu, l'invention n'est pas limitée à l'exemple de réalisation qui vient d'être d'écrit. Of course, the invention is not limited to the embodiment which comes to be written.

On a représenté sur la figure 6 une variante de réalisation qui diffère du dispositif précédemment décrit par le fait que l'élément formant réservoir intermédiaire 15 est remplacé par un élément formant réservoir intermédiaire 15' qui ne comporte plus les cloisons 47 et 48.FIG. 6 shows an alternative embodiment which differs from the device previously described by the fact that the element forming an intermediate reservoir 15 is replaced by an intermediate reservoir element 15 'which no longer comprises partitions 47 and 48.

Le dispositif est identique pour le restant.The device is identical for the rest.

L'absence des cloisons 47 et 48 permet à l'applicateur de s'enfoncer davantage dans l'élément formant réservoir intermédiaire 15' au cours de l'utilisation.The absence of partitions 47 and 48 allows the applicator to sink further in the intermediate reservoir element 15 'during use.

On a illustré sur la figure 7 une variante dans laquelle les cloisons 47 et 48 sont remplacées par des cloisons 47' et 48' pourvues de passages 62 qui permettent au produit de circuler entre les anneaux formés par les cloisons 47' et 48'. La répartition du produit est ainsi plus homogène dans l'élément formant réservoir intermédiaire.A variant has been illustrated in FIG. 7 in which the partitions 47 and 48 are replaced by partitions 47 'and 48' provided with passages 62 which allow the product to circulate between the rings formed by the partitions 47 'and 48'. The distribution of product is thus more homogeneous in the element forming the intermediate reservoir.

Les cloisons 47' et 48' constituent des portées contre lesquelles l'applicateur vient en appui au moment de l'utilisation.The partitions 47 'and 48' constitute staves against which the applicator comes to bear at the time of use.

Le dispositif représenté sur la figure 8 diffère de celui représenté sur la figure 6 par le fait que l'applicateur 30 est remplacé par un applicateur 30' comportant une partie centrale 64 qui épouse la forme de la concavité de l'élément formant réservoir intermédiaire 15'.The device shown in Figure 8 differs from that shown in Figure 6 by the fact that the applicator 30 is replaced by an applicator 30 'comprising a part central unit 64 which follows the shape of the concavity of the reservoir element intermediate 15 '.

Autrement dit, le matériau alvéolaire constituant l'applicateur 30' occupe tout le volume intérieur de l'élément formant réservoir intermédiaire 15'.In other words, the cellular material constituting the applicator 30 'occupies all of the internal volume of the intermediate reservoir element 15 '.

Le produit s'accumule dans l'élément formant réservoir intermédiaire 15' au sein du matériau alvéolaire constituant l'applicateur 30'.The product accumulates in the intermediate reservoir element 15 'at within the cellular material constituting the applicator 30 '.

On peut encore réaliser, dans des variantes non illustrées, l'applicateur avec un revêtement destiné à accroítre le confort d'utilisation, par exemple un flocage.It is also possible, in variants not illustrated, to apply the applicator with coating intended to increase the comfort of use, for example a flocking.

On peut utiliser, pour constituer l'applicateur, tout matériau agencé pour permettre le passage du produit par capillarité et/ou gravité.One can use, to constitute the applicator, any material arranged for allow the product to pass by capillarity and / or gravity.

On peut réaliser l'élément formant réservoir intermédiaire avec une forme ou une structure différente.The element forming the intermediate reservoir can be produced with a shape or a different structure.

Claims (22)

  1. A device (1) for packaging and applying a substance (P), in particular a cosmetic or a care product, the device comprising a receptacle (2) for containing the substance, said receptacle being provided at the top with an applicator (30) that is permeable to the substance and that has an inside face (41) fed with the substance coming from the receptacle, the device comprising an element that forms an intermediate reservoir (15), in the vicinity of the bottom face (41) of the applicator (30), the device being characterized by the fact that the intermediate reservoir is in permanent communication with the receptacle and is suitable for retaining a certain quantity of the substance when the device is turned upside-down from a head-up position and is then returned to the head-up position, said intermediate reservoir-forming element (15) also being arranged to enable the substance retained in this way to feed the applicator, at least in certain conditions of use of the device.
  2. A device according to the preceding claim, characterized by the fact that the intermediate reservoir-forming element (15) and the applicator (30) are arranged in such a manner that, in use, the applicator comes into contact with the substance (P) retained by the intermediate reservoir-forming element (15) when sufficient pressure is exerted on the applicator.
  3. A device according to either preceding claim, characterized by the fact that the applicator (30) is made of an open-celled, elastically deformable, cellular material.
  4. A device according to any preceding claim, characterized by the fact that the intermediate reservoir-forming element includes a cup (45) which is concave towards the applicator.
  5. A device according to any preceding claim, characterized by the fact that the intermediate reservoir-forming element (15) includes partitions (47, 48) tending to oppose return of the substance retained by the intermediate reservoir-forming element to the bottom of the receptacle when the device is tilted relative to the vertical from an initial head-up position.
  6. A device according to the preceding claim, characterized by the fact that said partitions (47, 48) are cylindrical, about the same axis (X) as the receptacle (2).
  7. A device according to any preceding claim, characterized by the fact that the intermediate reservoir-forming element has partitions (47', 48') provided with gaps enabling the substance to flow between them.
  8. A device according to any preceding claim, characterized by the fact that the applicator has an outside face (40) of dome shape, and by the fact that the inside face (41) defines a recess into which the intermediate reservoir-forming element (15) is engaged, at least in part.
  9. A device cording to any preceding claim, characterized by the fact that the applicator (30) is secured at its periphery to a support piece (31) made of non-cellular material.
  10. A device according to any preceding claim, characterized by the fact that the receptacle has a bottom body (3) and a top portion (4) for receiving a closure cap (8), said top portion (4) being constituted by a piece fitted on the body (3).
  11. A device according to either one of the two preceding claims, characterized by the fact that the top portion (4) of the receptacle (2) includes fastening means (19, 20) suitable for co-operating with the support piece (31) of the applicator by snap-fastening.
  12. A device according to the preceding claim, characterized by the fact that the support piece of the applicator (31) has two fastening tabs (34) that are diametrically opposite and arranged when pressed inwards to enable the applicator (30) to be separated from the receptacle (2).
  13. A device according to any one of the three preceding claims, characterized by the fact that the bottom body (3) is made of a rigid plastics material.
  14. A device according to any one of the four preceding claims, characterized by the fact that the top portion (4) of the receptacle has a neck (7) onto which the closure cap (8) is screwed.
  15. A device according to any one of the five preceding claims, characterized by the fact that the intermediate reservoir-forming element (15) and the remainder of the top portion of the receptacle (4) are made as a single piece.
  16. A device according to any preceding claim, characterized by the fact that the intermediate reservoir-forming element (15) is supported by a perforated wall (23) having lateral passages (24) allowing the substance (P) contained in the receptacle (2) to reach the space (50) lying between the intermediate reservoir-forming element (15) and the bottom face (41) of the applicator (30) when the receptacle (2) is turned upside-down.
  17. A device according to the preceding claim, characterized by the fact that the perforated wall (23) is connected to the intermediate reservoir-forming element (15) without forming a projecting edge.
  18. A device according to any preceding claim, characterized by the fact that the region (42) of the bottom face (41) of the applicator that is directly in register with the intermediate reservoir-forming element (15) is plane or convex towards said element.
  19. A device according to any preceding claim, characterized by the fact that the applicator (30') occupies substantially the entire inside volume of the intermediate reservoir-forming element, said inside volume being that in which the substance retained by the intermediate reservoir-forming element can accumulate.
  20. A device according to any preceding claim, characterized by the fact that the receptacle (2) contains a liquid.
  21. A device according to any preceding claim, characterized by the fact that the reservoir-forming element has a rigid wall (45).
  22. The use of a device as defined in any preceding claim to apply a substance constituted by a cosmetic or a care product to the body.
EP01400400A 2000-02-16 2001-02-15 Device for storing and applying comprising an intermediate storage element Expired - Lifetime EP1125517B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0001901 2000-02-16
FR0001901A FR2804845B1 (en) 2000-02-16 2000-02-16 PACKAGING AND APPLICATION DEVICE COMPRISING AN ELEMENT FORMING AN INTERMEDIATE RESERVOIR

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EP1125517A1 EP1125517A1 (en) 2001-08-22
EP1125517B1 true EP1125517B1 (en) 2004-09-15

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US (1) US6773193B2 (en)
EP (1) EP1125517B1 (en)
JP (1) JP3656035B2 (en)
CN (1) CN1184110C (en)
AR (1) AR028506A1 (en)
AT (1) ATE275843T1 (en)
BR (1) BR0100563B1 (en)
CA (1) CA2337184C (en)
DE (1) DE60105459T2 (en)
ES (1) ES2227079T3 (en)
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FR2804845B1 (en) 2002-04-26
US6773193B2 (en) 2004-08-10
CN1184110C (en) 2005-01-12
DE60105459D1 (en) 2004-10-21
MXPA01001427A (en) 2002-06-04
US20010031171A1 (en) 2001-10-18
DE60105459T2 (en) 2005-09-29
JP3656035B2 (en) 2005-06-02
CA2337184C (en) 2005-06-07
BR0100563B1 (en) 2010-02-09
ATE275843T1 (en) 2004-10-15
AR028506A1 (en) 2003-05-14
ES2227079T3 (en) 2005-04-01
CN1309068A (en) 2001-08-22
FR2804845A1 (en) 2001-08-17
EP1125517A1 (en) 2001-08-22
CA2337184A1 (en) 2001-08-16
BR0100563A (en) 2001-09-11
JP2001269221A (en) 2001-10-02

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