EP1074790B1 - Burner with exhaust recirculation - Google Patents

Burner with exhaust recirculation Download PDF

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Publication number
EP1074790B1
EP1074790B1 EP00430026A EP00430026A EP1074790B1 EP 1074790 B1 EP1074790 B1 EP 1074790B1 EP 00430026 A EP00430026 A EP 00430026A EP 00430026 A EP00430026 A EP 00430026A EP 1074790 B1 EP1074790 B1 EP 1074790B1
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EP
European Patent Office
Prior art keywords
duct
burner
ducts
air
fuel
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EP00430026A
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German (de)
French (fr)
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EP1074790A1 (en
Inventor
Jean-Claude Gauthier
Frédéric Bury
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Entreprise Generale de Chauffage Industriel Pillard SA
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Entreprise Generale de Chauffage Industriel Pillard SA
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D17/00Burners for combustion conjointly or alternatively of gaseous or liquid or pulverulent fuel
    • F23D17/002Burners for combustion conjointly or alternatively of gaseous or liquid or pulverulent fuel gaseous or liquid fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C9/00Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
    • F23C9/08Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for reducing temperature in combustion chamber, e.g. for protecting walls of combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/46Details, e.g. noise reduction means
    • F23D14/72Safety devices, e.g. operative in case of failure of gas supply
    • F23D14/78Cooling burner parts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2202/00Fluegas recirculation
    • F23C2202/20Premixing fluegas with fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2202/00Fluegas recirculation
    • F23C2202/40Inducing local whirls around flame

Definitions

  • the present invention relates to improvements made industrial burners with liquid or gaseous fuel.
  • the technical field of the invention is the field of manufacture industrial burners.
  • the present invention more particularly relates to improvements in low-emission gaseous fuel burners nitrogen oxide having primary gas injection means fuel arranged in the center of the burner and injection means secondary devices, and intended to be mounted either in an orifice intended for that in the wall of an enclosure, such as the chamber of combustion or hearth of a furnace or boiler, that is, in the central part of a turbine exhaust gas flow duct of a installation of co-generation of electrical and thermal energy, in order to warm up these exhaust gases.
  • the present invention has more particularly concerned a burner in which combines the two above methods of flue gas recirculation, on the one hand, and staging of the fuel supply, on the other hand.
  • US Pat. No. 5,284,438 describes a burner of similar structure but more complex, in which the burner block delimits a convergent and a divergent separated by a constriction, and includes conduits fumes extraction by fuel jets which, by their dimensions, their flared shape at the entrance, their inclined position and their exit located in the divergent from the block, are supposed to ensure a defined dosage of the mixture fuel - fumes and its injection into a mixing zone with air, which is situated in the divergent;
  • this burner comprises a central duct injection nozzle equipped with a nozzle, and a stabilizer of flame ;
  • this structure causes the formation of jets (of a mixture fuel - smoke) turbulent and swirling, and causes them to mixing with the air in the mixing zones delimited by the block.
  • EP 675 321 discloses a gaseous fuel burner which has several primary fuel injection rods arranged in the central part of an air duct delimited by the body tubular burner; the ends of the rods are bent outwards, arranged under the slots of a flame stabilizer, and the ends of rods are pierced with holes through which fuel gas is injected in the focus through the slits of the stabilizer; the burner has in in addition to (secondary) gaseous fuel injection rods, which are distributed around the primary injection rods, and which end with a single nozzle each opening into a recirculation duct smoke produced in the home; these secondary injection canes, as well that the associated recirculation ducts, are located inside the canal of air, to ensure their cooling by the air circulating there.
  • Each recirculation duct opens into the firebox in parallel to the air channel, and communicates at its other end with the hearth by a orifice pierced in the wall of the air channel, at the outer periphery of the burner; these orifices allow, by suction effect and drive, to recirculate the fumes that mix with the gas fuel and reduce the formation of nitrogen oxides; to complete this reduction by increasing the staging of combustion, the burner includes (tertiary) fuel injection rods crossing the wall of the hearth enclosure; each cane is associated with a air intake channel surrounding the cane.
  • Patent EP 675 321 also describes a burner devoid of means tertiary fuel injection, whose performance is reduced.
  • the burner described in this document has certain disadvantages: the gaseous currents delivered by the rods and the air channels associated with these tertiary means of injection, are likely to form a curtain surrounding the secondary means of fuel gas injection, which is likely to disturb and limit the efficiency of the recirculation system smoke by secondary means for injecting gaseous fuel; a Another disadvantage is the difficulty of regulating and controlling the effect produced by the jets of air surrounding the gas jets of tertiary means injection, and in particular to control these coaxial jets and their mixture necessary for good combustion with other jets caused by this burner, which is equipped with three separate injection systems gaseous fuel and two separate transport and injection systems air in the burner (and hearth); in addition, a disadvantage related to canes extending through the walls delimiting the enclosure of the home, lies in the large size of this system and the difficulty of repairing it, maintain and / or modify such a system partially embedded in the wall of the hearth of the hearth.
  • An object of the present invention is to provide a burner improved and at least partially remedy the disadvantages of burners known while improving their performance in reducing the formation of nitrogen oxides.
  • An object of the present invention is in particular to improve the self-recirculation of fumes.
  • An object of the present invention is also to propose a compact burner, simple, inexpensive and likely to be used in a Turbine exhaust gas transport duct (s).
  • the invention consists in proposing a burner gaseous fuel which comprises a central transport duct fuel, a central air duct surrounding said duct central fuel, several gaseous fuel extending at least partly outside the duct central air transport, preferably parallel to it, and completed each by a fuel ejection nozzle;
  • the burner has in in addition to a rectilinear section of cylindrical conduit (or tube) of recirculation of fumes, which is arranged in the extension of each nozzle and at a distance (in front) thereof;
  • the air transport duct and the smoke extraction ducts are metallic, substantially parallel between them, and preferably open substantially in the same plane perpendicular to the longitudinal axis of the burner;
  • the suction ducts of The fumes are fixed on the metal body of the burner, preferably on the air transport duct, by a metal connection which contributes to ensure, by conduction, the cooling of the suction ducts by the burner body (especially by the air duct) which is itself cooled by the air it carries
  • each peripheral fuel nozzle from the inlet of the associated recirculation tube is preferably same order of magnitude as the radius or diameter of the pipe section of recirculation, for example of the order of 2 to 20 centimeters; thus, the space between the nozzle and the inlet (the upstream end) of the recirculation facilitates the extraction of fumes and the mixing of gas combustible with the fumes present in the hearth, delineating a passage section for smokes of significantly larger dimensions large than that defined by the peripheral opening of the tubes of recirculation described in EP 675 321; in addition, this provision allows and / or facilitates the adjustment, during assembly or the installation of the burner, this distance, which makes it possible to optimize suction, mixing and entrainment of fumes by gas jets combustible.
  • the cooling of Conducted flue gas recirculation ducts with the central duct air transport is sufficient to prevent deterioration of these ducts although these flues are located in the fireplace (and / or are subjected to intense heating by the direct radiation of the flame); preferably, for this purpose, the metal link serving as a heat sink extends over a large area, particularly substantially over the entire length of the recirculation ducts; this link is preferably obtained by welding.
  • the cooling of flue gas tubes can not be obtained by convection with a flow of air (relatively cold) as is the case in EP 675 321 and in the patent application FR 98/10350 filed August 7, 1998 by the Claimant; in this document indeed, peripheral nozzles of air injection are arranged nested with the peripheral nozzles fuel injection.
  • Said peripheral nozzles and the associated suction ducts are preferably identical, arranged equidistant from the axis longitudinal axis of the burner (that is to say on a circle) and in a symmetry of revolution (that is, angularly equidistant).
  • the peripheral gas injection nozzles fuel and the associated flue gas pipes are three to twelve, in particular six to eight, arranged in a crown, regularly (angularly) distributed around the longitudinal axis (of general symmetry) of the burner.
  • the invention consists of a gas heater turbine, which comprises a burner according to the invention which is mounted in the central part of a turbine gas transport duct which is equipped with partial closure shutters.
  • the external position of the smoke circulation tubes avoids disturbing the combustion of the fuel delivered in the central part.
  • FIG. 1 illustrates in longitudinal sectional view a burner with liquid and gaseous fuel according to the invention.
  • FIG. 2 is a front view of the front end of the burner of the Figure 1 and is a view along II of Figure 1.
  • FIG. 3 illustrates in longitudinal sectional view a heater of turbine outlet gas according to the invention.
  • the burner 1 (FIGS. 1 and 2) comprises a first ferrule cylindrical 2 longitudinal axis 3 horizontal, and a second ferrule cylindrical 4 coaxial with the first, which delimits a duct 5; the ferrule 2 defines a central duct 31 for air passage, which extends the duct 5 air inlet.
  • the burner extends through a cylindrical orifice 6 provided in the wall 7 separating the hearth 8 from the outside 9 of the enclosure.
  • the burner comprises in central part a central rod of transport of liquid fuel (in particular such as heavy fuel oil, diesel fuel, gasoline, oils, residual liquids ...) up to the equipped burner head a central nozzle 11 and a flame stabilizer 12, which are arranged at the front end of the duct 31 and the ferrule 2, and are salient at inside the fireplace 8; the burner further comprises a central rod 100 injection of gaseous fuel.
  • liquid fuel in particular such as heavy fuel oil, diesel fuel, gasoline, oils, residual liquids
  • the burner comprises a bundle of six peripheral tubes 13 of transport of fuel gas, which are each equipped at their end before a nozzle 14 arranged protruding (for example prominent 1 centimeter) to the inner face 15 of the wall 7.
  • the tubes 13 extends parallel to the axis 3 inside duct 5 for air transport; the tubes 13 are powered by a common collector 16, and pass through an annular flange 17 connecting ferrules 2 and 4; as illustrated in FIG. 2, the six identical nozzles 14 fuel gas ejection are angularly spaced 60 degrees.
  • the longitudinal axes 20 of the nozzles 14 which are parallel to the axis 3, are located on identical or neighboring rays.
  • the axis of the tubes 22 coincides with the axis of the nozzles 14 and the end rear 24 identical sections 22 is disposed at a distance 25 from the corresponding nozzle 14, which distance is close to 50 millimeters, and corresponding to the diameter of the tubes 22.
  • the front end 23 of the tubes 22 extends in the plane 112 containing the outlet orifice of the central duct 31.
  • the burner 1 is mounted in a duct 200, of axis coincides with the axis 3 of the burner, delimited by walls 201 (In the case where several burners are mounted in the duct 200, their axes 3 are parallel to that of the duct).
  • the pipe 200 carries (according to the arrows 103) gas leaving a turbine, whose temperature is of the order of 500 ° C or, when the turbine is stopped, air; in the latter case, shutters 104, which are pivotally mounted in the conduit 200 along axes 105, seal partially - in the position shown in solid lines - the section of passage of the duct 200 leaving the passage free - according to the arrows 102 - through the conduit 2 of the burner; the (open) position of the shutters shown in dashed lines corresponds to the case where the turbine gases are present.
  • the burner is fixed in the duct 200 by means represented.
  • peripheral ducts 13 are supplied with gas fuel by a second collector 16; the flow of gaseous fuel injected by the peripheral nozzles is generally of the order of 90 95% of the total fuel flow.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)

Description

La présente invention a pour objet des perfectionnements apportés aux brûleurs industriels à combustible liquide ou gazeux.The present invention relates to improvements made industrial burners with liquid or gaseous fuel.

Le secteur technique de l'invention est le domaine de la fabrication de brûleurs industriels.The technical field of the invention is the field of manufacture industrial burners.

La présente invention a plus particulièrement pour objet des perfectionnements de brûleurs à combustible gazeux à très faible émission d'oxyde d'azote comportant des moyens d'injection primaires de gaz combustible disposés au centre du brûleur et des moyens d'injection secondaires périphériques, et destinés à être montés soit dans un orifice prévu pour cela dans le mur d'une enceinte, telle que la chambre de combustion ou foyer d'un four ou d'une chaudière, soit en partie centrale d'un conduit de circulation de gaz d'échappement de turbine d'une installation de co-génération d'énergie électrique et thermique, afin de réchauffer ces gaz d'échappement.The present invention more particularly relates to improvements in low-emission gaseous fuel burners nitrogen oxide having primary gas injection means fuel arranged in the center of the burner and injection means secondary devices, and intended to be mounted either in an orifice intended for that in the wall of an enclosure, such as the chamber of combustion or hearth of a furnace or boiler, that is, in the central part of a turbine exhaust gas flow duct of a installation of co-generation of electrical and thermal energy, in order to warm up these exhaust gases.

Pour réduire la teneur en oxyde d'azote des fumées, il est connu de réduire la teneur en oxygène libre des gaz dans la flamme pour éviter une trop forte combinaison de celui-ci avec l'azote de l'air, et de limiter la température maximale de la flamme. Pour réduire la teneur en oxygène dans la flamme et pour réduire la température de flamme, une solution est de recycler une partie des fumées présentes dans le foyer : il est connu de réaliser cette recirculation au moyen de systèmes d'éjection qui utilisent la dépression créée par l'éjection du combustible.To reduce the nitrogen oxide content of the fumes, it is known to reduce the free oxygen content of the gases in the flame to avoid a too strong combination of it with the nitrogen of the air, and limit the maximum temperature of the flame. To reduce the oxygen content in the flame and to reduce the flame temperature, one solution is to to recycle some of the fumes present in the hearth: it is known to perform this recirculation by means of ejection systems that use the depression created by the ejection of the fuel.

Par ailleurs, il est connu que, pour limiter la température maximale de flamme, on peut étager la combustion, c'est-à-dire qu'au lieu de mettre en présence dans une seule zone la totalité du combustible et du comburant, on procède par étapes : soit on étage l'injection du comburant sans modifier l'injection du combustible, soit au contraire, on étage l'injection du combustible sans étager celle du comburant ; l'injection étagée de comburant provoque aussi une baisse de la teneur en oxygène libre, contrairement à l'injection étagée du seul combustible. Moreover, it is known that to limit the maximum temperature of flame, one can stagger the combustion, that is to say that instead of putting the presence in a single zone of all the fuel and oxidant, one proceeds in stages: either one stages the injection of the oxidizer without modifying the injection of the fuel, either on the contrary, one floor fuel injection without storing that of the oxidizer; injection staged oxidizer also causes a drop in oxygen content free, unlike staged injection of fuel alone.

La présente invention a plus particulièrement objet un brûleur dans lequel on combine les deux procédés ci-dessus de recirculation des fumées, d'une part, et d'étagement de l'alimentation de combustible, d'autre part.The present invention has more particularly concerned a burner in which combines the two above methods of flue gas recirculation, on the one hand, and staging of the fuel supply, on the other hand.

Le brevet US 5,073,105 décrit un brûleur monté sur une paroi d'un four, qui comprend un bloc percé d'ouvertures recevant des gicleurs primaires et secondaires de combustible, et délimitant une zone de combustion primaire ; l'air pénètre dans cette zone par une plaque perforée et se mélange avec des jets horizontaux et / ou radiaux de combustible mélangé aux fumées aspirée par la dépression résultant de ces jets au travers des ouvertures correspondantes prévues dans le bloc ; des jets verticaux de combustible mélangé aux fumées aspirées au travers d'autres ouvertures, sortent à l'extrémité aval du bloc, dans une autre zone de combustion.US Pat. No. 5,073,105 discloses a burner mounted on a wall of a oven, which comprises a block pierced with openings receiving sprinklers primary and secondary fuel, and delimiting a zone of primary combustion; air enters this area through a perforated plate and mixes with horizontal and / or radial fuel jets mixed with the fumes sucked by the depression resulting from these jets at through corresponding openings in the block; jets of fuel mixed with fumes sucked through other openings, go out at the downstream end of the block, into another zone of combustion.

Le brevet US 5,284,438 décrit un brûleur de structure similaire mais plus complexe, dans lequel le bloc du brûleur délimite un convergent et un divergent séparés par un étranglement, et comporte des conduits d'aspiration de fumées par jets de combustible qui, par leurs dimensions, leur forme évasée en entrée, leur position inclinée et leur sortie située dans le divergent du bloc, sont censées assurer un dosage défini du mélange combustible - fumées et son injection dans une zone de mélange avec l'air, qui est située dans le divergent ; ce brûleur comporte un conduit central d'injection de combustible équipé d'une buse, et un stabilisateur de flamme ; cette structure provoque la formation de jets (d'un mélange combustible - fumées) turbulents et tourbillonnants, et provoque leur mélange avec l'air dans les zones de mélange délimitées par le bloc.US Pat. No. 5,284,438 describes a burner of similar structure but more complex, in which the burner block delimits a convergent and a divergent separated by a constriction, and includes conduits fumes extraction by fuel jets which, by their dimensions, their flared shape at the entrance, their inclined position and their exit located in the divergent from the block, are supposed to ensure a defined dosage of the mixture fuel - fumes and its injection into a mixing zone with air, which is situated in the divergent; this burner comprises a central duct injection nozzle equipped with a nozzle, and a stabilizer of flame ; this structure causes the formation of jets (of a mixture fuel - smoke) turbulent and swirling, and causes them to mixing with the air in the mixing zones delimited by the block.

Ces brûleurs dont les canaux d'aspiration de fumées sont formés dans des blocs épais généralement réalisés en béton réfractaire, sont fragiles, encombrants, coûteux, et d'un entretien difficile.These burners whose fume extraction channels are formed in thick blocks generally made of refractory concrete, are fragile, bulky, expensive, and difficult maintenance.

Le document EP 675 321 décrit un brûleur à combustible gazeux qui comporte plusieurs cannes d'injection primaire de combustible, disposées dans la partie centrale d'un canal d'amenée d'air délimité par le corps tubulaire du brûleur ; les extrémités des cannes sont pliées vers l'extérieur, disposées sous les fentes d'un stabilisateur de flamme, et les extrémités des cannes sont percées de trous par lesquels le gaz combustible est injecté dans le foyer à travers les fentes du stabilisateur ; le brûleur comporte en outre des cannes (secondaires) d'injection du combustible gazeux, qui sont réparties autour des cannes d'injection primaire, et qui se terminent par une buse unique débouchant chacune dans un conduit de recirculation des fumées produites dans le foyer ; ces cannes secondaires d'injection, ainsi que les conduits de recirculation associés, sont situées à l'intérieur du canal d'air, pour assurer leur refroidissement par l'air qui y circule.EP 675 321 discloses a gaseous fuel burner which has several primary fuel injection rods arranged in the central part of an air duct delimited by the body tubular burner; the ends of the rods are bent outwards, arranged under the slots of a flame stabilizer, and the ends of rods are pierced with holes through which fuel gas is injected in the focus through the slits of the stabilizer; the burner has in in addition to (secondary) gaseous fuel injection rods, which are distributed around the primary injection rods, and which end with a single nozzle each opening into a recirculation duct smoke produced in the home; these secondary injection canes, as well that the associated recirculation ducts, are located inside the canal of air, to ensure their cooling by the air circulating there.

Chaque conduit de recirculation débouche dans le foyer parallèlement au canal d'air, et communique à son autre extrémité avec le foyer par un orifice percé dans la paroi du canal d'air, à la périphérie extérieure du brûleur ; ces orifices permettent, par effet d'aspiration et d'entraínement, de réaliser une recirculation des fumées qui se mélangent avec le gaz combustible et réduisent la formation des oxydes d'azote ; pour compléter cette réduction par augmentation de l'étagement de la combustion, le brûleur comporte des cannes (tertiaires) d'injection de combustible traversant la paroi de l'enceinte du foyer ; chaque canne est associée à un canal d'amenée d'air entourant la canne.Each recirculation duct opens into the firebox in parallel to the air channel, and communicates at its other end with the hearth by a orifice pierced in the wall of the air channel, at the outer periphery of the burner; these orifices allow, by suction effect and drive, to recirculate the fumes that mix with the gas fuel and reduce the formation of nitrogen oxides; to complete this reduction by increasing the staging of combustion, the burner includes (tertiary) fuel injection rods crossing the wall of the hearth enclosure; each cane is associated with a air intake channel surrounding the cane.

Le brevet EP 675 321 décrit par ailleurs un brûleur dénué de moyens tertiaires d'injection de combustible, dont les performances sont réduites.Patent EP 675 321 also describes a burner devoid of means tertiary fuel injection, whose performance is reduced.

Le brûleur décrit dans ce document présente certains inconvénients : les courants gazeux délivrés par les cannes et les canaux d'air associés à ces moyens tertiaires d'injection, sont susceptibles de former un rideau entourant les moyens secondaires d'injection de gaz combustible, ce qui est susceptible de perturber et de limiter l'efficacité du système de recirculation de fumée par les moyens secondaires d'injection de combustible gazeux ; un autre inconvénient résulte de la difficulté de régler et de maítriser l'effet produit par les jets d'air entourant les jets de gaz des moyens tertiaires d'injection, et en particulier de maítriser ces jets coaxiaux et leur mélange nécessaire à une bonne combustion avec les autres jets provoqués par ce brûleur, qui est équipé de trois systèmes distincts d'injection de combustible gazeux et de deux systèmes distincts de transport et d'injection d'air dans le brûleur (et le foyer) ; en outre, un inconvénient lié aux cannes s'étendant au travers des parois délimitant l'enceinte du foyer, réside dans l'encombrement important de ce système et dans la difficulté à réparer, entretenir et/ou modifier un tel système en partie noyé dans le mur d'enceinte du foyer.The burner described in this document has certain disadvantages: the gaseous currents delivered by the rods and the air channels associated with these tertiary means of injection, are likely to form a curtain surrounding the secondary means of fuel gas injection, which is likely to disturb and limit the efficiency of the recirculation system smoke by secondary means for injecting gaseous fuel; a Another disadvantage is the difficulty of regulating and controlling the effect produced by the jets of air surrounding the gas jets of tertiary means injection, and in particular to control these coaxial jets and their mixture necessary for good combustion with other jets caused by this burner, which is equipped with three separate injection systems gaseous fuel and two separate transport and injection systems air in the burner (and hearth); in addition, a disadvantage related to canes extending through the walls delimiting the enclosure of the home, lies in the large size of this system and the difficulty of repairing it, maintain and / or modify such a system partially embedded in the wall of the hearth of the hearth.

Un objectif de la présente invention est de proposer un brûleur amélioré et de remédier en partie au moins aux inconvénients des brûleurs connus tout en améliorant leurs performances dans la réduction de la formation des oxydes d'azote.An object of the present invention is to provide a burner improved and at least partially remedy the disadvantages of burners known while improving their performance in reducing the formation of nitrogen oxides.

Un objectif de la présente invention consiste en particulier à améliorer l'auto-recirculation des fumées.An object of the present invention is in particular to improve the self-recirculation of fumes.

Un objectif de la présente invention est également de proposer un brûleur compact, simple, peu coûteux et susceptible d'être utilisé dans un conduit de transport de gaz d'échappement de turbine(s).An object of the present invention is also to propose a compact burner, simple, inexpensive and likely to be used in a Turbine exhaust gas transport duct (s).

Selon un premier aspect, l'invention consiste à proposer un brûleur à combustible gazeux qui comporte un conduit central de transport de combustible, un conduit central de transport d'air entourant ledit conduit central de combustible, plusieurs conduits périphériques de transport de combustible gazeux s'étendant en partie au moins à l'extérieur du conduit central de transport d'air, de préférence parallèlement à celui-ci, et terminés chacun par une buse d'éjection du combustible ; le brûleur comporte en outre un tronçon rectiligne de conduit cylindrique (ou tube) de recirculation de fumées, qui est disposé dans le prolongement de chaque buse et à distance (en avant) de celle-ci ; le conduit de transport d'air et les conduits d'aspiration de fumées sont métalliques, sensiblement parallèles entre eux, et débouchent de préférence sensiblement dans un même plan perpendiculaire à l'axe longitudinal du brûleur ; les conduits d'aspiration de fumées sont fixés sur le corps métallique du brûleur, de préférence sur le conduit de transport d'air, par une liaison métallique qui contribue à assurer, par conduction, le refroidissement des conduits d'aspiration par le corps de brûleur (en particulier par le conduit d'air) qui est lui-même refroidi par l'air qu'il transporte.According to a first aspect, the invention consists in proposing a burner gaseous fuel which comprises a central transport duct fuel, a central air duct surrounding said duct central fuel, several gaseous fuel extending at least partly outside the duct central air transport, preferably parallel to it, and completed each by a fuel ejection nozzle; the burner has in in addition to a rectilinear section of cylindrical conduit (or tube) of recirculation of fumes, which is arranged in the extension of each nozzle and at a distance (in front) thereof; the air transport duct and the smoke extraction ducts are metallic, substantially parallel between them, and preferably open substantially in the same plane perpendicular to the longitudinal axis of the burner; the suction ducts of The fumes are fixed on the metal body of the burner, preferably on the air transport duct, by a metal connection which contributes to ensure, by conduction, the cooling of the suction ducts by the burner body (especially by the air duct) which is itself cooled by the air it carries.

Du fait que les conduits de circulation de fumée ne sont pas, à l'inverse du brûleur décrit dans le brevet EP 675 321, protubérants à l'intérieur du conduit d'air, ils ne perturbent pas le fonctionnement du brûleur, notamment lorsque celui-ci - doté à cet effet d'une canne centrale d'injection de combustible liquide - est alimenté en combustible liquide uniquement.Because the flue ducts are not, at the opposite of the burner described in patent EP 675 321, protuberant to inside the air duct, they do not disturb the operation of the burner, especially when the latter - equipped for this purpose with a central cane liquid fuel injection - is fueled with liquid fuel only.

Des essais ont montré qu'un tel brûleur provoque une faible émission d'oxydes d'azote.Tests have shown that such a burner causes a low emission nitrogen oxides.

La position des conduits de circulation de fumées disposés à l'extérieur du conduit d'air résulte en une séparation des jets du mélange combustible / fumées par rapport au courant d'air transporté par le conduit central (principal) ; le mélange de ces jets avec la flamme résultant de la combustion du combustible délivré par le conduit central intervient progressivement et plus loin (par comparaison avec la structure décrite dans le brevet EP 675 321) en aval du nez du brûleur, ce qui renforce l'effet d'étagement de l'injection du combustible.The position of the flue pipes arranged to the outside of the air duct results in a separation of the jets of the mixture fuel / smoke compared to the air flow carried by the duct central (main); mixing these jets with the flame resulting from the combustion of the fuel delivered by the central duct intervenes gradually and further (compared to the structure described in EP 675 321) downstream of the nose of the burner, which reinforces the effect staging of the fuel injection.

L'effet d'aspiration et d'entraínement des fumées par les jets de gaz combustible délivrés par les buses périphériques est amélioré par le fait que l'entrée des fumées à l'extrémité amont des conduits de recirculation s'effectue sur toute la périphérie de ceux-ci ; une plus grande quantité de fumées est ainsi aspirée et mélangée à chaque jet de combustible.The effect of suction and entrainment of fumes by gas jets fuel delivered by the peripheral nozzles is improved by the fact that the flue gas inlet at the upstream end of the recirculation ducts is carried out on the whole periphery of these; a greater amount of The fumes are thus sucked up and mixed with each fuel jet.

En outre, le jet de mélange combustible / fumées sortant de chaque conduit périphérique de recirculation provoque, du fait de sa vitesse, un entraínement supplémentaire de fumées.In addition, the jet of fuel / fume mixture coming out of each recirculation device leads, due to its speed, to a additional training of fumes.

La distance séparant chaque buse périphérique de combustible de l'orifice d'entrée du tube de recirculation associé, est de préférence du même ordre de grandeur que le rayon ou le diamètre du tronçon de tube de recirculation, par exemple de l'ordre de 2 à 20 centimètres ; ainsi, l'espace libre entre la buse et l'entrée (l'extrémité amont) du conduit de recirculation facilite l'aspiration des fumées et le mélange du gaz combustible avec les fumées présentes dans le foyer, en délimitant une section de passage pour des fumées de dimensions notablement plus grandes que celle délimitée par l'ouverture périphérique des tubes de recirculation décrits dans le document EP 675 321 ; en outre, cette disposition permet et/ou facilite le réglage, lors du montage ou de l'installation du brûleur, de cette distance, ce qui permet d'optimiser l'aspiration, le mélange et l'entraínement des fumées par les jets de gaz combustible.The distance separating each peripheral fuel nozzle from the inlet of the associated recirculation tube is preferably same order of magnitude as the radius or diameter of the pipe section of recirculation, for example of the order of 2 to 20 centimeters; thus, the space between the nozzle and the inlet (the upstream end) of the recirculation facilitates the extraction of fumes and the mixing of gas combustible with the fumes present in the hearth, delineating a passage section for smokes of significantly larger dimensions large than that defined by the peripheral opening of the tubes of recirculation described in EP 675 321; in addition, this provision allows and / or facilitates the adjustment, during assembly or the installation of the burner, this distance, which makes it possible to optimize suction, mixing and entrainment of fumes by gas jets combustible.

Il a été constaté que, de façon surprenante, le refroidissement des conduits de recirculation de fumées par conduction avec le conduit central de transport d'air est suffisant pour éviter la détérioration de ces conduits bien que ces conduits de fumées soient disposés dans le foyer (et/ou soient soumis à un échauffement intense par le rayonnement direct de la flamme) ; de préférence, à cet effet, la liaison métallique servant de drain thermique s'étend sur une surface importante, en particulier sensiblement sur toute la longueur des conduits de recirculation ; cette liaison est de préférence obtenue par soudure.It has been found that, surprisingly, the cooling of Conducted flue gas recirculation ducts with the central duct air transport is sufficient to prevent deterioration of these ducts although these flues are located in the fireplace (and / or are subjected to intense heating by the direct radiation of the flame); preferably, for this purpose, the metal link serving as a heat sink extends over a large area, particularly substantially over the entire length of the recirculation ducts; this link is preferably obtained by welding.

En effet, dans le brûleur selon l'invention, le refroidissement des tubes de circulation de fumées ne peut pas être obtenu par convection avec un flux d'air (relativement froid) comme c'est le cas dans le brevet EP 675 321 et dans la demande de brevet FR 98/10350 déposée le 7 août 1998 par la Demanderesse ; dans ce document en effet, des buses périphériques d'injection d'air sont disposées imbriquées avec les buses périphériques d'injection de combustible.Indeed, in the burner according to the invention, the cooling of flue gas tubes can not be obtained by convection with a flow of air (relatively cold) as is the case in EP 675 321 and in the patent application FR 98/10350 filed August 7, 1998 by the Claimant; in this document indeed, peripheral nozzles of air injection are arranged nested with the peripheral nozzles fuel injection.

Selon d'autres caractéristiques préférentielles, qui contribuent à améliorer la compacité, la simplicité et l'efficacité du brûleur :

  • le rapport de la longueur des conduits de recirculation associés aux buses d'éjection de gaz, à leur diamètre, est supérieur à 1 et inférieur ou égal à 10, en particulier voisin de 2 à 4 ;
  • les buses périphériques d'éjection de gaz sont disposées sensiblement affleurantes ou de façon peu saillante sur la face interne des parois de l'enceinte du foyer ;
  • l'orifice de sortie du conduit central d'air est saillant à l'intérieur de l'enceinte du foyer, et les extrémités avant des conduits de recirculation situés dans le prolongement des buses d'éjection de gaz combustible, sont disposées sensiblement dans le même plan que ledit orifice de sortie du conduit central d'air ;
  • les tubes de recirculation associés aux buses d'éjection de gaz combustible, sont soudés sur la virole du conduit central d'air, sur la surface externe de celle-ci.
According to other preferred features, which contribute to improving the compactness, simplicity and efficiency of the burner:
  • the ratio of the length of the recirculation ducts associated with the gas ejection nozzles, to their diameter, is greater than 1 and less than or equal to 10, in particular close to 2 to 4;
  • the peripheral gas ejection nozzles are arranged substantially flush or slightly protruding on the inner face of the walls of the hearth enclosure;
  • the outlet orifice of the central air duct protrudes inside the hearth enclosure, and the front ends of the recirculation ducts located in the extension of the fuel gas ejection nozzles are arranged substantially in the same plane as said outlet port of the central air duct;
  • the recirculation tubes associated with the fuel gas ejection nozzles, are welded to the shell of the central air duct, on the outer surface thereof.

Lesdites buses périphériques et les conduits d'aspiration associés sont de préférence identiques, disposés à égale distance de l'axe longitudinal du brûleur (c'est-à-dire sur un cercle) et selon une symétrie de révolution (c'est-à-dire angulairement équidistants).Said peripheral nozzles and the associated suction ducts are preferably identical, arranged equidistant from the axis longitudinal axis of the burner (that is to say on a circle) and in a symmetry of revolution (that is, angularly equidistant).

De préférence, les buses périphériques d'injection de gaz combustible, ainsi que les tubes de fumées associés, sont au nombre de trois à douze, en particulier de six à huit, disposées en couronne, régulièrement (angulairement) réparties autour de l'axe longitudinal (de symétrie générale) du brûleur.Preferably, the peripheral gas injection nozzles fuel and the associated flue gas pipes are three to twelve, in particular six to eight, arranged in a crown, regularly (angularly) distributed around the longitudinal axis (of general symmetry) of the burner.

Bien que les axes longitudinaux des buses périphériques et des conduits de fumées associés puissent s'étendre de façon conique divergente (au plus 5 degrés), il est préférable que ces axes soient sensiblement parallèles à l'axe longitudinal du brûleur.Although the longitudinal axes of the peripheral nozzles and associated flues may extend cone divergently (at most 5 degrees), it is preferable that these axes are substantially parallel to the longitudinal axis of the burner.

Selon un autre aspect, l'invention consiste en un réchauffeur de gaz de turbine, qui comporte un brûleur selon l'invention qui est monté dans la partie centrale d'un conduit de transport de gaz de turbine qui est équipé de volets de fermeture partielle.In another aspect, the invention consists of a gas heater turbine, which comprises a burner according to the invention which is mounted in the central part of a turbine gas transport duct which is equipped with partial closure shutters.

Dans cette utilisation particulière du brûleur selon l'invention, la position externe des tubes de circulation de fumée évite de perturber la combustion du combustible délivré en partie centrale.In this particular use of the burner according to the invention, the external position of the smoke circulation tubes avoids disturbing the combustion of the fuel delivered in the central part.

Les avantages procurés par l'invention seront mieux compris au travers de la description suivante qui se réfère aux dessins annexés, qui illustrent sans aucun caractère limitatif des modes préférentiels de réalisation de l'invention.The advantages provided by the invention will be better understood at through the following description which refers to the accompanying drawings, which illustrate without any limiting character the preferential modes of embodiment of the invention.

Dans les dessins, les éléments identiques ou similaires portent, sauf indication contraire, les mêmes références d'une figure à l'autre.In the drawings, identical or similar elements shall bear, except otherwise, the same references from one figure to another.

La figure 1 illustre en vue en coupe longitudinale un brûleur à combustible liquide et gazeux conforme à l'invention.FIG. 1 illustrates in longitudinal sectional view a burner with liquid and gaseous fuel according to the invention.

La figure 2 est une vue de face de l'extrémité avant du brûleur de la figure 1 et est une vue selon II de la figure 1. FIG. 2 is a front view of the front end of the burner of the Figure 1 and is a view along II of Figure 1.

La figure 3 illustre en vue en coupe longitudinale un réchauffeur de gaz de sortie de turbine conforme à l'invention.FIG. 3 illustrates in longitudinal sectional view a heater of turbine outlet gas according to the invention.

Le brûleur 1 (figures 1 et 2) comporte une première virole cylindrique 2 d'axe longitudinal 3 horizontal, et une deuxième virole cylindrique 4 coaxiale à la première, qui délimite un conduit 5 ; la virole 2 délimite un conduit central 31 de passage d'air, qui prolonge le conduit 5 d'entrée d'air.The burner 1 (FIGS. 1 and 2) comprises a first ferrule cylindrical 2 longitudinal axis 3 horizontal, and a second ferrule cylindrical 4 coaxial with the first, which delimits a duct 5; the ferrule 2 defines a central duct 31 for air passage, which extends the duct 5 air inlet.

Le brûleur s'étend au travers d'un orifice cylindrique 6 prévu dans la paroi 7 séparant le foyer 8 de l'extérieur 9 de l'enceinte.The burner extends through a cylindrical orifice 6 provided in the wall 7 separating the hearth 8 from the outside 9 of the enclosure.

Le brûleur comporte en partie centrale une canne 10 centrale de transport de combustible liquide (en particulier tel que fuel-oil lourd, gasoil, essence, huiles, liquides résiduaires...) jusqu'à la tête du brûleur équipé d'une buse centrale 11 et d'un stabilisateur 12 de flamme, qui sont disposés à l'extrémité avant du conduit 31 et de la virole 2, et sont saillants à l'intérieur du foyer 8 ; le brûleur comporte en outre une canne 100 centrale d'injection de combustible gazeux.The burner comprises in central part a central rod of transport of liquid fuel (in particular such as heavy fuel oil, diesel fuel, gasoline, oils, residual liquids ...) up to the equipped burner head a central nozzle 11 and a flame stabilizer 12, which are arranged at the front end of the duct 31 and the ferrule 2, and are salient at inside the fireplace 8; the burner further comprises a central rod 100 injection of gaseous fuel.

Le brûleur comporte un faisceau de six tubes périphériques 13 de transport de gaz combustible, qui sont chacun équipés à leur extrémité avant d'une buse 14 disposée saillante (par exemple proéminente de 1 centimètre) à la face interne 15 de la paroi 7.The burner comprises a bundle of six peripheral tubes 13 of transport of fuel gas, which are each equipped at their end before a nozzle 14 arranged protruding (for example prominent 1 centimeter) to the inner face 15 of the wall 7.

Une partie des tubes 13 s'étend parallèlement à l'axe 3 à l'intérieur du conduit 5 de transport d'air; les tubes 13 sont alimentés par un collecteur commun 16, et passent au travers d'une bride annulaire 17 reliant les viroles 2 et 4 ; comme illustré figure 2, les six buses identiques 14 d'éjection de gaz combustible sont espacées angulairement de 60 degrés.Part of the tubes 13 extends parallel to the axis 3 inside duct 5 for air transport; the tubes 13 are powered by a common collector 16, and pass through an annular flange 17 connecting ferrules 2 and 4; as illustrated in FIG. 2, the six identical nozzles 14 fuel gas ejection are angularly spaced 60 degrees.

Les axes longitudinaux 20 des buses 14 qui sont parallèles à l'axe 3, sont situés sur des rayons identiques ou voisins.The longitudinal axes 20 of the nozzles 14 which are parallel to the axis 3, are located on identical or neighboring rays.

Six tronçons 22 rectilignes de tubes de section circulaire, coupés à angle droit à leurs deux extrémités 23, 24, sont disposés dans le prolongement des buses 14 d'éjection de gaz, et sont soudés le long d'une de leurs génératrices à un barreau métallique 101 plein, associé à chacun des conduits, qui s'étend parallèlement au conduit 22 et qui est lui-même soudé (sur toute sa longueur) sur la face externe de la partie d'extrémité avant de la virole 2, selon des génératrices de celle-ci.Six straight sections 22 of circular section tubes, cut to right angle at their two ends 23, 24, are arranged in the extension of the gas ejection nozzles 14, and are welded along a from their generators to a full metal bar 101, associated with each ducts, which extends parallel to the duct 22 and which is itself welded (over its entire length) to the outer face of the end portion before the ferrule 2, according to generators thereof.

L'axe des tubes 22 est confondu avec l'axe des buses 14 et l'extrémité arrière 24 des tronçons 22 identiques est disposée à une distance 25 de la buse 14 correspondante, laquelle distance est voisine de 50 millimètres, et correspondant au diamètre des tubes 22.The axis of the tubes 22 coincides with the axis of the nozzles 14 and the end rear 24 identical sections 22 is disposed at a distance 25 from the corresponding nozzle 14, which distance is close to 50 millimeters, and corresponding to the diameter of the tubes 22.

L'extrémité avant 23 des tubes 22 s'étend dans le plan 112 contenant l'orifice de sortie du conduit central 31.The front end 23 of the tubes 22 extends in the plane 112 containing the outlet orifice of the central duct 31.

Par référence à la figure 3, le brûleur 1 est monté dans un conduit 200, d'axe confondu avec l'axe 3 du brûleur, délimité par des parois 201 (dans le cas où plusieurs brûleurs sont montés dans le conduit 200, leurs axes 3 sont parallèles à celui du conduit).With reference to FIG. 3, the burner 1 is mounted in a duct 200, of axis coincides with the axis 3 of the burner, delimited by walls 201 (In the case where several burners are mounted in the duct 200, their axes 3 are parallel to that of the duct).

Le conduit 200 transporte (selon les flèches 103) du gaz sortant d'une turbine, dont la température est de l'ordre de 500°C ou bien, lorsque la turbine est à l'arrêt, de l'air ; dans ce dernier cas, des volets 104, qui sont montés pivotants dans le conduit 200 selon des axes 105, obturent partiellement - dans la position représentée en traits pleins - la section de passage du conduit 200 en laissant le passage libre - selon les flèches 102 - au travers du conduit 2 du brûleur ; la position (ouverte) des volets illustrée en traits interrompus correspond au cas où les gaz de turbine sont présents.The pipe 200 carries (according to the arrows 103) gas leaving a turbine, whose temperature is of the order of 500 ° C or, when the turbine is stopped, air; in the latter case, shutters 104, which are pivotally mounted in the conduit 200 along axes 105, seal partially - in the position shown in solid lines - the section of passage of the duct 200 leaving the passage free - according to the arrows 102 - through the conduit 2 of the burner; the (open) position of the shutters shown in dashed lines corresponds to the case where the turbine gases are present.

Le brûleur est fixé dans le conduit 200 par des supports non représentés.The burner is fixed in the duct 200 by means represented.

Dans les deux cas de fonctionnement, un apport d'air extérieur (correspondant à 5 % de l'air total) est introduit par un conduit 106 pour refroidir la partie centrale du brûleur où sont situés en particulier le stabilisateur 105 des flammes centrales (principales) de combustion du gaz injecté par les conduits centraux 100 qui traversent une rosace déflectrice 104 ; les conduits 100 sont alimentés par un collecteur 107.In both cases of operation, a supply of outside air (corresponding to 5% of the total air) is introduced via a conduit 106 for cool the central part of the burner where are located in particular the Stabilizer 105 of central (main) gas combustion flames injected through the central ducts 100 which pass through a deflecting rosette 104; the ducts 100 are fed by a collector 107.

Par ailleurs, les conduits périphériques 13 sont alimentés en gaz combustible par un deuxième collecteur 16 ; le débit de combustible gazeux injecté par les buses périphériques représente généralement de l'ordre de 90 à 95 % du débit total de combustible. Un avantage du brûleur est que les jets de mélange sortant des tubes 22 contribuent à allonger la flamme, ce qui améliore le rendement du réchauffeur de gaz et de l'installation de récupération de chaleur, disposée en aval du brûleur.In addition, the peripheral ducts 13 are supplied with gas fuel by a second collector 16; the flow of gaseous fuel injected by the peripheral nozzles is generally of the order of 90 95% of the total fuel flow. An advantage of the burner is that the jets of mixture coming out of the tubes 22 contribute to lengthen the flame, which which improves the efficiency of the gas heater and the installation of heat recovery, arranged downstream of the burner.

Claims (9)

  1. Gaseous fuel burner (1), which comprises a central fuel transporting duct (10, 100), a central air transporting duct (2) surrounding the said central fuel duct, and several peripheral gaseous fuel transporting ducts (13), characterized in that the said peripheral ducts extend at least partly to the outside of the central air transporting duct, in that the burner further includes a straight portion of flue gas circulation duct (22) that lies in the extension of each nozzle (14) with which the peripheral ducts (13) are equipped and in that the flue gas intake ducts (22) are fixed by a link (101) to the air transporting duct (2), on the outside of the latter, and are not in contact with a stream of air, the ducts (22) being cooled by conduction via the said link (101).
  2. Burner according to Claim 1, in which the ducts (22) are welded along their generatrices to a metal linking bar (101) which is welded to a generatrix of the duct (2), parallel to the latter.
  3. Burner according to either of Claims 1 and 2, which includes a flame stabilizer (105) and a deflector (106) that are placed in the air duct (2, 31) near its end plane (112).
  4. Burner according to any one of Claims 1 to 3, in which the upstream orifice (24) of each duct (22) is placed at a distance (25) from the corresponding nozzle (14) that is of the order of the diameter of the duct (22).
  5. Burner according to any one of Claims 1 to 4, in which the outlet orifice (23) of the ducts (22) lies approximately in the transverse outlet plane (112) of the duct (2).
  6. Burner according to any one of Claims 1 to 5,' in which the nozzles (14) and the ducts (2, 22) project into the hearth (8).
  7. Burner according to any one of Claims 1 to 6, in which the flue gas circulation ducts (22) and the air transporting duct (2) are made of metal.
  8. Heater for heating turbine gases transported by a duct (200) fitted with closure flaps (104), characterized in that it includes a burner according to any one of Claims 1 to 7.
  9. Heater according to Claim 8, which includes a duct (106) for supplying air in order to cool the burner.
EP00430026A 1999-08-04 2000-07-27 Burner with exhaust recirculation Expired - Lifetime EP1074790B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9910296A FR2797321B1 (en) 1999-08-04 1999-08-04 LOW-EMISSION NITROGEN OXIDE SMOKE RECIRCULATION BURNERS AND GAS HEATERS COMPRISING SUCH BURNERS
FR9910296 1999-08-04

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EP1074790A1 EP1074790A1 (en) 2001-02-07
EP1074790B1 true EP1074790B1 (en) 2004-11-24

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WO2007134580A1 (en) * 2006-05-19 2007-11-29 Ulrich Dreizler Flame modelling
FR2914398B1 (en) * 2007-04-02 2009-12-18 Pillard Chauffage GASEOUS FUEL BURNER
CN103277795B (en) * 2013-05-27 2015-05-20 中国科学院广州能源研究所 Gas burner capable of adjusting gas to be self-recycling
US9593847B1 (en) 2014-03-05 2017-03-14 Zeeco, Inc. Fuel-flexible burner apparatus and method for fired heaters
CN110360559B (en) * 2018-04-09 2024-07-30 江苏弗雷姆环境科技有限公司 Industrial gas ultralow nitrogen energy-saving burner
CN109631036B (en) * 2019-01-14 2023-08-25 唐山亿昌热能科技有限公司 Combustion method of ultralow nitrogen oxides, matched combustion head and combustion device
CN110594743B (en) * 2019-10-12 2024-05-07 西藏仁泽环境技术有限公司 Mixed fuel burner for burning low-heat-value waste gas by using high-heat-value waste liquid
CN112303621B (en) * 2020-03-02 2023-06-16 青岛永泰锅炉有限公司 Ultralow nitrogen boiler gas burner
IT202000028394A1 (en) * 2020-11-25 2022-05-25 Baltur S P A BURNER AND INDUSTRIAL EQUIPMENT WITH REDUCED EMISSIONS
CN217131272U (en) * 2020-11-25 2022-08-05 百得股份公司 Reduced emission industrial combustor and apparatus
CN116379431A (en) * 2023-03-30 2023-07-04 武汉明正动力工程有限公司 Four-in-one low-nitrogen combustor

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FR2760071B1 (en) * 1997-02-27 1999-05-28 Pillard Chauffage DEVICE FOR MOUNTING BURNERS IN A GAS DUCT FOR HEATING
FR2782150B1 (en) * 1998-08-07 2000-11-10 Pillard Chauffage IMPROVEMENTS ON LOW-EMITTING AND LOW-EMITTING NITROGEN OXIDES BURNER

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DE60016106D1 (en) 2004-12-30
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FR2797321B1 (en) 2001-10-26
FR2797321A1 (en) 2001-02-09

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