EP0484736A1 - Combustibles pour moteurs à allumage par étincelle - Google Patents

Combustibles pour moteurs à allumage par étincelle Download PDF

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Publication number
EP0484736A1
EP0484736A1 EP91118032A EP91118032A EP0484736A1 EP 0484736 A1 EP0484736 A1 EP 0484736A1 EP 91118032 A EP91118032 A EP 91118032A EP 91118032 A EP91118032 A EP 91118032A EP 0484736 A1 EP0484736 A1 EP 0484736A1
Authority
EP
European Patent Office
Prior art keywords
fuels
formula
detergent
contain
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP91118032A
Other languages
German (de)
English (en)
Other versions
EP0484736B1 (fr
Inventor
Knut Dr. Oppenlaender
Juergen Dr. Mohr
Roland Dr. Schwen
Juergen Dr. Thomas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
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Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP0484736A1 publication Critical patent/EP0484736A1/fr
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Publication of EP0484736B1 publication Critical patent/EP0484736B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B1/00—Engines characterised by fuel-air mixture compression
    • F02B1/02—Engines characterised by fuel-air mixture compression with positive ignition
    • F02B1/04—Engines characterised by fuel-air mixture compression with positive ignition with fuel-air mixture admission into cylinder

Definitions

  • the invention relates to fuels for gasoline engines which contain small amounts of a mixture of a detergent and a mono- or dialkoxylated polyisobutylamine.
  • Carburetor and intake system of gasoline engines are increasingly contaminated by contaminants caused by dust particles from the air, unburned hydrocarbon residues from the combustion chamber and the crankcase ventilation gases that are led into the carburetor.
  • the first additive generation could only prevent the formation of deposits in the intake system, but not remove existing deposits in the intake system, whereas the modern additives of the second generation can do both (“keep-clean” and clean-up effect ”) and indeed, due to changed thermal properties, in particular also at zones of high temperatures, namely at the inlet valves.
  • a detergent component in the mixture with the dispersant according to the invention it is possible in principle to use any known product suitable for this purpose, such as those e.g. with J. Falbe, U. Hasserodt, catalysts, surfactants and mineral oil additives, G. Thieme Verlag Stuttgart 1978, p. 221 f. or in K. Owen, Gasoline and Diesel Fuel Additives, John Wiley & Sons 1989, pp. 23 ff.
  • Polyisobutylamines according to EP 0 244 616, ethylenediamine acetic acid amides and / or imides according to EP 0 188 786 or polyether amines according to EP 0 356 725 are preferably used, reference being made to the definitions in these references. Due to the manufacturing process, the products described there have the additional advantage of being almost free of chlorine or chloride.
  • the detergents mentioned usually show excellent effectiveness in valve and carburetor cleanliness, but, as already mentioned above, are at best neutral, i.e. without an adverse effect on an engine lubricant, so show no positive effect with regard to a desired sludge dispersion.
  • fuels for gasoline engines are, in addition to (A) the detergents mentioned (B), polyisobutylamine derivatives in small amounts, preferably in amounts of 50 to 2000 ppm, of the formula I. added, in which R is a polyisobutyl radical with a molecular weight of 500 to 5000, R1 is hydrogen, methyl or ethyl and m and n independently of one another are the numbers 0 or 1.
  • the ratio of (A) to (B) is usually 1: 2 to 10: 1.
  • polyisobutylamines preferably obtained by hydroformylation and subsequent reductive amination of reactive polyisobutenes according to EP-A2-0 244 616, to which reference is hereby made, are reacted with alkylene oxides in a manner known per se.
  • the polyisobutene used has a molecular weight between 500 and 5000, preferably between 800 and 1500. It is obtained according to a known method by cationic polymerization of isobutene, with a reactive double bond remaining in the monomer last incorporated after termination of the polymer chain, which is used for the purpose of further functionalization can be.
  • the mono- or dialkoxylation is carried out by reacting the amine with alkylene oxides, preferably with ethylene oxide, in a manner known per se, e.g. in the presence of a certain proportion of water in a pressure vessel, the amine is reacted with the approx. 1 to 5 times molar amount of alkylene oxide, e.g. at S.P. McManus et al., Synth. Commun. 3, 177 (1973). Depending on the choice of the amount of alkoxide, mono- or dialkoxylated amines are obtained.
  • the alkoxylation products of the formula I in addition to their known valve cleaning action, have a particularly positive effect on the sludge-carrying capacity of weakly or not at all additive engine oils, particularly when ethylene oxide is used as the alkylene oxide.
  • Leaded and unleaded regular and premium gasoline can be used as fuels for gasoline engines.
  • the gasolines can also contain components other than hydrocarbons, e.g. Alcohols such as methanol, ethanol, tert. Butanol and ether, e.g. Contain methyl tertiary butyl ether.
  • the fuels generally also contain additives such as corrosion inhibitors, stabilizers, antioxidants and / or other detergents.
  • Corrosion inhibitors are mostly ammonium salts org. Carboxylic acids which tend to form films due to the structure of the starting compounds. Amines to lower the pH are also often found in corrosion inhibitors. Heterocyclic aromatics are mostly used as non-ferrous metal corrosion protection. Rating Engine part Basic value Add 125 ppm polyisobutylamine + 125 ppm ethoxylated polyisobutylamine Add 250 ppm of non-ethoxylated polyisobutylamine Cylinder head cover 8.7 9.2 8.9 Oil distribution pipe 8.3 9.3 8.5 Cylinder head 8.3 9.5 8.5 Oil pan 8.2 9.5 8.9 Timing case cover 8.5 9.6 8.6 Average 8.4 9.4 8.7
  • the table shows the advantageous effect of the polyisobutyl ethoxylate to be used according to the invention compared to the starting polyisobutylamine.
  • the dispersing properties of the ethoxylate make it possible to raise the mean value from the rating of the individual engine parts from 8.4 to 9.4 (max. 10).
  • the use of polyisobutylamine does not lead to an improvement compared to the basic value.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Lubricants (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
EP91118032A 1990-11-09 1991-10-23 Combustibles pour moteurs à allumage par étincelle Expired - Lifetime EP0484736B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4035609A DE4035609A1 (de) 1990-11-09 1990-11-09 Kraftstoffe fuer ottomotoren
DE4035609 1990-11-09

Publications (2)

Publication Number Publication Date
EP0484736A1 true EP0484736A1 (fr) 1992-05-13
EP0484736B1 EP0484736B1 (fr) 1994-05-18

Family

ID=6417913

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91118032A Expired - Lifetime EP0484736B1 (fr) 1990-11-09 1991-10-23 Combustibles pour moteurs à allumage par étincelle

Country Status (4)

Country Link
EP (1) EP0484736B1 (fr)
CA (1) CA2054972A1 (fr)
DE (2) DE4035609A1 (fr)
ES (1) ES2053259T3 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997006225A1 (fr) * 1995-08-03 1997-02-20 Texaco Development Corporation Additifs detergents pour carburants de moteurs
CN103992827A (zh) * 2014-05-20 2014-08-20 美孚美斯克（泉州）化工有限公司 一种润滑抗磨节能增加动力的汽油添加剂组合物

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1083610A (en) * 1965-08-23 1967-09-20 Chevron Res Hydrocarbyl amine additives
US3407051A (en) * 1960-10-31 1968-10-22 Eastman Kodak Co Thermally stabilized, liquid hydrocarbon fuels
US3960515A (en) * 1973-10-11 1976-06-01 Chevron Research Company Hydrocarbyl amine additives for distillate fuels
US4247301A (en) * 1978-06-19 1981-01-27 Chevron Research Company Deposit control and dispersant additives
EP0188786A1 (fr) * 1985-01-11 1986-07-30 BASF Aktiengesellschaft Carburants pour moteurs
EP0244616A2 (fr) * 1986-04-04 1987-11-11 BASF Aktiengesellschaft Polybutène et polyisobutèneamine, leur procédé de préparation et compositions de combustibles et de lubrifiants qui les contiennent
EP0277345A1 (fr) * 1987-01-08 1988-08-10 BASF Aktiengesellschaft Composition de carburant ou de lubrifiant, contenant des dérivés de polybutyl ou polyisobutyl
EP0356725A1 (fr) * 1988-08-05 1990-03-07 BASF Aktiengesellschaft Carburants pour moteurs à allumage par étincelle contenant des polyétheramines ou des dérivés de polyétheramines
DE3942860A1 (de) * 1989-12-23 1991-06-27 Basf Ag Kraftstoffe fuer ottomotoren

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3407051A (en) * 1960-10-31 1968-10-22 Eastman Kodak Co Thermally stabilized, liquid hydrocarbon fuels
GB1083610A (en) * 1965-08-23 1967-09-20 Chevron Res Hydrocarbyl amine additives
US3960515A (en) * 1973-10-11 1976-06-01 Chevron Research Company Hydrocarbyl amine additives for distillate fuels
US4247301A (en) * 1978-06-19 1981-01-27 Chevron Research Company Deposit control and dispersant additives
EP0188786A1 (fr) * 1985-01-11 1986-07-30 BASF Aktiengesellschaft Carburants pour moteurs
EP0244616A2 (fr) * 1986-04-04 1987-11-11 BASF Aktiengesellschaft Polybutène et polyisobutèneamine, leur procédé de préparation et compositions de combustibles et de lubrifiants qui les contiennent
EP0277345A1 (fr) * 1987-01-08 1988-08-10 BASF Aktiengesellschaft Composition de carburant ou de lubrifiant, contenant des dérivés de polybutyl ou polyisobutyl
EP0356725A1 (fr) * 1988-08-05 1990-03-07 BASF Aktiengesellschaft Carburants pour moteurs à allumage par étincelle contenant des polyétheramines ou des dérivés de polyétheramines
DE3942860A1 (de) * 1989-12-23 1991-06-27 Basf Ag Kraftstoffe fuer ottomotoren

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997006225A1 (fr) * 1995-08-03 1997-02-20 Texaco Development Corporation Additifs detergents pour carburants de moteurs
CN103992827A (zh) * 2014-05-20 2014-08-20 美孚美斯克（泉州）化工有限公司 一种润滑抗磨节能增加动力的汽油添加剂组合物
CN103992827B (zh) * 2014-05-20 2016-05-18 美孚美斯克（泉州）化工有限公司 一种润滑抗磨节能增加动力的汽油添加剂组合物

Also Published As

Publication number Publication date
EP0484736B1 (fr) 1994-05-18
ES2053259T3 (es) 1994-07-16
DE4035609A1 (de) 1992-05-14
CA2054972A1 (fr) 1992-05-10
DE59101671D1 (de) 1994-06-23

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