EP0017183A3 - Hydroformylation medium, process of production thereof and process for producing aldehydes using the hydroformylation medium - Google Patents

Hydroformylation medium, process of production thereof and process for producing aldehydes using the hydroformylation medium Download PDF

Info

Publication number
EP0017183A3
EP0017183A3 EP80101665A EP80101665A EP0017183A3 EP 0017183 A3 EP0017183 A3 EP 0017183A3 EP 80101665 A EP80101665 A EP 80101665A EP 80101665 A EP80101665 A EP 80101665A EP 0017183 A3 EP0017183 A3 EP 0017183A3
Authority
EP
European Patent Office
Prior art keywords
hydroformylation medium
production
producing aldehydes
hydroformylation
medium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP80101665A
Other versions
EP0017183B1 (en
EP0017183A2 (en
Inventor
Werner Otte
Wolfgang Hans Eduard Muller
Manfred Zur Hausen
David Robert Bryant
Richard Allen Galley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27187939&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0017183(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from DE2912230A external-priority patent/DE2912230B1/en
Priority claimed from US06/120,101 external-priority patent/US4297239A/en
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Priority to AT80101665T priority Critical patent/ATE7222T1/en
Publication of EP0017183A2 publication Critical patent/EP0017183A2/en
Publication of EP0017183A3 publication Critical patent/EP0017183A3/en
Application granted granted Critical
Publication of EP0017183B1 publication Critical patent/EP0017183B1/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • B01J31/4023Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • B01J31/4053Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP80101665A 1979-03-28 1980-03-27 Hydroformylation medium, process of production thereof and process for producing aldehydes using the hydroformylation medium Expired EP0017183B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT80101665T ATE7222T1 (en) 1979-03-28 1980-03-27 HYDROFORMYLATING AGENT, PROCESS FOR ITS PRODUCTION AND USE OF SUCH HYDROFORMYLATING AGENT IN THE PRODUCTION OF ALDEHYDE.

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
DE2912230 1979-03-28
DE2912230A DE2912230B1 (en) 1979-03-28 1979-03-28 Process for the recovery and reactivation of used rhodium and phosphine-containing catalysts from reaction products of rhodium-catalyzed oxosynthesis
US5812379A 1979-07-16 1979-07-16
US06/120,101 US4297239A (en) 1979-07-16 1980-02-28 Hydroformylation catalyst reactivation
US58123 1993-05-10
US120101 1998-07-21

Publications (3)

Publication Number Publication Date
EP0017183A2 EP0017183A2 (en) 1980-10-15
EP0017183A3 true EP0017183A3 (en) 1981-01-07
EP0017183B1 EP0017183B1 (en) 1984-04-25

Family

ID=27187939

Family Applications (1)

Application Number Title Priority Date Filing Date
EP80101665A Expired EP0017183B1 (en) 1979-03-28 1980-03-27 Hydroformylation medium, process of production thereof and process for producing aldehydes using the hydroformylation medium

Country Status (11)

Country Link
EP (1) EP0017183B1 (en)
AU (1) AU541966B2 (en)
BR (1) BR8001825A (en)
DE (1) DE3067607D1 (en)
DK (1) DK132780A (en)
ES (2) ES489995A0 (en)
HU (1) HU188563B (en)
MX (1) MX155342A (en)
NO (1) NO156742C (en)
SG (1) SG86986G (en)
YU (1) YU43217B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3046355A1 (en) * 1980-12-09 1982-07-15 Basf Ag, 6700 Ludwigshafen METHOD FOR HYDROFORMYLATING OLEFINICALLY UNSATURATED COMPOUNDS
US4363764A (en) * 1980-12-30 1982-12-14 Union Carbide Corporation Preparation of rhodium complex compounds
GB2097795B (en) * 1981-05-01 1984-08-01 Johnson Matthey Plc Recovering triaryl phosphine from poisoned thodium catalyst systems
DE3420491A1 (en) * 1984-06-01 1985-12-05 Ruhrchemie Ag, 4200 Oberhausen METHOD FOR PRODUCING ALDEHYDES
US5001274A (en) * 1989-06-23 1991-03-19 Union Carbide Chemicals And Plastics Company Inc. Hydroformylation process
MXPA05002283A (en) 2002-08-31 2005-06-08 Oxeno Olefinchemie Gmbh Method for the hydroformylation of olefinically unsaturated compounds, especially olefins, in the presence of cyclic carbonic acid esters.
US7667079B2 (en) * 2005-04-21 2010-02-23 Oxea Corporation Processes for recovery of a triarylphosphine from a group VIII metal catalyst complex mixture
CN102143933B (en) 2008-07-03 2014-09-17 陶氏技术投资有限公司 Process of controlling heavies in a recycle catalyst stream
CN102515286B (en) * 2011-11-14 2014-01-15 中国海洋石油总公司 Method for preparing high-purity rhodium chloride by using waste rhodium catalyst digestion solution
SE1930249A1 (en) * 2019-07-18 2020-11-17 Perstorp Ab Use of a method for reduction of heavy end formation and catalyst loss in a hydroformylation process comprising a bidentate phosphite ligand

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1338237A (en) * 1969-12-22 1973-11-21 Union Carbide Corp Hydroformylation process
DE2406323A1 (en) * 1974-02-09 1975-08-21 Ruhrchemie Ag Continuous hydroformylation of olefinic cpds - using recycled rhodium-contg product-distn residue as catalyst in presence of water
GB1440413A (en) * 1973-09-21 1976-06-23 Mitsubishi Chem Ind Process for producing butyraldehydes
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1338237A (en) * 1969-12-22 1973-11-21 Union Carbide Corp Hydroformylation process
GB1440413A (en) * 1973-09-21 1976-06-23 Mitsubishi Chem Ind Process for producing butyraldehydes
DE2406323A1 (en) * 1974-02-09 1975-08-21 Ruhrchemie Ag Continuous hydroformylation of olefinic cpds - using recycled rhodium-contg product-distn residue as catalyst in presence of water
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins

Also Published As

Publication number Publication date
EP0017183B1 (en) 1984-04-25
ES8104781A1 (en) 1981-05-16
YU43217B (en) 1989-06-30
DE3067607D1 (en) 1984-05-30
AU541966B2 (en) 1985-01-31
AU5686880A (en) 1980-10-02
YU81080A (en) 1986-04-30
MX155342A (en) 1988-02-19
NO156742C (en) 1987-11-18
EP0017183A2 (en) 1980-10-15
ES8104175A1 (en) 1981-04-01
HU188563B (en) 1986-04-28
BR8001825A (en) 1980-11-18
NO800820L (en) 1980-09-29
DK132780A (en) 1980-09-29
NO156742B (en) 1987-08-10
SG86986G (en) 1991-01-18
ES494730A0 (en) 1981-05-16
ES489995A0 (en) 1981-04-01

Similar Documents

Publication Publication Date Title
DE2965157D1 (en) Process for the production of aldehydes by hydroformylation of alkenes
DE3060487D1 (en) Process for the production of alpha,beta olefinically unsaturated aldehydes containing 3 or 4 c-atoms
YU190277A (en) Process for producing methacrolein
GB2023597B (en) Process for producing methacrolein
DE3169669D1 (en) Process for the manufacture of polyvinyl alcohol, and the polyvinyl alcohol obtained
DE3067607D1 (en) Hydroformylation medium, process of production thereof and process for producing aldehydes using the hydroformylation medium
DE3060336D1 (en) Process for the production of citral
GB2033775B (en) Catalysts and process for the production of methacrolein catalysts
YU40601B (en) Process for obtaining aldehydes
DE3168976D1 (en) Process for the preparation of i-alkenes, catalyst useful therefor and process for the production thereof
DE3063315D1 (en) Process for the production of 2,6-dialkylcyclohexylamines
DE3063676D1 (en) Process for the production of higher unsaturated ketones
DE2960744D1 (en) Process for the preparation of aldehydes
DE3061510D1 (en) Process for the production of olefinically unsaturated carbonyl compounds and alcohols
DE3061326D1 (en) Process for the continuous production of glyoxal
EP0012942A3 (en) Process for producing benzaldehydes
DE3170330D1 (en) Process for the production of aldehydes and intermediate products
DE3171113D1 (en) Process for the production of phenyl substituted aldehydes and of phenyl substituted alcohols
HU179757B (en) Process for producing aldehydes
EP0011401A3 (en) Process for the production of cyano-substituted aldehydes and alcohols
GB2091256B (en) Process for producing 6-phenoxypicolinic aldehydes
ZA824921B (en) Process for producing aldehydes
IL57511A0 (en) 3-phenoxy-and 3-benzylbenzylideneamines,their production and their use for preparing the corresponding aldehydes
IT8021036A0 (en) IMPROVED PROCESS FOR THE PRODUCTION OF 3-O-DEMETHYLFORTYMICINS.
ZA747154B (en) Hard board or medium density board process for production thereof and means for practicizing the process

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT NL SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT NL SE

17P Request for examination filed

Effective date: 19810622

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: UNION CARBIDE CORPORATION

ITF It: translation for a ep patent filed
GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT NL SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Effective date: 19840425

REF Corresponds to:

Ref document number: 7222

Country of ref document: AT

Date of ref document: 19840515

Kind code of ref document: T

REF Corresponds to:

Ref document number: 3067607

Country of ref document: DE

Date of ref document: 19840530

ET Fr: translation filed
REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

26 Opposition filed

Opponent name: BASF AKTIENGESELLSCHAFT

Effective date: 19841212

NLR1 Nl: opposition has been filed with the epo

Opponent name: BASF AG

REG Reference to a national code

Ref country code: FR

Ref legal event code: LD

PLBN Opposition rejected

Free format text: ORIGINAL CODE: 0009273

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: OPPOSITION REJECTED

27O Opposition rejected

Effective date: 19881201

NLR2 Nl: decision of opposition
ITTA It: last paid annual fee
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19930112

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19930331

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19931231

Year of fee payment: 15

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Effective date: 19940327

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19941001

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 19950130

Year of fee payment: 16

EAL Se: european patent in force in sweden

Ref document number: 80101665.0

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Effective date: 19950327

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19950327

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Effective date: 19960331

BERE Be: lapsed

Owner name: UNION CARBIDE CORP.

Effective date: 19960331

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19990302

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19990304

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19990305

Year of fee payment: 20

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: THE PATENT HAS BEEN ANNULLED BY A DECISION OF A NATIONAL AUTHORITY

Effective date: 20000330

EUG Se: european patent has lapsed

Ref document number: 80101665.0

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO