EA044070B1 - HERBICIDALLY ACTIVE 3-PHENYLISOXAZOLINE-5-CARBOXAMIDES OF CYCLOPENTENYLCARBOXYLIC ACID DERIVATIVES - Google Patents

Description

The invention relates to the technical field of herbicides, in particular herbicides for selective control of weeds and weeds in healthy cereal crops.

This invention particularly concerns substituted 3-phenylisoxazoline-5-carboxamides and

5-thioamides from cyclopentenylcarboxylic acid derivatives, methods of their preparation and use as herbicides.

WO 1995/014681 A1, WO1995/014680 A1, WO 2008/035315 A1, WO 2005/051931 A1 and WO 2005/021515 A1 describe, inter alia, respectively, 3-phenylisoxazoline-5-carboxamides which are substituted on the phenyl ring at 3 and 4 positions with alkoxy residues. Among other things, WO 1998/057937 A1 describes compounds which are substituted at 4 positions on the phenyl ring by alkoxy residues. Among other things, WO 2006/016237 A1 describes compounds which are substituted at 4 positions on the phenyl ring with amido residues. The compounds described in the previously mentioned documents have pharmacological effects.

WO 2005/021516 A1 discloses 3-(([3-(3-tert-butylphenyl)-5-ethyl-4,5-dihydro-1,2-oxazol-5yl]carbonyl)amino)-5-fluoro-4 -oxopentane and 3-(([3-(3-tert-butylphenyl)-5-isopropyl-4,5-dihydro1,2-oxazol-5-yl]carbonyl)amino)-5-fluoro-4-oxopentanoic acids in as pharmacologically effective compounds.

From DE 4026018 A1, EP 0520371 A2 and DE 4017665 3-phenylisoxazoline-5-carboxamides are known which have a hydrogen atom in the 5th position of the isoxazoline ring. These compounds are described there as agrochemically acting protective agents, i.e. as compounds that eliminate the undesirable herbicidal effect of herbicides on crop plants. The herbicidal effect of these compounds has not been disclosed. Priority, previously unpublished European patent application No. 10170238 reveals herbicidal and fungicidal 3-phenylisoxazoline-5-carboxamides and 3-phenylisoxazoline-5-thioamides, which have a hydrogen atom in the 5th position of the isoxazoline ring. From Monatshefte Chemie (2010), 141, 461; and Letters in Organic Chemistry (2010), 7, 502, 3-phenylisoxazoline-5-carboxamides are also known, which have a hydrogen atom at the 5-position of the isoxazoline ring. Some of these compounds exhibit fungicidal activity but no herbicidal activity.

WO 2014/048827 describes the herbicidal action of 3-phenylisoxazoline-5-carboxylic acids, 3-phenylisoxazoline-5-carboxylic acid esters, 5-carbaldehydes and 5-nitriles.

WO 2014/048853 describes isoxazoline-5-carboxamides and -5-thioamides with heterocycles in the 3rd position (herbicide and fungicide).

WO 2014/048940 has a quinoline as a special heterocycle in the 3rd position (fungicide), WO 2014/048882 has an alkoxy as a special residue in the 5th position.

WO 2014/048882 describes isoxazoline carboxamides with alkoxy as a special residue in the 5th position.

WO 2012/130798 describes herbicidal and fungicidal active 3-phenylisoxazoline-5carboxamides and 5-thioamides of substituted heterocycles.

The herbicidal action of these known compounds, especially at low application rates, or their compatibility with crop plants must be improved.

As a result of the above reasons, there is a need for stronger herbicides and/or plant growth regulators for selective use in crops or for use in non-crop plants, these active substances preferably having other advantageous properties for use, such as improved compatibility with crops. plants.

Therefore, the object of the present invention is to obtain compounds with herbicidal action (herbicides), which, even at a relatively low application rate, are highly effective against economically important harmful plants and, preferably, with good effectiveness against harmful plants, should be used selectively in cultivated plants, and when In this case, they should preferably show good compatibility with cultivated plants. Preferably, these herbicidal compounds should be particularly effective and efficient against a wide range of weeds, and preferably additionally exhibit good effectiveness against many weeds.

In addition to the herbicidal effect, numerous compounds of formula (I) also have a fungicidal effect, which, however, is only minor.

Surprisingly, it has been found that the following 3-phenylisoxazoline-5-carboxamides from the cyclopentenylcarboxylic acids of formula (I) and their salts exhibit excellent herbicidal activity against a wide range of economically important mono- and dicotyledonous annual pests.

- 1 044070

The subjects of the present invention are therefore the compounds of general formula (I)

and their agriculturally acceptable salts, in which

G is a group of the formula OR ⁴ or NR ⁿ R ¹² ;

R ¹ and R ² are, independently of each other, hydrogen, halogen or cyano or suitably substituted by m residues from the group consisting of halogen and cyano, (C ₁ -C ₄ )-alkyl or (C 1 -C ₄ )-alkoxy;

R ³ means cyano or fluorine or suitably substituted with m residues from the group consisting of halogen, cyano, (C ₁ -C ₅ )-alkoxy and hydroxy, (C 1 -C ₅ )-alkyl, (C ₃ -C ₆ )-cycloalkyl , (C ₂ -C ₅ )-alkenyl, (C ₂ -C ₅ )-alkynyl or (C1-C ₅ )-alkoxy;

R ⁴ means hydrogen or suitably substituted with m residues from the group consisting of halogen, cyano, (C1-C ₆ )-alkoxy, hydroxy and aryl, (C1-C ₁₂ )-alkyl, (C ₃ -C ₇ )-cycloalkyl, (C ₃ -C ₇ )-cycloalkyl(C1-C ₈ )-alkyl, (C ₂ -C ₈ )-alkenyl, (C ₅ -C ₆ )-cycloalkenyl or (C ₂ -C ₈ )-alkynyl;

Y stands for oxygen or sulfur;

W stands for oxygen or sulfur;

Z is a monounsaturated cyclopentane ring, which is substituted with residues from the group ^R10 , ( ^R1 °)k

z, with the arrow correspondingly indicating the connection with the C=W group of formula (I);

R ¹⁰ means halogen, cyano or CO2R ⁷ or suitably substituted with m residues from the group consisting of fluorine and chlorine, (C1- _C2 )-alkyl or (C1- _C2 )-alkoxy;

R ¹¹ , R ¹² mean, independently of each other, hydrogen, cyano, OR ⁷ , S(O)nR ⁵ , so2nr ⁶ r ⁷ , co2r ⁸ , conr ⁶ r ⁸ , cor ⁶ , nr ⁶ r ⁸ , nr ⁶ cor ⁸ , nr ⁶ conr ⁸ r ⁸ , nr ⁶ co2r ⁸ , nr ⁶ so2r ⁸ , nr ⁶ so2nr ⁶ r ⁸ , C(R ⁶ )=NOR ⁸ , optionally substituted aryl, optionally substituted heteroaryl and optionally substituted heterocyclyl, or respectively substituted by m residues from the group consisting of halogen, cyano, nitro, OR ⁷ , S(O)nR ⁵ , SO2NR6R ⁷ , CO2R ⁸ , CONR ⁶ R ⁸ , COR ⁶ , NR ⁶ R ⁸ , NR ⁶ COR ⁸ , NR ⁶ CONR ⁸ R ⁸ , NR ⁶ CO2R ⁸ , NR ⁶ SO2R ⁸ , NR ⁶ SO2NR ⁶ R ⁸ , C(R ⁶ )=NOR ⁸ , optionally substituted aryl, optionally substituted heteroaryl and optionally substituted heterocyclyl, substituted (C1- C ₁₂ )-alkyl, (C ₃ -C ₈ )-cycloalkyl, (C ₃ -C ₇ )-cycloalkyl-(C ₁ -C ₇ )-alkyl, (C ₂ -C ₁₂ )-alkenyl, (C ₅ - C ₇ )-cycloalkenyl or (C ₂ -C ₁₂ )-alkynyl; or

R ¹¹ and R ¹² together with the nitrogen atom to which they are attached form, if necessary, substituted one to six times with residues from the group consisting of halogen, cyano, nitro, (C1-C6)-alkyl, halogen(C1-C6)- alkyl, oxo, OR ⁷ , S(O)nR ⁵ , SO2NR ⁶ R ⁷ , CO2R ⁸ , CONR ⁶ R ⁸ , COR ⁶ , NR ⁶ R ⁸ , NR ⁶ COR ⁸ , NR ⁶ CONR ⁸ R ⁸ , NR ⁶ CO ₂ R ⁸ , NR ⁶ SO2R ⁸ , NR ⁶ SO2NR ⁶ R ⁸ and C(R ⁶ )=NOR ⁸ , a saturated, partially or fully unsaturated five-, six- or seven-membered ring, which in addition to the indicated nitrogen atom contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the group consisting of NR ⁷ and NCOR ⁷ as ring atoms;

X ² , X ⁴ and X ⁶ mean, independently of each other, hydrogen, halogen or cyano or substituted, respectively, by m radicals from the group consisting of fluorine, chlorine, bromine and (C1- _C2 )-alkoxy, (C1- _C2 )- alkyl;

X ³ and X ⁵ mean, independently of each other, hydrogen, fluorine, chlorine, bromine, iodine, hydroxy, cyano, nitro, S(O)nR ⁶ or CO2R ⁷ or respectively substituted by m residues from the group consisting of fluorine, chlorine and bromine, (C1-C3)-alkyl, (C1- _C3 )-alkoxy, ( _C3 - _C4 )-cycloalkyl, ( _C2 - _C3 )-alkenyl or (C2 _{- C3} )-alkynyl;

R ⁵ is suitably substituted with m residues from the group consisting of halogen, cyano and hydroxy, (C1- _C8 )-alkyl, ( _C3 - _C6 )-cycloalkyl or aryl;

R ⁶ is hydrogen or R ⁵ ;

R ⁷ means hydrogen or suitably substituted with m residues from the group consisting of halogen, cyano and (C1- _C2 )-alkoxy, (C1- _C6 )-alkyl, ( _C3 - _C6 )-cycloalkyl, ( _C3 - C ₄ )-alkenyl or (C ₃ -C ₄ )-alkynyl;

R ⁸ means hydrogen or suitably substituted with m residues from the group consisting of halogen, cyano and (C1- _C2 )-alkoxy, (C1- _C8 )-alkyl, ( _C3 - _C6 )-cycloalkyl, ( _C3 - C ₈ )-alkenyl or (C ₃ -C ₈ )-alkynyl;

k means an ordinal number 0, 1 or 2, and for k>1 R ¹⁰ can be the same or different independently of each other;

m means the ordinal number 0, 1, 2, 3, 4 or 5;

- 2 044070 n means the ordinal number 0, 1 or 2;

o means the ordinal number 0, 1 or 2;

p means the ordinal number 0 or 1;

q means ordinal number 0 or 1; and r means the ordinal number 3, 4, 5 or 6.

Alkyl means a saturated, linear or branched hydrocarbon residue, respectively, with a specified number of carbon atoms, for example C ₁ -C ₆ -alkyl, such as methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, 1, 1-dimethylethyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1-ethylpropyl, hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1- ethylbutyl, 2-ethylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl and 1-ethyl-2-methylpropyl.

Halogen-substituted alkyl means linear or branched alkyl groups, and in these groups the hydrogen atoms may be partially or completely replaced by halogen atoms, for example C ₁ -C ₂ -haloalkyl, such as chloromethyl, bromomethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl , dichlorofluoromethyl, chlorodifluoromethyl, 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro,2-difluoroethyl , 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl and 1,1,1-trifluoroprop-2-yl.

Alkenyl means unsaturated, linear or branched hydrocarbon residues, respectively, with the indicated number of carbon atoms and a double bond in any position, for example C ₂ -C ₆ -alkenyl, such as ethenyl, 1-propenyl, 2-propenyl, 1-methylethenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-methyl-1-propenyl, 2-methyl-1-propenyl, 1-methyl-2-propenyl, 2-methyl-2-propenyl, 1-pentenyl, 2-pentenyl, 3- pentenyl, 4-pentenyl, 1-methyl-1-butenyl, 2-methyl-1-butenyl, 3-methyl-1-butenyl, 1-methyl2-butenyl, 2-methyl-2-butenyl, 3-methyl-2- butenyl, 1-methyl-3-butenyl, 2-methyl-3-butenyl, 3-methyl-3-butenyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1,2-dimethyl- 2-propenyl, 1-ethyl-1-propenyl, 1-ethyl-2-propenyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1-methyl-1-pentenyl, 2- methyl-1-pentenyl, 3-methyl-1-pentenyl, 4-methyl-1-pentenyl, 1-methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl, 4-methyl- 2-pentenyl, 1-methyl-3-pentenyl, 2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1-methyl-4-pentenyl, 2-methyl-4- pentenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1-dimethyl-3-butenyl, 1,2-dimethyl-1-butenyl, 1, 2-dimethyl-2-butenyl, 1,2-dimethyl3-butenyl, 1,3-dimethyl-1-butenyl, 1,3-dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl, 2,2- dimethyl-3-butenyl, 2,3-dimethyl-1-butenyl, 2,3-dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 3,3-dimethyl-1-butenyl, 3,3- dimethyl2-butenyl, 1-ethyl-1-butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyl, 2-ethyl-1-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3- butenyl, 1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl, 1-ethyl-2-methyl-1-propenyl and 1-ethyl-2-methyl-2-propenyl.

Alkynyl means linear or branched hydrocarbon residues, respectively, with the indicated number of carbon atoms and a triple bond in any position, for example C ₂ -C ₆ -alkynyl, such as ethynyl, 1-propynyl, 2-propynyl (or propargyl), 1-butynyl, 2- butynyl, 3-butynyl, 1-methyl-2-propynyl, 1-pentynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 3-methyl-1-butynyl, 1-methyl-2-butynyl, 1-methyl- 3butynyl, 2-methyl-3-butynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 1-hexynyl, 2-hexynyl, 3hexynyl, 4-hexynyl, 5-hexynyl, 3-methyl- 1-pentynyl, 4-methyl-1-pentynyl, 1-methyl-2-pentynyl, 4methyl-2-pentynyl, 1-methyl-3-pentynyl, 2-methyl-3-pentynyl, 1-methyl-4-pentynyl, 2-methyl-4-pentynyl, 3-methyl-4-pentynyl, 1,1-dimethyl-2-butynyl, 1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2- dimethyl3-butynyl, 3,3-dimethyl-1-butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-butynyl, 2-ethyl-3-butynyl and 1-ethyl-1methyl-2-propynyl.

Cycloalkyl means a carbocyclic, saturated ring system, preferably with 3-8 ring C-atoms, for example cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl. If, if desired, a substituted cycloalkyl is present, then a cyclic system with substituents is also present, and substituents with a double bond on the cycloalkyl moiety are also present, for example an alkylidene group such as methylidene.

If a substituted cycloalkyl is optionally present, multicyclic aliphatic systems are also contained, such as, for example, bicyclo[1.1.0]butan-1-yl, bicyclo[1.1.0]butan-2-yl, bicyclo[2.1.0]pentan- 1-yl, bicyclo[2.1.0]pentan-2-yl, bicyclo[2.1.0]pentan-5-yl, bicyclo[2.2.1]hept-2-yl (norbornyl), adamantan-1-yl and adamantane -2-il.

If a substituted cycloalkyl is also present, then a spirocyclic aliphatic system is also present, such as spiro[2.2]pent-1-yl, spiro[2.3]hex-1-yl, spiro[2.3]hex-4-yl, 3-spiro [2.3]hex5-yl.

Cycloalkenyl means a carbocyclic, non-aromatic, partially unsaturated ring system, preferably with 4-8 C atoms, for example 1-cyclobutenyl, 2-cyclobutenyl, 1-cyclopentenyl, 2-cyclopentenyl, 3-cyclopentenyl, or 1-cyclohexenyl, 2-cyclohexenyl, 3-cyclohexenyl, 1,3-cyclohexadienyl or 1,4-cyclohexadienyl, whereby substituents with a double bond on the cycloalkenyl moiety are also present, for example an alkylidene group such as methylidene. If at

- 3 044070 if substituted cycloalkenyl is present, the explanations also apply to substituted cycloalkyl.

Alkyl means a saturated, straight-chain or branched hydrocarbon residue, respectively, with a specified number of carbon atoms, for example C ₁ -C ₆ -alkoxy, such as methoxy, ethoxy, propoxy, 1-methylethoxy, butoxy, 1-methylpropoxy, 2-methylpropoxy, 1,1-dimethylethoxy, pentoxy, 1-methylbutoxy, 2-methylbutoxy, 3-methylbutoxy, 2,2-dimethylpropoxy, 1-ethylpropoxy, hexoxy, 1,1-dimethylpropoxy, 1,2-dimethylpropoxy, 1-methylpentoxy, 2-methylpentoxy, 3-methylpentoxy, 4-methylpentoxy, 1,1-dimethylbutoxy, 1,2-dimethylbutoxy, 1,3-dimethylbutoxy, 2,2-dimethylbutoxy, 2,3-dimethylbutoxy, 3,3-dimethylbutoxy, 1- ethylbutoxy, 2-ethylbutoxy, 1,1,2-trimethylpropoxy, 1,2,2-trimethylpropoxy, 1-ethyl-1-methylpropoxy and 1-ethyl-2-methylpropoxy. Halogen-substituted alkyl means straight-chain or branched alkoxy residues with a corresponding number of carbon atoms, and in these groups the hydrogen atoms can be partially or completely replaced by halogen atoms, for example C ₁ -C ₂ -haloalkoxy, such as chloromethoxy, bromomethoxy, dichloromethoxy, trichloromethoxy, fluoromethoxy, difluoromethoxy, trifluoromethoxy, chlorofluoromethoxy, dichlorofluoromethoxy, chlorodifluoromethoxy, 1-chloroethoxy, 1-bromoethoxy, 1-fluoroethoxy, 2-fluoroethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro- 2-fluoroethoxy, 2-chloro-1,2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy, pentafluoroethoxy and 1,1,1-trifluoroprop-2-oxy.

The term aryl means an optionally substituted mono-, bi- or polycyclic aromatic system, preferably with 6-14, especially preferably 6-10 ring C-atoms, for example phenyl, naphthyl, anthryl, phenanthrenyl, etc., preferably phenyl.

The term optionally substituted aryl also includes multicyclic systems such as tetrahydronaphthyl, indenyl, indenyl, fluorenyl, biphenylyl, where the junction is on the aromatic system. From a systematic point of view, the term aryl also includes the term, optionally, substituted phenyl.

The aryls listed above are preferably independently substituted one to five times, for example with hydrogen, halogen, alkyl, haloalkyl, hydroxy, alkoxy, cycloalkoxy, aryloxy, alkoxyalkyl, alkoxyalkoxy, cycloalkyl, halocycloalkyl, aryl, arylalkyl, heteroaryl, heterocyclyl, alkenyl, alkylcarbonyl, cycloalkylcarbonyl, arylcarbonyl, heteroarylcarbonyl, alkoxycarbonyl, hydroxycarbonyl, cycloalkoxycarbonyl, cycloalkylalkoxycarbonyl, alkoxycarbonylalkyl, arylalkoxycarbonyl, arylalkoxycarbonylalkyl, alkynyl, alkynylalkyl, alkylalkynyl, tris-al kylsilylalkynyl, nitro, amino, cyano, haloalkoxy, haloalkylthio, alkylthio, hydrothio, hydroxyalkyl, heteroarylalkoxy, arylalkoxy, heterocyclylalkoxy, heterocyclylalkylthio, heterocyclyloxy, heterocyclylthio, heteroaryloxy, bis-alkylamino, alkylamino, cycloalkylamino, hydroxycarbonylalkylamino, alkoxy-carbonylalkylamino, arylalkoxycarbonylalkylamino, alkoxycarbonyl-alkyl(alkyl)amino, aminocarbonyl, alkylaminocar bonyl, bis-alkylaminocarbonyl, cycloalkylaminocarbonyl, hydroxycarbonyl-alkylaminocarbonyl, alkoxycarbonylalkylaminocarbonyl, arylalkoxycarbonylalkylaminocarbonyl.

A heterocyclic residue (heterocyclyl) contains at least one heterocyclic ring (=carbocyclic ring in which at least one C-atom is replaced by a heteroatom, preferably one heteroatom from the group N, O, S, P), which is saturated, unsaturated, partially saturated or heteroaromatic and may be unsubstituted or substituted, the site of connection being on the ring atom.

If the heterocyclic moiety or heterocyclic ring is optionally substituted, it can be annulated with other carbocyclic or heterocyclic rings. If the heterocyclic moiety or heterocyclic ring is optionally substituted, it can be annealed to other carbocyclic or heterocyclic rings. If, if necessary, a substituted heterocyclyl is present, then multicyclic systems are also present, such as 8-aza-bicyclo[2.2.2]octanyl or 1-aza-bicyclo[2.2.1]heptyl. If, if desired, a substituted heterocyclyl is present, spirocyclic systems are also present, such as 1-oxa-5-aza-spiro[2.3]hexyl. Unless otherwise specified, the heterocyclic ring preferably contains 3-9 ring atoms, especially preferably 3-6 ring atoms, and one or more, preferably 1-4, especially preferably 1, 2 or 3 heteroatoms in the heterocyclic ring, preferably from group N , O, and S, however, two oxygen atoms should not be located next to each other, such as, for example, with one heteroatom from the group N, O and S 1- or 2- or 3-pyrrolidinyl, 3,4-dihydro- 2H-pyrrol-2- or 3-yl, 2,3-dihydro-1H-pyrrol-1- or 2-, or 3-, or 4-, or 5-yl; 2,5-dihydro-1H-pyrrol-1-or 2-or 3-yl, 1-or 2-or 3-or 4-piperidinyl; 2,3,4,5-tetrahydropyridin-2-or 3-or 4-or 5-yl or 6-yl; 1,2,3,6-tetrahydropyridin-1-or 2-or 3-or 4-or 5-or 6-yl; 1,2,3,4-tetrahydropyridin-1-or 2-or 3-or 4-or 5-or 6-yl; 1,4dihydropyridin-1-or 2-or 3-or 4-yl; 2,3-dihydropyridin-2-or 3-or 4-or 5-or 6-yl; 2,5dihydropyridin-2-or 3-or 4-or 5-or 6-yl, 1-or 2-or 3-or 4-azepanil; 2,3,4,5-tetrahydro1H-azepine-1-or 2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,4,7-tetrahydro-1H-azepine-1-or 2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,6,7-tetrahydro-1H-azepine-1-or 2-or 3-or 4-yl; 3,4,5,6- 4 044070 tetrahydro-2H-azepine-2-or 3-or 4-or 5-or 6-or 7-yl; 4,5-dihydro-1H-azepine-1- or 2- or 3- or 4-yl; 2,5-dihydro-1H-azepine-1- or -2- or 3- or 4- or 5- or 6- or 7-yl; 2,7-dihydro-III-azepine 1- or -2- or 3- or 4-yl; 2,3-dihydro-1H-azepine-1- or -2- or 3- or 4- or 5- or 6- or 7-yl; 3,4-dihydro-2H-azepine-2-or 3-or 4-or 5-or 6-or 7-yl; 3,6-dihydro-2H-azepine-2-or 3-or 4-or 5-or 6-or 7-yl; 5,6-dihydro-2H-azepine-2-or 3-or 4-or 5-or 6-or 7-yl; 4,5dihydro-3H-azepine-2- or 3- or 4- or 5- or 6- or 7-yl; 1H-azepine-1-or -2-, or 3-, or 4-, or 5-, or 6-, or 7-yl; 2H-azepine-2-or 3-or 4-or 5-or 6-or 7-yl; 3H-azepine-2-or 3-or 4-or 5-or 6-or 7-yl; 4H-azepine-2-or 3-or 4-or 5-or 6-or 7-yl, 2-or 3-oxolanyl (= 2-or 3-tetrahydrofuranyl); 2,3-dihydrofuran-2-or 3-or 4-or 5-yl; 2,5-dihydrofuran-2-or 3-yl, 2-or 3-or 4-oxanyl (= 2-or 3-or 4-tetrahydropyranyl); 3,4-dihydro-2H-pyran-2- or 3- or 4- or 5- or 6-yl; 3,6-dihydro-2H-pyran-2-or 3-or 4-or 5-or 6-yl; 2H-pyran-2- or 3- or 4- or 5- or 6-yl; 4H-pyran-2-or 3-or 4-yl, 2-or 3-or 4-oxepanyl; 2,3,4,5-tetrahydrooxepin-2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,4,7-tetrahydrooxepin-2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,6,7-tetrahydrooxepin-2-or 3-or 4-yl; 2,3-dihydrooxepin-2-or 3-or 4-or 5-or 6-or 7-yl; 4,5-dihydrooxepin-2- or 3- or 4-yl; 2,5-dihydrooxepin-2-or 3-or 4-or 5-or 6-or 7-yl; oxepin-2- or 3-, or 4-, or 5-, or 6-, or 7-yl; 2- or 3-tetrahydrothiophenyl; 2,3-dihydrothiophen-2 or 3- or 4- or 5-yl; 2,5-dihydrothiophen-2- or 3-yl; tetrahydro-2H-thiopyran-2- or 3- or 4-yl; 3,4-dihydro-2H-thiopyran-2-or 3-or 4-or 5-or 6-yl; 3,6-dihydro-2H-thiopyran-2-or 3-or 4-or 5-or 6-yl; 2H-thiopyran-2-or 3-or 4-or 5-or 6-yl; 4H-thiopyran-2-or 3-or 4-yl. Preferred 3-ring and 4-ring heterocycles are, for example, 1- or 2-aziridinyl, oxiranyl, thiiranyl, 1- or 2- or 3-azetidinyl, 2- or 3-oxetanyl, 2- or 3-thietanyl, 1 ,3-dioxetan2-yl. Other examples of heterocyclyls are a partially or fully hydrogenated heterocyclic residue with two heteroatoms from the group N, O and S, such as 1- or 2- or 3- or 4-pyrazolidinyl 4,5-dihydro-3H-pyrazol-3- , or 4-, or 5-yl; 4,5-dihydro-1H-pyrazol-1- or 3- or 4- or 5-yl; 2,3-dihydro-1H-pyrazol-1-or 2-or 3-or 4-or 5-yl; 1-or 2-or 3-or 4-imidazolidinyl 2,3-dihydro-1H-imidazol-1-or 2-or 3-or 4-yl; 2,5-dihydro-1H-imidazol-1- or 2- or 4- or 5-yl; 4,5-dihydro-1H-imidazol-1- or 2- or 4- or 5-yl; hexahydropyridazin-1- or 2- or 3- or 4-yl; 1,2,3,4-tetrahydropyridazin-1-or 2-or 3-or 4-or 5-or 6-yl; 1,2,3,6tetrahydropyridazin-1-or 2-or 3-or 4-or 5-or 6-yl; 1,4,5,6-tetrahydropyridazin-1-or 3-or 4-or 5-or 6-yl; 3,4,5,6-tetrahydropyridazin-3-, or 4-, or 5-yl; 4,5-dihydropyridazin-3 or 4-yl; 3,4-dihydropyridazin-3-or 4-or 5-or 6-yl; 3,6-dihydropyridazin-3- or 4-yl; 1,6-dihydropyriazin-1- or 3- or 4- or 5- or 6-yl; hexahydropyrimidin-1-or 2-or 3-or 4-yl; 1,4,5,6-tetrahydropyrimidin-1-or 2-or 4-or 5-or 6-yl; 1,2,5,6-tetrahydropyrimidin-1-or 2-or 4-or 5-or 6-yl; 1,2,3,4-tetrahydropyrimidin-1-or 2-or 3-or 4-or 5-or 6-yl; 1,6-dihydropyrimidin-1-or 2-or 4-or 5-or 6-yl; 1,2-dihydropyrimidin-1-or 2-or 4-or 5-or 6-yl; 2,5-dihydropyrimidin-2-, or 4-, or 5-yl; 4,5-dihydropyrimidin-4- or 5- or 6-yl; 1,4-dihydropyrimidin-1- or 2- or 4- or 5- or 6-yl; 1- or 2- or 3-piperazinyl; 1,2,3,6tetrahydropyrazin-1- or 2- or 3- or 5- or 6-yl; 1,2,3,4-tetrahydropyrazin-1-or 2-or 3-or 4-or 5-or 6-yl; 1,2-dihydropyrazin-1-or 2-or 3-or 5-or 6-yl; 1,4-dihydropyrazin-1 - or 2- or 3-yl; 2,3-dihydropyrazin-2-or 3-or 5-or 6-yl; 2,5-dihydropyrazin-2- or 3-yl; 1,3-dioxolan-2-, or 4-, or 5-yl; 1,3-dioxol-2- or 4-yl; 1,3-dioxane-2-, or 4-, or 5-yl; 4H-1,3dioxin-2- or 4-, or 5-, or 6-yl; 1,4-dioxane-2-or 3-or 5-or 6-yl; 2,3-dihydro-1,4-dioxin-2 or 3- or 5- or 6-yl; 1,4-dioxin-2- or 3-yl; 1,2-dithiolan-3- or 4-yl; 3H-1,2-dithiol-3-, or 4-, or 5-yl; 1,3-dithiolan-2- or 4-yl; 1,3-dithiol-2- or 4-yl; 1,2-dithian-3- or 4-yl; 3,4-dihydro-1,2-dithiin-3 or 4- or 5- or 6-yl; 3,6-dihydro-1,2-dithiin-3- or 4-yl; 1,2-dithiin-3- or 4-yl; 1,3-dithian-2-, or 4-, or 5-yl; 4H-1,3-dithiin-2-or 4-or 5-or 6-yl; isoxazolidin-2- or 3- or 4- or 5-yl; 2,3-dihydroisoxazol-2-or 3-or 4-or 5-yl; 2,5-dihydroisoxazol-2-or 3-or 4-or 5-yl; 4,5-dihydroisoxazol-3-or 4-or 5-yl; 1,3-oxazolidin-2-or 3-or 4-or 5-yl; 2,3-dihydro-1,3oxazol-2-or 3-or 4-or 5-yl; 2,5-dihydro-1,3-oxazol-2-, or 4-, or 5-yl; 4,5-dihydro-1,3-oxazol2-, or 4-, or 5-yl; 1,2-oxazinan-2-or 3-or 4-or 5-or 6-yl; 3,4-dihydro-2H-1,2-oxazin-2-or 3-or 4-or 5-or 6-yl; 3,6-dihydro-2H-1,2-oxazin-2-or 3-or 4-or 5-or 6-yl; 5,6-dihydro2H-1,2-oxazin-2-or 3-or 4-or 5-or 6-yl; 5,6-dihydro-4H-1,2-oxazin-3-or 4-or 5-or 6-yl; 2H-1,2-oxazin-2-or 3-or 4-or 5-or 6-yl; 6H-1,2-oxazin-3-or 4-or 5-or 6-yl; 4H-1,2oxazin-3-or 4-, or 5-, or 6-yl; 1,3-oxazinan-2-or 3-or 4-or 5-or 6-yl; 3,4-dihydro-2H-1,3oxazin-2-or 3-or 4-or 5-or 6-yl; 3,6-dihydro-2H-1,3-oxazin-2-or 3-or 4-or 5-or 6-yl; 5,6-dihydro-2H-1,3-oxazin-2-or 4-or 5-or 6-yl; 5,6-dihydro-4H-1,3-oxazin-2-or 4-or 5-or 6-yl; 2H-1,3-oxazin-2-or 4-or 5-or 6-yl; 6H-1,3-oxazin-2-or 4-or 5-or 6-yl; 4H-1,3oxazin-2-or 4-or 5-or 6-yl; morpholin-2- or 3- or 4-yl; 3,4-dihydro-2H-1,4-oxazin-2-or 3-or 4-or 5-or 6-yl; 3,6-dihydro-2H-1,4-oxazin-2-or 3-or 5-or 6-yl; 2H-1,4-oxazin-2-or 3-or 5-or 6-yl; 4H-1,4-oxazin-2- or 3-yl; 1,2-oxazepane-2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,4,5-tetrahydro-1,2-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,4,7-tetrahydro-1,2oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,6,7-tetrahydro-1,2-oxazepine-2-or 3-or

- 5 044070

4-, or 5-, or 6-, or 7-yl; 2,5,6,7-tetrahydro-1,2-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 4,5,6,7-tetrahydro-1,2-oxazepine-3-or 4-or 5-or 6-or 7-yl; 2,3-dihydro-1,2-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 2,5-dihydro-1,2-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 2,7-dihydro-1,2-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 4,5-dihydro-1,2-oxazepine-3-or 4-or 5-or 6-or 7-yl; 4,7-dihydro-1,2-oxazepine-3-or 4-or 5-or 6-or 7-yl; 6,7-dihydro-1,2oxazepine-3-or 4-or 5-or 6-or 7-yl; 1,2-oxazepine-3-or 4-or 5-or 6-or 7-yl; 1,3-oxazepane-2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,4,5-tetrahydro-1,3-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,4,7-tetrahydro-1,3-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,6,7-tetrahydro-1,3-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 2,5,6,7-tetrahydro-1,3oxazepine-2-or 4-or 5-or 6-or 7-yl; 4,5,6,7-tetrahydro-1,3-oxazepine-2-or 4-or 5-or 6-or 7-yl; 2,3-dihydro-1,3-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 2,5-dihydro-1,3oxazepine-2-or 4-or 5-or 6-or 7-yl; 2,7-dihydro-1,3-oxazepine-2-or 4-or 5-or 6-or 7-yl; 4,5-dihydro-1,3-oxazepine-2-or 4-or 5-or 6-or 7-yl; 4,7-dihydro-1,3-oxazepine-2-or 4-or 5-or 6-or 7-yl; 6,7-dihydro-1,3-oxazepine-2-or 4-or 5-or 6-or 7-yl; 1,3-oxazepine-2 or 4-, or 5-, or 6-, or 7-yl; 1,4-oxazepan-2-or 3-or 5-or 6-or 7-yl; 2,3,4,5-tetrahydro-1,4oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,4,7-tetrahydro-1,4-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 2,3,6,7-tetrahydro-1,4-oxazepine-2-or 3-or 5-or 6-or 7-yl; 2,5,6,7tetrahydro-1,4-oxazepine-2-or 3-or 5-or 6-or 7-yl; 4,5,6,7-tetrahydro-1,4-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 2,3-dihydro-1,4-oxazepine-2-or 3-or 5-or 6-or 7-yl; 2,5-dihydro-1,4-oxazepine-2-or 3-or 5-or 6-or 7-yl; 2,7-dihydro-1,4-oxazepine-2-or 3-or 5-or 6-or 7-yl; 4,5-dihydro-1,4-oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 4,7-dihydro-1,4oxazepine-2-or 3-or 4-or 5-or 6-or 7-yl; 6,7-dihydro-1,4-oxazepine-2-or 3-or 5-or 6-or 7-yl; 1,4-oxazepine-2-or 3-or 5-or 6-or 7-yl; isothiazolidin-2- or 3- or 4- or 5-yl; 2,3-dihydroisothiazol-2-or 3-or 4-or 5-yl; 2,5-dihydroisothiazol-2-or 3-or 4-or 5-yl; 4,5-dihydroisothiazol-3-, or 4-, or 5-yl; 1,3-thiazolidin-2-or 3-or 4-or 5-yl; 2,3-dihydro-1,3thiazol-2-or 3-or 4-or 5-yl; 2,5-dihydro-1,3-thiazol-2-, or 4-, or 5-yl; 4,5-dihydro-1,3-thiazol-2-, or 4-, or 5-yl; 1,3-thiazinan-2-or 3-or 4-or 5-or 6-yl; 3,4-dihydro-2H-1,3-thiazin-2-or 3-or 4-or 5-or 6-yl; 3,6-dihydro-2H-1,3-thiazin-2-or 3-or 4-or 5-or 6-yl; 5,6-dihydro-2H1,3-thiazin-2-or 4-or 5-or 6-yl; 5,6-dihydro-4H-1,3-thiazin-2-or 4-or 5-or 6-yl; 2H-1,3thiazin-2-or 4-or 5-or 6-yl; 6H-1,3-thiazin-2-or 4-or 5-or 6-yl; 4H-1,3-thiazin-2-or 4-or 5-or 6-yl. Other examples of heterocyclyl are a partially or fully hydrogenated heterocyclic residue with 3 heteroatoms from the group N, O and S, such as 1,4,2-dioxazolidin-2 or 3-or 5-yl; 1,4,2-dioxazol-3- or 5-yl; 1,4,2-dioxazinan-2- or -3- or 5- or 6-yl; 5,6-dihydro1,4,2-dioxazin-3- or 5- or 6-yl; 1,4,2-dioxazin-3- or 5- or 6-yl; 1,4,2-dioxazepane-2-or 3-or 5-or 6-or 7-yl; 6,7-dihydro-5H-1,4,2-dioxazepine-3-or 5-or 6-or 7-yl; 2,3-dihydro-7H-1,4,2dioxazepine-2-or 3-or 5-or 6-or 7-yl; 2,3-dihydro-5H-1,4,2-dioxazepine-2-or 3-or 5-or 6-or 7-yl; 5H-1,4,2-dioxazepine-3-or 5-or 6-or 7-yl; 7H-1,4,2-dioxazepine-3-or 5-or 6-or 7-yl.

The heterocycles listed above are preferably substituted independently of each other one to six times, for example, with hydrogen, halogen, alkyl, haloalkyl, hydroxy, alkoxy, cycloalkoxy, aryloxy, alkoxyalkyl, alkoxyalkoxy, cycloalkyl, halocycloalkyl, aryl, arylalkyl, heteroaryl, heterocyclyl, alkenyl, alkylcarbonyl, cycloalkylcarbonyl, arylcarbonyl, heteroarylcarbonyl, alkoxycarbonyl, hydroxycarbonyl, cycloalkoxycarbonyl, cycloalkylalkoxycarbonyl, alkoxycarbonylalkyl, arylalkoxycarbonyl, arylalkoxycarbonylalkyl, alkynyl, alkynylalkyl, alkylalkynyl, tris-alkylsilylalkyne silt, nitro, amino, cyano, haloalkoxy, haloalkylthio, alkylthio, hydrothio, hydroxyalkyl, oxo, heteroarylalkoxy, arylalkoxy, heterocyclylalkoxy, heterocyclylalkylthio, heterocyclyloxy, heterocyclylthio, heteroaryloxy, bis-alkylamino, alkylamino, cycloalkylamino, hydroxycarbonylalkylamino, alkoxycarbonylalkylamino, arylalkoxycarbonylalkylamino, alkoxycarbonylalkyl(alkyl)amino, aminocarbonyl , alkylaminocarbonyl, bis-alkylaminocarbonyl, cycloalkyl-aminocarbonyl, hydroxycarbonylalkylaminocarbonyl, alkoxycarbonyl-alkylaminocarbonyl, arylalkoxycarbonyl-alkylaminocarbonyl.

If the main substance is substituted by one or more residues from the list of residues (=groups) or from the main group of residues, then it can accordingly be simultaneously replaced by several identical and/or structurally different residues.

If we are talking about a partially or completely saturated nitrogen heterocycle, then it can be connected to the rest of the molecule using both carbon and nitrogen.

As substituents for the substituted heterocyclic radical, the following substituents, also additionally oxo and thioxo, are taken into account. An oxo group as a substituent on the ring C atom then means, for example, a carbonyl group on a heterocyclic ring. Which also preferably includes lactones and lactams. The oxo group can also arise on ring heteroatoms, which can be at different stages of oxidation, for example, at N and S, and form in this case, for example, the divalent group N(O), S(O) (also abbreviated SO ) and S(O)2 (also abbreviated SO2) in the heterocyclic ring. In the case of -N(O)- and -S(O)-groups, both enantiomers are present, respectively.

According to the invention, the term heteroaryl means heteroaromatic compounds, i.e. fully unsaturated aromatic heterocyclic compounds, preferably 5-7 membered rings with 1-4, preferably 1 or 2 identical or different heteroatoms, preferably O, S or N. Heteroaryls according to the invention are, for example, N-pyrrol-1-yl; Sh-pyrrol-2-yl; Sh-pyrrol-3-yl; furan-2-yl; furan-3-yl; thien-2-yl; thien-3-yl, 1H-imidazol-1-yl; 1H-imidazol-2-yl; 1H-imidazol-4-yl; 1H-imidazol-5-yl; 1H-pyrazol-1-yl; 1H-pyrazol-3-yl; 1H-pyrazol-4-yl; 1H-pyrazol5-yl, 1H-1,2,3-triazol-1-yl, 1H-1,2,3-triazol-4-yl, 1H-1,2,3-triazol-5-yl, 2H- 1,2,3-triazol-2-yl, 2H-1,2,3triazol-4-yl, 1H-1,2,4-triazol-1-yl, 1H-1,2,4-triazol-3- yl, 4H-1,2,4-triazol-4-yl, 1,2,4-oxadiazol-3-yl, 1,2,4-oxadiazol-5-yl, 1,3,4-oxadiazol-2- yl, 1,2,3-oxadiazol-4-yl, 1,2,3-oxadiazol-5-yl, 1,2,5-oxadiazol-3yl, azepinil, pyridin-2-yl, pyridin-3-yl, pyridin-4-yl, pyrazin-2-yl, pyrazin-3-yl, pyrimidin-2-yl, pyrimidin-4-yl, pyrimidin-5-yl, pyridazin-3-yl, pyridazin-4-yl, 1, 3,5-triazin-2-yl, 1,2,4-triazin-3yl, 1,2,4-triazin-5-yl, 1,2,4-triazin-6-yl, 1,2,3- triazin-4-yl, 1,2,3-triazin-5-yl, 1,2,4-, 1,3,2-, 1,3,6- and 1,2,6-oxazinyl, isoxazole-3 -yl, isoxazol-4-yl, isoxazol-5-yl, 1,3-oxazol-2-yl, 1,3-oxazol-4-yl, 1,3-oxazol-5-yl, isothiazol-3-yl , isothiazol-4-yl, isothiazol-5-yl, 1,3-thiazol-2-yl, 1,3-thiazol-4-yl, 1,3-thiazol-5-yl, oxepinil, thiepinil, 1,2 ,4-triazoloniol and 1,2,4-diazepinyl, 2H-1,2,3,4-tetrazol-5-yl, 1H-1,2,3,4-tetrazol-5-yl, 1,2,3 ,4-oxatriazol-5-yl, 1,2,3,4-thiatriazol-5-yl, 1,2,3,5-oxatriazol-4-yl, 1,2,3,5-thiatriazol-4-yl . Further, the heteroaryl groups according to the invention can be substituted by one or more identical or different radicals. If two adjacent carbon atoms are a component of another aromatic ring, then we are talking about annellated heteroaromatic systems, such as benzofused or several times annellated heteroaromatic compounds.

Preferred, for example, are quinolines (for example, quinolin-2-yl, quinolin-3-yl, quinolin-4-yl, quinolin-5-yl, quinolin-6-yl, quinolin-7-yl, quinolin-8-yl ); isoquinolines (eg, isoquinolin-1-yl, isoquinolin-3-yl, isoquinolin-4-yl, isoquinolin-5-yl, isoquinolin-6-yl, isoquinolin-7-yl, isoquinolin-8-yl); quinoxaline; quinazoline; cinnoline; 1,5-naphthyridine; 1,6-naphthyridine; 1,7-naphthyridine; 1,8-naphthyridine; 2,6-naphthyridine; 2,7-naphthyridine; phthalazine; pyridopyrazine; pyridopyrimidine; pyridopyridazines; pteridines; pyrimidopyrimidine. Examples of heteroaryl are also 5- or 6-membered benzo-fused rings from the group 1H-indol-1-yl, 1H-indol-2-yl, 1H-indol-3-yl, 1H-indol4-yl, 1H-indol-5- yl, 1H-indol-6-yl, 1H-indol-7-yl, 1-benzofuran-2-yl, 1-benzofuran-3-yl, 1-benzofuran-4-yl, 1-benzofuran-5-yl, 1- benzofuran-6-yl, 1-benzofuran-7-yl, 1-benzothiophen-2-yl, 1-benzothiophen-3-yl, 1-benzothiophen-4-yl, 1-benzothiophen-5-yl, 1-benzothiophen- 6-yl, 1-benzothiophen-7yl, 1H-indazol-1-yl, 1H-indazol-3-yl, 1H-indazol-4-yl, 1H-indazol-5-yl, 1H-indazol-6-yl, 1H-indazol-7-yl, 2H-indazol-2-yl, 2H-indazol-3-yl, 2H-indazol-4-yl, 2H-indazol-5-yl, 2H-indazol6-yl, 2H-indazol- 7-yl, 2H-isoindol-2-yl, 2H-isoindol-1-yl, 2H-isoindol-3-yl, 2H-isoindol-4-yl, 2H-isoindol-5-yl, 2H-isoindol-6- silt; 2H-isoindol-7-yl, 1H-benzimidazol-1-yl, 1H-benzimidazol-2-yl, 1H-benzimidazol-4-yl, 1H-benzimidazol-5-yl, 1H-benzimidazol-6-yl, 1H-benzimidazol- 7-yl, 1,3-benzoxazol-2-yl, 1,3-benzoxazol-4-yl, 1,3-benzoxazol-5-yl, 1,3-benzoxazol-6-yl, 1,3-benzoxazol- 7yl, 1,3-benzthiazol-2-yl, 1,3-benzthiazol-4-yl, 1,3-benzthiazol-5-yl, 1,3-benzthiazol-6-yl, 1,3-benzthiazol-7yl, 1,2-benzisoxazol-3-yl, 1,2-benzisoxazol-4-yl, 1,2-benzisoxazol-5-yl, 1,2-benzisoxazol-6-yl, 1,2-benzisoxazol-7-yl, 1,2-benzisothiazol-3-yl, 1,2-benzisothiazol-4-yl, 1,2-benzisothiazol-5-yl, 1,2-benzisothiazol-6-yl, 1,2-benzisothiazol-7-yl.

The heteroaryls listed above are preferably substituted independently of each other one to six times, for example, with hydrogen, halogen, alkyl, haloalkyl, hydroxy, alkoxy, cycloalkoxy, aryloxy, alkoxyalkyl, alkoxyalkoxy, cycloalkyl, halocycloalkyl, aryl, arylalkyl, heteroaryl, heterocyclyl, alkenyl, alkylcarbonyl, cycloalkylcarbonyl, arylcarbonyl, heteroarylcarbonyl, alkoxycarbonyl, hydroxycarbonyl, cycloalkoxycarbonyl, cycloalkylalkoxycarbonyl, alkoxycarbonylalkyl, arylalkoxycarbonyl, arylalkoxycarbonylalkyl, alkynyl, alkynylalkyl, alkylalkynyl, tris-alkylsilylalkyne silt, nitro, amino, cyano, haloalkoxy, haloalkylthio, alkylthio, hydrothio, hydroxyalkyl, oxo, heteroarylalkoxy, arylalkoxy, heterocyclylalkoxy, heterocyclylalkylthio, heterocyclyloxy, heterocyclylthio, heteroaryloxy, bis-alkylamino, alkylamino, cycloalkylamino, hydroxycarbonylalkylamino, alkoxycarbonylalkylamino, arylalkoxycarbonylalkylamino, alkoxycarbonylalkyl(alkyl)amino, aminocarbonyl , alkylaminocarbonyl, bis-alkylaminocarbonyl, cycloalkyl-aminocarbonyl, hydroxycarbonylalkylaminocarbonyl, alkoxycarbonylalkylaminocarbonyl, arylalkoxycarbonylalkylaminocarbonyl.

The term halogen means fluorine, chlorine, bromine or iodine. When this term is used for a residue, halogen means a fluorine, chlorine, bromine or iodine atom.

The compounds of formula (I), depending on the type and type of substituents, may be present in the form of stereoisomers. For example, if one or more asymmetric substituted atoms are present

- 7 044070 carbon and/or sulfoxide, thus enantiomers and diastereomers can occur. Stereoisomers can arise when mixtures are prepared by conventional separation methods, for example, using chromatographic separation methods. It is also possible to selectively obtain stereoisomers using stereoselective reactions using optically active starting materials and/or auxiliary substances.

The present invention also applies to all stereoisomers and mixtures thereof which are contained in formula (I) but are not specifically defined. However, in the following, for the sake of brevity, we speak only of the compounds of formula (I), although they can be represented both as pure compounds and, if necessary, mixtures with various components of isomeric compounds.

Depending on the type of the above-mentioned substituents, the compounds of formula (I) have acidic properties and, together with inorganic or organic bases or metal ions, can also, if necessary, form internal salts or adducts. If the compounds of formula (I) contain hydroxy, carboxy or other groups that induce acidic properties, then these compounds can be converted into salts with bases. Suitable bases are, for example, hydroxides, carbonates, hydrocarbonates of alkali and alkaline earth metals, in particular sodium, potassium, magnesium and calcium, also ammonia, primary, secondary and tertiary amines with (C^CC-alkyl groups, mono-, di- and trialkanolamines (C1- _C4 )-alkanols, choline and also chlorocholine, as well as organic amines such as trialkylamines, morpholine, piperidine or pyridine.These salts are compounds in which the acidic hydrogen is replaced by an agriculturally suitable cation, e.g. metals, in particular alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or also ammonium salts, salts with organic amines or quaternary ammonium salts, for example with cations of the formula [NRR'RR'] ⁺ , where R -R''' respectively independently of each other represent an organic radical, in particular alkyl, aryl, arylalkyl or alkylaryl.Alkylsulfonium and alkylsulfoxonium salts are also taken into account, such as (CrCC-trialkylsulfonium and (C1-C4)-trialkylsulfonium salts).

The compounds of formula (I) during the addition of suitable inorganic or organic acids, such as mineral acids, such as HCl, HBr, H2SO ₄ , H ₃ PO ₄ or HNO ₃ , or organic acids, such as carboxylic acids, such as formic acid, acetic acid, propionic acid, oxalic acid, lactic or salicylic acid or sulfonic acids, such as ptoluenesulfonic acid, can form salts to an alkaline group, such as amino, alkylamino, dialkylamino, piperidino, morpholino or pyridino. These salts contain the conjugate base of the acid as an anion.

Suitable substituents that are present in deprotonated form, such as sulfonic acids or carboxylic acids, can form internal salts with groups that are protonated on their part, such as amino groups.

If a group is substituted several times by residues, it means that the group is substituted by one or more of the same or different residues mentioned.

In all the following formulas, substituents and symbols, unless otherwise indicated, have the same meaning as in formula (I). The arrows in the chemical formula indicate the sites of attachment to the residual molecule.

Preferred, especially preferred and highly preferred meanings for individual substituents are described below, respectively. The remaining substituents of the general formula (I), which are not named below, have the above meanings.

In a first embodiment of the present invention, R ¹ and R 2 are preferably, independently of each other, hydrogen, fluorine, chlorine or cyano, or suitably substituted with m residues from the group consisting of fluorine, chlorine, bromine and cyano, (C1-C ₃ )- alkyl or (C ₁ -C ₃ )-alkoxy.

Particularly preferably, R ¹ and R 2 are, independently of each other, respectively hydrogen, fluorine, chlorine or cyano, or respectively substituted with m residues from the group consisting of fluorine and chlorine, methyl or methoxy.

Most preferably, R ¹ and R ² are respectively hydrogen.

In a second embodiment of the present invention, R ³ is preferably cyano, or suitably substituted with m residues from the group consisting of fluorine, chlorine, bromine, cyano, (C1- _C4 )-alkoxy and hydroxy, (C1- _C4 )-alkyl, (C ₃ -C ₅ )-cycloalkyl, (C2-C ₄ )-alkenyl, (C2-C ₄ )-alkynyl or (C ₁ -C ₄ )-alkoxy.

Particularly preferably, R ³ is suitably substituted with m radicals from the group consisting of fluorine, chlorine and (C ₁ -C ₂ )-alkoxy, (C 1 -C ₃ )-alkyl, (C ₃ -C ₄ )-cycloalkyl, (C ₂ -C ₃ )-alkenyl or (C ₁ -C ₃ )-alkoxy.

In a third embodiment of the present invention, R ⁴ is preferably hydrogen, or suitably substituted with m radicals from the group consisting of fluorine, chlorine, bromine, cyano, (C1- _C4 )-alkoxy, hydroxy and aryl, (C1- _C6 )- alkyl, (C ₃ -C ₆ )-cycloalkyl, (C ₃ -Cb)-cycloalkyl-(C ₁ -Cb)-alkyl, (C ₂ -C ₆ )-alkenyl, (C ₅ -C ₆ )-cycloalkenyl or (C ₂ -C ₆ )-alkynyl.

In the fourth embodiment of the present invention, Y is oxygen.

- 8 044070

In a fifth embodiment of the present invention, W is oxygen.

In the sixth embodiment of the present invention, Z is preferably the group

Z-1-Z-22, with Z-1-Z-22 having the following meanings:

wherein the arrow respectively denotes a connection with the C=W group of formula (I).

- 9 044070

Particularly preferably, Z is the group Z-1-Z-12, with Z-1-Z-12 having the following meanings:

wherein the arrow respectively denotes a connection with the C=W group of formula (I). Most preferably, Z means Z-1, Z-4 and Z-6:

Z-1 z-4 Z-6, with the arrow respectively indicating the connection with the C=W group of formula (I).

In a seventh embodiment of the present invention, R ¹⁰ is preferably fluorine, chlorine, cyano, CO2H, CO2CH3 or CO2CH2CH3 or suitably substituted with m residues from the group consisting of fluorine and chlorine, (C1- _C2 )-alkyl or ( _C1 - _C2 )-alkoxy.

In the eighth embodiment of the present invention, R ¹¹ is preferably hydrogen or suitably substituted with m residues from the group consisting of fluorine and chlorine, (C ₁ -C ₃ )-alkyl or (C ₃ -C ₆ )-cycloalkyl.

In the ninth embodiment of the present invention, R ¹² is preferably hydrogen, cyano, OR ⁷ , S(O)nR ⁵ , SO2NR6R ⁷ , COR ⁶ , NR6R ⁸ , NR6COR ⁸ or NR6SO2R ⁸ or suitably substituted with m residues from the group consisting of fluorine, chlorine, bromine, cyano, OR ⁷ , S(O)nR ⁵ , NR6R ⁸ and NR6CO2R ⁸ , (C1- _C6 )-alkyl, ( _C3 - _C6 )-cycloalkyl, ( _C2 - _C3 )-alkenyl or (C ₂ -C ₃ )-alkynyl.

In a tenth embodiment of the present invention, R ¹¹ and R ¹² preferably together with the nitrogen atom to which they are attached form, optionally substituted one-six times with residues from the group consisting of halogen, cyano, nitro, (C1-C6)-alkyl, halogen -(C1-C6)alkyl, oxo, OR ⁷ , S(O)n R ⁵ , CO2R ⁸ , COR ⁶ , NR6COR ⁸ and NR6SO2R ⁸ , a saturated, partially or fully unsaturated five-, six- or seven-membered ring, which in the addition to said nitrogen atom contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the group consisting of NR ⁷ and NCOR ⁷ as ring atoms.

Particularly preferably, R ¹¹ and R ¹² together with the nitrogen atom to which they are attached form, if necessary, substituted one to six times with residues from the group consisting of halogen, cyano, nitro, (C1-C ₆ )-alkyl, halogen-(C ₁ -C ₆ )-alkyl, oxo, OR ⁷ , CO2R ⁸ and NR6SO2R ⁸ , a saturated, partially or fully unsaturated five-, six- or seven-membered ring, which in addition to the indicated nitrogen atom contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the group consisting of NR ⁷ and NCOR ⁷ as ring atoms.

Most preferably, R ¹¹ and R ¹² together with the nitrogen atom to which they are attached form, optionally substituted one to six times with residues from the group consisting of halogen, (C1- _C6 )-alkyl, halogen-( _C1 - _C6 )-alkyl and oxo, saturated, partially or fully unsaturated five-, six- or seven-membered ring which, in addition to the said nitrogen atom, contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the group consisting of NR ⁷ and NCOR ⁷ as ring atoms.

In an eleventh embodiment of the present invention, X ² , X ⁴ and X ⁶ are preferably, independently of each other, hydrogen, fluorine, chlorine, bromine or cyano, or suitably substituted with m residues from the group consisting of fluorine and chlorine, methyl or methoxy.

Particularly preferably, X ² , X ⁴ and X ⁶ are independently hydrogen or fluorine.

- 10 044070

In the twelfth embodiment of the present invention, X ³ and X ⁵ are preferably, independently of each other, hydrogen, fluorine, chlorine, bromine, hydroxy or cyano, or suitably substituted with m residues from the group consisting of fluorine, chlorine and bromine, (C1-C ₃ )-alkyl, (C1- _C3 )-alkoxy, ( _C3 - _C4 )-cycloalkyl, (C2- _C3 )-alkenyl or (C2- _C3 )-alkynyl.

Particularly preferably, X ³ and X ⁵ are, independently of each other, hydrogen, fluorine, chlorine, CF ₃ , CHF 2 or methyl.

In a thirteenth embodiment of the present invention, R ⁵ is preferably suitably substituted with m residues from the group consisting of fluorine and chlorine, (C1-C6)-alkyl or (C ₃ -C ₆ )-cycloalkyl.

In a fourteenth embodiment of the present invention, R ⁷ is preferably hydrogen, or suitably substituted with m radicals from the group consisting of fluorine, chlorine and (C ₁ -C ₂ )-alkoxy, (C ₁ -C ₆ )-alkyl or (C ₃ - C ₆ )-cycloalkyl.

In the fifteenth embodiment of the present invention, R ⁸ is preferably hydrogen, or suitably substituted with m radicals from the group consisting of fluorine, chlorine and (C ₁ -C ₂ )-alkoxy, (C ₁ -C ₆ )-alkyl or (C ₃ - C ₆ )-cycloalkyl.

In the sixteenth embodiment of the present invention, m is an ordinal number 0, 1, 2 or 3.

Within the framework of this invention, it is possible to combine individual preferred, especially preferred and most preferred values for the substituents R ¹ - R ⁸ , R ¹⁰ - R ¹² , X ² - X ⁶ , W, Y and Z, as well as the ordinal numbers k, m, n , o, p, q and r in any way with each other.

This means that the present invention provides compounds of general formula (I) in which, for example, the substituent R ¹ has a preferred meaning and the substituents R ⁵ -R ⁷ have a general meaning, or the substituent R ² has a preferred meaning and the substituent R ³ has a particularly preferred meaning value or highly preferred value and the remaining substituents have a general meaning.

These four combinations of the above-defined values for the substituents R1- ^R8 , ^R10 - ^R12 , ^X2 - ^X6 , W, Y and Z, as well as the ordinal values k, m, n, o, p, q and r are described below in more detail in detail based on examples, and accordingly other embodiments are also presented for better explanation.

In the seventeenth embodiment of the present invention

G means a group of the formula OR ⁴ ;

R ¹ and R ² are, independently of each other, hydrogen, fluorine, chlorine or cyano, or suitably substituted by m radicals from the group consisting of fluorine, chlorine, bromine and cyano, (C1- _C3 )-alkyl or (C1- _C3 )-alkoxy;

R ³ means cyano or suitably substituted with m residues from the group consisting of fluorine, chlorine, bromine, cyano, (C1- _C2 )-alkoxy and hydroxy, (C1- _C3 )-alkyl, ( _C3 - _C4 )- cycloalkyl, (C ₂ -C ₃ )-alkenyl, (C ₂ -C ₃ )-alkynyl or (C ₁ -C ₃ )-alkoxy;

R ⁴ means hydrogen or suitably substituted with m residues from the group consisting of fluorine, chlorine, bromine, cyano, (C ₁ -C ₄ )-alkoxy, hydroxy and aryl, (C 1 -C ₆ )-alkyl, (C ₃ -C ₆ )-cycloalkyl, (C ₃ -C ₆ )-cycloalkyl-(C ₁ -C ₆ )-alkyl, (C ₂ -C ₆ )-alkenyl, (C ₅ -C ₆ )-cycloalkenyl or (C ₂ -C ₆ )-alkynyl.

Y is for oxygen; W stands for oxygen;

Z means the group Z-1-Z-12, with Z-1-Z-12 having the following meanings:

wherein the arrow respectively denotes a connection with the C=W group of formula (I);

X ² , X ⁴ and X ⁶ are, independently of each other, hydrogen, fluorine, chlorine, bromine or cyano

- 11 044070 or suitably substituted with m residues from the group consisting of fluorine and chlorine, methyl or methoxy;

X ³ and X ⁵ mean, independently of each other, hydrogen, fluorine, chlorine, bromine, hydroxy or cyano, or respectively substituted by m residues from the group consisting of fluorine, chlorine and bromine, (C ₁ -C ₃ )-alkyl, (C _g C ₃ )-alkoxy, (C ₃ -C ₄ )-cycloalkyl, (C ₂ -C ₃ )-alkenyl or (C ₂ -C ₃ )-alkynyl; and m means the ordinal number 0, 1, 2 or 3.

In the eighteenth embodiment of the present invention

G means a group of the formula OR ⁴ ;

R ¹ and R ² are respectively hydrogen;

R ³ means suitably substituted with m residues from the group consisting of fluorine, chlorine and (C ₁ -C ₂ )-alkoxy, (C 1 -C ₃ )-alkyl, (C ₃ -C ₄ )-cycloalkyl, (C ₂ -C ₃ )-alkenyl or (C1- _C3 )-alkoxy;

R ⁴ means hydrogen, or suitably substituted with m residues from the group consisting of fluorine, chlorine, bromine, cyano, (C1- _C4 )-alkoxy, hydroxy and aryl, (C1- _C6 )-alkyl, ( _C3 -C ₆ )-cycloalkyl, (C ₃ -C ₆ )-cycloalkyl (C ₁ -C ₆ )-alkyl, (C ₂ -C ₆ )-alkenyl, (C ₅ -C ₆ )-cycloalkenyl or (C ₂ -C ₆ )-alkynyl;

Y is for oxygen; W stands for oxygen;

Z means group Z-1, Z-4 and Z-6:

wherein the arrow respectively denotes a connection with the C=W group of formula (I);

X ² , X ⁴ and X ⁶ are independently of each other hydrogen or fluorine;

X ³ and X ⁵ are, independently of each other, respectively hydrogen, fluorine, chlorine, CF ₃ , CHF ₂ or methyl; and m means the ordinal number 0, 1, 2 or 3.

In the nineteenth embodiment of the present invention

G represents a group of the formula NR11R ¹² ;

R ¹ and R ² are, independently of each other, hydrogen, fluorine, chlorine or cyano, or suitably substituted with m radicals from the group consisting of fluorine, chlorine, bromine and cyano, (C1- _C3 )-alkyl or ( _C1 -C ₃ )-alkoxy;

R ³ means cyano, or suitably substituted with m residues from the group consisting of fluorine, chlorine, bromine, cyano, (C ₁ -C ₂ )-alkoxy and hydroxy, (C 1 -C ₃ )-alkyl, (C ₃ -C ₄ )-cycloalkyl, (C ₂ -C ₃ )-alkenyl or (C1-C ₃ )-alkoxy;

Y is for oxygen; W stands for oxygen;

Z means the group Z-1-Z-12, with Z-1-Z-12 having the following meanings:

wherein the arrow respectively denotes a connection with the C=W group of formula (I);

X ² , X ⁴ and X ⁶ are, independently of each other, respectively hydrogen, fluorine, chlorine, bromine or cyano, or respectively substituted by m residues from the group consisting of fluorine and chlorine, methyl or methoxy;

X ³ and X ⁵ mean, independently of each other, hydrogen, fluorine, chlorine, bromine, hydroxy or cyano, or respectively substituted by m residues from the group consisting of fluorine, chlorine and bromine (C ₁ -C ₃ )-alkyl, (C ₁ -C ₃ )-alkoxy, (C ₃ -C ₄ )-cycloalkyl, (C ₂ -C ₃ )-alkenyl or (C ₂ -C ₃ )-alkynyl; And

- 12 044070

R ⁵ is suitably substituted with m residues from the group consisting of fluorine and chlorine, (C1- _C6 )-alkyl or ( _C3 - _C6 )-cycloalkyl;

R ⁶ is hydrogen or R ⁵ ;

R ⁷ is hydrogen, or suitably substituted with m radicals from the group consisting of fluorine, chlorine and (C1-C2)-alkoxy, (C1- _C6 )-alkyl or ( _C3 - _C6 )-cycloalkyl;

R ⁸ is hydrogen, or suitably substituted with m radicals from the group consisting of fluorine, chlorine and (C1-C2)-alkoxy, (C1- _C6 )-alkyl or (C3- _C6 )-cycloalkyl;

R ¹¹ means hydrogen, or suitably substituted with m residues from the group consisting of fluorine and chlorine, (C1-C3)-alkyl or (C3-C ₆ )-cycloalkyl;

R ¹² is preferably hydrogen, cyano, OR ⁷ , S(O)nR ⁵ , SO2NR6R ⁷ , COR ⁶ , NR ⁶ R ⁸ , NR ⁶ COR ⁸ or NR6SO2R ⁸ , or suitably substituted with m residues from the group consisting of fluorine, chlorine , bromine, cyano, OR ⁷ , S(O)nR ⁵ , NR ⁶ R ⁸ and NR6CO2R ⁸ , (C1-C ₆ )-alkyl, (C3-C ₆ )-cycloalkyl, (C ₂ -C3)-alkenyl or (C ₂ -C ₃ )-alkynyl; or

R ¹¹ and R ¹² together with the nitrogen atom to which they are attached form, if necessary, substituted one to six times with residues from the group consisting of halogen, cyano, nitro, (C1-C ₆ )-alkyl, halogen-(C ₁ - C ₆ )-alkyl, oxo, OR ⁷ , CO2R ⁸ and NR6SO2R ⁸ , a saturated, partially or fully unsaturated five-, six- or seven-membered ring which, in addition to the indicated nitrogen atom, contains r carbon atoms, o oxygen atoms, p atoms sulfur and q elements from the group consisting of NR ⁷ and NCOR ⁷ as ring atoms;

m means ordinal number 0,1,2 or 3.

n means the ordinal number 0, 1 or 2;

o means the ordinal number 0, 1 or 2;

p means the ordinal number 0 or 1;

q means ordinal number 0 or 1; and r means the ordinal number 3, 4 or 5.

In the twentieth embodiment of the present invention

G represents a group of the formula NR11R ¹² ;

R ¹ and R ² are respectively hydrogen;

R ³ means suitably substituted with m residues from the group consisting of fluorine, chlorine and (C1- _C2 )-alkoxy, (C1- _C3 )-alkyl, ( _C3 - _C4 )-cycloalkyl, ( _C2 - _C3 )-alkenyl or (C1- _C3 )-alkoxy;

Y is for oxygen; W stands for oxygen; Z means group Z-1, Z-4 and Z-6:

Z-1 Z-4 z-6, with the arrow respectively indicating the connection with the C=W group of formula (I);

X ² , X ⁴ and X ⁶ are independently of each other hydrogen or fluorine;

X ³ and X ⁵ are, independently of each other, hydrogen, fluorine, chlorine, CF3, CHF2 or methyl;

R ⁵ is suitably substituted with m residues from the group consisting of fluorine and chlorine, (C ₁ -C ₆ )-alkyl or (C ₃ -C ₆ )-cycloalkyl;

R ⁶ is hydrogen or R ⁵ ;

R ⁷ is hydrogen, or suitably substituted with m residues from the group consisting of fluorine, chlorine and (C1- _C2 )-alkoxy, ( _C1 - _C6 )-alkyl or ( _C3 - _C6 )-cycloalkyl;

R ⁸ is hydrogen, or suitably substituted with m residues from the group consisting of fluorine, chlorine and (C ₁ -C ₂ )-alkoxy, (C ₁ -C ₆ )-alkyl or (C ₃ -C ₆ )-cycloalkyl;

R ¹¹ means hydrogen, or suitably substituted with m residues from the group consisting of fluorine and chlorine, (C ₁ -C ₃ )-alkyl or (C ₃ -C ₆ )-cycloalkyl;

R ¹² means hydrogen, cyano, OR ⁷ , S(O)nR ⁵ , SO2NR ⁶ R ⁷ , COR ⁶ , NR ⁶ R ⁸ , NR ⁶ COR ⁸ or NR ⁶ SO2R ⁸ or suitably substituted with m residues from the group consisting of fluorine , chlorine, bromine, cyano, OR ⁷ , S(O)nR ⁵ , NR ⁶ R ⁸ and NR6CO2R ⁸ , (C1-C6)-alkyl, (C ₃ -C ₆ )-cycloalkyl, (C ₂ -C ₃ ) -alkenyl or (C ₂ -C ₃ )-alkynyl; or

R ¹¹ and R ¹² together with the nitrogen atom to which they are attached form, optionally substituted one to six times with residues from the group consisting of halogen, (C1-C ₆ )-alkyl, halogen-(C1-C ₆ )alkyl and an oxo, saturated, partially or fully unsaturated five-, six- or seven-membered ring which, in addition to the said nitrogen atom, contains r carbon atoms, o oxygen atoms, p sulfur atoms and q elements from the group consisting of NR ⁷ and NCOR ⁷ , as ring atoms;

m means the ordinal number 0, 1, 2 or 3;

n means the ordinal number 0, 1 or 2;

o means the ordinal number 0, 1 or 2;

p means the ordinal number 0 or 1;

q means ordinal number 0 or 1; And

- 13 044070 r means the ordinal number 3, 4 or 5.

Below, examples of compounds of general formula (I) are presented in table form. In the next table. 1 the substituents defined in formula (I) are indicated individually.

Table 1.1

Compounds of general formula (I), with X ² =X ⁴ =X ⁶ =R ¹ =R ² =H, Y=W=O and G=OR ⁴

Example No. X ³ X ⁵ R ³ Z R ⁴ Note 1-001 n F СНз Z-1 n (1H,48)-cyclopent-2ene-1-carboxyl 1-002 n F СНз Z-1 n (18.4K)-cyclopent-2ene-1-carboxyl 1-003 n F СНз Z-1 СНз (1C,48)-cyclopent-2ene-1-carboxyl 1-004 n F СНз Z-1 СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-005 n F СНз Z-1 CH ₂ CHZ (1H,48)-cyclopent-2ene-1-carboxyl 1-006 n F СНз Z-1 CH ₂ CHZ (18.4K)-cyclopent-2ene-1-carboxyl 1-007 F F СНз Z-1 С(СНз)з (18.4K)-cyclopent-2ene-1-carboxyl 1-008 F F СНз Z-1 benzyl (18.4K)-cyclopent-2ene-1-carboxyl 1-009 F F СНз Z-1 CH ₂ CH ₂ C1 (18.4K)-cyclopent-2ene-1-carboxyl 1-010 F F СНз Z-1 CH2CF3 (18.4K)-cyclopent-2ene-1-carboxyl 1-011 F F (S) - dn=dn ₂ Z-1 n (18.4K)-cyclopent-2ene-1-carboxyl 1-012 F F (S) - dn=dn ₂ Z-1 СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-013 F F (S) - dn=dn ₂ Z-1 CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-014 F F (S) - dn=dn ₂ Z-1 n (1 K,4 K)-cyclopent-2 e-1-carboxyl 1-015 F F dn=dn ₂ Z-1 CH ₂ CF ₃ (18.4K)-cyclopent-2ene-1-carboxyl

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1-016 F F CH= _CH2 Z-l CH ₂ CHF ₂ (18.4K)-cyclopent-2ene-1-carboxyl 1-017 F F CH= _CH2 Z-l CH ₂ CH ₂ CF ₃ (18.4K)-cyclopent-2ene-1-carboxyl 1-018 F F CH= _CH2 Z-l CH ₂ CH ₂ OCHz (18.4K)-cyclopent-2ene-1-carboxyl 1-019 F F CH3O Z-l СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-020 F F Pre-trial detention center Z-l CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-020 F F SNZO Z-l _CH2CH3 (18.4K)-cyclopent-2ene-1-carboxyl 1-021 H H CF ₃ Z-l CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-022 CH ₃ F CF ₃ Z-l CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-023 СНз Cl CF ₃ Z-l CH2CH3 (18.4K)-cyclopent-2ene-1-carboxyl 1-024 СНз F CF ₃ Z-l СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-025 Η H CF ₃ Z-l CH ₂ CH ₂ C1 (18.4K)-cyclopent-2ene-1-carboxyl 1-026 Η H CF ₃ Z-l СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-027 СНз Cl CF ₃ Z-l СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-028 СНз Cl CF ₃ Z-l CH ₂ CH ₂ C1 (18.4K)-cyclopent-2ene-1-carboxyl 1-029 СНз Cl CF ₃ Z-l CH ₂ CF ₃ (18.4K)-cyclopent-2ene-1-carboxyl 1-030 Η H CF ₃ Z-l ch ₂ cf ₃ (18.4K)-cyclopent-2ene-1-carboxyl 1-031 СНз F CF ₃ Z-l СН2СН2С1 (18.4K)-cyclopent-2ene-1-carboxyl

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1-032 СНз F CF ₃ Z-l ch ₂ cf ₃ (18.4K)-cyclopent-2ene-1-carboxyl 1-033 F F CH= _CH2 Z-l benzyl (18.4K)-cyclopent-2ene-1-carboxyl 1-034 F F CH= _CH2 Z-l CH(CHz) ₂ (18.4K)-cyclopent-2ene-1-carboxyl 1-035 F F CH= _CH2 Z-l СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-036 CF ₃ СНз CF ₃ Z-l CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-037 F F CH= _CH2 Z-l Η (18.4K)-cyclopent-2ene-1-carboxyl 1-038 Cl Cl CF ₃ Z-l CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-039 Cl Cl CF ₃ Z-l СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-040 Cl Cl CF ₃ Z-l CH ₂ CH ₂ C1 (18.4K)-cyclopent-2ene-1-carboxyl 1-041 Cl Cl CF ₃ Z-l CH ₂ CF ₃ (18.4K)-cyclopent-2ene-1-carboxyl 1-042 H Cl CF ₃ Z-l CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-043 CH3O CH3O CF ₃ Z-l CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-044 CH3O CH3O CF ₃ Z-l CH ₂ CH ₂ C1 (18.4K)-cyclopent-2ene-1-carboxyl 1-045 Η Cl CF ₃ Z-l CH ₂ CH ₂ C1 (18.4K)-cyclopent-2ene-1-carboxyl 1-046 Η Cl CF ₃ Z-l СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-047 CH3O CH3O CF ₃ Z-l СНз (18.4K)-cyclopent-2ene-1-carboxyl

- 16 044070

1-048 CF ₃ СНз CF ₃ Z-l СНз (1 S,4R)-iiHKnoneHT-2en-1-carboxyl 1-049 CF ₃ СНз CF ₃ Z-l CH ₂ CH ₂ C1 (1 B.4I)-cyclopsnt-2ene-1-carboxyl 1-050 CF ₃ СНз CF ₃ Z-l CH ₂ CF ₃ (1 S,4R)-iiHKnoneHT-2en-1-carboxyl 1-051 H Cl CF ₃ Z-l ch ₂ cf ₃ (1 S,4R)-iiHKnoneHT-2en-1-carboxyl 1-052 CH3O CH3O CF ₃ Z-l ch ₂ cf ₃ (1 S,4R)-iiHKnoneHT-2en-1-carboxyl 1-053 СНз СНз CF ₃ Z-l CH ₂ CHz (1 S,4R)-iiHKnoneHT-2en-1-carboxyl 1-054 F F (S) - CH=CH ₂ Z-l СНз (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-055 СНз СНз CF ₃ Z-l СНз (1 S,4R)-iiHKnoneHT-2en-1-carboxyl 1-056 СНз СНз CF ₃ Z-l CH ₂ CH ₂ C1 (1 S,4R)-iiHKnoneHT-2en-1-carboxyl 1-057 СНз СНз CF ₃ Z-l CH ₂ CF ₃ (1 S,4R)-iiHKnoneHT-2en-1-carboxyl 1-058 F F CF ₃ Z-l CH ₂ CHz (1 S,4R)-ijHKHoneHT-2en-1-carboxyl 1-059 F F СНз Z-l CH ₂ CHz (1 S,4R)-iiHKnoneHT-2en-1-carboxyl 1-060 F F CH= _CH2 Z-l С(СНз)з (1C48)-cyclopent-2ene-1-carboxyl 1-061 F F CH= _CH2 Z-l CH ₂ CH ₂ C1 (lR4S)-iiHKnoneHT-2en-1-carboxyl 1-062 F F (R)-CF ₃ Z-l СНз (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-063 F F CF ₃ Z-l СНз (1 S,4R)-iiHKnoneHT-2en-1-carboxyl 1-064 F F CF ₃ Z-l CH(CHz) ₂ (1 S,4R)-iiHKnoneHT-2ene-1-carboxyl

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1-065 F F CF ₃ Z-1 Benzyl (18.4K)-cyclopent-2ene-1-carboxyl 1-066 F F CF ₃ Z-1 С(СНз)з (18.4K)-cyclopent-2ene-1-carboxyl 1-067 F F CF ₃ Z-1 CH ₂ CH ₂ C1 (18.4K)-cyclopent-2ene-1-carboxyl 1-068 F F CF ₃ Z-1 ch ₂ cf ₃ (18.4K)-cyclopent-2ene-1-carboxyl 1-069 CN H CH3 Z-1 CH ₂ CHz (18.4I)-cyclopsnt-2en-1-carboxyl 1-070 CN H СНз Z-1 Η (18.4K)-cyclopent-2ene-1-carboxyl 1-071 CN F CF ₃ Z-1 CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-072 CN H CF ₃ Z-1 CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-073 CN F СНз Z-1 CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-074 CONH ₂ F СНз Z-1 CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-075 CN F СНз Z-1 n (18.4K)-cyclopent-2ene-1-carboxyl 1-076 F F (R)-CF ₃ Z-1 CH ₂ CH ₂ OCHz (18.4I)-cyclopsnt-2en-1-carboxyl 1-077 F F (R)-CF ₃ Z-1 CH ₂ CH ₂ OCH ₂ CH3 (18.4K)-cyclopent-2ene-1-carboxyl 1-078 Cl F CF ₃ Z-1 CH ₂ CHz (18.4I)-cyclopsnt-2en-1-carboxyl 1-079 CN H СНз Z-1 CH ₂ CH ₂ C1 (18.4K)-Cyclopent-2ene-1-carboxyl 1-080 CN H СНз Z-1 СНз (18.4I)-cyclopsnt-2en-1-carboxyl 1-081 CN H СНз Z-1 CH ₂ CH ₂ OCHz (18.4I)-cyclopsnt-2en-1-carboxyl

- 18 044070

1-082 CN F CH ₃ Z-l CH2CH2OCH3 (1 S,4R)-4HKnoneHT-2en-1-carboxyl 1-083 CN F СНз Z-l CH2CH2C1 (1 S,4R)-pHKnoncHT-2en-1-carboxyl 1-084 CN F СНз Z-l СНз (1 S,4R)-pHKnoncHT-2en-1-carboxyl 1-085 CN H CF ₃ Z-l H (18.4I)-cyclopsnt-2en-1-carboxyl 1-086 CN H CF ₃ Z-l CH2CH2OCH3 (1 S,4R)-pHKnoncHT-2en-1-carboxyl 1-087 CN H CF ₃ Z-l СНз (1 S,4R)-pHKnoncHT-2en-1-carboxyl 1-088 CN H CF ₃ Z-l CH2CH2C1 (1 S,4R)-pHKnoncHT-2en-1-carboxyl 1-089 CN F CF ₃ Z-l CH2CH2C1 (1 S,4R)-pHKnoncHT-2en-1-carboxyl 1-090 CN F CF ₃ Z-l H (1 S,4R)-pHKnoncHT-2en-1-carboxyl 1-091 F F cyclopropyl Z-l CH2CH3 (1 S,4R)-pHKnoncHT-2en-1-carboxyl 1-092 F F (R) - СНз Z-l CH2CH2OCH3 (1 S,4R)-pHKnoncHT-2en-1-carboxyl 1-093 F F (R) - СНз Z-l CH2CH2OCH2CH3 (18.4I)-cyclopsnt-2en-1-carboxyl 1-094 F F cyclopropyl Z-l H (18.4I)-cyclopsnt-2en-1-carboxyl 1-095 CN H СНз Z-l С(СНз)з (18.4I)-cyclopsnt-2ene-1-carboxyl 1-096 CN F CF ₃ Z-l CH2CF3 (18.4I)-cyclopsnt-2en-1-carboxyl 1-097 CN F (S) or (R) CF ₃ Z-l СНз (18.4I)-cyclopsnt-2en-1-carboxyl

- 19 044070

1-098 CN F (S) or (R) CF ₃ Z-l CH ₃ (18.4R)-cyclopent-2ene-1-carboxyl 1-099 CN F (S)-CF ₃ Z-l CH ₂ CH ₂ OCH ₃ (18.4R)-cyclopent-2ene-1-carboxyl I-100 CN F (R)-CF ₃ Z-l CH ₂ CH ₂ OCH ₃ (18.4R)-cyclopent-2ene-1-carboxyl 1-101 F F (S) - CH=CH2 Z-l CH ₂ CH ₂ OCH ₃ (18.4R)-cyclopent-2ene-1-carboxyl 1-102 F F (S) - CH=CH2 Z-l CH ₂ CH ₂ OCH ₂ CH ₃ (18.4R)-cyclopent-2ene-1-carboxyl 1-103 F F cyclopropyl Z-l C(CH ₃ ) ₃ (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-104 F F CN Z-l CH ₂ CH ₃ (18.4R)-cyclopent-2ene-1-carboxyl 1-105 F F (R)-CH ₃ Z-l CH ₃ (18.4R)-cyclopent-2ene-1-carboxyl 1-105 H F (R)-CH ₃ Z-l CH ₃ (18.4R)-cyclopent-2ene-1-carboxyl 1-105 H F (R)-CH ₃ Z-l CH ₃ (18.4R)-cyclopent-2ene-1-carboxyl 1-106 H F (S)-CH ₃ Z-l CH ₃ (18.4K)-cyclopent-2ene-1-carboxyl 1-107 F F (S) or (R) cyclopropyl Z-l CH ₂ CF ₃ (18.4R)-cyclopent-2ene-1-carboxyl 1-108 F F (S) or (R) cyclopropyl Z-l ch ₂ cf ₃ (18.4R)-cyclopent-2ene-1-carboxyl 1-109 F F (S) or (R) cyclopropyl Z-l ch ₂ cf ₃ (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-110 F F (S) or (R) cyclopropyl Z-l ch ₂ cf ₃ (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-111 F F CH ₂ C1 Z-l H (18.4R)-cyclopent-2ene-1-carboxyl 1-112 F F (S) or (R) cyclopropyl Z-l CH2CH2C1 (18.4R)-cyclopent-2ene-1-carboxyl

- 20 044070

1-113 F F (S) or (R) cyclopropyl Z-l CH2CH2C1 (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-114 F F (S) or (R) cyclopropyl Z-l CH2CH2C1 (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-115 F F (S) or (R) cyclopropyl Z-l CH2CH2C1 (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-116 CN H СНз Z-l CH2CF3 (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-117 F F (R)-CF ₃ Z-l СНз (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-118 F F CH ₂ C1 Z-l CH2CH2C1 (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-119 CN H CF ₃ Z-l С(СНз)з (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-120 F F CH2CI Z-l CH2CH3 (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-121 F F cyclopropyl Z-l CH2CH2OCH3 (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-122 CN H CF ₃ Z-l CH2CF3 (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-123 F F CH2CI Z-l CH2CHF2 (18.4H)-cyclopent-2ene-1-carboxyl 1-124 F F CH2CI Z-l CH2CH2OCH3 (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-125 F F CH2CI Z-l СНз (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-126 H H CH= _CH2 Z-l СНз (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-127 СНз F CH= _CH2 Z-l СНз (1 S,4R)-pHKaoneHT-2en-1-carboxyl 1-128 H H CH= _CH2 Z-l n (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-129 СНз F (S) or (R) CF ₃ Z-l СНз (1 S,4R)-pHKnoneHT-2en-1-carboxyl

- 21 044070

1-130 СНз F (S) or (R) CF ₃ Z-1 СНз (18.4B)-cyclopent-2ene-1-carboxyl 1-131 Η H (S) or (R) CF ₃ Z-1 СНз (18.4B)-cyclopent-2ene-1-carboxyl 1-132 Η H (S) or (R) CF ₃ Z-1 СНз (18.4B)-cyclopent-2ene-1-carboxyl 1-133 СНз F CH= _CH2 Z-1 Η (18.4K)-cyclopent-2ene-1-carboxyl 1-134 F F (R)-CF ₃ Z-1 Η (18.4B)-cyclopent-2ene-1-carboxyl 1-135 F F (S) - CH=CH ₂ Z-1 ch ₂ chf ₂ (18.4B)-cyclopent-2ene-1-carboxyl 1-136 F F (S) - CH=CH ₂ Z-1 ch ₂ chf ₂ (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-137 F F (S) - CH=CH ₂ Z-1 ch ₂ ch ₂ cf ₃ (18.4B)-cyclopent-2ene-1-carboxyl 1-138 F F (S) - CH=CH ₂ Z-1 ch ₂ ch ₂ cf ₃ (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-139 CN H СНз Z-1 ch ₂ chf ₂ (18.4B)-cyclopent-2ene-1-carboxyl 1-140 F F (S) or (R) CH3O Z-1 CH ₂ CHz (18.4B)-cyclopent-2ene-1-carboxyl 1-141 F F (S) or (R) CH3O Z-1 CH ₂ CHz (18.4B)-cyclopent-2ene-1-carboxyl 1-142 F F (S) or (R) CH ₂ C1 Z-1 CH ₂ CH ₂ C1 (18.4B)-cyclopent-2ene-1-carboxyl 1-143 F F (S) or (R) CH ₂ C1 Z-1 CH ₂ CH ₂ C1 (18.4B)-cyclopent-2ene-1-carboxyl 1-144 F F (S) or (R) CH ₂ C1 Z-1 CH ₂ CH ₂ C1 (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-145 F F (S) or (R) CH ₂ C1 Z-1 CH ₂ CH ₂ C1 (1 R.4 I)-cyclo ps nt-2 ey-1-carboxyl

- 22 044070

1-146 Η n (S) or (R) dc = dc ₂ Z-1 СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-147 Η n (S) or (R) dc = dc ₂ Z-1 СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-148 CN n CF ₃ Z-1 CH ₂ CHF ₂ (18.4K)-cyclopent-2ene-1-carboxyl 1-149 F F CH ₂ C1 Z-1 С(СНз)з (18.4K)-cyclopent-2ene-1-carboxyl 1-150 СНз F (S) or (R) CF ₃ Z-1 CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-151 СНз F (S) or (R) CF ₃ Z-1 CH ₂ CHz (18,4P)-cyclopent-2ene-1-carboxyl 1-152 СНз F (S) or (R) CF ₃ Z-1 CH ₂ CHz (1 K,4K)-cyclopent-2 en-1-carboxyl 1-153 СНз F (S) or (R) CF ₃ Z-1 CH ₂ CHz (1 K,4K)-cyclopent-2 en-1-carboxyl 1-154 N N (S) or (R) CF ₃ Z-1 CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-155 N N (S) or (R) CF ₃ Z-1 CH ₂ CHz (18.4K)-cyclopent-2ene-1-carboxyl 1-156 n N (S) or (R) CF ₃ Z-1 CH ₂ CHz (1 R.4 R)-cyclo ps nt-2 en-1-carboxyl 1-157 n N (S) or (R) CF ₃ Z-1 CH ₂ CHz (1 K,4K)-cyclopent-2 en-1-carboxyl 1-158 CN C1 СНз Z-1 СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-159 CN CN СНз Z-1 СНз (18.4K)-cyclopent-2ene-1-carboxyl 1-160 CN C1 СНз Z-1 n (18,4P)-cyclopent-2ene-1-carboxyl 1-161 CN CN СНз Z-1 С(СНз)з (18.4K)-cyclopent-2ene-1-carboxyl 1-162 CN C1 СНз Z-1 С(СНз)з (18.4K)-cyclopent-2ene-1-carboxyl

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1-163 Η F (R) - СНз Z-1 n (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-164 CN Cl СНз Z-1 CH2CH3 (1 S,4R)-pHKnoneHT-2ene-1-carboxyl 1-165 CN CN СНз Z-1 n (1 8.4I)-cyclopsnt-2en-1-carboxyl 1-166 CN Cl СНз Z-1 CH2CHF2 (18.4I)-cyclopsnt-2en-1-carboxyl 1-167 CN Cl СНз Z-1 CH2CH2OCH3 (18.4I)-cyclopsnt-2ene-1-carboxyl 1-168 CN Cl СНз Z-1 СН2СН2С1 (18.4I)-cyclopsnt-2en-1-carboxyl 1-169 СНз F (S) or (R) dc = dc ₂ Z-1 СНз (18.4I)-cyclopsnt-2en-1-carboxyl 1-170 СНз F (S) or (R) dc = dc ₂ Z-1 СНз (18.4I)-cyclopsnt-2en-1-carboxyl 1-171 CN CN СНз Z-1 CH2CH2OCH3 (18.4I)-cyclopsnt-2en-1-carboxyl 1-172 CN CN СНз Z-1 СН2СН2С1 (18.4I)-cyclopsnt-2ene-1-carboxyl 1-173 CN CN СНз Z-1 CH2CHF2 (18.4K)-cyclopent-2ene-1-carboxyl 1-174 F F CH3O Z-1 n (18.4I)-cyclopsnt-2en-1-carboxyl 1-175 H H dn=dn ₂ Z-1 CH2CH3 (18.4I)-cyclopsnt-2en-1-carboxyl 1-176 H H dn=dn ₂ Z-1 СН2СН2С1 (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-177 H H dn=dn ₂ Z-1 CH2CH2OCH3 (1 S,4R)-pHKnoneHT-2en-1-carboxyl 1-178 CN Cl CF ₃ Z-1 СНз (18.4I)-cyclopsnt-2en-1-carboxyl 1-179 СНз СНз dn=dn ₂ Z-1 CH2CH3 (18.4I)-cyclopsnt-2en-1-carboxyl

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1-180 Η F (R) - СНз Z-l H (1 R.4 R)-cyclo ps nt-2 en-1-carboxyl 1-181 Η F (S) or (R) CF ₃ Z-l СНз (18.4I)-cyclopsnt-2en-1-carboxyl 1-182 Η Η CH= _CH2 Z-l CH2CHF2 (18.4I)-cyclopsnt-2en-1-carboxyl 1-183 Η F (S) or (R) CF ₃ Z-l СНз (18,4D)-cyclopent-2ene-1-carboxyl 1-184 СНз F CH= _CH2 Z-l CH2CH2C1 (18.4I)-cyclopsnt-2en-1-carboxyl 1-185 СНз F CH= _CH2 Z-l CH2CH2OCH3 (18.4I)-cyclopsnt-2en-1-carboxyl 1-186 СНз F CH= _CH2 Z-l CH2CHF2 (18.4I)-cyclopsnt-2en-1-carboxyl 1-187 СНз F CH= _CH2 Z-l CH2CH3 (18.4I)-cyclopsnt-2en-1-carboxyl 1-188 Η F (R) - СНз Z-l CH2CH2CH3 (18.4I)-cyclopsnt-2en-1-carboxyl 1-189 Η F (R) - СНз Z-l CH(CH3)2 (18.4I)-cyclopsnt-2en-1-carboxyl 1-190 Η F (R) - СНз Z-l С(СНз)з (18.4I)-cyclopsnt-2en-1-carboxyl 1-191 Η F (R) - СНз Z-l СН2СН2С1 (18.4I)-cyclopsnt-2en-1-carboxyl 1-192 Η F (R) - СНз Z-l CH2CH2OCH3 (18.4I)-cyclopsnt-2en-1-carboxyl 1-193 Η F (R) - СНз Z-l Benzyl (18,4P)-cyclopent-2ene-1-carboxyl 1-194 Η F (R) - СНз Z-l 4-F-benzyl (18.4I)-cyclopsnt-2en-1-carboxyl 1-195 F F (R) _-CH2C1 Z-l CH2CH2OCH3 (18,4P)-cyclopent-2ene-1-carboxyl

- 25 044070

1-196 F F (R) - CH ₂ C1 Z-1 CH ₂ CH ₂ OCHz (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-197 F F (S) - CH ₂ C1 Z-1 CH2CH2OCH3 (1 S,4R)-4HKnoneHT-2ene-1-carboxyl 1-198 F F (S) - CH ₂ C1 Z-1 CH2CH2OCH3 (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-199 CN C1 (S) or (R) СНз Z-1 CH2CH2OCH3 (1 S,4R)-4HKnoneHT-2en-1-carboxyl 1-200 CN C1 (S) or (R) СНз Z-1 CH2CH2OCH3 (1 S,4R)-4HKnoneHT-2ene-1-carboxyl 1-201 CN C1 (S) or (R) СНз Z-1 CH2CH2OCH3 (1 R.4 R)-cyclo ps nt-2 ei-1-carboxyl 1-202 C1 F СНз Z-1 CH2CH3 (1 S,4R)-4HKnoneHT-2en-1-carboxyl 1-203 F F (S) or (R) cyclopropyl Z-1 CH2CH2OCH3 (1 S,4R)-4HKnoneHT-2en-1-carboxyl 1-204 F F (S) or (R) cyclopropyl Z-1 CH2CH2OCH3 (1 S,4R)-4HKnoneHT-2en-1-carboxyl 1-206 СНз СНз dn=dn ₂ Z-1 СНз (1 S,4R)-4HKnoneHT-2ene-1-carboxyl 1-207 СНз СНз dn=dn ₂ Z-1 n (1 S,4R)-4HKaoneHT-2ene-1-carboxyl Ш-01 N F СНз Z-4 n (4I)-cyclopsnt-1-ene1-carboxyl Ш-02 N F СНз Z-4 n (48)-cyclopent-1-ene-1 carboxyl sh-oz N F СНз Z-4 СНз (4K)-cyclopsnt-1-ene1-carboxyl Ш-04 N F СНз Z-4 СНз (48)-cyclopent-1-ene-1 carboxyl Ш-05 N F СНз Z-4 CH2CH3 (4I)-cyclopsnt-1-ene1-carboxyl Ш-06 N F СНз Z-4 CH2CH3 (48)-cyclopent-1-ene-1 carboxyl

- 26 044070

Ш-07 F F СНз Z-4 CH ₂ CH ₃ (48)-cyclopent-1-ene-1 carboxyl Ш-08 F F CH=CH ₂ Z-4 СНз (48)-cyclopent-1-ene-1 carboxyl Ш-09 F F CH=CH ₂ Z-4 Η (48)-cyclopent-1-ene-1 carboxyl III-10 F F СНз Z-4 СНз (48)-cyclopent-1-ene-1 carboxyl III-11 F F СНз Z-4 CH(CHz) ₂ (48)-cyclopent-1-ene-1 carboxyl III-12 F F СНз Z-4 Benzyl (48)-cyclopent-1-ene-1 carboxyl III-13 F F CH=CH ₂ Z-4 CH(CHz) ₂ (48)-cyclopent-1-ene-1 carboxyl III-14 F F CH=CH ₂ Z-4 CH ₂ CH ₂ C1 (48)-cyclopent-1-ene-1 carboxyl III-15 F F CH=CH ₂ Z-4 CH ₂ CH ₂ OCHz (48)-cyclopent-1-ene-1 carboxyl III-16 F F dn=dn ₂ Z-4 CH ₂ CH ₂ OCH ₂ CH3 (48)-cyclopent-1-ene-1 carboxyl III-17 F F dn=dn ₂ Z-4 CH ₂ CHz (48)-cyclopent-1-ene-1 carboxyl III-18 F F dn=dn ₂ Z-4 Benzyl (48)-cyclopent-1-ene-1 carboxyl III-19 F F CF ₃ Z-4 СНз (48)-cyclopent-1-ene-1 carboxyl Sh-20 F F СНз Z-4 С(СНз)з (48)-cyclopent-1-ene-1 carboxyl Sh-21 F F СНз Z-4 CH ₂ CH ₂ C1 (48)-cyclopent-1-ene-1 carboxyl Sh-22 F F CF ₃ Z-4 CH ₂ CHz (48)-cyclopent-1-ene-1 carboxyl Sh-23 F F CF ₃ Z-4 СН(СНЗ)2 (48)-cyclopent-1-ene-1 carboxyl

- 27 044070

Sh-24 F F CF ₃ Z-4 CH2CH2C1 (48)-cyclopent-1-ene-1 carboxyl Sh-25 F F CF ₃ Z-4 Benzyl (48)-cyclopent-1-ene-1 carboxyl Sh-26 F F CF ₃ Z-4 C(CH ₃ ) ₃ (48)-cyclopent-1-ene-1 carboxyl Sh-27 F F CF ₃ Z-4 CH ₂ CH ₂ OCH ₃ (48)-cyclopent-1-ene-1 carboxyl Sh-28 F F CH ₃ Z-4 CH ₂ CH ₂ OCH ₃ (48)-cyclopent-1-ene-1 carboxyl Sh-29 F F CF ₃ Z-4 H (48)-cyclopent-1-ene-1 carboxyl V-01 F F (R)-CH3 Z-6 H (3 8)-cyclopent-1-eu-1 carboxyl V-05 F F (R)-CF3 Z-6 CH3 (3 8)-cyclopent-1-eu-1 carboxyl V-02 F F (R)-CH3 Z-6 CH3 (3 8)-cyclopent-1-eu-1 carboxyl V-03 F F (R)-CH3 Z-6 CH ₂ CH ₂ OCH ₃ (3 8)-cyclopent-1-eu-1 carboxyl V-04 F F (R)-CF3 Z-6 H (3 8)-cyclopent-1-eu-1 carboxyl

Table 1.2

Compounds of general formula (I), with X ² =X ⁴ =X ⁶ =R ¹ =R ² =H, Y=W=O and G=NR ⁿ R ¹²

Example No. X ³ X ⁵ R ³ Z NRHR ¹² Note P-01 n F CH ₃ Z-1 methoxyamino (1 I,48)-cyclopent-2 en-1-carboxyl P-02 F F dn ₃ Z-1 methoxyamino (18,4P)-cyclopent-2ene-1-carboxyl P-03 N F dn ₃ Z-1 ethoxyamino (1 P,48)-cyclopent-2 en-1-carboxyl

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P-04 N F СНз Z-1 ethoxyamino (1S,4K)-cyclopent-2 en-1-carboxyl P-05 N F СНз Z-1 isopropyloxyamino (1C,48)-cyclopent-2ene-1-carboxyl P-06 F F СНз Z-1 1,2-oxazo lidin-2-yl (1S,4K)-cyclopent-2 en-1-carboxyl P-07 F F СНз Z-1 oxasinan-2-yl (1S,4K)-cyclopent-2 en-1-carboxyl P-08 F F СНз Z-1 (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-09 F F СНз Z-1 (1-methoxy-2-methyl-1 oxopropan-2-yl)amino (1S,4K)-cyclopent-2 en-1-carboxyl II-10 F F СНз Z-1 2-cyanopropan-2-ylamino (1S,4K)-cyclopent-2 en-1-carboxyl II-11 F F СНз Z-1 (1-methoxy-3-methyl-1 oxobutan-2-yl)amino (1S,4K)-cyclopent-2 en-1-carboxyl II-12 F F СНз Z-1 (1-cyano-2methylpropyl)amino (1S,4K)-cyclopent-2 en-1-carboxyl II-13 N F СНз Z-1 methanesulfonamido (1C,48)-cyclopent-2ene-1-carboxyl II-14 F F CH=CH ₂ Z-1 propylsulfonylamino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl II-15 N F СНз Z-1 trifluoromethylsulfonyl foreign (1C,48)-cyclopent-2ene-1-carboxyl II-16 N F СНз Z-1 trifluoromethylsulfonyl foreign (1S,4K)-cyclopent-2 en-1-carboxyl II-17 F F dn=dn ₂ Z-1 (1-cyano-2methylpropyl)amino (1S,4K)-cyclopent-2 en-1-carboxyl II-18 F F dn=dn ₂ Z-1 (2-methoxy-2oxoethyl)sulfonylamino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl II-19 F F dn=dn ₂ Z-1 2-cyanopropan-2-ylamino (1H,4K)-cyclopent-2ene-1-carboxyl P-20 F F dn=dn ₂ Z-1 2-cyanopropan-2-ylamino (1S,4K)-cyclopent-2 en-1-carboxyl

- 29 044070

P-21 F F (R)CH=CH ₂ Z-1 (1-methoxy-2-methyl-1 oxopropan-2-yl)amino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-22 F F (S) dn=dn ₂ Z-1 (1-methoxy-2-methyl-1 oxopropan-2-yl)amino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-23 F F (S) or (R) dc = dc ₂ Z-1 (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-24 F F (S) or (R) dc = dc ₂ Z-1 (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-25 F F dn=dn ₂ Z-1 (1-methoxy-3-methyl-1 oxobutan-2-yl] amino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-26 F F dn=dn ₂ Z-1 (1-methoxy-3-methyl-1 oxobutan-2-yl)amino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-27 F F (S) dn=dn ₂ Z-1 1,2-oxazo lidin-2-yl (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-28 F F (S) dn=dn ₂ Z-1 1,2-oxazo lidin-2-yl (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-29 F F dn=dn ₂ Z-1 oxasinan-2-yl (lR,4R)-pHKnoneHT-2en-1-carboxyl P-30 F F dn=dn ₂ Z-1 oxasinan-2-yl (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-31 F F CF ₃ Z-1 oxasinan-2-yl (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-32 F F CF ₃ Z-1 1,2-oxazo lidin-2-yl (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-33 F F CF ₃ Z-1 propylsulfonylamino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-34 F F CF ₃ Z-1 2-cyanopropan-2-ylamino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-35 F F CF ₃ Z-1 (1-cyano-2methylpropyl)amino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-36 F F CF ₃ Z-1 (1-methoxy-2-methyl-1 oxopropan-2-yl)amino (1S .4 R)-cyclo ps nt-2 en-1-carboxyl P-37 F F CF ₃ Z-1 (1-methoxy-3-methyl-1 oxobutan-2-yl)amino (1S,4R)-cyclopent-2 en-1-carboxyl

-30044070

P-38 F F CF ₃ Z-l (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1 S,4R)-pHKnoneHT-2en-1-carboxyl P-39 F F CF ₃ Z-l (2-methoxy-2oxoethyl)sulfonylamino (1S .4 R (-cyclo not nt-2 en-1-carboxyl P-40 CN F CF ₃ Z-l (1,1,1-trifluoro-2 methylpropan-2-yl)amino (lR,4R)-pHKnoneHT-2en-1-carboxyl P-41 F F CF ₃ Z-l (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1S .4 R (-cyclo ns nt-2 en-1 -carboxyl P-42 F F (R)-CF ₃ Z-l 3-oxo-2azabicyclo[2.2.1]hept-5-en2-yl (1S .4 R (-cyclo ns nt-2 en-1-carboxyl P-43 F F C1CH ₂ Z-l (2-methoxy-2oxoethyl)sulfonylamino (1S .4 R (-cyclo ns nt-2 en-1 -carboxyl P-44 N CN CF ₃ Z-l (1,1,1-trifluoro-2 methylpropan-2-yl)amino (lR,4R)-cyclopent-2ene-l-capboxyl P-45 N CN CF ₃ Z-l (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1S .4 R (-cyclo ns nt-2 en-1 -carboxyl P-46 N CN CH ₃ Z-l (1,1,1-trifluoro-2 methylpropan-2-yl)amino (lR,4R)-pHKnoneHT-2en-1-carboxyl P-47 N CN CH ₃ Z-l (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1S .4 R (-cyclo ns nt-2 en-1 -carboxyl P-48 F F CICH2 Z-l (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1S .4 R (-cyclo ps nt-2 en-1 -carboxyl P-49 N CN CF ₃ Z-l (2-methoxy-2oxoethyl)sulfonylamino (1S .4 R (-cyclo ps nt-2 en-1 -carboxyl P-50 N CN (S) or (R) CH ₃ Z-l (2-methoxy-2oxoethyl)sulfonylamino (1S .4 R (-cyclo ps nt-2 en-1 -carboxyl P-51 N CN (S) or (R) CH ₃ Z-l (2-methoxy-2oxoethyl)sulfonylamino (1S .4 R (-cyclo ps nt-2 en-1 -carboxyl P-52 N CN (S) or (R) CH ₃ Z-l (2-methoxy-2oxoethyl)sulfonylamino (lR,4R)-pHKnoneHT-2en-1-carboxyl P-53 N CN (S) or (R) CH ₃ Z-l (2-methoxy-2oxoethyl)sulfonylamino (lR,4R)-pHKnoneHT-2en-1-carboxyl

- 31 044070

P-54 F F C1CH ₂ Z-1 (1,1,1-trifluoro-2 methylpropan-2-yl)amino (lR4R)-4HKnoneHT-2en-1-carboxyl P-55 CN CN СНз Z-1 (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1I.4I)-cyclopsnt-2ene-1-carboxyl P-56 CN C1 СНз Z-1 (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1S .4 R)-cyclo ps nt-2 ei-1-carboxyl P-57 CN C1 СНз Z-1 (2-methoxy-2oxoethyl)amino (lR4R)-4HKnoneHT-2en-1-carboxyl P-58 CN C1 (S) or (R) СНз Z-1 (2-methoxy-2oxoethyl)amino (1S .4 R)-cyclo ps nt-2 ei-1-carboxyl P-59 CN C1 СНз Z-1 (2-methoxy-2oxoethyl)sulfonylamino (1S .4 R)-cyclo ps nt-2 ei-1-carboxyl P-60 CN CN СНз Z-1 (2-methoxy-2oxoethyl)amino (1S .4 R)-cyclo ps nt-2 ei-1-carboxyl P-61 CN CN СНз Z-1 (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1 R.4R)-cycloπcnt-2c n-1-carboxyl P-62 CN CN СНз Z-1 (1,1,1-trifluoro-2 methylpropan-2-yl)amino (1S .4 R)-cyclo ps nt-2 ei-1-carboxyl P-63 CN CN СНз Z-1 (2-methoxy-2oxoethyl)sulfonylamino (1S .4 R)-cy clo ps nt-2 ei-1-carboxyl IV-01 N F SNZ Z-4 dimethylamino (4P)-cyclopent-1-ene-1 carboxyl IV-02 n F SNZ Z-4 dimethylamino (4 S)-cyclopent-1-ene-1 carboxyl IV-03 n F SNZ Z-4 methoxyamino (4R)-uHKnoneHT-1-en-1 carboxyl IV-04 n F SNZ Z-4 methoxyamino (4 S)-cyclopent-1-ene-1 carboxyl IV-05 n F SNZ Z-4 dimethylhydrazino (4R)-pnKnoneHT-1-en-1 carboxyl IV-06 n F SNZ Z-4 dimethylhydrazino (4 S)-cyclopent-1-ene-1 carboxyl IV-07 n F SNZ Z-4 methanesulfonamido (4 S)-cyclopent-1-ene-1 carboxyl IV-08 F F SNZ Z-4 sulfamoylamino (4 S)-cyclopent-1-ene-1 carboxyl IV-09 F F CF3 Z-4 sulfamoylamino (4 S)-cyclopent-1-ene-1 carboxyl IV-10 F F CH=CH2 Z-4 sulfamoylamino (4 S)-cyclopent-1-ene-1 carboxyl IV-11 F F CH=CH2 Z-4 (1,1,1-trifluoro-2 methylpropan-2-yl)amino (4 S)-cyclopent-1-ene-1 carboxyl IV-12 F F SNZ Z-4 (1,1,1-trifluoro-2 methylpropan-2-yl)amino (4 S)-cyclopent-1-ene-1 carboxyl IV-13 F F CF3 Z-4 (1,1,1-trifluoro-2 methylpropan-2-yl)amino (4 S)-cyclopent-1-ene-1 carboxyl

- 32 044070

The compounds of the invention can be prepared by various methods, which are presented below by way of examples.

Scheme 1

In Scheme 1 and subsequent diagrams, (X)n represents the substituents X ² , X ³ , X ⁴ , X ⁵ and X ⁶ . Such 1,3-dipolar cycloadditions of nitrile oxides with suitable dipolarophiles are described, for example, in the review 1,3 dipolar Cycloaddition Chemistry, Padwa, ed. Wiley, New York, 1984; Kanemasa & Tsuge, Heterocycles, 1990, 30, 719.

For chloroximes, see Kim, Jae N., Ryu, Eung K., J. Org. Chem., 1992, 57, 6649.

The compounds of the invention which are substituted at the 4 and 5 positions of the isoxazoline ring system can also be prepared by 1,3-dipolar cycloaddition using suitable 1,2-disubstituted olefins as dipolarophiles. This reaction most often produces mixtures of diastereoisomers, which can be separated using column chromatography. Optically active isoxazolines can be prepared by chiral HPLC preliminary or final steps, also by enantioselective reactions such as enzymatic ester or amide elimination, or by the use of chiral dipolarophile auxiliaries as described by Olssen (J. Org. Chem., 1988, 53, 2468).

Substituted 2-alkoxyactylic acid amides can also be used to prepare the compounds according to the invention (Scheme 3). The acrylic acid esters described in Scheme 2 are obtained after hydrolysis and the formation of amides.

Scheme 2

In this case, carbodiimides, such as EDCI, are proposed for the activation of acrylic acids (Chen, F.M.F.; Benoiton, N.L., Synthesis, 1979, 709). For the preparation of acrylic acid amides, see US 2521902, JP 60112746, J. of Polymer Science, 1979, 17 (6), 1655. Suitable substituted acrylic acid amides can be prepared by 1,3-cycloaddition with nitrile oxides to the compounds of the invention ( scheme 3).

Scheme 3

Transformations of functional groups ^R3 are possible both at the stage of alkenes and at the stage of isoxazolines.

The collection of compounds of formula (I) and/or their salts, which can be synthesized as a result of the above-mentioned reactions, can also be obtained in a comparative manner, this can be done manually, partially automatically or fully automatically. In this case, for example, it is possible to automate the reaction, process or purify the product or intermediate products. A similar method is described, for example, in D. Tiebes in Combinatorial Chemistry - Synthesis, Analysis, Screening (Herausgeber Gunther Jung), Wiley, 1999, p. 1-34.

The compounds according to the invention of formula (I) (and/or salts thereof), hereinafter referred to as compounds according to the invention, have excellent herbicidal activity against a wide range of economically important mono- and dicotyledonous annual pests.

Therefore, the subject of the present invention is also a method for controlling unwanted plants or regulating plant growth, preferably in plant crops, in which one

- 33 044 070 or more compounds according to the invention are applied to plants (for example, harmful plants such as mono- or dicotyledonous weeds or undesirable crop plants), seed material (for example, grains, seeds or vegetative reproductive organs such as tubers or sprouts with buds) or on the soil on which the plants grow (for example, on a cultivated surface). In this case, the compounds according to the invention can be applied, for example, in the pre-sowing (if necessary also when applying fertilizers to the soil), pre-emergence and/or post-emergence period. In particular, examples should be given to representatives of mono- and dicotyledonous weeds that can be controlled by the compounds of the invention, but the invention should not be limited to these names:

monocotyledonous pests of the species Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cenchrus, Commelina (commelina), Cynodon (pigweed), Cyperus (sweetweed), Dactyloctenium (dactyloctenium), Digitaria (crabgrass), Echinochloa (barngrass), Eleocharis (marshgrass), Eleusine (dagussa), Eragrostis (bentgrass), Eriochloa (woolgrass), Festuca (fescue), Fimbristylis, Heteranthera, Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris (canary grass), Phleum (arzhan), Roa (bluegrass), Rottboellia (rothbellia), Sagittaria (arrowhead), Scirpus (reed), Setaria (bristle grass), Sorghum (sorghum);

dicotyledonous weeds of the species Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens (succession), Capsella (shepherd's purse), Carduus (thistle), Cassia (cassia), Centaurea (cornflower), Chenopodium (pigweed), Cirsium (thistle), Convolvulus (convolvulus), Datura (datura), Desmodium (telegraph plant) , Emex, Erysimum, Euphorbia, Galeopsis, Galinsoga, Galium, Hibiscus, Ipomoea, Kochia, Lamium , Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago, Polygonum knotweed), Portulaca (purslane), Ranunculus (buttercup), Raphanus (radish), Rorippa (frog), Rotala (rotala), Rumex (sorrel), Salsola (saltwort), Senecio (ragus), Sesbania (sesbania), Sida ( sida), Sinapis (sesbania), Solanum (nightshade), Sonchus (sow thistle), Sphenoclea (sphenoclea), Stellaria (chickweed), Taraxacum (dandelion), Thlaspi (jarutka), Trifolium (clover), Urtica (nettle), Veronica ( Veronica), Viola (violet), Xanthium (cocklebur).

If the compounds according to the invention are applied to the soil surface before sprouting, the growth of weed sprouts is completely stopped, or the weeds grow up to the cotyledon stage, but then their growth stops.

When applying active substances to the green parts of plants during post-emergence application, growth stops after treatment, and harmful plants are at the growth stage at which they were at the time of application or die completely after a certain period of time, thus eliminating competition very early and for a long period in the form of harmful weeds.

The compounds of the invention may be selective in crops of useful plants and can also be used as non-selective herbicides.

Due to their herbicidal and growth-regulating properties, the active substances can also be used to control harmful plants in crops of known or new plants modified by genetic engineering or conventional mutagenesis. Transgenic plants are usually distinguished by particularly preferable properties, for example, their resistance to certain active substances used in the agricultural processing industry, especially certain herbicides, resistance to plant diseases or their pathogens, such as certain insects or microorganisms, such as fungi, bacteria or viruses. Other special properties generally relate to the harvested crop, regarding quantity, quality, storage stability, composition and special components. Thus, transgenic plants with increased starch content or altered starch properties, or plants with a different fatty acid composition in the harvested crop are known. Other special properties include tolerance or resistance to abiotic stress factors such as heat, cold, drought, high salt content and ultraviolet radiation.

Preference is given to the use of the compounds of formula (I) according to the invention or their salts in certain economic transgenic crops of useful and ornamental plants.

The compounds of formula (I) can be used as herbicides in useful industrial crops that are resistant to the phytotoxic effects of herbicides or have become resistant due to genetic engineering methods.

Common methods of obtaining new plants that exhibit new modified qualities in comparison with previously existing plants are, for example, classical cultivation methods and the creation of mutated plants. Alternatively, new plants with modified properties can be obtained using genetic engineering methods (see, for example, EP 0221044, EP 0131624). For example, in many cases genetic technical changes in cultivated plants caused by changes in starch synthesized in plants are described (for example, WO 92/011376 A, WO 92/014827 A, WO 91/019806 A);

transgenic crop plants which are resistant to certain herbicides such as glufosinate (see, for example, EP 0242236 A, EP 0242246 A) or glyphosate (WO 92/000377 A) or sulfonylureas (EP 257993 A, US 5013659) or combinations or mixtures these herbicides through gene packaging, such as transgenic crops such as corn or soybeans under the trade name Optimum™ GAT™ (Glyphosate ALS Tolerance);

transgenic crops, for example cotton, which can produce Bacillus thuringiensis toxins (Bt toxins) that make the plants resistant to certain pests (EP 0142924 A, EP 0193259 A);

transgenic crop plants with altered fatty acid composition (WO 91/013972 A);

genetically modified crop plants with new constituents or secondary substances, for example new phytoalexins, which cause increased disease resistance (EP 309862 A, EP 464461 A);

genetically modified plants with reduced photorespiration, which have high yields and increased tolerance to stress factors (EP 0305398 A);

transgenic crop plants that produce pharmaceutically or diagnostically important proteins (molecular pharming);

transgenic crop plants that are characterized by high yield or improved quality;

transgenic crop plants that differ, for example, in combinations of new properties (gene packaging).

The specialist knows many molecular biological technologies with which new transgenic plants with altered properties can be obtained; see, for example, I. Potrykus and G. Spangenberg (eds.), Gene Transfer to Plants, Springer Lab Manual (1995), Springer Publishing Berlin, Heidelberg or Christou, Trends in Plant Science, 1 (1996), 423 -431.

For genetic engineering manipulations of this kind, nucleic acid molecules can be delivered into plasmids, which allow mutagenesis or changes to the nucleotide DNA sequence. Using standard techniques, for example, cation exchange can be carried out, partial sequences can be removed or natural or synthetic sequences can be added. To connect DNA fragments to each other, adapters or linkers can be attached to the fragments; see, for example, Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2nd ed. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; or Winnacker Gene und Klone, VCH Weinheim, 2nd ed., 1996.

Creation of plant cells with reduced gene product activity can, for example, be achieved by expression of at least one corresponding antisense RNA, one sense RNA for RNAi extraction, or expression of at least a corresponding engineered ribosome, a specific transcript of the above gene product. In addition, DNA molecules that span the total encoded sequence of the gene product, including any flanking sequences present, can be used, as well as DNA molecules that span only a portion of the encoded sequence, which portion must be long enough to produce an antisense effect in cells. It is also possible to use DNA sequences that indicate a high degree of homology to the encoded sequences, but are not completely identical.

When nucleic acid molecules are expressed in plants, the synthetic protein can be localized in any compartment of the plant cell. But to achieve localization to a specific compartment, the encoded region can, for example, bind to DNA sequences that provide localization to one specific compartment. Such sequences are known to the skilled person (see, for example, Braun et al., EMBO J., 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci., USA, 85 (1988), 846 -850; Sonnewald et al., Plant J., 1 (1991), 95-106). Expression of nucleic acid molecules can also occur in plant cell organelles.

Transgenic plant cells can be regenerated into whole plants by known methods. In the case of transgenic plants, we can basically talk about plants of any species, i.e. both monocots and dicots. Thus, commercially available transgenic plants may have altered properties due to increased expression, suppression or inhibition of homologous (=natural) genes or gene sequence, or expression of heterologous (=foreign) genes or gene sequence.

Advantageously, in transgenic crops, compounds according to the invention can be used that are resistant to growth substances, such as 2,4-D, dicamba, or to herbicides that inhibit essential plant enzymes, such as acetolactate synthase (ALS), EPSP synthase, glutamine synthase (GS) or hydroxyphenylpyruvate dioxygenase (HPDH), or to herbicides from the group of sulfonylureas, glyphosate, glufosinate or benzoyloxazole and similar active

- 35 044070 active ingredients or any combination of these active ingredients.

Particularly preferably, the compounds according to the invention can be used in transgenic crop plants that are resistant to a combination of glyphosates and glufosinates, glyphosates and sulfonylureas or imidazolinones. Very preferably, the compounds of the invention can be used in transgenic crop plants, such as corn or soybean under the trade name or designation Optimum™ GAT™ (glyphosate tolerance ALS).

When the active ingredients are used in transgenic crops according to the invention, in addition to the results observed against harmful plants in other crops, results that are specific to these transgenic crops often occur, for example, a changed or specially expanded range of weeds that can be suppressed, a changed quantity used, which can be used for application, preferably good compatibility with herbicides to which transgenic crops are resistant, as well as influence on the growth and yield of transgenic crops.

Therefore, the subject of the invention is also the use of the compounds of formula (I) according to the invention as herbicides for the control of harmful plants in crops of beneficial plants in transgenic crop plants.

The compounds of the invention can be used in the form of powder injections, emulsifiable concentrates, spray solutions, sprays or granulates in the form of conventional preparations. The object of the invention is therefore also to provide herbicidal and plant growth regulating agents which contain the compounds according to the invention.

The compounds of the invention can be formulated in various ways, depending on what biological and/or chemical-physical parameters are specified. For example, the following formulation options are taken into account: spray powders (WP), water-soluble powders (SP), water-soluble concentrates, emulsion-forming concentrates (EC), emulsions (EW), such as oil-in-water and water-in-oil emulsions, spray solutions, suspension concentrates (SC), dispersion in oil or water phase, oil emulsion solutions, capsule suspensions (CS), spray agent (DP), disinfectants, granulates for spreading and soil treatment, granulates (GR) in the form of microgranules , dispersible granulates, coated granulates and absorption granulates, water-dispersible granulates (WG), water-soluble granulates (SG), ultra-low volume (ULV) formulations, microcapsules and waxes. These individual types of formulations are in principle known to the person skilled in the art and are described, for example, in Winnacker-Kuchler, Chemische Technologie, vol. 7, published by S. Hanser Publishing House Munich, 4th ed., 1986; Wade van Valkenburg, Pesticide Formulations, Marcel Dekker, N.Y., 1973; K. Martens, Spray Drying Handbook, 3rd ed. 1979, G. Goodwin Ltd., London.

These individual types of formulation auxiliaries, such as inerts, surfactants, solvents and other additives, are also known and are described, for example, in Watkins, Handbook of Insecticide Dust Diluents and Carriers, 2nd ed., Darland Books, Caldwell N.J., H.v. Olphen, Introduction to Clay Colloid Chemistry, 2nd ed., J. Wiley & Sons, N.Y., C. Marsden, Solvents Guide, 2nd ed., Interscience, N.Y. 1963, McCutcheon's Detergents and Emulsifiers Annual, MC Publ. Corp., Ridgewood N.J., Sisley & Wood, Encyclopedia of Surface Active Agents, Chem. Publ. Co. Inc., N.Y. 1964, Schonfeldt, Grenzflachenaktive Athylenoxide-addukte, Wiss. Verlagsgesell., Stuttgart 1976, Winnacker-Kuchler, Chemische Technologie, vol. 7, published by S. Hanser, published by Munich, 4th ed. 1986.

Based on these formulations, combinations with other active ingredients, such as insecticides, acaricides, herbicides, fungicides, as well as protective agents, fertilizers and/or growth regulators, for example, in the form of ready-made formulations or in the form of mixing in a container.

As combining partners for the compounds according to the invention in mixed formulations or when mixed in containers, known active substances are used, which are based, for example, on the inhibition of, for example, the enzyme acetolactate synthase, the enzyme acetyl-CoA carboxylase, cellulose synthase, enolpyruvate shikimate- 3-phosphate synthase, glutamine synthase, p-hydroxyphenylpyruvate dioxygenase, phytoene desaturase, photosystem I, photosystem II, protoporphyrinogen oxidase, as described, for example, in Weed Research 26, (1986) 441-445; or The Pesticide Manual, 15th ed., The British Crop Protection Council and the Royal Soc. of Chemistry, 2006 and the literature mentioned there. Mentioned below are examples of known herbicides or plant growth regulators that can be combined with the compounds of the invention, these active substances being either indicated by a generic name in English according to the International Organization for Standardization (ISO) or by a chemical name or by a code number. All forms of use are present, such as acids, salts, esters, as well as all isomeric forms, such as stereoisomers and optical isomers, even if they are not explicitly stated.

Examples of such herbicidal mixing partners are acetochlor, acifluorphene, acifluorphene sodium, aclonifen, alachlor, allidochlor, alloxydim, alloxydim sodium, ametrine, amicarba

- 36 044070 zones, amidochlor, amidosulfuron, aminocyclopyrapyrachlor, aminocyclopyrachlor-potassium, aminocyclopyrachlor-methyl, aminopyralid, amitrol, ammonium sulfamate, anilofos, asulam, atrazine, azaphenidine, azimsulfuron, beflubutamide, benazoline, bena zoline-ethyl, benfluralin, benfuresat, bensulfuron, бенсульфурон-метил, бенсулид, бентазон, бензобициклон, бензофенап, бициклопирон, бифенокс, биланафос, биланафос-натрий, биспирибак, биспирибак-натрий, бромацил, бромобутид, бромофеноксим, бромоксинил, бромоксинил-бутират, -калий, -гептаноат и -октаноат, бусоксинон , butachlor, butafenacil, butamifos, butenachlor, butralin, butroxidim, butylate, cafenstrol, carbetamide, carfentrazone, carfentrazone-ethyl, chloramben, chlorbromuron, chlorfenac, chlorfenac-sodium, chlorfenprop, chloroflurenol, chloroflurenol-methyl, chloridazon, chlorimuron, chlorimuron-ethyl , chlorophthalim, chlorotoluron, chlorthaldimethyl, chlorsulfuron, 3-[5-chloro-4-(trifluoromethyl)pyridin-2-yl]-4-hydroxy-1-methylimidazolidin2-one, cynidone, cynidone-ethyl, cinmethylin, cinosulfuron, clacifos, clethodim, clodinafop, clodinafop-propargyl, clomazone, clomeprop, clopyralid, cloransulam, cloransulam-methyl, cumyluron, cyanamide, cyanazine, cycloate, cyclopyranil, cyclopyrimorate, cyclosulfamuron, cycloxydim, cyhalofop, cyhalofop-butyl, cyprazine, 2,4- D, 2,4-D-butothyl, -butyl, dimethylammonium, -diolamine, -ethyl, 2-ethylhexyl, -isobutyl, -isooctyl, -isopropylammonium, -potassium, -triisopropanolammonium and -trolamine, 2,4-DB, 2,4 -OV-6util, -dimethylammonium, isooctyl, -potassium and -sodium, daimuron (Dimron), dalapon, dazomet, n-decanol, desmedipham, detosil-pyrazolate (DTP), dicamba, dichlobenil, 2-(2,4-dichlorobenzyl )-4,4dimethyl-1,2-oxazolidin-3-one, 2-(2,5-dichlorobenzyl)-4,4-dimethyl-1,2-oxazolidin-3-one, dichlorprop, dichlorprop-R, diclofop, diclofop-methyl, diclofop-R-methyl, diclosulam, difenzoquat, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dimefuron, dimepiperate, dimethachlor, dimethamethrin, dimethenamid, dimethenamid-R, dimerasulfuron, dinitramine, dinoterb, difenamide, diquat, diquat-dibromide, dithiopyr, diuron, DNOC, endothal, EPTC, esprocarb, ethalfluralin, etamethsulfuron, etamethsulfuronmethyl, etiosin, etofumesate, ethoxyphene, ethoxyphene-ethyl, ethoxysulfuron, etobenzanide, F-9600, F-5231, i.e. N-[2-chloro-4-fluoro-5-[4-(3-fluoropyl)-4,5-dihydro-5-oxo-1H-tetrazol-1-yl]-phenyl]-ethanesulfonamide, F-7967, those. 3-[7-chloro-5-fluoro-2-(trifluoromethyl)-1H-benzimidazol-4-ul]-1-methyl-6-(trifluoromethyl)pyrimidine2,4(1H,3H)-dione, fenoxaprop, fenoxaprop- R, fenoxaprop-ethyl, fenoxaprop-R-ethyl, fenoxasulfone, fenquinotrione, fentrisamide, flamprop, flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, florasulam, florpyrauxifen, florpyrauxifen-benzyl, fluazifop, fluazifop-R, fluazifopbutyl, fluazifop-R-butyl, flucarbazone, flucarbazone-sodium, flucetosulfuron, fluchloralin, flufenacet, flufenpyr, flufenpyr-ethyl, flumetsulam, flumiclorac, flumiclorac-pentyl, flumioxazin, fluometuron, flurenol, flurenol-butyl, -dimethylammonium and -methyl, fluorine roglycofen, fluoroglycophenethyl, flupropanate, flupirsulfuron, flupirsulfuron-methyl-sodium, fluridone, flurochloridone, fluroxypyr, fluroxypyr-meptyl, flurtamone, flutiacet, flutiacet-methyl, fomesafen, fomesafen sodium, foramsulfuron, fosamine, glufosinate, glufosinate-am monium, glufosinate-R-sodium, glufosinate-R-ammonium, glufosinate-R-sodium, glyphosate, glyphosate-ammonium, -isopropylammonium, -diammonium, -dimethylammonium, -potassium, -sodium and -trimesium, H-9201, i.e. O-(2,4-dimethyl-6-nitrophenyl)-O-ethylisopropylphosphoramidothioate, halauxifen, halauxifen-methyl, halosaphen, halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop-R, haloxyfop-ethoxyethyl, haloxyfop-R-ethoxyethyl, haloxyfopmethyl, haloxyfop-R-methyl, hexazinone, HW-02, i.e. 1-(dimethoxyphosphoryl)-ethyl-(2,4-dichlorophenoxy)acetate, 4-hydroxy-1-methoxy-5-methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one, 4 -hydroxy-1methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one, imazamethabenz, imazamethabenz-methyl, imazamox, imazamox-ammonium, imazapic, imazapic-ammonium, imazapyr, imazapyr-isopropylammonium, imazaquin , imazaquin-ammonium, imazethapyr, imazethapyr-immonium, imazosulfuron, indanofan, indaziflam, iodosulfuron, iodosulfuron-methyl-sodium, ioxynil, ioxynyl-octanoate, -potassium and sodium, ipfencarbazone, isoproturon, isouron, isoxaben, isoxaflutole, carbutylate, KU H- 043, i.e. 3-({[5-(difluoromethyl)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl}sulfonyl)-5,5-dimethyl4,5-dihydro-1,2-oxazole, ketospiradox, lactofen, lenacyl, linuron, MCPA, MCPA-butyl, -dimethylammonium, -2-ethylhexyl, -isopropylammonium, -potassium and -sodium, MSRP, MSRP-methyl, -ethyl and -sodium, mecoprop, mecoprop-sodium, and -butotyl, mecoprop-R, mecoprop-R-butotyl, -dimethylammonium, -2-ethylhexyl and -potassium, mefenacet, mefluidide, mesosulfuron, mesosulfuron-methyl, mesotrione, metabenzthiazuron, metam, metamifop, metamitron, metazachlor, metazosulfuron, metabenzthiazuron, methiopyrsulfuron, methiozoline, methyl isothiocmanate, metobromuron, metolachlor, S-metolachlor, metosulam, methoxuron, metribuzin, metsulfuron, metsulfuron-methyl, molinate, monolinuron, monosulfuron, monosulfuron ester, MT-5950, i.e. N-[3-chloro-4-(1-methylethyl)phenyl]-2-methylpentanamide, NGGC-011, napropamide, NC-310, i.e. 4-(2,4-dichlorobenzoyl)-1-methyl-5-benzyloxypyrazole, neburon, nicosulfuron, nonylic acid (pelargonic acid), norflurazon, oleic acid (fatty acid), orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazop, oxasulfuron, oxacyclomefone, oxyfluorphene, paraquat, paraquat dichloride, pebulate, pendimethalin, penoxsulam, pentachlorophenol, pentoxazone, petoxamide, mineral oil, phenmedipham, picloram, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfuron, primisulfuron-methyl, prodiamine, profoxidim, promethone, prometrin , propachlor, propanil, propaquizafop, propazine, profam, propisochlor, propoxycarbazone, propoxycarbazone sodium, propyrisulfuron, propyzamide, prosulfocarb, prosulfuron, pyraclonil, piraph

- 37 044070 lufen, pyraflufen-ethyl, pyrasulfotol, pyrazolinate (pyrazolate), pyrazosulfuron, pyrazosulfuronethyl, pyrazoxifene, pyribambenz, pyribambenz-isopropyl, piribambenz-propyl, piribambenzoxime, pyributicarb, pyridafol, pyridate, pyrifthalide, pyriminobac, pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyrithiobac-sodium, pyroxasulfone, pyroxsulam, quinclorac, quinmerac, quinoclamine, quizalofop, quizalofop-ethyl, quizalofop-R, quizalofop-R-ethyl, quizalofop-R-tefuril, rimsulfuron, saflufenacil, sethoxydim, siduron, simazine, symetrine , SL-261, sulcotrione, sulfentrazone, sulfometuron, sulfometuron-methyl, sulfosulfuron, SYN-523, SYP-249, i.e. 1-ethoxy-3-methyl-1-oxobut-3en-2-yl-5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate, SYP-300, i.e. 1-[7-fluoro-3-oxo-4-(prop-2in-1-yl)-3,4-dihydro-2H-1,4-benzoxazin-6-yl]-3-propyl-2-thioxoimidazolidin- 4,5-dione, 2,3,6-TBA, TCA (trifluoroacetic acid), TCA sodium, tebuthiuron, tefuryltrione, tembotrione, tepraloxydim, terbacil, terbucarb, terbumetone, terbutylazine, terbutryn, tenylchlor, thiazopyr, thiencarbazone, thiencarbazonemethyl, thifensulfuron, thifensulfuron-methyl, thiobencarb, thiaphenacyl, tolpiralate, topramesone, tralkoxydim, triafamone, tri-allate, triasulfuron, triaziflam, tribenuron, tribenuron-methyl, triclopyr, trietazine, trifloxysulfuron, trifloxysulfuron-sodium, trifludimoxazine, trifluralin , trifluusulfuron, triflusulfuron- methyl, tritosulfuron, urea sulfate, vernolate, XDE-848, ZJ-0862, i.e. 3,4-dichloro-N-{2-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzyl}aniline, as well as the following compounds:

Examples of possible mixing partners for plant growth regulators are acibenzolar, acibenzolar-S-methyl, 5-aminolevulinic acid, ancymidol, 6-benzylaminopurine, brassinolide, catechin, chlormequat chloride, cloprop, cyclanilide, 3-(cycloprop-1-enyl)propionic acid, daminoside, dazomet, n-decanol, dikegulac, dikegulac sodium, endothal, endothal dipotassium, -disodium, and mono(N,N-dimethylalkylammonium), ethephon, flumetralin, flurenol, flurenol-butyl, flurprimidol, forchlorfenuron, gibberellic acid, inabenfide, indole-3-acetic acid (IAA), 4-indol-3ylbutyric acid, isoprothiolane, probenazole, jasmonic acid, jasmonic acid methyl ester, maleic hydrazide, mepiquat chloride, 1-methylcyclopropene, 2-(1-naphthyl) acetamide, 1-naphthylacetic acid, 2-naphthyloxyacetic acid, nitrophenolate mixture, 4-oxo-4[(2-phenylethyl)amino]butyric acid, paclobutrazol, N-phenylphthalic acid polyamide, prohexadione, prohexadione-calcium, prohydroyasmon, salicylic acid, strigolactone, tecnazene, thidiazuron, triacontanol, trinexapac, trinexapac-ethyl, tsitodef, uniconazole, uniconazole-R.

Protective agents which can be used in combination with the compounds of formula (I) according to the invention and, if necessary, in combination with other active substances, such as insecticides, acaricides, herbicides, fungicides as described above, preferably selected from the group consisting of the following.

S1) Compounds of formula (S1)

D, (S1) w _A R _a , and the symbols and indices have the following meanings:

n _A means a natural number 0-5, preferably 0-3;

RA ¹ means halogen, (C ₁ -C ₄ )-alkyl, (C ₁ -C ₄ )-alkoxy, nitro or (C ₁ -C ₄ )-haloalkyl;

W _A means an unsubstituted or substituted divalent heterocyclic residue from the group of partially unsaturated or aromatic heterocycles with five rings with 1-3 ring heteroatoms from the group N and O, and at least one N-atom and at most one O-atom are present in the ring, preferably a residue from the group (W _A ¹ )-(W _A ⁴ )

- 38 044070

m _A means 0 or 1;

R _a ² means ORA ³ , SRA ³ or NRA ³ RA ⁴ or a saturated or unsaturated 3-6 membered heterocycle with at least one N atom and containing up to 3 heteroatoms, preferably from the group O and S, which is linked by N- atom with a carbonyl group in (S1) and is unsubstituted or substituted by residues from the group (C1-C4)-alkyl, (C1-C4)-alkoxy or optionally substituted by phenyl, preferably a residue of the formula ORA ³ , NHRA ⁴ or N(CH ₃ ) ₂ , especially preferably the formula ORA ³ ;

R _A ³ means hydrogen or an unsubstituted or substituted aliphatic hydrocarbon residue, preferably with 1-18 C atoms;

R _a ⁴ means hydrogen, (C1-C ₆ )-alkyl, (C1-C ₆ )-alkoxy or substituted or unsubstituted phenyl;

R _a ⁵ means H, (C1-C8)-alkyl, (C1-C8)-haloalkyl, (C1-C4)-alkoxy(C1-C8)-alkyl, cyano or COORA ⁹ , where Ra ⁹ means hydrogen, (C1 -C ₈ )-alkyl, (C ₁ -C ₈ )-haloalkyl, (C ₁ -C ₄ )-alkoxy-(C ₁ -C ₄ )-alkyl, (C1-C ₆ )-hydroxyalkyl, (C ₃ - C ₁₂ )-cycloalkyl or tri-(C ₁ -C ₄ )-alkyl-silyl;

R _a ⁶ , Ra ⁷ , Ra ⁸ are or other than hydrogen, (C ₁ -C ₈ )-alkyl, (C 1 -C ₈ )-haloalkyl, (C ₃ -C ₁₂ )-cycloalkyl or substituted or unsubstituted phenyl; preferably

a) compounds of the dichlorophenylpyrazoline-3-carboxylic acid (S1 ^a ) type, preferably compounds such as 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylic acid, ethyl 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylic acid ester (S1-1) (mefenpyr-diethyl), and related compounds which are described in WO-A -91/07874;

b) dichlorophenylpyrazolecarboxylic acid derivatives ( ^S1b ), preferably compounds such as 1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylic acid ethyl ester (S1-2), 1-(2,4- dichlorophenyl)-5-isopropylpyrazole-3-carboxylic acid (S1-3), 1-(2,4-dichlorophenyl)-5-(1,1-dimethyl-ethyl)pyrazole-3-carboxylic acid ethyl ester (S1-4 ) and related compounds, which are described in EP-A-333131 and EP-A-269806;

c) derivatives of 1,5-diphenylpyrazole-3-carboxylic acid (S1 ^c ), preferably compounds such as 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylic acid ethyl ester (S1-5), methyl 1-(2-chlorophenyl)-5-phenylpyrazole-3-carboxylic acid ester (S1-6) and related compounds, which are described, for example, in EP-A-268554;

d) compounds of the triazolecarboxylic acid type (S1 ^d ), preferably compounds such as fenchlorazole (ethyl ester), i.e. 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1,2,4-triazole-3carboxylic acid ethyl ester (S1-7), and related compounds, which are described in EP-A-174562 and EP -A-346620;

e) compounds of the type 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid or 5,5-diphenyl2-isoxazoline-3-carboxylic acid (S1 ^e ), preferably compounds such as 5-ethyl ester (2,4-dichlorobenzyl)-2-isoxazoline-3-carboxylic acid (S1-8) or 5-phenyl-2-isoxazoline3-carboxylic acid ethyl ester (S1-9) and related compounds which are described in WO-A- 91/08202, or 5,5-diphenyl-2-isoxazoline-carboxylic acid (S1-10) or 5,5-diphenyl-2-isoxazoline3-carboxylic acid ethyl ester (S1-11) (isoxaphene-ethyl) or -n -propyl ester (S1-12) or 5-(4-fluorophenyl)-5-phenyl-2-isoxazoline-3-carboxylic acid ethyl ester (S1-13), as described in patent application WO-A-95/07897.

S2) quinoline derivatives of formula (S2)

and the symbols and indices have the following meanings:

RB ¹ means halogen, (C1- _C4 )-alkyl, (C1- _C4 )-alkoxy, nitro or ( _C1 - _C4 )-haloalkyl;

n _B means a natural number 0-5, preferably 0-3;

Rb ² means ORB ³ , SRB ³ or NRB3RB ⁴ or a saturated or unsaturated 3-7 membered heterocycle with at least one N atom and containing up to 3 heteroatoms, preferably from the group O and S, which is linked via an N atom to the carbonyl group group in (S2) and is unsubstituted or substituted with residues from the group (C1-C4)-alkyl, (C1-C4)-alkoxy or optionally substituted with phenyl, preferably a residue of the formula ORB ³ , NHRB ⁴ or N(CH3) ₂ , particularly preferably the formula OR _B ³ ;

- 39 044070

RB ³ means hydrogen or an unsubstituted or substituted aliphatic hydrocarbon residue, preferably with 1-18 C atoms;

RB ⁴ means hydrogen, (C _g C ₆ )-alkyl, (C ₁ -C ₆ )-alkoxy or substituted or unsubstituted phenyl;

Tb means a (C ₁ or C 2 )-alkanediyl chain which is unsubstituted or may be substituted by one or two (C ₁ -C ₄ )-alkyl residues or [(C ₁ -C ₃ )-alkoxy]carbonyl; preferably

a) compounds of the type 8-quinolineoxyacetic acid (S2 ^a ), preferably (1-methylhexyl)ester (5-chloro-8-quinolineoxy)acetic acid (cloquintocet-mexyl) (S2-1), (1,3dimethyl-but-1-yl )(5-chloro-8-quinolinoxy)acetic acid ester (S2-2), (5-chloro-8-quinolinoxy)acetic acid 4-allyloxy-butyl ester (S2-3), 1-allyloxy-prop-2- (5-chloro-8-quinolinoxy)acetic acid ethyl ester (S2-4), (5-chloro-8-quinolinoxy)acetic acid ethyl ester (S2-5), (5-chloro-8-quinolinoxy)acetic acid methyl ester ( S2-6), (5-chloro-8quinolinoxy)acetic acid allyl ester (S2-7), (5-chloro-8quinolinoxy)acetic acid 2-(2-propylidene-iminoxy)-1-ethyl ester (S2-8) , (5-chloro-8-quinolinoxy)acetic acid 2-oxo-prop-1-yl ester (S2-9) and related compounds as described in EP-A-86750, EP-A-94349 and EP-A- 191736 or EP-A-0492366, as well as (5-chloro-8-quinolinoxy)acetic acid (S2-10), its hydrates and salts, for example their lithium, sodium, potassium, calcium, magnesium, aluminum, iron, ammonium salts , quaternary ammonium, sulfonium, or phosphonium salts, which are described in WO-A-2002/34048;

b) compounds of the type (5-chloro-8-quinolinoxy)malonic acid (S2 ^b ), preferably compounds such as (5-chloro-8-quinolinoxy)malonic acid diethyl ester, (5-chloro8-quinolinoxy)malonic acid diallyl ester , (5-chloro-8-quinolinoxy)malonic acid methyl ethyl ester and related compounds, which are described in EP-A-0582198.

S3) Compounds of formula (S3)

O ^R _c ²

R _c N ^{c c} I , (S3)

Rc where the symbols and indices have the following meanings:

RC ¹ means (C ₁ -C ₄ )-alkyl, (C ₁ -C ₄ )-haloalkyl, (C ₂ -C ₄ )-alkenyl, (C ₂ -C ₄ )-haloalkenyl, (C ₃ -C ₇ ) -cycloalkyl, preferably dichloromethyl;

RC ² , RC ³ are equal to or different from hydrogen, (C ₁ -C ₄ )-alkyl, (C ₂ -C ₄ )-alkenyl, (C ₂ -C ₄ )-alkynyl, (C ₁ -C ₄ )-haloalkyl , (C ₂ -C ₄ )-haloalkenyl, (C ₁ -C ₄ )-alkylcarbamoyl-(C ₁ -C ₄ )-alkyl, (C ₂ -C ₄ )-alkenylcarbamoyl (C ₁ -C ₄ )-alkyl, (C ₁ -C ₄ )-alkoxy-(C ₁ -C ₄ )-alkyl, dioxolanyl-(C ₁ -C ₄ )-alkyl, thiazolyl, furyl, furylalkyl, thienyl, piperidyl, substituted or unsubstituted phenyl; or

_RC ² and _RC ³ together form a substituted or unsubstituted heterocyclic ring, preferably an oxazolidine, thiazolidine, piperidine, morpholine, hexahydropyrimidine or benzoxazine ring; preferably active ingredients of the dichloroacetamide type, which are often used as pre-emergence protectants (soil protectants), such as dichloromide (N,N-diallyl-2,2-dichloroacetamide) (S3-1),

R-29148 (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine) from Stauffer (S3-2),

R-28725 (3-dichloroacetyl-2,2,-dimethyl-1,3-oxazolidine) from Stauffer (S3-3), benoxacor (4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4 -benzoxazine) (S3-4),

PPG-1292 (N-allyl-N-[(1,3-dioxolan-2-yl)methyl]dichloroacetamide) from PPG Industries (S3-5),

DKA-24 (N-allyl-N-[(allylaminocarbonyl)methyl]dichloroacetamide) from Sagro-Chem (S3-6),

AD-67 or MON 4660 (3-dichloroacetyl-1-oxa-3-aza-spiro[4,5]decane) from Nitrokemia or Monsanto (S3-7),

TI-35 (1-dichloroacetyl-azepane) from TRI-Chemical RT (S3-8), diclonone (dicyclonone) or BAS145138 or LAB145138 (S3-9), ((RS)-1-dichloroacetyl-3,3,8a- trimethylperhydropyrrolo[1,2-a]nirimidin-6-one) from BASF, furilazole or MON 13900 ((RS)-3-dichloroacetyl-5-(2-furyl)-2,2-dimethyloxazolidine) (S3-10), as well as their (R)-isomer (S3-11).

S4) N-acylsulfonamides of formula (S4) and their salts

where the symbols and subscripts have the following meanings: A _d means SO2-NRD3-CO or CO-NRD3-SO2;

- 40 044070

XD means CH or N;

RD ¹ means CO-NRD5RD ⁶ or NHCO-RD ⁷ ;

RD ² means halogen, (C ₁ -C ₄ )-haloalkyl, (C ₁ -C ₄ )-haloalkoxy, nitro, (C ₁ -C ₄ )-alkyl, (C ₁ -C ₄ )-alkoxy, (C ₁ -C ₄ )-alkylsulfonyl, (C1-C ₄ )-alkoxycarbonyl or (C1-C ₄ )-alkylcarbonyl;

RD ³ means hydrogen, (C1- _C4 )-alkyl, ( _C2 - _C4 )-alkenyl or ( _C2 - _C4 )-alkynyl;

RD ⁴ means halogen, nitro, (C1- _C4 )-alkyl, ( _C1 - _C4 )-haloalkyl, ( _C1 - _C4 )-haloalkoxy, ( _C3 - _C6 )-cycloalkyl, phenyl, (C1 -C ₄ )-alkoxy, cyano, (C ₁ -C ₄ )-alkylthio, (C ₁ -C ₄ )-alkylsulfinyl, (C ₁ -C ₄ )-alkylsulfonyl, (C ₁ -C ₄ )-alkoxycarbonyl or ( C1- _C4 )-alkylcarbonyl;

RD ⁵ means hydrogen, (C1- _C6 )-alkyl, ( _C3 - _C6 )-cycloalkyl, ( _C2 - _C6 )-alkenyl, ( _C2 - _C6 )-alkynyl, ( _C5 - _C6) )-cycloalkenyl, phenyl or 3-6-membered heterocyclyl containing a vD heteroatom from the group of nitrogen, oxygen and sulfur, with the last seven residues being substituted by vD substituents from the halogen group, (C1- _C6 )-alkoxy, (C1- _C6 )-haloalkoxy, (C1- _C2 )-alkylsulfinyl, ( _C1 - _C2 )-alkylsulfonyl, ( _C3 - _C6 )-cycloalkyl, (C1- _C4 )-alkoxycarbonyl, ( _C1 - _C4 )- alkylcarbonyl and phenyl and in the case of cyclic radicals also (C1- _C4 )-alkyl and (C1- _C4 )-haloalkyl are substituted;

R _D ⁶ means hydrogen, (C ₁ -C ₆ )-alkyl, (C ₂ -C ₆ )-alkenyl or (C ₂ -C ₆ )-alkynyl, the last three residues being replaced by vD residues from the halogen group, hydroxy, (C1- _C4 )-alkyl, (C1- _C4 )-alkoxy and (C1- _C4 )-alkylthio; or

RD ⁵ and RD ⁶ together with the nitrogen atom present form a pyrrolidinyl or piperidinyl residue;

RD ⁷ represents hydrogen, (C1- _C4 )-alkylamino, di-( _C1 - _C4 )-alkylamino, (C1- _C6 )-alkyl, ( _C3 - _C6 )-cycloalkyl, with the last 2 residues are substituted with vD substituents from the halogen group, (C1- _C4 )-alkoxy, ( _C1 - _C6 )-haloalkoxy and (C1- _C4 )-alkylthio, and in the case of cyclic residues are also substituted with ( _C1 - _C4 )-alkyl and (C ₁ -C ₄ )-haloalkyl;

nD means 0, 1 or 2;

mD means 1 or 2;

v _D means 0, 1, 2 or 3;

Of these, preference is given to compounds of the N-acylsulfonamide type, for example of the following formula (S4 ^a ), which are known, for example, from WO-A-97/45016

where RD ⁷ means (C1-C ₆ )-alkyl, (C ₃ -C ₆ )-cycloalkyl, and the last 2 residues are substituted with vD substituents from the halogen group, (C ₁ -C ₄ )-alkoxy, (C ₁ -C ₆ )-haloalkoxy and (C1- _C4 )-alkylthio and in the case of cyclic residues also substituted ( _C1 - _C4 )-alkyl and ( _C1 - _C4 )-haloalkyl;

RD ⁴ means halogen, (C1-C ₄ )-alkyl, (C1-C ₄ )-alkoxy, CF ₃ ;

mD means 1 or 2;

v _D means 0, 1, 2 or 3;

as well as acylsulfamoylbenzoic acid amides, for example of the following formula (S4 ^b ), which are, for example, known from WO-A-99/16744,

O

for example, those where RD ⁵ =cyclopropyl and (RD ⁴ ) = 2-OMe (cyprosulfamides, S4-1);

RD ⁵ =cyclopropyl and (RD ⁴ ) = 5-Cl-2-Ome (S4-2);

RD ⁵ =ethyl and (RD ⁴ )=2-Ome (S4-3);

RD ⁵ =cyclopropyl and (RD ⁴ ) = 5-Cl-2-Ome (S4-4); And

RD ⁵ =ethyl and (RD ⁴ ) = 2-Ome (S4-5), as well as compounds of the N-acylsulfamoylphenylurea type (S4c), which are, for example, known from EP-A-365484,

where RD ⁸ and RD9 are independently hydrogen, (C1- _C8 )-alkyl, ( _C3 - _C8 )-cycloalkyl, ( _C3 - _C6 )-alkenyl, (C3-C6)-alkynyl,

RD ⁴ means halogen, (C1-C4)-alkyl, (C1-C4)-alkoxy, CF3;

m _D means 1 or 2;

for example, 1-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3-methylurea, 1-[4-(N-2methoxybenzoylsulfamoyl)phenyl]-3,3-dimethylurea, 1-[4-(N-4, 5-dimethylbenzoylsulfamoyl)phenyl] - 41 044070

3-methylurea, as well as

N-phenylsulfonyl terephthalamides of formula (S4 ^d ), which are for example known from CN 101838227

for example, those where RD ⁴ means halogen, (C1-C ₄ )-alkyl, (C1-C ₄ )-alkoxy, CF ₃ ;

mD means 1 or 2;

RD ⁵ means hydrogen, (C1- _C6 )-alkyl, ( _C3 - _C6 )-cycloalkyl, ( _C2 - _C6 )-alkenyl, ( _C2 - _C6 )-alkynyl, ( _C5 - _C6) )-cycloalkenyl.

S5) active ingredients from the class of hydroxy-aromatic compounds and aromatic-aliphatic carboxylic acid derivatives (S5), for example 3,4,5-triacetoxybenzoic acid ethyl ester, 3,5-dimethoxy-4-hydroxybenzoic acid, 3,5-dihydroxybenzoic acid, 4 -hydroxysalicylic acid, 4-fluorosalicylic acid, 2-hydroxycinnamic acid, 2,4-dichlorocinnamic acid, which are described in WO-A-2004/084631, WO-A-2005/015994,

WO-A-2005/016001.

S6) active substances from the class of 1,2-dihydroquinoxalin-2-ones (S6), for example, 1-methyl-3-(2thienyl)-1,2-dihydroquinoxalin-2-one, 1-methyl-3-(2- thienyl)-1,2-dihydroquinoxalin-2-thione, 1-(2-aminoethyl)3-(2-thienyl)-1,2-dihydroquinoxalin-2-one hydrochloride, 1-(2-methylsulfonylaminoethyl)- 3-(2-thienyl)1,2-dihydroquinoxalin-2-one, which are described in WO-A-2005/112630.

S7) Compounds of formula (S7) which are described in WO-A-1998/38856 n ₂ s ^-a _E (θ)ηΕ1 ^15.1 where the symbols and subscripts have the following meanings:

RE ¹ , RE ² mean, independently of each other, halogen, (C1- _C4 )-alkyl, ( _C1 - _C4 )-alkoxy, (C1- _C4 )-haloalkyl, (C1- _C4 )-alkylamino, di -(C ₁ -C ₄ )-alkylamino, nitro;

AE stands for COORE ³ or COSRE ⁴ ;

RE ³ , RE ⁴ independently of each other mean hydrogen, (C1- _C4 )-alkyl, ( _C2 - _C6 )-alkenyl, ( _C2 - _C4 )-alkynyl, cyanoalkyl, (C1- _C4 )- haloalkyl, phenyl, nitrophenyl, benzyl, halobenzyl, pyridinyl alkyl and alkylammonium, nE ¹ means 0 or 1;

n _E ² , n _E ³ independently of each other mean 0, 1 or 2; preferably diphenylmethoxyacetic acid, diphenylmethoxyacetic acid ethyl ester, diphenylmethoxyacetic acid methyl ester (CAS Reg. No. 41858-19-9) (S7-1).

S8) Compounds of formula (S8) which are described in WO-A-98/27049, where

O ^{(S8) X} FR _F ³

XF means CH or N;

nF, if XF=N, means an integer from 0 to 4 and, if X _F =CH, means an integer from 0 to 5;

RF ¹ means halogen, (C1- _C4 )-alkyl, ( _{C1 - C4} )-haloalkyl, (C1-C4)-alkoxy, ( _C1 - _C4 )-haloalkoxy, nitro, (C1- _C4 )-alkylthio, (C1- _C4 )-alkylsulfonyl, ( _C1 - _C4 )-alkoxycarbonyl, optionally substituted phenyl, optionally substituted phenoxy;

RF ² means hydrogen or (C1- _C4 )-alkyl;

RF ³ means hydrogen, (C1- _C8 )-alkyl, ( _C2 - _C4 )-alkenyl, ( _C2 - _C4 )-alkynyl or aryl, each of the previously named C-containing residues being unsubstituted or substituted by one or more, preferably up to three, identical or different radicals from the group consisting of halogen and alkoxy;

or salts thereof, preferably compounds where XF is CH;

nF means integer 0-2;

RF ¹ means halogen, (C1- _C4 )-alkyl, (C1- _C4 )-haloalkyl, (C1- _C4 )-alkoxy, ( _C1 - _C4 )-haloalkoxy;

RF ² means hydrogen or (C1- _C4 )-alkyl;

RF ³ means hydrogen, (C1- _C8 )-alkyl, ( _C2 - _C4 )-alkenyl, ( _C2 - _C4 )-alkynyl or aryl, each of

- 42 044070 of the previously named C-containing radicals is unsubstituted or is substituted by one or more, preferably up to three, identical or different radicals from the group consisting of halogen and alkoxy;

or their salts.

S9) Active ingredients from the class of 3-(5-tetrazolylcarbonyl)-2-quinolones (S9), for example 1,2-dihydro-4-hydroxy-1-ethyl-3-(5-tetrazolylcarbonyl)-2-quinolone (reg. CAS No. 219479-18-2), 1,2-dihydro4-hydroxy-1-methyl-3-(5-tetrazolylcarbonyl)-2-quinolone (CAS Reg. No. 95855-00-8), which are described in WO -A-1999/000020.

S10) compounds of formula (S10a) or (S10b) which are described in WO-A-2007/023719 and WO-A-2007/023764

(S10 ^a ) (S10 ^b ) where RG ¹ means halogen, (C ₁ -C ₄ )-alkyl, methoxy, nitro, cyano, CF ₃ , OCF ₃ ;

YG, ZG independently of each other mean O or S;

n _G means integer 0-4;

RG ² means (C1- _C16 )-alkyl, ( _C2 - _C6 )-alkenyl, ( _C3 - _C6 )-cycloalkyl, aryl, benzyl, halobenzyl;

RG ³ means hydrogen or (C1-C ₆ )-alkyl.

S11) Active substances of the type hydroxyimino compounds (S11), which are used as seed dressings, such as oxabetrinil ((Z)-1,3-dioxolan-2ylmethoxyimino(phenyl)acetonitrile) (S11-1), which used as a protective agent for treating millet seeds against damage caused by metolachlor, fluxofenim (1-(4-chlorophenyl)2,2,2-trifluoro-1-ethanone-O-(1,3-dioxolan-2-ylmethyl) oxime) (S11-2), which is used as a seed protectant for switchgrass against damage caused by metolachlor, and ciometrinil or CGA-43089 ((Z)-cyanomethoxyimino(phenyl)-acetonitrile) (S11-3), which used as a protective agent for treating millet seeds against damage caused by metolachlor.

S12) Active ingredients from the class of isothiochromanones (S12), such as methyl [(3-oxo-1H2-benzothiopyran-4(3H)-ylidene)methoxy] acetate (CAS Reg. No. 205121-04-6) (S12 -1) and related compounds from WO-A-1998/13361.

S13) One or more compounds from group (S13) naphthalic anhydride (1,8-naphthalenedicarboxylic acid anhydride) (S13-1), which is used as a protectant for treating corn seeds against damage caused by thiocarbamate herbicides, fenclorim (4,6 -dichloro-2-phenylpyrimidine) (S13-2), which is used as a protectant against pretilachlor in planted rice, flurazole (benzyl-2-chloro-4-trifluoromethyl-1,3-thiazol-5-carboxylate) (S13- 3), which is used as a protective agent for treating millet seeds against damage caused by alachlor and metolachlor,

CL 304415 (CAS Reg. No. 31541-57-8), (4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid) (S13-4) from American Cyanamid, which is used as a protective agents for corn against damage caused by imidazolinones,

MG 191 (registration no. CAS 96420-72-3) (2-dichloromethyl-2-methyl-1,3-dioxolane) (S13-5) from Nitrokemia, which is used as a corn protectant,

MG 838 (CAS Reg. No. 133993-74-5), (2-propenyl 1-oxa-4-azaspiro[4.5]decane-4-carbodithioate) (S13-6) from Nitrokemia, disulfoton (O,O-diethyl S -2-ethylthioethylphosphorothioate) (S13-7), dietolate (O,O-diethyl-Ophenylphosphorothioate) (S13-8), mephenate (4-chlorophenyl-methylcarbamate) (S13-9).

S14) Active substances which, in addition to the herbicidal effect against harmful plants, also have a protective effect on crop plants such as rice, such as dimepiperate or MY-93 (S-1-methyl-1-phenylethyl-piperidine-1-carbothioate ), which is a protective agent for rice against damage caused by the herbicide molinate;

daimuron or SK 23 (1-(1-methyl-1-phenylethyl)-3-p-tolyl-urea), which is a protective agent for rice against damage caused by the herbicide imazosulfuron, cumiduron=JC-940 (3-(2- chlorophenylmethyl)-1-(1-methyl-1-phenyl-ethyl)urea, see JP-A-60087254), which is a rice protectant against damage caused by certain herbicides, methoxyphenone or NK 049 (3,3-dimethyl -4-methoxy-benzophenone), which is a protective agent for rice against damage caused by some herbicides,

- 43 044070

CSB (1-bromo-4-(chloromethylsulfonyl)benzene) from Kumiai (CAS Reg. No. 54091-06-4), which protects rice against damage caused by certain herbicides.

S15) Compounds of formula (S15) or tautomers thereof

ABOUT

Il I h (S15) R^N^O n which are described in WO-A-2008/131861 and WO-A-2008/131860, where RH ¹ means (C ₁ -C ₆ )-haloalkyl radical;

RH ² means hydrogen or halogen; And

RH ³ , RH ⁴ independently of each other mean hydrogen, (C1-C ₁₆ )-alkyl, (C ₂ -C ₁₆ )-alkenyl or (C ₂ -C ₁₆ )-alkynyl, each of the last three residues being unsubstituted or may be substituted by one or more radicals from the halogen group, hydroxy, cyano, (C1- _C4 )-alkoxy, (C1- _C4 )-haloalkoxy, (C1- _C4 )-alkylthio, (C1- _C4 )- alkylamino, di[(C1-C ₄ )-alkyl]amino, [(C1-C ₄ )-alkoxy]carbonyl, [(C1-C ₄ )haloalkoxy]carbonyl, (C ₃ -C ₆ )-cycloalkyl, which is unsubstituted or substituted, phenyl which is unsubstituted or substituted, and heterocyclyl which is unsubstituted or substituted, or (C ₃ -C ₆ )-cycloalkyl, (C ₄ -C ₆ )-cycloalkenyl, (C ₃ -C ₆ )- cycloalkyl, which on the ring side is condensed with one 4-6-membered saturated or unsaturated carbocyclic ring, or (C ₄ -C ₆ )-cycloalkenyl, which on the ring side is condensed with one 4-6-membered saturated or unsaturated carbocyclic ring, each of The last 4 residues named are unsubstituted or may be substituted by one or more residues from the group halogen, hydroxy, cyano, (C1- _C4 )-alkyl, (C1- _C4 )-haloalkyl, (C1- _C4 )-alkoxy, ( C1- _C4 )-haloalkoxy, (C1- _C4 )-alkylthio, (C1- _C4 )-alkylamino, di[(C1- _C4 )-alkyl]amino, [(C1- _C4 )-alkoxy]carbonyl , [(C1- _C4 )-haloalkoxy]carbonyl, ( _C3 - _C6 )-cycloalkyl which is unsubstituted or substituted, phenyl which is unsubstituted or substituted, and heterocyclyl which is unsubstituted or substituted; or

RH ³ means (C1- _C4 )-alkoxy, ( _C2 - _C4 )-alkenyloxy, ( _C2 - _C6 )-alkynyloxy or ( _C2 - _C4 )-haloalkoxy; And

RH ⁴ means hydrogen or (C1-C ₄ )-alkyl; or

RH ³ and RH ⁴ together with the directly connected N-atom means a 4-8 membered heterocyclic ring, which, in addition to the N-atom, can also contain other ring heteroatoms, preferably up to 2 other ring heteroatoms from the group N, O and S, and which is unsubstituted or substituted by one or more residues from the group of halogen, cyano, nitro, (C1-C ₄ )-alkyl, (C1-C ₄ )-haloalkyl, (C1-C ₄ )-alkoxy, (C1-C ₄ )- haloalkoxy and (C1- _C4 )-alkylthio.

S16) Active substances which are primarily used as herbicides, but which also have a protective effect on crop plants, for example (2,4-dichlorophenoxy)acetic acid (2,4-D), (4-chlorophenoxy)acetic acid, (R ,S)-2-(4-chloro-o-tolyloxy)nropionic acid (mecoprop), 4-(2,4-dichlorophenoxy)butyric acid (2,4-DB), (4-chloro-o-tolyloxy)acetic acid (MCPA), 4-(4-chloro-o-tolyloxy)butyric acid, 4-(4-chlorophenoxy)butyric acid, 3,6-dichloro-2methoxybenzoic acid (dicamba), 1-(ethoxycarbonyl)ethyl-3, 6-dichloro-2-methoxybenzoate (lactidichloroethyl).

Particularly preferred protectants are mefenpyr diethyl, cyprosulfamide, isoxadifen ethyl, cloquintocet mexyl, benoxacor, dichlormide and metcamifene.

Powders for spraying are preparations that are uniformly dispersed in water, which, along with the active substance, in addition to a diluent or inert substance, also contain nonionic and/or ionic surfactants (wetting agents, dispersants), for example, polyoxyethylated alkylphenols, polyoxethylated aliphatic alcohols, polyoxethylated aliphatic amines, fatty alcohol polyglycol ether sulfates, alkanesulfonates, alkyl benzene sulfonates, sodium lignin sulfonic acid, sodium 2,2'-dinaphthylmethane-6,6-disulfonic acid, sodium dibutylnaphthalene sulfonic acid or also sodium oleol methyl taurine acid. For the production of spray powders, the herbicidal active substances are finely ground, for example using conventional equipment such as a hammer mill, a blower mill or an air jet mill, and either directly or subsequently mixed with formulation auxiliaries.

Emulsifiable concentrates are obtained by dissolving the biologically active substance in an organic solvent, for example, butanol, cyclohexanone, dimethylformamide, xylene, or also in high-boiling aromatic compounds or hydrocarbons, or mixtures of an organic solvent using one or more ionic and/or nonionic surfactants (emulsifiers). As emulsifiers, for example, calcium salts of alkylaryl sulfonic acid, such as Ca-dodecylbenzenesulfonate, or nonionic emulsifiers, such as polyglycol fatty acid ester, alkylaryl polyglycol ether, polyglycol ether of fatty alcohol, condensation products of propylene oxide-ethylene oxide, alkyl polyether, sorbitan ester, such as sorbitan fatty acid ester or polyoxyethylene sorbitan ester, such as polyoxyethylene sorbitan fatty acid ester.

Pollinating agents are obtained by grinding the biologically active substance with finely ground solids such as talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.

Suspension concentrates can be water or oil based. They can be obtained, for example, by wet grinding using standard bead mills, if necessary with the addition of a surfactant, as, for example, already mentioned in other types of formulations.

Emulsions, for example oil-in-water (EW) emulsions, can be prepared using stirrers, colloid mills and/or static mixers using aqueous organic solvents and optionally surfactants, as, for example, already mentioned in other types of formulations.

Granulates can be produced by spraying the active ingredient onto granular inert adsorbents or applying a concentrate of the active ingredient using binders such as polyvinyl alcohol, sodium polyacrylic acid or also mineral oils onto the surface of a filler such as sand, kaolinite or granular inert material. Also for the production of granulates for fertilizers, the relevant active substances are crushed in the usual way, optionally mixed with fertilizers.

Water-dispersible granulates are generally produced by conventional processes such as spray drying, fluidized bed granulation, disc granulation, high-speed mixer granulation and solid-free extrusion.

For the production of granulates using a disc granulator, fluidized bed, extruder and spray drying granulates, see, for example, the method in the Spray-Drying Handbook, 3rd ed., 1979, G. Goodwin Ltd., London, J.E. Browning, Agglomeration, Chemical and Engineering, 1967, p. 147 and others; Perry's Chemical Engineer's Handbook, 5th ed., McGraw-Hill, New York 1973, p. 8-57.

For further details on formulations of plant protection products, see, for example, G.C. Klingman, Weed Control as a Science, John Wiley and Sons, Inc., New York, 1961, p. 81-96; and J.D. Freyer, S.A. Evans, Weed Control Handbook, 5th ed., Blackwell Scientific Publications, Oxford, 1968, p. 101-103.

Agrochemical preparative forms contain, as a rule, 0.1-99% by weight, especially 0.1-95% by weight, of the compounds according to the invention. In dusting powders, the concentration of the active substance is, for example, 10-90% by weight of the residue to 100% by weight of the usual components of the preparative form. In emulsifiable concentrates, the concentration of biologically active substance can be approximately 1-90, preferably 5-80 wt.%. Dust-like preparative forms contain 1-30 wt.% of the active substance, preferably at least 5-20 wt.% of the active substance, solutions for scattering contain approximately 0.05-80 wt.%, preferably 2-50 wt.% of the active substance. In water-dispersible granulates, the content of the active component depends in part on whether the active compound is present in liquid or solid form and what granulating auxiliaries, fillers, etc. are used. are used. In water-dispersible granulates, the active substance content is, for example, 1-95% by weight, preferably 10-80% by weight.

In addition, the named compounds of active substances, if necessary, contain the usual adhesive, wetting, dispersing, emulsifying, penetrating, preservative agents, anti-frost agents and solvents, fillers, carriers, dyes, defoamers, brake evaporators and antitranspirants and agents influencing pH level and viscosity.

Based on these compositions, it is also possible to obtain combinations with other pesticidal active substances, such as insecticides, acaricides, herbicides, fungicides, as well as protective agents, fertilizers and/or growth regulators, for example, in the form of ready-made compositions or in the form of mixing in a container .

For use, the conventionally present compositions are diluted with water in the usual manner, for example in the form of sprayable powders, emulsifiable concentrates, dispersions and water-dispersible granulates. Pulverized compositions, soil granules or granulates, and spray solutions are generally not diluted with other inert substances before use.

When exposed to external conditions, such as temperature, humidity, type of herbicide used, etc., the required rates of compounds of formula (I), as well as their salts, change. They may vary within certain limits, for example 0.001-10.0 kg/ha or more of the active substance, but preferably it is 0.005-5 g/ha, even more preferably from 0.01 to 1.5 kg/ha, especially preferably from 0.05 to 1 kg/ha. This applies to pre-emergence or post-emergence applications.

Excipient means a natural or synthetic, organic or inorganic substance with which active ingredients are mixed or combined for improved usability, for application to plants or plant parts, or seed material. The filler, which can be solid or liquid, is generally inert and should be used in agriculture.

As solid or liquid fillers, take into account, for example, ammonium salts and natural stone flour, such as kaolin, alumina, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic stone flour, such as highly dispersed silicic acid, aluminum oxide and natural or synthetic silicates, resins, waxes, solid fertilizers, water, alcohol, especially butanol, organic solvents, mineral and vegetable oils, as well as their derivatives. Mixtures of such fillers can also be used. As solid fillers for granulates, we take into account, for example, broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite, as well as synthetic granulates from inorganic and organic flour, as well as granulates from organic materials such as sawdust, coconut shells, corn cobs and tobacco plant stems.

As liquefied gaseous diluents or fillers, liquids that are gaseous at normal temperature and pressure are taken into account, for example aerosol propellants such as halocarbons, but also butane, propane, nitrogen and carbon dioxide.

Adhesion promoters such as carboxymethylcellulose, natural and synthetic powdered, particulate or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids such as cephalin and lecithin, and synthetic phospholipids can be used in the compositions. Other additives may include mineral and vegetable oils.

In the case of using water as a diluent, it is possible, for example, to also use organic solvents as auxiliary solvents. The following are generally taken into account as liquid solvents: Aromatic hydrocarbons such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic hydrocarbons or chlorinated aliphatic hydrocarbons such as chlorobenzene, chloroethenes or dichloromethane, aliphatic hydrocarbons such as cyclohexane or paraffin, for example petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanope, very polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.

The products according to the invention may additionally contain two components, such as clomazone and surfactants. Suitable surfactants include emulsifiers and/or foaming agents, dispersants or wetting agents with ionic or non-ionic properties, or mixtures of these surfactants. Examples thereof are salts of polyacrylic acid, salts of lignosulfonic acid, salts of phenolsulfonic acid or naphthalene sulfonic acid, polycondensates of ethylene oxide with aliphatic alcohols or with aliphatic amines, substituted phenols (preferably alkylphenols or arylphenols), salts of sulfosuccinic acid esters, taurine derivatives (preferably alkyl taurate), phosphate esters polyethoxylated alcohols or phenols, fatty acid esters of polyhydric alcohols, and derivatives of compounds containing sulfates, sulfonates and phosphates, for example alkylaryl polyglycol ether, alkyl sulfonate, alkyl sulfate, arylsulfonate, protein hydrolysates, lignin sulfite liquor and methylcellulose. The presence of surfactants is necessary if one of the active substances and/or one of the excipients is insoluble in water and if the application takes place in water. The amount of surfactants is 5-40 wt.% according to the invention. Inorganic pigments such as iron oxide, titanium oxide, ferrocyano blue and organic dyes such as alizarin dyes, azo dyes and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.

If necessary, other additional components may also be present, for example, protective colloids, binders, adhesives, thickeners, thixotropes, penetration enhancers, stabilizers, complexing compound, complexing agents. In general, the active ingredients can be combined with solid or liquid additives that are typically used for the composition. In general, the agents and compositions according to the invention contain 0.05-99, 0.01-98% by weight, preferably 0.1-95% by weight, particularly preferably 0.5-90% of the active substance, very preferably 10-70% by weight .%. The active substances or agents according to the invention can be used in pure form or, depending on their respective physical and/or chemical properties, in the form of their compositions or application forms derived from them, such as aerosols, capsule suspensions, cold fog concentrates, hot fog concentrates, granulates in capsules, fine granulates, liquid concentrate for seed treatment, ready-to-use solution, dusting powder, emulsifiable concentrate, oil-in-water emulsions, water-in-oil emulsions, macrogranulates, microgranulates, oil-dispersible powder, liquid mixing concentrate in oil, oil-mixable liquids, foams, pastes, pesticide-coated seeds, suspension concentrates, suspension-emulsion concentrate, soluble concentrate, suspension, spray powders, soluble powder, pollinators and granules,

- 46 044070 water-soluble granules or tablets, water-soluble seed processing powder, drenching powder, natural and synthetic materials impregnated with active substances, as well as fine-grained substances in capsules of polymeric substances and in seed coatings, as well as compositions for ULV cold and hot fog generator.

Said compositions can be prepared in a known manner, for example by mixing the active substances with at least one conventional diluent, solvent, emulsifier, dispersant and/or astringent or fixative, wetting agent, aqueous repellent, optionally a drier and UV stabilizers and optionally a dye and pigment, defoamers, preservative, secondary thickener, adhesive, gibberellins, as well as other technological additives.

The products according to the invention contain not only compositions that are ready for use and can be applied to plants or seed material using special equipment, but also commercially available concentrates, which must be diluted with water before use.

The active substances according to the invention can be present in pure form or in the form of their (conventional) mixtures, as well as forms of application obtained from these compositions in mixtures with other (known) active substances, such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides , growth regulators, herbicides, fertilizers, protective agents or semiochemicals.

Treatment according to the invention of plants and plant parts with active substances or means is carried out by direct application or exposure to the environment, habitat or storage place by conventional treatment methods, for example, dipping (spraying), spraying, spraying, irrigation, liquid spray, atomization, dusting (scattering ) by shedding, foaming, coating, pre-coating, watering (solid watering), drip irrigation also on plant propagation material, especially seeds, then using dry etching, wet etching, etching in solutions, applying a layer, applying one or more shells, etc. .d. Next, you can apply the active ingredients using the ultra-low volume method or inject a solution of the active ingredients or the active ingredient itself into the soil.

One of the advantages of the present invention is that, due to the special systemic properties of the active substances or agents according to the invention, the treatment of seed material with these active substances or agents protects not only the seed material, but also the plants obtained from it after germination from phytopathogenic fungi. In this way, it is possible not to carry out direct processing of crops at the time of sowing or immediately after it.

It is also considered advantageous that the active substances or agents according to the invention can especially be used on transgenic seed material, whereby the plants growing from this seed material are capable of expressing a protein that has an effect on pests. By treating such seed material with the active substances or agents according to the invention by expressing, for example, an insecticidal protein, certain pests can be controlled. At the same time, another synergistic effect was unexpectedly observed, which further increases the effectiveness of protection against pest damage.

The means according to the invention are suitable for protecting the seed material of any plants that are grown in agriculture, in a greenhouse, in forests or in horticulture and viticulture. This particularly means the seed material of cereal crops (such as wheat, barley, rye, triticale, millet and oats), corn, cotton, soybeans, rice, potatoes, sunflowers, beans, coffee, beets (such as sugar beets and fodder beets), peanuts, rapeseed, poppy seeds, olives, coconut, cocoa, sugar cane, tobacco, vegetables (such as tomatoes, cucumbers, onions and lettuce), lawn grass and ornamental plants (see also below). Of particular importance is the processing of seed material of cereal crops (such as wheat, barley, rye, triticale and oats), corn and rice.

As also described below, the treatment of transgenic seed material with the active substances or agents according to the invention is of particular importance. This applies to plant seeds that contain at least one heterologous gene that promotes the expression of a polypeptide or protein with insecticidal properties. The heterologous gene in the transgenic seed material can be derived, for example, from microorganisms of the species Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium. Preferably, the heterologous gene is derived from Bacillus sp., the gene product having activity against the European corn borer and/or the Western corn rootworm. Particularly preferably the heterologous one comes from Bacillus thuringiensis.

In the context of the present invention, the agent according to the invention, alone or in a suitable composition, is applied to the seed material. Preferably, the seed material is processed in a state in which it is stable so that damage does not occur during processing. In general, seed processing can be carried out at any time between harvest and sowing. Typically, seed material is used that does not have additional plant parts, cobs,

- 47 044070 peel, stems, shell, hairs or pulp of the fruit. For example, you can use seed material that has been collected, cleaned and dried to a moisture content of less than 15% by weight. Alternatively, it is also possible to use seed material which, for example, after drying, has been treated with water and then dried again.

In general, during the processing of seed material, care must be taken to ensure that the amount of the product according to the invention and/or other additives applied to the seed material does not harm the germination of the seeds or harm the plants grown from them. This is primarily taken into account when using those active substances that, at a certain rate of consumption, can have a phytotoxic effect.

The products according to the invention can be applied in pure form, i.e. without containing other components and without dilution with water. In general, it is preferred to apply the agents to the seed in the form of suitable compositions. Suitable compositions and methods for treating seed material are known in the art and are described, for example, in the following documents: US 4272417 A, US 4245432 A, US 4808430, US 5876739, US 2003/0176428 A1, WO 2002/080675 A1, WO 2002/028186 A2 .

The active substances used according to the invention can be converted into conventional seed treatment compositions, such as solutions, emulsions, suspensions, powders, foams, seed suspensions or other seed coatings, as well as ULV compositions.

These compositions are prepared in a known manner, for example by mixing the active substances with conventional additives, such as conventional diluents, as well as solvents or fillers, coloring agents, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and also water .

The dyes that may be present in the dressing agent compositions used according to the invention include all dyes customary for such purposes. In this case, you can use both poorly water-soluble pigments and water-soluble dyes. As examples, the well-known dyes rhodamine B, C.I. pigment red 112 and S.T. solvent red 1.

As wetting agents that may be present in the disinfectant compositions used according to the invention, all substances customary for wetting compositions of agrochemical substances are taken into account. Preferably, alkyl naphthalene sulfonates are used, such as diisopropyl or diisobutyl naphthalene sulfonates.

Dispersants and/or emulsifiers that may be present in the disinfectant compositions used according to the invention include all nonionic, anionic and cationic dispersants customary for such a composition. Preferably, nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants are used. Particular mention should be made as suitable nonionic dispersants of ethylene oxide-propylene oxide block copolymers, alkylphenol polyglycol ethers, as well as tristyrylphenol polyglycol ether and their phosphated or sulfated derivatives. Suitable anionic dispersants are particularly lignin sulfonates, polyacrylic acid salts and arylsulfonate formaldehyde condensates.

As defoaming agents which may be present in the dressing agent compositions used according to the invention, all conventional anti-foaming agents for agrochemical compositions are taken into account. Preferably, silicone defoamers and magnesium stearate are used.

All suitable substances used in agrochemicals may be present in the preservative compositions used according to the invention as preservatives. For example, dichlorophen and benzyl alcohol hemiformal should be named.

As secondary thickeners that may be present in the dressing agent compositions used according to the invention, all substances used for this purpose in agrochemicals are taken into account. Preferably, cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and highly dispersed silicic acid are taken into account.

As adhesives that may be present in the dressing agent compositions used according to the invention, all adhesives used in the dressing agents for this purpose are taken into account. Preferably, polyvinylpyrrolylone, polyvinyl acetate, polyvinyl alcohol and tylose should be mentioned.

The disinfectant compositions used according to the invention can be used either in pure form or after preliminary dilution with water to treat seed material of various types, including seed material of transgenic plants. Moreover, when interacting with substances formed as a result of expression, additional synergistic effects may also occur.

To treat the seed material with the dressing compositions used according to the invention or the compositions obtained from them by adding water, all mixers used for dressing are usually taken into account. In particular, when dressing the seed material is placed in a mixer, the appropriate required amount of the dressing composition is added either in pure form or after preliminary dilution with water and mixed until the composition is evenly distributed on the seed material. If necessary, the drying process is also added.

The active substances according to the invention, with good compatibility with plants, lack of toxicity for warm-blooded animals and good environmental compatibility, are suitable for protecting plants and plant organs, increasing the amount of harvest, improving the quality of the harvest. They can preferably be used as plant protection agents. They act on species with normal sensitivity and resistant species, and also act at all or individual stages of development.

Among the plants that can be treated according to the invention are the following main cultivated plants: corn, soybeans, cotton, Brassica oilseeds such as Brassica napus (for example canola), Brassica rapa, B. juncea (for example field mustard) and Brassica carinata, rice, wheat, sugar beets, sugar cane, oats, rye, barley, millet, triticale, flax, grapes and various fruits and vegetables of different botanical classes, such as Rosaceae sp. (e.g. pome fruits such as apples and pears, as well as stone fruits such as apricots, cherries, almonds and peaches, and horticultural crops such as strawberries), Ribesioidae sp., Juglandaceae sp., Betulaceae sp., Anacardiaceae sp. ., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp., Musaceae sp. (e.g. banana trees and plantations), Rubiaceae sp. (e.g. coffee), Theaceae sp., Sterculiceae sp., Rutaceae sp. (eg lemons, oranges and grapefruits); Solanaceae sp. (e.g. tomatoes, potatoes, peppers, eggplants), Liliaceae sp., Compositae sp. (e.g. lettuce, artichoke and lettuce endive - including root endive, endive or regular endive), Umbelliferae sp. (e.g. carrots, parsley, stalk celery and root celery), Cucurbitaceae sp. (e.g. cucumbers - including pickling cucumbers, pumpkin, watermelon, bottle gourd and melon), Alliaceae sp. (e.g. green onions and onions), Cruciferae sp. (e.g. white cabbage, red cabbage, broccoli, cauliflower, Brussels sprouts, pak choi, kohlrabi, radish, horseradish, watercress and bok choy), Leguminosae sp. (eg peanuts, peas and legumes - such as runner beans and broad beans), Chenopodiaceae sp. (e.g. Swiss chard, fodder beet, spinach, red beet), Malvaceae (e.g. okra), Asparagaceae (e.g. asparagus); useful and ornamental plants in the garden and forest; as well as correspondingly genetically modified species of these plants.

As mentioned above, all plants and parts thereof can be treated according to the invention. In a preferred embodiment, wild plants or plants obtained by traditional breeding methods, such as crossing or protoplast synthesis, are processed, as well as their parts. In another preferred embodiment, transgenic plants and plants obtained using genetic technological methods, if necessary in combination with traditional methods (genetically modified organisms), and their parts are processed. The concept of part or part of plants was mentioned above. Particularly preferably, the plants according to the invention are treated according to common or used plant varieties. Plant varieties mean plants with new properties (Traits), which were obtained using traditional breeding methods, mutagenesis, and recombinant DNA technologies. These can be varieties, breeds, bio- and genotypes.

The methods of the invention can be used to process genetically modified organisms (GMOs), for example plants or seeds. Genetically modified plants (or transgenic plants) are plants in which one heterologous gene is stably integrated into the genome. The term heterologous gene generally means a gene which is obtained or assembled outside the plant and which, when introduced into the nuclear genome of a plant cell, the chloroplast genome or the mitochondrial genome of the transformed plant, imparts to it new or improved agrochemical or similar properties, due to the expression of a new essential protein or polypeptide, or reprogramming or disabling another gene that is present in the plant, or other genes that are present in the plant (for example, using antisense technologies, cosuppression technologies, or RNA interference [RNAi] technologies). A heterologous gene that is present in the genome is also called a transgene. A transgene, which is defined by its specific location in the plant genome, is called a transformation or transgenic event.

Depending on the species or varieties of plants, where they grow and their growth conditions (soil, climate, growing season, nutrition), the treatment according to the invention can also lead to super-additive (synergistic) effects. For example, the following effects that exceed the expected ones are possible: reducing application rates and/or expanding the range of effects and/or increasing the effectiveness of active substances and compositions used according to this invention that can be used according to the invention, better plant growth, increased tolerance to high and low temperatures, increased tolerance to dryness or to the water and salt content of the soil, increased flowering productivity, easier harvesting, faster ripening, increased harvest size, larger fruits, larger plant sizes, deeper green leaf color, more early flowering, improved quality and/or increased nutritional value of the crop product, higher sugar content of the fruit, increased storage stability and/or processability of the crop product.

At certain application rates, the combinations of active substances according to the invention can also have a strong effect on plants. Therefore, they are suitable for mobilizing the plant defense system against damage by unwanted phytopathogenic fungi and/or microorganisms and/or viruses. If necessary, this may be one of the reasons for the increased effectiveness of the combination according to the invention, for example against mushrooms. Plant strengthening (defense-inducing) substances in this context should also mean those substances or combinations of substances that are capable of stimulating the plant defense system in such a way that the treated plants, if in addition inoculated with undesirable phytopathogenic fungi, exhibit significant resistance to these undesirable plant pathogens. phytopathogenic fungi. Therefore, the substances according to the invention can be used to protect the plant from damage by the mentioned pathogens for a certain period of time after treatment. The period of time during which the protective effect is exerted is generally 1-10 days, preferably 1-7 days after treatment of the plants with the active substances.

Plants and plant varieties that can be advantageously processed according to the invention include all plants that possess certain hereditary material that gives these plants particularly advantageous, beneficial traits (whether due to traditional breeding and/or biotechnology).

Plants and plant varieties that can also be treated according to the invention are resistant to one or more biotic stress factors, i.e. these plants exhibit improved protection against animal and microbiological pests such as nematodes, insects, mites, phytopathogenic fungi, bacteria, viruses and/or viroids.

Examples of nematode-resistant plants are, for example, the following plants described in US patent applications 11/765491, 11/765494, 10/926819, 10/782020, 12/032479, 10/783417, 10/782096, 11/657964, 12 /192904, 11/396808, 12/166253, 12/166239, 12/166124, 12/166209, 11/762886, 12/364335, 11/763947, 12/252453, 12/209354, 12/ 491396 and 12/497221 .

Plants and plant varieties that can also be treated according to the invention are those that are resistant to one or more abiotic stress factors. Abiotic stress conditions may include, for example, drought, cold and hot conditions, osmotic stress, stagnant water, increased soil salt, increased mineral deposition, ozone conditions, high light conditions, limited nitrogen nutrient availability, limited phosphorus nutrient availability or shadow avoidance.

Plants and plant varieties that can also be treated according to the present invention are those that exhibit enhanced yield qualities. Increased yield in these plants may, for example, be associated with improved plant physiology, improved plant growth, and improved plant development, such as efficient water use, efficient water retention, improved nitrogen utilization, increased carbon assimilation, improved photosynthesis, increased embryo vigor, and accelerated maturation. Along with this, yields can be increased by improving plant architecture (under stress and non-stress conditions), including early flowering, control of flowering for hybrid seed production, plant embryo development capacity, plant size, internodal number and spacing, root growth, seed size, fruit size, pod size, number of pods or ears, number of grains per pod or ear, seed mass, increased seed filling, reduced seed drop, reduced pod bursting, and storage stability. Other attributes of crop products include seed composition such as carbohydrate content, protein content, oil content and oil composition, nutritional value, reduction of nutritionally undesirable compounds, improved processability and improved shelf life of crop products.

Plants that can be treated according to this invention are hybrid plants that express the properties of heterosis, respectively, the hybrid effect, which generally leads to higher yield, higher growth, better health and better resistance to biotic and abiotic stress factors. Such plants are typically created by crossing a raised parent line with sterile pollen (the female partner in the cross) with another trained parent line with fertile (reproductive) pollen (the male partner in the cross). Hybrid seed is typically obtained from plants with sterile pollen and sold to those involved in further propagation. Plants with sterile pollen can sometimes be obtained (for example, in the case of corn) by detasseling (i.e., mechanical removal of the male reproductive organs, respectively, inflorescences); however, it is more common when pollen sterility is due to genetic determinants in the plant genome. In this case, particularly when seeds are the desired product to be harvested from hybrid plants, it is usually useful to ensure that pollen fertility is fully restored in hybrid plants that contain the genetic determinants responsible for pollen sterility. This can be achieved by using, when crossing, such male partners that contain the appropriate genes that restore fertility (reproduction), which have the ability to restore pollen fertility in hybrid plants containing genetic determinants responsible for pollen sterility. Genetic determinants responsible for pollen sterility can be localized in the cytoplasm. Examples of cytoplasmic pollen sterility (CMS) include, for example, species of the genus Brassica. Genetic determinants of pollen sterility may also be localized in the genome of the cell nucleus. Plants with sterile pollen can also be produced by plant biotechnology methods such as gene technology. A particularly advantageous means for creating plants with sterile pollen is described in W0 89/10396, whereby, for example, one ribonuclease, such as Barnase selectiv, is expressed in tapetum cells in pollinating leaves. Fertility can also be restored by expressing a ribonuclease inhibitor such as Barstar in Tapetum cells.

The plants or plant varieties (which can be obtained by plant biotechnology methods, such as gene technology) that can be treated according to the present invention are herbicide-tolerant plants, i.e. plants that are grown tolerant to one or more specified herbicides. Such plants can be obtained either as a result of genetic transformation or as a result of plant selection that includes a single mutation that provides such herbicide tolerance.

Herbicide-tolerant plants include, for example, plants tolerant to glyphosate, i.e. plants grown tolerant to the herbicide glyphosate or its salts. Plants can become tolerant to glyphosate through a variety of methods. Thus, for example, glyphosate-tolerant plants can be obtained by transforming the plant with a gene that encodes the enzyme 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS). Examples of such EPSPS genes include the AroA gene (CT7 mutant) of the bacterium Salmonella typhimurium (Comai et al., 1983, Science, 221, 370-371), the CP4 gene of the bacterium Agrobacterium sp. (Barry et al., 1992, Curr. Topics Plant Physiol., 7, 139-145), genes that encode one EPSPS from petunia, one EPSPS from tomato (Shah et al., 1986, Science, 233, 478-481 ) and one EPSPS from tomato (Gasser et al., 1988, J. Biol. Chem., 263, 4280-4289) or one EPSPS from eleusine (WO 01/66704). This may also refer to mutated EPSPS. Glyphosate-tolerant plants can also be obtained by expressing the gene that encodes the glyphosate oxidoreductase enzyme. Glyphosate-tolerant plants can also be obtained by expressing a gene that encodes the glyphosate acetyltransferase enzyme. Glyphosate-tolerant plants can also be obtained by breeding plants that contain naturally occurring mutations in the genes mentioned above. Plants that express the EPSPS gene, which confers tolerance to glyphosate, have been described. Plants have been described that express another gene that confers tolerance to glyphosate, such as the decarboxylase gene.

Other herbicide-tolerant plants include, for example, plants that are grown tolerant to herbicides that inhibit the glutamine synthase enzyme, such as bialaphos, phosphinothricin or glufosinate. Such plants can be obtained by expressing an enzyme that neutralizes the herbicide or a single mutant of the glutamine synthase enzyme that is resistant to inhibition. Such an effective detoxifying enzyme is, for example, an enzyme that encodes phosphinothricin acetyltransferase (such as the bar or pat protein found in Streptomyces species). Plants that express exogenous phosphinothricin acetyltransferase have been described.

Other herbicide-tolerant plants also include plants that are grown tolerant to herbicides that inhibit the enzyme hydroxyphenylpyruvate dioxygenase (HPPD). Hydroxyphenylpyruvate dioxygenases refer to enzymes that catalyze the reaction that converts para-hydroxyphenylpyruvate (HPP) to homogentisate. Plants that are tolerant to HPPD inhibitors can be transformed with a gene that encodes a naturally occurring resistant HPPD enzyme, or a gene that encodes a mutated or chimeric HPPD enzyme, as described in WO 96/38567, WO 99 /24585, WO 99/24586, WO 2009/144079, WO 2002/046387 or US 6768044. Tolerance to HPPD inhibitors can also be achieved by transforming plants with genes that encode certain enzymes that promote homogentisate formation , despite inhibition of the native HPPD enzyme by an HPPD inhibitor. Such plants are described in WO 99/34008 and WO 02/36787. Plant tolerance to HPPD inhibitors can also be improved by further transforming the plant that encodes the HPPD tolerant enzyme with a gene that encodes the prephenate dehydrogenase enzyme as described in WO 2004/024928. In addition, plants can be made more tolerant of HPPD inhibitors by introducing into the genome a gene that encodes an enzyme that metabolizes or degrades the HPPD inhibitor, such as CYP450 enzymes (see WO 2007/103567 and WO 2008/150473).

- 51 044070

Other herbicide-tolerant plants include plants grown tolerant to acetolactate synthase inhibitors (ALS inhibitors). Known ALS inhibitors include, for example, sulfonylurea, imidazolinone, triazolopyrimidine, pyrimidinyloxy(thio)benzoate and/or sulfonylaminocarbonyltriazolinone herbicides. Various mutations in the ALS enzyme (also known as acetohydroxyacid synthase, AHAS) are known to confer tolerance to various herbicides or groups of herbicides, such as those described in Tranel und Wright (Weed Science 2002, 50, 700-712). The production of plants tolerant to sulfonylureas, as well as plants tolerant to imidazolinone, is described. Other plants tolerant to sulfonylurea and imidazolinone have also been described.

Other plants tolerant to imidazolinone and/or sulfonylurea can be obtained by induced mutagenesis, selection of cell cultures in the presence of a herbicide, or by mutation selection (see, for example, for soybeans US 5084082, for rice WO 97/41218, for sugar beet US 5773702 and WO 99/057965, for lettuce US 5198599 or for sunflower WO 01/065922).

Plants or plant varieties (which are obtained by plant biotechnology methods, such as gene technology) that can also be processed according to this invention are transgenic plants that are insect resistant, i.e. plants that are grown to resist attack by specific target insects. Such plants can be obtained as a result of genetic transformation, or as a result of plant selection that includes a single mutation that provides such insect resistance.

The term insect-resistant transgenic plant covers in this context any plant that contains at least one transgene that includes a coding sequence encoding the following:

1) an insecticidal crystal protein (protein) from Bacillus thuringiensis or an insecticidal portion thereof, such as the insecticidal crystal proteins listed in Crickmore et al. (Microbiology and Molecular Biology Reviews, 1998, 62, 807-813), updated in Crickmore et al. (2005) in the Toxin Nomenclature of the bacterium Bacillus thuringiensis, presented online at: https://www.lifesci.Sussex.ac.uk/Home/Neil_Crickmore/Bt/), or its insecticidal part, for example, the Cry1Ab class of Cry proteins, CrylAc, Cry1B, Cry1C, Cry1D, Cry1F, Cry2Ab, Cry3Aa, or Cry3Bb or an insecticidal portion thereof (for example, EP-A 1999141 and WO 2007/107302), or such a protein encoded by a synthetic gene as described in US patent application 12/ 249.016; or

2) a crystal protein from Bacillus thuringiensis or a part thereof, which, in the presence of a second, different crystal protein from Bacillus thuringiensis or a part thereof, acts insecticidal, as a binary toxin, which consists of the crystal proteins Cy34 and Cy35; or (Nat. Biotechnol., 2001, 19, 668-72; Applied Environm. Microbiol., 2006, 71, 1765-1774) or a double toxin, which consists of Cry1A or Cry1F proteins and Cry2Aa or Cry2Ab or Cry2Ae protein (patent application US 12/214,022 and EP08010791.5); or

3) an insecticidal fusion protein that includes parts of two different insecticidal crystal proteins from Bacillus thuringiensis, such as a hybrid of proteins 1) above, or a hybrid of proteins 2) above, for example, the CrylA protein. 105, which is produced from the maize variant MON98034 (WO 2007/027777); or

4) a protein according to one of claims 1-3 above, in which some, in particular 1-10 amino acids are replaced by another amino acid in order to achieve higher insecticidal effectiveness against the target insects and/or in order to expand the range of relevant target insects, and/or due to changes that were induced in the coding DNA during cloning or transformation, such as the Cry3Bb1 protein in the maize variant MON863 or MON88017 or the Cry3A protein in the maize variant MIR 604;

5) insecticidal isolated protein from Bacillus thuringiensis or Bacillus cereus or an insecticidal part thereof, such as vegetative insecticidal proteins (vegetative insecticidal proteins, VIP), which are listed in https://www.lifesci.sussex.ac.uk /Home/Neil_Crickmore/Bt/vip.html, for example, Proteine der Proteinklasse VIP3 Aa; or

6) an isolated protein from Bacillus thuringiensis or Bacillus cereus, which, in the presence of another isolated protein from Bacillus thuringiensis or B. cereus, acts insecticidal, as well as a binary toxin, which consists of the VIPIA and VIP2A proteins (WO 94/21795); or

7) an insecticidal fusion protein that includes parts of various isolated proteins from Bacillus thuringiensis or Bacillus cereus, such as a fusion of proteins 1) or a fusion of proteins 2) above; or

8) a protein according to one of claims 5-7 above, in which some, especially 1-10 amino acids are replaced by another amino acid in order to achieve higher insecticidal effectiveness in relation to the target insect species and/or in order to expand range of relevant target insect species, and/or due to changes that have been induced in the coding DNA during cloning or transformation (whereby the coding is retained for one

- 52 044070 insecticidal protein), such as the VIP3Aa protein in the cotton variant COT 102; or

9) an isolated protein from Bacillus thuringiensis or Bacillus cereus, which in the presence of another isolated protein from Bacillus thuringiensis acts insecticidal, as well as a binary toxin that consists of the proteins VIP3 and Cry1A or Cry1F (US patent applications 61/126083 and 61/195019) , or a binary toxin that consists of VIP3 and Cry2Aa or Cry2Ab proteins or Cry2Ae proteins (US patent application 12/214022 and EP 8010791.5); or

10) a protein according to claim 9 above, in which some, especially 1-10 amino acids are replaced by another amino acid in order to achieve higher insecticidal effectiveness in relation to the target insect species and/or in order to expand the range of the corresponding target species insects, and/or due to changes that were induced in the coding DNA during cloning or transformation (whereby the coding is retained for a single insecticidal protein).

Naturally, insecticide-resistant transgenic plants in this invention also include any plant that includes a combination of genes that encode proteins from one of the above classes 1-10. In one embodiment of the invention, the insecticide-resistant plant contains more than one transgene encoding a protein from one of the above classes 1-10, in order to expand the range of relevant target insect species or in order to slow down the development of insect resistance to the plant, resulting in that they incorporate various proteins that have an insecticidal effect on the target insect species, but have a different mode of action, such as attachment to different receptor attachment sites in the insect.

An insecticide-resistant transgenic plant in this context means a plant that contains at least one transgene that contains an RNA double helix production sequence that, upon ingestion of a pest insect, inhibits the growth of that pest.

Plants or plant varieties (that have been produced by plant biotechnology methods such as gene technology) that can also be processed according to the present invention are tolerant of abiotic stress factors. Such plants can be obtained as a result of genetic transformation, or as a result of plant selection, which includes one mutation that provides such resistance to stress factors. Particularly useful stress-tolerant plants include the following:

a) plants that contain a transgene capable of reducing the expression and/or activity of the gene responsible for poly(ADP-ribose) polymerase (PARP) in plant cells or in plants.

b) plants that contain a transgene that creates stress tolerance, which is capable of reducing the expression and/or activity of the gene responsible for encoding PARG in plants or in plant cells;

c) plants that contain a transgene that creates stress tolerance, which encodes a plant-functional enzyme of the nicotinamide adenine dinucleotide-salvage biosynthesis pathway, among them nicotinamide, nicotinate phosphoribosyltransferase, nicotinic acid mononucleotide adenyltransferase, nicotinamide adenine dinucleotide synthetase or nicotinamide phosphoribosyltransferase.

Plants or plant varieties (that have been produced by plant biotechnology methods, such as gene technology) that can also be processed according to this invention are characterized by altered quantity, quality and/or better shelf life of the crop product and/or altered properties of certain components of the crop product , for example the following.

1) Transgenic plants that synthesize modified starch characterized by altered physicochemical properties, in particular amylose content or amylose/amylopectin ratio, degree of branching, average chain length, side chain separation, viscosity behavior, gel strength, starch grain size and/ or the morphology of the starch grains compared to starch that is synthesized by wild plant or plant cell types, so that this modified starch is better suited for some applications.

2) Transgenic plants that synthesize non-starch carbohydrate polymers, or non-starch carbohydrate polymers, the properties of which are changed compared to wild types of plants without genetic modifications. For example, plants that produce polyfructose, preferably of the inulin and levan type, plants that produce alpha-1,4-glucan, plants that produce alpha-1,6-branched alpha-1,4-glucans and plants that produce alternan.

3) Transgenic plants that produce hyaluronan.

4) Transgenic plants or hybrid plants, such as onions, with certain properties such as high soluble solids content, low pungency (LP) and/or long storage stability (LS).

Plants or plant varieties (that have been produced by plant biotechnology methods such as gene technology) that can also be processed according to the present invention are

- 53 044070 are cotton plants with altered fiber properties. Such plants can be obtained as a result of genetic transformation, or as a result of selection of plants that contain one mutation that causes such changes in fiber properties; These include

a) plants, such as cotton plants, which contain an altered form of cellulose synthase genes;

b) plants, such as cotton plants, which contain an altered form of rsw2 or gatl/3 homologs of nucleic acids; cotton plants with increased expression of sucrose phosphate synthase;

c) plants, such as cotton plants, with increased expression of sucrose synthase;

d) plants, such as cotton plants, in which the timing of plasmodesmata transmission at the base of the fiber cell is altered, for example as a result of down-regulation of fiber-selective β-1,3-glucanase;

e) plants, such as cotton plants with fibers with altered reactivity, for example, as a result of the expression of the N-acetylglucosamine transferase gene, among them also nodC, and the chitin synthase gene.

Plants or plant varieties (that have been produced by plant biotechnology methods such as gene technology) that can also be processed according to the present invention are rapeseed or Brassica-related plants with modified oil composition properties. Such plants can be obtained as a result of genetic transformation, or as a result of selection of plants that contain one mutation that causes such changes in the properties of the oil; These include

a) plants, such as rapeseed plants, which produce oil with a high oleic acid content;

b) plants, such as rapeseed plants, which produce oil with low linolenic acid content;

c) plants, such as rapeseed plants, which produce oil low in saturated fatty acids.

Plants or plant varieties (which can be obtained using plant biotechnology methods such as gene technology) that can also be processed according to the present invention are plants such as potatoes that are resistant to viruses, for example potato virus Y (event SY230 and SY233 Tecnoplant, Argentina), or which are resistant to diseases such as top rot or potato late blight (for example, the RB gene), or which show a reduction in cold-induced sweet taste (carried by the Nt-Inh genes , II-INV) or which show a dwarfism phenotype (A-20 oxidase gene).

Plants or plant varieties (that have been produced by plant biotechnology methods such as gene technology) that can also be processed according to the present invention are rapeseed plants or related Brassica plants with modified seed shattering properties. Such plants can be obtained by genetic transformation, or by selection of plants that contain a single mutation that causes such altered properties, and include plants such as rapeseed with delayed or reduced seed cracking.

Particularly useful transgenic plants that can be treated according to the present invention are those with a single transforming event or a combination of transforming events, which are the subject of the Animal and Plant Health Inspection Service (APHIS) of the United States Department of Agriculture (USDA). granted or pending applications for unregulated status. Information about this can be obtained at any time from APHIS (4700 River Road Riverdale, MD 20737, USA), for example, or at https://www.aphis.usda.gov/brs/not_reg.html. As of the date of this APHIS application, such petitions have already been filed or are pending.

Petition: personal identification number of the petition. A technical description of the transformation events received from APHIS can be found on the Internet page under the petition number. Moreover, these descriptions are disclosed based on reviews.

Petition Amendment: A review of an earlier petition that requires an amendment or additional information.

Institution: The name of the person filing the petition.

Subject of regulation: related plant species.

Transgenic phenotype: properties (Trait) that plants acquired as a result of transformation events.

Transformation event or lines: The name of the event or events (sometimes also called line/lines) for which unregulated status is required.

APHIS Documents: Various documents that have been published by APHIS regarding the petition or may be obtained from APHIS upon request.

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Particularly useful transgenic plants that can be treated according to this invention are those with one or more genes encoding one or more toxins, which are sold under the trade names: YIELD GARD® (e.g. corn, cotton, soybeans ), KnockOut® (eg corn), BiteGard® (eg corn), BT-Xtra® (eg corn), StarLink® (eg corn), Bollgard® (cotton), Nucotn® (cotton), Nucotn 33B ® (cotton), NatureGard® (e.g. corn), Protecta® and NewLeaf® (potatoes). Herbicide-tolerant plants worth mentioning are, for example, corn varieties, cotton varieties and soybean varieties, which are sold under the following trade names: Roundup Read®y (glyphosate tolerance, e.g. corn, cotton, soybeans), Liberty Link®) (phosphinothricin tolerance, eg canola), IMI® (imidazolinone tolerance) and SCS® (sulfonylurea tolerance, eg corn). Herbicide-tolerant plants (plants traditionally bred to tolerate herbicides) that should be mentioned include those sold under the trade name Clearfield® (such as corn).

Particularly useful transgenic plants that can be processed according to the present invention are plants in which transformation events or a combination of transformation events have occurred and which, for example, are listed in the database of various national or regional authorities (see, for example, https://gmoinfo .jrc.it/gmp_browse.aspx and https://ceragmc.org/index.php?evidcode=&hstIDXCode=&gType=&AbbrCode=&atCode=&stCode=&coIDCode=&action =gm_crop_database&mode=Submit).

The active substances or agents according to this can also be used in material protection to protect technical materials from attack and destruction by unwanted microorganisms, such as fungi and insects.

Furthermore, the compounds according to the present invention, alone or in combination with other biologically active substances, can be used as antifouling agents.

In this regard, technical materials should be understood as non-living materials that are prepared for use in technology. For example, technical materials that must be protected from microbial alteration or degradation may include adhesives, clays, paper, wallboard and cardboard, textiles, carpets, leather, wood, paints and plastics, cutting fluids, and others. materials that can be attacked or destroyed by microorganisms. Among the materials to be protected, mention should also be made of parts of production plants and buildings, for example water cooling circuits, cooling and heating systems, and ventilation and air conditioning units, which can be damaged by the proliferation of microorganisms. Within the scope of this invention, technical materials to be mentioned are preferably adhesives substances, clays, paper and cardboard, leather, wood, paints and varnishes, lubricants and coolants, especially preferably wood. The active substances or agents according to the invention can prevent undesirable effects such as rotting, decay, staining, discoloration or molding. In addition, the compounds according to the present invention can be used to protect against fouling of objects, in particular ship hulls, screens, nets, structures, mooring installations and signal installations, which may be in contact with sea water or waste water.

The method for controlling unwanted fungi according to the present invention can also be used to protect goods subject to long-term storage (Storage Goods). By goods subject to long-term storage are meant natural substances of plant or animal origin, or products of their processing, which are obtained from nature and for which long-term protection is necessary. Storable goods of plant origin, such as plants or parts of plants, for example stems, leaves, tubers, seeds, fruits, grains, can be protected as freshly harvested crops or after processing with (pre-)drying, moistening , chopping, grinding, pressing or roasting. Storable goods also include useful wood, whether it is unprocessed such as timber, utility poles and fencing, or in the form of finished products such as furniture. Products subject to long-term storage of animal origin include, for example, animal skins, leather, fur coats and hair. The active substances or agents according to the invention can prevent such negative effects as rotting, decay, staining, discoloration or molding.

By way of example, and in no way limiting, some of the fungal pathogens that can be treated according to this invention include: diseases caused by powdery mildew, such as, for example, species of the genus Bloomeria, for example, Blumeria graminis; species of the genus Podosphaera, such as, for example, Podosphaera leucotricha; species of the genus Sphaerotheca, such as, for example, Sphaerotheca fuliginea; kinds

- 55 044070 genus Uncinula, such as, for example, Uncinula necator; diseases caused by rust pathogens, such as, for example, species of the genus Gymnosporangium, such as, for example, Gymnosporangium sabinae; species of the genus Hemileia, such as, for example, Hemileia vastatrix; species of the genus Phakopsora, such as, for example, Phakopsora pachyrhizi and Phakopsora meibomiae; species of the genus Puccinia, such as, for example, Puccinia recondita or Puccinia triticina; species of the genus Uromyces, such as, for example, Uromyces appendiculatus; diseases caused by pathogens from the group of oomycetes (Oomycetes), such as, for example, species of the genus Bremia, such as, for example, Bremia lactucae; species of the genus Peronospora, such as, for example, Peronospora pisi or P. brassicae; species of the genus Phytophthora, such as, for example, Phytophthora infestans; species of the genus Plasmopara, such as, for example, Plasmopara viticola; species of the genus Pseudoperonospora, such as, for example, Pseudoperonospora humuli or Pseudoperonospora cubensis; species of the genus Pythium, such as, for example, Pythium ultimum; diseases leading to the formation of spots on the leaves, which cause, for example, species of leaves of the genus Alternaria (Alternaria), such as, for example, Alternaria solani; species of the genus Cercospora, such as, for example, Cercospora beticola; species of the genus Cladosporium, such as, for example, Cladosporium cucumerinum; species of the genus Cochliobolus, such as, for example, Cochliobolus sativus (conidial form: Drexler, syn: helminthosporium); species of the genus Colletotrichum, such as, for example, Colletotrichum lindemuthanium; species of the genus Cycloconium, such as, for example, Cycloconium oleaginum; species of the genus Diaporthe, such as, for example, Diaporthe citri; species of the genus Elsinoe, such as, for example, Elsinoe fawcettii; species of the genus Gloeosporium, such as, for example, Gloeosporium laeticolor; species of the genus Glomerella, such as, for example, Glomerella cingulata; species of the genus Guignardia, such as, for example, Guignardia bidwelli; species of the genus Leptosphaeria, such as, for example, Leptosphaeria maculans; species of the genus Magnaporthe, such as, for example, Magnaporthe grisea; species of the genus Microdochium, such as, for example, Microdochium nivale; species of the genus Mycosphaerella, such as, for example, Mycosphaerelle graminicola and M. fijiensis; species of the genus Phaeosphaeria, such as, for example, Phaeosphaeria nodorum; species of the genus Pyrenophora, such as, for example, Pyrenophora teres; species of the genus Ramularia, such as, for example, Ramularia collo-cygni; species of the genus Rhynchosporium, such as, for example, Rhynchosporium secalis; species of the genus Septoria, such as, for example, Septoria apii; species of the genus Typhula, such as, for example, Typhula incamata; species of the genus Venturia, such as, for example, Venturia inaequalis; diseases of roots and stems, which are caused, for example, by species of the genus Corticium, such as, for example, Corticium graminearum; species of the genus Fusarium, such as, for example, Fusarium oxysporum; species of the genus Gaeumannomyces, such as, for example, Gaeumannomyces graminis; species of the genus Rhizoctonia, such as, for example, Rhizoctonia solani; species of the genus Tapesia, such as, for example, Tapesia acuformis; species of the genus Thielaviopsis, such as, for example, Thielaviopsis basicola; diseases of ears and panicles (including heads of corn), which are caused, for example, by species of the genus Alternaria, such as, for example, Alternaria spp.; species of the genus Aspergillus, such as, for example, Aspergillus flavus; species of the genus Cladosporium, such as, for example, Cladosporium cladosporioides; species of the genus Claviceps, such as, for example, Claviceps purpurea; species of the genus Fusarium, such as, for example, Fusarium culmorum; species of the genus Gibberella, such as, for example, Gibberella zeae; species of the genus Monographella, such as, for example, Monographella nivalis; species of the genus Septoria, such as, for example, Septoria nodorum; diseases caused by smut fungi, such as, for example, species of the genus Sphacelotheca, such as, for example, Sphacelotheca reiliana; species of the genus Tilletia, such as, for example, Tilletia caries, T. controversa; species of the genus Urocystis, such as, for example, Urocystis occulta; species of the genus Ustilago, such as, for example, Ustilago nuda, U. nuda tritici; rotting of fruits, which is caused, for example, by species of the genus Aspergillus, such as, for example, Aspergillus flavus; species of the genus Botrytis, such as, for example, Botrytis cinerea; species of the genus Penicillium, such as, for example, Penicillium expansum and P. purpurogenum; species of the genus Sclerotinia, such as, for example, Sclerotinia sclerotiorum; species of the genus Verticilium, such as, for example, Verticilium alboatrum; diseases of seedlings originating from seeds and soil rot, which are caused by Fusarium, such as, for example, wilts, and for example, species of Fusarium culmorum; also genus species of the genus Phytophthora, such as, for example, Phytophthora cactorum; species of the genus Pythium, such as, for example, Pythium ultimum; species of the genus Rhizoctonia, such as, for example, Rhizoctonia solani; species of the genus Sclerotium, such as, for example, Sclerotium rolfsii; cancers, galls (growths) and witch's panicles, which are caused, for example, by species of the genus Nectria, such as, for example, Nectria galligena;

wilting diseases, which are caused, for example, by species of the genus Monilinia, such as, for example, Monilinia laxa;

deformations of leaves, inflorescences and fruits, which are caused, for example, by species of the genus Taphrina, such as, for example, Taphrina deformans; degenerative diseases of woody plants, which

- 56 044070 are caused, for example, by species of the genus Esca, such as, for example, Phaemoniella clamydospora, Phaeoacremonium aleophilum and Fomitiporia mediterranea; diseases of flowers and seeds, which are caused, for example, by species of the genus Botrytis, such as, for example, Botrytis cinerea; diseases of plant tubers, which are caused, for example, by species of the genus Rhizoctonia, such as, for example, Rhizoctonia solani; species of the genus Helminthosporium, such as, for example, Helminthosporium solani; diseases that are caused by bacterial pathogens, for example species of the genus Xanthomonas, such as, for example, Xanthomonas campestris pv. oryzae; species of the genus Pseudomonas, such as, for example, Pseudomonas syringae pv. lachrymans; species of the genus Erwinia, such as, for example, Erwinia amylovora;

The following diseases of soybeans can be preferably controlled: fungal diseases of leaves, stems, pods and seeds, which cause, for example, leaf spots caused by Alternaria species (Alternaria spec, atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. truncatum), brown spots (Septoria glycines), leaf spots and leaf wilt caused by Cercospora kikuchii, leaf wilt caused by Choanephora infundibulifera trispora (syn.), leaf spots caused by c. Dactuliophora glycines, downy mildew caused by Peronospora manshurica, wilt caused by Drechslera glycini, banded leaf spots caused by Cercospora sojina, leaf spots caused by Cercospora sojina Leptosphaerulina trifolii, leaf spots caused by Phyllosticta sojaecola, pod and stem wilting caused by Phomopsis sojae, powdery mildew caused by Microsphaera diffusa, leaf spots, caused by species of the genus Pyrenochaeta glycines, wilting of aerial parts, foliage and plant tissues caused by species of the genus Rhizoctonia solani, rust, smut caused by species of the genus Phakopsora pachyrhizi, Phakopsora meibomiae, crust-like spots caused by species of the genus Sphaceloma (Sphaceloma glycines), leaf wilt caused by Stemphylium botryosum, pinpoint spots caused by Corynespora cassiicola.

Fungal diseases on roots and stems that cause, for example, black rot of roots caused by the species of the genus Calonectria crotalariae, charcoal rot caused by the species of the genus Macrophomina phaseolina, wilting or drooping, rot of roots and crowns and pods caused by the species Fusarium genus (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), root rot caused by species of the genus Mycoleptodiscus terrestris, Neocosmospora vasinfecta, wilting of the crown and stems caused by species of the genus Diaporte (Diaporthe phaseolo rum), stem canker , caused by the type of genus the dispended (DiaPorthe Phaseolorum Var. Caulivora), rotting caused by the type of phytophthore (Phytophthora Megasperma), brown decay of stems (Phialophora Gregata), rotting caused Anidermatum, Pythium Irregulare, Pythium Debaryanum, Pythium Myriotylum , Pythium ultimum), root rot, stem destruction and mildew caused by Rhizoctonia solani, stem destruction caused by Sclerotinia sclerotiorum, southern wilt caused by Sclerotinia rolfsii, root rot , caused by a species of the genus Thielaviopsis (Thielaviopsis basicola).

Microorganisms that can cause destruction or alteration of technical materials include, for example, bacteria, fungi, yeast, algae and mucus organisms. The biologically active substances according to the invention act predominantly on fungi, especially molds, staining and wood-destroying fungi (basidiomycetes), as well as slime organisms and algae. Mention should be made, for example, of microorganisms of the following genera: Alternaria, such species as Alternaria tenuis; aspergillus (Aspergillus), such species as Aspergillus niger; chaetomium, such species as Chaetomium globosum; coniophora (Coniophora), such species as Coniophora puetana; Lentinus, such species as Lentinus tigrinus; penicillium, such species as Penicillium glaucum; polyporus, such species as Polyporus versicolor; aureobasidium, such species as Aureobasidium pullulans; sclerophoma, such species as Sclerophoma pityophila; trichoderma (Trichoderma), such species as Trichoderma viride; Escherichia, such species as Escherichia coli; pseudomonas (Pseudomonas), such species as Pseudomonas aeruginosa; staphylococcus (Staphylococcus), such species as Staphylococcus aureus.

In addition, the biologically active substances according to this invention exhibit a very good antimycotic effect. They have a very broad antimycotic spectrum, in particular against dermatophytes and shoot fungi, molds and diphasic fungi (for example, against Candida species such as Candida albicans, Candida glabrata), as well as Epidermophyton floccosum, Aspergillus species such such as Aspergillus niger and Aspergillus fumigatus, Trichophyton species such as Trichophyton mentagrophytes, Microsporon species such as Microsporon canis and audouinii. The listing of these fungi is in no way a limitation of the mycotic spectrum covered, but is only explanatory.

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Biologically active substances in this regard can be used for both medical and non-medical applications.

The compounds according to the invention can be used, if necessary in certain concentrations or application amounts, as herbicides, protectants, plant growth regulators or plant enhancers, or as microbicides, for example as fungicides, antimycotics, bactericides, viricides ( including anti-viroid agents) or anti-MLO (mycoplasma-like organisms) and RLO (Rickettsia-like organisms) agents. If necessary, they can be used as intermediates and precursors for the synthesis of other biologically active substances.

A. Chemical examples.

NMR data of published examples are presented either in classical form (δ-values, multiplicity, number of H atoms) or in the form of so-called NMR peak lists. NMR peak list methods list the NMR data of selected examples as lists of NMR peaks, with each signal peak first given a δ-value in parts per thousand (ppm) and then signal intensity separately, separated by a space character. The 5-magnitude-signal-intensity data pair of the different signal peaks is separated from each other by a semicolon.

Therefore, the list of example peaks has the form δ1 (intensity); δ ₂ (intensity);........; _δi (intensity);......; _δπ (intensity)

The intensity of the clear signals is in correlation with the height of the signals in the printed example of the NMR spectrum in cm and shows the actual signal intensity relationship. Broad signals may show multiple peaks or the middle of the signal and its relative intensity compared to the most intense signal in the spectrum.

To calibrate the chemical shift of ¹ H-NMR spectra, we used tetramethylsilane and/or solvent chemical shift, especially for spectra measured in DMSO. Therefore, tetramethylsilane may appear at the peak of the NMR lists, but this is not necessary.

^1H -NMR peak lists are similar to classic printed 1H-NMR lists and usually contain all the peaks that are mentioned in the classic NMR interpretations.

In addition, they can, like classic printed ¹ H-NMR lists, show solvent signals, stereoisomers of the desired compounds, which are also the subject of the invention, and/or impurity peaks.

In the signal data of compounds in the delta region of solvents and/or water, our ¹ H-NMR peaks show common solvent peaks, such as the DMSO peaks in DMSO-O6 and the water peak, which generally show high intensity on average.

Stereoisomer peaks of target compounds and/or impurity peaks typically have lower intensities than peaks of the desired compounds (eg, >90% purity).

Such stereoisomers and/or impurities may be typical of the respective production processes. Thus, their peaks can help in recognizing the reproduction of our method of obtaining by-product fingerprints.

An expert who estimates the peaks of the required compounds using known methods (MestreC, ACD modeling, or using empirically derived, analyzed expected values) can isolate the peaks of the required compounds as necessary, with an additional intensity filter applied if necessary. Such isolation would be similar to the aforementioned peak mapping in the classical interpretation of ¹ H-NMR.

Other details of ¹ H-NMR peak lists can be taken from the theoretical research base Research Disclosure Database No. 564025.

The following examples explain the invention in more detail.

Intermediate connection 1.

Preparation of 3,5-difluoro-N-hydroxybenzenecarboximidoyl chloride Similar to the prescription in WO2012/130798 for 3,5-dichloro-N-hydroxybenzenecarboximidoyl chloride, 3,5-difluoro-Nhydroxybenzenecarboximidoyl chloride was prepared from 3,5-difluorobenzaldehyde in two steps.

Intermediate 2.

Preparation of 3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-methyl ester of carboxylic acid.

Similar to the prescription in WO2012/130798 for 3-(3,5-dichlorophenyl)-5-methyl-4H-isoxazole-5methyl carboxylic acid ester, 3-(3,5-Dichlorophenyl)-5-methyl-4H-isoxazole-5- carboxylic acid methyl ester was prepared from 3,5-difluorobenzaldehyde in three steps.

Intermediate 3.

Preparation of 3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carboxylic acid.

Similar to the prescription in WO2012/130798 for 3-(3,5-dichlorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid, 3-(3,5-dichlorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid prepared from 3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-methyl carboxylic acid ester.

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Intermediate 4.

Preparation of 3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid chloride.

By analogy with the prescription in WO 2012/130798 for N-tert-butyl-3-(3,5-dichlorophenyl)-5-methyl-4,5dihydro-1,2-oxazol-5-carboxamide, 3-(3,5- Difluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid chloride was prepared from 3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid by reaction with oxalyl chloride and used as the starting material without additional cleaning.

Intermediate 5.

Preparation of 3-(3,5-difluorophenyl)-5-(1-hydroxyethyl)-4H-isoxazole-5-methyl ester of carboxylic acid.

19.9 g (104 mmol) 3,5-difluoro-N-hydroxybenzimidol chloride (s. intermediate 1) was dissolved in 330 ml 2-propanol and mixed with 15.0 g (104 mmol) 3-hydroxy-2methylenebutanoic acid methyl ester . After adding 43.8 g (522 mmol) of sodium hydrogen carbonate, the suspension was heated to 50°C and the temperature was maintained for 2 hours until complete conversion of the starting material. The suspension was filtered and the filtrate was concentrated in vacuo. The resulting residue was taken up in dichloromethane, then washed with a saturated sodium chloride solution, the organic phases were dried over sodium sulfate and, after filtration, evaporated in vacuo. The crude product thus obtained was taken up in toluene and crystallized by the addition of n-heptane. Thus, 25.5 g (86%) of 3-(3,5-difluorophenyl)-5-(1-hydroxyethyl)-4H-isoxazole-5-carboxylic acid methyl ester were obtained in the form of colorless crystals.

Diastereoisomer 1:

1H NMR (CDCl3): δ 1.20 (d, 3H), 2.36 (d, 1H), 3.52 (d, 1H), 3.72 (d, 1H), 3.83 (s, 3H ), 4.34 (m, 1H), 6.88 (m, 1H), 7.20 (m, 2H).

Diastereoisomer 2:

1H NMR (CDCl3): δ 1.29 (d, 3H), 2.12 (d, 1H), 3.58 (d, 1H), 3.68 (d, 1H), 3.83 (s, 3H), 4.23 (m, 1H), 6.88 (m, 1H), 7.20 (m, 2H).

Intermediate 6.

Preparation of 3-(3,5-difluorophenyl)-5-[1-(trifluoromethylsulfonyloxy)ethyl]-4H-isoxazole-5-meth ester of carboxylic acid.

29.9 (105 mmol) 3-(3,5-difluorophenyl)-5-(1-hydroxyethyl)-4H-isoxazole-5-methyl carboxylic acid ester in 660 ml of dichloromethane was cooled to 0°C and mixed with 16.3 g (210 mmol) pyridine. A solution of 38.6 g (137 mmol) of trifluoromethanesulfonic acid anhydride was then slowly added and cooled to 80 ml of dichloromethane. After 30 minutes at 0°C, it was mixed with 300 ml of dichloromethane and the organic phase was washed three times with 200 ml of a solution of saturated sodium chloride and 1 N hydrochloric acid (3:1). The organic phase was then washed twice with saturated sodium chloride solution, dried with sodium sulfate and the solvent was removed in vacuo. The starting product thus obtained was used without further purification in the next step.

Diastereoisomer 1:

1H NMR (CDCl3): δ 1.54 (d, 3H), 3.44 (d, 1H), 3.89 (s, 3H), 3.94 (d, 1H), 5.49 (q, 1H ), 6.91 (m, 1H), 7.20 (m, 2H).

Diastereoisomer 2:

1H NMR (CDCl3): δ 1.59 (d, 3H), 3.53 (d, 1H), 3.89 (s, 3H), 3.90 (d, 1H), 5.57 (q, 1H ), 6.91 (m, 1H), 7.20 (m, 2H).

Intermediate 7.

Preparation of 3-(3,5-difluorophenyl)-5-vmnyl-4H-isoxazole-5-carboxylic acid methyl ester.

43.0 g (103 mmol) of the crude product of the last step (3-(3,5-difluorophenyl)-5-[1(trifluoromethylsulfonyloxy)ethyl]-4H-isoxazole-5-carboxylic acid methyl ester) was dissolved in 500 ml of dimethylacetamide and mixed dropwise over 20 minutes with a solution of 18.8 g (124 mmol) DBU in 50 ml dimethylacetamide. The reaction mixture was stirred for 2 hours at room temperature, then ice-cold 2 N hydrochloric acid was added to 1 liter and extracted twice with 500 ml of diethyl ether. The combined organic phases were dried over sodium sulfate, filtered and evaporated in vacuo. After purification by chromatography on silica gel using dichloromethane as a solvent, the starting product was crystallized from cyclohexane. 23.4 g (85%) of colorless crystals were thus obtained.

1H NMR (CDCl3): δ 3.34 (d, 1H), 3.84 (s, 3H), 3.93 (d, 1H), 5.38 (d, 1H), 5.55 (d, 1H ), 6.14 (dd, 1H), 6.88 (m, 1H), 7.19 (m, 2H).

Intermediate 8.

Preparation of 3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carboxylic acid.

7.5 g of 3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carboxylic acid methyl ester (28.0 mmol) was mixed with 21 ml of 2 N sodium hydroxide solution and heated for 8 hours under reflux. After cooling, the reaction mixture was washed with ethyl acetate, the aqueous phase was acidified with 2 N hydrochloric acid to pH 1, the colorless precipitate was filtered off and air dried. The output was

- 59 044070

6.8 g (96%).

^1H NMR (CDC13): δ 3.40 (d, 1H), 3.92 (d, 1H), 5.00 (dd, 1H), 5.45 (d, 1H), 5.63 (d, 1H), 6.16 (dd, 1H), 6.87-6.93 (m, 1H), 7.16-7.21 (m, 2H).

Intermediate 9.

Preparation of 3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carboxylic acid chloride.

2.70 g (10.6 mmol) of 3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carboxylic acid was added to 45 ml of dichloromethane, then three drops of dimethylformamide (DMF) were added and then 2.03 g (15.9 mmol) oxalyl chloride. A sharp transformation of the gas was observed. The mixture was stirred for 6 hours at room temperature, and then the solvent and excess oxallyl chloride were evaporated in vacuo. The starting product thus obtained was used without further purification in the next step.

Intermediate connection 10.

Preparation of 3-fluoro-K-hydroxybenzenecarboximidoyl chloride.

Similar to the prescription in WO 2012/130798 for 3,5-dichloro-N-hydroxybenzenecarboxymidoyl chloride, 3,5-difluoro-N-hydroxybenzenecarboxymidoyl chloride was prepared from 3-fluorobenzaldehyde in two steps.

Intermediate 11.

Preparation of 3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-methyl ester of carboxylic acid.

Similar to the prescription in WO 2012/130798 for 3-(3,5-dichlorophenyl)-5-methyl-4H-isoxazole-5methyl carboxylic acid ester, 3-(3,5-dichlorophenyl)-5-methyl-4H-isoxazole-5 -Carboxylic acid methyl ester was prepared from 3-fluorobenzaldehyde in three steps.

Intermediate connection 12.

Preparation of 3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid.

Similar to the prescription in WO 2012/130798 for 3-(3,5-dichlorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid, 3-(3,5-dichlorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid the acid was obtained from 3-(3,5-fluorophenyl)-5-methyl-4H-isoxazole-5-methyl ester of carboxylic acid.

Intermediate 13.

Preparation of (1R,4S)-4-aminocyclopent-2-ene-1-carboxylic acid methyl ester hydrochloride.

(1R,4S)-4-aminocyclopent-2-ene-1-carboxylic acid methyl ester hydrochloride can be prepared from the commercially available vince-lactam (1S,4R)-2-azabiclo[2.2.1]hept-5-ene- 3-one, by a method similar to that described in Marco D. Migliore et al., J. Med. Chem., 2007, 50, 6485-6492.

Intermediate 14.

Preparation of (1S,4R)-4-aminocyclopent-2-ene-1-methyl carboxylic acid methyl ester hydrochloride.

(1S,4R)-4-aminocyclopent-2-ene-1-carboxylic acid methyl ester hydrochloride can be prepared from the commercially available vince-lactam (1R,4S)-2-azabiclo[2.2.1]hept-5-ene- 3-ona by a method similar to that described in Marco D. Migliore et al., J. Med. Chem., 2007, 50, 6485-6492.

Intermediate 15.

Preparation of (4R)-4-aminocyclopent-1-ene-1-carboxylic acid methyl ester hydrochloride.

(4R)-4-Aminocyclopent-1-ene-1-carboxylic acid methyl ester hydrochloride can be prepared by a method similar to that provided for intermediate 13 in M.E.B. Smith et al., Tetrahedron Letters, 42 (2001), 1347-1350.

Intermediate 16.

Preparation of (4S)-4-aminocyclopent-1-ene-1-carboxylic acid methyl ester hydrochloride.

(4S)-4-Aminocyclopent-1-ene-1-carboxylic acid methyl ester hydrochloride can be prepared by a method similar to that provided for intermediate 14 in M.E.B. Smith et al., Tetrahedron Letters, 42 (2001), 1347-1350.

Example I-003.

Preparation of (1R,4S)-4-[[[3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent2-ene-1-methyl ester of carboxylic acid .

200 mg (0.90 mmol) 3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid along with 154 mg (0.99 mmol) 86% 1-hydroxybenzotriazole (HOBt) in 10 ml dichloromethane stirred for 30 minutes at room temperature. Then, one by one, 175 mg (0.99 mmol) (1R,4S)-4-aminocyclopent-2-ene1-carboxylic acid methyl ester hydrochloride, 343 mg (1.79 mmol) 1-(3-dimethylaminopropyl)3-hydrochloride ethylcarbodiimide (EDAC) and 347 mg (2.69 mmol) K,K-diisopropylethylamine (DIPEA, Huenig's base) were mixed and stirred for 16 hours at room temperature.

The reaction mixture was then washed with 0.5 mmol hydrochloric acid, the organic phase was separated, dried over sodium sulfate and evaporated in vacuo. The evaporated residue was purified by chromatography on silica gel (eluent: ethyl acetate/n-heptane). 290 mg (91%) of the title compound were obtained in this manner.

Example I-001.

Preparation of (1R,S)-4-[[[3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2ene-1-carboxylic acid.

- 60 044070

270 mg (0.78 mmol) (1R,4S)-4-[[[3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5yl]carbonyl]amino]cyclopent-2-ene -1-methyl ester of carboxylic acid was dissolved in 4 ml of tetrahydrofuran and cooled to 0°C. To this solution, 156 mg (3.90 mmol) of sodium hydroxide solution in 4 ml of water was added dropwise and then allowed to warm to room temperature. After 1 h, the mixture was diluted with water and oxidized in 2 mmol of hydrochloric acid.

It was extracted with ethyl acetate and hydrochloric acid, the organic phase was separated, dried over sodium sulfate and evaporated in vacuum. The evaporated residue was purified by chromatography on silica gel (eluent: ethyl acetate/n-heptane). 190 mg (72%) of the title compound were obtained in this manner.

Example II-01.

Preparation of 3-(3-fluorophenyl)-N-[(1S,4R)-4-[(methoxyamino)carbonyl]-cyclopent-2-en-1-yl]-5-methyl4H-1,2-oxazol-5- carboxamide.

mg (0.09 mmol) (1R,4S)-4-[[[3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5yl]carbonyl]amino]cyclopent-2-ene- 1-Carboxylic acid along with 16 mg (0.10 mmol) 86% 1-hydroxybenzotriazole (HOBt) in 2 ml dichloromethane were taken and stirred for 20 minutes at room temperature. Then, one after the other, 9 mg (0.11 mmol) methoxylamine hydrochloride, 36 mg (0.19 mmol) 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride (EDAC) and 37 mg (0.28 mmol) K,K α-diisopropylethylamine (DIPEA, Huenig's base) was mixed and stirred for 16 hours at room temperature.

The reaction mixture was then washed with 0.5 mmol hydrochloric acid, the organic phase was separated, dried over sodium sulfate and evaporated in vacuo. The evaporated residue was purified by chromatography on silica gel (eluent: ethyl acetate/n-heptane). 26 mg (72%) of the title compound were obtained in this manner.

Example 1H-03.

Preparation of (4R)-4-[[[(5SR)-3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-ul]carbonyl]amino]cyclopentene 1-methyl ester of carboxylic acid.

501 mg (2.25 mmol) 3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carboxylic acid and 439 mg (2.47 mmol) (4R)-4-aminocyclopent-1-ene-1-methyl the carboxylic acid ester was dissolved in 20 ml of dichloromethane, 4.29 g (6.74 mmol) of a 50% solution of propylphosphoric acid anhydride (T3P) was added and stirred for 4 hours at room temperature.

The reaction mixture was then washed with saturated sodium hydride solution, the organic phase was separated, dried over sodium sulfate and evaporated in vacuo. The evaporated residue was purified by chromatography on silica gel (eluent: ethyl acetate/n-heptane). 720 mg (90%) of the title compound were obtained in this manner.

Example 1H-01.

Preparation of (4R)-4-[[[(5SR)-3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5-ul]carbonyl]amino]cyclopentene1-carboxylic acid.

620 mg (1.79 mmol) (1R,4S)-4-[[[3-(3-fluorophenyl)-5-methyl-4H-1,2-oxazol-5yl]carbonyl]amino]cyclopent-2-ene-1 -Carboxylic acid methyl ester was dissolved in 6 ml of tetrahydrofuran and cooled to 0°C. To this solution was added dropwise 129 mg (5.37 mmol) of a solution of lithium hydroxide in 6 ml of water, and then waited until it warmed to room temperature. After 30 min, due to the low solubility of the starting materials, another 1 ml of tetrahydrofuran and 1 ml of water were added. After a total of 4 h, the mixture was diluted with water and oxidized in 2 mmol hydrochloric acid. It was then extracted with ethyl acetate, the organic phase was separated, dried over sodium sulfate and evaporated in vacuo. The evaporated residue was used in its crude form. 610 mg (100%) of the title compound were obtained in this manner.

Example IV-03.

(5 SR)-3-(3-fluorophenyl)-K-[( 1 R)-3-[(methoxyamino)carbonyl]cyclopent-3-en-1 -yl]-5-methyl-4H-1,2oxazol- 5-carboxamide.

121 mg (0.36 mmol) (4R)-4-[[[(5SR)-3-(3-phorophenyl)-5-methyl-4H-1,2-oxazol-5yl]carbonyl]amino]cyclopentene-1 -carboxylic acid and 36 mg (0.44 mmol) of metaxylamine hydrochloride, 36 mg (0.19 mmol) were dissolved in 5 ml of dichloromethane and with 347 mg (0.55 mmol) of a 50% solution, 347 g (0. 55 mmol) of a 50% solution of propylphosphoric acid anhydride (T3P), and 92 mg (0.91 mmol) of triethylamine were added and stirred for 2 hours at room temperature.

The reaction mixture was then washed with saturated sodium hydride solution, the organic phase was separated, dried over sodium sulfate and evaporated in vacuo. The evaporated residue was purified by chromatography on silica gel (eluent: ethyl acetate/n-heptane). 86 mg (65%) of the title compound were obtained in this manner.

- 61 044070

Analytical data of examples I-001-I-201 (see table 1.1)

1-001: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5180 (3.0); 7.4067 (1.1); 7.3989 (1.3); 7.3884 (2.5); 7.3814 (1.4); 7.3766 (3.4); 7.3745 (4.5); 7.3712 (5.4); 7.3647 (3.0); 7.3622 (3.9); 7.2894 (0.6); 7.2591 (545.2); 7.2347 (0.6); 7.2301 (0.7); 7.2245 (1.0);

7.2213 (0.9); 7.1975 (0.7); 7.1489 (0.7); 7.1426 (1.1); 7.1386 (0.7); 7.1322 (0.8); 7.1254 (1.1); 7.1207 (1.1); 7.1164 (1.2); 7.1086 (0.7); 7.1045 (0.6); 7.0983 (0.5); 6.9951 (3.1); 6.0127 (0.7); 6.0086 (0.8);

5.9989 (1.0); 5.9927 (1.5); 5.9886 (1.5); 5.9822 (0.7); 5.9788 (0.7); 5.9724 (0.8); 5.9681 (0.7); 5.9171 (0.9); 5.9115 (1.7); 5.9057 (1.0); 5.8976 (1.4); 5.8920 (0.7); 5.8426 (0.8); 5.8368 (1.4); 5.8310 (0.8);

5.8229 (1.1); 5.8173 (0.6); 4.9851 (0.8); 4.1309 (0.9); 4.1131 (1.0); 3.8227 (2.4); 3.8161 (2.9); 3.7795 (2.8); 3.7729 (3.2); 3.5983 (0.7); 3.5919 (0.8); 3.5877 (0.8); 3.5769 (0.9); 3.2322 (3.0); 3.2267 (2.5);

3.1890 (2.6); 3.1834 (2.2); 2.6391 (0.6); 2.6176 (0.9); 2.6039 (0.7); 2.5963 (0.6); 2.5820 (1.6); 2.5603 (1.6); 2.5464 (0.8); 2.5387 (0.7); 2.5249 (1.3); 2.5035 (0.7); 2.0438 (4.6); 2.0280 (0.6); 2.0171 (1.0);

2.0060 (0.6); 1.9929 (0.5); 1.9820 (0.9); 1.9484 (0.6); 1.9377 (1.1); 1.9269 (0.6); 1.9133 (0.6); 1.9022 (1.0); 1.8917 (0.6); 1.7209 (14.2); 1.7131 (16.0); 1.2766 (1.4); 1.2587 (3.3); 1.2408 (1.5); 0.1460 (0.6);

0.0080 (6.5); -0.0002 (211.6); -0.0085 (5.9); -0.1496 (0.7)

1-002: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5180 (4.8); 7.4076 (1.1); 7.3987 (1.5); 7.3891 (2.5); 7.3779 (3.4); 7.3754 (4.9); 7.3724 (5.5); 7.3631 (4.0); 7.3096 (1.4); 7.3015 (0.6); 7.2968 (0.9); 7.2919 (1.3); 7.2887 (1.7); 7.2848 (1.4); 7.2840 (1.6);

7.2833 (1.6); 7.2816 (1.8); 7.2808 (1.9); 7.2801 (1.9); 7.2792 (1.9); 7.2784 (2.0); 7.2777 (2.3); 7.2768 (2.4); 7.2760 (2.7); 7.2752 (3.0); 7.2745 (3.2); 7.2737 (3.3); 7.2729 (3.7); 7.2721 (3.9); 7.2713 (4.1);

7.2705 (4.8); 7.2697 (5.3); 7.2689 (5.7); 7.2681 (6.6); 7.2673 (7.6); 7.2665 (9.0); 7.2657 (10.5); 7.2648 (12.9); 7.2591 (844.5); 7.2536 (10.4); 7.2528 (8.3); 7.2520 (6.2); 7.2511 (4.7); 7.2503 (4.0); 7.2495 (3.7);

7.2487 (3.2); 7.2479 (2.9); 7.2471 (2.8); 7.2463 (2.4); 7.2455 (2.1); 7.2447 (2.1); 7.2439 (1.9); 7.2431 (1.7); 7.2423 (1.6); 7.2415 (1.5); 7.2407 (1.5); 7.2399 (1.4); 7.2383 (1.3); 7.2375 (1.1); 7.2359 (1.1);

7.2320 (1.0); 7.2274 (1.3); 7.2256 (1.2); 7.2185 (1.0); 7.1971 (1.1); 7.1503 (0.9); 7.1440 (1.2); 7.1386 (0.8); 7.1332 (0.9); 7.1267 (1.3); 7.1204 (1.2); 7.1173 (1.2); 7.1099 (0.7); 7.0997 (0.6); 6.9951 (4.8);

6.0126 (0.8); 6.0061 (0.8); 5.9983 (1.0); 5.9926 (1.6); 5.9884 (1.6); 5.9823 (0.8); 5.9790 (0.9); 5.9750 (0.9); 5.9688 (0.8); 5.9164 (0.9); 5.9107 (1.7); 5.9051 (1.0); 5.8969 (1.4); 5.8913 (0.8); 5.8427 (0.9);

5.8371 (1.5); 5.8314 (0.9); 5.8232 (1.2); 5.8175 (0.7); 4.9869 (0.9); 4.1309 (0.8); 4.1130 (0.9); 3.8225

- 62 044070 (2.6); 3.8159 (2.8); 3.7793 (3.1); 3.7727 (3.2); 3.5886 (0.9); 3.2321 (3.0); 3.2268 (2.7); 3.1889 (2.6); 3.1835 (2.4); 2.6406 (0.6); 2.6190 (1.0); 2.6052 (0.8); 2.5977 (0.6); 2.5839 (1.6); 2.5625 (1.7); 2.5487 (0.8); 2.5414 (0.7); 2.5274 (1.3); 2.5062 (0.5); 2.0438 (4.3); 2.0173 (1.1); 2.0068 (0.6); 1.9927 (0.5);

1.9821 (0.9); 1.9507 (0.7); 1.9398 (1.1); 1.9295 (0.6); 1.9153 (0.7); 1.9049 (1.0); 1.8941 (0.7); 1.7212 (15.6); 1.7132 (16.0); 1.2766 (1.5); 1.2588 (3.2); 1.2409 (1.3); 0.1460 (1.0); 0.0240 (0.6); 0.0208 (0.7);

0.0160 (1.0); 0.0136 (1.3); 0.0128 (1.4); 0.0112 (1.8); 0.0080 (10.4); 0.0065 (4.3); 0.0056 (4.7); 0.0048 (5.7); -0.0002 (325.4); -0.0058 (4.9); -0.0066 (4.2); -0.0085 (9.4); -0.1494 (0.9)

1-003: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3828 (0.6); 7.3781 (1.0); 7.3739 (0.7); 7.3703 (0.6); 7.2620 (75.2); 3.8274 (0.5); 3.8222 (0.5);

3.7842 (0.6); 3.7790 (0.6); 3.7554 (4.0); 3.7254 (4.0); 3.2336 (0.6); 3.2264 (0.6); 1.7269 (2.8); 1.7154 (2.8); 1.5533 (16.0); 0.0080 (0.8); -0.0002 (27.2); -0.0085 (0.8)

1-004: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5210 (0.7); 7.3897 (0.8); 7.3867 (0.7); 7.3828 (1.4); 7.3781 (2.2); 7.3739 (1.5); 7.3704 (1.2); 7.3651 (0.8); 7.2621 (120.2); 7.1298 (0.5); 6.9980 (0.7); 5.9476 (0.6); 5.8954 (0.7); 5.8061 (0.6); 5.7923 (0.5);

3.8275 (1.1); 3.8223 (1.1); 3.7843 (1.2); 3.7791 (1.2); 3.7555 (8.4); 3.7254 (8.3); 3.2337 (1.1); 3.2265 (1.1); 3.1905 (1.0); 3.1833 (1.0); 1.7270 (5.9); 1.7154 (5.9); 1.5550 (16.0); 0.0080 (1.4); -0.0002 (43.8); 0.0085 (1.2)

1-007: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5190 (1.4); 7.2762 (0.5); 7.2754 (0.5); 7.2746 (0.6); 7.2738 (0.7); 7.2730 (0.7); 7.2722 (0.8); 7.2714 (0.9); 7.2706 (1.0); 7.2698 (1.1); 7.2690 (1.2); 7.2682 (1.4); 7.2674 (1.6); 7.2666 (1.9); 7.2658 (2.4);

7.2650 (3.0); 7.2600 (235.0); 7.2505 (0.9); 7.2489 (0.5); 7.1761 (1.8); 7.1702 (2.6); 7.1665 (3.4); 7.1635 (2.4); 7.1607 (3.4); 7.1562 (3.2); 7.1503 (3.4); 7.1466 (3.3); 7.1408 (2.0); 7.1340 (0.5); 7.0784 (0.6);

6.9960 (1.4); 6.8947 (0.8); 6.8889 (1.6); 6.8835 (1.3); 6.8729 (1.6); 6.8671 (2.7); 6.8614 (1.5); 6.8512 (0.8); 6.8453 (1.3); 6.8395 (0.6); 5.9532 (0.9); 5.9497 (1.1); 5.9470 (1.0); 5.9433 (1.0); 5.9394 (1.1);

5.9336 (1.6); 5.9298 (1.5); 5.9239 (0.7); 5.9203 (0.7); 5.9163 (0.8); 5.9140 (0.8); 5.9101 (0.7); 5.8572 (0.8); 5.8517 (1.6); 5.8461 (0.9); 5.8434 (0.7); 5.8379 (1.3); 5.8324 (0.8); 5.7706 (0.7); 5.7650 (1.5);

5.7591 (1.2); 5.7512 (1.3); 5.7453 (0.9); 4.9764 (0.8); 3.8038 (0.7); 3.7963 (2.5); 3.7910 (3.1); 3.7606 (0.8); 3.7532 (2.8); 3.7479 (3.4); 3.4111 (0.8); 3.4052 (0.6); 3.2003 (0.7); 3.1962 (1.4); 3.1919 (2.9);

3.1815 (2.3); 3.1571 (0.6); 3.1529 (1.2); 3.1488 (2.5); 3.1383 (2.0); 2.5279 (0.5); 2.5068 (0.9); 2.4931 (0.7); 2.4857 (0.6); 2.4775 (0.7); 2.4720 (1.1); 2.4564 (1.2); 2.4510 (0.7); 2.4427 (0.8); 2.4352 (0.7);

2.4216 (1.2); 2.4005 (0.7); 1.9201 (0.9); 1.9099 (1.1); 1.8997 (0.6); 1.8749 (0.9); 1.8646 (0.6); 1.8285 (0.8); 1.8179 (1.2); 1.8073 (0.8); 1.7937 (0.6); 1.7833 (1.0); 1.7725 (1.2); 1.7222 (13.4); 1.7164 (9.2);

1.7075 (16.0); 1.6794 (0.5); 1.5434 (18.6); 1.4979 (10.3); 1.4791 (57.7); 1.4415 (67.5); 1.4258 (16.5);

1.3684 (0.5); 1.2550 (0.5); 0.0080 (2.4); -0.0002 (90.6); -0.0085 (2.9)

1-008: ¹ H-NMR(400.0 MHz, CDC13):

- 63 044070 δ= 7.5181 (9.4); 7.4220 (2.7); 7.4089 (3.0); 7.4038 (3.3); 7.3792 (4.4); 7.3709 (14.2); 7.3659 (7.5); 7.3595 (10.2); 7.3555 (11.8); 7.3504 (13.7); 7.3462 (11.5); 7.3399 (11.6); 7.3271 (5.6); 7.3096 (2.2); 7.3072 (2.0); 7.3017 (1.6); 7.2961 (1.6); 7.2929 (1.6); 7.2912 (2.0); 7.2889 (2.1); 7.2881 (2.2); 7.2858 (2.5); 7.2850 (2.4); 7.2841 (2.5); 7.2834 (3.0); 7.2826 (2.6); 7.2818 (2.7); 7.2810 (3.1); 7.2802 (3.2);

7.2794 (3.0); 7.2786 (3.2); 7.2778 (3.5); 7.2770 (3.5); 7.2762 (4.0); 7.2754 (4.6); 7.2746 (4.8); 7.2738 (5.3); 7.2730 (5.4); 7.2722 (5.8); 7.2714 (6.5); 7.2706 (7.2); 7.2698 (8.4); 7.2690 (9.6); 7.2682 (10.3);

7.2675 (11.1); 7.2666 (12.7); 7.2658 (15.0); 7.2650 (18.2); 7.2642 (22.7); 7.2634 (29.4); 7.2626 (39.5);

7.2592 (1761.4); 7.2545 (19.6); 7.2536 (14.7); 7.2528 (11.4); 7.2520 (8.5); 7.2512 (6.5); 7.2504 (4.1); 7.2496 (2.8); 7.2488 (1.6); 7.2480 (1.9); 7.2472 (1.9); 7.2464 (1.7); 7.2456 (1.5); 7.2448 (1.4); 7.2095 (3.9); 7.1697 (3.0); 7.1641 (4.2); 7.1594 (5.0); 7.1468 (3.0); 7.1442 (3.4); 7.1380 (2.2); 6.9952 (10.2);

6.8705 (2.0); 6.0318 (1.3); 6.0221 (1.5); 6.0162 (1.6); 5.9762 (1.6); 5.8918 (1.5); 5.8578 (1.6); 5.8517 (2.2); 5.8379 (1.9); 5.8056 (1.3); 5.3058 (6.0); 5.2971 (11.0); 5.1835 (7.1); 5.1518 (4.5); 5.1302 (11.9);

5.1154 (3.9); 3.8959 (1.2); 3.7963 (4.1); 3.7749 (1.8); 3.7530 (3.8); 3.7486 (3.1); 3.7222 (2.4); 3.6983 (1.2); 3.1943 (3.1); 3.1820 (2.1); 3.1508 (3.1); 3.1387 (1.7); 2.7370 (1.3); 2.7284 (1.2); 2.7161 (1.3);

2.6931 (1.2); 2.0048 (11.1); 1.9740 (1.3); 1.9362 (1.3); 1.7564 (4.0); 1.7124 (14.5); 1.7073 (16.0); 1.5325 (189.8); 1.2551 (1.3); 0.1458 (1.5); 0.0080 (17.1); -0.0002 (649.1); -0.0085 (18.4); -0.0499 (1.5); -0.1496 (1.5)

1-009: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5184 (4.9); 7.3083 (8.8); 7.2595 (719.7); 7.2087 (2.2); 7.1645 (5.2); 7.1503 (4.6); 6.9956 (4.1); 6.8887 (1.9); 5.9882 (2.1); 5.9146 (1.6); 5.8146 (1.7); 4.5239 (2.8); 4.5089 (1.6); 4.4260 (1.8); 4.4124 (2.7); 4.3877 (3.2); 4.3737 (3.9); 4.3582 (3.8); 4.3514 (3.4); 4.3368 (3.5); 4.3213 (1.8); 3.8054 (3.3);

3.7981 (4.3); 3.7878 (3.1); 3.7714 (4.4); 3.7544 (6.5); 3.7368 (3.6); 3.7194 (4.5); 3.7049 (4.5); 3.6825 (4.3); 3.6683 (3.6); 3.6546 (2.0); 3.2021 (2.8); 3.1951 (2.6); 3.1882 (2.3); 3.1595 (2.4); 3.1454 (2.2);

2.0051 (5.6); 1.7278 (13.4); 1.7199 (16.0); 1.7127 (12.2); 1.5323 (123.4); 0.0480 (3.2); -0.0002 (252.3); 0.0085 (10.0)

1-010: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5189 (2.2); 7.3103 (1.2); 7.2785 (0.6); 7.2777 (0.6); 7.2769 (0.6); 7.2762 (0.7); 7.2754 (0.7); 7.2745 (0.8); 7.2737 (0.9); 7.2730 (1.0); 7.2722 (1.1); 7.2714 (1.2); 7.2706 (1.4); 7.2698 (1.4); 7.2690 (1.7);

7.2682 (1.9); 7.2674 (2.1); 7.2666 (2.6); 7.2658 (3.2); 7.2650 (4.0); 7.2641 (5.2); 7.2633 (7.4); 7.2599 (391.8); 7.2512 (1.4); 7.2487 (0.8); 7.2471 (0.6); 7.2100 (1.3); 7.1794 (1.4); 7.1736 (1.9); 7.1709 (3.2);

7.1682 (2.5); 7.1651 (3.5); 7.1626 (3.0); 7.1598 (2.6); 7.1538 (2.9); 7.1512 (3.2); 7.1490 (2.6); 7.1454 (2.8); 7.1330 (0.5); 7.0631 (0.6); 6.9960 (2.4); 6.9098 (0.7); 6.9019 (0.8); 6.8983 (0.9); 6.8880 (1.2);

6.8855 (1.2); 6.8824 (1.4); 6.8800 (1.3); 6.8767 (1.5); 6.8744 (1.5); 6.8607 (0.7); 6.8528 (0.7); 6.7889 (0.6); 6.0675 (1.2); 6.0632 (1.3); 6.0614 (1.3); 6.0570 (1.2); 6.0536 (1.4); 6.0493 (1.5); 6.0474 (1.5);

6.0431 (1.5); 6.0389 (0.6); 6.0323 (0.6); 6.0249 (0.7); 6.0185 (0.8); 5.9937 (0.6); 5.9854 (1.3); 5.9799 (2.4); 5.9755 (1.8); 5.9715 (1.6); 5.9662 (2.2); 5.9619 (2.0); 5.9525 (0.7); 5.9452 (1.3); 5.9398 (1.7);

- 64 044070

5.9327 (1.6); 5.9267 (2.8); 5.9209 (1.7); 5.9188 (1.8); 5.9131 (2.9); 5.9073 (1.5); 5.8994 (0.8); 5.8612 (0.6); 5.8557 (1.3); 5.8474 (1.4); 5.8417 (1.4); 5.8362 (0.6); 5.8334 (0.7); 5.2987 (0.5); 5.1930 (0.5);

5.1877 (0.7); 5.1822 (0.7); 5.1775 (0.8); 5.1721 (0.6); 5.1666 (0.6); 5.1234 (0.7); 5.1026 (0.7); 5.0272 (0.6); 4.6740 (2.3); 4.6718 (1.5); 4.6537 (6.9); 4.6515 (4.3); 4.6335 (7.2); 4.6312 (4.2); 4.6132 (2.5);

4.6108 (1.5); 4.5666 (1.2); 4.5591 (0.8); 4.5553 (0.9); 4.5457 (3.7); 4.5383 (2.1); 4.5345 (2.4); 4.5293 (2.4); 4.5247 (4.1); 4.5174 (2.4); 4.5136 (2.5); 4.5084 (5.9); 4.5061 (3.9); 4.5039 (2.1); 4.5004 (1.2);

4.4946 (2.6); 4.4875 (6.2); 4.4852 (3.9); 4.4795 (2.8); 4.4737 (2.5); 4.4665 (2.2); 4.4585 (2.7); 4.4527 (0.9); 4.4375 (0.9); 3.9071 (0.8); 3.9041 (1.4); 3.9011 (1.1); 3.8951 (1.1); 3.8891 (0.9); 3.8852 (0.8);

3.8792 (1.1); 3.8732 (1.1); 3.8673 (0.9); 3.8393 (0.5); 3.8335 (0.5); 3.8112 (0.5); 3.8045 (1.7); 3.7983 (2.9); 3.7866 (2.1); 3.7612 (1.8); 3.7551 (3.6); 3.7465 (2.8); 3.7435 (2.4); 3.7262 (0.6); 3.7109 (1.1);

3.6630 (0.6); 3.6316 (0.6); 3.2055 (1.8); 3.2004 (2.2); 3.1922 (2.1); 3.1623 (1.6); 3.1572 (1.9); 3.1490 (1.8); 2.7915 (1.1); 2.7795 (1.0); 2.7709 (1.1); 2.7588 (1.1); 2.7560 (1.3); 2.7440 (1.3); 2.7353 (1.2);

2.7233 (1.3); 2.6884 (0.6); 2.6524 (0.6); 2.6301 (0.9); 2.6239 (0.6); 2.6160 (0.7); 2.6088 (0.6); 2.6028 (1.0); 2.5948 (0.9); 2.5879 (0.9); 2.5820 (0.6); 2.5736 (0.6); 2.5667 (1.5); 2.5519 (0.6); 2.5452 (0.7);

2.5309 (0.8); 2.5099 (0.6); 2.0746 (0.5); 2.0668 (0.8); 2.0530 (1.0); 2.0417 (1.1); 2.0311 (1.7); 2.0198 (1.2); 2.0175 (1.0); 2.0051 (2.9); 1.9958 (1.2); 1.9849 (1.5); 1.9745 (0.7); 1.9620 (0.5); 1.9507 (1.1); 1.9401 (0.6); 1.9173 (0.8); 1.9066 (0.8); 1.8823 (0.5); 1.8716 (0.8); 1.8653 (0.5); 1.7560 (0.8); 1.7236 (13.3); 1.7208 (16.0); 1.7129 (12.0); 1.5405 (29.0); 1.2558 (0.9); 0.0502 (0.6); 0.0080 (4.2); -0.0002 (146.2); -0.0085 (3.8)

1-011: ¹ H-NMR(400.6 MHz, CDC13):

δ= 8.7204 (0.6); 7.3504 (5.3); 7.3284 (5.4); 7.2803 (5.6); 7.1949 (1.0); 7.1894 (1.9); 7.1770 (9.8); 7.1716 (12.3); 7.1574 (12.2); 7.1521 (9.6); 7.1398 (1.7); 6.8809 (2.4); 6.8753 (4.2); 6.8697 (2.4); 6.8593 (4.8);

6.8536 (8.0); 6.8480 (4.3); 6.8376 (2.5); 6.8319 (4.0); 6.8264 (2.0); 6.2028 (8.5); 6.1761 (9.4); 6.1598 (10.0); 6.1331 (10.2); 6.0241 (5.3); 6.0202 (4.8); 6.0157 (5.6); 6.0120 (6.5); 5.9206 (4.8); 5.9152 (8.6);

5.9096 (5.9); 5.9015 (7.0); 5.8962 (3.9); 5.5434 (16.0); 5.5004 (14.1); 5.3397 (15.4); 5.3129 (14.5);

5.0674 (2.1); 5.0479 (3.9); 5.0282 (2.1); 3.9584 (12.8); 3.9152 (14.4); 3.7392 (0.5); 3.5761 (3.5); 3.5624 (3.6); 3.3609 (14.8); 3.3178 (12.9); 2.5451 (2.3); 2.5241 (4.6); 2.5100 (3.3); 2.5033 (3.1); 2.4892 (5.0);

2.4684 (2.4); 2.0524 (1.1); 1.9537 (2.7); 1.9442 (4.9); 1.9346 (2.8); 1.9187 (2.6); 1.9093 (4.4); 1.8998 (2.5); 1.2609 (1.7); 1.2580 (2.3); -0.0002 (3.6)

1-012: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2616 (17.7); 7.1908 (1.4); 7.1877 (1.0); 7.1850 (1.5); 7.1819 (0.9); 7.1741 (1.0); 7.1709 (1.6); 7.1652 (1.3); 6.8999 (0.5); 6.8840 (0.6); 6.8781 (1.0); 6.8723 (0.5); 6.8564 (0.5); 6.2027 (1.0); 6.1759 (1.2); 6.1596 (1.2); 6.1328 (1.3); 5.9550 (0.6); 5.9512 (0.7); 5.9488 (0.7); 5.9450 (0.6); 5.8834 (0.6);

5.8779 (1.2); 5.8722 (0.7); 5.8697 (0.5); 5.8640 (0.9); 5.5540 (1.7); 5.5523 (1.8); 5.5109 (1.5); 5.5092 (1.5); 5.3417 (1.5); 5.3402 (1.5); 5.3150 (1.4); 5.3135 (1.4); 3.9357 (1.9); 3.8928 (2.2); 3.7349 (16.0);

- 65 044070

3.3290 (1.8); 3.2860 (1.6); 2.5007 (0.8); 2.4868 (0.6); 2.4797 (0.5); 2.4658 (0.9); 1.9029 (0.8); 1.8680 (0.7); 1.5730 (2.1); -0.0002 (6.6)

1-013: Ή-ΉΜΡ(400.0 MHz, CDC13):

δ= 7.2611 (45.2); 7.2013 (0.6); 7.1954 (0.6); 7.1890 (2.7); 7.1859 (2.2); 7.1833 (3.2); 7.1802 (1.9);

7.1722 (1.8); 7.1691 (3.0); 7.1634 (2.8); 7.1571 (0.7); 7.1511 (0.6); 6.9034 (0.6); 6.8975 (1.0); 6.8917 (0.5); 6.8816 (1.2); 6.8758 (2.0); 6.8700 (1.0); 6.8598 (0.6); 6.8541 (1.0); 6.2005 (2.0); 6.1737 (2.2);

6.1574 (2.4); 6.1306 (2.4); 5.9689 (0.9); 5.9652 (1.0); 5.9627 (1.0); 5.9589 (1.0); 5.9552 (1.2); 5.9514 (1.3); 5.9489 (1.3); 5.9451 (1.2); 5.8777 (1.2); 5.8722 (2.3); 5.8666 (1.3); 5.8640 (1.0); 5.8583 (1.7);

5.8528 (0.9); 5.5505 (3.2); 5.5488 (3.3); 5.5073 (2.9); 5.5057 (2.9); 5.3384 (2.9); 5.3369 (2.9); 5.3117 (2.7); 5.3102 (2.7); 5.0256 (0.7); 5.0219 (0.7); 4.2102 (1.5); 4.1930 (4.7); 4.1925 (4.7); 4.1751 (5.0);

4.1571 (1.7); 3.9377 (3.7); 3.8948 (4.2); 3.5132 (0.5); 3.5095 (0.6); 3.5065 (0.6); 3.5036 (0.6); 3.5005 (0.6); 3.4976 (0.7); 3.4948 (0.7); 3.4919 (0.6); 3.4888 (0.7); 3.4859 (0.6); 3.4824 (0.6); 3.4792 (0.5);

3.3265 (3.6); 3.2835 (3.2); 2.5160 (0.9); 2.4949 (1.6); 2.4810 (1.1); 2.4738 (0.9); 2.4600 (1.8); 2.4389 (0.9); 1.9103 (0.8); 1.9006 (1.5); 1.8909 (0.8); 1.8753 (0.7); 1.8656 (1.3); 1.8559 (0.7); 1.5651 (10.1);

1.2996 (7.7); 1.2817 (16.0); 1.2639 (7.6); 0.0080 (0.5); -0.0002 (16.3)

1-014: Ή-ΉΜΡ(400.0 MHz, CDC13):

δ= 7.2623 (40.5); 7.1967 (0.9); 7.1910 (1.9); 7.1785 (9.6); 7.1728 (11.6); 7.1698 (7.4); 7.1620 (7.4);

7.1588 (11.7); 7.1532 (9.5); 7.1465 (1.8); 7.1407 (1.8); 6.9176 (2.4); 6.9119 (4.1); 6.9061 (2.3); 6.8960 (5.0); 6.8902 (8.2); 6.8844 (4.3); 6.8743 (2.6); 6.8686 (4.1); 6.8628 (2.0); 6.7857 (4.9); 6.7653 (5.0);

6.1919 (8.4); 6.1651 (9.2); 6.1487 (9.8); 6.1220 (10.1); 6.0063 (4.4); 6.0018 (5.5); 6.0004 (5.7); 5.9959 (5.0); 5.9924 (5.8); 5.9879 (6.7); 5.9865 (6.8); 5.9820 (5.5); 5.8774 (5.2); 5.8718 (9.3); 5.8660 (5.9);

5.8637 (5.3); 5.8579 (7.7); 5.8522 (4.2); 5.5474 (13.9); 5.5461 (14.2); 5.5043 (12.3); 5.5029 (12.5);

5.3522 (12.9); 5.3511 (13.1); 5.3255 (12.2); 5.3244 (12.3); 5.3001 (16.0); 5.1360 (1.8); 5.1305 (1.9);

5.1253 (2.4); 5.1204 (3.2); 5.1154 (3.3); 5.1091 (3.4); 5.1045 (3.1); 5.0994 (2.5); 5.0948 (2.0); 5.0890 (1.7); 3.9526 (13.2); 3.9094 (15.0); 3.7771 (2.5); 3.7713 (3.5); 3.7655 (3.8); 3.7596 (3.6); 3.7552 (3.6);

3.7494 (4.0); 3.7435 (3.7); 3.7377 (2.7); 3.6848 (0.5); 3.3362 (13.5); 3.2930 (11.9); 2.6937 (3.2); 2.6820 (3.4); 2.6732 (3.5); 2.6613 (4.1); 2.6586 (4.5); 2.6469 (3.8); 2.6380 (3.5); 2.6263 (3.4); 1.8828 (3.2);

1.8712 (3.4); 1.8607 (3.6); 1.8484 (5.3); 1.8360 (3.4); 1.8255 (3.0); 1.8139 (3.1); 1.2558 (3.5); 0.8806 (0.8); 0.0079 (2.0); -0.0002 (53.2); -0.0085 (2.4)

1-015: Ή-ΉΜΡ(400.0 MHz, CDC13):

δ= 7.5190 (0.6); 7.2602 (103.5); 7.1881 (0.8); 7.1780 (1.6); 7.1724 (1.8); 7.1686 (1.5); 7.1624 (1.6);

7.1588 (1.6); 6.9961 (0.6); 6.8849 (1.0); 6.8794 (0.9); 6.1980 (0.6); 6.1954 (0.6); 6.1686 (0.7); 6.1551 (0.8);

6.1522 (0.8); 6.1282 (0.7); 6.1255 (0.8); 5.9632 (0.7); 5.8718 (0.6); 5.5705 (0.9); 5.5512 (1.6); 5.5260 (0.8);

5.5081 (1.4); 5.3590 (1.0); 5.3453 (0.7); 5.3321 (1.0); 5.3171 (0.6); 4.5456 (0.8); 4.5377 (1.3); 4.5244 (0.8);

4.5200 (1.3); 4.5168 (1.4); 4.5135 (0.8); 4.4991 (1.2); 4.4920 (0.6); 4.1796 (0.6); 4.1666 (0.5); 3.9381 (1.2);

3.9319 (0.8); 3.9015 (0.6); 3.8951 (1.3); 3.8890 (0.9); 3.5844 (0.6); 3.5697 (0.8); 3.3324 (1.5); 3.3273 (1.1);

- 66 044070

3.2893 (1.2); 3.2844 (1.0); 1.8561 (0.8); 1.8484 (1.1); 1.8409 (0.7); 1.8325 (0.7); 1.5453 (16.0); 1.2559 (0.8); 0.9055 (0.5); 0.8898 (0.6); 0.0080 (1.3); -0.0002 (37.3); -0.0085 (1.2)

1-016: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5204 (1.5); 7.3604 (0.7); 7.3426 (0.5); 7.3138 (0.9); 7.3104 (0.6); 7.3018 (0.9); 7.2992 (1.0); 7.2931 (1.2); 7.2898 (1.0); 7.2871 (1.2); 7.2846 (1.3); 7.2829 (1.4); 7.2796 (1.7); 7.2738 (2.4); 7.2723 (2.6);

7.2702 (3.9); 7.2615 (264.6); 7.2538 (3.3); 7.2515 (1.0); 7.2478 (1.0); 7.2456 (1.0); 7.2442 (1.0); 7.2407 (1.1); 7.2389 (0.9); 7.2363 (1.1); 7.2304 (0.8); 7.2262 (1.0); 7.2219 (0.9); 7.2200 (0.8); 7.2114 (2.0);

7.2066 (1.4); 7.1886 (8.0); 7.1828 (11.0); 7.1807 (13.7); 7.1779 (14.1); 7.1749 (16.4); 7.1721 (16.1);

7.1689 (14.0); 7.1632 (14.2); 7.1610 (15.2); 7.1553 (12.4); 7.0943 (2.0); 7.0755 (3.0); 7.0565 (1.9);

6.9974 (1.5); 6.9133 (3.5); 6.9071 (4.1); 6.9031 (4.6); 6.9010 (4.6); 6.8974 (4.9); 6.8950 (5.1); 6.8916 (5.4); 6.8853 (6.3); 6.8813 (7.6); 6.8793 (7.1); 6.8756 (5.2); 6.8735 (4.7); 6.8701 (3.0); 6.8635 (3.2);

6.8596 (3.6); 6.8577 (3.3); 6.8539 (2.0); 6.8382 (1.5); 6.8338 (1.4); 6.8228 (1.5); 6.8182 (1.0); 6.7565 (1.2); 6.7384 (1.2); 6.1991 (7.1); 6.1938 (3.6); 6.1894 (2.3); 6.1829 (2.0); 6.1723 (7.8); 6.1669 (4.3);

6.1626 (2.7); 6.1561 (10.1); 6.1505 (4.4); 6.1462 (2.8); 6.1398 (2.6); 6.1292 (9.3); 6.1235 (5.3); 6.1130 (3.3); 6.1044 (3.9); 6.0942 (2.2); 6.0835 (0.6); 6.0730 (1.4); 6.0624 (1.3); 6.0523 (0.6); 6.0098 (0.9);

5.9945 (3.4); 5.9882 (3.4); 5.9843 (8.6); 5.9772 (8.4); 5.9742 (8.2); 5.9700 (6.8); 5.9669 (11.9); 5.9639 (8.1); 5.9569 (8.9); 5.9538 (5.9); 5.9508 (3.8); 5.9464 (4.5); 5.9406 (3.2); 5.9355 (2.9); 5.9248 (2.7);

5.9167 (3.8); 5.9112 (6.1); 5.9056 (3.4); 5.9030 (2.5); 5.8974 (4.1); 5.8917 (2.5); 5.8832 (2.2); 5.8774 (1.4); 5.8668 (3.6); 5.8611 (6.1); 5.8556 (4.2); 5.8529 (4.2); 5.8471 (9.4); 5.8414 (4.9); 5.8330 (2.5);

5.8293 (4.3); 5.8191 (2.0); 5.8082 (0.6); 5.7979 (1.3); 5.7872 (1.1); 5.6195 (0.6); 5.6148 (0.6); 5.5916 (0.8); 5.5710 (8.7); 5.5696 (8.6); 5.5503 (15.2); 5.5441 (3.6); 5.5280 (7.4); 5.5265 (7.4); 5.5071 (12.8);

5.5010 (2.9); 5.4035 (0.9); 5.3905 (1.0); 5.3766 (1.1); 5.3597 (10.0); 5.3554 (4.8); 5.3452 (8.4); 5.3438 (7.6); 5.3329 (9.4); 5.3287 (4.5); 5.3185 (7.5); 5.1264 (0.8); 5.1210 (1.0); 5.1165 (1.2); 5.1109 (1.3);

5.1059 (1.3); 5.1005 (1.3); 5.0958 (1.0); 5.0389 (3.2); 5.0346 (3.2); 4.6555 (0.5); 4.6465 (0.8); 4.6359 (1.4); 4.6257 (1.5); 4.6156 (1.6); 4.6057 (1.3); 4.5957 (0.8); 4.5857 (0.6); 4.4901 (0.6); 4.4807 (0.6); 4.4566 (1.2); 4.4468 (1.2); 4.4227 (0.8); 4.4132 (0.8); 4.3881 (2.2); 4.3774 (8.0); 4.3672 (7.5); 4.3588 (5.0); 4.3541 (4.6); 4.3488 (5.3); 4.3433 (16.0); 4.3331 (14.2); 4.3250 (9.0); 4.3202 (5.8); 4.3151 (8.5); 4.3093 (9.8);

4.2989 (7.6); 4.2909 (5.0); 4.2864 (6.0); 4.2810 (4.4); 4.2756 (3.8); 4.2627 (1.9); 4.2523 (2.8); 4.2414 (1.7);

3.9689 (0.7); 3.9487 (3.7); 3.9445 (4.2); 3.9388 (11.6); 3.9368 (12.5); 3.9296 (3.7); 3.9055 (4.1); 3.9013 (4.9); 3.8959 (13.6); 3.8938 (14.5); 3.8864 (4.3); 3.8801 (1.1); 3.8361 (0.7); 3.8303 (1.0); 3.8240 (1.1);

3.8161 (1.2); 3.8102 (1.4); 3.8020 (1.3); 3.7943 (1.1); 3.7881 (0.9); 3.7822 (0.6); 3.6098 (2.6); 3.6042 (3.1);

3.5989 (3.2); 3.5935 (3.2); 3.5911 (3.1); 3.5880 (3.2); 3.5852 (2.9); 3.3846 (0.8); 3.3628 (2.3); 3.3482 (2.6);

3.3348 (8.9); 3.3320 (13.6); 3.3283 (10.2); 3.3070 (1.2); 3.2890 (11.4); 3.2852 (8.7); 3.0935 (0.6); 3.0729 (0.7); 3.0460 (1.1); 3.0246 (1.1); 3.0190 (1.0); 2.9973 (1.0); 2.7229 (0.9); 2.7106 (0.9); 2.7023 (1.2); 2.6996 (1.0); 2.6877 (2.0); 2.6787 (1.2); 2.6755 (1.1); 2.6671 (1.9); 2.6549 (1.1); 2.6438 (1.1); 2.6316 (1.0); 2.6184 (2.2); 2.5973 (3.8); 2.5833 (2.9); 2.5760 (2.9); 2.5722 (2.6); 2.5621 (4.3); 2.5511 (4.0); 2.5408 (2.7); 2.5370

- 67 044070 (3.3); 2.5301 (3.0); 2.5160 (4.6); 2.4948 (2.7); 2.4646 (1.0); 2.4597 (1.0); 2.4332 (0.9); 2.4268 (0.9); 2.3858 (0.7); 1.9669(2.2); 1.9566 (4.3); 1.9462 (2.5); 1.9344 (3.3); 1.9239(5.1); 1.9144(2.7); 1.9110(2.8); 1.8992 (2.6); 1.8892 (3.9); 1.8793 (2.1); 1.8756 (1.3); 1.8624 (0.9); 1.8517 (0.8); 1.8402 (0.8); 1.5840 (5.0); 0.9038 (1.4); 0.9001 (1.5); 0.8883 (1.3); 0.8845 (1.4); 0.0081 (4.4); -0.0002 (146.2); -0.0084 (5.6); -0.0138 (0.8); -

0.0160 (0.6); -0.0504 (0.8)

1-017: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5201 (2.0); 7.3116 (2.0); 7.2613 (353.0); 7.2285 (1.9); 7.2115 (1.8); 7.1871 (6.0); 7.1795 (11.5);

7.1738 (13.4); 7.1676 (10.6); 7.1599 (12.5); 7.1542 (9.5); 7.1417 (2.6); 7.1139 (1.7); 7.0955 (2.1); 6.9972 (2.0); 6.9070 (4.1); 6.9005 (4.2); 6.8944 (3.8); 6.8911 (4.2); 6.8850 (5.9); 6.8794 (6.7); 6.8732 (4.1);

6.8637 (2.7); 6.8571 (3.3); 6.7431 (1.2); 6.2023 (4.1); 6.1987 (5.0); 6.1948 (2.5); 6.1756 (4.7); 6.1719 (5.5); 6.1681 (2.9); 6.1592 (5.2); 6.1555 (6.9); 6.1390 (1.4); 6.1324 (4.9); 6.1288 (6.1); 6.1121 (1.0);

5.9631 (3.3); 5.9490 (5.8); 5.9446 (5.5); 5.9398 (5.2); 5.9368 (5.2); 5.9255 (2.8); 5.9193 (2.2); 5.8940 (2.5); 5.8885 (4.5); 5.8805 (3.4); 5.8748 (3.7); 5.8690 (2.1); 5.8601 (1.9); 5.8458 (3.1); 5.8401 (4.4);

5.8344 (2.7); 5.8264 (3.8); 5.8203 (2.6); 5.8138 (2.2); 5.8088 (1.6); 5.5703 (7.0); 5.5688 (7.4); 5.5491 (12.5); 5.5271 (6.2); 5.5256 (6.3); 5.5060 (11.0); 5.3577 (8.4); 5.3423 (5.9); 5.3309 (8.1); 5.3156 (5.5);

5.0955 (1.1); 5.0328 (3.1); 4.6260 (0.7); 4.6157 (0.8); 4.6056 (1.1); 4.5960 (0.8); 4.4041 (1.2); 4.3901 (3.8); 4.3784 (7.4); 4.3747 (6.0); 4.3717 (5.6); 4.3657 (6.5); 4.3623 (7.2); 4.3586 (5.2); 4.3555 (7.1);

4.3523 (7.5); 4.3476 (4.5); 4.3400 (4.4); 4.3364 (5.5); 4.3207 (3.2); 4.3181 (3.3); 4.3101 (2.6); 4.3066 (3.0); 4.2947 (1.2); 4.2908 (1.3); 4.1926 (1.8); 4.1798 (4.2); 4.1667 (3.8); 4.1290 (1.5); 4.1179 (1.7);

3.9494 (2.9); 3.9447 (3.6); 3.9381 (14.1); 3.9284 (1.9); 3.9063 (3.4); 3.9016 (4.0); 3.8951 (16.0); 3.8854 (2.1); 3.7431 (1.1); 3.5846 (5.4); 3.5697 (5.8); 3.5638 (3.7); 3.5559 (4.2); 3.5408 (3.5); 3.3299 (10.0); 3.3273 (9.8); 3.3094 (1.5); 3.2982 (1.6); 3.2869 (8.8); 3.2842 (8.6); 3.0154 (0.8); 2.6826 (0.9); 2.6700 (1.4); 2.6494 (1.3); 2.6356 (0.9); 2.6142 (0.6); 2.5831 (1.6); 2.5617 (4.4); 2.5500 (5.5); 2.5392 (5.4);

2.5355 (7.4); 2.5237 (7.6); 2.5193 (6.4); 2.5128 (5.4); 2.5090 (8.4); 2.4975 (8.4); 2.4832 (6.6); 2.4708 (5.0); 2.4548 (3.7); 2.4445 (2.0); 2.4288 (1.6); 2.3503 (1.2); 2.3319 (0.9); 1.9505 (1.7); 1.9404 (2.7); 1.9347 (1.9); 1.9116 (3.0); 1.9024 (4.4); 1.8961 (3.3); 1.8766 (3.7); 1.8644 (6.4); 1.8572 (6.8); 1.8486 (8.1); 1.8413 (5.6); 1.8328 (5.2); 1.5628 (12.0); 1.3002 (1.5); 1.2818 (1.5); 1.2555 (5.7); 1.0634 (0.9);

0.9033 (4.3); 0.8966 (3.6); 0.8875 (4.6); 0.8808 (3.8); 0.0501 (0.7); 0.0080 (3.7); -0.0002 (121.4); -0.0084 (5.1); -0.0498 (0.7)

1-018: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5189 (0.6); 7.2601 (108.4); 7.1902 (1.3); 7.1844 (1.7); 7.1805 (2.0); 7.1746 (2.5); 7.1704 (2.4); 7.1645 (2.0); 7.1605 (1.8); 7.1549 (1.8); 6.9961 (0.6); 6.8964 (0.8); 6.8807 (0.8); 6.8749 (1.4); 6.8691 (0.7); 6.8531 (0.7); 6.2032 (1.0); 6.1999 (1.0); 6.1764 (1.0); 6.1731 (1.1); 6.1601 (1.2); 6.1567 (1.2); 6.1333 (1.2); 6.1299 (1.2); 5.9775 (0.6); 5.9751 (0.6); 5.9709 (0.9); 5.9672 (1.0); 5.9640 (1.2); 5.9610 (1.0); 5.9572 (1.0); 5.9526 (0.6); 5.9504 (0.6); 5.8813 (0.6); 5.8756 (1.1); 5.8701 (0.7); 5.8675 (0.5); 5.8619 (0.8); 5.8290 (0.6); 5.8233 (1.0); 5.8177 (0.6); 5.8095 (0.8); 5.5719 (1.5); 5.5704 (1.4); 5.5499 (1.6); 5.5483 (1.6); 5.5288 (1.3); 5.5272

- 68 044070 (1.3); 5.5068 (1.4); 5.5052 (1.4); 5.3540 (1.4); 5.3527 (1.3); 5.3376 (1.4); 5.3362 (1.4); 5.3273 (1.3); 5.3259 (1.2); 5.3109 (1.3); 5.3094 (1.2); 5.0345 (0.6); 4.3078 (1.0); 4.3015 (1.2); 4.2965 (2.2); 4.2889 (2.0); 4.2839 (2.6); 4.2781 (1.2); 4.2717 (1.8); 4.2607 (1.1); 3.9398 (1.9); 3.9371 (1.9); 3.8968 (2.1); 3.8942 (2.2); 3.6367 (2.0); 3.6259 (2.1); 3.6238 (2.4); 3.6203 (1.7); 3.6186 (1.5); 3.6131 (2.0); 3.6073 (2.4); 3.5968 (1.3); 3.5948 (1.4); 3.5892 (0.7); 3.5778 (0.8); 3.5675 (0.7); 3.5647 (0.7); 3.5563 (0.7); 3.4053 (1.0); 3.3999 (14.2);

3.3939 (1.0); 3.3905 (1.3); 3.3818 (16.0); 3.3726 (0.5); 3.3252 (1.9); 3.3209 (1.7); 3.2822 (1.6); 3.2778 (1.5); 2.5489 (0.7); 2.5282 (0.7); 2.5139 (0.8); 2.5079 (0.8); 2.4937 (0.7); 2.4729 (0.8); 1.9473 (0.6); 1.9217 (0.7); 1.9120 (1.2); 1.9021 (0.7); 1.8768 (0.6); 1.5465 (4.3); 0.9019 (0.6); 0.8979 (0.5); 0.8862 (0.6); 0.0080 (1.5); -0.0002 (42.1); -0.0085 (1.6)

1-020: ¹ H-NMR(599.7 MHz, CDC13):

δ= 7.2614 (50.0); 7.2433 (1.6); 7.2321 (1.1); 7.2203 (0.5); 7.2166 (0.8); 7.2129 (0.9); 7.2080 (3.0); 7.2045 (5.6); 7.2015 (4.8); 7.1981 (3.4); 7.1946 (4.8); 7.1916 (5.6); 7.1882 (3.0); 7.1834 (0.8); 7.1797 (0.6); 6.9120 (1.1); 6.9083 (1.9); 6.9046 (1.1); 6.8976 (2.2); 6.8938 (3.6); 6.8901 (1.9); 6.8832 (1.2);

6.8793 (1.8); 6.8757 (0.9); 5.9870 (1.2); 5.9832 (2.4); 5.9807 (2.5); 5.9741 (3.1); 5.9716 (3.1); 5.9678 (1.5); 5.9284 (1.4); 5.9248 (2.6); 5.9210 (1.6); 5.9156 (2.0); 5.9120 (1.2); 5.9075 (1.4); 5.9038 (2.6);

5.8999 (1.6); 5.8946 (2.0); 5.8909 (1.1); 5.2999 (0.9); 5.1292 (0.6); 5.1161 (1.7); 5.1022 (1.7); 5.0892 (0.6); 4.2093 (2.2); 4.1974 (7.0); 4.1929 (1.6); 4.1855 (7.4); 4.1834 (4.7); 4.1810 (4.1); 4.1735 (2.9);

4.1714 (4.2); 4.1691 (3.9); 4.1629 (0.5); 4.1594 (1.4); 4.1573 (1.3); 4.1511 (0.4); 3.8563 (4.2); 3.8491 (4.2); 3.8262 (4.7); 3.8189 (4.6); 3.5480 (1.0); 3.5437 (1.5); 3.5393 (1.8); 3.5345 (2.0); 3.5298 (1.9);

3.5254 (1.5); 3.5211 (1.1); 3.3748 (30.5); 3.3668 (30.7); 3.3610 (0.9); 3.3566 (0.7); 3.3522 (5.1); 3.3482 (5.0); 3.3220 (4.4); 3.3180 (4.5); 2.5618 (1.0); 2.5478 (1.9); 2.5381 (1.8); 2.5337 (1.2); 2.5239 (3.4);

2.5140 (1.3); 2.5098 (1.8); 2.5000 (2.1); 2.4859 (1.0); 1.9951 (1.0); 1.9891 (2.2); 1.9816 (2.2); 1.9756 (1.1); 1.9718 (1.0); 1.9658 (2.0); 1.9582 (2.0); 1.9522 (1.0); 1.5968 (2.7); 1.3098 (7.8); 1.2977 (19.9);

1.2853 (20.2); 1.2733 (7.7); 1.2672 (0.6); 1.2628 (0.5); 1.2552 (0.7); 0.8821 (0.4); 0.0695 (6.6); 0.0053 (1.4); -0.0001 (40.2); -0.0056 (1.3)

1-021: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.8170 (1.1); 7.8139 (1.4); 7.8098 (0.7); 7.8020 (0.5); 7.7968 (1.7); 7.7929 (1.2); 7.6775 (3.0); 7.6741 (3.7); 7.6700 (4.4); 7.6667 (4.0); 7.6626 (2.9); 7.6575 (4.4); 7.6532 (4.3); 7.6502 (4.6); 7.6459 (3.6);

7.5190 (0.6); 7.5016 (0.7); 7.4986 (1.1); 7.4948 (0.9); 7.4892 (1.0); 7.4864 (1.3); 7.4800 (3.6); 7.4729 (1.9); 7.4667 (3.4); 7.4627 (5.3); 7.4585 (3.5); 7.4519 (7.0); 7.4480 (4.4); 7.4442 (1.7); 7.4375 (3.5);

7.4333 (7.4); 7.4208 (1.4); 7.4164 (2.5); 7.4116 (2.1); 7.4080 (0.8); 7.3787 (1.2); 7.3737 (1.2); 7.2602 (83.3); 6.0435 (0.6); 6.0352 (0.5); 6.0298 (0.8); 6.0243 (0.5); 6.0048 (1.0); 6.0013 (1.1); 5.9983 (1.2);

5.9943 (1.8); 5.9907 (2.3); 5.9875 (2.4); 5.9843 (2.3); 5.9807 (2.2); 5.9766 (1.4); 5.9737 (1.3); 5.9701 (1.2); 5.9632 (0.6); 5.9560 (0.5); 5.9210 (1.2); 5.9154 (2.1); 5.9098 (1.3); 5.9073 (1.0); 5.9017 (1.6);

5.8961 (0.9); 5.8492 (1.2); 5.8437 (2.0); 5.8380 (1.3); 5.8356 (1.1); 5.8299 (1.7); 5.8243 (0.9); 5.3404 (0.5); 5.1095 (0.5); 5.0902 (1.3); 5.0815 (0.9); 5.0777 (0.9); 5.0693 (1.2); 4.2372 (2.1); 4.2193 (6.7);

- 69 044070

4.2132 (2.4); 4.2014 (7.2); 4.1953 (6.8); 4.1835 (2.8); 4.1812 (2.5); 4.1774 (6.8); 4.1596 (2.3); 4.0391 (3.1); 3.9941 (4.6); 3.8189 (4.6); 3.8140 (4.7); 3.7740 (3.2); 3.7691 (3.3); 3.5453 (0.8); 3.5391 (1.2);

3.5332 (1.3); 3.5265 (1.4); 3.5241 (1.4); 3.5180 (1.5); 3.5144 (1.4); 3.5120 (1.5); 3.5055 (1.2); 3.5029 (1.0); 3.4999 (0.8); 3.0156 (0.7); 2.5691 (0.8); 2.5480 (1.5); 2.5338 (1.1); 2.5269 (0.9); 2.5193 (0.8);

2.5127 (1.8); 2.5050 (1.3); 2.4916 (1.0); 2.4840 (2.3); 2.4698 (1.1); 2.4631 (1.2); 2.4488 (1.8); 2.4278 (0.8); 2.0432 (1.2); 2.0060 (1.1); 1.9973 (1.6); 1.9891 (0.9); 1.9704 (0.8); 1.9623 (2.1); 1.9538 (2.2);

1.9450 (0.8); 1.9274 (0.7); 1.9186 (1.3); 1.9099 (0.7); 1.5605 (16.0); 1.3255 (7.2); 1.3076 (15.0); 1.2981 (7.5); 1.2918 (7.4); 1.2898 (8.2); 1.2803 (14.5); 1.2741 (3.8); 1.2624 (7.7); 1.2504 (0.7); 0.8818 (1.2); 0.0080 (1.2); -0.0002 (32.1); -0.0085 (1.2)

1-023: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.4713 (2.0); 7.4665 (2.2); 7.4620 (2.1); 7.3739 (0.8); 7.3454 (3.2); 7.3416 (3.0); 7.2717 (3.8); 7.2600 (54.8); 6.0064 (0.7); 6.0030 (0.7); 5.9964 (1.3); 5.9928 (1.6); 5.9895 (1.6); 5.9863 (1.6); 5.9828 (1.6); 5.9792 (1.0); 5.9762 (0.9); 5.9727 (0.8); 5.9202 (0.8); 5.9147 (1.4); 5.9090 (0.9); 5.9009 (1.1); 5.8954 (0.6); 5.8496 (0.8); 5.8441 (1.3); 5.8383 (0.9); 5.8303 (1.1); 5.8247 (0.6); 5.0831 (0.9); 5.0624 (0.9);

4.2369 (1.3); 4.2191 (4.2); 4.2012 (4.6); 4.1980 (4.3); 4.1831 (1.9); 4.1802 (4.1); 4.1623 (1.4); 4.0006 (2.1); 3.9556 (3.1); 3.7722 (2.9); 3.7665 (2.9); 3.7272 (2.0); 3.7215 (2.0); 3.5258 (1.0); 3.5200 (1.0);

3.5133 (1.0); 2.5583 (0.5); 2.5371 (1.0); 2.5229 (0.7); 2.5160 (0.6); 2.5018 (1.2); 2.4920 (0.6); 2.4807 (0.6); 2.4710 (1.1); 2.4569 (0.7); 2.4501 (0.6); 2.4359 (1.2); 2.4149 (0.6); 2.3685 (16.0); 2.0036 (0.6);

1.9955 (1.1); 1.9876 (0.6); 1.9681 (0.6); 1.9607 (1.2); 1.9537 (1.4); 1.9458 (0.6); 1.9271 (0.5); 1.9190 (0.9); 1.9106 (0.5); 1.5490 (14.5); 1.3252 (4.3); 1.3073 (8.9); 1.3024 (4.8); 1.2894 (4.9); 1.2846 (8.9); 1.2667 (4.9); 1.2525 (0.6); 0.8817 (1.2); 0.0079 (0.8); -0.0002 (21.1); -0.0084 (0.9)

1-024: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3699 (0.6); 7.2607 (52.9); 7.2252 (2.3); 7.2237 (2.3); 7.2188 (2.7); 7.2150 (3.3); 7.2135 (3.4); 7.2105 (3.1); 7.1912 (1.2); 7.1871 (1.2); 7.0106 (1.3); 7.0086 (1.3); 6.9967 (1.1); 6.9892 (1.2); 6.9856 (1.2); 6.0213 (0.6); 6.0174 (0.6); 6.0113 (0.6); 6.0073 (1.1); 6.0033 (0.9); 6.0009 (0.9); 5.9970 (1.3); 5.9933 (1.2); 5.9900 (1.3); 5.9868 (1.2); 5.9833 (1.3); 5.9797 (0.8); 5.9766 (0.7); 5.9731 (0.6); 5.9265 (0.6); 5.9210 (1.2); 5.9154 (0.7); 5.9130 (0.5); 5.9073 (0.8); 5.8695 (0.5); 5.8615 (0.8); 5.8559 (1.4); 5.8502 (0.9); 5.8423 (0.9); 5.8367 (0.5); 5.2987 (0.6); 5.0745 (0.7); 4.0007 (1.8); 3.9556 (2.7); 3.7857 (1.7); 3.7834 (1.9); 3.7777 (2.8); 3.7712 (2.8); 3.7623 (4.5); 3.7590 (15.3); 3.7496 (3.1); 3.7397 (16.0); 3.7329 (2.2); 3.7262 (1.8); 3.7043 (6.0); 3.6929 (5.5); 3.5527 (0.7); 3.5462 (0.7); 3.5409 (0.8); 3.5364 (0.7); 3.5340 (0.7); 3.5250 (0.5); 2.5461 (0.9); 2.5318 (0.6); 2.5251 (0.5); 2.5109 (1.1); 2.5041 (0.6); 2.4898 (0.6); 2.4831 (1.0); 2.4688 (0.7); 2.4623 (0.6); 2.4480 (1.0); 2.4270 (0.6); 2.3877 (14.8); 2.0027 (0.8); 1.9670 (0.9); 1.9571 (1.0); 1.9484 (0.7); 1.9216 (0.8); 1.9132 (0.6); 1.5571 (5.3); 0.0078 (0.7); 0.0002 (19.9); -0.0085 (0.7)

1-025: ¹ H-NMR(400.0 MHz, CDC13):

- 70 044070 δ= 7.6779 (1.8); 7.6745 (2.3); 7.6703 (3.2); 7.6671 (3.3); 7.6632 (2.3); 7.6580 (2.8); 7.6536 (2.9); 7.6504 (3.7); 7.6463 (3.0); 7.5186 (0.8); 7.5019 (0.9); 7.4931 (1.1); 7.4830 (2.3); 7.4762 (1.5); 7.4700 (1.9);

7.4659 (3.3); 7.4615 (2.8); 7.4552 (3.9); 7.4459 (1.6); 7.4408 (2.4); 7.4355 (3.7); 7.4244 (0.8); 7.4189 (1.1); 7.4148 (0.7); 7.3311 (0.8); 7.3097 (0.8); 7.2597 (117.1); 6.9957 (0.6); 6.0331 (0.6); 6.0272 (1.0);

6.0233 (1.0); 6.0207 (0.9); 6.0127 (1.2); 6.0069 (1.3); 6.0030 (1.1); 5.9982 (0.8); 5.9945 (0.8); 5.9916 (0.7); 5.9881 (0.7); 5.9455 (0.7); 5.9400 (1.3); 5.9344 (0.8); 5.9262 (0.9); 5.9206 (0.5); 5.8753 (0.8);

5.8697 (1.2); 5.8640 (0.7); 5.8616 (0.6); 5.8559 (1.0); 5.8503 (0.6); 5.0939 (0.7); 4.5542 (0.6); 4.5394 (0.5); 4.4235 (1.9); 4.4095 (2.5); 4.4068 (1.9); 4.3950 (3.7); 4.3913 (1.6); 4.3811 (2.5); 4.3767 (2.1);

4.3715 (0.9); 4.3662 (1.5); 4.3631 (1.6); 4.3576 (1.4); 4.3426 (1.4); 4.3290 (0.7); 4.0380 (1.4); 3.9931 (2.2); 3.8291 (1.6); 3.8236 (3.1); 3.8183 (3.1); 3.8121 (0.5); 3.7889 (1.0); 3.7863 (1.1); 3.7841 (1.1);

3.7786 (2.0); 3.7735 (2.4); 3.7598 (0.5); 3.7428 (2.6); 3.7285 (3.0); 3.7144 (5.2); 3.6999 (4.7); 3.6861 (3.4); 3.6714 (1.4); 3.6591 (0.8); 3.6060 (0.6); 3.5989 (0.8); 3.5919 (0.8); 3.5834 (0.8); 2.5891 (0.9);

2.5748 (0.6); 2.5679 (0.6); 2.5537 (1.0); 2.5432 (0.5); 2.5325 (0.6); 2.5221 (1.0); 2.5079 (0.6); 2.5011 (0.5); 2.4869 (1.0); 2.4658 (0.5); 2.0295 (0.9); 1.9948 (1.0); 1.9873 (1.2); 1.9784 (0.6); 1.9522 (1.0);

1.5424 (16.0); 1.2558 (1.0); 0.0079 (1.5); -0.0002 (43.1); -0.0085 (1.5)

1-027: Ή-ΉΜΡ(400.0 MHz, CDC13):

δ= 7.5183 (1.0); 7.4721 (1.6); 7.4671 (2.1); 7.4624 (2.5); 7.3490 (2.1); 7.3472 (2.2); 7.3426 (2.2); 7.3405 (2.2); 7.3386 (2.2); 7.3349 (1.9); 7.2782 (2.5); 7.2735 (3.0); 7.2697 (2.5); 7.2594 (171.0); 6.9954 (1.0);

6.0174 (0.5); 6.0113 (0.5); 6.0070 (0.8); 6.0028 (0.8); 5.9963 (1.2); 5.9924 (1.2); 5.9891 (1.3); 5.9859 (1.3); 5.9824 (1.3); 5.9787 (0.8); 5.9757 (0.7); 5.9724 (0.6); 5.9257 (0.6); 5.9202 (1.2); 5.9146 (0.7);

5.9064 (0.8); 5.8601 (0.8); 5.8545 (1.4); 5.8488 (0.9); 5.8407 (0.9); 5.0722 (0.7); 3.9987 (1.8); 3.9538 (2.6); 3.7791 (1.6); 3.7738 (2.7); 3.7670 (3.0); 3.7593 (16.0); 3.7500 (2.2); 3.7405 (16.0); 3.7289 (1.9);

3.7220 (1.8); 3.7040 (5.2); 3.6929 (5.0); 3.5539 (0.7); 3.5454 (0.7); 3.5397 (0.7); 3.5338 (0.7); 2.5439 (0.9); 2.5295 (0.6); 2.5228 (0.5); 2.5085 (1.0); 2.5010 (0.6); 2.4876 (0.5); 2.4801 (0.9); 2.4658 (0.6);

2.4593 (0.5); 2.4449 (1.0); 2.4241 (0.6); 2.3717 (13.5); 2.3706 (13.6); 2.0016 (0.8); 1.9660 (0.8); 1.9547 (0.9); 1.9463 (0.6); 1.9194 (0.8); 1.9111 (0.6); 1.5378 (9.0); 0.0080 (2.0); -0.0002 (64.1); -0.0085 (2.4) 1-028: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5186 (0.6); 7.4652 (2.6); 7.4614 (2.7); 7.3520 (1.0); 7.3480 (1.8); 7.3460 (2.2); 7.3385 (2.3); 7.3344 (2.2); 7.3242 (0.6); 7.3146 (0.9); 7.3125 (0.9); 7.3083 (1.1); 7.3035 (1.0); 7.3005 (0.9); 7.2969 (1.0);

7.2868 (2.2); 7.2830 (2.4); 7.2789 (3.2); 7.2743 (3.6); 7.2683 (2.5); 7.2598 (106.4); 7.2571 (9.4); 7.2519 (1.5); 7.2491 (1.3); 7.2417 (0.7); 7.2085 (0.8); 6.9958 (0.6); 6.0419 (0.5); 6.0381 (0.6); 6.0284 (1.0);

6.0232 (0.9); 6.0152 (1.2); 6.0118 (1.3); 6.0089 (1.3); 6.0053 (1.3); 6.0014 (0.8); 5.9979 (0.7); 5.9948 (0.7); 5.9913 (0.7); 5.9443 (0.6); 5.9387 (1.2); 5.9331 (0.7); 5.9249 (0.9); 5.8756 (0.7); 5.8699 (1.2);

5.8641 (0.7); 5.8561 (0.9); 5.8505 (0.5); 5.0928 (0.7); 4.5685 (0.6); 4.5540 (0.8); 4.5393 (0.7); 4.4234

- 71 044070 (1.8); 4.4094 (2.4); 4.4068 (1.8); 4.3987 (1.5); 4.3953 (3.5); 4.3852 (2.4); 4.3808 (1.8); 4.3703 (2.0);

4.3677 (1.5); 4.3589 (1.4); 4.3430 (1.4); 4.3314 (0.8); 3.9991 (1.4); 3.9536 (2.1); 3.9299 (0.5); 3.7887 (1.1); 3.7827 (1.8); 3.7767 (3.0); 3.7710 (2.7); 3.7596 (0.8); 3.7418 (2.8); 3.7385 (1.4); 3.7314 (2.6);

3.7273 (3.9); 3.7185 (2.9); 3.7136 (2.7); 3.7042 (3.6); 3.6996 (1.5); 3.6901 (3.1); 3.6852 (1.5); 3.6749 (1.3); 3.6714 (1.3); 3.6611 (1.0); 3.6001 (0.8); 3.5926 (0.9); 3.5853 (0.9); 2.5796 (0.8); 2.5651 (0.5);

2.5440 (0.9); 2.5330 (0.5); 2.5232 (0.6); 2.5118 (0.8); 2.4975 (0.6); 2.4909 (0.5); 2.4766 (1.0); 2.4555 (0.5); 2.3706 (13.5); 2.0278 (0.8); 1.9933 (1.0); 1.9861 (1.0); 1.9594 (0.6); 1.9509 (0.8); 1.5413 (16.0); 0.0081 (1.3); -0.0002 (38.6); -0.0029 (4.3); -0.0084 (1.6)

1-029: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.4632 (2.4); 7.3500 (1.5); 7.3481 (1.6); 7.3461 (1.8); 7.3440 (1.8); 7.3421 (1.9); 7.3403 (1.8); 7.2779 (2.6); 7.2598 (74.5); 7.2127 (0.7); 7.1926 (0.7); 6.0210 (0.6); 6.0183 (0.6); 6.0151 (0.8); 6.0035 (1.3);

5.9980 (1.1); 5.9917 (0.8); 5.9891 (0.8); 5.9854 (0.7); 5.9688 (0.7); 5.9633 (1.1); 5.9578 (0.7); 5.9495 (0.7); 5.9010 (0.7); 5.8953 (1.2); 5.8896 (0.7); 5.8873 (0.6); 5.8815 (0.9); 5.8758 (0.6); 5.2984 (2.9);

5.0966 (0.6); 5.0935 (0.6); 5.0812 (0.6); 5.0781 (0.6); 4.5675 (1.0); 4.5466 (3.2); 4.5418 (1.0); 4.5379 (0.6); 4.5257 (3.4); 4.5209 (2.1); 4.5170 (1.6); 4.5048 (1.3); 4.5000 (2.1); 4.4960 (1.6); 4.4888 (0.7);

4.4791 (1.0); 4.4751 (0.6); 4.4679 (0.7); 3.9952 (1.3); 3.9505 (2.0); 3.7859 (1.2); 3.7809 (2.2); 3.7737 (2.4); 3.7407 (0.9); 3.7359 (1.5); 3.7287 (1.6); 3.6615 (0.6); 3.6585 (0.6); 3.6550 (0.7); 3.6524 (0.7);

3.6490 (0.7); 3.6460 (0.7); 3.6430 (0.7); 3.6401 (0.8); 3.6372 (0.6); 2.6358 (0.8); 2.6214 (0.6); 2.6146 (0.5); 2.6003 (0.9); 2.5792 (0.5); 2.5622 (0.8); 2.5478 (0.6); 2.5413 (0.5); 2.5269 (0.9); 2.3703 (13.1);

2.0236 (0.8); 2.0145 (0.5); 1.9956 (0.7); 1.9871 (1.1); 1.9787 (0.6); 1.9594 (0.5); 1.9505 (0.7); 1.5416 (16.0); 0.0080 (0.9); -0.0002 (28.1); -0.0084 (1.1)

1-033: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5181 (2.7); 7.3763 (3.6); 7.3684 (17.2); 7.3634 (7.0); 7.3563 (31.3); 7.3506 (18.4); 7.3426 (5.8);

7.3382 (3.9); 7.3271 (1.9); 7.3086 (1.6); 7.2962 (1.5); 7.2592 (478.9); 7.2268 (0.5); 7.2206 (0.5); 7.1967 (1.2); 7.1843 (5.6); 7.1789 (6.3); 7.1751 (5.0); 7.1689 (5.2); 7.1644 (6.9); 7.1588 (5.7); 6.9952 (2.6);

6.9037 (0.9); 6.8979 (1.6); 6.8906 (1.9); 6.8821 (1.8); 6.8760 (3.2); 6.8688 (3.3); 6.8629 (1.8); 6.8542 (1.6); 6.8470 (1.7); 6.8411 (0.7); 6.1970 (1.4); 6.1890 (1.5); 6.1703 (4.3); 6.1624 (1.7); 6.1539 (1.7);

6.1459 (2.2); 6.1436 (3.3); 6.1272 (4.9); 6.1192 (1.8); 6.1004 (3.4); 5.9658 (1.4); 5.9618 (1.8); 5.9589 (1.7); 5.9558 (1.8); 5.9520 (1.7); 5.9478 (1.1); 5.9418 (0.8); 5.8796 (0.9); 5.8740 (1.6); 5.8682 (1.0);

5.8602 (1.2); 5.8546 (0.7); 5.8292 (0.8); 5.8234 (1.6); 5.8176 (1.0); 5.8096 (1.3); 5.8040 (0.8); 5.5626 (2.4); 5.5458 (7.8); 5.5193 (2.1); 5.5027 (6.8); 5.3765 (5.5); 5.3496 (5.3); 5.3447 (2.6); 5.3360 (2.3);

5.3179 (2.2); 5.3093 (2.2); 5.2938 (2.0); 5.2631 (8.4); 5.2458 (8.3); 5.2150 (2.0); 5.1985 (0.7); 5.1783 (9.5); 5.1681 (4.7); 5.1615 (4.6); 5.1310 (0.7); 5.0308 (1.0); 3.9367 (3.5); 3.9237 (5.4); 3.8936 (4.0);

3.8814 (6.2); 3.5596 (1.1); 3.3470 (5.8); 3.3275 (2.8); 3.3213 (2.8); 3.3046 (5.1); 3.2845 (2.4); 3.2782 (2.4); 2.5800 (0.7); 2.5591 (1.2); 2.5452 (0.8); 2.5377 (1.0); 2.5239 (1.3); 2.5150 (1.2); 2.5012 (1.0);

2.4942 (0.7); 2.4802 (1.3); 2.4588 (0.6); 1.9655 (0.7); 1.9552 (1.1); 1.9452 (0.7); 1.9393 (0.7); 1.9295

- 72 044070 (1.4); 1.9199 (1.3); 1.9104 (0.6); 1.8942 (1.0); 1.8840 (0.5); 1.5549 (16.0); 0.1459 (0.6); 0.0079 (7.0); 0.0002 (177.6); -0.0085 (6.8); -0.1491 (0.6)

1-034: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5189 (2.8); 7.3216 (0.6); 7.2941 (1.5); 7.2600 (491.5); 7.2393 (11.7); 7.2368 (12.2); 7.2310 (8.9); 7.2257 (2.0); 7.2098 (1.7); 7.2063 (1.4); 7.1936 (5.4); 7.1879 (6.7); 7.1847 (4.8); 7.1739 (7.8); 7.1683 (7.3); 7.1601 (3.4); 7.1560 (3.4); 7.1503 (2.3); 6.9960 (2.8); 6.9493 (1.0); 6.9437 (1.7); 6.9379 (1.0); 6.9258 (2.9); 6.9220 (3.9); 6.9162 (2.4); 6.9098 (3.2); 6.9041 (5.2); 6.8984 (3.4); 6.8882 (2.1); 6.8823 (3.1); 6.8765 (1.8); 6.8585 (0.8); 6.1921 (4.8); 6.1653 (5.1); 6.1490 (5.8); 6.1222 (6.1); 6.0160 (1.3); 6.0115 (1.5); 6.0079 (1.5); 6.0021 (2.1); 5.9977 (2.4); 5.9118 (0.8); 5.8977 (0.7); 5.8922 (0.6); 5.8675 (1.2); 5.8576 (1.2); 5.8520 (2.0); 5.8461 (1.3); 5.8379 (1.5); 5.8322 (0.9); 5.6506 (8.5); 5.6074 (7.3); 5.5647 (1.8); 5.5508 (1.7); 5.5228 (1.6); 5.5077 (1.4); 5.4631 (7.8); 5.4363 (7.3); 5.3592 (2.0); 5.3466 (1.2); 5.3324 (2.0); 5.3208 (1.2); 5.1652 (0.6); 5.1495 (1.6); 5.1338 (2.2); 5.1180 (1.7); 5.1022 (0.8); 5.0354 (0.8); 5.0198 (1.7); 5.0042 (2.2); 4.9885 (1.7); 4.9727 (0.6); 3.9528 (7.0); 3.9354 (3.2); 3.9099 (8.2); 3.8923 (3.6); 3.7283 (0.9); 3.7220 (1.1); 3.7161 (1.2); 3.7100 (1.2); 3.7064 (1.1); 3.7003 (1.2); 3.6944 (1.2); 3.6881 (1.1); 3.5775 (1.5); 3.5216 (6.6); 3.4970 (7.0); 3.4248 (8.6); 3.3820 (7.6); 3.3694 (2.6); 3.3368 (3.0); 3.3316 (3.4); 3.2936 (2.5); 3.2884 (2.9); 3.1501 (1.9); 3.1372 (1.8); 2.7180 (0.7); 2.7056 (0.9); 2.6972 (0.9); 2.6827 (1.0); 2.6704 (1.0); 2.6620 (0.9); 2.6497 (0.8); 2.5886 (0.8); 2.5747 (0.6); 2.5678 (0.6); 2.5538 (1.1); 2.5398 (0.7); 2.5043 (0.7); 2.3430 (0.7); 2.3274 (1.9); 2.3185 (0.8); 2.3118 (2.0); 2.3029 (2.0); 2.2871 (2.0); 2.2716 (0.7); 1.9909 (0.9); 1.9650 (0.5); 1.9551 (1.6); 1.9444 (1.2); 1.9330 (1.0); 1.9198 (1.2); 1.9086 (1.1); 1.8978 (0.9); 1.8867 (0.8); 1.5282 (2.7); 1.5124 (3.8); 1.4146 (0.5); 1.3984 (0.6); 1.3698 (15.4); 1.3612 (4.3); 1.3541 (16.0); 1.3458 (4.4); 1.3249 (1.8); 1.3086 (0.7); 1.2832 (2.7); 1.2676 (2.7); 1.2453 (8.0); 1.2401 (8.0); 1.2297 (8.2); 1.2245 (8.2); 1.0377 (0.8); 1.0204 (0.6); 0.9529 (15.8); 0.9372 (16.0); 0.1458 (0.6); 0.0079 (6.0); -0.0002 (196.6); -0.0085 (9.7); 0.0210(3.8); -0.1496 (0.6)

1-035: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2607 (46.2); 7.1905 (1.7); 7.1847 (2.0); 7.1814 (2.4); 7.1755 (2.6); 7.1708 (2.6); 7.1649 (2.6); 7.1615 (2.2); 7.1558 (1.7); 7.1436 (0.5); 7.1378 (0.5); 6.8996 (0.7); 6.8976 (0.7); 6.8836 (0.8); 6.8817 (0.9); 6.8778 (1.4); 6.8760 (1.4); 6.8721 (0.8); 6.8702 (0.7); 6.8561 (0.7); 6.8543 (0.7); 6.2043 (1.3);

6.2028 (1.2); 6.1775 (1.4); 6.1759 (1.4); 6.1612 (1.6); 6.1596 (1.5); 6.1344 (1.6); 6.1329 (1.5); 5.9687 (0.6); 5.9650 (0.6); 5.9625 (0.6); 5.9578 (1.0); 5.9543 (1.2); 5.9511 (1.4); 5.9482 (1.2); 5.9445 (1.2);

5.9397 (0.8); 5.9374 (0.8); 5.9335 (0.7); 5.8832 (0.7); 5.8777 (1.3); 5.8721 (0.8); 5.8696 (0.6); 5.8639 (1.0); 5.8583 (0.5); 5.8342 (0.7); 5.8286 (1.3); 5.8229 (0.8); 5.8205 (0.6); 5.8148 (1.0); 5.8091 (0.6);

5.5740 (1.8); 5.5727 (1.7); 5.5539 (1.8); 5.5524 (1.7); 5.5309 (1.6); 5.5296 (1.5); 5.5107 (1.6); 5.5093 (1.5); 5.3568 (1.7); 5.3416 (1.7); 5.3300 (1.6); 5.3148 (1.6); 5.0273 (0.8); 3.9375 (2.5); 3.9356 (2.4);

3.8945 (2.9); 3.8927 (2.7); 3.7467 (16.0); 3.7349 (15.7); 3.5291 (0.8); 3.5260 (0.7); 3.5233 (0.8); 3.5201 (0.8); 3.5172 (0.8); 3.5142 (0.8); 3.3284 (2.2); 3.3232 (2.1); 3.2855 (1.9); 3.2801 (1.9); 2.5444 (0.9);

- 73 044070

2.5306 (0.6); 2.5230 (0.8); 2.5095 (1.0); 2.5008 (0.9); 2.4873 (0.8); 2.4797 (0.5); 2.4658 (1.0); 2.4448 (0.5); 1.9408 (0.9); 1.9155 (0.6); 1.9125 (0.6); 1.9056 (1.0); 1.9030 (1.0); 1.8959 (0.6); 1.8932 (0.6); 1.8679 (0.8); 1.5561 (8.7); 0.0079 (0.6); -0.0002 (17.9); -0.0085 (0.6) 1-037: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2617 (68.3); 7.2085 (0.8); 7.1961 (0.9); 7.1839 (3.3); 7.1781 (4.0); 7.1735 (3.8); 7.1674 (4.2); 7.1641 (4.5); 7.1582 (4.0); 7.1535 (3.2); 7.1477 (2.2); 6.9007 (0.6); 6.8950 (1.3); 6.8910 (1.2); 6.8790 (1.2); 6.8734 (2.1); 6.8694 (2.1); 6.8637 (1.0); 6.8574 (0.6); 6.8516 (1.0); 6.8476 (1.0); 6.2006 (1.9); 6.1963 (1.8); 6.1738 (2.1); 6.1695 (2.0); 6.1575 (2.2); 6.1532 (2.2); 6.1306 (2.2); 6.1264 (2.2); 6.0200 (1.1); 6.0164 (1.2); 6.0138 (1.2); 6.0100 (1.2); 6.0002 (2.3); 5.9908 (1.1); 5.9867 (1.1); 5.9805 (0.9);

5.9126 (1.0); 5.9070 (1.8); 5.9012 (1.1); 5.8931 (1.4); 5.8874 (0.8); 5.8671 (1.2); 5.8616 (1.9); 5.8558 (1.1); 5.8478 (1.7); 5.8421 (1.1); 5.5646 (2.7); 5.5632 (2.6); 5.5501 (2.7); 5.5486 (2.6); 5.5214 (2.3);

5.5201 (2.2); 5.5109 (1.0); 5.5070 (2.4); 5.5055 (2.3); 5.3591 (0.7); 5.3522 (2.6); 5.3420 (2.5); 5.3327 (0.8); 5.3254 (2.4); 5.3152 (2.3); 5.2989 (8.3); 5.0248 (1.1); 3.9593 (0.6); 3.9538 (0.7); 3.9384 (3.0);

3.9345 (3.1); 3.9162 (0.7); 3.9107 (0.8); 3.8953 (3.4); 3.8915 (3.4); 3.7803 (0.8); 3.7762 (1.6); 3.7726 (5.6); 3.7706 (3.7); 3.7663 (3.6); 3.7622 (4.7); 3.7560 (13.4); 3.7499 (4.7); 3.7457 (3.3); 3.7414 (3.6); 3.7393 (5.5); 3.7357 (1.3); 3.5871 (0.8); 3.5764 (1.1); 3.5734 (1.2); 3.3418 (1.0); 3.3344 (2.9); 3.3273 (2.9); 3.2984 (0.9); 3.2913 (2.6); 3.2842 (2.5); 2.6055 (0.6); 2.5844 (1.1); 2.5705 (0.8); 2.5631 (0.7);

2.5578 (0.7); 2.5492 (1.2); 2.5366 (1.1); 2.5281 (0.7); 2.5226 (0.8); 2.5155 (0.7); 2.5015 (1.2); 2.4805 (0.6); 1.9951 (0.6); 1.9846 (1.1); 1.9744 (0.6); 1.9599 (0.6); 1.9489 (1.4); 1.9386 (1.6); 1.9281 (0.7); 1.9128 (0.6); 1.9030 (1.2); 1.8929 (1.2); 1.8791 (1.4); 1.8750 (5.5); 1.8672 (5.2); 1.8630 (3.7); 1.8584 (16.0); 1.8536 (3.8); 1.8497 (5.0); 1.8418 (5.2); 1.4320 (1.4); 0.0079 (0.7); -0.0002 (24.0); -0.0085 (0.9) 1-039: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5587 (4.9); 7.5540 (5.5); 7.5478 (5.4); 7.5432 (7.0); 7.5390 (2.0); 7.4776 (0.6); 7.4757 (0.9); 7.4730 (1.0); 7.4688 (1.9); 7.4665 (1.9); 7.4642 (2.7); 7.4619 (2.7); 7.4596 (1.5); 7.4573 (1.3); 7.3753 (0.6);

7.3558 (0.6); 7.2603 (59.9); 6.0122 (0.6); 6.0090 (0.7); 6.0025 (1.0); 5.9988 (1.1); 5.9955 (1.2); 5.9922 (1.2); 5.9888 (1.2); 5.9854 (0.7); 5.9821 (0.7); 5.9789 (0.6); 5.9305 (0.6); 5.9250 (1.1); 5.9194 (0.6);

5.9112 (0.8); 5.8680 (0.8); 5.8623 (1.2); 5.8566 (0.7); 5.8542 (0.8); 5.8485 (1.0); 5.2987 (4.2); 5.0758 (0.6); 5.0646 (0.6); 3.9987 (1.6); 3.9536 (2.3); 3.7610 (16.0); 3.7573 (3.3); 3.7526 (1.6); 3.7494 (2.7); 3.7424 (14.8); 3.7176 (0.7); 3.7121 (1.7); 3.7056 (4.1); 3.6955 (3.4); 3.5556 (0.6); 3.5510 (0.7); 3.5444 (0.7); 3.5394 (0.7); 2.5348 (0.8); 2.5204 (0.6); 2.4995 (0.9); 2.4677 (0.8); 2.4533 (0.5); 2.4325 (0.9);

2.0053 (0.8); 1.9705 (0.9); 1.9640 (1.0); 1.9567 (0.5); 1.9290 (0.7); 1.5473 (11.1); 1.2588 (0.7); 0.8817 (0.7); 0.0079 (0.7); -0.0002 (21.9); -0.0085 (0.8)

1-040: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5569 (10.4); 7.5522 (12.0); 7.5472 (14.3); 7.5425 (16.0); 7.5196 (0.5); 7.4809 (1.1); 7.4786 (1.3); 7.4763 (1.9); 7.4740 (2.1); 7.4695 (4.2); 7.4675 (4.2); 7.4649 (6.0); 7.4629 (6.0); 7.4604 (3.4); 7.4583 (2.9); 7.3103 (1.4); 7.2971 (1.4); 7.2908 (1.5); 7.2750 (1.3); 7.2607 (88.1); 6.9967 (0.5); 6.0483 (0.6);

- 74 044070 .0438 (1.0); 6.0363 (1.5); 6.0299 (1.7); 6.0260 (1.6); 6.0226 (2.5); 6.0192 (2.7); 6.0161 (2.7); 6.0127 (2.5); 6.0089 (1.6); 6.0054 (1.6); 6.0023 (1.5); 5.9989 (1.3); 5.9487 (1.3); 5.9432 (2.3); 5.9376 (1.4);

5.9294 (1.7); 5.9239 (1.0); 5.8915 (0.7); 5.8829 (1.6); 5.8773 (2.8); 5.8716 (1.8); 5.8692 (1.3); 5.8634 (1.9); 5.8578 (1.1); 5.8386 (0.7); 5.8247 (0.6); 5.2988 (4.6); 5.1128 (0.6); 5.0927 (1.4); 5.0741 (1.4);

.0543 (0.5); 4.5688 (1.6); 4.5545 (2.2); 4.5396 (1.8); 4.5293 (0.6); 4.4255 (4.4); 4.4135 (4.0); 4.4116 (5.4); 4.4090 (3.8); 4.4021 (3.1); 4.3975 (6.1); 4.3887 (4.5); 4.3839 (3.7); 4.3738 (3.6); 4.3713 (3.2);

4.3611 (1.8); 4.3565 (1.2); 4.3481 (1.3); 4.3453 (1.8); 4.3341 (1.1); 3.9981 (3.1); 3.9625 (1.3); 3.9529 (4.5); 3.9302 (0.7); 3.8221 (0.5); 3.8159 (0.6); 3.8098 (0.6); 3.7893 (2.1); 3.7830 (0.5); 3.7745 (2.4);

3.7662 (2.5); 3.7603 (6.6); 3.7536 (5.2); 3.7426 (5.4); 3.7310 (3.9); 3.7284 (6.0); 3.7264 (4.6); 3.7222 (7.0); 3.7147 (8.2); 3.7082 (10.3); 3.7012 (2.1); 3.6942 (5.0); 3.6867 (2.2); 3.6774 (1.8); 3.6729 (2.0); 3.6636 (1.3); 3.6179 (1.2); 3.6119 (1.4); 3.6055 (1.6); 3.5980 (1.7); 3.5911 (1.6); 3.5847 (1.4); 3.5790 (1.0); 2.5931 (0.9); 2.5721 (1.7); 2.5576 (1.2); 2.5509 (1.0); 2.5366 (1.9); 2.5233 (1.0); 2.5155 (1.0);

2.5023 (1.7); 2.4879 (1.2); 2.4814 (1.0); 2.4669 (1.9); 2.4459 (1.0); 2.0391 (1.0); 2.0312 (1.7); 2.0232 (1.0); 2.0038 (1.8); 1.9957 (3.3); 1.9877 (1.8); 1.9684 (0.8); 1.9605 (1.8); 1.9523 (0.8); 1.5523 (10.3); 1.2561 (1.4); 0.0080 (1.0); -0.0002 (32.1); -0.0085 (1.2)

1-041: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5559 (2.2); 7.5512 (2.6); 7.5469 (3.3); 7.5423 (3.6); 7.5184 (0.7); 7.4734 (0.8); 7.4707 (1.1); 7.4688 (1.2); 7.4661 (1.5); 7.4616 (0.7); 7.2595 (122.0); 6.9955 (0.7); 6.0110 (0.6); 6.0077 (0.6); 6.0041 (0.6);

5.9032 (0.6); 5.2986 (2.1); 4.5699 (0.6); 4.5490 (1.8); 4.5280 (2.1); 4.5236 (0.8); 4.5062 (0.9); 4.5027 (0.8); 3.9951 (0.6); 3.9499 (0.9); 3.7631 (1.1); 3.7554 (1.3); 3.7425 (0.5); 3.7179 (0.7); 3.7103 (0.9); 1.9923 (0.7); 1.5327 (16.0); 1.2561 (0.9); 0.0080 (1.5); -0.0002 (46.6); -0.0085 (1.8)

1-042: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6939 (2.0); 7.6893 (3.7); 7.6838 (3.3); 7.6782 (4.0); 7.6738 (2.6); 7.5373 (1.4); 7.5340 (2.1); 7.5306 (2.5); 7.5277 (2.3); 7.5238 (1.6); 7.5181 (1.9); 7.5147 (2.7); 7.5114 (3.3); 7.5084 (2.8); 7.5047 (1.9);

7.4646 (1.7); 7.4613 (2.1); 7.4569 (1.9); 7.4509 (0.7); 7.4446 (3.2); 7.4401 (3.6); 7.4369 (2.7); 7.4033 (0.6); 7.3952 (4.8); 7.3843 (1.7); 7.3758 (6.4); 7.3654 (1.5); 7.3559 (3.1); 7.2609 (51.7); 6.0098 (1.1);

.0064 (1.2); 6.0033 (1.2); 5.9996 (2.0); 5.9960 (2.5); 5.9928 (2.6); 5.9895 (2.5); 5.9860 (2.5); 5.9823 ( 1.5); 5.9792 (1.4); 5.9757 (1.3); 5.9240 (1.3); 5.9184 (2.3); 5.9128 (1.4); 5.9104 (1.1); 5.9047 (1.7);

5.8991 (1.0); 5.8551 (1.2); 5.8495 (2.1); 5.8439 (1.4); 5.8415 (1.2); 5.8357 (1.7); 5.8302 (1.0); 5.2986 (13.2); 5.1086 (0.5); 5.0863 (1.4); 5.0658 (1.4); 4.2383 (2.1); 4.2205 (6.8); 4.2152 (2.6); 4.2026 (7.2);

4.1973 (7.2); 4.1848 (2.7); 4.1795 (7.2); 4.1617 (2.6); 4.0181 (3.1); 3.9731 (4.5); 3.7928 (0.6); 3.7853 (4.9); 3.7795 (4.8); 3.7403 (3.5); 3.7345 (3.5); 3.5422 (1.0); 3.5364 (1.3); 3.5299 (1.5); 3.5222 (1.6);

3.5155 (1.6); 3.5091 (1.3); 3.5034 (1.0); 3.0507 (0.7); 3.0070 (0.8); 2.9938 (0.8); 2.5585 (0.9); 2.5375 ( 1.6); 2.5232 (1.1); 2.5164 (1.0); 2.5022 (1.8); 2.4909 (0.9); 2.4811 (1.0); 2.4700 (1.8); 2.4557 (1.1);

- 75 044070

2.4490 (1.0); 2.4348 (2.0); 2.4138 (0.9); 2.0072 (0.9); 1.9994 (1.6); 1.9915 (0.9); 1.9693 (1.3); 1.9613 (2.1); 1.9561 (1.2); 1.9530 (1.1); 1.9340 (0.8); 1.9258 (1.5); 1.9176 (0.8); 1.5628 (6.4); 1.3259 (7.5); 1.3152 (0.7); 1.3080 (15.4); 1.3019 (8.3); 1.2975 (1.5); 1.2901 (7.8); 1.2840 (16.0); 1.2662 (8.0); 1.2523 (1.1); 1.2462 (0.6); 0.8818 (0.6); 0.0080 (1.0); -0.0002 (30.2); -0.0084 (1.2)

1-043: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2607 (21.2); 6.7975 (2.3); 6.7917 (2.7); 6.7890 (2.5); 6.7833 (2.5); 6.5578 (1.0); 6.5524 (1.6); 6.5468 (0.8); 5.9893 (0.6); 5.9857 (0.6); 5.9824 (0.5); 5.9792 (0.5); 5.9138 (0.5); 5.8467 (0.5); 5.2986 (2.7); 4.2346 (0.5); 4.2168 (2.2); 4.1989 (3.4); 4.1811 (2.3); 4.1632 (0.6); 4.0039 (0.8); 3.9589 (1.2); 3.8132 (16.0); 3.8103 (14.3); 3.7824 (1.2); 3.7784 (1.1); 3.7375 (0.8); 3.7334 (0.8); 1.9563 (0.5); 1.5566 (3.4); 1.3239 (1.9); 1.3060 (4.0); 1.3013 (2.0); 1.2881 (2.1); 1.2834 (3.9); 1.2656 (1.9); -0.0002 (8.2) 1-044: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2608 (15.6); 6.7967 (1.9); 6.7910 (2.2); 6.7881 (2.1); 6.7823 (2.7); 6.7789 (1.0); 6.7764 (0.9); 6.5604 (1.0); 6.5545 (1.4); 6.5487 (0.7); 4.4208 (0.8); 4.4068 (1.0); 4.4043 (0.7); 4.3990 (0.5); 4.3924 (1.0); 4.3851 (0.9); 4.3801 (0.7); 4.3703 (0.7); 4.3665 (0.5); 4.0018 (0.5); 3.9568 (0.8); 3.8140 (16.0); 3.8110 (12.3); 3.7930 (0.6); 3.7869 (1.1); 3.7824 (1.0); 3.7740 (0.5); 3.7405 (1.3); 3.7375 (0.8); 3.7259 (1.1); 3.7174 (1.0); 3.7120 (1.0); 3.7032 (1.7); 3.6996 (0.5); 3.6891 (1.2); 1.9887 (0.5); 1.5575 (2.0); 0.0002 (7.8)

1-045: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6925 (2.6); 7.6882 (4.9); 7.6827 (5.1); 7.6772 (6.7); 7.6729 (4.2); 7.5388 (1.8); 7.5352 (2.6); 7.5319 (3.7); 7.5290 (3.6); 7.5252 (2.9); 7.5198 (2.8); 7.5160 (3.4); 7.5128 (4.8); 7.5098 (4.6); 7.5061 (3.6);

7.4773 (0.9); 7.4747 (1.0); 7.4720 (1.1); 7.4656 (2.5); 7.4636 (3.0); 7.4602 (2.9); 7.4546 (1.9); 7.4520 (1.8); 7.4481 (3.7); 7.4463 (4.2); 7.4434 (5.0); 7.4414 (4.1); 7.4071 (1.3); 7.4051 (1.4); 7.3981 (4.6);

7.3855 (1.9); 7.3778 (5.8); 7.3679 (1.0); 7.3587 (2.2); 7.3141 (1.6); 7.3005 (1.6); 7.2612 (92.0); 6.8177 (0.6); 6.0509 (0.6); 6.0449 (0.9); 6.0409 (1.0); 6.0313 (1.9); 6.0261 (2.0); 6.0224 (1.7); 6.0184 (3.1);

6.0149 (3.2); 6.0119 (3.3); 6.0085 (3.0); 6.0043 (1.9); 6.0007 (1.9); 5.9978 (1.8); 5.9943 (1.7); 5.9476 (1.6); 5.9421 (3.0); 5.9365 (1.8); 5.9283 (2.2); 5.9227 (1.2); 5.8994 (0.5); 5.8937 (0.9); 5.8880 (0.6); 5.8800 (2.3); 5.8745 (3.2); 5.8689 (1.8); 5.8666 (1.6); 5.8608 (2.4); 5.8552 (1.3); 5.8401 (0.8); 5.8262 (0.8); 5.2988 (16.0); 5.0928 (1.7); 5.0762 (1.6); 4.5686 (7.3); 4.5542 (9.2); 4.5525 (5.7); 4.5394 (7.9);

4.4247 (5.1); 4.4126 (5.0); 4.4108 (6.4); 4.4082 (4.6); 4.3986 (4.4); 4.3963 (8.3); 4.3853 (5.6); 4.3804 (4.7); 4.3705 (4.2); 4.3675 (3.6); 4.3596 (2.5); 4.3435 (2.4); 4.3315 (1.4); 4.0156 (3.4); 3.9712 (4.9);

3.8990 (1.0); 3.8301 (0.5); 3.8243 (0.5); 3.8204 (0.7); 3.8144 (0.9); 3.8082 (1.0); 3.8022 (1.1); 3.7960 (3.0); 3.7896 (12.2); 3.7844 (7.1); 3.7763 (6.2); 3.7746 (9.5); 3.7601 (7.6); 3.7510 (2.1); 3.7453 (6.4);

3.7431 (7.9); 3.7394 (5.4); 3.7313 (4.5); 3.7287 (7.4); 3.7189 (7.0); 3.7148 (6.9); 3.7093 (1.9); 3.7046 (9.1); 3.7005 (3.4); 3.6906 (7.0); 3.6863 (2.6); 3.6754 (2.3); 3.6724 (2.3); 3.6616 (1.8); 3.6156 (1.2); 3.6091 (1.6); 3.6025 (2.0); 3.5952 (2.1); 3.5879 (2.1); 3.5814 (1.7); 3.5752 (1.2); 2.6016 (1.1); 2.5806 (2.1); 2.5662 (1.4); 2.5594 (1.2); 2.5451 (2.3); 2.5326 (1.2); 2.5240 (1.3); 2.5117 (2.1); 2.4973 (1.4);

- 76 044070

2.4906 (1.3); 2.4763 (2.4); 2.4553 (1.2); 2.0392 (1.2); 2.0309 (2.1); 2.0226 (1.2); 2.0025 (1.8); 1.9944 (3.3); 1.9865 (2.1); 1.9756 (0.5); 1.9663 (1.1); 1.9583 (1.9); 1.9501 (1.2); 1.5628 (2.2); 0.0079 (1.3); 0.0002 (47.8); -0.0085 (1.9)

1-046: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6948 (1.1); 7.6902 (1.9); 7.6830 (1.5); 7.6785 (2.5); 7.6743 (1.8); 7.5399 (0.7); 7.5367 (1.0); 7.5328 (1.4); 7.5293 (1.3); 7.5256 (1.1); 7.5207 (1.2); 7.5175 (1.4); 7.5136 (1.7); 7.5102 (1.6); 7.5065 (1.3);

7.4648 (1.0); 7.4625 (1.2); 7.4592 (1.2); 7.4536 (0.8); 7.4508 (0.8); 7.4471 (1.5); 7.4451 (1.7); 7.4423 (2.0); 7.4401 (1.6); 7.4037 (0.8); 7.3971 (2.1); 7.3839 (1.3); 7.3780 (2.7); 7.3588 (1.2); 7.2612 (33.5);

6.0098 (0.8); 6.0058 (0.8); 6.0033 (0.8); 5.9993 (1.2); 5.9956 (1.3); 5.9923 (1.3); 5.9890 (1.3); 5.9855 (1.3); 5.9818 (0.8); 5.9787 (0.7); 5.9753 (0.6); 5.9295 (0.6); 5.9239 (1.2); 5.9183 (0.7); 5.9101 (0.8);

5.8652 (0.8); 5.8597 (1.2); 5.8541 (0.7); 5.8515 (0.7); 5.8459 (0.9); 5.8404 (0.5); 5.2987 (1.2); 5.0765 (0.7); 4.0167 (1.8); 3.9717 (2.6); 3.7952 (1.0); 3.7929 (1.1); 3.7878 (2.6); 3.7807 (2.6); 3.7604 (16.0);

3.7531 (1.4); 3.7499 (1.7); 3.7398 (15.8); 3.7359 (2.6); 3.7048 (3.7); 3.6932 (3.7); 3.5533 (0.7); 3.5501 (0.7); 3.5423 (0.8); 3.5356 (0.8); 2.5445 (0.8); 2.5301 (0.6); 2.5235 (0.5); 2.5092 (1.0); 2.5001 (0.5);

2.4882 (0.5); 2.4792 (0.9); 2.4649 (0.6); 2.4584 (0.5); 2.4441 (1.0); 2.0134 (0.5); 2.0054 (0.9); 1.9701 (1.2); 1.9618 (1.4); 1.9266 (0.9); 1.5661 (0.6); 0.0079 (0.6); -0.0002 (16.9); -0.0085 (0.6)

1-047: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2610 (13.0); 6.7980 (1.8); 6.7923 (2.2); 6.7895 (2.0); 6.7837 (2.6); 6.7780 (1.0); 6.7757 (0.9);

6.5596 (1.0); 6.5538 (1.4); 6.5482 (0.7); 5.9886 (0.5); 5.9851 (0.5); 5.8570 (0.5); 4.1302 (0.5); 4.1123 (0.5); 4.0016 (0.8); 3.9566 (1.2); 3.8140 (16.0); 3.8108 (12.2); 3.7930 (0.5); 3.7903 (0.5); 3.7841 (1.0);

3.7789 (1.0); 3.7565 (5.5); 3.7488 (0.9); 3.7387 (6.0); 3.7341 (1.0); 3.7036 (1.6); 3.6927 (1.6); 2.5163 (0.5); 2.0430 (2.3); 1.5612 (2.1); 1.2762 (1.1); 1.2650 (1.3); 1.2584 (1.9); 1.2405 (0.7); 0.8986 (0.6); 0.8818 (1.9); 0.8641 (0.8); -0.0002 (7.3)

1-048: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7131 (2.4); 7.6571 (1.8); 7.5349 (2.8); 7.3893 (0.7); 7.3777 (0.6); 7.2609 (36.7); 6.0158 (0.5);

6.0115 (0.9); 6.0079 (0.9); 6.0015 (0.9); 5.9977 (1.2); 5.9943 (1.3); 5.9914 (1.3); 5.9881 (1.2); 5.9816 (0.8); 5.9785 (0.8); 5.9751 (0.7); 5.9321 (0.7); 5.9266 (1.3); 5.9210 (0.8); 5.9129 (0.9); 5.9074 (0.5);

5.8633 (0.7); 5.8578 (1.2); 5.8520 (0.8); 5.8439 (0.9); 5.8384 (0.5); 5.2985 (9.6); 5.0744 (0.7); 4.0586 (2.0); 4.0135 (2.8); 3.8251 (1.2); 3.8194 (2.6); 3.8124 (2.4); 3.7811 (1.0); 3.7744 (2.1); 3.7669 (2.7);

3.7623 (16.0); 3.7522 (0.9); 3.7485 (1.3); 3.7390 (15.7); 3.7053 (4.0); 3.6926 (4.1); 3.5639 (0.5); 3.5575 (0.7); 3.5510 (0.9); 3.5438 (0.9); 3.5367 (0.9); 3.5305 (0.7); 3.5242 (0.5); 2.5443 (0.9); 2.5299 (0.6);

2.5232 (0.6); 2.5090 (1.0); 2.4967 (0.6); 2.4879 (0.6); 2.4759 (1.3); 2.4602 (13.6); 2.4407 (1.1); 2.4198 (0.5); 2.0091 (0.8); 1.9738 (1.0); 1.9634 (1.1); 1.9545 (0.6); 1.9281 (0.9); 1.9194 (0.5); 1.5598 (4.2); 0.0002 (14.0); -0.0085 (0.5)

1-049: !H-NMR(400.0 MHz, CDC13):

- 77 044070 δ= 7.7147 (2.9); 7.6602 (2.4); 7.5361 (3.5); 7.3228 (0.9); 7.3078 (0.9); 7.2609 (45.6); 6.0428 (0.6);

6.0321 (1.0); 6.0286 (1.1); 6.0248 (0.9); 6.0179 (1.6); 6.0147 (1.7); 6.0115 (1.6); 6.0046 (0.9); 6.0010 (1.0); 5.9980 (0.9); 5.9946 (0.8); 5.9507 (0.8); 5.9451 (1.5); 5.9395 (1.0); 5.9314 (1.2); 5.9258 (0.6);

5.8785 (0.9); 5.8730 (1.4); 5.8672 (0.9); 5.8592 (1.2); 5.8536 (0.7); 5.2986 (2.4); 5.0985 (0.9); 5.0821 (0.9); 4.5687 (0.8); 4.5544 (1.0); 4.5395 (0.8); 4.4264 (2.6); 4.4125 (3.2); 4.4100 (2.2); 4.3981 (4.4);

4.3941 (1.8); 4.3842 (2.9); 4.3795 (2.5); 4.3694 (1.8); 4.3660 (1.7); 4.3596 (1.4); 4.3446 (1.4); 4.3313 (0.8); 4.0579 (2.1); 4.0128 (3.0); 3.8284 (1.6); 3.8223 (3.3); 3.8162 (3.2); 3.7892 (1.1); 3.7832 (1.1);

3.7770 (2.7); 3.7712 (2.3); 3.7601 (0.9); 3.7440 (3.1); 3.7321 (2.2); 3.7297 (3.5); 3.7165 (5.0); 3.7028 (5.0); 3.6888 (4.2); 3.6729 (1.5); 3.6609 (1.0); 3.6179 (0.7); 3.6108 (0.8); 3.6034 (1.1); 3.5970 (1.2);

3.5897 (1.1); 3.5829 (0.9); 3.5761 (0.7); 2.6018 (0.6); 2.5806 (1.0); 2.5662 (0.7); 2.5595 (0.6); 2.5452 (1.2); 2.5298 (0.6); 2.5241 (0.7); 2.5089 (1.1); 2.4945 (0.8); 2.4878 (0.8); 2.4734 (1.7); 2.4599 (16.0);

2.0 436 (0.6); 2.0353 (1.0); 2.0272 (0.6); 2.0080 (0.6); 2.0004 (1.3); 1.9938 (1.4); 1.9858 (0.7); 1.9672 (0.7); 1.9588 (1.0); 1.9503 (0.6); 1.5559 (3.6); 0.0080 (0.6); -0.0002 (17.4); -0.0083 (0.8)

1-050: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7123 (2.4); 7.6612 (2.5); 7.5385 (3.3); 7.2600 (54.8); 7.2220 (1.0); 7.2023 (1.0); 6.0273 (0.7);

6.0 235 (0.9); 6.0209 (0.9); 6.0174 (0.8); 6.0075 (1.7); 5.9982 (1.0); 5.9944 (1.0); 5.9918 (1.0); 5.9882 (0.9); 5.9760 (0.9); 5.9705 (1.6); 5.9650 (0.9); 5.9567 (1.0); 5.9512 (0.6); 5.9047 (0.8); 5.8992 (1.5);

5.8934 (0.9); 5.8854 (1.2); 5.8797 (0.6); 5.2982 (4.1); 5.1033 (0.8); 5.0821 (0.8); 4.5702 (1.3); 4.5493 (3.8); 4.5376 (0.8); 4.5335 (1.0); 4.5284 (4.0); 4.5168 (2.1); 4.5126 (2.1); 4.5075 (1.5); 4.5016 (0.6);

4.4959 (2.1); 4.4918 (2.1); 4.4750 (0.7); 4.4708 (0.7); 4.0517 (1.5); 4.0067 (2.1); 3.8261 (3.0); 3.8183 (2.9); 3.7811 (2.1); 3.7733 (2.1); 3.7635 (0.6); 3.7486 (0.5); 3.7390 (0.5); 3.7052 (0.8); 3.6925 (0.7);

3.6565 (0.9); 3.6506 (1.0); 3.6445 (0.9); 3.6304 (0.5); 2.6576 (0.6); 2.6365 (1.0); 2.6221 (0.7); 2.6154 (0.7); 2.6010 (1.1); 2.5796 (1.1); 2.5584 (1.1); 2.5439 (0.7); 2.5374 (0.6); 2.5230 (1.2); 2.5021 (0.7);

2.4596 (16.0); 2.0410 (0.6); 2.0320 (1.0); 2.0227 (0.6); 2.0028 (0.8); 1.9938 (1.3); 1.9871 (0.8); 1.9672 (0.5); 1.9581 (0.9); 1.9489 (0.5); 1.5450 (3.0); 0.0080 (0.8); -0.0002 (20.4); -0.0084 (0.8)

1-051: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6905 (2.0); 7.6863 (3.3); 7.6813 (3.8); 7.6763 (4.6); 7.6721 (3.1); 7.5396 (1.4); 7.5356 (1.9); 7.5325 (2.2); 7.5308 (2.4); 7.5268 (2.1); 7.5204 (2.1); 7.5183 (2.9); 7.5134 (3.0); 7.5116 (3.2); 7.5075 (2.6);

7.4715 (1.4); 7.4688 (1.9); 7.4665 (2.4); 7.4643 (2.1); 7.4615 (2.0); 7.4513 (2.4); 7.4492 (3.1); 7.4463 (3.8); 7.4442 (3.2); 7.4414 (2.3); 7.3986 (3.6); 7.3977 (3.3); 7.3874 (1.2); 7.3794 (4.5); 7.3785 (4.4);

7.3593 (1.9); 7.2915 (0.5); 7.2701 (1.4); 7.2693 (1.5); 7.2669 (2.2); 7.2660 (2.5); 7.2652 (2.9); 7.2596 (245.8); 7.2515 (4.3); 7.2499 (3.4); 7.2300 (1.3); 7.2227 (1.7); 7.2187 (1.8); 7.1966 (1.5); 6.9956 (1.4);

6.0 242 (1.0); 6.0180 (1.2); 6.0064 (2.4); 5.9999 (2.0); 5.9949 (1.7); 5.9924 (1.7); 5.9887 (1.6); 5.9721 (1.2); 5.9666 (2.1); 5.9610 (1.2); 5.9528 (1.3); 5.9471 (0.8); 5.9057 (1.4); 5.9001 (2.3); 5.8944 (1.4);

5.8920 (1.2); 5.8863 (1.9); 5.8806 (1.1); 5.1003 (1.2); 5.0820 (1.1); 4.5689 (2.2); 4.5480 (6.8); 4.5418 (1.4); 4.5386 (1.3); 4.5271 (7.0); 4.5208 (3.3); 4.5177 (3.2); 4.5062 (2.7); 4.5000 (3.5); 4.4967 (3.2);

- 78 044070

4.4891 (0.9); 4.4792 (1.5); 4.4759 (1.1); 4.4681 (0.8); 4.0130 (2.4); 3.9680 (3.5); 3.7984 (1.1); 3.7930 (4.1); 3.7860 (5.2); 3.7606 (2.8); 3.7480 (3.0); 3.7401 (6.4); 3.7049 (1.3); 3.6933 (0.9); 3.6602 (1.1); 3.6574 (1.3); 3.6547 (1.2); 3.6480 (1.3); 3.6451 (1.3); 3.6424 (1.3); 2.6579 (0.9); 2.6367 (1.5); 2.6223 (1.2); 2.6156 (1.1); 2.6013 (1.7); 2.5835 (0.9); 2.5803 (1.1); 2.5625 (1.4); 2.5481 (1.0); 2.5417 (0.8); 2.5272 (1.6); 2.5063 (0.8); 2.0359 (0.9); 2.0267 (1.5); 2.0175 (1.0); 2.0005 (1.5); 1.9913 (2.6); 1.9822 (1.5); 1.9658 (0.7); 1.9562 (1.2); 1.9469 (0.8); 1.5362 (16.0); 0.0080 (3.0); 0.0056 (1.3); 0.0048 (1.5); 0.0002 (94.5); -0.0066 (2.2); -0.0084 (3.7)

1-052: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2599 (30.1); 6.7955 (2.0); 6.7897 (2.4); 6.7878 (2.8); 6.7821 (2.9); 6.7779 (0.5); 6.5623 (0.8); 6.5606 (0.8); 6.5566 (1.2); 6.5549 (1.4); 6.5510 (0.6); 6.5493 (0.7); 6.0029 (0.6); 5.9999 (0.6); 5.9967 (0.6); 5.9931 (0.6); 5.9622 (0.5); 5.8978 (0.6); 4.5449 (1.4); 4.5240 (1.5); 4.5204 (0.9); 4.5177 (0.8);

4.5030 (0.6); 4.4995 (0.8); 4.4967 (0.7); 3.9969 (0.6); 3.9520 (0.9); 3.8136 (14.8); 3.8109 (16.0); 3.7898 (1.0); 3.7842 (1.2); 3.7448 (0.6); 3.7391 (0.8); 1.5432 (3.4); 1.2647 (0.8); 1.2585 (0.6); 0.8819 (1.4);

0.8642 (0.5); -0.0002 (14.8)

1-053: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3801 (0.6); 7.3717 (0.7); 7.2752 (2.6); 7.2601 (23.2); 7.1038 (1.6); 5.9994 (0.5); 5.9957 (0.6); 5.9930 (0.6); 5.9890 (0.8); 5.9855 (0.9); 5.9821 (0.9); 5.9790 (0.8); 5.9753 (0.8); 5.9712 (0.5); 5.9093 (0.8); 5.8954 (0.6); 5.8317 (0.7); 5.8179 (0.6); 4.2353 (0.8); 4.2174 (2.5); 4.1995 (2.8); 4.1973 (2.6); 4.1868 (0.5); 4.1795 (2.4); 4.1616 (0.8); 4.0116 (1.0); 3.9666 (1.5); 3.7988 (1.4); 3.7941 (1.4); 3.7539 (1.0); 3.7491 (1.0); 3.5265 (0.5); 3.5201 (0.6); 3.5149 (0.6); 3.5107 (0.6); 3.5079 (0.6); 2.5467 (0.5); 2.5113 (0.6); 2.4852 (0.7); 2.4498 (0.6); 2.4030 (1.8); 2.3719 (1.8); 2.3510 (0.9); 2.3382 (16.0); 2.3058 (1.6); 1.9917 (0.5); 1.9564 (0.5); 1.9483 (0.6); 1.9394 (0.6); 1.5716 (0.8); 1.3252 (2.5); 1.3207 (0.8); 1.3073 (5.2); 1.3027 (1.9); 1.3004 (3.0); 1.2895 (3.0); 1.2869 (1.9); 1.2826 (5.6); 1.2685 (1.6); 1.2647 (3.5); 1.2504 (0.6); 0.8818 (1.5); 0.8641 (0.6); -0.0002 (12.6); -0.0085 (0.6)

1-054: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2601 (37.2); 7.1795 (1.7); 7.1741 (2.1); 7.1708 (1.4); 7.1597 (2.0); 7.1543 (1.5); 6.9115 (0.7); 6.8955 (0.8); 6.8898 (1.3); 6.8841 (0.7); 6.8681 (0.6); 6.7323 (0.6); 6.7124 (0.6); 6.1937 (1.2); 6.1669 (1.3); 6.1505 (1.4); 6.1237 (1.5); 5.9849 (0.7); 5.9804 (1.0); 5.9746 (0.8); 5.9711 (1.0); 5.9664 (1.3);

5.9608 (0.9); 5.8516 (0.8); 5.8460 (1.5); 5.8400 (1.0); 5.8321 (1.2); 5.8265 (0.6); 5.5480 (2.6); 5.5049 (2.3); 5.3506 (2.4); 5.3238 (2.2); 5.1148 (0.6); 5.1099 (0.6); 5.1043 (0.6); 5.0990 (0.6); 3.9487 (2.3);

3.9056 (2.6); 3.7469 (0.6); 3.7418 (1.4); 3.7349 (1.8); 3.7295 (0.7); 3.7250 (0.7); 3.7191 (0.7); 3.7131 (0.7); 3.7071 (0.5); 3.6954 (0.7); 3.6844 (16.0); 3.3319 (2.6); 3.2887 (2.2); 2.6854 (0.6); 2.6734 (0.6); 2.6648 (0.6); 2.6523 (0.8); 2.6382 (0.7); 2.6297 (0.6); 2.6176 (0.6); 1.8654 (0.7); 1.8543 (0.7); 1.8434 (0.7); 1.8316 (1.0); 1.8191 (0.7); 1.8083 (0.7); 1.7971 (0.7); 0.0079 (0.9); -0.0002 (22.2); -0.0085 (0.8) 1-055: ¹ H-NMR(400.0 MHz, CDC13):

- 79 044070 δ= 7.3926 (0.6); 7.3835 (0.6); 7.3733 (0.6); 7.2781 (2.3); 7.2764 (2.4); 7.2724 (2.6); 7.2636 (12.0); 7.1090 (1.5); 6.0013 (0.6); 5.9974 (0.7); 5.9949 (0.7); 5.9904 (0.8); 5.9873 (0.8); 5.9838 (0.8); 5.9809 (0.7); 5.9775 (0.6); 5.9173 (0.7); 5.8447 (0.6); 5.3018 (2.6); 5.0733 (0.5); 4.0117 (1.0); 3.9667 (1.5); 3.8140 (0.6); 3.8115 (0.6); 3.8063 (1.2); 3.8003 (1.2); 3.7595 (8.2); 3.7557 (3.0); 3.7476 (1.2); 3.7408 (7.8); 3.7100 (0.6); 3.7040 (2.3); 3.6920 (2.1); 3.5453 (0.5); 3.5430 (0.5); 3.5371 (0.5); 2.5167 (0.5); 2.4919 (0.6); 2.4043 (1.7); 2.3738 (1.7); 2.3412 (16.0); 2.3093 (1.4); 1.9419 (0.5); 1.6041 (2.0); -0.0002 (6.5) 1-056: 'H-NMR(400.0 MHz, CDC13):

δ= 7.3434 (0.6); 7.3210 (0.6); 7.2717 (2.9); 7.2630 (18.1); 7.1096 (1.5); 6.0234 (0.6); 6.0173 (0.7); 6.0134 (0.6); 6.0064 (0.8); 6.0037 (0.8); 5.9354 (0.7); 5.9216 (0.5); 5.8596 (0.7); 5.8458 (0.5); 5.3019 (4.6); 4.4228 (1.0); 4.4089 (1.5); 4.3981 (1.2); 4.3954 (2.1); 4.3848 (1.5); 4.3807 (1.4); 4.3699 (1.1);

4.3676 (0.9); 4.3588 (0.7); 4.3434 (0.7); 4.0121 (0.8); 3.9671 (1.3); 3.8141 (0.7); 3.8082 (1.5); 3.8036 (1.4); 3.7634 (1.0); 3.7585 (0.9); 3.7468 (1.5); 3.7425 (0.5); 3.7324 (1.9); 3.7293 (1.2); 3.7205 (1.9);

3.7186 (1.8); 3.7146 (0.9); 3.7062 (2.2); 3.7031 (1.0); 3.6922 (2.0); 3.6776 (0.7); 3.6753 (0.6); 3.5979 (0.5); 3.5914 (0.6); 2.5508 (0.5); 2.5220 (0.5); 2.4867 (0.5); 2.4045 (1.7); 2.3735 (1.6); 2.3412 (16.0);

2.3093 (1.4); 1.9820 (0.6); 1.9731 (0.6); 1.5854 (2.7); -0.0002 (10.3)

1-057: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2761 (2.6); 7.2729 (2.6); 7.2624 (22.9); 7.2308 (0.5); 7.1120 (1.5); 6.0157 (0.5); 6.0094 (0.6); 6.0055 (0.6); 6.0018 (0.9); 5.9981 (0.9); 5.9956 (0.9); 5.9918 (0.8); 5.9592 (0.8); 5.8844 (0.7); 5.8705 (0.6); 5.3018 (2.6); 4.5675 (0.7); 4.5466 (2.1); 4.5256 (2.2); 4.5172 (1.0); 4.5125 (1.0); 4.5046 (1.0);

4.4962 (1.0); 4.4916 (1.0); 4.0079 (0.7); 3.9635 (1.1); 3.8119 (1.4); 3.8054 (1.3); 3.7670 (1.0); 3.7606 (1.0); 3.6505 (0.5); 3.6451 (0.5); 2.6063 (0.5); 2.5345 (0.5); 2.4044 (1.7); 2.3737 (1.6); 2.3410 (16.0);

2.3082 (1.5); 1.9853 (0.6); 1.9750 (0.6); 1.5716 (3.6); -0.0002 (12.6) 1-058: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3735 (0.6); 7.3508 (0.6); 7.2598 (77.6); 7.2113 (1.2); 7.2055 (1.6); 7.2016 (2.0); 7.1958 (2.4); 7.1920 (2.3); 7.1862 (2.1); 7.1822 (1.7); 7.1765 (1.3); 6.9527 (0.8); 6.9378 (0.9); 6.9320 (1.5); 6.9263 (0.8); 6.9104 (0.7); 6.0140 (0.5); 6.0105 (0.6); 6.0041 (1.0); 6.0004 (1.2); 5.9972 (1.2); 5.9938 (1.2);

5.9904 (1.3); 5.9840 (0.7); 5.9806 (0.6); 5.9262 (0.6); 5.9207 (1.1); 5.9152 (0.7); 5.9070 (0.8); 5.8611 (0.6); 5.8556 (1.0); 5.8501 (0.7); 5.8419 (0.9); 5.0868 (0.7); 5.0655 (0.7); 4.2383 (0.9); 4.2204 (3.0);

4.2170 (1.4); 4.2025 (3.4); 4.1991 (3.7); 4.1846 (1.4); 4.1812 (3.7); 4.1634 (1.4); 3.9961 (1.3); 3.9514 (1.9); 3.7513 (2.4); 3.7454 (2.5); 3.7062 (1.7); 3.7003 (1.7); 3.5317 (0.7); 3.5199 (0.7); 2.5308 (0.8);

2.5165 (0.6); 2.4954 (0.9); 2.4632 (0.8); 2.4488 (0.6); 2.4280 (1.0); 2.0004 (0.8); 1.9734 (0.7); 1.9661 (1.3); 1.9584 (0.8); 1.9315 (0.7); 1.5384 (16.0); 1.3248 (4.2); 1.3069 (9.0); 1.3039 (5.3); 1.2890 (5.6); 1.2860 (9.2); 1.2681 (7.7); 1.2648 (5.3); 1.2540 (1.8); 1.2468 (0.9); 1.2360 (0.6); 0.8989 (2.3); 0.8819 (7.8); 0.8642 (3.0); 0.0080 (1.5); -0.0002 (46.2); -0.0085 (1.7)

1-059: ¹ H-NMR(400.0 MHz, CDC13):

- 80 044070 δ= 7.2615 (42.4); 7.2120 (0.7); 7.2076 (0.8); 7.2022 (0.9); 7.1960 (0.7); 7.1895 (2.1); 7.1837 (2.8);

7.1809 (2.9); 7.1750 (2.6); 7.1702 (3.6); 7.1644 (3.9); 7.1612 (2.8); 7.1552 (2.2); 7.1508 (2.0); 7.1451 (1.6); 6.9133 (0.7); 6.8974 (1.2); 6.8916 (2.2); 6.8858 (1.2); 6.8757 (1.3); 6.8699 (2.3); 6.8642 (1.2);

6.8541 (0.5); 6.8484 (0.8); 5.9750 (0.8); 5.9717 (0.9); 5.9689 (0.9); 5.9654 (0.7); 5.9615 (0.8); 5.9554 (1.4); 5.9515 (1.4); 5.9452 (0.7); 5.9416 (0.7); 5.9377 (0.8); 5.9353 (0.8); 5.9315 (0.7); 5.8945 (0.7);

5.8890 (1.3); 5.8833 (0.8); 5.8809 (0.6); 5.8751 (1.0); 5.8696 (0.5); 5.8067 (0.6); 5.8011 (1.2); 5.7954 (0.8); 5.7931 (0.7); 5.7873 (1.0); 5.7817 (0.6); 5.2991 (4.9); 5.0304 (0.6); 5.0136 (0.8); 5.0094 (0.8);

5.0056 (0.8); 4.2306 (1.2); 4.2128 (3.9); 4.2016 (1.4); 4.1991 (1.7); 4.1949 (4.1); 4.1840 (3.4); 4.1814 (1.9); 4.1771 (1.5); 4.1662 (3.4); 4.1484 (1.1); 3.8676 (2.6); 3.8247 (3.0); 3.8019 (2.2); 3.7977 (2.2);

3.7587 (2.5); 3.7545 (2.6); 3.5274 (0.5); 3.5212 (0.6); 3.5068 (0.9); 3.5039 (0.8); 3.5006 (0.8); 3.2605 (2.7); 3.2177 (2.4); 3.1978 (2.2); 3.1897 (2.2); 3.1545 (2.0); 3.1464 (1.9); 2.5625 (0.5); 2.5414 (1.0);

2.5275 (0.7); 2.5203 (0.6); 2.5061 (1.5); 2.4848 (1.4); 2.4707 (0.6); 2.4635 (0.6); 2.4497 (1.0); 2.4286 (0.5); 1.9706 (0.7); 1.9613 (1.0); 1.9264 (0.8); 1.8867 (0.5); 1.8770 (0.9); 1.8421 (0.8); 1.7874 (16.0);

1.7254 (11.8); 1.7197 (2.1); 1.7114 (12.0); 1.3224 (4.0); 1.3106 (1.7); 1.3046 (8.3); 1.2913 (5.0); 1.2867 (4.5); 1.2734 (8.6); 1.2621 (0.6); 1.2555 (4.2); 1.2444 (0.6); 0.0079 (0.8); -0.0002 (24.4); -0.0085 (1.0) 1-060: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2599 (26.2); 7.1845 (0.5); 7.1789 (0.8); 7.1763 (1.0); 7.1706 (0.9); 7.1680 (0.8); 7.1649 (0.8);

7.1593 (1.0); 7.1567 (0.9); 7.1510 (0.6); 6.8722 (0.8); 6.1992 (0.8); 6.1724 (0.8); 6.1561 (0.9); 6.1293 (0.9); 5.9349 (0.5); 5.9296 (0.5); 5.5667 (0.7); 5.5465 (0.9); 5.5237 (0.6); 5.5034 (0.8); 5.3483 (0.8);

5.3333 (0.7); 5.3215 (0.8); 5.3064 (0.6); 3.9383 (1.2); 3.8954 (1.4); 3.3238 (0.8); 3.3179 (0.8); 3.2808 (0.8); 3.2749 (0.7); 2.4630 (0.6); 1.4739 (16.0); 1.4510 (15.7); 1.4374 (3.1); 1.4265 (2.9); 1.2586 (0.5);

0.8818 (0.6); 0.0079 (0.5); -0.0002 (15.2); -0.0082 (0.8)

1-061: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5184 (0.6); 7.2596 (96.0); 7.1889 (0.7); 7.1832 (0.8); 7.1802 (1.1); 7.1744 (1.2); 7.1694 (1.1);

7.1634 (1.1); 7.1605 (1.0); 7.1549 (0.8); 6.9955 (0.5); 6.8780 (0.7); 6.2037 (0.5); 6.2001 (0.5); 6.1769 (0.6); 6.1734 (0.6); 6.1606 (0.6); 6.1570 (0.6); 6.1338 (0.6); 6.1302 (0.6); 5.9764 (0.6); 5.9724 (0.6);

5.9661 (0.6); 5.8974 (0.6); 5.8472 (0.6); 5.5706 (0.8); 5.5510 (1.2); 5.5288 (0.7); 5.5078 (1.0); 5.3567 (0.9); 5.3416 (0.8); 5.3299 (0.9); 5.3140 (0.7); 4.5687 (2.2); 4.5543 (2.8); 4.5395 (2.4); 4.4164 (0.6);

4.4092 (0.6); 4.4024 (1.0); 4.3957 (1.6); 4.3878 (0.7); 4.3815 (1.5); 4.3678 (1.1); 3.9388 (1.9); 3.8958 (2.1); 3.7889 (2.4); 3.7741 (2.8); 3.7597 (2.2); 3.7417 (1.0); 3.7275 (2.2); 3.7251 (1.6); 3.7129 (1.6);

3.7108 (1.5); 3.6967 (1.2); 3.3287 (1.1); 3.3250 (1.0); 3.2856 (1.0); 3.2820 (0.9); 1.9347 (0.6); 1.5335 (16.0); 0.0079 (1.9); -0.0002 (56.5); -0.0084 (2.1)

1-062: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2600 (36.4); 7.2027 (1.4); 7.1970 (1.7); 7.1939 (1.2); 7.1866 (1.0); 7.1835 (1.7); 7.1778 (1.5);

6.9680 (0.6); 6.9522 (0.7); 6.9464 (1.2); 6.9406 (0.6); 6.9249 (0.6); 6.0291 (0.7); 6.0248 (0.8); 6.0229 (0.8); 6.0186 (0.7); 6.0152 (0.8); 6.0108 (1.0); 6.0090 (1.0); 6.0047 (0.8); 5.8752 (0.7); 5.8695 (1.4);

- 81 044070

5.8637 (0.8); 5.8614 (0.7); 5.8556 (1.2); 5.8498 (0.7); 5.2983 (2.6); 4.0055 (0.9); 3.9601 (1.3); 3.7791 (0.6); 3.7724 (0.6); 3.7664 (0.7); 3.7615 (2.9); 3.7547 (0.7); 3.7505 (0.6); 3.7446 (0.7); 3.7408 (0.7);

3.7387 (0.7); 3.7164 (1.8); 3.6951 (16.0); 3.0530 (0.5); 2.7231 (0.6); 2.7113 (0.6); 2.7024 (0.6); 2.6905 (0.7); 2.6879 (0.8); 2.6760 (0.7); 2.6671 (0.6); 2.6553 (0.6); 1.8975 (0.6); 1.8861 (0.6); 1.8755 (0.6);

1.8639 (0.7); 1.8624 (0.7); 1.8508 (0.6); 1.8402 (0.5); 1.8288 (0.5); 1.5437 (3.8); 0.0079 (0.6); -0.0002 (19.7); -0.0085 (0.8)

1-063: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3723 (0.6); 7.3531 (0.5); 7.2598 (81.9); 7.2132 (1.3); 7.2075 (1.6); 7.2028 (2.2); 7.1969 (2.9);

7.1939 (3.0); 7.1880 (2.2); 7.1834 (2.3); 7.1809 (1.9); 7.1777 (2.0); 6.9615 (0.5); 6.9593 (0.6); 6.9556 (0.7); 6.9534 (0.8); 6.9497 (0.8); 6.9465 (0.8); 6.9439 (0.7); 6.9399 (1.0); 6.9378 (1.0); 6.9340 (1.3);

6.9319 (1.3); 6.9282 (0.9); 6.9261 (0.8); 6.9162 (0.5); 6.9124 (0.6); 6.9104 (0.6); 6.0096 (0.7); 6.0038 (1.0); 5.9999 (1.0); 5.9966 (1.1); 5.9933 (1.0); 5.9898 (1.1); 5.9835 (0.6); 5.9801 (0.6); 5.9313 (0.6);

5.9258 (1.0); 5.9203 (0.6); 5.9120 (0.7); 5.8700 (0.8); 5.8650 (1.1); 5.8596 (0.7); 5.8562 (0.7); 5.8512 (0.8); 5.0806 (0.6); 5.0658 (0.6); 3.9944 (1.6); 3.9494 (2.2); 3.7640 (3.0); 3.7601 (16.0); 3.7529 (3.8);

3.7461 (2.8); 3.7409 (15.0); 3.7141 (1.0); 3.7082 (2.3); 3.7059 (5.2); 3.7012 (1.9); 3.6952 (5.0); 3.5537 (0.6); 3.5451 (0.6); 2.5382 (0.7); 2.5238 (0.5); 2.5172 (0.5); 2.5028 (0.9); 2.4730 (0.9); 2.4586 (0.5);

2.4378 (1.0); 2.0062 (0.7); 1.9754 (0.6); 1.9676 (0.9); 1.9592 (0.6); 1.9323 (0.7); 1.9239 (0.5); 1.5384 (11.8); 0.0079 (1.4); -0.0002 (47.0); -0.0085 (1.7)

1-064: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5191 (0.5); 7.3604 (0.9); 7.3398 (1.0); 7.2602 (91.3); 7.2118 (1.8); 7.2060 (2.5); 7.2023 (3.7);

7.1965 (4.4); 7.1925 (3.9); 7.1866 (3.6); 7.1829 (3.3); 7.1773 (2.7); 6.9961 (0.6); 6.9581 (0.9); 6.9519 (1.7); 6.9460 (1.4); 6.9364 (1.5); 6.9304 (2.6); 6.9246 (1.5); 6.9149 (0.8); 6.9089 (1.2); 6.9032 (0.6);

6.0233 (0.7); 6.0190 (0.8); 6.0172 (0.8); 6.0130 (0.7); 6.0052 (0.5); 6.0034 (0.5); 5.9990 (1.0); 5.9955 (0.8); 5.9894 (1.3); 5.9822 (1.5); 5.9790 (1.5); 5.9757 (1.6); 5.9696 (0.9); 5.9663 (0.8); 5.9183 (0.9);

5.9128 (1.6); 5.9072 (1.0); 5.9048 (0.7); 5.8991 (1.1); 5.8935 (0.6); 5.8569 (0.7); 5.8494 (1.1); 5.8437 (1.7); 5.8380 (1.1); 5.8302 (1.2); 5.8248 (0.7); 5.8061 (0.6); 5.7922 (0.6); 5.1150 (0.6); 5.0996 (0.9);

5.0841 (2.0); 5.0684 (2.8); 5.0530 (3.0); 5.0374 (2.8); 5.0217 (2.0); 5.0061 (1.2); 4.9930 (0.8); 4.9903 (0.7); 4.0020 (1.8); 3.9967 (1.4); 3.9568 (2.7); 3.9517 (2.0); 3.7602 (2.0); 3.7515 (3.5); 3.7467 (3.3);

3.7153 (1.7); 3.7102 (1.0); 3.7064 (2.7); 3.7016 (2.5); 3.5038 (0.9); 3.4971 (1.0); 3.4950 (0.9); 3.4888 (1.0); 3.4824 (1.0); 2.7020 (0.5); 2.5395 (0.6); 2.5185 (1.1); 2.5042 (0.8); 2.4973 (0.7); 2.4831 (1.2);

2.4681 (0.7); 2.4620 (0.7); 2.4472 (1.2); 2.4328 (0.8); 2.4262 (0.7); 2.4119 (1.4); 2.3911 (0.6); 1.9896 (0.6); 1.9822 (1.1); 1.9745 (0.6); 1.9655 (0.7); 1.9576 (1.3); 1.9468 (1.1); 1.9392 (0.6); 1.9303 (0.6);

1.9224 (1.2); 1.9148 (0.6); 1.5444 (12.0); 1.2918 (7.8); 1.2806 (8.7); 1.2761 (8.8); 1.2678 (10.3); 1.2648 (16.0); 1.2523 (9.0); 1.2488 (9.0); 1.2419 (3.6); 1.2340 (3.7); 1.2304 (5.9); 1.2263 (3.4); 1.2184 (3.2);

1.2151 (3.1); 0.0080 (1.7); -0.0002 (54.0); -0.0085 (1.8)

- 82 044070

1-065: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5178 (1.0); 7.3767 (5.3); 7.3714 (12.5); 7.3651 (5.3); 7.3633 (5.3); 7.3607 (4.1); 7.3532 (9.1); 7.3457 (4.8); 7.3362 (2.7); 7.3318 (2.2); 7.3110 (0.8); 7.3067 (0.7); 7.3033 (0.6); 7.2963 (0.7); 7.2590 (172.3); 7.2113 (1.4); 7.2088 (1.6); 7.2056 (1.7); 7.2022 (2.1); 7.1963 (3.0); 7.1920 (3.0); 7.1864 (2.7); 7.1827 (2.0); 7.1771 (2.3); 7.1714 (1.1); 6.9949 (1.0); 6.9604 (0.6); 6.9551 (1.0); 6.9484 (0.8); 6.9394 (1.1); 6.9335 (1.7); 6.9273 (1.0); 6.9180 (0.6); 6.9117 (0.8); 6.0173 (0.5); 6.0141 (0.6); 6.0110 (0.6); 6.0040 (1.1); 6.0005 (1.2); 5.9974 (1.2); 5.9940 (1.2); 5.9870 (0.7); 5.9843 (0.7); 5.9808 (0.6); 5.9256 (0.6); 5.9201 (1.2); 5.9145 (0.7); 5.9062 (0.9); 5.8623 (0.7); 5.8568 (1.2); 5.8511 (0.7); 5.8430 (0.9); 5.8375 (0.5); 5.1886 (4.1); 5.1858 (4.2); 5.1674 (3.8); 5.1639 (4.0); 5.1363 (1.9); 5.1249 (1.8); 5.0862 (0.7); 5.0638 (0.7); 4.7125 (1.0); 4.7002 (1.0); 3.9918 (1.5); 3.9464 (2.2); 3.7543 (3.5); 3.7471 (2.4); 3.7092 (2.6); 3.7020 (1.7); 3.5793 (0.8); 3.5721 (0.8); 2.5549 (0.8); 2.5405 (0.6); 2.5197 (0.9); 2.4987 (0.5); 2.4834 (0.9); 2.4691 (0.6); 2.4483 (1.0); 2.0171 (0.8); 1.9994 (0.5); 1.9906 (1.1); 1.9821 (1.2); 1.9739 (0.6); 1.9558 (0.8); 1.5332 (16.0); 1.2558 (0.6); 0.0080 (3.1); -0.0002 (100.0); -0.0085 (3.5) 1-067: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5186 (1.2); 7.3100 (1.1); 7.3003 (1.2); 7.2597 (215.7); 7.2232 (0.8); 7.2114 (2.5); 7.2057 (3.2); 7.2021 (4.4); 7.1963 (5.1); 7.1923 (4.8); 7.1864 (4.5); 7.1827 (4.0); 7.1771 (3.1); 7.1648 (0.5); 6.9957 (1.2); 6.9610 (0.9); 6.9550 (1.4); 6.9511 (1.2); 6.9478 (1.2); 6.9412 (1.8); 6.9393 (1.9); 6.9354 (2.5); 6.9335 (2.5); 6.9296 (1.6); 6.9196 (1.1); 6.9137 (1.2); 6.9080 (0.6); 6.0587 (0.5); 6.0495 (0.7); 6.0448 (1.0); 6.0368 (1.4); 6.0304 (1.5); 6.0235 (2.0); 6.0199 (2.1); 6.0170 (2.1); 6.0135 (2.0); 6.0066 (1.2); 6.0039 (1.1); 6.0004 (1.0); 5.9493 (1.1); 5.9438 (2.0); 5.9381 (1.2); 5.9300 (1.6); 5.9245 (0.9); 5.8987 (0.6); 5.8928 (0.9); 5.8853 (1.4); 5.8796 (2.4); 5.8739 (1.4); 5.8661 (1.6); 5.8605 (0.9); 5.8417 (0.8); 5.8356 (0.5); 5.8277 (0.7); 5.0944 (1.1); 5.0773 (1.1); 4.5687 (1.1); 4.5543 (1.4); 4.5394 (1.2); 4.4252 (3.6); 4.4133 (3.2); 4.4113 (4.3); 4.4086 (3.1); 4.4031 (2.4); 4.3992 (2.9); 4.3971 (4.7); 4.3895 (3.8); 4.3844 (3.0); 4.3746 (2.9); 4.3716 (2.7); 4.3613 (2.2); 4.3453 (2.2); 4.3340 (1.3); 3.9944 (2.2); 3.9495 (3.2); 3.8224 (0.5); 3.8163 (0.6); 3.8110 (0.6); 3.7890 (1.6); 3.7741 (1.6); 3.7625 (2.5); 3.7598 (2.1); 3.7560 (4.4); 3.7500 (4.3); 3.7416 (4.7); 3.7300 (3.2); 3.7274 (5.0); 3.7254 (3.6); 3.7211 (5.3); 3.7182 (2.7); 3.7134 (5.3); 3.7110 (4.5); 3.7068 (7.5); 3.7010 (2.4); 3.6930 (4.6); 3.6866 (2.3); 3.6769 (2.0); 3.6727 (2.0); 3.6631 (1.5); 3.6067 (1.2); 3.5989 (1.3); 3.5919 (1.3); 2.5966 (0.8); 2.5756 (1.4); 2.5611 (0.9); 2.5545 (0.8); 2.5401 (1.5); 2.5293 (0.8); 2.5189 (0.8); 2.5084 (1.5); 2.4941 (1.0); 2.4875 (0.8); 2.4731 (1.6); 2.4521 (0.8); 2.0396 (0.8); 2.0315 (1.3); 2.0236 (0.7); 2.0045 (1.0); 1.9982 (2.0); 1.9907 (1.2); 1.9721 (1.0); 1.9632 (1.5); 1.9551 (0.9); 1.9266 (0.7); 1.5359 (16.0); 1.2555 (2.1); 0.0080 (4.0); 0.0002 (125.2);-0.0085 (4.5)

1-068: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5185 (2.3); 7.2964 (1.3); 7.2596 (414.7); 7.2262 (0.9); 7.2105 (4.8); 7.2048 (6.5); 7.2022 (8.9); 7.1965 (9.8); 7.1916 (8.1); 7.1858 (8.2); 7.1830 (8.2); 7.1774 (7.3); 6.9956 (2.3); 6.9636 (1.6); 6.9577 (2.4); 6.9521 (1.5); 6.9440 (2.5); 6.9419 (3.1); 6.9383 (3.9); 6.9362 (4.7); 6.9325 (2.4); 6.9304 (2.5);

- 83 044070

6.9203 (1.8); 6.9146 (2.4); 6.9088 (1.2); 6.0293 (1.5); 6.0256 (1.6); 6.0186 (3.0); 6.0150 (3.8); 6.0119 (4.1); 6.0087 (3.9); 6.0051 (4.1); 6.0008 (2.8); 5.9981 (2.6); 5.9945 (2.4); 5.9748 (2.0); 5.9693 (3.4);

5.9638 (2.0); 5.9555 (2.1); 5.9499 (1.3); 5.9248 (0.6); 5.9116 (2.5); 5.9060 (4.5); 5.9005 (2.7); 5.8923 (3.4); 5.8866 (1.9); 5.1034 (2.1); 5.0810 (1.9); 4.5694 (3.8); 4.5485 (11.8); 4.5427 (2.2); 4.5276 (12.6);

4.5217 (5.2); 4.5066 (5.0); 4.5046 (5.4); 4.5008 (5.1); 4.4907 (0.8); 4.4837 (1.7); 4.4799 (1.9); 4.4697 (0.9); 3.9907 (4.6); 3.9456 (6.4); 3.7658 (1.3); 3.7597 (6.6); 3.7528 (8.9); 3.7146 (4.8); 3.7077 (6.5);

3.6648 (2.2); 3.6486 (2.3); 2.6534 (1.6); 2.6323 (3.0); 2.6178 (2.1); 2.6112 (1.9); 2.5967 (3.3); 2.5808 (1.3); 2.5755 (1.8); 2.5598 (2.4); 2.5454 (1.6); 2.5389 (1.4); 2.5244 (2.5); 2.5036 (1.3); 2.0370 (1.6);

2.0283 (3.0); 2.0193 (1.7); 2.0057 (1.7); 2.0015 (2.0); 1.9964 (3.0); 1.9928 (3.4); 1.9839 (2.0); 1.9701 (1.7); 1.9611 (2.8); 1.9526 (2.0); 1.9171 (1.1); 1.8074 (0.7); 1.7140 (1.2); 1.6798 (1.3); 1.6152 (0.8);

1.5840 (0.7); 1.5368 (16.0); 1.3686 (1.3); 1.3345 (1.4); 1.3057 (0.9); 1.2845 (0.9); 1.2553 (2.1); 1.1972 (0.7); 1.1672 (0.7); 1.1441 (0.9); 1.1354 (1.0); 1.1056 (1.2); 1.0857 (0.9); 0.1459 (0.9); 0.0366 (0.6);

0.0080 (7.3); -0.0002 (237.9); -0.0085 (8.5); -0.1498 (0.8)

1-069: Ή-ΉΜΡ(400.0 MHz, CDC13):

δ= 7.9525 (1.4); 7.9494 (2.4); 7.9484 (2.5); 7.9454 (1.6); 7.9443 (1.5); 7.9383 (1.6); 7.9353 (2.5); 7.9343 (2.5); 7.9313 (1.6); 7.8692 (1.1); 7.8660 (1.3); 7.8618 (2.0); 7.8586 (1.4); 7.8543 (1.1); 7.8493 (1.3);

7.8462 (1.5); 7.8451 (1.5); 7.8419 (2.2); 7.8388 (1.5); 7.8376 (1.5); 7.8345 (1.2); 7.7082 (2.1); 7.7040 (1.3); 7.6930 (1.5); 7.6889 (2.6); 7.6848 (1.4); 7.5521 (2.5); 7.5325 (4.0); 7.5128 (1.8); 7.2623 (46.2);

7.2059 (0.6); 7.1845 (1.1); 7.1608 (0.6); 5.9776 (0.8); 5.9739 (0.8); 5.9714 (0.9); 5.9676 (0.8); 5.9638 (1.1); 5.9600 (1.2); 5.9571 (1.4); 5.9538 (1.4); 5.9494 (1.0); 5.9455 (0.9); 5.9419 (1.0); 5.9381 (1.0);

5.9356 (1.0); 5.9318 (0.9); 5.8975 (1.0); 5.8920 (1.8); 5.8864 (1.0); 5.8838 (0.8); 5.8782 (1.3); 5.8726 (0.7); 5.8045 (0.9); 5.7988 (1.7); 5.7931 (1.0); 5.7908 (0.9); 5.7850 (1.4); 5.7794 (0.8); 5.0362 (0.5);

5.0298 (0.6); 5.0264 (0.7); 5.0140 (1.0); 5.0088 (1.0); 4.9966 (0.7); 4.9933 (0.6); 4.9903 (0.5); 4.2331 (1.7); 4.2152 (5.4); 4.2006 (2.0); 4.1974 (5.6); 4.1829 (5.0); 4.1796 (2.2); 4.1651 (5.0); 4.1472 (1.7);

3.8541 (2.9); 3.8479 (3.0); 3.8110 (3.3); 3.8047 (3.4); 3.5296 (0.5); 3.5265 (0.5); 3.5235 (0.6); 3.5203 (0.6); 3.5172 (0.8); 3.5144 (0.8); 3.5112 (0.9); 3.5082 (1.0); 3.5050 (1.0); 3.5018 (1.1); 3.4987 (0.9);

3.4955 (0.8); 3.4927 (0.8); 3.4898 (0.6); 3.4866 (0.6); 3.4800 (0.5); 3.2313 (3.0); 3.2223 (3.0); 3.1882 (2.7); 3.1791 (2.7); 2.5647 (0.6); 2.5436 (1.2); 2.5298 (0.8); 2.5225 (0.7); 2.5086 (1.3); 2.5010 (0.7);

2.4876 (0.7); 2.4799 (1.3); 2.4661 (0.8); 2.4589 (0.7); 2.4450 (1.4); 2.4239 (0.7); 1.9728 (0.6); 1.9633 (1.2); 1.9537 (0.6); 1.9379 (0.6); 1.9283 (1.0); 1.9188 (0.6); 1.8853 (0.7); 1.8756 (1.2); 1.8660 (0.6);

1.8504 (0.6); 1.8406 (1.0); 1.8309 (0.6); 1.7388 (15.9); 1.7323 (2.5); 1.7250 (16.0); 1.5759 (6.1); 1.3261 (5.8); 1.3082 (12.0); 1.2935 (6.4); 1.2904 (6.2); 1.2757 (12.0); 1.2578 (5.8); 1.2436 (0.6); 0.0079 (0.8); 0.0002 (25.6); -0.0085 (0.9)

1-070: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9617 (1.2); 7.9576 (2.0); 7.9547 (1.3); 7.9414 (0.9); 7.9371 (1.8); 7.9330 (2.4); 7.9289 (1.5); 7.8593 (0.5); 7.8562 (0.6); 7.8453 (2.1); 7.8407 (1.5); 7.8362 (0.7); 7.8298 (1.3); 7.8255 (2.3); 7.7111 (1.1);

- 84 044070

7.7066 (2.0); 7.7047 (1.9); 7.7025 (1.5); 7.6916 (1.3); 7.6875 (2.1); 7.5526 (2.4); 7.5514 (2.4); 7.5442 (0.8); 7.5329 (3.9); 7.5319 (3.8); 7.5191 (0.8); 7.5134 (1.7); 7.5121 (1.7); 7.2602 (111.9); 7.2408 (0.6);

7.2120 (0.7); 7.1883 (0.6); 6.9962 (0.6); 6.0275 (0.7); 6.0239 (0.9); 6.0212 (0.8); 6.0171 (0.9); 6.0137 (1.0); 6.0101 (1.3); 6.0074 (1.1); 6.0036 (1.0); 6.0009 (0.9); 5.9965 (1.0); 5.9906 (0.8); 5.9868 (0.8);

5.9828 (0.9); 5.9806 (0.9); 5.9766 (0.8); 5.9305 (0.8); 5.9248 (1.5); 5.9191 (0.9); 5.9168 (0.7); 5.9110 (1.2); 5.9054 (0.7); 5.8480 (0.8); 5.8423 (1.5); 5.8366 (0.9); 5.8343 (0.8); 5.8285 (1.3); 5.8228 (0.7);

5.2985 (1.4); 5.0059 (0.9); 3.8732 (0.5); 3.8647 (0.6); 3.8510 (2.6); 3.8468 (2.6); 3.8298 (0.6); 3.8214 (0.7); 3.8078 (3.0); 3.8036 (3.0); 3.6061 (0.5); 3.6012 (0.6); 3.5955 (0.8); 3.5918 (0.9); 3.5851 (0.9);

3.5816 (0.8); 3.2472 (0.9); 3.2399 (2.6); 3.2317 (2.5); 3.2033 (0.8); 3.1967 (2.3); 3.1884 (2.2); 2.6029 (1.0); 2.5890 (0.7); 2.5816 (0.6); 2.5677 (1.0); 2.5540 (0.5); 2.5464 (0.5); 2.5328 (1.0); 2.5190 (0.7);

2.5117 (0.6); 2.4978 (1.1); 2.4766 (0.5); 2.0443 (0.9); 2.0263 (0.5); 2.0160 (0.9); 2.0056 (0.6); 1.9808 (0.8); 1.9282 (0.6); 1.9182 (1.0); 1.9081 (0.5); 1.8932 (0.5); 1.8832 (0.8); 1.7359 (16.0); 1.7283 (14.1);

1.2588 (0.6); 0.0079 (2.0); -0.0002 (65.3); -0.0085 (2.3)

1-071: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7474 (2.1); 7.7441 (3.9); 7.7406 (2.7); 7.7365 (2.6); 7.7331 (4.1); 7.7297 (2.4); 7.6671 (1.2); 7.6633 (1.2); 7.6609 (1.4); 7.6566 (2.0); 7.6524 (1.5); 7.6500 (1.6); 7.6456 (2.0); 7.6414 (1.4); 7.6390 (1.5);

7.6347 (2.0); 7.6305 (1.4); 7.6282 (1.5); 7.6244 (1.3); 7.4840 (1.5); 7.4812 (2.1); 7.4783 (2.5); 7.4753 (2.1); 7.4726 (1.6); 7.4650 (1.6); 7.4622 (2.2); 7.4593 (2.4); 7.4562 (1.9); 7.4536 (1.3); 7.3881 (1.3);

7.3670 (1.3); 7.2609 (68.3); 6.0217 (1.0); 6.0185 (1.0); 6.0150 (1.1); 6.0083 (2.1); 6.0052 (2.2); 6.0016 (2.2); 5.9985 (2.2); 5.9920 (1.3); 5.9886 (1.2); 5.9855 (1.1); 5.9322 (1.2); 5.9267 (2.0); 5.9211 (1.3);

5.9129 (1.5); 5.9074 (0.8); 5.8632 (1.2); 5.8578 (1.9); 5.8522 (1.3); 5.8497 (1.1); 5.8440 (1.6); 5.8385 (0.9); 5.1114 (0.5); 5.0879 (1.3); 5.0642 (1.2); 4.2423 (1.2); 4.2402 (1.3); 4.2244 (3.8); 4.2224 (3.9);

4.2173 (2.5); 4.2065 (4.0); 4.2045 (4.1); 4.1994 (6.8); 4.1885 (1.5); 4.1867 (1.6); 4.1816 (6.7); 4.1637 (2.2); 4.0391 (2.8); 3.9941 (3.9); 3.7796 (0.5); 3.7717 (4.1); 3.7645 (4.2); 3.7266 (3.1); 3.7194 (3.2);

3.5512 (1.0); 3.5448 (1.3); 3.5377 (1.4); 3.5307 (1.5); 3.5256 (1.4); 3.5187 (1.3); 3.5124 (1.0); 2.5448 (0.8); 2.5238 (1.5); 2.5094 (1.0); 2.5029 (0.9); 2.4884 (1.7); 2.4703 (1.0); 2.4676 (1.0); 2.4496 (1.5);

2.4352 (1.0); 2.4288 (0.9); 2.4143 (1.7); 2.3936 (0.8); 2.0136 (0.8); 2.0063 (1.5); 1.9993 (0.8); 1.9785 (1.5); 1.9712 (2.8); 1.9640 (1.6); 1.9434 (0.7); 1.9360 (1.4); 1.9288 (0.7); 1.5588 (2.2); 1.3274 (7.2);

1.3195 (0.6); 1.3095 (16.0); 1.2901 (16.0); 1.2722 (7.2); 1.2659 (1.0); 1.2549 (0.8); 0.0080 (1.2); -0.0002 (39.8); -0.0084(1.6)

1-072: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9856 (1.7); 7.9815 (3.0); 7.9785 (2.2); 7.9772 (2.1); 7.9735 (2.2); 7.9704 (3.1); 7.9695 (3.1); 7.9664 (2.0); 7.8935 (1.2); 7.8904 (1.6); 7.8892 (1.5); 7.8858 (2.2); 7.8825 (1.7); 7.8782 (1.5); 7.8736 (1.6);

7.8706 (1.8); 7.8694 (1.8); 7.8659 (2.5); 7.8626 (1.8); 7.8614 (1.8); 7.8583 (1.5); 7.7716 (1.4); 7.7673 (2.4); 7.7631 (1.6); 7.7522 (1.8); 7.7481 (2.9); 7.7438 (1.6); 7.6006 (2.0); 7.5988 (2.6); 7.5792 (4.3);

7.5613 (1.4); 7.5595 (1.9); 7.3909 (1.3); 7.3687 (1.3); 7.3615 (1.1); 7.2608 (81.2); 6.0180 (0.9); 6.0145

- 85 044070 (1.0); 6.0113 (1.0); 6.0047 (1.8); 6.0014 (2.0); 5.9981 (2.0); 5.9949 (1.9); 5.9884 (1.2); 5.9851 (1.2);

5.9819 (1.1); 5.9300 (1.1); 5.9245 (1.9); 5.9189 (1.2); 5.9164 (0.9); 5.9107 (1.4); 5.9052 (0.8); 5.8599 (1.1); 5.8543 (1.9); 5.8487 (1.2); 5.8462 (1.0); 5.8405 (1.5); 5.8350 (0.9); 5.0895 (1.2); 5.0669 (1.2);

4.2422 (1.3); 4.2410 (1.3); 4.2243 (4.1); 4.2232 (4.1); 4.2166 (2.3); 4.2064 (4.4); 4.2054 (4.3); 4.1987 (6.6); 4.1884 (1.7); 4.1809 (6.6); 4.1631 (2.2); 4.0510 (2.6); 4.0060 (3.6); 3.8037 (0.5); 3.7955 (4.1);

3.7891 (4.1); 3.7505 (3.0); 3.7440 (3.1); 3.5485 (0.8); 3.5422 (1.1); 3.5349 (1.3); 3.5281 (1.4); 3.5217 (1.4); 3.5153 (1.2); 3.5094 (0.8); 2.5532 (0.7); 2.5322 (1.4); 2.5179 (1.0); 2.5112 (0.8); 2.4969 (1.6);

2.4801 (0.8); 2.4759 (0.9); 2.4593 (1.5); 2.4449 (1.0); 2.4384 (0.8); 2.4240 (1.6); 2.4032 (0.8); 2.0132 (0.8); 2.0058 (1.4); 1.9983 (0.8); 1.9768 (1.3); 1.9694 (2.2); 1.9618 (1.2); 1.9412 (0.7); 1.9335 (1.2);

1.9257 (0.7); 1.5505 (16.0); 1.3282 (7.0); 1.3103 (14.9); 1.3058 (7.7); 1.2925 (7.6); 1.2880 (14.8); 1.2701 (7.0); 1.2654 (1.1); 1.2533 (0.9); 0.0080 (1.5); -0.0002 (46.3); -0.0085 (1.7)

1-073: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7140 (1.8); 7.7106 (3.2); 7.7071 (2.0); 7.7011 (2.0); 7.6978 (3.3); 7.6943 (1.9); 7.6332 (1.0); 7.6295 (1.0); 7.6270 (1.1); 7.6232 (1.2); 7.6212 (1.2); 7.6174 (1.2); 7.6149 (1.3); 7.6109 (1.8); 7.6070 (1.2);

7.6044 (1.2); 7.6007 (1.2); 7.5987 (1.2); 7.5949 (1.1); 7.5924 (1.1); 7.5888 (1.0); 7.4201 (1.3); 7.4176 (1.6); 7.4145 (1.9); 7.4117 (1.6); 7.4088 (1.2); 7.4010 (1.3); 7.3986 (1.6); 7.3954 (1.8); 7.3925 (1.4);

7.3897 (1.0); 7.2613 (58.4); 7.1898 (0.7); 7.1692 (1.2); 7.1477 (0.7); 5.9811 (0.8); 5.9776 (0.9); 5.9749 (0.9); 5.9711 (0.9); 5.9674 (1.1); 5.9637 (1.3); 5.9605 (1.7); 5.9570 (1.6); 5.9536 (1.0); 5.9498 (0.9);

5.9462 (1.0); 5.9424 (1.1); 5.9397 (1.0); 5.9361 (0.9); 5.8993 (1.0); 5.8937 (1.8); 5.8881 (1.1); 5.8856 (0.8); 5.8800 (1.3); 5.8744 (0.7); 5.8084 (1.0); 5.8027 (1.7); 5.7970 (1.0); 5.7947 (0.9); 5.7889 (1.4);

5.7833 (0.8); 5.0335 (0.5); 5.0305 (0.5); 5.0247 (0.7); 5.0188 (0.8); 5.0127 (1.0); 4.9878 (0.5); 4.9850 (0.5); 4.2331 (1.7); 4.2153 (5.4); 4.2026 (1.7); 4.1974 (5.5); 4.1848 (4.5); 4.1796 (2.0); 4.1669 (4.6);

4.1491 (1.6); 3.8346 (3.0); 3.8287 (2.9); 3.7915 (3.4); 3.7856 (3.3); 3.5319 (0.6); 3.5288 (0.6); 3.5257 (0.6); 3.5194 (0.8); 3.5169 (0.8); 3.5104 (1.2); 3.5075 (1.1); 3.5045 (1.2); 3.4981 (0.8); 3.4956 (0.8);

3.4892 (0.6); 3.4861 (0.6); 3.4833 (0.6); 3.2069 (3.0); 3.1967 (3.0); 3.1637 (2.6); 3.1535 (2.6); 2.5545 (0.6); 2.5335 (1.2); 2.5195 (0.8); 2.5124 (0.7); 2.4985 (1.4); 2.4889 (0.7); 2.4774 (0.7); 2.4678 (1.3);

2.4539 (0.8); 2.4468 (0.7); 2.4329 (1.4); 2.4119 (0.7); 1.9739 (0.7); 1.9648 (1.2); 1.9557 (0.7); 1.9389 (0.6); 1.9298 (1.1); 1.9207 (0.6); 1.8874 (0.8); 1.8782 (1.2); 1.8690 (0.7); 1.8525 (0.6); 1.8432 (1.1);

1.8341 (0.6); 1.7414 (16.0); 1.7335 (2.5); 1.7271 (15.9); 1.5612 (11.6); 1.3255 (5.7); 1.3077 (11.7);

1.2971 (5.8); 1.2898 (5.8); 1.2793 (11.6); 1.2614 (5.8); 1.2455 (0.6); 0.0079 (1.2); -0.0002 (32.4); -0.0085 (1.0)

1-074: !H-NMR(400.0 MHz, CDC13):

δ= 7.8584 (1.9); 7.8548 (3.5); 7.8511 (2.0); 7.8389 (2.0); 7.8353 (3.5); 7.8316 (2.1); 7.8266 (0.6); 7.6330 (0.9); 7.6292 (1.0); 7.6268 (1.1); 7.6230 (1.1); 7.6195 (1.2); 7.6157 (1.3); 7.6131 (1.4); 7.6113 (1.5);

7.6095 (1.5); 7.6076 (1.4); 7.6051 (1.2); 7.6013 (1.1); 7.5978 (1.2); 7.5940 (1.2); 7.5916 (1.2); 7.5879 (1.0); 7.5213 (1.2); 7.5200 (1.2); 7.5179 (1.3); 7.5147 (1.8); 7.5112 (1.8); 7.5082 (1.2); 7.5046 (1.0);

- 86 044070

7.4993 (1.2); 7.4957 (1.3); 7.4926 (1.7); 7.4890 (1.7); 7.4861 (1.0); 7.4825 (0.9); 7.2610 (107.2); 7.2001 (0.8); 7.1836 (1.0); 7.1635 (0.8); 7.1597 (0.6); 6.9970 (0.6); 5.9787 (0.9); 5.9749 (1.1); 5.9723 (1.0);

5.9687 (1.0); 5.9648 (1.2); 5.9611 (1.4); 5.9586 (1.3); 5.9547 (1.4); 5.9524 (1.2); 5.9485 (1.2); 5.9460 (1.1); 5.9421 (1.1); 5.9384 (1.2); 5.9346 (1.3); 5.9321 (1.3); 5.9284 (1.3); 5.8961 (1.7); 5.8904 (2.2);

5.8848 (1.3); 5.8822 (1.1); 5.8765 (1.5); 5.8710 (0.9); 5.8086 (1.1); 5.8029 (2.0); 5.7972 (1.3); 5.7948 (1.1); 5.7891 (1.7); 5.7836 (1.0); 5.0227 (0.9); 5.0138 (1.0); 4.2299 (1.8); 4.2120 (5.7); 4.1942 (7.5);

4.1766 (7.5); 4.1588 (5.8); 4.1409 (2.0); 3.8802 (2.7); 3.8661 (2.8); 3.8370 (3.1); 3.8230 (3.1); 3.5297 (0.6); 3.5204 (0.8); 3.5176 (0.9); 3.5146 (1.0); 3.5034 (1.2); 3.4957 (1.0); 3.4930 (0.9); 3.4834 (0.7);

3.2515 (2.9); 3.2397 (2.8); 3.2083 (2.6); 3.1964 (2.5); 2.5642 (0.7); 2.5431 (1.2); 2.5292 (0.8); 2.5220 (0.8); 2.5082 (1.4); 2.5036 (0.8); 2.4870 (0.8); 2.4824 (1.3); 2.4686 (0.9); 2.4612 (0.8); 2.4474 (1.4);

2.4262 (0.8); 1.9711 (0.7); 1.9630 (3.1); 1.9521 (0.7); 1.9360 (0.6); 1.9266 (1.1); 1.9171 (0.6); 1.8855 (0.8); 1.8759 (1.2); 1.8664 (0.8); 1.8506 (0.6); 1.8409(1.1); 1.8314(0.6); 1.7366 (15.6); 1.7249(16.0); 1.5804 (1.1); 1.3233 (6.2); 1.3162 (0.6); 1.3054 (13.1); 1.2985 (1.0); 1.2903 (8.0); 1.2876 (7.0); 1.2724 (13.4); 1.2592 (1.2); 1.2546 (6.2); 1.2430 (0.8); 0.0079 (2.0); -0.0002 (61.5); -0.0085 (2.2)

1-075: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7247 (1.3); 7.7215 (2.4); 7.7180 (1.7); 7.7129 (1.1); 7.7097 (1.1); 7.7070 (1.2); 7.7004 (1.7); 7.6971 (2.6); 7.6938 (1.7); 7.6208 (1.2); 7.6176 (1.1); 7.6149 (1.2); 7.6110 (1.0); 7.6088 (1.1); 7.6025 (1.5);

7.5986 (1.9); 7.5951 (1.3); 7.5925 (1.2); 7.5885 (1.0); 7.5865 (1.0); 7.5826 (0.9); 7.5803 (0.9); 7.5766 (0.8); 7.4326 (0.5); 7.4297 (0.6); 7.4268 (0.6); 7.4145 (1.8); 7.4119 (2.0); 7.4091 (1.8); 7.3958 (1.5);

7.3929 (1.6); 7.3899 (1.4); 7.2658 (10.1); 7.2373 (1.3); 7.2161 (0.8); 6.0359 (0.7); 6.0331 (0.9); 6.0297 (0.8); 6.0228 (1.2); 6.0192 (1.4); 6.0059 (0.9); 6.0030 (1.0); 5.9998 (1.0); 5.9963 (0.8); 5.9926 (0.8);

5.9887 (0.9); 5.9863 (0.9); 5.9826 (0.8); 5.9404 (0.7); 5.9349 (1.3); 5.9291 (0.8); 5.9211 (1.0); 5.9155 (0.6); 5.8562 (0.7); 5.8506 (1.3); 5.8447 (0.8); 5.8368 (1.1); 5.8309 (0.8); 5.8242 (0.5); 5.0206 (0.8);

5.0121 (0.8); 4.1507 (1.1); 4.1328 (3.4); 4.1150 (3.4); 4.0971 (1.2); 3.8717 (0.6); 3.8596 (0.6); 3.8397 (3.6); 3.8281 (0.8); 3.8160 (1.0); 3.8101 (0.5); 3.7964 (4.2); 3.7884 (0.5); 3.5887 (0.9); 3.5825 (0.9);

3.5671 (0.5); 3.2333 (1.4); 3.2294 (2.3); 3.2190 (2.1); 3.1861 (2.1); 3.1756 (1.9); 2.5832 (0.8); 2.5691 (0.6); 2.5621 (0.5); 2.5481 (0.9); 2.5273 (0.8); 2.5066 (0.8); 2.4924 (0.6); 2.4714 (0.9); 2.0464 (14.9);

2.0267 (0.5); 2.0171 (0.9); 1.9820 (0.7); 1.9168 (0.5); 1.9076 (0.9); 1.8985 (0.5); 1.8726 (0.8); 1.7398 (16.0); 1.7328 (12.3); 1.2774 (4.0); 1.2596 (8.1); 1.2417 (4.0); -0.0002 (8.4)

1-076: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3720 (0.7); 7.3514 (0.7); 7.2610 (48.5); 7.2126 (1.4); 7.2069 (1.7); 7.2021 (2.3); 7.1964 (3.0);

7.1935 (2.8); 7.1875 (2.3); 7.1828 (2.3); 7.1772 (1.7); 6.9590 (0.6); 6.9520 (1.0); 6.9464 (1.0); 6.9432 (0.7); 6.9373 (1.0); 6.9315 (1.5); 6.9250 (1.0); 6.9158 (0.5); 6.9099 (0.7); 6.0355 (0.5); 6.0280 (0.6);

6.0246 (0.8); 6.0211 (0.6); 6.0141 (1.0); 6.0107 (1.1); 6.0076 (1.1); 6.0043 (1.0); 6.0010 (0.7); 5.9974 (0.6); 5.9944 (0.6); 5.9910 (0.6); 5.9302 (0.6); 5.9247 (1.0); 5.9190 (0.6); 5.9109 (0.8); 5.8650 (0.7);

5.8594 (1.3); 5.8537 (0.8); 5.8455 (0.8); 5.0902 (0.6); 5.0694 (0.6); 4.3249 (0.9); 4.3131 (1.6); 4.3099

- 87 044070 (1.1); 4.3061 (0.5); 4.3002 (1.7); 4.2981 (1.9); 4.2891 (2.2); 4.2760 (2.1); 4.2703 (0.6); 4.2659 (1.2);

4.2590 (1.1); 4.2507 (1.1); 4.2469 (1.2); 4.2392 (0.8); 3.9972 (1.6); 3.9522 (2.3); 3.7620 (1.1); 3.7594 (1.1); 3.7517 (2.3); 3.7456 (2.2); 3.7168 (0.8); 3.7142 (0.8); 3.7067 (1.6); 3.7005 (1.6); 3.6396 (2.3);

3.6279 (3.3); 3.6187 (2.0); 3.6161 (2.4); 3.6072 (4.0); 3.5955 (3.7); 3.5837 (2.5); 3.5720 (1.2); 3.4020 (16.0); 3.3983 (3.0); 3.3879 (7.0); 3.3844 (15.9); 3.3798 (1.8); 3.3768 (6.2); 2.9574 (0.6); 2.8845 (0.5);

2.7276 (0.6); 2.5468 (0.7); 2.5324 (0.6); 2.5257 (0.5); 2.5114 (0.8); 2.4768 (0.8); 2.4624 (0.5); 2.4416 (0.9); 2.0103 (0.7); 1.9832 (0.6); 1.9785 (1.0); 1.9746 (0.9); 1.9515 (0.6); 1.9434 (0.7); 1.4320 (0.7);

0.0080 (0.9); -0.0002 (28.2); -0.0085 (1.0)

1-077: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5190 (1.0); 7.3767 (1.3); 7.3556 (1.4); 7.3101 (0.6); 7.2601 (178.1); 7.2248 (0.7); 7.2116 (2.5);

7.2058 (3.4); 7.2010 (4.9); 7.1952 (6.2); 7.1922 (5.6); 7.1863 (4.8); 7.1817 (4.7); 7.1760 (3.5); 7.1632 (0.6); 6.9961 (1.2); 6.9680 (0.8); 6.9587 (1.1); 6.9522 (2.1); 6.9464 (2.0); 6.9407 (1.2); 6.9370 (2.0);

6.9310 (3.0); 6.9251 (2.1); 6.9154 (1.0); 6.9096 (1.4); 6.9038 (0.7); 6.7595 (0.6); 6.0580 (0.5); 6.0537 (0.6); 6.0475 (0.9); 6.0436 (0.9); 6.0403 (0.9); 6.0377 (0.9); 6.0336 (1.0); 6.0269 (1.5); 6.0231 (1.5);

6.0202 (1.1); 6.0166 (1.2); 6.0129 (2.1); 6.0096 (2.2); 6.0065 (2.2); 6.0031 (2.1); 5.9996 (1.4); 5.9961 (1.3); 5.9931 (1.2); 5.9897 (1.1); 5.9261 (1.1); 5.9207 (2.0); 5.9150 (1.3); 5.9126 (1.1); 5.9069 (1.6);

5.9013 (0.9); 5.8707 (0.8); 5.8618 (1.3); 5.8563 (2.4); 5.8507 (1.5); 5.8422 (1.6); 5.8366 (0.9); 5.8190 (0.8); 5.8132 (0.5); 5.8051 (0.7); 5.1088 (0.6); 5.0877 (1.2); 5.0656 (1.3); 4.4386 (0.6); 4.4266 (0.6);

4.4143 (0.6); 4.3372 (0.5); 4.3191 (1.8); 4.3075 (4.1); 4.2965 (4.2); 4.2920 (2.8); 4.2901 (2.6); 4.2849 (2.5); 4.2827 (3.0); 4.2793 (3.2); 4.2751 (2.7); 4.2666 (3.5); 4.2614 (1.0); 4.2531 (1.5); 4.2496 (1.5);

4.2404 (1.7); 4.2379 (1.6); 4.2272 (1.0); 3.9944 (3.0); 3.9495 (4.2); 3.8094 (0.6); 3.8035 (0.8); 3.7975 (0.7); 3.7913 (0.6); 3.7819 (0.5); 3.7692 (0.8); 3.7614 (2.2); 3.7588 (2.4); 3.7508 (4.5); 3.7443 (4.2);

3.7308 (0.8); 3.7160 (1.8); 3.7138 (1.9); 3.7059 (3.6); 3.6992 (3.1); 3.6758 (4.3); 3.6638 (6.1); 3.6556 (4.1); 3.6518 (4.5); 3.6431 (5.3); 3.6380 (1.7); 3.6315 (5.7); 3.6191 (2.9); 3.6075 (2.2); 3.5958 (1.5);

3.5837 (1.5); 3.5762 (1.8); 3.5725 (3.0); 3.5625 (1.1); 3.5581 (3.5); 3.5550 (8.0); 3.5470 (1.7); 3.5377 (10.6); 3.5296 (3.3); 3.5208 (6.8); 3.5121 (3.0); 3.5037 (2.1); 3.4946 (0.9); 2.9572 (0.8); 2.8846 (0.6);

2.7503 (0.5); 2.7425 (0.8); 2.7300 (1.2); 2.7275 (1.2); 2.7150 (0.8); 2.7062 (0.6); 2.6943 (0.7); 2.5652 (0.8); 2.5442 (1.4); 2.5299 (1.1); 2.5233 (1.0); 2.5090 (1.6); 2.4941 (0.9); 2.4879 (1.0); 2.4731 (1.6);

2.4588 (1.0); 2.4522 (0.9); 2.4379 (1.8); 2.4171 (0.8); 2.0162 (0.8); 2.0083 (1.5); 2.0004 (0.9); 1.9848 (1.0); 1.9770 (1.9); 1.9731 (1.6); 1.9687 (1.4); 1.9569 (0.5); 1.9498 (0.9); 1.9420 (1.5); 1.9334 (1.0);

1.8731 (0.5); 1.4319 (1.4); 1.3790 (0.6); 1.2858 (0.5); 1.2552 (1.2); 1.2434 (1.1); 1.2371 (7.7); 1.2321 (3.9); 1.2285 (2.4); 1.2240 (8.7); 1.2221 (6.0); 1.2196 (15.7); 1.2146 (7.4); 1.2112 (3.4); 1.2065 (16.0);

1.2048 (8.9); 1.2021 (8.7); 1.1971 (3.8); 1.1938 (1.8); 1.1890 (7.5); 1.1740 (0.7); 0.0691 (1.0); 0.0080 (3.4); -0.0002 (107.4); -0.0085 (3.7)

1-078: ¹ H-NMR(400.0 MHz, CDC13):

- 88 044070 δ= 7.3544 (0.6); 7.3367 (0.6); 7.2605 (63.5); 7.2124 (1.3); 7.2066 (1.6); 7.2013 (2.2); 7.1959 (3.0);

7.1931 (2.9); 7.1872 (2.4); 7.1819 (2.5); 7.1765 (1.8); 6.9618 (0.6); 6.9599 (0.6); 6.9559 (0.8); 6.9537 (0.9); 6.9501 (0.8); 6.9471 (0.9); 6.9443 (0.7); 6.9403 (1.0); 6.9383 (1.1); 6.9344 (1.3); 6.9324 (1.4);

6.9286 (0.9); 6.9265 (0.9); 6.9187 (0.5); 6.9166 (0.5); 6.9128 (0.6); 6.9108 (0.6); 6.0409 (0.5); 6.0357 (0.6); 6.0302 (0.5); 6.0263 (0.6); 6.0229 (0.8); 6.0116 (1.0); 6.0083 (1.0); 6.0050 (1.0); 5.9970 (0.6);

5.9940 (0.6); 5.9906 (0.5); 5.9376 (0.6); 5.9322 (1.0); 5.9266 (0.6); 5.9184 (0.7); 5.8737 (0.8); 5.8682 (1.0); 5.8626 (0.6); 5.8600 (0.7); 5.8545 (0.8); 5.0905 (0.6); 5.0720 (0.6); 4.3434 (2.1); 4.3389 (0.7);

4.3264 (4.6); 4.3220 (2.2); 4.3093 (2.5); 4.3050 (4.0); 4.2912 (1.0); 4.2881 (2.0); 4.2803 (0.9); 4.2743 (1.6); 4.2633 (1.6); 4.2573 (0.8); 4.2464 (0.8); 4.0020 (1.2); 3.9948 (0.9); 3.9565 (1.7); 3.9494 (1.2);

3.9417 (0.6); 3.7616 (1.6); 3.7537 (2.6); 3.7487 (2.2); 3.7454 (1.0); 3.7164 (1.0); 3.7087 (1.7); 3.7036 (1.5); 3.5715 (0.6); 3.5654 (0.6); 3.5553 (0.6); 3.5500 (0.6); 2.9624 (1.1); 2.8882 (0.9); 2.7851 (2.0);

2.7681 (4.5); 2.7618 (0.8); 2.7492 (4.5); 2.7445 (1.3); 2.7323 (2.6); 2.7274 (1.8); 2.7204 (0.7); 2.7168 (1.8); 2.7106 (1.0); 2.6998 (1.4); 2.5562 (0.7); 2.5419 (0.5); 2.5208 (0.8); 2.4896 (0.8); 2.4752 (0.6);

2.4543 (0.8); 2.1848 (0.9); 2.1830 (1.1); 2.1725 (2.4); 2.1677 (14.5); 2.1624 (2.4); 2.1508 (16.0); 2.1406 (6.2); 2.1093 (2.0); 2.0256 (0.7); 1.9983 (0.8); 1.9904 (1.4); 1.9823 (0.9); 1.9632 (0.5); 1.9552 (0.7);

1.9470 (0.6); 1.4319 (0.8); 1.2568 (0.5); 0.0079 (1.1); -0.0002 (36.5); -0.0085 (1.4)

1-079: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9507 (1.3); 7.9465 (2.9); 7.9421 (3.4); 7.9378 (3.6); 7.9367 (3.6); 7.9335 (3.4); 7.9295 (2.0); 7.8705 (1.0); 7.8675 (1.2); 7.8662 (1.2); 7.8630 (1.8); 7.8597 (1.5); 7.8582 (1.7); 7.8551 (2.2); 7.8506 (2.4);

7.8477 (2.1); 7.8431 (2.2); 7.8397 (1.7); 7.8384 (2.0); 7.8353 (2.4); 7.8307 (1.6); 7.8279 (0.9); 7.7269 (0.7); 7.7238 (1.4); 7.7202 (1.5); 7.7151 (1.3); 7.7105 (2.0); 7.7081 (2.1); 7.7045 (2.1); 7.7008 (2.0);

7.6958 (1.6); 7.6915 (2.4); 7.6871 (1.4); 7.5671 (1.0); 7.5657 (1.1); 7.5635 (1.1); 7.5622 (1.1); 7.5563 (1.6); 7.5546 (2.0); 7.5528 (1.6); 7.5461 (1.9); 7.5438 (1.9); 7.5349 (3.2); 7.5278 (1.0); 7.5265 (1.0);

7.5242 (0.9); 7.5171 (1.1); 7.5153 (1.4); 7.2623 (48.6); 7.1621 (0.6); 7.1496 (0.8); 7.1284 (0.7); 6.7840 (0.7); 6.7632 (0.7); 6.0105 (0.6); 6.0062 (0.7); 6.0045 (0.7); 5.9966 (1.6); 5.9923 (2.1); 5.9907 (1.8);

5.9862 (1.8); 5.9811 (1.3); 5.9785 (1.8); 5.9746 (1.4); 5.9725 (1.6); 5.9687 (1.0); 5.9662 (0.9); 5.9624 (0.8); 5.9587 (0.9); 5.9549 (1.0); 5.9524 (1.0); 5.9486 (0.9); 5.9239 (0.9); 5.9184 (1.6); 5.9128 (1.0);

5.9103 (0.7); 5.9046 (1.2); 5.8990 (0.7); 5.8925 (0.7); 5.8868 (1.2); 5.8810 (0.7); 5.8787 (0.6); 5.8729 (1.0); 5.8672 (0.5); 5.8321 (0.8); 5.8265 (1.6); 5.8207 (1.0); 5.8182 (1.0); 5.8125 (1.7); 5.8069 (1.0);

5.8030 (0.7); 5.7971 (1.0); 5.7913 (0.5); 5.1129 (0.5); 5.1064 (0.6); 5.1002 (0.6); 5.0941 (0.5); 5.0445 (0.5); 5.0238 (1.0); 4.4286 (1.5); 4.4192 (1.5); 4.4152 (2.1); 4.4142 (2.0); 4.4058 (1.8); 4.4043 (2.0);

4.4002 (1.8); 4.3915 (1.7); 4.3868 (2.0); 4.3855 (2.0); 4.3740 (2.9); 4.3713 (2.4); 4.3696 (2.6); 4.3663 (1.9); 4.3579 (2.6); 4.3541 (2.0); 4.3522 (2.3); 4.3498 (2.8); 4.3377 (3.2); 4.3329 (1.7); 4.3212 (1.8);

3.8634 (1.8); 3.8573 (2.0); 3.8536 (3.0); 3.8501 (2.9); 3.8201 (2.2); 3.8140 (2.4); 3.8104 (3.8); 3.8069 (3.6); 3.8001 (0.8); 3.7943 (0.7); 3.7883 (0.8); 3.7827 (0.8); 3.7769 (0.6); 3.7711 (0.6); 3.7669 (0.6);

3.7608 (0.7); 3.7567 (2.1); 3.7541 (2.2); 3.7491 (0.7); 3.7423 (2.8); 3.7400 (3.5); 3.7288 (1.8); 3.7257

- 89 044070 (1.8); 3.7199 (3.6); 3.7056 (3.6); 3.6971 (2.3); 3.6917 (3.2); 3.6821 (4.0); 3.6680 (3.4); 3.6537 (2.1);

3.5947 (0.5); 3.5918 (0.5); 3.5859 (0.7); 3.5768 (1.0); 3.5739 (1.0); 3.5650 (0.7); 3.5593 (0.5); 3.5564 (0.5); 3.5501 (0.5); 3.2396 (2.6); 3.2342 (3.0); 3.2263 (2.8); 3.1962 (2.3); 3.1910 (2.7); 3.1831 (2.5);

2.7135 (0.5); 2.7113 (0.6); 2.6991 (0.5); 2.6949 (0.5); 2.6908 (0.5); 2.6828 (0.6); 2.6785 (0.5); 2.6741 (0.5); 2.6621 (0.6); 2.6597 (0.6); 2.6477 (0.5); 2.6391 (0.5); 2.6014 (0.6); 2.5803 (1.1); 2.5663 (0.8);

2.5590 (0.7); 2.5451 (1.2); 2.5362 (0.6); 2.5239 (0.7); 2.5150 (1.1); 2.5011 (0.8); 2.4938 (0.7); 2.4799 (1.2); 2.4587 (0.6); 2.0109 (0.6); 2.0014 (1.0); 1.9919 (0.6); 1.9758 (0.5); 1.9662 (0.9); 1.9565 (0.9);

1.9211 (0.6); 1.9186 (0.7); 1.9094 (1.3); 1.8993 (1.0); 1.8881 (0.5); 1.8835 (0.6); 1.8739 (0.9); 1.8641 (1.0); 1.8291 (0.6); 1.7417 (15.0); 1.7337 (16.0); 1.7271 (15.9); 1.5745 (9.2); 1.2845 (0.8); 0.0079 (1.1); 0.0002 (34.2); -0.0085 (1.4)

1-080: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9522 (1.0); 7.9484 (1.8); 7.9437 (1.9); 7.9353 (3.2); 7.8722 (0.7); 7.8689 (1.0); 7.8641 (1.1); 7.8604 (1.1); 7.8558 (1.3); 7.8524 (1.9); 7.8487 (2.0); 7.8451 (1.5); 7.8404 (1.2); 7.8359 (1.3); 7.8327 (1.3);

7.7258 (0.6); 7.7225 (1.3); 7.7191 (1.3); 7.7146 (1.0); 7.7113 (1.6); 7.7075 (1.8); 7.7032 (1.8); 7.6996 (1.6); 7.6952 (1.2); 7.6919 (1.9); 7.6885 (1.8); 7.5645 (1.0); 7.5618 (0.9); 7.5525 (1.3); 7.5450 (1.6);

7.5421 (1.5); 7.5330 (2.0); 7.5252 (0.8); 7.5212 (0.8); 7.5149 (0.9); 7.2614 (46.2); 7.1924 (0.6); 6.7714 (0.6); 6.7513 (0.6); 5.9843 (0.6); 5.9799 (0.6); 5.9764 (1.5); 5.9720 (1.7); 5.9705 (1.7); 5.9661 (1.5);

5.9626 (1.3); 5.9584 (1.4); 5.9565 (1.4); 5.9523 (1.6); 5.9483 (0.7); 5.9458 (0.7); 5.9418 (0.6); 5.9383 (0.7); 5.9343 (0.7); 5.9320 (0.7); 5.9281 (0.6); 5.9037 (0.7); 5.8982 (1.2); 5.8926 (0.7); 5.8843 (0.9);

5.8702 (0.6); 5.8645 (1.0); 5.8587 (0.6); 5.8506 (0.8); 5.8126 (0.7); 5.8070 (1.2); 5.8012 (0.7); 5.7988 (0.7); 5.7934 (1.3); 5.7880 (1.3); 5.7824 (0.5); 5.7743 (0.7); 5.1013 (0.5); 5.0958 (0.6); 5.0909 (0.6);

5.0857 (0.5); 5.0108 (0.8); 3.8611 (1.6); 3.8557 (1.6); 3.8512 (2.2); 3.8460 (2.0); 3.8178 (1.8); 3.8124 (1.8); 3.8080 (2.5); 3.8029 (2.3); 3.7658 (0.6); 3.7568 (15.3); 3.7439 (0.6); 3.7380 (0.7); 3.7265 (14.8);

3.7108 (0.6); 3.6989 (9.8); 3.6820 (10.6); 3.5219 (0.7); 3.2369 (2.5); 3.2323 (2.3); 3.2235 (2.1); 3.1936 (2.2); 3.1891 (2.0); 3.1803 (1.8); 2.6383 (0.5); 2.5534 (0.8); 2.5395 (0.6); 2.5185 (1.0); 2.4974 (0.5);

2.4855 (0.8); 2.4716 (0.6); 2.4506 (1.0); 1.9678 (0.8); 1.9326 (0.8); 1.8955 (0.5); 1.8874 (0.6); 1.8777 (0.9); 1.8680 (0.5); 1.8427 (0.8); 1.8349 (0.6); 1.8016 (0.5); 1.7397 (11.5); 1.7313 (14.4); 1.7272 (12.5);

1.5626 (16.0); 0.0079 (1.2); -0.0002 (33.7); -0.0085 (1.1)

1-081: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9567 (0.9); 7.9527 (1.5); 7.9496 (1.0); 7.9395 (2.4); 7.9356 (3.2); 7.8675 (0.7); 7.8644 (0.9); 7.8601 (1.5); 7.8562 (1.4); 7.8527 (1.2); 7.8474 (1.1); 7.8445 (1.1); 7.8434 (1.1); 7.8402 (1.7); 7.8363 (1.6);

7.8329 (1.3); 7.7226 (0.8); 7.7194 (0.8); 7.7150 (0.5); 7.7073 (1.9); 7.7032 (1.7); 7.7002 (1.0); 7.6957 (0.6); 7.6878 (1.7); 7.5659 (0.7); 7.5615 (0.6); 7.5513 (1.6); 7.5497 (1.3); 7.5475 (1.3); 7.5417 (1.0);

7.5317 (2.4); 7.5214 (0.7); 7.5121 (1.0); 7.2625 (34.0); 7.1753 (0.7); 6.7707 (0.5); 6.7495 (0.5); 5.9959 (0.7); 5.9905 (1.4); 5.9861 (1.1); 5.9810 (0.8); 5.9768 (1.1); 5.9708 (1.0); 5.9669 (1.0); 5.9636 (0.7);

5.9611 (0.6); 5.9571 (0.6); 5.9535 (0.6); 5.9497 (0.7); 5.9472 (0.6); 5.9434 (0.6); 5.9022 (0.6); 5.8966

- 90 044070 (1.1); 5.8910 (0.6); 5.8885 (0.5); 5.8828 (0.8); 5.8772 (0.5); 5.8683 (0.8); 5.8544 (0.7); 5.8090 (0.6); 5.8034 (1.1); 5.7974 (1.0); 5.7898 (1.1); 5.7838 (0.8); 5.7775 (0.6); 5.0183 (0.6); 5.0149 (0.6); 5.0099 (0.6); 5.0063 (0.5); 4.3161 (1.0); 4.3092 (1.1); 4.3049 (1.8); 4.2968 (1.9); 4.2924 (1.2); 4.2857 (1.3);

4.2741 (1.8); 4.2716 (1.2); 4.2633 (1.6); 4.2603 (2.0); 4.2563 (0.9); 4.2529 (1.4); 4.2507 (1.2); 4.2443 (1.6); 4.2395 (1.0); 4.2337 (1.5); 4.2262 (1.1); 4.2213 (0.8); 4.2155 (0.7); 3.8592 (1.6); 3.8569 (2.4);

3.8477 (1.8); 3.8158 (1.9); 3.8137 (2.8); 3.8046 (2.1); 3.7790 (0.5); 3.7728 (0.5); 3.6447 (1.6); 3.6343 (2.2); 3.6314 (1.9); 3.6216 (1.4); 3.6203 (1.4); 3.6170 (1.4); 3.6139 (1.2); 3.6033 (3.0); 3.5909 (2.9);

3.5862 (2.0); 3.5799 (1.7); 3.5742 (2.6); 3.5626 (1.9); 3.4036 (16.0); 3.3851 (10.2); 3.3793 (15.4); 3.3695 (11.3); 3.2359 (2.3); 3.2295 (1.9); 3.2193 (1.9); 3.1925 (2.0); 3.1864 (1.7); 3.1761 (1.6); 2.6746 (0.5);

2.6623 (0.6); 2.5559 (0.7); 2.5420 (0.5); 2.5209 (0.8); 2.4925 (0.8); 2.4575 (0.8); 1.9760 (0.7); 1.9412 (0.7); 1.9320 (0.6); 1.8976 (0.7); 1.8876 (0.8); 1.8525 (0.9); 1.7389 (10.2); 1.7303 (12.6); 1.7233 (10.1); 1.5811 (11.6); 0.0079 (0.7); -0.0002 (24.0); -0.0085 (0.8)

1-082: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7172 (1.0); 7.7138 (2.0); 7.7103 (1.3); 7.7067 (1.0); 7.7027 (2.5); 7.6989 (3.3); 7.6953 (1.8); 7.6337 (0.6); 7.6300 (0.6); 7.6275 (0.7); 7.6238 (0.7); 7.6207 (0.8); 7.6143 (1.3); 7.6109 (1.6); 7.6077 (1.2);

7.6048 (1.0); 7.6013 (0.8); 7.5981 (0.9); 7.5919 (1.2); 7.5881 (1.1); 7.4303 (0.7); 7.4270 (0.7); 7.4197 (0.9); 7.4168 (1.4); 7.4137 (1.6); 7.4112 (1.5); 7.4082 (1.3); 7.4006 (0.9); 7.3975 (1.0); 7.3949 (1.1);

7.3922 (0.9); 7.2614 (60.1); 7.1584 (0.7); 6.0023 (0.8); 5.9980 (0.9); 5.9962 (1.0); 5.9919 (1.1); 5.9884 (0.9); 5.9844 (0.9); 5.9808 (0.8); 5.9777 (0.9); 5.9743 (0.8); 5.9712 (1.0); 5.9655 (0.6); 5.9618 (0.5);

5.9581 (0.6); 5.9544 (0.6); 5.9517 (0.6); 5.9481 (0.5); 5.9040 (0.6); 5.8984 (1.1); 5.8928 (0.6); 5.8903 (0.5); 5.8846 (0.8); 5.8670 (0.7); 5.8531 (0.6); 5.8131 (0.6); 5.8075 (1.0); 5.8018 (0.6); 5.7994 (0.6);

5.7937 (1.0); 5.7898 (0.8); 5.7760 (0.6); 5.0149 (0.6); 5.0062 (0.6); 4.3172 (1.0); 4.3057 (1.6); 4.2964 (1.8); 4.2936 (1.4); 4.2877 (1.1); 4.2855 (1.2); 4.2775 (1.3); 4.2750 (1.9); 4.2642 (2.1); 4.2618 (1.3);

4.2575 (0.8); 4.2541 (1.4); 4.2520 (1.2); 4.2477 (0.9); 4.2451 (1.3); 4.2414 (1.2); 4.2368 (1.2); 4.2343 (0.9); 4.2286 (1.0); 4.2241 (0.7); 4.2180 (0.6); 3.8419 (1.3); 3.8378 (2.6); 3.8283 (1.7); 3.7986 (1.6);

3.7946 (3.1); 3.7852 (2.2); 3.7809 (0.6); 3.6436 (1.7); 3.6331 (2.1); 3.6306 (1.9); 3.6198 (2.5); 3.6170 (1.4); 3.6089 (1.5); 3.6044 (2.6); 3.5962 (1.6); 3.5928 (2.6); 3.5878 (1.9); 3.5802 (1.7); 3.5758 (2.6);

3.5643 (1.6); 3.4037 (15.0); 3.3853 (10.6); 3.3833 (16.0); 3.3711 (9.8); 3.2116 (2.0); 3.2053 (1.9); 3.1940 (1.7); 3.1682 (1.8); 3.1622 (1.6); 3.1508 (1.5); 2.5457 (0.7); 2.5107 (0.8); 2.4809 (0.8); 2.4460 (0.8);

1.9771 (0.7); 1.9420 (0.7); 1.8896 (0.8); 1.8546 (0.7); 1.7417(9.5); 1.7326(11.1); 1.7257(10.1); 1.7164 (0.7); 1.5619 (12.4); 1.2588 (0.6); 0.8818 (0.8); 0.0080 (1.1); -0.0002 (33.9); -0.0085 (1.2)

1-083: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7145 (1.5); 7.7111 (2.9); 7.7076 (2.6); 7.7042 (2.8); 7.7007 (4.0); 7.6974 (3.8); 7.6942 (1.9); 7.6325 (0.8); 7.6288 (0.9); 7.6263 (1.0); 7.6220 (1.4); 7.6179 (1.6); 7.6152 (1.8); 7.6116 (2.1); 7.6062 (1.4);

7.6039 (1.2); 7.5995 (1.5); 7.5955 (1.6); 7.5927 (1.8); 7.5892 (1.8); 7.5863 (1.0); 7.5830 (0.6); 7.4358 (0.6); 7.4326 (1.1); 7.4295 (1.1); 7.4263 (1.1); 7.4231 (1.5); 7.4205 (1.5); 7.4171 (2.2); 7.4136 (2.3);

- 91 044070

7.4111 (1.6); 7.4073 (1.2); 7.4040 (1.6); 7.4010 (1.5); 7.3983 (1.6); 7.3954 (1.3); 7.3925 (0.9); 7.2611 (80.9); 7.1282 (0.8); 7.1150 (0.7); 6.7372 (0.6); 6.7178 (0.6); 6.0159 (0.5); 6.0098 (0.6); 6.0024 (1.3);

5.9978 (1.7); 5.9919 (1.3); 5.9898 (1.4); 5.9856 (1.6); 5.9791 (1.6); 5.9745 (0.9); 5.9717 (0.8); 5.9679 (0.8); 5.9643 (0.9); 5.9606 (0.9); 5.9580 (0.9); 5.9542 (0.8); 5.9249 (0.8); 5.9194 (1.6); 5.9138 (0.9);

5.9113 (0.7); 5.9055 (1.1); 5.9001 (0.6); 5.8910 (0.5); 5.8853 (1.0); 5.8795 (0.6); 5.8714 (0.8); 5.8352 (0.8); 5.8295 (1.5); 5.8238 (0.9); 5.8216 (0.8); 5.8156 (1.7); 5.8098 (1.6); 5.8038 (0.6); 5.8016 (0.5);

5.7957 (0.8); 5.2988 (1.6); 5.0980 (0.5); 5.0244 (0.9); 4.4288 (1.4); 4.4200 (1.5); 4.4151 (2.1); 4.4067 (1.9); 4.4052 (1.9); 4.4004 (1.7); 4.3908 (2.3); 4.3771 (2.6); 4.3755 (2.6); 4.3735 (2.3); 4.3675 (1.5);

4.3621 (2.7); 4.3532 (2.6); 4.3514 (2.3); 4.3393 (3.0); 4.3357 (1.5); 4.3241 (1.6); 3.8460 (1.5); 3.8393 (1.7); 3.8349 (2.8); 3.8311 (2.8); 3.8026 (1.9); 3.7958 (2.3); 3.7916 (3.6); 3.7881 (3.5); 3.7795 (0.7);

3.7633 (0.5); 3.7548 (2.1); 3.7530 (2.0); 3.7391 (3.7); 3.7270 (2.0); 3.7232 (3.8); 3.7089 (3.5); 3.6977 (2.3); 3.6950 (3.2); 3.6838 (3.6); 3.6697 (3.7); 3.6560 (1.8); 3.6037 (0.5); 3.6009 (0.5); 3.5977 (0.6);

3.5911 (0.6); 3.5886 (0.7); 3.5819 (1.0); 3.5789 (0.9); 3.5758 (1.0); 3.5693 (0.7); 3.5668 (0.7); 3.5602 (0.5); 3.5542 (0.5); 3.2152 (2.2); 3.2096 (2.8); 3.2009 (2.6); 3.1718 (1.9); 3.1664 (2.4); 3.1577 (2.3);

2.6643 (0.5); 2.5940 (0.6); 2.5729 (1.0); 2.5589 (0.7); 2.5517 (0.6); 2.5377 (1.2); 2.5286 (0.6); 2.5165 (0.6); 2.5075 (1.1); 2.4935 (0.7); 2.4863 (0.6); 2.4723 (1.2); 2.4512 (0.6); 2.0111 (0.6); 2.0021 (1.0);

1.9929 (0.6); 1.9760 (0.5); 1.9670 (0.9); 1.9577 (0.5); 1.9200 (1.0); 1.9110 (1.1); 1.9068 (0.6); 1.9019 (0.6); 1.8849 (0.8); 1.8759 (0.9); 1.8667 (0.5); 1.8271 (0.5); 1.7443 (14.3); 1.7360 (13.4); 1.7291 (14.6);

1.5545 (16.0); 1.2641 (0.8); 1.2585 (0.7); 0.8818 (1.3); 0.8640 (0.5); 0.0080 (1.5); -0.0002 (46.5); -0.0085 (1.6)

1-084: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7153 (1.1); 7.7120 (2.1); 7.7082 (1.6); 7.7029 (2.8); 7.6992 (3.5); 7.6958 (1.8); 7.6365 (0.6); 7.6329 (0.7); 7.6303 (0.8); 7.6266 (0.7); 7.6237 (0.8); 7.6199 (0.8); 7.6171 (1.1); 7.6139 (1.8); 7.6103 (1.6);

7.6078 (1.4); 7.6042 (1.2); 7.6012 (0.9); 7.5975 (0.8); 7.5946 (1.0); 7.5913 (1.2); 7.5879 (0.9); 7.5852 (0.7); 7.4317 (0.8); 7.4286 (0.8); 7.4255 (0.9); 7.4226 (1.1); 7.4196 (1.4); 7.4164 (1.8); 7.4131 (1.8);

7.4100 (1.4); 7.4064 (1.0); 7.4035 (1.1); 7.4005 (1.4); 7.3974 (1.4); 7.3943 (1.2); 7.3913 (0.7); 7.2620 (46.4); 7.1770 (0.7); 5.9835 (0.6); 5.9796 (1.0); 5.9772 (1.4); 5.9735 (1.1); 5.9700 (1.1); 5.9658 (1.1);

5.9632 (1.2); 5.9596 (1.2); 5.9566 (1.2); 5.9532 (0.7); 5.9505 (0.6); 5.9467 (0.6); 5.9431 (0.7); 5.9393 (0.7); 5.9367 (0.7); 5.9329 (0.6); 5.9054 (0.6); 5.8998 (1.2); 5.8942 (0.7); 5.8917 (0.5); 5.8860 (0.8);

5.8631 (0.8); 5.8491 (0.6); 5.8162 (0.6); 5.8106 (1.1); 5.8049 (0.7); 5.8026 (0.6); 5.7968 (1.0); 5.7917 (0.7); 5.7869 (0.7); 5.7730 (0.6); 5.2991 (1.5); 5.0075 (0.8); 3.8444 (1.2); 3.8385 (1.2); 3.8328 (2.1);

3.8279 (2.0); 3.8011 (1.4); 3.7951 (1.4); 3.7896 (2.4); 3.7847 (2.3); 3.7673 (0.5); 3.7572 (16.0); 3.7453 (0.5); 3.7390 (0.6); 3.7294 (15.7); 3.7195 (0.5); 3.7001 (8.2); 3.6847 (8.7); 3.5398 (0.5); 3.5372 (0.6);

3.5308 (0.8); 3.5278 (0.7); 3.5248 (0.8); 3.5184 (0.6); 3.5158 (0.5); 3.2135 (1.9); 3.2091 (2.2); 3.1993 (2.0); 3.1701 (1.6); 3.1659 (1.9); 3.1561 (1.8); 2.5441 (0.8); 2.5302 (0.6); 2.5231 (0.5); 2.5092 (0.9);

2.4753 (0.8); 2.4613 (0.6); 2.4403 (0.9); 1.9693 (0.8); 1.9343 (0.7); 1.9255 (0.6); 1.8902 (0.7); 1.8801

- 92 044070 (1.1); 1.8707 (0.5); 1.8453 (0.7); 1.7428 (11.0); 1.7333 (10.6); 1.7295 (12.0); 1.5672 (7.5); 0.0080 (0.8); 0.0002 (27.0); -0.0085 (1.0)

1-085: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9992 (5.1); 7.9959 (8.8); 7.9920 (5.6); 7.9745 (9.8); 7.9708 (11.6); 7.9670 (6.9); 7.8833 (3.3); 7.8792 (3.1); 7.8729 (6.6); 7.8695 (9.1); 7.8659 (7.9); 7.8531 (7.5); 7.8496 (9.8); 7.8459 (7.2); 7.7804 (3.4); 7.7683 (6.6); 7.7650 (11.5); 7.7617 (9.9); 7.7489 (8.1); 7.7455 (11.6); 7.7423 (7.0); 7.6111 (3.6); 7.5991 (10.0); 7.5915 (6.0); 7.5794 (16.0); 7.5720 (3.2); 7.5597 (7.2); 7.5187 (2.5); 7.3483 (2.8); 7.3269 (3.5); 7.3139 (3.1); 7.2977 (1.1); 7.2598 (412.8); 7.2101 (1.0); 6.9958 (2.2); 6.8311 (0.8); 6.8064 (1.6); 6.7859 (1.0); 6.0808 (1.2); 6.0700 (4.2); 6.0669 (5.3); 6.0533 (7.4); 6.0437 (3.4); 6.0399 (3.7); 6.0365 (3.8); 6.0335 (3.7); 6.0301 (3.4); 5.9726 (3.3); 5.9670 (5.9); 5.9613 (3.7); 5.9532 (4.6); 5.9476 (2.6); 5.9237 (1.4); 5.9180 (2.3); 5.9094 (4.2); 5.9038 (7.5); 5.8981 (4.4); 5.8899 (4.8); 5.8842 (2.7); 5.8668 (1.1); 5.8610 (2.1); 5.8546 (1.2); 5.8470 (1.8); 5.8413 (1.0); 5.2984 (3.0); 5.1902 (1.1); 5.1793 (1.1); 5.1585 (1.1); 5.1025 (2.5); 5.0819 (4.8); 5.0615 (2.4); 4.1494 (0.6); 4.1316 (1.6); 4.1136 (1.6); 4.0959 (0.6); 4.0726 (1.8); 4.0657 (1.7); 4.0450 (8.0); 4.0275 (2.3); 4.0202 (2.4); 3.9999 (11.2); 3.8517 (1.2); 3.8455 (1.2); 3.8357 (1.6); 3.8296 (1.9); 3.8235 (2.2); 3.8176 (2.1); 3.8090 (8.1); 3.8014 (12.9); 3.7917 (12.1); 3.7640 (5.5); 3.7563 (8.6); 3.7466 (8.6); 3.6075 (4.0); 3.6015 (4.0); 2.7933 (0.6); 2.7817 (0.7); 2.7733 (1.0); 2.7607 (1.1); 2.7583 (1.4); 2.7538 (0.6); 2.7459 (1.6); 2.7377 (1.4); 2.7329 (1.1); 2.7305 (0.8); 2.7249 (1.4); 2.7118 (1.4); 2.7090 (1.3); 2.6971 (1.1); 2.6884 (1.1); 2.6766 (1.0); 2.6136 (2.1); 2.5927 (4.0); 2.5782 (2.9); 2.5717 (2.6); 2.5571 (4.4); 2.5397 (2.9); 2.5362 (2.9); 2.5191 (4.2); 2.5046 (3.1); 2.4982 (2.8); 2.4838 (4.7); 2.4629 (2.3); 2.1144 (1.1); 2.0634 (2.2); 2.0552 (4.0); 2.0446 (8.7); 2.0278 (2.1); 2.0197 (3.6); 2.0113 (2.5); 1.9978 (2.9); 1.9890 (4.8); 1.9809 (2.6); 1.9629 (2.6); 1.9536 (4.0); 1.9451 (3.1); 1.9330 (1.1); 1.9229 (1.1); 1.9107 (1.2); 1.8976 (1.0); 1.8873 (0.9); 1.8759 (0.8);

1.4319 (1.7); 1.2767 (2.2); 1.2589 (4.5); 1.2411 (2.1); 0.1461 (1.1); 0.0080 (9.0); -0.0002 (297.1); -0.0085 (11.0); -0.0498 (0.9); -0.1495 (1.0)

1-086: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9889 (0.9); 7.9850 (1.6); 7.9807 (1.6); 7.9764 (2.4); 7.9723 (3.1); 7.9684 (1.6); 7.8930 (0.7); 7.8900 (0.9); 7.8854 (1.4); 7.8807 (1.5); 7.8775 (1.4); 7.8731 (1.3); 7.8702 (1.1); 7.8655 (1.6); 7.8608 (1.7); 7.8577 (1.5); 7.8530 (0.6); 7.7820 (0.9); 7.7787 (1.0); 7.7750 (0.6); 7.7714 (0.8); 7.7662 (1.7); 7.7626 (1.8); 7.7592 (1.3); 7.7556 (0.7); 7.7519 (1.0); 7.7480 (1.5); 7.6125 (0.6); 7.6091 (0.7); 7.5991 (1.3); 7.5939 (1.1); 7.5893 (1.2); 7.5794 (2.0); 7.5698 (0.6); 7.5598 (0.9); 7.3839 (0.6); 7.3622 (0.6); 7.2621 (36.8); 6.7728 (0.5); 6.0583 (0.5); 6.0566 (0.5); 6.0528 (0.7); 6.0488 (0.8); 6.0429 (0.9); 6.0388 (0.8); 6.0330 (0.8); 6.0291 (0.9); 6.0256 (0.6); 6.0221 (0.5); 6.0154 (1.0); 6.0122 (1.1); 6.0089 (1.0); 6.0023 (0.6); 5.9989 (0.6); 5.9957 (0.6); 5.9923 (0.5); 5.9341 (0.6); 5.9285 (1.0); 5.9229 (0.6); 5.9205 (0.5); 5.9148 (0.8); 5.8781 (0.7); 5.8641 (1.0); 5.8584 (1.2); 5.8527 (0.6); 5.8503 (0.5); 5.8445 (0.8); 5.8200 (0.8); 5.8061 (0.7); 5.0930 (0.6); 5.0708 (0.6); 4.3287 (0.9); 4.3169 (1.4); 4.3119 (0.9); 4.3051 (1.1); 4.2997 (2.2); 4.2884 (2.8); 4.2753 (2.1); 4.2711 (1.0); 4.2649 (1.4); 4.2600 (1.6); 4.2511 (1.6); 4.2470

- 93 044070 (1.7); 4.2402 (1.0); 4.2378 (1.0); 4.2339 (0.8); 4.2269 (0.6); 4.0576 (0.9); 4.0510 (1.6); 4.0123 (1.3); 4.0060 (2.3); 3.8055 (1.8); 3.8031 (2.1); 3.7966 (2.5); 3.7897 (2.2); 3.7603 (1.1); 3.7578 (1.3); 3.7515 (1.6); 3.7446 (1.4); 3.6425 (1.9); 3.6308 (3.0); 3.6191 (2.4); 3.6092 (3.7); 3.5966 (3.4); 3.5948 (3.7); 3.5831 (3.2); 3.5709 (1.4); 3.4040 (13.8); 3.3877 (13.0); 3.3857 (16.0); 3.3753 (8.9); 2.7113 (0.6); 2.5480 (0.6); 2.5126 (0.7); 2.4733 (0.7); 2.4381 (0.8); 2.0155 (0.6); 1.9882 (0.9); 1.9797 (1.4); 1.9721 (0.7);

1.9532 (0.6); 1.9440 (0.8); 1.5683 (5.6); 0.8817 (0.5); 0.0079 (0.6); -0.0002 (21.0); -0.0084 (0.8) 1-087: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9868 (1.0); 7.9827 (2.2); 7.9782 (2.5); 7.9740 (2.7); 7.9708 (2.4); 7.9671 (1.2); 7.8979 (0.7); 7.8948 (0.9); 7.8901 (0.9); 7.8860 (0.9); 7.8818 (1.2); 7.8778 (1.6); 7.8750 (1.9); 7.8705 (1.2); 7.8662 (1.0); 7.8620 (1.2); 7.8596 (1.1); 7.8572 (1.1); 7.8553 (1.0); 7.8526 (0.6); 7.7821 (1.0); 7.7787 (1.0); 7.7740 (0.9); 7.7711 (1.5); 7.7674 (1.5); 7.7628 (1.4); 7.7592 (1.3); 7.7546 (1.2); 7.7516 (1.7); 7.7482 (1.6); 7.7454 (0.8); 7.6098 (0.8); 7.6016 (1.3); 7.5917 (1.3); 7.5900 (1.4); 7.5820 (2.0); 7.5721 (0.6); 7.5704 (0.7); 7.5623 (0.9); 7.3913 (0.6); 7.3705 (0.6); 7.2617 (41.4); 6.0405 (0.5); 6.0387 (0.5); 6.0342 (0.6); 6.0308 (0.6); 6.0267 (1.0); 6.0204 (0.8); 6.0145 (1.0); 6.0084 (0.9); 6.0034 (1.0); 6.0007 (1.1); 5.9975 (1.1); 5.9942 (1.0); 5.9882 (0.6); 5.9849 (0.6); 5.9816 (0.6); 5.9352 (0.6); 5.9297 (1.2); 5.9241 (0.7); 5.9217 (0.6); 5.9159 (0.8); 5.8738 (0.8); 5.8689 (0.8); 5.8641 (1.1); 5.8595 (0.9); 5.8553 (0.7); 5.8502 (0.8); 5.8176 (0.8); 5.8116 (0.5); 5.8036 (0.8); 5.0841 (0.6); 5.0682 (0.6); 4.0627 (0.6); 4.0576 (0.8); 4.0506 (1.7); 4.0173 (0.9); 4.0123 (1.2); 4.0055 (2.4); 3.8048 (2.3); 3.7991 (2.6); 3.7914 (2.5); 3.7848 (0.6); 3.7786 (0.5); 3.7749 (0.7); 3.7639 (14.9); 3.7540 (2.3); 3.7462 (2.5); 3.7418 (16.0); 3.7070 (9.8); 3.6950 (8.2); 3.5629 (0.6); 3.5553 (0.8); 3.5492 (0.8); 3.5423 (0.8); 3.5357 (0.6); 2.7256 (0.5); 2.5404 (0.7); 2.5260 (0.5); 2.5050 (0.8); 2.4701 (0.9); 2.4557 (0.6); 2.4349 (1.0); 2.0119 (0.7); 1.9765 (1.2);

1.9693 (1.2); 1.9646 (0.6); 1.9616 (0.6); 1.9425 (0.8); 1.9342 (0.8); 1.5596 (6.8); 0.0080 (0.7); -0.0002 (23.3); -0.0085 (0.9)

1-088: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9802 (10.5); 7.9777 (11.3); 7.9743 (11.3); 7.9697 (9.6); 7.9657 (4.8); 7.8956 (2.9); 7.8916 (4.0); 7.8885 (5.3); 7.8841 (4.4); 7.8809 (5.8); 7.8760 (6.6); 7.8730 (6.0); 7.8686 (6.3); 7.8644 (5.0); 7.8611 (6.4); 7.8585 (4.8); 7.7828 (3.9); 7.7794 (4.2); 7.7745 (3.9); 7.7716 (6.1); 7.7681 (6.2); 7.7635 (5.7); 7.7599 (5.5); 7.7551 (4.9); 7.7521 (7.1); 7.7489 (6.6); 7.6108 (3.7); 7.6010 (5.5); 7.5910 (6.0); 7.5821 (8.8); 7.5715 (2.9); 7.5626 (3.8); 7.5203 (0.8); 7.3244 (1.9); 7.3113 (3.0); 7.2898 (2.2); 7.2614 (154.1); 6.9974 (0.9); 6.8076 (1.3); 6.7857 (2.2); 6.7625 (1.1); 6.0654 (1.8); 6.0596 (2.2); 6.0545 (2.7); 6.0514 (2.8); 6.0475 (3.9); 6.0410 (5.0); 6.0344 (4.3); 6.0297 (3.5); 6.0245 (4.7); 6.0213 (4.9); 6.0181 (4.6); 6.0115 (2.6); 6.0080 (2.7); 6.0049 (2.6); 6.0015 (2.3); 5.9532 (2.7); 5.9477 (4.7); 5.9420 (2.9); 5.9339 (3.5); 5.9284 (2.0); 5.9029 (1.5); 5.8972 (2.8); 5.8914 (1.8); 5.8891 (1.7); 5.8836 (4.2); 5.8784 (4.8); 5.8730 (2.7); 5.8649 (3.4); 5.8593 (2.0); 5.8455 (1.8); 5.8397 (3.3); 5.8338 (2.1); 5.8258 (3.0); 5.8200 (1.6); 5.2019 (0.5); 5.1959 (0.6); 5.1913 (0.7); 5.1862 (1.0); 5.1810 (1.2); 5.1672 (1.3); 5.1571 (1.4); 5.1526 (1.6); 5.1472 (1.5); 5.1422 (1.2); 5.1366 (1.0); 5.1318 (0.8); 5.1260 (1.2); 5.1208 (1.3); 5.0992

- 94 044070 (2.6); 5.0806 (2.7); 4.4285 (7.9); 4.4146 (9.5); 4.4120 (6.5); 4.4030 (6.3); 4.4002 (11.3); 4.3895 (8.8);

4.3843 (7.4); 4.3747 (9.1); 4.3713 (6.2); 4.3614 (9.3); 4.3578 (5.4); 4.3458 (8.9); 4.3337 (4.6); 4.0592 (3.1); 4.0491 (6.3); 4.0139 (4.4); 4.0041 (9.0); 3.8477 (1.1); 3.8417 (1.5); 3.8355 (1.7); 3.8295 (1.7);

3.8255 (2.1); 3.8194 (2.7); 3.8131 (3.6); 3.8072 (11.9); 3.8018 (11.4); 3.7952 (9.3); 3.7852 (1.3); 3.7620 (7.1); 3.7568 (7.4); 3.7501 (6.8); 3.7449 (9.6); 3.7333 (6.5); 3.7306 (10.0); 3.7288 (7.4); 3.7225 (10.8);

3.7168 (9.2); 3.7135 (3.3); 3.7083 (16.0); 3.7019 (7.7); 3.6944 (9.8); 3.6910 (9.0); 3.6877 (8.6); 3.6767 (7.0); 3.6739 (8.3); 3.6630 (4.9); 3.6216 (1.8); 3.6154 (2.5); 3.6089 (3.2); 3.6019 (3.4); 3.5947 (3.3);

3.5881 (2.7); 3.5819 (2.0); 2.7856 (1.4); 2.7732 (1.3); 2.7651 (1.5); 2.7526 (1.7); 2.7503 (1.8); 2.7416 (1.4); 2.7378 (1.7); 2.7298 (2.5); 2.7209 (1.4); 2.7173 (1.6); 2.7092 (1.4); 2.7065 (1.4); 2.6946 (1.2);

2.6857 (1.2); 2.6739 (1.1); 2.5988 (1.5); 2.5777 (2.9); 2.5633 (2.0); 2.5566 (1.8); 2.5422 (3.3); 2.5270 (1.9); 2.5212 (1.8); 2.5061 (3.4); 2.4916 (2.2); 2.4851 (2.0); 2.4707 (3.8); 2.4497 (1.8); 2.0453 (1.7);

2.0375 (2.9); 2.0296 (1.7); 2.0083 (2.7); 2.0003 (6.0); 1.9919 (2.8); 1.9784 (1.6); 1.9723 (1.9); 1.9646 (4.3); 1.9548 (2.1); 1.9430 (1.3); 1.9323 (1.4); 1.9284 (1.3); 1.9168 (1.1); 1.9064 (1.2); 1.8935 (1.5);

1.8815 (1.1); 1.8710 (1.0); 1.8595 (1.0); 1.5561 (14.6); 1.2561 (0.9); 0.0080 (3.0); -0.0002 (91.0); -0.0085 (3.5)

1-089: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7480 (2.9); 7.7449 (6.1); 7.7417 (6.7); 7.7382 (6.7); 7.7344 (6.2); 7.7307 (3.0); 7.6680 (1.4); 7.6641 (1.6); 7.6617 (1.9); 7.6583 (2.7); 7.6546 (2.5); 7.6522 (2.9); 7.6484 (3.3); 7.6460 (3.1); 7.6422 (2.7);

7.6399 (2.2); 7.6364 (2.8); 7.6328 (2.5); 7.6303 (2.8); 7.6266 (3.0); 7.6241 (1.6); 7.6205 (1.1); 7.5200 (0.6); 7.4964 (1.7); 7.4932 (1.9); 7.4901 (1.9); 7.4873 (2.8); 7.4844 (2.9); 7.4811 (3.5); 7.4779 (3.9);

7.4748 (2.9); 7.4712 (2.0); 7.4683 (2.8); 7.4654 (2.9); 7.4623 (2.9); 7.4592 (2.4); 7.4565 (1.4); 7.3183 (1.0); 7.3110 (1.0); 7.2966 (1.7); 7.2744 (1.3); 7.2612 (102.3); 6.9971 (0.6); 6.7656 (0.7); 6.7434 (1.0);

6.7211 (0.6); 6.0721 (0.9); 6.0679 (1.1); 6.0662 (1.1); 6.0618 (1.1); 6.0585 (1.5); 6.0540 (1.9); 6.0481 (1.9); 6.0454 (2.1); 6.0412 (1.9); 6.0392 (2.2); 6.0350 (2.0); 6.0291 (2.4); 6.0257 (2.5); 6.0225 (2.4);

6.0161 (1.4); 6.0128 (1.4); 6.0095 (1.4); 6.0062 (1.2); 5.9552 (1.4); 5.9496 (2.5); 5.9439 (1.6); 5.9358 (1.9); 5.9304 (1.1); 5.9014 (0.7); 5.8956 (1.4); 5.8873 (1.9); 5.8817 (3.2); 5.8760 (2.0); 5.8678 (1.8);

5.8622 (1.0); 5.8443 (0.9); 5.8385 (1.7); 5.8326 (1.1); 5.8306 (1.0); 5.8246 (1.5); 5.8188 (0.8); 5.2990 (0.5); 5.1822 (0.6); 5.1717 (0.7); 5.1674 (0.6); 5.1628 (0.7); 5.1571 (0.7); 5.1527 (0.8); 5.1474 (0.7);

5.1424 (0.6); 5.1262 (0.6); 5.1212 (0.7); 5.0983 (1.5); 5.0794 (1.5); 5.0592 (0.6); 4.4290 (4.5); 4.4218 (0.8); 4.4172 (3.8); 4.4151 (5.2); 4.4123 (3.6); 4.4060 (3.1); 4.4012 (6.5); 4.3926 (4.8); 4.3872 (3.9);

4.3777 (3.6); 4.3745 (4.6); 4.3635 (4.3); 4.3588 (2.7); 4.3499 (2.7); 4.3475 (4.4); 4.3363 (2.2); 4.0552 (1.1); 4.0492 (1.4); 4.0375 (3.5); 4.0098 (1.6); 4.0039 (2.0); 3.9924 (4.9); 3.8489 (0.6); 3.8428 (0.8);

3.8366 (0.9); 3.8305 (0.8); 3.8270 (1.2); 3.8211 (1.4); 3.8150 (1.4); 3.8090 (1.0); 3.8051 (0.7); 3.7992 (0.7); 3.7933 (0.8); 3.7834 (5.1); 3.7779 (5.4); 3.7708 (4.6); 3.7443 (5.4); 3.7381 (4.2); 3.7328 (7.5);

3.7303 (6.7); 3.7279 (5.4); 3.7253 (9.3); 3.7163 (6.0); 3.7110 (8.6); 3.7062 (1.7); 3.7029 (3.9); 3.6971 (5.3); 3.6932 (3.7); 3.6886 (4.2); 3.6791 (3.2); 3.6748 (3.6); 3.6653 (2.4); 3.6250 (1.0); 3.6189 (1.4);

- 95 044070

3.6114 (1.6); 3.6061 (1.7); 3.5996 (1.6); 3.5920 (1.5); 3.5861 (1.1); 2.7894 (0.7); 2.7770 (0.7); 2.7688 (0.8); 2.7564 (0.9); 2.7540 (0.9); 2.7460 (0.7); 2.7415 (0.9); 2.7338 (1.1); 2.7253 (0.7); 2.7211 (0.8);

2.7135 (0.7); 2.7108 (0.7); 2.6990 (0.6); 2.6901 (0.6); 2.6784 (0.6); 2.5921 (0.8); 2.5711 (1.6); 2.5566 (1.1); 2.5500 (1.0); 2.5355 (1.8); 2.5207 (1.0); 2.5145 (1.0); 2.4999 (1.8); 2.4853 (1.2); 2.4789 (1.1);

2.4644 (2.0); 2.4435 (1.0); 2.0458 (0.9); 2.0382 (1.6); 2.0306 (0.9); 2.0097 (1.7); 2.0020 (3.1); 1.9979 (1.5); 1.9945 (1.8); 1.9871 (0.8); 1.9753 (1.2); 1.9657 (2.2); 1.9586 (1.0); 1.9517 (0.7); 1.9406 (0.6);

1.9298 (0.7); 1.9260 (0.6); 1.9143 (0.6); 1.9040 (0.6); 1.8923 (0.7); 1.8790 (0.5); 1.8572 (0.5); 1.5528 (16.0); 1.3072 (1.0); 1.2976 (0.7); 1.2893 (0.7); 1.2798 (0.6); 1.2649 (1.4); 0.8985 (0.7); 0.8818 (2.3); 0.8641 (0.9); 0.0080 (1.8); -0.0002 (56.4); -0.0085 (2.0)

1-090: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7620 (2.0); 7.7587 (3.8); 7.7553 (2.3); 7.7491 (1.0); 7.7456 (2.1); 7.7414 (3.7); 7.7374 (4.6); 7.7339 (2.4); 7.6600 (0.6); 7.6556 (1.8); 7.6496 (2.0); 7.6459 (2.4); 7.6423 (1.5); 7.6398 (1.7); 7.6337 (2.0);

7.6296 (2.0); 7.6240 (2.4); 7.6205 (1.5); 7.6181 (1.4); 7.6143 (1.2); 7.4968 (0.8); 7.4935 (0.8); 7.4909 (0.8); 7.4879 (0.8); 7.4815 (2.2); 7.4782 (3.0); 7.4755 (2.9); 7.4723 (2.6); 7.4626 (2.2); 7.4593 (2.3);

7.4565 (2.0); 7.4533 (1.8); 7.3357 (1.0); 7.3251 (1.2); 7.3115 (1.2); 7.3039 (1.1); 7.2613 (67.3); 6.7814 (0.6); 6.0809 (1.3); 6.0760 (1.4); 6.0718 (1.7); 6.0666 (1.8); 6.0602 (2.2); 6.0570 (2.4); 6.0524 (1.4);

6.0497 (1.1); 6.0457 (1.2); 6.0424 (1.2); 6.0392 (1.2); 6.0359 (1.1); 5.9810 (1.1); 5.9754 (1.9); 5.9697 (1.2); 5.9674 (1.0); 5.9616 (1.5); 5.9560 (0.9); 5.9200 (1.0); 5.9178 (1.2); 5.9122 (2.3); 5.9064 (1.8);

5.8984 (1.7); 5.8928 (0.9); 5.8624 (0.7); 5.8485 (0.6); 5.2991 (1.8); 5.1044 (0.8); 5.0826 (1.6); 5.0620 (0.8); 4.1505 (1.1); 4.1326 (3.4); 4.1147 (3.4); 4.0969 (1.1); 4.0727 (0.5); 4.0634 (0.6); 4.0391 (2.4);

4.0276 (0.8); 4.0181 (0.8); 3.9939 (3.4); 3.8371 (0.5); 3.8311 (0.7); 3.8252 (0.7); 3.8192 (0.5); 3.7884 (2.5); 3.7824 (3.9); 3.7705 (3.7); 3.7431 (1.9); 3.7373 (2.9); 3.7253 (2.8); 3.6264 (1.2); 3.6211 (1.3);

3.6143 (1.3); 3.6093 (1.3); 3.6041 (1.3); 2.6070 (0.6); 2.5860 (1.3); 2.5714 (0.9); 2.5650 (0.8); 2.5505 (1.4); 2.5295 (1.3); 2.5086 (1.3); 2.4941 (1.0); 2.4878 (0.8); 2.4733 (1.4); 2.4525 (0.7); 2.0643 (0.8);

2.0564 (1.4); 2.0461 (16.0); 2.0287 (0.6); 2.0209 (1.2); 2.0129 (0.7); 1.9923 (0.8); 1.9843 (1.4); 1.9757 (1.0); 1.9568 (0.7); 1.9491 (1.3); 1.9407 (0.8); 1.2774 (4.5); 1.2595 (9.2); 1.2416 (4.4); 0.0079 (1.2); 0.0002 (39.6); -0.0085 (1.4)

1-091: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5195 (0.6); 7.2725 (0.9); 7.2607 (100.5); 7.1863 (0.6); 7.1740 (2.7); 7.1682 (3.5); 7.1656 (4.1); 7.1598 (3.9); 7.1570 (3.5); 7.1542 (3.8); 7.1485 (4.1); 7.1458 (3.5); 7.1401 (2.8); 7.1280 (0.6); 7.1030 (0.8); 7.0832 (1.5); 7.0629 (0.9); 6.9966 (0.6); 6.8942 (0.9); 6.8887 (1.6); 6.8826 (1.0); 6.8723 (1.8);

6.8668 (3.0); 6.8617 (1.7); 6.8514 (1.0); 6.8454 (1.6); 6.8399 (0.9); 5.9704 (1.4); 5.9668 (1.3); 5.9645 (1.4); 5.9608 (1.5); 5.9566 (2.2); 5.9529 (2.8); 5.9504 (2.6); 5.9468 (2.6); 5.9427 (1.4); 5.9390 (1.5);

5.9348 (1.8); 5.9319 (2.1); 5.9287 (2.6); 5.9049 (1.4); 5.8994 (2.6); 5.8939 (1.5); 5.8912 (1.1); 5.8856 (1.8); 5.8801 (1.0); 5.8179 (1.2); 5.8122 (2.3); 5.8065 (1.4); 5.8043 (1.3); 5.7985 (2.0); 5.7929 (1.1);

5.2096 (0.8); 5.2061 (1.4); 5.2024 (0.8); 5.0531 (1.3); 5.0348 (1.2); 5.0315 (1.2); 4.2272 (2.3); 4.2093

- 96 044070 (7.2); 4.2013 (2.3); 4.1915 (7.5); 4.1834 (7.0); 4.1736 (2.8); 4.1703 (2.0); 4.1656 (7.2); 4.1526 (1.7);

4.1478 (2.5); 4.1420 (0.5); 4.1348 (0.6); 3.8245 (4.5); 3.8229 (4.5); 3.7811 (5.4); 3.7796 (5.4); 3.5261 (0.9); 3.5229 (1.0); 3.5079 (1.7); 3.5020 (1.7); 3.4991 (1.6); 3.3436 (4.0); 3.3382 (4.0); 3.3003 (3.3);

3.2948 (3.4); 2.5767 (0.9); 2.5556 (1.6); 2.5418 (1.1); 2.5345 (1.0); 2.5207 (1.8); 2.5127 (1.2); 2.4996 (1.0); 2.4916 (2.2); 2.4778 (1.4); 2.4706 (1.3); 2.4567 (2.4); 2.4356 (1.2); 1.9582 (1.3); 1.9486 (1.6);

1.9392 (0.9); 1.9233 (1.1); 1.9137 (1.5); 1.9043 (0.8); 1.8939 (1.0); 1.8839 (1.6); 1.8740 (0.9); 1.8589 (0.8); 1.8491 (1.4); 1.8393 (0.8); 1.5707 (1.1); 1.5578 (3.6); 1.5535 (2.8); 1.5504 (2.3); 1.5442 (1.4);

1.5398 (2.6); 1.5367 (2.6); 1.5265 (1.5); 1.5233 (1.6); 1.5190 (1.5); 1.5160 (1.3); 1.5055 (0.8); 1.5024 (0.7); 1.3210 (7.7); 1.3032 (15.9); 1.2988 (3.2); 1.2914 (8.1); 1.2853 (8.2); 1.2809 (5.2); 1.2735 (16.0); 1.2631 (2.7); 1.2557 (7.9); 1.2463 (0.7); 0.8437 (0.9); 0.8240 (0.8); 0.7171 (0.8); 0.7134 (0.8); 0.7038 (0.9); 0.6997 (0.9); 0.6927 (0.7); 0.6887 (1.0); 0.6793 (1.1); 0.6760 (0.9); 0.6684 (1.0); 0.6652 (0.9);

0.6592 (0.9); 0.6496 (0.8); 0.6457 (1.2); 0.6365 (1.2); 0.6323 (0.8); 0.6234 (0.8); 0.5926 (0.6); 0.5803 (1.3); 0.5711 (2.0); 0.5685 (2.4); 0.5647 (2.6); 0.5619 (2.6); 0.5526 (3.0); 0.5501 (2.8); 0.5473 (2.9);

0.5442 (3.1); 0.5410 (3.2); 0.5373 (1.8); 0.5317 (3.3); 0.5236 (1.6); 0.5198 (1.7); 0.5102 (2.0); 0.5049 (1.1); 0.4978 (1.2); 0.4912 (1.2); 0.4847 (1.3); 0.4729 (1.7); 0.4693 (2.2); 0.4602 (1.9); 0.4558 (1.6);

0.4496 (0.8); 0.4470 (0.8); 0.4411 (0.9); 0.4362 (0.6); 0.4324 (0.5); 0.0080 (1.6); -0.0002 (55.2); -0.0084 (2.2)

1-094: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5185 (6.9); 7.3095 (5.2); 7.2923 (1.9); 7.2596 (1208.8); 7.2462 (3.8); 7.2334 (1.7); 7.2100 (2.2); 7.1714 (8.9); 7.1655 (12.8); 7.1620 (16.8); 7.1562 (16.4); 7.1516 (15.5); 7.1456 (16.7); 7.1421 (14.2); 7.1367 (9.4); 7.1000 (3.0); 7.0790 (3.5); 7.0450 (2.8); 6.9956 (7.0); 6.8970 (3.5); 6.8895 (5.8); 6.8838 (4.7); 6.8750 (6.6); 6.8680 (10.0); 6.8621 (6.0); 6.8521 (3.3); 6.8466 (5.1); 6.6739 (1.5); 6.0153 (4.5);

6.0013 (10.2); 5.9951 (10.9); 5.9912 (9.5); 5.9836 (8.4); 5.9771 (5.9); 5.9654 (3.8); 5.9330 (4.7); 5.9274 (8.2); 5.9218 (4.9); 5.9136 (5.9); 5.9080 (3.7); 5.9004 (2.2); 5.8864 (1.6); 5.8633 (4.2); 5.8576 (7.7);

5.8518 (5.0); 5.8438 (6.6); 5.8274 (1.5); 5.2328 (4.3); 5.1372 (1.6); 5.0264 (4.8); 3.8226 (12.7); 3.8133 (12.2); 3.7792 (16.0); 3.7699 (14.7); 3.5901 (5.2); 3.3615 (5.5); 3.3499 (13.1); 3.3446 (12.6); 3.3181 (4.6); 3.3065 (10.9); 3.3012 (10.9); 2.7662 (1.2); 2.7108 (1.2); 2.6341 (2.7); 2.6129 (5.2); 2.5989 (3.6);

2.5917 (3.4); 2.5774 (5.7); 2.5524 (6.1); 2.5386 (4.2); 2.5312 (3.5); 2.5172 (6.1); 2.4960 (3.2); 2.0166 (3.6); 2.0069 (5.6); 1.9974 (3.1); 1.9818 (3.2); 1.9716 (5.0); 1.9617 (3.0); 1.9451 (3.8); 1.9346 (6.2);

1.9241 (4.1); 1.9099 (3.6); 1.8993 (5.4); 1.8889 (3.5); 1.8496 (1.4); 1.5743 (3.0); 1.5654 (4.4); 1.5535 (6.5); 1.5442 (7.8); 1.5401 (8.6); 1.5313 (5.5); 1.5239 (4.4); 1.5195 (4.7); 1.5058 (2.6); 1.4322 (2.6);

1.3050 (2.4); 1.2878 (2.4); 1.2555 (2.8); 0.9562 (1.6); 0.9033 (1.3); 0.8794 (1.8); 0.8774 (2.9); 0.8732 (1.7); 0.8369 (2.0); 0.8346 (1.8); 0.8301 (2.9); 0.8235 (4.0); 0.8221 (3.2); 0.8176 (3.4); 0.8105 (2.5);

0.8087 (1.9); 0.8072 (2.0); 0.8033 (2.8); 0.8016 (3.4); 0.7984 (2.6); 0.7945 (2.0); 0.7885 (1.7); 0.7851 (1.7); 0.7685 (1.4); 0.6938 (2.2); 0.6691 (5.7); 0.6608 (6.2); 0.6561 (5.4); 0.6467 (4.8); 0.6417 (4.8);

0.6321 (5.2); 0.6188 (3.8); 0.5776 (6.6); 0.5720 (6.8); 0.5675 (10.1); 0.5638 (9.9); 0.5589 (11.4); 0.5470

- 97 044070 (11.4); 0.5374 (11.3); 0.5281 (7.7); 0.5246 (7.3); 0.5149 (5.7); 0.5065 (2.7); 0.4983 (2.7); 0.4776 (4.6); 0.4728 (5.7); 0.4685 (6.4); 0.4599 (6.6); 0.4545 (5.6); 0.4464 (4.8); 0.4356 (3.2); 0.4260 (1.8); 0.1459 (2.5); 0.0498 (2.3); 0.0080 (22.1); -0.0002 (690.0); -0.0085 (25.8); -0.0496 (1.7); -0.1496 (2.6)

1-095: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9437 (0.6); 7.9406 (0.5); 7.9313 (0.6); 7.8366 (0.5); 7.7049 (0.6); 7.6888 (0.5); 7.6854 (0.7); 7.5487 (0.6); 7.5291 (1.0); 7.2611 (16.5); 3.8517 (0.6); 3.8456 (0.7); 3.8086 (0.7); 3.8025 (0.8); 3.2291 (0.7);

3.2177 (0.6); 3.1859 (0.6); 3.1745 (0.5); 1.7360 (3.4); 1.7297 (1.0); 1.7212 (4.0); 1.4816 (13.0); 1.4400 (16.0); 1.4243 (1.6); -0.0002 (9.5)

1-096: !H-NMR(400.0 MHz, CDC13):

δ= 7.7373 (16.0); 7.7335 (15.3); 7.7298 (11.6); 7.6690 (2.0); 7.6628 (2.7); 7.6593 (5.1); 7.6532 (5.8); 7.6495 (6.3); 7.6473 (6.5); 7.6438 (5.4); 7.6412 (5.1); 7.6375 (5.5); 7.6313 (5.6); 7.6277 (5.9); 7.5192 (1.7); 7.4976 (4.6); 7.4946 (5.1); 7.4903 (5.8); 7.4871 (5.4); 7.4839 (5.5); 7.4809 (7.4); 7.4783 (6.8);

7.4716 (5.6); 7.4682 (5.1); 7.4650 (4.6); 7.4620 (3.8); 7.4590 (2.3); 7.2603 (278.8); 7.1921 (2.6); 7.1695 (2.6); 6.9963 (1.6); 6.9470 (1.2); 6.9099 (2.1); 6.9041 (1.3); 6.8828 (1.1); 6.8776 (1.6); 6.8729 (1.1);

6.7742 (1.2); 6.7522 (1.8); 6.7304 (1.1); 6.0587 (1.6); 6.0530 (1.9); 6.0452 (2.7); 6.0401 (4.0); 6.0346 (4.2); 6.0249 (4.4); 6.0213 (5.3); 6.0180 (4.2); 6.0145 (4.0); 6.0077 (2.6); 6.0047 (2.5); 6.0012 (2.3);

5.9811 (2.2); 5.9755 (3.8); 5.9699 (2.3); 5.9617 (2.4); 5.9562 (1.4); 5.9334 (1.6); 5.9277 (3.0); 5.9220 (1.9); 5.9138 (4.5); 5.9082 (5.1); 5.9026 (2.5); 5.8945 (3.1); 5.8888 (1.8); 5.8777 (1.7); 5.8719 (3.1);

5.8660 (1.9); 5.8579 (2.7); 5.8522 (1.4); 5.1556 (1.5); 5.1501 (1.4); 5.1449 (1.2); 5.1244 (1.3); 5.1032 (2.2); 5.0860 (2.1); 4.7178 (0.6); 4.7084 (1.0); 4.6986 (1.3); 4.6886 (1.4); 4.6783 (1.4); 4.6690 (1.0);

4.6589 (0.6); 4.5786 (1.3); 4.5734 (2.8); 4.5669 (2.0); 4.5578 (4.1); 4.5522 (9.7); 4.5461 (6.6); 4.5368 (4.4); 4.5311 (12.9); 4.5253 (9.5); 4.5101 (8.2); 4.5053 (9.9); 4.4928 (7.7); 4.4892 (2.9); 4.4839 (6.6);

4.4719 (7.5); 4.4626 (2.0); 4.4509 (2.5); 4.0532 (2.4); 4.0475 (2.8); 4.0332 (5.8); 4.0080 (3.4); 4.0018 (3.9); 3.9881 (8.3); 3.9064 (1.0); 3.9003 (1.3); 3.8941 (1.5); 3.8847 (2.0); 3.8786 (2.5); 3.8727 (2.4);

3.8667 (1.8); 3.8571 (1.4); 3.8513 (1.3); 3.8455 (0.9); 3.7906 (4.6); 3.7851 (13.1); 3.7796 (8.0); 3.7721 (7.8); 3.7453 (3.3); 3.7398 (9.6); 3.7344 (5.6); 3.7270 (5.7); 3.6504 (2.4); 3.1213 (1.0); 3.1106 (1.2);

3.1014 (1.1); 3.0908 (1.0); 3.0687 (1.1); 3.0509 (1.3); 3.0112 (0.5); 2.7935 (1.2); 2.7811 (1.3); 2.7730 (1.4); 2.7605 (1.5); 2.7578 (1.7); 2.7460 (2.2); 2.7372 (1.8); 2.7254 (2.2); 2.7143 (1.4); 2.7112 (1.4);

2.6997 (1.3); 2.6906 (1.2); 2.6787 (1.3); 2.6499 (1.4); 2.6289 (2.7); 2.6144 (1.9); 2.6078 (2.1); 2.5932 (3.4); 2.5724 (2.1); 2.5597 (1.5); 2.5537 (3.8); 2.5390 (2.5); 2.5326 (2.1); 2.5181 (3.4); 2.4972 (2.4);

2.4490 (0.6); 2.0437 (1.5); 2.0350 (2.8); 2.0304 (1.9); 2.0268 (1.7); 2.0195 (1.5); 2.0080 (3.6); 1.9983 (5.6); 1.9905 (2.8); 1.9840 (1.5); 1.9723 (2.1); 1.9629 (4.0); 1.9540 (1.7); 1.9415 (1.2); 1.9294 (1.6); 1.9164 (1.2); 1.9062 (1.0); 1.8944 (1.1); 1.5410 (15.3); 1.2569 (0.7); 0.1462 (0.7); 0.0080 (5.0); -0.0002 (157.1); -0.0084 (5.9); -0.1498 (0.6)

1-101: ¹ H-NMR(400.0 MHz, CDC13):

- 98 044070 δ= 7.2622 (7.1); 7.1906 (1.4); 7.1849 (1.8); 7.1815 (1.4); 7.1742 (1.5); 7.1708 (2.0); 7.1650 (1.7); 7.1586 (0.7); 7.1559 (0.8); 7.1530 (0.7); 6.8969 (0.6); 6.8811 (0.6); 6.8753 (1.1); 6.8694 (0.6); 6.8536 (0.5); 6.2000 (1.1); 6.1732 (1.2); 6.1569 (1.2); 6.1301 (1.3); 5.9816 (0.6); 5.9778 (0.6); 5.9755 (0.6); 5.9716 (0.6); 5.9678 (0.7); 5.9640 (0.8); 5.9617 (0.7); 5.9578 (0.6); 5.8813 (0.8); 5.8758 (1.3); 5.8702 (0.8); 5.8678 (0.6); 5.8620 (1.0); 5.8564 (0.6); 5.5499 (1.7); 5.5483 (2.0); 5.5068 (1.5); 5.5051 (1.7); 5.3374 (1.5); 5.3362 (1.6); 5.3106 (1.5); 5.3094 (1.5); 5.2991 (5.9); 4.2956 (1.0); 4.2838 (2.0); 4.2714 (1.9); 4.2607 (1.0); 3.9374 (1.9); 3.8945 (2.2); 3.6202 (1.4); 3.6187 (1.4); 3.6072 (2.6); 3.5967 (1.2); 3.5949 (1.3); 3.5890 (0.5); 3.5770 (1.0); 3.5652 (0.7); 3.3817 (16.0); 3.3724 (3.3); 3.3305 (0.6); 3.3257 (1.9); 3.2828 (1.7); 2.5078 (0.8); 2.4939 (0.6); 2.4729 (0.9); 1.9218 (0.6); 1.9120 (0.9); 1.8770 (0.8); 1.5856 (1.0); -0.0002 (9.2)

1-102: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2621 (14.9); 7.2022 (0.6); 7.1963 (0.6); 7.1899 (2.8); 7.1842 (3.5); 7.1812 (2.8); 7.1732 (2.6); 7.1701 (3.6); 7.1644 (3.2); 7.1578 (1.5); 7.1523 (1.0); 6.9024 (0.6); 6.8964 (1.3); 6.8904 (0.9); 6.8806 (1.3); 6.8748 (2.2); 6.8689 (1.2); 6.8589 (0.7); 6.8531 (1.0); 6.8473 (0.5); 6.2000 (2.2); 6.1945 (0.5); 6.1732 (2.4); 6.1677 (0.6); 6.1569 (2.6); 6.1513 (0.6); 6.1301 (2.6); 6.1246 (0.6); 5.9804 (1.1); 5.9767 (1.2); 5.9742 (1.1); 5.9703 (1.1); 5.9666 (1.3); 5.9628 (1.4); 5.9604 (1.4); 5.9565 (1.3); 5.8775 (1.4); 5.8720 (2.5); 5.8663 (1.4); 5.8638 (1.2); 5.8581 (1.9); 5.8526 (1.2); 5.8470 (0.5); 5.5496 (3.5); 5.5480 (4.0); 5.5065 (3.1); 5.5048 (3.5); 5.3493 (0.8); 5.3364 (3.0); 5.3350 (3.0); 5.3226 (0.7); 5.3096 (2.9); 5.3081 (2.9); 5.2989 (12.7); 5.0457 (0.5); 5.0364 (0.5); 5.0280 (0.8); 5.0240 (0.8); 4.2886 (2.0); 4.2832 (2.1); 4.2783 (2.4); 4.2762 (2.6); 4.2716 (2.5); 4.2692 (2.3); 4.2641 (2.1); 4.2593 (2.1); 4.2405 (0.8); 4.2304 (0.6); 3.9481 (0.8); 3.9365 (3.9); 3.9050 (0.9); 3.8936 (4.4); 3.6560 (2.9); 3.6517 (1.0); 3.6435 (6.9); 3.6355 (1.0); 3.6321 (2.5); 3.6306 (2.5); 3.6254 (1.0); 3.6132 (1.0); 3.6012 (0.8); 3.5764 (0.6); 3.5724 (0.7); 3.5663 (0.8); 3.5608 (0.8); 3.5531 (2.8); 3.5424 (1.2); 3.5356 (7.0); 3.5250 (1.7); 3.5181 (7.1); 3.5075 (1.6); 3.5006 (2.4); 3.4900 (0.6); 3.3309 (0.9); 3.3252 (3.7); 3.2877 (0.8); 3.2822 (3.3); 2.5265 (0.8); 2.5054 (1.6); 2.4915 (1.1); 2.4844 (1.0); 2.4705 (1.8); 2.4495 (0.9); 2.0700 (0.6); 2.0433 (0.7); 1.9205 (1.0); 1.9105 (1.6); 1.9006 (0.9); 1.8855 (0.8); 1.8757 (1.5); 1.8657 (1.0); 1.5838 (2.3); 1.2585 (0.9); 1.2203 (8.0); 1.2028 (16.0); 1.1853 (7.7); 0.0079 (0.6); -0.0002 (18.4); -0.0085 (0.6) 1-103: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2640 (5.3); 7.1638 (1.7); 7.1574 (1.6); 7.1464 (1.6); 7.0361 (0.6); 7.0153 (0.6); 6.8866 (0.6); 6.8704 (0.8); 6.8650 (1.0); 6.8596 (0.6); 5.9366 (1.0); 5.9314 (1.0); 5.9124 (0.6); 5.8707 (0.7); 5.7794 (0.6); 5.7726 (0.6); 5.7657 (0.5); 3.8291 (1.2); 3.7858 (1.5); 3.4165 (0.7); 3.3440 (1.1); 3.3365 (0.9); 3.3007 (1.0); 3.2931 (0.8); 1.6172 (1.2); 1.5523 (0.6); 1.5457 (0.6); 1.5377 (0.8); 1.5328 (0.8); 1.5247 (0.6); 1.5187 (0.6); 1.4986 (0.6); 1.4785 (14.8); 1.4529 (7.4); 1.4457 (16.0); 1.4352 (1.0); 1.4280 (1.8); 0.5636 (1.2); 0.5438 (1.5); 0.5295 (0.9); 0.5162 (0.6); 0.4855 (0.5); 0.4792 (0.6); 0.4667 (0.7); 0.4551 (0.6); 0.0002 (2.8)

1-104: ¹ H-NMR(400.0 MHz, CDC13):

- 99 044070 δ= 7.4391 (0.6); 7.4177 (0.7); 7.3837 (0.7); 7.3709 (0.6); 7.3650 (0.8); 7.3622 (0.8); 7.2635 (21.8); 7.2072 (0.5); 7.2005 (2.6); 7.1947 (3.1); 7.1913 (2.0); 7.1882 (3.1); 7.1843 (3.5); 7.1816 (4.6); 7.1795 (3.6); 7.1756 (3.2); 7.1736 (2.1); 7.1724 (2.1); 7.1691 (3.3); 7.1663 (2.6); 7.1633 (2.8); 7.1564 (0.7); 7.1504 (0.5); 6.9806 (0.7); 6.9784 (0.8); 6.9748 (1.3); 6.9726 (1.3); 6.9691 (0.8); 6.9669 (0.7); 6.9590 (1.5); 6.9569 (1.6); 6.9533 (2.6); 6.9511 (2.6); 6.9475 (1.5); 6.9454 (1.4); 6.9375 (0.9); 6.9353 (1.0); 6.9317 (1.4); 6.9296 (1.4); 6.9260 (0.8); 6.9238 (0.7); 6.0464 (0.8); 6.0435 (0.9); 6.0397 (1.0); 6.0369 (1.0); 6.0326 (1.3); 6.0298 (1.4); 6.0259 (1.4); 6.0232 (1.4); 6.0099 (1.0); 6.0069 (1.1); 6.0031 (1.1); 6.0004 (1.2); 5.9962 (1.3); 5.9932 (1.3); 5.9895 (1.3); 5.9866 (1.3); 5.9791 (1.3); 5.9736 (2.1); 5.9681 (1.3); 5.9656 (1.0); 5.9599 (1.5); 5.9545 (0.9); 5.8700 (1.1); 5.8645 (1.8); 5.8589 (1.2); 5.8564 (1.1); 5.8507 (1.6); 5.8453 (1.0); 5.2995 (13.1); 5.0582 (1.1); 5.0521 (1.0); 5.0474 (0.8); 5.0410 (0.8); 5.0361 (1.0); 5.0300 (1.2); 5.0082 (0.5); 4.2443 (1.2); 4.2412 (1.2); 4.2264 (3.9); 4.2233 (3.8); 4.2085 (4.0); 4.2055 (3.9); 4.2006 (2.6); 4.1963 (0.6); 4.1906 (1.5); 4.1877 (1.5); 4.1827 (7.3); 4.1649 (7.4); 4.1470 (2.4); 4.1149 (2.6); 4.0965 (2.5); 4.0711 (5.7); 4.0527 (5.7); 4.0075 (5.6); 3.9945 (5.7); 3.9636 (2.6); 3.9506 (2.5); 3.5605 (1.0); 3.5540 (1.0); 3.5467 (1.1); 3.5396 (1.9); 3.5341 (2.0); 3.5271 (1.2); 3.5199 (1.2); 3.5134 (1.1); 2.5295 (0.8); 2.5087 (1.5); 2.4940 (1.0); 2.4879 (0.9); 2.4732 (1.8); 2.4524 (0.9); 2.4482 (0.9); 2.4275 (1.6); 2.4128 (1.0); 2.4069 (0.9); 2.3922 (1.8); 2.3715 (0.9); 2.0828 (0.8); 2.0762 (1.5); 2.0696 (0.9); 2.0473 (0.7); 2.0407 (1.3); 2.0341 (0.8); 1.9800 (0.8); 1.9735 (1.6); 1.9670 (0.9); 1.9446 (0.7); 1.9382 (1.4); 1.9317 (0.8); 1.6059 (0.8); 1.3259 (7.6); 1.3175 (1.2); 1.3081 (15.8); 1.2995 (1.2); 1.2950 (8.1); 1.2902 (8.0); 1.2772 (16.0); 1.2593 (7.7); -0.0002 (12.4); -0.0085 (0.5)

1-105: ¹ H-NMR(400.0 MHz, CDC13):

δ= 8.0165 (1.0); 7.4105 (0.7); 7.4062 (0.8); 7.4039 (0.6); 7.3913 (1.0); 7.3886 (1.0); 7.3864 (1.5); 7.3824 (2.5); 7.3799 (2.1); 7.3782 (2.1); 7.3756 (1.8); 7.3700 (0.8); 7.3675 (1.2); 7.2613 (12.9); 7.1370 (0.5);

7.1297 (0.6); 7.1218 (0.6); 5.9732 (0.5); 5.9694 (0.6); 5.9672 (0.6); 5.9633 (0.6); 5.9594 (0.8); 5.9555 (0.8); 5.9533 (0.8); 5.9495 (0.7); 5.9011 (0.7); 5.8956 (1.3); 5.8900 (0.8); 5.8874 (0.6); 5.8818 (0.9);

5.8762 (0.5); 5.2998 (2.1); 3.8248 (2.0); 3.7816 (2.3); 3.7244 (16.0); 3.4961 (0.7); 3.2356 (2.2); 3.1924 (1.9); 2.4995 (0.9); 2.4855 (0.6); 2.4784 (0.5); 2.4645 (1.0); 2.4435 (0.5); 1.8767 (0.9); 1.8418 (0.8);

1.7150 (11.6); 0.0080 (0.6); -0.0002 (14.9); -0.0084 (0.6)

1-106: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.4007 (0.6); 7.3973 (0.8); 7.3934 (0.9); 7.3908 (0.8); 7.3875 (0.9); 7.3791 (1.1); 7.3753 (3.8); 7.3718 (2.2); 7.3692 (1.8); 7.3622 (1.4); 7.2620 (6.3); 7.1237 (0.6); 7.1168 (0.5); 5.9460 (0.5); 5.9420 (0.6);

5.9398 (0.6); 5.9358 (0.6); 5.9322 (0.7); 5.9282 (0.8); 5.9260 (0.7); 5.9220 (0.6); 5.8108 (0.6); 5.8052 (1.2); 5.7995 (0.7); 5.7971 (0.6); 5.7914 (1.0); 5.7857 (0.6); 3.8270 (2.0); 3.7838 (2.3); 3.7533 (16.0);

3.2238 (2.1); 3.1806 (1.9); 2.5612 (0.8); 2.5474 (0.6); 2.5401 (0.5); 2.5263 (0.9); 1.9630 (0.8); 1.9281 (0.7); 1.7246 (11.4); -0.0002 (6.2)

- 100 044070

1-107: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5191 (0.9); 7.2602 (154.7); 7.1916 (1.4); 7.1859 (2.2); 7.1798 (1.6); 7.1733 (7.3); 7.1677 (8.6);

7.1566 (5.1); 7.1534 (8.3); 7.1478 (6.9); 7.1413 (1.4); 7.1356 (1.3); 7.1297 (0.6); 6.9961 (2.8); 6.9719 (2.3); 6.9009 (1.8); 6.8951 (3.2); 6.8893 (1.8); 6.8792 (3.5); 6.8734 (6.0); 6.8676 (3.2); 6.8575 (1.8);

6.8516 (3.0); 6.8459 (1.6); 5.9818 (2.1); 5.9782 (2.2); 5.9680 (4.6); 5.9643 (5.9); 5.9625 (6.2); 5.9595 (6.1); 5.9540 (6.0); 5.9494 (9.2); 5.9443 (4.6); 5.9403 (1.6); 5.9355 (3.2); 5.9304 (2.1); 5.0737 (1.2);

5.0683 (1.3); 5.0521 (2.2); 5.0465 (2.1); 5.0358 (1.2); 5.0309 (1.2); 5.0258 (1.1); 4.5334 (5.2); 4.5125 (15.7); 4.4915 (16.0); 4.4705 (5.4); 3.9927 (1.2); 3.8632 (1.3); 3.8202 (12.6); 3.8171 (10.7); 3.7738 (11.4); 3.6374 (1.8); 3.6338 (2.0); 3.6283 (2.2); 3.6263 (2.1); 3.6226 (2.3); 3.6174 (2.3); 3.6123 (2.2);

3.6069 (2.1); 3.6014 (1.9); 3.3514 (10.3); 3.3081 (8.7); 3.1802 (1.4); 3.1377 (1.6); 2.5925 (2.5); 2.5715 (4.5); 2.5574 (3.1); 2.5504 (2.8); 2.5364 (5.0); 2.5153 (2.6); 2.3285 (1.8); 1.9278 (2.5); 1.9172 (4.4);

1.9066 (2.4); 1.8927 (2.3); 1.8821 (4.1); 1.8715 (2.3); 1.7286 (8.0); 1.5723 (2.0); 1.5589 (4.0); 1.5515 (4.3); 1.5453 (3.2); 1.5380 (6.2); 1.5309 (2.4); 1.5247 (3.4); 1.5171 (3.2); 1.5037 (1.6); 1.2568 (1.5);

0.6763 (1.0); 0.6700 (1.3); 0.6664 (1.6); 0.6632 (1.4); 0.6603 (1.9); 0.6560 (2.5); 0.6528 (1.8); 0.6463 (2.7); 0.6424 (3.4); 0.6330 (3.4); 0.6290 (2.0); 0.6197 (2.1); 0.5994 (1.3); 0.5904 (1.3); 0.5782 (3.3);

0.5687 (3.3); 0.5648 (2.6); 0.5579 (4.2); 0.5538 (3.3); 0.5478 (4.2); 0.5437 (4.4); 0.5375 (3.1); 0.5335 (4.2); 0.5261 (2.5); 0.5223 (3.4); 0.5127 (3.3); 0.5007 (1.2); 0.4915 (1.5); 0.4834 (2.4); 0.4744 (2.1);

0.4702 (3.7); 0.4611 (3.2); 0.4566 (2.7); 0.4506 (1.8); 0.4471 (2.3); 0.4433 (1.9); 0.4404 (1.5); 0.4371 (1.6); 0.4331 (1.3); 0.4267 (1.0); 0.0079 (3.1); -0.0002 (88.0); -0.0084 (3.3)

1-108: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5192 (1.2); 7.2603 (209.4); 7.2095 (0.5); 7.1918 (1.3); 7.1860 (1.9); 7.1783 (2.2); 7.1723 (3.7);

7.1661 (10.3); 7.1603 (10.6); 7.1572 (7.2); 7.1492 (7.0); 7.1462 (10.6); 7.1405 (8.4); 7.1282 (1.5); 7.1224 (0.6); 6.9962 (1.9); 6.9733 (3.2); 6.9519 (2.9); 6.8990 (2.4); 6.8932 (3.9); 6.8875 (2.3); 6.8773 (4.6);

6.8715 (7.6); 6.8658 (4.0); 6.8555 (2.3); 6.8497 (3.8); 6.8440 (1.9); 5.9645 (4.6); 5.9590 (5.1); 5.9542 (5.0); 5.9505 (5.7); 5.9468 (5.8); 5.9446 (6.1); 5.9406 (4.8); 5.8712 (4.5); 5.8656 (8.4); 5.8598 (5.0);

5.8576 (4.2); 5.8517 (6.4); 5.8461 (3.5); 5.0903 (1.5); 5.0868 (1.7); 5.0688 (2.9); 5.0476 (2.0); 5.0438 (1.9); 4.5761 (0.6); 4.5653 (3.9); 4.5628 (4.1); 4.5552 (0.9); 4.5444 (11.9); 4.5418 (12.3); 4.5336 (1.9);

4.5234 (12.3); 4.5208 (12.4); 4.5125 (4.1); 4.5024 (4.3); 4.4998 (4.2); 4.4916 (3.9); 4.4706 (1.3); 3.9928 (1.3); 3.8632 (1.8); 3.8244 (12.9); 3.8203 (16.0); 3.7811 (14.1); 3.7738 (3.2); 3.6573 (2.0); 3.6526 (2.4);

3.6469 (2.6); 3.6432 (2.8); 3.6358 (3.0); 3.6324 (3.1); 3.6265 (3.0); 3.6220 (2.6); 3.3513 (2.9); 3.3447 (12.6); 3.3080 (2.4); 3.3012 (10.7); 3.1803 (1.8); 3.1378 (2.0); 2.6637 (3.0); 2.6426 (5.3); 2.6286 (3.8);

2.6214 (3.4); 2.6074 (5.8); 2.5863 (3.1); 2.5715 (1.1); 2.5576 (0.8); 2.5504 (0.7); 2.5364 (1.1); 2.5155 (0.6); 2.3284 (1.0); 1.9877 (3.0); 1.9775 (5.4); 1.9673 (3.0); 1.9526 (2.8); 1.9424 (4.8); 1.9321 (2.8);

1.9171 (1.1); 1.9065 (0.6); 1.8927 (0.5); 1.8821 (1.0); 1.8715 (0.5); 1.7930 (0.6); 1.7286 (10.6); 1.5711

- 101 044070 (2.3); 1.5577 (5.8); 1.5502 (7.8); 1.5448 (6.0); 1.5369 (8.6); 1.5298 (3.2); 1.5236 (4.4); 1.5161 (4.1);

1.5027 (2.1); 1.2571 (1.4); 0.7131 (1.5); 0.7103 (1.8); 0.7066 (2.1); 0.7002 (1.7); 0.6955 (2.8); 0.6860 (2.4); 0.6824 (3.8); 0.6734 (3.5); 0.6694 (2.8); 0.6606 (2.5); 0.6461 (0.7); 0.6424 (0.8); 0.6329 (0.9);

0.6195 (0.6); 0.6078 (1.2); 0.5996 (1.3); 0.5863 (3.6); 0.5779 (4.6); 0.5709 (5.2); 0.5685 (5.9); 0.5655 (6.7); 0.5623 (4.5); 0.5574 (4.4); 0.5528 (6.7); 0.5480 (6.0); 0.5443 (4.5); 0.5412 (4.6); 0.5317 (4.5);

0.5192 (1.5); 0.5104 (2.0); 0.5042 (2.6); 0.4960 (2.6); 0.4911 (3.9); 0.4831 (4.1); 0.4781 (2.1); 0.4703 (3.5); 0.4610 (2.6); 0.4584 (2.5); 0.4546 (2.1); 0.0080 (3.8); -0.0002 (120.1); -0.0085 (4.8) 1-109: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5187 (1.3); 7.2599 (220.2); 7.1652 (8.4); 7.1597 (10.6); 7.1454 (10.1); 7.1401 (8.1); 6.9957 (1.3); 6.9122 (2.1); 6.9064 (3.4); 6.9006 (2.4); 6.8905 (4.2); 6.8848 (6.3); 6.8790 (3.7); 6.8689 (2.3); 6.8631 (3.3); 6.8579 (1.9); 6.6755 (3.4); 6.6559 (3.4); 5.9910 (3.1); 5.9862 (4.4); 5.9773 (5.0); 5.9721 (6.4); 5.9672 (4.7); 5.9217 (4.3); 5.9162 (7.4); 5.9104 (4.8); 5.9023 (5.1); 5.8968 (2.9); 5.1464 (2.8); 5.1414 (3.2); 5.1358 (3.0); 5.1310 (2.8); 4.5339 (0.9); 4.5021 (5.6); 4.4811 (15.8); 4.4601 (16.0); 4.4392 (5.5); 3.9925 (0.6); 3.8478 (2.5); 3.8420 (3.3); 3.8360 (3.7); 3.8302 (4.1); 3.8223 (11.7); 3.8141 (4.3); 3.8084 (2.8); 3.7788 (11.2); 3.3591 (10.6); 3.3156 (8.8); 2.7020 (2.6); 2.6903 (2.6); 2.6814 (2.9); 2.6668 (3.9); 2.6547 (3.1); 2.6459 (3.0); 2.6340 (2.8); 1.9156 (2.8); 1.9041 (2.8); 1.8934 (3.0); 1.8809 (4.5); 1.8686 (2.8); 1.8580 (2.6); 1.8467 (2.6); 1.7951 (0.7); 1.5834 (1.7); 1.5700 (3.5); 1.5626 (4.4); 1.5488 (9.6);

1.5363 (10.2); 1.5287 (6.8); 1.5148 (3.0); 1.3555 (0.8); 1.2563 (4.5); 0.8559 (1.3); 0.6571 (2.6); 0.6513 (3.0); 0.6430 (3.1); 0.6380 (3.8); 0.6296 (4.0); 0.6163 (4.2); 0.5960 (3.8); 0.5864 (4.3); 0.5828 (3.9);

0.5754 (5.5); 0.5658 (5.3); 0.5622 (5.6); 0.5533 (5.3); 0.5416 (4.2); 0.5327 (3.6); 0.5200 (1.6); 0.5109 (1.6); 0.4802 (2.3); 0.4679 (4.0); 0.4583 (3.8); 0.4445 (3.2); 0.1457 (0.5); -0.0002 (123.7); -0.1496 (0.7) 1-110: !H-NMR(400.0 MHz, CDC13):

δ= 7.5189 (1.6); 7.2600 (266.5); 7.1632 (10.7); 7.1578 (12.5); 7.1436 (12.1); 6.9960 (1.5); 6.9042 (4.0); 6.8881 (5.2); 6.8823 (7.4); 6.8768 (4.8); 6.8607 (4.0); 6.6874 (3.4); 6.6659 (3.5); 5.9836 (3.8); 5.9781 (5.2); 5.9732 (4.9); 5.9698 (5.1); 5.9646 (5.8); 5.9595 (4.2); 5.9164 (1.2); 5.9025 (0.9); 5.8636 (3.8);

5.8580 (6.6); 5.8518 (4.8); 5.8441 (5.5); 5.8383 (3.0); 5.1300 (3.0); 5.1246 (3.2); 5.1187 (3.1); 5.1139 (2.9); 4.6432 (0.8); 4.6222 (0.7); 4.5740 (0.7); 4.5524 (1.8); 4.5315 (2.2); 4.5178 (5.5); 4.4969 (15.7);

4.4759 (16.0); 4.4602 (3.6); 4.4550 (5.7); 4.4394 (1.1); 3.9929 (0.6); 3.8754 (2.2); 3.8696 (3.1); 3.8634 (3.5); 3.8573 (3.4); 3.8533 (3.3); 3.8477 (3.8); 3.8416 (3.7); 3.8355 (3.3); 3.8188 (10.2); 3.7752 (11.2); 3.3613 (11.4); 3.3177 (9.5); 3.1367 (0.8); 2.7602 (2.4); 2.7479 (2.6); 2.7396 (2.8); 2.7251 (3.8); 2.7124 (3.1); 2.7044 (3.2); 2.6922 (2.9); 2.6667 (0.8); 2.6337 (0.6); 1.9844 (2.6); 1.9732 (2.8); 1.9623 (2.9);

1.9502 (4.0); 1.9380 (2.6); 1.9270 (2.6); 1.9159 (2.9); 1.8932 (0.6); 1.8814 (0.8); 1.8686 (0.7); 1.7944 (0.9); 1.5864 (2.5); 1.5729 (4.8); 1.5655 (5.9); 1.5521 (9.8); 1.5388 (7.9); 1.5313 (6.7); 1.5181 (3.8);

1.3552 (1.0); 1.2572 (4.1); 0.8800 (1.3); 0.6618 (2.8); 0.6576 (3.3); 0.6511 (3.8); 0.6436 (3.7); 0.6378 (4.5); 0.6298 (4.8); 0.6247 (3.6); 0.6162 (4.5); 0.5993 (4.8); 0.5898 (5.4); 0.5777 (7.0); 0.5666 (6.4);

- 102 044070

0.5597 (6.9); 0.5466 (4.9); 0.5382 (3.8); 0.5258 (2.0); 0.5167 (1.9); 0.4836 (2.5); 0.4714 (4.3); 0.4621 (4.2); 0.4582 (3.9); 0.4484 (3.5); 0.4433 (3.5); 0.1465 (0.6); -0.0002 (152.4); -0.1504 (0.8)

1-111: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3618 (1.1); 7.3505 (1.3); 7.3409 (1.3); 7.3296 (1.2); 7.2610 (24.9); 7.1999 (0.6); 7.1941 (0.6); 7.1873 (3.2); 7.1817 (4.6); 7.1784 (3.2); 7.1710 (5.0); 7.1675 (5.9); 7.1653 (6.0); 7.1621 (5.6); 7.1556 (2.6); 7.1513 (3.4); 7.1456 (2.7); 7.1389 (0.6); 7.1332 (0.6); 6.9280 (0.6); 6.9118 (2.0); 6.9099 (2.1);

6.9062 (2.6); 6.9004 (1.7); 6.8940 (2.0); 6.8900 (2.8); 6.8883 (3.2); 6.8844 (3.4); 6.8787 (1.6); 6.8723 (0.9); 6.8666 (1.4); 6.8627 (1.5); 6.8570 (0.7); 6.0459 (0.6); 6.0423 (1.4); 6.0388 (1.7); 6.0361 (1.7);

6.0323 (2.0); 6.0257 (3.0); 6.0223 (3.2); 6.0193 (2.9); 6.0125 (1.5); 6.0085 (1.5); 6.0060 (1.4); 6.0022 (1.3); 5.9412 (1.3); 5.9356 (2.4); 5.9299 (1.4); 5.9276 (1.2); 5.9218 (1.9); 5.9162 (1.1); 5.8992 (0.8);

5.8853 (0.6); 5.8770 (1.3); 5.8713 (2.3); 5.8656 (1.4); 5.8634 (1.2); 5.8575 (1.9); 5.8519 (1.1); 5.8396 (0.7); 5.8257 (0.7); 5.0351 (1.2); 5.0269 (1.2); 5.0222 (1.2); 4.1500 (1.1); 4.1321 (3.4); 4.1143 (3.4);

4.0964 (1.2); 4.0609 (1.0); 4.0420 (3.1); 4.0308 (1.9); 4.0281 (2.9); 4.0203 (0.6); 4.0119 (5.7); 3.9980 (5.8); 3.9556 (6.6); 3.9537 (6.4); 3.9468 (1.8); 3.9389 (1.7); 3.9255 (3.2); 3.9235 (3.2); 3.9167 (1.0);

3.9089 (1.1); 3.8006 (0.6); 3.7945 (0.6); 3.7885 (0.6); 3.7437 (1.0); 3.7407 (1.0); 3.7097 (3.3); 3.7073 (3.3); 3.6994 (1.6); 3.6965 (1.6); 3.6657 (5.6); 3.6632 (5.5); 3.6086 (0.8); 3.6056 (0.8); 3.6021 (1.1);

3.5993 (1.2); 3.5964 (1.4); 3.5935 (1.5); 3.5899 (1.5); 3.5870 (1.6); 3.5841 (1.5); 3.5807 (1.6); 3.5778 (1.5); 3.5747 (1.2); 3.5718 (1.3); 3.5631 (5.4); 3.5511 (4.4); 3.5372 (1.3); 3.5190 (2.8); 3.5070 (2.6);

3.4928 (0.9); 2.6095 (0.7); 2.5884 (1.4); 2.5742 (1.1); 2.5673 (1.0); 2.5531 (1.6); 2.5370 (1.0); 2.5322 (1.0); 2.5160 (1.6); 2.5018 (1.1); 2.4950 (1.0); 2.4809 (1.7); 2.4599 (0.9); 2.0596 (0.9); 2.0454 (16.0);

2.0244 (0.7); 2.0150 (1.3); 2.0055 (0.8); 1.9614 (0.9); 1.9568 (0.6); 1.9520 (1.6); 1.9426 (0.9); 1.9262 (0.7); 1.9168 (1.4); 1.9075 (0.8); 1.2769 (4.5); 1.2590 (9.2); 1.2411 (4.4); 0.0079 (1.0); -0.0002 (32.7); 0.0085 (1.1)

1-112: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5190 (1.3); 7.2601 (235.5); 7.1923 (0.7); 7.1868 (1.5); 7.1745 (7.1); 7.1688 (8.6); 7.1658 (5.3); 7.1577 (5.4); 7.1546 (8.6); 7.1489 (7.1); 7.1367 (1.4); 7.1310 (0.6); 7.0601 (2.4); 7.0381 (2.4); 6.9961 (1.4); 6.8987 (1.8); 6.8929 (3.1); 6.8870 (1.7); 6.8770 (3.5); 6.8712 (6.0); 6.8654 (3.1); 6.8553 (1.9);

6.8494 (3.0); 6.8437 (1.4); 5.9916 (2.8); 5.9879 (3.1); 5.9855 (3.2); 5.9817 (2.9); 5.9778 (4.2); 5.9741 (4.8); 5.9717 (4.7); 5.9680 (4.1); 5.9295 (4.0); 5.9240 (7.4); 5.9185 (4.4); 5.9159 (3.2); 5.9102 (5.0);

5.9046 (2.8); 5.0734 (1.4); 5.0700 (1.4); 5.0482 (2.4); 5.0303 (1.4); 5.0269 (1.3); 4.3876 (7.5); 4.3856 (7.7); 4.3742 (12.7); 4.3713 (10.6); 4.3703 (10.6); 4.3588 (8.9); 4.3577 (9.0); 3.8230 (10.2); 3.7797 (11.9); 3.7164 (14.1); 3.7019 (16.0); 3.6881 (12.3); 3.5720 (2.3); 3.5692 (2.2); 3.5663 (2.3); 3.5633 (2.3); 3.5606 (2.2); 3.5569 (2.3); 3.3467 (10.7); 3.3033 (9.0); 2.5475 (2.5); 2.5263 (4.7); 2.5124 (3.2); 2.5052 (2.8); 2.4913 (5.2); 2.4701 (2.6); 1.9268 (2.6); 1.9171 (4.6); 1.9075 (2.5); 1.8919 (2.2); 1.8821 (4.2); 1.8723 (2.4); 1.7287 (0.5); 1.5730 (1.4); 1.5596 (3.3); 1.5518 (4.9); 1.5439 (15.2); 1.5390 (10.2); 1.5317 (3.0); 1.5254 (3.4); 1.5178 (3.1); 1.5045 (1.5); 1.2565 (1.4); 1.2007 (0.7); 0.8806 (0.5); 0.6792 (1.1);

- 103 044070

0.6735 (1.4); 0.6698 (1.8); 0.6646 (1.9); 0.6592 (2.6); 0.6563 (1.9); 0.6499 (2.6); 0.6458 (3.5); 0.6364 (3.4); 0.6325 (2.1); 0.6233 (2.1); 0.5969 (1.3); 0.5881 (1.2); 0.5756 (3.2); 0.5663 (3.4); 0.5624 (2.8); 0.5565 (3.9); 0.5546 (4.2); 0.5459 (4.1); 0.5436 (3.9); 0.5340 (4.2); 0.5258 (2.6); 0.5224 (3.6); 0.5127 (3.4); 0.5005 (1.2); 0.4914 (1.5); 0.4825 (2.2); 0.4735 (2.2); 0.4693 (3.6); 0.4603 (3.2); 0.4555 (2.4); 0.4467 (2.3); 0.4415 (2.2); 0.4362 (1.7); 0.4324 (1.4); 0.4266 (1.0); 0.0080 (4.4); -0.0002 (135.2); -0.0084 (6.0)

1-113: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5191 (0.8); 7.2602 (140.6); 7.1782 (1.1); 7.1658 (5.3); 7.1603 (6.6); 7.1490 (4.3); 7.1459 (6.5); 7.1403 (5.3); 7.1283 (1.0); 7.0508 (2.0); 7.0296 (2.0); 6.9962 (0.9); 6.8968 (1.3); 6.8911 (2.3); 6.8852 (1.2); 6.8751 (2.7); 6.8693 (4.4); 6.8636 (2.3); 6.8534 (1.4); 6.8475 (2.2); 6.8418 (1.1); 5.9697 (2.3); 5.9635 (2.8); 5.9596 (2.7); 5.9560 (3.1); 5.9520 (3.4); 5.9498 (3.4); 5.9459 (2.8); 5.8448 (2.8); 5.8391 (5.1); 5.8333 (3.3); 5.8253 (4.1); 5.8197 (2.3); 5.0819 (1.2); 5.0596 (2.0); 5.0422 (1.2); 4.4345 (0.6); 4.4185 (4.9); 4.4147 (5.0); 4.4045 (8.3); 4.4008 (7.9); 4.3900 (5.5); 4.3868 (5.4); 4.3703 (0.6); 3.8222 (7.4); 3.7789 (8.8); 3.7449 (8.9); 3.7308 (16.0); 3.7168 (7.2); 3.5925 (1.9); 3.5835 (1.8); 3.5772 (2.0); 3.3404 (7.9); 3.2970 (6.7); 2.6142 (1.8); 2.5931 (3.3); 2.5792 (2.3); 2.5719 (2.0); 2.5580 (3.8); 2.5368 (1.9); 1.9924 (2.0); 1.9829 (3.6); 1.9733 (2.0); 1.9574 (1.8); 1.9478 (3.2); 1.9383 (1.8); 1.5763 (1.0); 1.5630 (2.4); 1.5553 (3.3); 1.5446 (11.2); 1.5289 (2.8); 1.5213 (2.4); 1.5079 (1.2); 1.2561 (1.0); 0.7176 (1.5); 0.7137 (1.7); 0.7021 (2.1); 0.6897 (2.4); 0.6806 (2.1); 0.6769 (1.7); 0.6683 (1.4); 0.6059 (0.7); 0.5986 (0.6); 0.5845 (2.2); 0.5765 (2.7); 0.5717 (4.4); 0.5681 (4.3); 0.5638 (4.2); 0.5551 (3.6); 0.5506 (4.3); 0.5477 (3.9); 0.5429 (3.0); 0.5336 (2.6); 0.5205 (0.8); 0.5123 (1.1); 0.5047 (1.6); 0.4970 (1.7); 0.4917 (2.3); 0.4844 (2.3); 0.4794 (1.4); 0.4725 (2.3); 0.4688 (2.0); 0.4598 (1.7); 0.4551 (1.6); 0.0079 (3.2); -0.0002 (80.0); -0.0084 (3.8)

1-114: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5188 (2.0); 7.2714 (1.3); 7.2599 (375.1); 7.1816 (0.7); 7.1759 (1.4); 7.1634 (6.8); 7.1604 (5.4); 7.1577 (8.0); 7.1545 (4.8); 7.1467 (4.7); 7.1436 (8.1); 7.1379 (6.8); 7.1256 (1.3); 6.9959 (2.1); 6.9080 (1.7); 6.9022 (3.0); 6.8963 (1.6); 6.8863 (3.4); 6.8805 (5.9); 6.8747 (3.0); 6.8646 (1.8); 6.8588 (3.0); 6.8530 (1.4); 6.6721 (2.3); 6.6528 (2.3); 5.9969 (3.4); 5.9927 (3.9); 5.9910 (4.0); 5.9866 (3.6); 5.9831 (4.2); 5.9788 (4.6); 5.9771 (4.6); 5.9728 (4.1); 5.8315 (3.6); 5.8257 (6.9); 5.8199 (4.1); 5.8177 (3.6); 5.8118 (6.0); 5.8060 (3.3); 5.1468 (0.9); 5.1415 (1.1); 5.1361 (1.2); 5.1316 (1.7); 5.1260 (2.2); 5.1212 (2.3); 5.1156 (2.3); 5.1108 (2.1); 5.1053 (1.8); 5.1006 (1.2); 5.0951 (1.3); 5.0901 (0.9); 4.3679 (10.1); 4.3556 (9.8); 4.3539 (12.7); 4.3514 (9.5); 4.3396 (12.8); 3.8202 (10.5); 3.8128 (3.2); 3.8066 (3.1); 3.8006 (2.8); 3.7969 (2.8); 3.7909 (3.2); 3.7846 (3.4); 3.7768 (12.2); 3.6988 (13.6); 3.6868 (8.4); 3.6845 (14.8); 3.6705 (12.3); 3.3580 (10.0); 3.3144 (8.6); 2.7567 (2.8); 2.7443 (2.8); 2.7362 (2.9); 2.7238 (3.4); 2.7216 (3.6); 2.7092 (3.3); 2.7011 (3.0); 2.6887 (2.9); 1.9518 (2.8); 1.9408 (2.7); 1.9298 (2.8); 1.9187 (3.3); 1.9167 (3.2); 1.9057 (2.7); 1.8946 (2.5); 1.8837 (2.6); 1.5862 (1.3); 1.5727 (2.7); 1.5652 (2.8); 1.5587 (2.2); 1.5517 (6.0); 1.5384 (16.0); 1.5175 (2.0); 1.3437 (0.8); 1.2565 (3.2); 0.8804 (1.1); 0.6713 (1.0);

- 104 044070

0.6669 (1.3); 0.6631 (1.6); 0.6587 (2.1); 0.6520 (2.0); 0.6445 (1.9); 0.6388 (3.1); 0.6308 (2.8); 0.6255 (2.1); 0.6169 (3.5); 0.6083 (1.2); 0.5961 (3.5); 0.5867 (3.3); 0.5831 (2.7); 0.5782 (3.6); 0.5752 (5.3);

0.5706 (2.6); 0.5658 (4.5); 0.5623 (2.8); 0.5573 (5.0); 0.5544 (3.5); 0.5494 (2.5); 0.5450 (3.2); 0.5364 (2.9); 0.5236 (1.1); 0.5150 (1.1); 0.4834 (1.8); 0.4750 (2.0); 0.4709 (3.1); 0.4618 (3.1); 0.4579 (1.9);

0.4518 (1.6); 0.4481 (2.1); 0.4425 (2.4); 0.4380 (1.6); 0.4339 (1.3); 0.4287 (1.0); 0.1459 (0.7); 0.0080 (6.4); -0.0002 (217.6); -0.0085 (7.4); -0.1494 (0.6)

1-115: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5187 (2.1); 7.2599 (364.5); 7.1787 (1.5); 7.1661 (7.2); 7.1604 (8.4); 7.1572 (5.0); 7.1494 (5.0);

7.1463 (8.5); 7.1406 (6.8); 7.1341 (1.2); 7.1283 (1.3); 6.9958 (2.0); 6.9110 (1.9); 6.9052 (3.2); 6.8994 (1.7); 6.8893 (3.6); 6.8835 (6.0); 6.8777 (3.0); 6.8676 (1.8); 6.8618 (3.0); 6.8560 (1.5); 6.6637 (2.5);

6.6423 (2.6); 6.0046 (3.3); 6.0002 (3.9); 5.9987 (3.9); 5.9943 (3.6); 5.9907 (4.3); 5.9863 (5.0); 5.9847 (4.8); 5.9804 (4.2); 5.8913 (3.9); 5.8856 (7.2); 5.8799 (4.2); 5.8775 (3.6); 5.8717 (5.8); 5.8660 (3.1);

5.1643 (1.0); 5.1590 (1.2); 5.1531 (1.3); 5.1489 (1.8); 5.1433 (2.2); 5.1381 (2.4); 5.1327 (2.4); 5.1277 (2.3); 5.1222 (1.7); 5.1180 (1.3); 5.1121 (1.2); 5.1067 (0.8); 4.3518 (8.8); 4.3381 (11.7); 4.3354 (9.2);

4.3236 (11.8); 3.8239 (9.8); 3.7971 (1.0); 3.7911 (2.5); 3.7850 (4.0); 3.7803 (13.5); 3.7733 (3.4); 3.7691 (3.0); 3.7632 (3.4); 3.7572 (3.2); 3.7512 (2.4); 3.7451 (0.9); 3.6843 (13.9); 3.6699 (15.5); 3.6560 (12.4); 3.3568 (10.4); 3.3132 (8.7); 2.6997 (2.9); 2.6877 (2.8); 2.6790 (3.0); 2.6669 (3.5); 2.6645 (3.7); 2.6525 (3.3); 2.6438 (3.1); 2.6318 (3.0); 1.8799 (2.9); 1.8686 (2.9); 1.8578 (3.0); 1.8463 (3.8); 1.8334 (2.8);

1.8226 (2.6); 1.8114 (2.6); 1.5840 (1.5); 1.5706 (3.0); 1.5631 (3.3); 1.5568 (2.8); 1.5496 (7.4); 1.5382 (16.0); 1.5291 (5.8); 1.5154 (2.1); 1.3438 (1.0); 1.2569 (4.1); 0.8803 (1.6); 0.6718 (1.0); 0.6662 (1.4); 0.6625 (1.8); 0.6576 (2.1); 0.6517 (2.3); 0.6430 (2.6); 0.6382 (3.3); 0.6297 (3.2); 0.6249 (2.2); 0.6158 (2.7); 0.6049 (1.3); 0.5927 (3.6); 0.5832 (3.4); 0.5795 (2.7); 0.5719 (4.0); 0.5623 (3.6); 0.5595 (4.0);

0.5522 (4.0); 0.5432 (2.5); 0.5391 (3.4); 0.5301 (3.1); 0.5176 (1.3); 0.5086 (1.4); 0.4794 (2.1); 0.4708 (2.0); 0.4667 (3.4); 0.4574 (3.3); 0.4531 (2.3); 0.4472 (1.8); 0.4437 (2.3); 0.4389 (2.0); 0.4337 (1.6);

0.4295 (1.3); 0.4236 (1.0); 0.1459 (0.8); 0.0079 (6.8); -0.0002 (216.9); -0.0085 (7.4); -0.1495 (0.7) 1-116: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9415 (2.8); 7.9375 (3.6); 7.9334 (2.6); 7.9291 (2.1); 7.9251 (1.4); 7.8749 (0.8); 7.8719 (1.0); 7.8673 (1.3); 7.8640 (1.1); 7.8597 (0.9); 7.8517 (2.0); 7.8474 (2.0); 7.8442 (1.3); 7.8398 (1.0); 7.8364 (0.8);

7.8337 (1.1); 7.8318 (1.3); 7.7280 (0.6); 7.7252 (1.2); 7.7214 (1.3); 7.7180 (1.1); 7.7149 (1.6); 7.7112 (1.5); 7.7086 (1.6); 7.7058 (1.6); 7.7021 (1.6); 7.6985 (1.4); 7.6955 (1.8); 7.6919 (1.7); 7.6892 (0.9);

7.5647 (1.1); 7.5555 (1.8); 7.5451 (1.7); 7.5358 (2.8); 7.5254 (0.8); 7.5194 (0.8); 7.5162 (1.2); 7.2606 (98.2); 7.0727 (0.7); 6.9966 (0.6); 6.7955 (0.6); 6.7747 (0.6); 5.9909 (0.6); 5.9831 (1.3); 5.9786 (1.4);

5.9728 (1.4); 5.9703 (1.5); 5.9654 (1.7); 5.9574 (0.7); 5.9537 (0.8); 5.9480 (1.5); 5.9430 (2.0); 5.9375 (0.8); 5.9291 (0.8); 5.9234 (0.9); 5.9176 (1.0); 5.9119 (0.6); 5.9037 (0.7); 5.8588 (0.7); 5.8531 (1.3);

5.8474 (0.9); 5.8438 (1.2); 5.8392 (1.2); 5.8336 (0.7); 5.8297 (0.8); 5.0290 (0.7); 5.0242 (0.7); 4.5696 (1.1); 4.5487 (3.5); 4.5278 (3.9); 4.5162 (0.8); 4.5083 (3.8); 4.4995 (1.0); 4.4953 (2.4); 4.4874 (3.5);

- 105 044070

4.4785 (2.4); 4.4743 (2.5); 4.4665 (1.2); 4.4576 (2.3); 4.4534 (0.9); 4.4366 (0.8); 3.8662 (0.6); 3.8622 (1.6); 3.8550 (2.9); 3.8507 (0.9); 3.8424 (2.3); 3.8392 (0.9); 3.8333 (0.6); 3.8189 (1.8); 3.8117 (3.6); 3.8055 (0.7); 3.7992 (2.5); 3.6327 (0.7); 3.6272 (0.7); 3.4900 (1.2); 3.2436 (1.8); 3.2413 (1.9); 3.2375 (2.4); 3.2286 (2.1); 3.2002 (1.6); 3.1979 (1.7); 3.1944 (2.1); 3.1853 (1.8); 2.6531 (0.5); 2.6319 (0.9); 2.6180 (0.6); 2.6108 (0.5); 2.5968 (0.8); 2.5626 (0.8); 2.5485 (0.6); 2.5415 (0.5); 2.5274 (0.9); 2.5062 (0.5); 2.0044 (0.5); 1.9904 (1.1); 1.9794 (0.6); 1.9673 (0.6); 1.9556 (1.1); 1.9449 (0.6); 1.9171 (0.5); 1.9065 (0.8); 1.8981 (0.6); 1.8715 (0.8); 1.8632 (0.6); 1.7374 (13.7); 1.7347 (16.0); 1.7267 (12.0); 1.5523 (6.9); 0.0080 (1.8); -0.0002 (55.8); -0.0085 (1.8)

1-117: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2601 (29.3); 7.2136 (1.3); 7.2080 (1.6); 7.2046 (1.0); 7.1977 (1.0); 7.1942 (1.6); 7.1886 (1.3); 6.9561 (0.6); 6.9402 (0.7); 6.9344 (1.1); 6.9287 (0.6); 6.9129 (0.6); 6.0133 (0.5); 6.0101 (0.6); 6.0068 (0.6); 6.0035 (0.6); 5.9996 (0.8); 5.9963 (0.8); 5.9931 (0.8); 5.9898 (0.7); 5.9315 (0.7); 5.9260 (1.2);

5.9204 (0.8); 5.9123 (0.9); 5.9067 (0.5); 5.2986 (3.3); 5.0676 (0.5); 3.9956 (1.0); 3.9505 (1.4); 3.7540 (2.6); 3.7411 (16.0); 3.7090 (1.8); 3.5545 (0.6); 3.5483 (0.5); 3.5338 (0.5); 2.4731 (0.9); 2.4587 (0.6);

2.4523 (0.5); 2.4379 (1.0); 2.4170 (0.5); 1.9755 (0.5); 1.9675 (0.9); 1.9323 (0.8); 1.5444 (5.6); 0.0079 (0.5); -0.0002 (16.1); -0.0084 (0.6)

1-118: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2607 (75.3); 7.2476 (2.6); 7.2151 (0.7); 7.2092 (1.0); 7.2039 (1.2); 7.1968 (3.8); 7.1911 (4.7); 7.1861 (6.7); 7.1803 (9.1); 7.1771 (9.1); 7.1713 (7.1); 7.1663 (7.7); 7.1607 (7.1); 7.1564 (3.3); 7.1483 (1.5); 7.1435 (0.9); 6.9356 (0.9); 6.9326 (1.4); 6.9299 (1.4); 6.9239 (1.8); 6.9177 (2.5); 6.9139 (2.6); 6.9111 (3.0); 6.9082 (2.8); 6.9023 (3.3); 6.8980 (3.8); 6.8963 (3.8); 6.8923 (2.8); 6.8903 (2.6); 6.8867 (1.8); 6.8807 (1.9); 6.8763 (2.2); 6.8747 (2.2); 6.8704 (1.8); 6.8459 (1.1); 6.0310 (1.1); 6.0267 (1.3); 6.0249 (1.4); 6.0211 (2.0); 6.0170 (2.4); 6.0111 (3.3); 6.0072 (3.4); 6.0013 (3.8); 5.9975 (3.8); 5.9944 (3.3); 5.9912 (3.0); 5.9876 (2.9); 5.9842 (1.9); 5.9805 (1.6); 5.9276 (1.6); 5.9220 (2.9); 5.9164 (1.7); 5.9139 (1.4); 5.9082 (2.2); 5.9026 (1.3); 5.8884 (1.2); 5.8827 (2.1); 5.8770 (1.3); 5.8746 (1.2); 5.8688 (1.8); 5.8631 (1.1); 5.8561 (1.4); 5.8504 (2.6); 5.8447 (1.6); 5.8425 (1.4); 5.8366 (2.2); 5.8306 (2.0); 5.8245 (2.0); 5.8186 (1.2); 5.8165 (1.2); 5.8105 (1.7); 5.8048 (1.0); 5.1501 (0.6); 5.1447 (0.7); 5.1398 (0.9); 5.1347 (1.0); 5.1290 (1.0); 5.1249 (1.0); 5.1192 (1.1); 5.1140 (1.0); 5.1088 (1.0); 5.1044 (0.8); 5.0987 (0.6); 5.0938 (0.5); 5.0437 (1.6); 5.0340 (1.6); 5.0130 (0.9); 4.4414 (0.7); 4.4253 (3.0); 4.4209 (3.0); 4.4114 (4.5); 4.4071 (4.2); 4.3970 (3.3); 4.3931 (3.2); 4.3841 (3.2); 4.3806 (3.2); 4.3705 (6.1); 4.3667 (5.8); 4.3557 (8.4); 4.3400 (5.8); 4.3272 (3.4); 4.0476 (4.7); 4.0293 (2.8); 4.0206 (4.5); 4.0176 (8.9); 3.9993 (4.9); 3.9907 (7.4); 3.9508 (9.3); 3.9435 (4.9); 3.9344 (4.4); 3.9215 (4.7); 3.9135 (2.6); 3.9044 (2.8); 3.8270 (0.7); 3.8209 (0.9); 3.8147 (1.0); 3.8085 (0.9); 3.8052 (1.1); 3.7991 (1.6); 3.7933 (1.6); 3.7875 (1.4); 3.7819 (1.1); 3.7776 (1.1); 3.7717 (1.3); 3.7658 (1.4); 3.7549 (5.8); 3.7461 (1.5); 3.7409 (9.6); 3.7360 (2.1); 3.7312 (4.1); 3.7268 (5.8); 3.7229 (5.2); 3.7175 (5.1); 3.7148 (7.5); 3.7004 (9.2); 3.6981 (6.4); 3.6866 (16.0); 3.6789 (7.7); 3.6731 (9.5); 3.6699 (6.6); 3.6585 (4.1); 3.6058 (1.0);

- 106 044070

3.6027 (1.0); 3.5975 (1.3); 3.5907 (1.7); 3.5856 (2.0); 3.5762 (2.0); 3.5695 (1.7); 3.5644 (1.7); 3.5573 (6.6); 3.5526 (7.3); 3.5295 (3.5); 3.5133 (3.7); 3.5085 (4.3); 3.4852 (2.2); 2.7529 (0.8); 2.7405 (0.8);

2.7324 (0.9); 2.7182 (1.7); 2.7054 (1.3); 2.6975 (1.7); 2.6846 (1.5); 2.6715 (1.0); 2.6625 (0.9); 2.6509 (0.9); 2.5956 (1.0); 2.5745 (1.8); 2.5603 (1.3); 2.5533 (1.2); 2.5392 (2.0); 2.5314 (1.2); 2.5180 (1.1);

2.5104 (2.0); 2.4962 (1.4); 2.4893 (1.2); 2.4751 (2.2); 2.4540 (1.1); 2.0418 (1.0); 2.0330 (1.8); 2.0240 (1.0); 2.0065 (1.0); 1.9977 (1.8); 1.9890 (1.7); 1.9780 (1.0); 1.9709 (1.3); 1.9671 (1.3); 1.9619 (2.2); 1.9534 (1.7); 1.9426 (0.9); 1.9356 (1.1); 1.9320 (1.0); 1.9266 (1.8); 1.9177 (1.0); 1.8946 (0.9); 1.8830 (0.8); 1.8725 (0.8); 1.8598 (1.1); 1.8477 (0.8); 1.8372 (0.7); 1.8258 (0.8); 1.5565 (4.1); 1.2542 (0.5); 0.0079 (2.6); -0.0002 (78.5); -0.0085 (3.4)

1-119: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9791 (0.7); 7.9761 (0.5); 7.9677 (0.7); 7.7647 (0.7); 7.7484 (0.5); 7.7452 (0.8); 7.7421 (0.5); 7.5968 (0.7); 7.5771 (1.1); 7.5574 (0.5); 7.2613 (4.4); 4.0080 (0.5); 3.9990 (0.5); 3.7933 (0.9); 3.7875 (0.9);

3.7483 (0.7); 3.7424 (0.6); 1.5601 (0.9); 1.4889 (0.6); 1.4822 (15.6); 1.4489 (16.0); 1.4332 (1.2); -0.0002 (5.2)

1-120: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3162 (1.1); 7.3008 (1.1); 7.2636 (9.0); 7.2041 (0.5); 7.1973 (2.6); 7.1916 (3.1); 7.1865 (3.2); 7.1807 (4.2); 7.1775 (4.4); 7.1716 (3.4); 7.1666 (2.8); 7.1609 (2.4); 7.1542 (0.5); 6.9216 (0.8); 6.9158 (1.4);

6.9101 (0.8); 6.8999 (1.6); 6.8941 (2.8); 6.8884 (1.5); 6.8782 (0.8); 6.8724 (1.4); 6.8667 (0.8); 5.9909 (1.0); 5.9872 (1.2); 5.9841 (1.9); 5.9805 (2.0); 5.9772 (2.3); 5.9736 (2.4); 5.9704 (2.5); 5.9668 (2.4);

5.9637 (1.4); 5.9600 (1.1); 5.9008 (1.3); 5.8953 (2.4); 5.8897 (1.4); 5.8872 (1.1); 5.8815 (1.8); 5.8759 (1.0); 5.8284 (1.0); 5.8228 (1.9); 5.8171 (1.2); 5.8147 (1.0); 5.8090 (1.6); 5.8033 (0.9); 5.0506 (0.5);

5.0472 (0.6); 5.0443 (0.7); 5.0411 (0.9); 5.0384 (1.0); 5.0354 (1.1); 5.0326 (1.1); 5.0297 (1.1); 5.0259 (1.0); 5.0222 (1.1); 5.0196 (1.1); 5.0165 (1.2); 5.0137 (1.1); 5.0078 (0.8); 5.0047 (0.6); 5.0016 (0.6);

4.9987 (0.5); 4.2329 (1.9); 4.2151 (6.0); 4.1972 (8.1); 4.1790 (8.5); 4.1611 (7.0); 4.1433 (2.4); 4.0414 (2.5); 4.0190 (2.6); 4.0114 (4.9); 3.9890 (6.1); 3.9538 (10.3); 3.9237 (4.8); 3.7209 (3.2); 3.7179 (2.9); 3.6769 (5.3); 3.6740 (4.8); 3.5591 (4.6); 3.5506 (4.0); 3.5332 (0.8); 3.5304 (0.8); 3.5255 (1.0); 3.5150 (3.9); 3.5114 (1.9); 3.5066 (3.6); 3.4988 (1.1); 3.4926 (0.9); 3.4897 (0.9); 2.5582 (0.8); 2.5372 (1.4);

2.5231 (1.0); 2.5161 (0.9); 2.5020 (1.6); 2.4933 (0.9); 2.4810 (0.8); 2.4723 (1.7); 2.4583 (1.1); 2.4514 (1.0); 2.4373 (1.9); 2.4163 (0.9); 2.0054 (0.8); 1.9966 (1.4); 1.9878 (0.8); 1.9703 (0.7); 1.9615 (1.2); 1.9527 (0.7); 1.9348 (0.9); 1.9257 (1.7); 1.9166 (0.9); 1.8997 (0.8); 1.8907 (1.5); 1.8816 (0.8); 1.3242 (6.7); 1.3063 (13.8); 1.2892 (10.3); 1.2718 (16.0); 1.2611 (0.6); 1.2540 (7.7); -0.0002 (11.9)

1-121: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2672 (6.3); 7.1766 (1.3); 7.1734 (1.2); 7.1708 (1.6); 7.1670 (2.7); 7.1611 (3.3); 7.1569 (3.2); 7.1508 (2.5); 7.1470 (2.9); 7.1414 (2.6); 7.1373 (1.1); 7.0801 (0.7); 6.8943 (0.6); 6.8888 (1.1); 6.8833 (1.2);

6.8785 (1.0); 6.8726 (1.1); 6.8668 (1.5); 6.8617 (1.1); 6.8569 (0.6); 6.8509 (0.6); 6.8459 (0.7); 6.8448 (0.7); 6.0003 (0.5); 5.9986 (0.6); 5.9966 (0.6); 5.9943 (0.6); 5.9907 (1.0); 5.9863 (1.1); 5.9844 (1.1);

- 107 044070

5.9803 (1.2); 5.9783 (1.0); 5.9727 (0.8); 5.9701 (0.7); 5.9658 (1.1); 5.9599 (1.1); 5.9552 (0.6); 5.9517 (0.6); 5.9478 (0.7); 5.9453 (0.7); 5.9415 (0.6); 5.9105 (0.6); 5.9050 (1.1); 5.8994 (0.6); 5.8912 (0.8);

5.8690 (0.9); 5.8632 (0.5); 5.8551 (0.7); 5.8240 (0.6); 5.8183 (1.1); 5.8130 (1.0); 5.8102 (0.7); 5.8076 (1.0); 5.8045 (1.1); 5.8019 (0.6); 5.7992 (0.8); 5.7937 (0.7); 5.0571 (0.6); 5.0541 (0.5); 5.0394 (0.5);

5.0362 (0.5); 4.3124 (1.0); 4.3036 (1.3); 4.3010 (1.9); 4.2914 (2.1); 4.2885 (1.4); 4.2863 (1.2); 4.2803 (1.2); 4.2764 (1.7); 4.2737 (1.4); 4.2662 (1.6); 4.2629 (1.7); 4.2594 (1.0); 4.2557 (1.6); 4.2538 (1.3);

4.2470 (1.5); 4.2429 (1.4); 4.2379 (1.5); 4.2299 (1.2); 4.2252 (0.8); 4.2192 (0.7); 3.8279 (2.0); 3.8249 (2.1); 3.8221 (2.0); 3.7845 (2.8); 3.7817 (2.7); 3.7783 (2.8); 3.7712 (0.7); 3.6399 (2.2); 3.6291 (2.5);

3.6272 (2.4); 3.6160 (2.4); 3.6130 (1.4); 3.6064 (1.7); 3.6013 (2.6); 3.5944 (2.5); 3.5906 (2.9); 3.5829 (2.0); 3.5784 (2.8); 3.5669 (2.0); 3.5618 (0.8); 3.5584 (0.6); 3.4031 (16.0); 3.3877 (10.5); 3.3790 (15.1); 3.3731 (12.3); 3.3554 (2.4); 3.3440 (1.7); 3.3365 (1.9); 3.3118 (2.0); 3.3007 (1.5); 3.2931 (1.6); 2.6825 (0.6); 2.6701 (0.6); 2.5675 (0.8); 2.5536 (0.5); 2.5325 (0.8); 2.5057 (0.7); 2.4708 (0.8); 1.9623 (0.7);

1.9274 (0.7); 1.8967 (0.7); 1.8617 (0.7); 1.5695 (0.7); 1.5618 (0.7); 1.5590 (0.7); 1.5563 (0.8); 1.5486 (1.6); 1.5378 (1.3); 1.5354 (1.6); 1.5277 (1.0); 1.5248 (0.7); 1.5225 (0.6); 1.5170 (0.7); 1.5146 (0.8);

0.6629 (0.6); 0.6604 (0.6); 0.6555 (0.6); 0.6493 (1.0); 0.6402 (0.8); 0.6362 (1.0); 0.6274 (0.9); 0.6230 (0.5); 0.6140 (0.6); 0.5927 (0.6); 0.5895 (0.6); 0.5832 (0.7); 0.5797 (1.2); 0.5754 (0.8); 0.5716 (1.5);

0.5673 (1.7); 0.5626 (1.8); 0.5591 (1.8); 0.5546 (1.3); 0.5511 (1.7); 0.5496 (1.7); 0.5462 (1.8); 0.5426 (1.7); 0.5365 (1.1); 0.5298 (1.3); 0.5221 (0.6); 0.5185 (0.7); 0.5087 (0.9); 0.5059 (0.6); 0.4862 (0.6);

0.4821 (0.6); 0.4777 (0.5); 0.4736 (1.0); 0.4693 (1.3); 0.4649 (0.7); 0.4605 (1.2); 0.4559 (1.2); 0.4500 (0.7); 0.4458 (0.8); 0.4410 (0.8); 0.4363 (0.6); 0.4320 (0.6); -0.0002 (7.8)

1-122: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9778 (11.7); 7.9741 (16.0); 7.9701 (12.1); 7.9656 (9.5); 7.9645 (9.3); 7.9615 (5.8); 7.8996 (3.7); 7.8966 (4.6); 7.8921 (6.8); 7.8890 (5.0); 7.8846 (4.4); 7.8797 (7.5); 7.8771 (9.1); 7.8724 (9.2); 7.8691 (5.6); 7.8679 (5.3); 7.8647 (4.6); 7.8576 (5.6); 7.7870 (2.7); 7.7810 (4.7); 7.7775 (5.4); 7.7744 (7.6);

7.7708 (7.5); 7.7678 (6.8); 7.7650 (6.0); 7.7580 (6.5); 7.7550 (8.9); 7.7514 (8.4); 7.7486 (4.2); 7.6124 (4.9); 7.6049 (5.8); 7.6032 (7.0); 7.6011 (5.6); 7.5927 (8.2); 7.5835 (11.1); 7.5731 (3.8); 7.5656 (4.0);

7.5639 (4.7); 7.5193 (0.6); 7.2603 (119.5); 7.2090 (3.5); 7.1872 (3.4); 6.9963 (0.9); 6.8172 (1.3); 6.7957 (2.1); 6.7723 (1.2); 6.0522 (2.0); 6.0479 (2.4); 6.0463 (2.4); 6.0415 (3.3); 6.0382 (3.2); 6.0325 (5.2);

6.0275 (5.8); 6.0229 (5.1); 6.0197 (6.3); 6.0164 (7.6); 6.0132 (6.2); 6.0097 (6.0); 6.0066 (3.6); 6.0027 (3.5); 6.0000 (3.3); 5.9963 (3.0); 5.9787 (3.5); 5.9733 (6.3); 5.9677 (3.5); 5.9650 (2.4); 5.9594 (3.9);

5.9539 (2.2); 5.9350 (1.9); 5.9293 (3.5); 5.9236 (2.1); 5.9212 (1.8); 5.9154 (2.9); 5.9103 (4.1); 5.9049 (5.5); 5.8992 (3.4); 5.8968 (2.8); 5.8911 (4.4); 5.8855 (2.4); 5.8788 (2.1); 5.8730 (3.9); 5.8671 (2.2);

5.8650 (2.0); 5.8591 (3.3); 5.8532 (1.8); 5.2036 (0.6); 5.1882 (1.1); 5.1826 (1.4); 5.1767 (1.6); 5.1712 (1.4); 5.1657 (1.4); 5.1603 (1.4); 5.1557 (1.8); 5.1500 (1.7); 5.1451 (1.4); 5.1397 (1.0); 5.1294 (1.6);

5.1240 (1.6); 5.1049 (2.9); 5.0985 (2.6); 5.0890 (2.8); 5.0864 (2.9); 5.0678 (1.2); 4.5727 (4.4); 4.5647 (0.8); 4.5518 (13.6); 4.5468 (3.9); 4.5432 (4.1); 4.5310 (14.2); 4.5259 (10.6); 4.5222 (10.6); 4.5103 (6.4);

- 108 044070

4.5048 (12.5); 4.5014 (11.6); 4.4908 (9.5); 4.4831 (8.0); 4.4698 (9.4); 4.4619 (2.4); 4.4489 (3.2); 4.0630 (2.8); 4.0584 (3.2); 4.0453 (5.9); 4.0176 (4.0); 4.0134 (4.5); 4.0003 (8.5); 3.9055 (1.2); 3.8995 (1.6);

3.8933 (1.8); 3.8872 (1.7); 3.8834 (2.4); 3.8773 (3.2); 3.8713 (3.2); 3.8653 (2.5); 3.8608 (1.7); 3.8550 (1.7); 3.8493 (1.5); 3.8433 (1.2); 3.8375 (0.6); 3.8095 (13.4); 3.8040 (12.3); 3.7970 (11.1); 3.7643 (9.6); 3.7589 (8.8); 3.7519 (8.1); 3.6761 (2.0); 3.6733 (2.6); 3.6705 (2.8); 3.6676 (3.0); 3.6640 (3.5); 3.6614 (3.6); 3.6555 (3.4); 3.6520 (3.5); 3.6494 (3.6); 3.6462 (3.1); 3.6404 (2.6); 3.6377 (2.1); 2.7900 (1.5);

2.7777 (1.5); 2.7694 (1.7); 2.7571 (1.9); 2.7544 (2.0); 2.7423 (3.0); 2.7339 (1.9); 2.7309 (1.6); 2.7217 (3.0); 2.7101 (1.6); 2.7071 (1.7); 2.6954 (1.6); 2.6864 (1.5); 2.6747 (1.5); 2.6563 (2.1); 2.6353 (3.8);

2.6208 (2.7); 2.6141 (2.4); 2.5997 (4.2); 2.5795 (3.2); 2.5592 (4.4); 2.5447 (3.0); 2.5382 (2.6); 2.5238 (4.8); 2.5028 (2.4); 2.0426 (2.1); 2.0336 (4.9); 2.0248 (2.3); 2.0110 (2.1); 2.0067 (4.0); 1.9977 (8.3); 1.9887 (3.9); 1.9754 (1.6); 1.9709 (2.2); 1.9621 (3.8); 1.9536 (2.6); 1.9440 (1.5); 1.9323 (1.8); 1.9189 (1.3); 1.9085 (1.2); 1.8969 (1.2); 1.5441 (6.0); 1.2549 (0.5); 0.0080 (4.4); -0.0002 (151.0); -0.0085 (5.3) 1-123: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2625 (36.5); 7.2189 (2.9); 7.2078 (2.6); 7.1954 (7.8); 7.1923 (6.9); 7.1896 (7.9); 7.1853 (9.9); 7.1797 (13.5); 7.1756 (13.0); 7.1699 (10.4); 7.1653 (10.1); 7.1601 (9.9); 7.1550 (4.1); 7.1476 (1.5);

7.1421 (0.9); 6.9391 (1.0); 6.9363 (1.2); 6.9334 (1.9); 6.9306 (2.0); 6.9279 (2.4); 6.9256 (2.3); 6.9223 (3.0); 6.9200 (3.0); 6.9173 (3.1); 6.9146 (3.4); 6.9118 (4.0); 6.9090 (4.0); 6.9062 (4.7); 6.9039 (4.4);

6.9006 (5.5); 6.8983 (5.2); 6.8949 (3.8); 6.8927 (3.7); 6.8902 (2.9); 6.8873 (2.9); 6.8846 (3.4); 6.8823 (3.4); 6.8789 (3.9); 6.8767 (3.7); 6.8732 (2.8); 6.8616 (1.5); 6.8549 (1.4); 6.1420 (1.0); 6.1320 (2.1); 6.1220 (1.0); 6.0993 (1.1); 6.0892 (2.5); 6.0783 (1.9); 6.0753 (0.9); 6.0679 (0.9); 6.0652 (1.5); 6.0552 (0.7); 6.0145 (1.6); 6.0101 (2.0); 6.0084 (2.2); 6.0044 (5.0); 5.9998 (4.6); 5.9945 (9.2); 5.9902 (6.3);

5.9848 (7.8); 5.9817 (5.9); 5.9792 (6.2); 5.9751 (5.0); 5.9722 (3.0); 5.9683 (2.5); 5.9619 (2.4); 5.9517 (5.1); 5.9412 (6.1); 5.9360 (5.4); 5.9304 (4.4); 5.9277 (4.9); 5.9221 (3.3); 5.9172 (2.5); 5.9049 (1.7); 5.8992 (3.0); 5.8935 (1.8); 5.8910 (1.5); 5.8853 (2.4); 5.8796 (1.4); 5.8705 (2.4); 5.8648 (4.2); 5.8571 (4.2); 5.8510 (3.6); 5.8472 (3.2); 5.8416 (3.1); 5.8357 (1.8); 5.8335 (1.7); 5.8276 (2.6); 5.8244 (1.6); 5.8218 (1.6); 5.8143 (2.6); 5.8031 (1.9); 5.8003 (0.9); 5.7929 (0.8); 5.7902 (1.5); 5.7802 (0.7); 5.1578 (0.5); 5.1521 (0.6); 5.1478 (0.7); 5.1426 (1.0); 5.1380 (1.3); 5.1325 (1.4); 5.1270 (1.4); 5.1232 (1.3);

5.1175 (1.4); 5.1125 (1.4); 5.1070 (1.3); 5.1026 (1.1); 5.0970 (0.8); 5.0925 (0.6); 5.0866 (0.6); 5.0613 (1.1); 5.0585 (1.3); 5.0555 (1.3); 5.0526 (1.6); 5.0494 (1.8); 5.0466 (1.9); 5.0435 (2.1); 5.0404 (2.3); 5.0378 (2.3); 5.0315 (2.3); 5.0281 (2.1); 5.0249 (1.9); 5.0223 (1.8); 5.0192 (1.6); 5.0161 (1.3); 5.0133 (1.2); 5.0104 (1.1); 5.0073 (0.9); 4.3870 (3.7); 4.3770 (3.7); 4.3528 (7.7); 4.3428 (10.6); 4.3368 (3.4);

4.3327 (3.8); 4.3266 (3.3); 4.3242 (3.4); 4.3186 (4.5); 4.3141 (3.5); 4.3086 (10.3); 4.3026 (6.3); 4.2986 (6.9); 4.2925 (6.0); 4.2900 (6.0); 4.2799 (5.1); 4.2744 (3.5); 4.2684 (3.2); 4.2645 (3.4); 4.2583 (3.0);

4.2558 (3.1); 4.2457 (2.4); 4.0490 (4.2); 4.0437 (5.6); 4.0309 (3.9); 4.0223 (6.1); 4.0191 (7.2); 4.0137 (9.8); 4.0008 (7.0); 3.9923 (10.9); 3.9472 (16.0); 3.9401 (6.7); 3.9304 (5.9); 3.9171 (8.1); 3.9101 (3.6); 3.9004 (3.7); 3.8535 (0.9); 3.8474 (1.2); 3.8412 (1.3); 3.8351 (1.2); 3.8317 (1.4); 3.8258 (2.2); 3.8198

- 109 044070 (2.1); 3.8143 (1.8); 3.8087 (1.4); 3.8043 (1.2); 3.7983 (1.4); 3.7925 (1.3); 3.7866 (0.9); 3.7327 (4.1); 3.7298 (4.0); 3.7193 (9.5); 3.6886 (6.1); 3.6856 (6.3); 3.6752 (15.4); 3.6388 (0.6); 3.6295 (1.4); 3.6265 (1.3); 3.6208 (1.8); 3.6146 (2.4); 3.6114 (2.6); 3.6084 (2.6); 3.6054 (2.6); 3.6025 (2.6); 3.5997 (2.4); 3.5939 (1.8); 3.5882 (1.4); 3.5847 (1.5); 3.5785 (0.9); 3.5755 (0.7); 3.5563 (8.9); 3.5520 (6.9); 3.5493 (8.8); 3.5265 (4.8); 3.5123 (5.4); 3.5077 (4.2); 3.5052 (5.4); 3.4822 (3.1); 2.7452 (1.2); 2.7327 (1.2); 2.7247 (1.4); 2.7104 (2.3); 2.6976 (1.7); 2.6898 (2.2); 2.6769 (2.1); 2.6639 (1.3); 2.6548 (1.2); 2.6431 (1.2); 2.6232 (1.5); 2.6021 (2.6); 2.5879 (2.0); 2.5810 (1.8); 2.5668 (2.9); 2.5541 (1.7); 2.5457 (1.7); 2.5330 (3.1); 2.5188 (2.2); 2.5120 (1.9); 2.4978 (3.3); 2.4768 (1.8); 2.1707 (0.7); 2.1476 (0.6); 2.1455 (0.8); 2.0300 (1.6); 2.0204 (3.1); 2.0112 (1.7); 2.0082 (1.5); 1.9964 (1.7); 1.9857 (3.6); 1.9759 (1.6); 1.9728 (1.4); 1.9616 (2.7); 1.9516 (3.6); 1.9424 (1.7); 1.9264 (1.5); 1.9168 (2.8); 1.9132 (1.7); 1.9072 (1.6); 1.9015 (1.3); 1.8910 (1.2); 1.8790 (1.6); 1.8661 (1.1); 1.8556 (1.0); 1.8440 (1.0); 1.5841 (0.9); 1.2565 (0.7); 0.0080 (1.7); -0.0002 (47.5); -0.0085 (1.6)

1-124: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3009 (0.5); 7.2883 (0.5); 7.2803 (0.5); 7.2618 (20.5); 7.1986 (1.5); 7.1928 (1.7); 7.1865 (2.1); 7.1805 (3.2); 7.1788 (2.8); 7.1730 (2.1); 7.1714 (1.9); 7.1668 (2.4); 7.1609 (2.6); 7.1549 (1.1); 6.9277 (0.5); 6.9218 (0.6); 6.9160 (1.0); 6.9104 (1.2); 6.9062 (1.0); 6.9001 (1.0); 6.8942 (1.4); 6.8927 (1.3); 6.8886 (1.0); 6.8784 (0.6); 6.8724 (0.7); 6.8710 (0.6); 6.0235 (0.5); 6.0211 (0.7); 6.0167 (0.7); 6.0142 (0.8); 6.0099 (0.9); 6.0072 (0.9); 6.0036 (1.1); 6.0007 (1.1); 5.9975 (1.1); 5.9943 (1.0); 5.9908 (1.0); 5.9872 (1.0); 5.9841 (1.1); 5.9804 (1.1); 5.9777 (0.6); 5.9062 (0.6); 5.9006 (1.0); 5.8950 (0.6); 5.8868 (0.8); 5.8632 (0.8); 5.8493 (0.6); 5.8288 (0.9); 5.8231 (0.5); 5.8150 (0.8); 5.8095 (0.8); 5.8039 (0.8); 5.7900 (0.6); 4.3164 (0.9); 4.3081 (1.1); 4.3050 (1.4); 4.2959 (1.7); 4.2927 (1.1); 4.2848 (1.1); 4.2806 (1.0); 4.2701 (1.7); 4.2677 (1.4); 4.2583 (1.8); 4.2563 (2.4); 4.2546 (1.9); 4.2517 (1.0); 4.2460 (2.1); 4.2407 (1.6); 4.2345 (0.9); 4.2319 (1.1); 4.2278 (0.9); 4.2211 (0.6); 4.0430 (1.5); 4.0260 (1.0); 4.0166 (1.4); 4.0129 (2.8); 3.9960 (1.8); 3.9866 (2.6); 3.9532 (2.7); 3.9514 (3.0); 3.9437 (1.7); 3.9336 (1.6); 3.9233 (1.4); 3.9214 (1.3); 3.9136 (0.9); 3.9036 (0.9); 3.7902 (0.5); 3.7838 (0.6); 3.7777 (0.6); 3.7285 (1.1); 3.7248 (1.2); 3.7211 (2.2); 3.6843 (1.7); 3.6806 (2.0); 3.6771 (3.5); 3.6426 (1.6); 3.6321 (1.9); 3.6295 (1.9); 3.6185 (1.3); 3.6108 (1.4); 3.6078 (1.4); 3.6042 (1.8); 3.5997 (1.8); 3.5963 (2.4); 3.5914 (3.3); 3.5874 (1.8); 3.5843 (2.0); 3.5798 (3.1); 3.5672 (1.9); 3.5559 (3.6); 3.5290 (1.3); 3.5119 (1.9); 3.4848 (0.8); 3.4018 (14.3); 3.3923 (0.7); 3.3855 (11.7); 3.3814 (1.7); 3.3773 (16.0); 3.3734 (12.0); 2.5469 (0.6); 2.5117 (0.7); 2.4841 (0.7); 2.4490 (0.8); 2.0083 (0.6); 1.9734 (0.6); 1.9644 (0.6); 1.9390 (0.8); 1.9293 (0.6); 1.9036 (0.6); 1.5761 (1.1); 0.0079 (0.8); -0.0002 (21.8); -0.0085 (0.7) 1-125: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3185 (0.6); 7.2621 (16.2); 7.1990 (1.6); 7.1932 (1.9); 7.1870 (1.9); 7.1808 (3.3); 7.1792 (3.6); 7.1746 (2.5); 7.1673 (2.2); 7.1653 (2.4); 7.1613 (2.6); 7.1553 (1.2); 6.9315 (0.5); 6.9284 (0.5); 6.9246 (0.6); 6.9224 (0.7); 6.9186 (0.8); 6.9162 (1.0); 6.9126 (1.0); 6.9100 (1.2); 6.9067 (1.0); 6.9029 (1.1); 6.9008 (1.2); 6.8970 (1.4); 6.8948 (1.4); 6.8911 (1.0); 6.8889 (1.0); 6.8851 (0.6); 6.8811 (0.6); 6.8791

- 110 044070 (0.6); 6.8753 (0.8); 6.8732 (0.7); 6.0063 (0.5); 6.0046 (0.6); 6.0004 (0.9); 5.9964 (1.0); 5.9943 (0.8);

5.9903 (1.4); 5.9865 (1.5); 5.9825 (1.4); 5.9803 (1.4); 5.9762 (1.7); 5.9726 (1.2); 5.9694 (1.2); 5.9660 (1.1); 5.9623 (0.7); 5.9587 (0.6); 5.9071 (0.7); 5.9016 (1.2); 5.8959 (0.7); 5.8935 (0.6); 5.8878 (0.9);

5.8602 (0.8); 5.8545 (0.5); 5.8463 (0.7); 5.8405 (0.5); 5.8381 (0.6); 5.8325 (1.0); 5.8268 (0.6); 5.8245 (0.5); 5.8187 (0.9); 5.8131 (0.5); 5.8025 (0.8); 5.7886 (0.7); 5.0257 (0.7); 5.0229 (0.7); 4.0444 (2.2);

4.0274 (1.1); 4.0202 (1.4); 4.0144 (3.9); 3.9974 (2.0); 3.9902 (3.1); 3.9562 (3.5); 3.9544 (3.1); 3.9433 (1.8); 3.9342 (1.7); 3.9261 (1.5); 3.9242 (1.6); 3.9133 (0.9); 3.9043 (1.1); 3.7718 (0.7); 3.7652 (0.7);

3.7574 (14.7); 3.7501 (1.0); 3.7439 (1.0); 3.7377 (0.8); 3.7301 (1.8); 3.7278 (2.2); 3.7234 (16.0); 3.7177 (2.7); 3.7103 (0.7); 3.7009 (9.3); 3.6882 (10.0); 3.6841 (2.4); 3.6736 (3.2); 3.5624 (2.4); 3.5536 (2.0);

3.5495 (2.5); 3.5382 (0.8); 3.5292 (2.1); 3.5221 (0.8); 3.5184 (1.8); 3.5095 (1.4); 3.5055 (1.5); 3.4851 (0.9); 2.5442 (0.7); 2.5301 (0.5); 2.5091 (0.8); 2.4795 (0.8); 2.4654 (0.6); 2.4445 (0.9); 2.0028 (0.7);

1.9762 (0.7); 1.9676 (0.7); 1.9364 (0.5); 1.9275 (0.9); 1.9186 (0.7); 1.8924 (0.7); 1.5781 (1.3); 0.0080 (0.6); -0.0002 (17.2); -0.0085 (0.6)

1-126: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6640 (1.4); 7.6598 (1.7); 7.6579 (1.9); 7.6537 (2.0); 7.6497 (1.2); 7.6470 (1.5); 7.6447 (1.5); 7.6398 (2.5); 7.6337 (1.7); 7.4334 (0.8); 7.4303 (1.0); 7.4179 (4.3); 7.4130 (1.9); 7.4117 (1.9); 7.4050 (1.3); 7.4012 (2.1); 7.3999 (2.3); 7.3875 (0.5); 7.3861 (0.6); 7.2606 (14.4); 6.2299 (1.7); 6.2032 (1.8); 6.1868 (2.0); 6.1600 (2.1); 5.9565 (0.5); 5.9544 (0.6); 5.9504 (0.5); 5.9465 (0.8); 5.9449 (0.8); 5.9407 (1.1);

5.9367 (0.8); 5.9311 (0.6); 5.9270 (0.6); 5.9249 (0.6); 5.9209 (0.6); 5.8801 (0.6); 5.8746 (1.1); 5.8690 (0.6); 5.8607 (0.8); 5.8237 (0.6); 5.8180 (1.0); 5.8123 (0.6); 5.8099 (0.5); 5.8042 (0.8); 5.5783 (1.4);

5.5764 (1.4); 5.5611 (1.4); 5.5591 (1.4); 5.5352 (1.2); 5.5333 (1.2); 5.5179 (1.2); 5.5160 (1.2); 5.3356 (1.2); 5.3338 (1.2); 5.3220 (1.2); 5.3202 (1.2); 5.3089 (1.2); 5.3071 (1.2); 5.2979 (2.5); 5.2953 (1.3);

5.2934 (1.2); 5.0307 (0.6); 5.0265 (0.6); 3.9885 (1.7); 3.9839 (1.7); 3.9456 (2.0); 3.9410 (2.0); 3.7614 (1.4); 3.7592 (0.9); 3.7550 (1.0); 3.7508 (1.7); 3.7447 (16.0); 3.7387 (1.5); 3.7344 (1.1); 3.7276 (14.0); 3.7141 (2.2); 3.5239 (0.5); 3.5213 (0.5); 3.5162 (0.5); 3.5133 (0.6); 3.5079 (0.5); 3.5056 (0.5); 3.5028 (0.5); 3.3940 (1.7); 3.3889 (1.7); 3.3511 (1.5); 3.3460 (1.5); 2.5606 (0.7); 2.5468 (0.5); 2.5390 (0.7);

2.5257 (0.8); 2.5173 (0.7); 2.5038 (0.7); 2.4824 (0.8); 1.9372 (0.6); 1.9023 (1.0); 1.8917 (1.0); 1.8680 (1.6); 1.8603 (1.2); 1.8566 (1.4); 1.8514 (3.7); 1.8465 (1.2); 1.8424 (1.2); 1.8348 (1.3); 1.3282 (0.5);

1.0206 (0.7); 1.0032 (1.0); 0.0079 (0.5); -0.0002 (18.5); -0.0085 (0.7)

1-127: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2607 (21.7); 7.2167 (1.5); 7.2150 (1.8); 7.2131 (1.9); 7.2112 (2.0); 7.2095 (1.7); 7.2006 (0.7); 7.1907 (0.9); 7.1674 (0.8); 6.9571 (0.8); 6.9357 (0.7); 6.9337 (0.8); 6.2123 (1.3); 6.1856 (1.4); 6.1692 (1.6); 6.1425 (1.7); 5.9625 (0.5); 5.9586 (0.5); 5.9563 (0.5); 5.9523 (0.5); 5.9489 (0.9); 5.9450 (1.0);

5.9427 (1.0); 5.9388 (0.9); 5.9355 (0.6); 5.9314 (0.6); 5.9293 (0.6); 5.9253 (0.5); 5.8789 (0.5); 5.8734 (1.0); 5.8678 (0.6); 5.8596 (0.7); 5.8249 (0.5); 5.8192 (0.9); 5.8135 (0.5); 5.8054 (0.8); 5.5702 (1.3);

5.5683 (1.3); 5.5516 (1.3); 5.5498 (1.3); 5.5270 (1.1); 5.5252 (1.1); 5.5085 (1.1); 5.5067 (1.1); 5.3404

- 111 044070 (1.1); 5.3387 (1.2); 5.3261 (1.2); 5.3243 (1.2); 5.3137 (1.1); 5.3120 (1.1); 5.2985 (4.0); 5.0227 (0.5); 3.9486 (1.5); 3.9446 (1.5); 3.9056 (1.7); 3.9017 (1.8); 3.7665 (0.6); 3.7617 (1.7); 3.7596 (1.2); 3.7553 (1.2); 3.7514 (2.2); 3.7503 (2.0); 3.7450 (16.0); 3.7389 (2.0); 3.7365 (1.6); 3.7320 (12.5); 3.7284 (2.6);

3.7246 (0.8); 3.7139 (3.5); 3.7029 (0.7); 3.5241 (0.5); 3.5187 (0.5); 3.5131 (0.5); 3.5077 (0.5); 3.3475 (1.5); 3.3424 (1.5); 3.3046 (1.3); 3.2994 (1.3); 2.5526 (0.6); 2.5313 (0.8); 2.5176 (0.7); 2.5100 (0.7);

2.4963 (0.8); 2.4751 (0.8); 2.3690 (8.8); 1.9362 (0.6); 1.9019 (0.7); 1.8928 (0.8); 1.8684 (2.0); 1.8605 (1.6); 1.8588 (1.7); 1.8518 (4.8); 1.8472 (1.4); 1.8428 (1.6); 1.8351 (1.7); 1.3514 (0.6); 1.3332 (1.3);

1.3149 (0.6); 1.0196 (1.0); 1.0033 (1.4); 0.9862 (0.6); 0.0079 (0.8); -0.0002 (27.8); -0.0068 (0.7); -0.0085 (1.1)

1-128: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6545 (1.4); 7.6510 (2.2); 7.6473 (1.8); 7.6410 (1.1); 7.6308 (2.0); 7.6274 (1.5); 7.4291 (1.3); 7.4231 (1.5); 7.4189 (3.2); 7.4157 (3.4); 7.4103 (1.7); 7.3989 (1.7); 7.2612 (11.7); 6.2244 (0.8); 6.2206 (0.8);

6.1977 (0.8); 6.1938 (0.8); 6.1814 (0.9); 6.1774 (0.8); 6.1546 (0.9); 6.1507 (0.9); 5.9982 (0.6); 5.9878 (0.8); 5.9832 (1.0); 5.9694 (0.6); 5.8939 (0.9); 5.8800 (0.7); 5.8403 (0.8); 5.8345 (0.5); 5.8265 (0.7);

5.5716 (1.1); 5.5699 (1.1); 5.5592 (1.2); 5.5575 (1.1); 5.5284 (1.0); 5.5268 (1.0); 5.5161 (1.0); 5.5143 (0.9); 5.3353 (1.1); 5.3260 (1.0); 5.3086 (1.0); 5.2992 (1.0); 4.1497 (1.2); 4.1318 (3.5); 4.1140 (3.6);

4.0961 (1.2); 3.9947 (1.2); 3.9890 (1.3); 3.9517 (1.4); 3.9461 (1.5); 3.4001 (1.3); 3.3946 (1.3); 3.3570 (1.1); 3.3516 (1.1); 2.5702 (0.6); 2.5600 (0.5); 2.5251 (0.6); 2.1729 (0.8); 2.0459 (16.0); 1.9564 (0.6); 1.9472 (0.6); 1.2772 (4.5); 1.2593 (9.1); 1.2414 (4.4); -0.0002 (14.0); -0.0086 (0.6)

1-129: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2610 (6.0); 7.2253 (2.7); 7.1971 (0.8); 7.0092 (0.8); 6.9861 (0.8); 6.0072 (0.6); 6.0038 (0.7); 6.0009 (0.7); 5.9974 (0.7); 5.9935 (0.9); 5.9901 (0.9); 5.9871 (0.9); 5.9838 (0.8); 5.9269 (0.8); 5.9213 (1.4);

5.9157 (0.9); 5.9076 (1.0); 5.9021 (0.6); 5.0678 (0.6); 4.0009 (1.2); 3.9559 (1.8); 3.7784 (2.8); 3.7401 (16.0); 3.7337 (2.4); 3.5496 (0.6); 3.5434 (0.6); 3.5358 (0.5); 3.5288 (0.6); 3.5223 (0.6); 2.5040 (0.5);

2.4831 (1.0); 2.4688 (0.7); 2.4623 (0.6); 2.4479 (1.2); 2.4271 (0.6); 2.3878 (9.8); 1.9655 (0.6); 1.9570 (1.1); 1.9485 (0.6); 1.9303 (0.5); 1.9218 (0.9); 1.9133 (0.5); 1.5615 (2.4); -0.0002 (7.4)

1-130: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3755 (0.5); 7.3542 (0.5); 7.2606 (9.1); 7.2162 (2.6); 7.1873 (0.8); 7.0075 (0.8); 6.9843 (0.8); 5.9969 (0.7); 5.9934 (0.7); 5.9905 (0.8); 5.9870 (0.7); 5.9831 (0.8); 5.9797 (0.9); 5.9768 (0.8); 5.9734 (0.8);

5.8616 (0.7); 5.8561 (1.3); 5.8503 (0.9); 5.8423 (1.1); 5.8368 (0.6); 5.0772 (0.6); 4.0001 (1.2); 3.9551 (1.8); 3.7714 (2.8); 3.7593 (16.0); 3.7509 (0.7); 3.7264 (1.8); 3.5610 (0.6); 3.5543 (0.6); 3.5471 (0.5);

3.5396 (0.6); 3.5333 (0.6); 2.5667 (0.5); 2.5458 (1.0); 2.5314 (0.7); 2.5248 (0.6); 2.5105 (1.1); 2.4895 (0.6); 2.3849 (9.8); 2.0107 (0.6); 2.0026 (1.0); 1.9945 (0.6); 1.9754 (0.5); 1.9673 (0.9); 1.9592 (0.5); 1.5521 (3.5); -0.0002 (11.1)

1-131: ¹ H-NMR(400.0 MHz, CDC13):

- 112 044070 δ= 7.6797 (1.6); 7.6764 (1.9); 7.6724 (1.0); 7.6651 (0.7); 7.6599 (2.3); 7.6556 (1.9); 7.4837 (1.0); 7.4703 (0.9); 7.4664 (1.5); 7.4621 (1.0); 7.4558 (2.2); 7.4521 (1.0); 7.4411 (1.1); 7.4374 (2.2); 7.4205 (0.8);

7.4154 (0.6); 7.2602 (15.8); 6.0056 (0.6); 6.0021 (0.6); 5.9993 (0.6); 5.9957 (0.6); 5.9918 (0.8); 5.9883 (0.8); 5.9855 (0.8); 5.9820 (0.7); 5.9279 (0.7); 5.9224 (1.3); 5.9167 (0.8); 5.9087 (0.9); 5.2992 (0.5);

5.0739 (0.5); 4.0375 (1.0); 3.9926 (1.5); 3.8224 (2.5); 3.7775 (1.7); 3.7367 (14.8); 2.4914 (0.9); 2.4771 (0.6); 2.4704 (0.5); 2.4562 (1.0); 2.4353 (0.5); 1.9641 (0.5); 1.9553 (0.9); 1.9466 (0.5); 1.9202 (0.8); 1.5474 (1.4); 1.5274 (16.0); 1.4322 (0.6); 1.2556 (0.6); 0.0078 (0.8); -0.0002 (19.8); -0.0084 (0.8) 1-132: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6716 (1.6); 7.6682 (2.0); 7.6642 (1.0); 7.6570 (0.7); 7.6517 (2.4); 7.6474 (2.0); 7.4824 (1.1); 7.4690 (0.9); 7.4651 (1.5); 7.4607 (1.0); 7.4536 (2.3); 7.4501 (1.0); 7.4389 (1.1); 7.4354 (2.3); 7.4184 (0.8);

7.4134 (0.5); 7.2605 (7.7); 5.9941 (0.6); 5.9906 (0.6); 5.9878 (0.7); 5.9842 (0.6); 5.9804 (0.7); 5.9768 (0.8); 5.9740 (0.8); 5.9705 (0.7); 5.8608 (0.7); 5.8553 (1.2); 5.8496 (0.8); 5.8473 (0.7); 5.8415 (1.0);

5.8359 (0.6); 5.2990 (2.7); 5.0809 (0.5); 4.0375 (1.0); 3.9925 (1.6); 3.8160 (2.6); 3.7711 (2.0); 3.7595 (16.0); 3.5384 (0.5); 3.5322 (0.5); 2.5749 (0.5); 2.5540 (0.9); 2.5397 (0.6); 2.5329 (0.6); 2.5187 (1.0); 2.4977 (0.5); 2.0126 (0.5); 2.0043 (1.0); 1.9958 (0.5); 1.9690 (0.8); 1.2571 (0.8); -0.0002 (9.6)

1-133: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2604 (37.8); 7.2313 (0.6); 7.2004 (5.0); 7.1806 (1.5); 6.9541 (1.3); 6.9334 (1.2); 6.2080 (1.4); 6.2034 (1.2); 6.1813 (1.6); 6.1766 (1.3); 6.1649 (1.7); 6.1602 (1.4); 6.1382 (1.7); 6.1335 (1.4); 6.0080 (0.8); 6.0040 (1.0); 5.9943 (1.6); 5.9901 (1.9); 5.9840 (1.4); 5.9806 (0.8); 5.9760 (0.9); 5.9704 (0.7);

5.9036 (0.7); 5.8980 (1.3); 5.8922 (0.8); 5.8842 (1.1); 5.8789 (0.7); 5.8545 (0.7); 5.8489 (1.4); 5.8431 (0.9); 5.8351 (1.1); 5.8295 (0.6); 5.5628 (2.0); 5.5500 (2.1); 5.5197 (1.7); 5.5069 (1.8); 5.3399 (2.2);

5.3295 (1.7); 5.3132 (2.1); 5.3027 (1.6); 5.0338 (0.5); 5.0120 (0.9); 5.0073 (0.9); 3.9639 (0.5); 3.9501 (2.2); 3.9449 (2.1); 3.9207 (0.6); 3.9071 (2.5); 3.9020 (2.4); 3.5857 (0.9); 3.5799 (0.9); 3.5758 (0.9);

3.3590 (0.8); 3.3518 (2.2); 3.3464 (2.2); 3.3155 (0.6); 3.3088 (1.9); 3.3033 (1.9); 2.6011 (0.9); 2.5873 (0.6); 2.5795 (0.7); 2.5660 (1.0); 2.5561 (0.9); 2.5424 (0.7); 2.5349 (0.5); 2.5209 (0.9); 2.3664 (16.0); 1.9983 (0.5); 1.9873 (0.9); 1.9762 (0.5); 1.9525 (1.2); 1.9420 (1.2); 1.9071 (0.8); 0.0078 (1.6); -0.0002 (48.0); -0.0086(1.7)

1-134: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5192 (0.5); 7.3269 (0.7); 7.3047 (0.7); 7.2602 (94.9); 7.2073 (2.5); 7.2016 (3.4); 7.1909 (2.0); 7.1880 (3.2); 7.1823 (2.8); 6.9963 (0.6); 6.9706 (0.5); 6.9511 (1.3); 6.9493 (1.2); 6.9353 (1.2); 6.9295 (2.0); 6.9238 (1.0); 6.9138 (0.6); 6.9080 (1.0); 6.0648 (1.2); 6.0586 (1.3); 6.0547 (1.2); 6.0510 (1.5);

6.0446 (1.7); 6.0410 (1.3); 5.9669 (1.0); 5.9615 (1.9); 5.9557 (1.2); 5.9476 (1.5); 5.9420 (0.8); 5.9106 (0.8); 5.8968 (0.7); 5.2997 (0.7); 5.0789 (0.7); 4.1268 (1.3); 4.1189 (0.9); 4.1090 (1.3); 4.1011 (2.5);

4.0833 (2.5); 4.0712 (0.8); 4.0655 (0.9); 4.0534 (2.5); 4.0357 (2.5); 4.0277 (1.2); 4.0179 (1.0); 4.0100 (1.8); 3.9922 (0.5); 3.9834 (1.5); 3.9654 (0.8); 3.9381 (2.2); 3.8172 (0.8); 3.7681 (1.7); 3.7566 (4.1);

3.7229 (1.1); 3.7116 (2.7); 3.6122 (0.7); 3.6065 (0.7); 3.5998 (0.7); 3.5908 (0.8); 3.5852 (0.8); 2.5433

- 113 044070 (0.8); 2.5224 (1.5); 2.5080 (1.0); 2.5015 (0.8); 2.4871 (1.6); 2.4662 (0.8); 1.9964 (0.8); 1.9881 (1.3); 1.9795 (0.7); 1.9611 (0.6); 1.9527 (1.2); 1.9442 (0.8); 1.8572 (0.8); 1.4322 (2.8); 1.3567 (7.9); 1.3390 (16.0); 1.3212 (7.8); 1.2545 (0.6); 1.2466 (0.6); 1.2228 (0.7); 0.0080 (3.9); -0.0002 (120.6); -0.0085 (3.9) 1-135: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2613 (28.8); 7.2070 (0.5); 7.2014 (1.0); 7.1890 (4.9); 7.1835 (6.0); 7.1726 (3.9); 7.1691 (6.1); 7.1636 (4.9); 7.1514 (1.0); 7.0983 (1.6); 7.0766 (1.6); 6.9100 (1.2); 6.9042 (2.0); 6.8984 (1.2); 6.8883 (2.4); 6.8825 (4.1); 6.8767 (2.1); 6.8666 (1.2); 6.8608 (2.1); 6.8552 (1.1); 6.1989 (3.8); 6.1721 (4.2);

6.1557 (4.4); 6.1290 (4.6); 6.1162 (1.0); 6.1061 (2.1); 6.0960 (1.0); 5.9783 (3.7); 5.9684 (6.2); 5.9639 (3.3); 5.9584 (5.3); 5.9541 (3.0); 5.9171 (2.8); 5.9117 (5.0); 5.9060 (2.9); 5.8979 (3.3); 5.8924 (1.8);

5.8412 (1.0); 5.8311 (2.1); 5.8210 (1.0); 5.5520 (7.1); 5.5088 (6.2); 5.3456 (6.7); 5.3188 (6.3); 5.0577 (0.9); 5.0541 (1.0); 5.0367 (1.7); 5.0326 (1.7); 5.0151 (1.0); 4.3601 (3.4); 4.3500 (3.4); 4.3260 (6.8);

4.3160 (6.6); 4.2919 (3.5); 4.2819 (3.3); 3.9373 (7.2); 3.8943 (8.2); 3.7355 (0.8); 3.5980 (1.6); 3.5922 (1.5); 3.5888 (1.6); 3.5832 (1.6); 3.5767 (1.6); 3.3331 (7.6); 3.2901 (6.6); 3.1120 (0.5); 2.5721 (1.7);

2.5510 (3.2); 2.5369 (2.2); 2.5299 (1.9); 2.5158 (3.6); 2.4947 (1.8); 2.1712 (16.0); 1.9347 (1.9); 1.9247 (3.4); 1.9146 (1.9); 1.8996 (1.7); 1.8895 (3.0); 1.8796 (1.7); 1.4348 (1.1); 1.3199 (0.7); 1.3018 (1.3); 1.2832 (0.8); 1.2567 (2.2); 0.8821 (0.6); 0.0077 (1.3); -0.0002 (34.2); -0.0084 (1.2)

1-136: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2610 (75.0); 7.1988 (0.9); 7.1931 (2.0); 7.1872 (1.9); 7.1806 (9.2); 7.1749 (11.2); 7.1718 (6.7); 7.1640 (6.4); 7.1609 (10.8); 7.1552 (8.7); 7.1485 (1.4); 7.1427 (1.5); 7.1370 (0.6); 6.9205 (2.4); 6.9148 (4.1); 6.9089 (2.2); 6.8988 (4.7); 6.8931 (8.0); 6.8872 (4.0); 6.8772 (2.4); 6.8714 (3.9); 6.8655 (1.9);

6.7513 (3.1); 6.7308 (3.1); 6.1937 (7.7); 6.1669 (8.6); 6.1505 (9.1); 6.1238 (9.4); 6.0735 (2.1); 6.0634 (4.2); 6.0533 (2.0); 5.9889 (4.4); 5.9845 (5.1); 5.9829 (5.0); 5.9785 (4.7); 5.9750 (5.7); 5.9706 (6.7);

5.9690 (6.5); 5.9646 (5.5); 5.9359 (4.3); 5.9258 (8.8); 5.9158 (4.2); 5.8888 (5.2); 5.8832 (9.4); 5.8774 (5.6); 5.8750 (4.5); 5.8693 (7.2); 5.8635 (3.9); 5.7983 (2.1); 5.7883 (4.4); 5.7783 (2.1); 5.6419 (0.6);

5.5989 (0.5); 5.5504 (12.9); 5.5491 (12.7); 5.5073 (11.5); 5.5059 (11.1); 5.4236 (0.5); 5.3554 (12.0); 5.3544 (11.5); 5.3287 (11.0); 5.3275 (11.0); 5.1494 (0.6); 5.1439 (1.2); 5.1383 (1.6); 5.1326 (1.8); 5.1282 (2.3); 5.1228 (2.9); 5.1179 (3.1); 5.1124 (3.1); 5.1072 (2.9); 5.1019 (2.2); 5.0974 (1.7); 5.0919 (1.6);

5.0863 (1.1); 5.0808 (0.6); 4.3204 (7.7); 4.3103 (7.8); 4.2862 (16.0); 4.2762 (15.4); 4.2520 (8.1); 4.2420 (7.7); 3.9611 (0.6); 3.9493 (13.4); 3.9184 (0.7); 3.9061 (15.3); 3.8287 (1.1); 3.8227 (2.8); 3.8168 (3.8); 3.8108 (4.1); 3.8049 (3.6); 3.8006 (3.6); 3.7947 (4.1); 3.7887 (3.9); 3.7828 (2.8); 3.7768 (1.1); 3.4155 (0.5); 3.3360 (13.7); 3.2928 (11.8); 3.1201 (0.6); 3.0986 (0.6); 2.7004 (3.7); 2.6885 (3.7); 2.6797 (3.9); 2.6677 (4.4); 2.6651 (4.7); 2.6532 (4.2); 2.6444 (4.0); 2.6325 (3.8); 1.9085 (3.8); 1.8972 (3.8); 1.8864 (4.0); 1.8747 (5.0); 1.8619 (3.7); 1.8511 (3.5); 1.8398 (3.4); 1.5654 (0.5); 1.5516 (0.5); 1.5356 (0.5);

1.5165 (0.5); 1.4634 (1.3); 1.4206 (1.3); 1.4026 (2.5); 1.3843 (1.3); 1.2563 (2.6); 0.9484 (0.6); 0.9327 (0.6); 0.9058 (0.7); 0.8901 (0.9); 0.8798 (1.0); 0.0080 (3.1); -0.0002 (93.9); -0.0085 (3.1)

1-137: ¹ H-NMR(400.0 MHz, CDC13):

- 114 044070 δ= 7.2623 (45.5); 7.2059 (0.9); 7.2002 (1.9); 7.1943 (1.7); 7.1878 (9.1); 7.1821 (11.0); 7.1790 (6.5);

7.1711 (6.3); 7.1680 (10.9); 7.1623 (9.2); 7.1558 (1.8); 7.1500 (1.8); 7.1442 (1.0); 7.1222 (2.7); 7.0999 (2.8); 6.9082 (2.4); 6.9024 (4.0); 6.8966 (2.2); 6.8865 (4.6); 6.8807 (8.0); 6.8749 (4.1); 6.8648 (2.4);

6.8590 (4.0); 6.8532 (1.9); 6.1990 (7.8); 6.1722 (8.8); 6.1559 (9.4); 6.1291 (9.5); 5.9551 (3.4); 5.9513 (3.9); 5.9490 (3.9); 5.9452 (3.6); 5.9413 (5.1); 5.9375 (5.8); 5.9351 (5.7); 5.9314 (5.3); 5.8944 (5.3);

5.8889 (9.7); 5.8833 (5.4); 5.8807 (3.8); 5.8751 (6.3); 5.8696 (3.5); 5.5510 (13.0); 5.5494 (13.2); 5.5078 (11.4); 5.5063 (11.5); 5.3445 (11.7); 5.3432 (11.6); 5.3177 (11.0); 5.3164 (10.8); 5.0527 (1.6); 5.0495 (1.7); 5.0464 (1.4); 5.0435 (1.5); 5.0401 (1.8); 5.0316 (2.9); 5.0277 (3.0); 5.0157 (1.4); 5.0129 (1.4);

5.0099 (1.7); 5.0066 (1.6); 4.4017 (0.6); 4.3857 (1.3); 4.3722 (8.3); 4.3682 (8.8); 4.3619 (2.0); 4.3560 (14.2); 4.3529 (15.6); 4.3407 (8.8); 4.3369 (8.8); 4.3232 (1.2); 4.3073 (0.8); 3.9394 (14.0); 3.8965 (16.0);

3.8420 (0.5); 3.8386 (0.8); 3.5544 (1.1); 3.5485 (2.1); 3.5445 (2.6); 3.5387 (2.8); 3.5356 (2.6); 3.5328 (2.7); 3.5299 (2.7); 3.5271 (2.6); 3.5241 (2.8); 3.5174 (2.7); 3.5142 (2.2); 3.5083 (1.2); 3.3315 (14.1);

3.2885 (12.3); 3.1171 (0.9); 3.1015 (0.9); 2.5660 (1.9); 2.5503 (3.3); 2.5400 (9.1); 2.5348 (2.7); 2.5242 (10.0); 2.5191 (7.4); 2.5138 (7.0); 2.5086 (6.5); 2.5051 (5.4); 2.4980 (13.4); 2.4875 (3.4); 2.4832 (9.5);

2.4720 (3.6); 2.4628 (3.7); 2.4564 (2.2); 1.9130 (3.3); 1.9032 (5.9); 1.8934 (3.3); 1.8778 (3.0); 1.8681 (5.3); 1.8583 (3.1); 1.4348 (0.5); 1.4207 (1.3); 1.4042 (2.5); 1.3871 (1.2); 1.2561 (1.7); 0.8809 (0.7); 0.0080 (1.6); -0.0002 (56.4); -0.0085 (2.1)

1-138: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5193 (0.6); 7.2605 (108.3); 7.1929 (0.8); 7.1870 (0.7); 7.1805 (4.2); 7.1747 (5.1); 7.1716 (3.0);

7.1639 (2.9); 7.1607 (5.0); 7.1550 (4.1); 7.1482 (0.7); 7.1425 (0.7); 6.9964 (0.6); 6.9198 (1.1); 6.9140 (1.9); 6.9082 (1.0); 6.8981 (2.2); 6.8923 (3.7); 6.8865 (1.9); 6.8764 (1.1); 6.8706 (1.9); 6.8648 (0.9);

6.7368 (1.5); 6.7158 (1.5); 6.1936 (3.7); 6.1668 (4.1); 6.1505 (4.4); 6.1237 (4.5); 5.9694 (2.0); 5.9650 (2.4); 5.9634 (2.4); 5.9591 (2.2); 5.9556 (2.6); 5.9512 (3.0); 5.9495 (3.0); 5.9452 (2.6); 5.8653 (2.5);

5.8597 (4.6); 5.8539 (2.6); 5.8515 (2.2); 5.8457 (3.5); 5.8400 (1.9); 5.5490 (6.1); 5.5476 (6.1); 5.5059 (5.4); 5.5044 (5.4); 5.3535 (5.6); 5.3523 (5.6); 5.3267 (5.2); 5.3256 (5.3); 5.1329 (0.6); 5.1274 (0.8);

5.1215 (0.8); 5.1171 (1.1); 5.1118 (1.4); 5.1065 (1.5); 5.1008 (1.4); 5.0963 (1.4); 5.0908 (1.1); 5.0863 (0.8); 5.0805 (0.7); 5.0751 (0.6); 4.3401 (0.6); 4.3264 (3.8); 4.3221 (4.0); 4.3103 (7.0); 4.3069 (7.4);

4.2950 (4.1); 4.2910 (3.9); 3.9494 (6.5); 3.9062 (7.4); 3.9024 (2.6); 3.7668 (0.5); 3.7608 (1.3); 3.7549 (1.8); 3.7489 (2.0); 3.7430 (1.7); 3.7388 (1.7); 3.7328 (2.0); 3.7268 (1.9); 3.7209 (1.3); 3.7149 (0.5);

3.3338 (6.5); 3.2907 (5.7); 2.6828 (1.8); 2.6708 (1.7); 2.6621 (1.8); 2.6501 (2.1); 2.6476 (2.2); 2.6356 (2.0); 2.6269 (1.9); 2.6149 (1.8); 2.5128 (0.9); 2.4971 (1.6); 2.4867 (2.8); 2.4816 (1.2); 2.4710 (4.5);

2.4607 (3.0); 2.4555 (2.9); 2.4450 (4.6); 2.4346 (1.2); 2.4294 (2.7); 2.4189 (1.5); 2.4034 (0.9); 1.8743 (1.8); 1.8630 (1.8); 1.8523 (1.8); 1.8407 (2.3); 1.8278 (1.7); 1.8170 (1.6); 1.8057 (1.6); 1.5420 (16.0); 1.2563 (0.7); 0.0080 (4.3); -0.0002 (135.2); -0.0085 (4.8)

1-139: Ή-ΗΜΡ(400.0 MHz, CDC13):

- 115 044070 δ= 7.9410 (3.0); 7.9376 (3.8); 7.9337 (2.9); 7.9291 (2.4); 7.9251 (1.5); 7.8776 (0.8); 7.8745 (1.0); 7.8702 (0.9); 7.8676 (1.0); 7.8645 (1.2); 7.8602 (1.1); 7.8575 (1.4); 7.8536 (2.2); 7.8503 (1.8); 7.8477 (1.6);

7.8447 (1.4); 7.8404 (1.1); 7.8365 (1.0); 7.8338 (1.2); 7.8319 (1.3); 7.8299 (1.1); 7.8273 (0.7); 7.7284 (0.7); 7.7253 (1.4); 7.7218 (1.5); 7.7185 (1.5); 7.7156 (1.7); 7.7120 (1.7); 7.7091 (1.7); 7.7059 (1.9);

7.7024 (1.8); 7.6991 (1.7); 7.6963 (2.0); 7.6926 (1.9); 7.6898 (1.0); 7.5669 (1.1); 7.5649 (1.1); 7.5569 (1.6); 7.5473 (1.8); 7.5452 (1.8); 7.5373 (2.6); 7.5276 (0.8); 7.5256 (0.8); 7.5177 (1.1); 7.2627 (18.6);

7.1017 (0.7); 6.7924 (0.6); 6.7727 (0.6); 6.1338 (0.7); 6.0973 (0.7); 6.0872 (0.5); 6.0064 (0.7); 5.9964 (1.5); 5.9861 (1.3); 5.9805 (1.5); 5.9759 (1.7); 5.9701 (2.1); 5.9673 (1.5); 5.9614 (2.2); 5.9600 (2.2);

5.9567 (1.3); 5.9497 (1.5); 5.9437 (0.9); 5.9379 (1.7); 5.9326 (1.9); 5.9295 (0.8); 5.9270 (0.9); 5.9233 (1.3); 5.9187 (0.9); 5.9131 (0.9); 5.9078 (0.6); 5.9021 (1.0); 5.8964 (0.6); 5.8882 (0.7); 5.8589 (0.7);

5.8474 (0.9); 5.8417 (1.4); 5.8359 (0.9); 5.8330 (1.3); 5.8275 (1.9); 5.8222 (1.6); 5.8129 (1.1); 5.1042 (0.5); 5.0983 (0.5); 5.0283 (0.7); 5.0240 (0.7); 5.0202 (0.7); 5.0161 (0.7); 4.3888 (1.3); 4.3788 (1.3);

4.3546 (2.6); 4.3486 (1.3); 4.3446 (2.7); 4.3386 (1.2); 4.3352 (1.0); 4.3251 (1.0); 4.3203 (1.6); 4.3184 (1.2); 4.3144 (2.0); 4.3103 (1.7); 4.3083 (1.3); 4.3043 (2.0); 4.3010 (1.9); 4.2908 (1.6); 4.2840 (1.8);

4.2803 (1.1); 4.2740 (1.7); 4.2702 (1.0); 4.2668 (1.0); 4.2567 (0.8); 4.2499 (0.9); 4.2398 (0.8); 3.8620 (1.5); 3.8543 (2.6); 3.8475 (2.6); 3.8428 (0.8); 3.8188 (2.0); 3.8111 (3.2); 3.8042 (3.0); 3.6017 (0.7);

3.5967 (0.7); 3.2436 (2.0); 3.2417 (2.1); 3.2376 (2.5); 3.2296 (2.2); 3.2002 (1.8); 3.1983 (1.8); 3.1944 (2.3); 3.1864 (2.0); 2.6261 (0.5); 2.6050 (0.9); 2.5910 (0.6); 2.5838 (0.6); 2.5698 (1.0); 2.5574 (0.5);

2.5487 (0.6); 2.5363 (0.9); 2.5223 (0.6); 2.5152 (0.6); 2.5012 (1.0); 2.4801 (0.6); 1.9855 (0.9); 1.9755 (0.5); 1.9603 (0.8); 1.9499 (1.0); 1.9384 (0.6); 1.9097 (0.6); 1.8997 (1.0); 1.8896 (0.5); 1.8745 (0.6);

1.8677 (0.6); 1.8646 (0.8); 1.8570 (0.5); 1.8548 (0.5); 1.8456 (0.5); 1.7392 (12.7); 1.7337 (16.0); 1.7274 (13.0); 1.5801 (2.2); 0.0080 (0.8); -0.0002 (23.0); -0.0085 (0.7)

1-140: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2614 (12.6); 7.2221 (0.5); 7.2096 (1.3); 7.2038 (1.5); 7.2006 (0.9); 7.1930 (0.9); 7.1898 (1.5);

7.1841 (1.2); 6.9155 (0.6); 6.8995 (0.6); 6.8937 (1.1); 6.8879 (0.5); 6.8720 (0.6); 5.9845 (0.5); 5.9817 (0.5); 5.9782 (0.5); 5.9744 (0.7); 5.9708 (0.8); 5.9680 (0.7); 5.9645 (0.7); 5.9114 (0.7); 5.9059 (1.2);

5.9003 (0.7); 5.8978 (0.6); 5.8921 (0.9); 4.2182 (1.1); 4.2004 (3.7); 4.1825 (3.8); 4.1647 (1.2); 3.8589 (1.9); 3.8135 (2.2); 3.3748 (16.0); 3.3587 (2.4); 3.3133 (2.0); 2.5536 (0.8); 2.5396 (0.6); 2.5185 (1.0);

1.9950 (0.8); 1.9599 (0.7); 1.5572 (3.3); 1.3157 (4.1); 1.2979 (8.5); 1.2800 (4.0); -0.0002 (15.0); -0.0085 (0.5)

1-141: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2603 (69.5); 7.2124 (1.2); 7.2067 (1.4); 7.1959 (0.8); 7.1927 (1.4); 7.1869 (1.2); 6.9162 (0.6);

6.9003 (0.6); 6.8945 (1.1); 6.8727 (0.5); 5.9852 (0.5); 5.9777 (0.7); 5.9744 (0.7); 5.9715 (0.7); 5.9682 (0.7); 5.9322 (0.7); 5.9268 (1.2); 5.9213 (0.7); 5.9130 (0.8); 4.2021 (0.7); 4.1857 (2.2); 4.1842 (2.2);

4.1678 (2.3); 4.1665 (2.1); 4.1498 (0.8); 3.8654 (1.8); 3.8202 (2.1); 3.3667 (16.0); 3.3540 (2.3); 3.3088

- 116 044070 (1.9); 2.5293 (0.9); 2.5152 (0.5); 2.4941 (0.9); 1.9868 (0.8); 1.9519 (0.7); 1.5445 (10.7); 1.3029 (4.2); 1.2851 (8.6); 1.2672 (4.1); 0.0080 (2.4); -0.0002 (82.0); -0.0085 (2.6)

1-142: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2773 (2.4); 7.2612 (45.7); 7.2160 (0.8); 7.2103 (1.3); 7.2043 (1.2); 7.1977 (5.8); 7.1922 (7.3); 7.1813 (4.8); 7.1780 (7.4); 7.1725 (6.1); 7.1602 (1.3); 6.9272 (1.4); 6.9215 (2.4); 6.9157 (1.4); 6.9055 (2.9); 6.8997 (4.8); 6.8940 (2.6); 6.8838 (1.6); 6.8781 (2.5); 6.8723 (1.3); 6.0125 (2.4); 6.0089 (2.8);

6.0063 (2.9); 6.0026 (2.8); 5.9988 (3.5); 5.9951 (3.9); 5.9925 (3.8); 5.9890 (3.5); 5.9281 (3.1); 5.9225 (5.7); 5.9168 (3.7); 5.9088 (4.4); 5.9032 (2.5); 5.0540 (1.3); 5.0329 (2.4); 5.0141 (1.4); 4.4015 (0.6);

4.3856 (5.3); 4.3821 (5.5); 4.3720 (10.4); 4.3675 (9.4); 4.3571 (6.3); 4.3542 (6.2); 4.3378 (0.7); 4.0221 (5.7); 3.9921 (13.2); 3.9517 (12.8); 3.9217 (5.6); 3.7288 (1.7); 3.7234 (7.2); 3.7169 (11.3); 3.7027 (16.0); 3.6888 (10.6); 3.6795 (11.4); 3.5902 (2.2); 3.5871 (2.1); 3.5841 (2.3); 3.5755 (2.2); 3.5687 (2.7); 3.5590 (11.8); 3.5149 (6.3); 2.5316 (2.0); 2.5106 (3.9); 2.4964 (2.7); 2.4895 (2.4); 2.4753 (4.4); 2.4543 (2.2); 1.9712 (2.2); 1.9623 (4.0); 1.9533 (2.3); 1.9361 (2.0); 1.9271 (3.6); 1.9182 (2.1); 1.5666 (1.9); 1.2565 (2.0); 0.8801 (0.6); 0.8526 (0.6); 0.0079 (2.0); -0.0002 (55.2); -0.0083 (3.2)

1-143: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2729 (2.1); 7.2610 (60.3); 7.2050 (0.6); 7.1993 (1.1); 7.1868 (5.1); 7.1811 (6.1); 7.1779 (3.8); 7.1703 (3.8); 7.1671 (6.0); 7.1615 (4.8); 7.1547 (0.8); 7.1490 (0.8); 6.9254 (1.2); 6.9196 (2.1); 6.9138 (1.2); 6.9037 (2.5); 6.8979 (4.1); 6.8921 (2.1); 6.8820 (1.3); 6.8762 (2.0); 6.8704 (1.0); 6.0052 (2.2);

6.0015 (2.4); 5.9989 (2.5); 5.9951 (2.4); 5.9915 (2.7); 5.9877 (2.9); 5.9851 (2.8); 5.9814 (2.5); 5.8567 (2.5); 5.8510 (4.4); 5.8453 (2.8); 5.8431 (2.5); 5.8372 (3.8); 5.8317 (2.1); 5.0661 (1.0); 5.0474 (1.9);

5.0264 (1.0); 4.4427 (0.6); 4.4266 (4.5); 4.4221 (4.7); 4.4127 (7.6); 4.4083 (6.9); 4.3982 (5.1); 4.3944 (4.9); 4.3779 (0.6); 4.0495 (5.9); 4.0194 (10.6); 3.9532 (10.1); 3.9232 (5.7); 3.7570 (9.2); 3.7481 (2.1); 3.7429 (16.0); 3.7382 (2.4); 3.7289 (7.5); 3.7181 (5.9); 3.6741 (9.3); 3.6070 (1.7); 3.6042 (1.6); 3.6012 (1.8); 3.5945 (1.6); 3.5923 (1.6); 3.5856 (1.9); 3.5825 (1.7); 3.5798 (1.8); 3.5537 (8.7); 3.5096 (5.3);

2.5958 (1.7); 2.5747 (3.1); 2.5605 (2.2); 2.5534 (1.9); 2.5393 (3.5); 2.5182 (1.8); 2.0420 (1.8); 2.0333 (3.2); 2.0245 (1.8); 2.0068 (1.7); 1.9980 (2.8); 1.9892 (1.6); 1.5643 (1.8); 1.2564 (1.9); 0.8812 (0.6);

0.8527 (0.6); 0.0080 (2.5); -0.0002 (76.7); -0.0085 (3.2)

1-144: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2610 (65.5); 7.2126 (1.4); 7.2068 (1.7); 7.2037 (1.2); 7.1929 (2.0); 7.1871 (2.0); 7.1822 (4.4); 7.1765 (5.1); 7.1735 (3.2); 7.1659 (3.1); 7.1627 (4.9); 7.1570 (4.0); 7.1504 (0.6); 7.1444 (0.7); 6.9372 (1.1); 6.9314 (1.8); 6.9256 (1.0); 6.9221 (0.7); 6.9156 (2.5); 6.9098 (3.8); 6.9039 (2.0); 6.9005 (1.1); 6.8943 (2.1); 6.8882 (2.4); 6.8823 (1.3); 6.8728 (1.8); 6.8501 (1.5); 6.0321 (2.1); 6.0278 (2.5); 6.0261 (2.5); 6.0219 (2.3); 6.0182 (2.4); 6.0139 (2.8); 6.0122 (2.8); 6.0080 (2.3); 5.9879 (0.6); 5.9853 (0.6); 5.9818 (0.6); 5.9778 (0.8); 5.9744 (0.8); 5.9715 (0.8); 5.9683 (0.7); 5.9322 (0.8); 5.9268 (1.3); 5.9213 (0.8); 5.9130 (0.8); 5.8305 (2.2); 5.8246 (4.0); 5.8188 (2.5); 5.8167 (2.2); 5.8108 (3.5); 5.8050 (1.9); 5.1409 (0.6); 5.1361 (0.9); 5.1305 (1.0); 5.1259 (1.3); 5.1203 (1.6); 5.1154 (1.7); 5.1099 (1.8); 5.1052

- 117 044070 (1.8); 5.0996 (1.4); 5.0952 (1.1); 5.0893 (1.0); 5.0844 (0.8); 4.3686 (5.2); 4.3552 (6.8); 4.3524 (5.6); 4.3407 (6.7); 4.2021 (0.8); 4.1857 (2.3); 4.1843 (2.3); 4.1677 (2.4); 4.1666 (2.4); 4.1499 (0.9); 4.0480 (5.3); 4.0181 (8.8); 3.9353 (8.2); 3.9053 (5.0); 3.8660 (2.0); 3.8341 (0.5); 3.8280 (1.4); 3.8210 (3.4);

3.8157 (2.0); 3.8096 (1.7); 3.8061 (1.7); 3.8000 (1.9); 3.7938 (1.8); 3.7877 (1.3); 3.7817 (0.5); 3.7318 (5.0); 3.6996 (8.2); 3.6875 (12.5); 3.6854 (10.9); 3.6714 (7.2); 3.5306 (7.1); 3.4863 (4.5); 3.3667 (16.0);

3.3545 (2.5); 3.3092 (2.1); 2.7537 (1.7); 2.7412 (1.6); 2.7332 (1.8); 2.7207 (2.1); 2.7185 (2.2); 2.7060 (1.9); 2.6980 (1.8); 2.6855 (1.8); 2.5293 (0.9); 2.5153 (0.6); 2.5082 (0.5); 2.4941 (1.0); 1.9997 (1.7);

1.9889 (2.1); 1.9779 (2.1); 1.9671 (2.1); 1.9646 (2.0); 1.9536 (2.0); 1.9427 (1.8); 1.9319 (1.5); 1.5596 (3.2); 1.3030 (4.5); 1.2852 (8.9); 1.2673 (4.9); 1.2564 (2.4); 0.8798 (0.8); 0.8535 (0.7); 0.0080 (2.9); 0.0002 (83.5); -0.0085 (2.9)

1-145: ¹ H-NMR(400.0 MHz, CDC13):

δ= 8.0232 (2.1); 7.5211 (0.6); 7.2622 (86.8); 7.2118 (0.6); 7.2061 (0.7); 7.2003 (1.4); 7.1876 (7.0);

7.1820 (8.3); 7.1788 (5.3); 7.1712 (5.2); 7.1681 (8.3); 7.1624 (6.6); 7.1556 (1.2); 7.1499 (1.2); 6.9981 (0.5); 6.9413 (1.8); 6.9356 (3.0); 6.9298 (1.7); 6.9197 (3.6); 6.9139 (6.0); 6.9082 (3.4); 6.8980 (3.1);

6.8923 (5.3); 6.8866 (3.0); 6.8708 (2.4); 6.0240 (3.2); 6.0196 (3.9); 6.0179 (3.8); 6.0135 (3.6); 6.0101 (4.1); 6.0057 (4.7); 6.0040 (4.5); 5.9996 (3.9); 5.8889 (3.7); 5.8832 (6.7); 5.8774 (4.2); 5.8751 (3.5);

5.8693 (5.5); 5.8636 (3.0); 5.1677 (0.9); 5.1620 (1.2); 5.1562 (1.3); 5.1518 (1.7); 5.1465 (2.2); 5.1412 (2.3); 5.1360 (2.3); 5.1307 (2.2); 5.1254 (1.7); 5.1211 (1.2); 5.1152 (1.1); 5.1099 (0.9); 4.3566 (7.8);

4.3449 (10.4); 4.3438 (10.6); 4.3406 (9.0); 4.3290 (10.0); 4.1581 (0.6); 4.1401 (0.6); 4.0348 (7.9); 4.0047 (14.5); 3.9451 (13.6); 3.9150 (7.4); 3.8093 (1.2); 3.8031 (2.2); 3.7972 (2.9); 3.7913 (3.1); 3.7855 (2.8);

3.7810 (2.8); 3.7752 (3.3); 3.7693 (3.2); 3.7634 (2.6); 3.7575 (1.2); 3.7359 (7.8); 3.7125 (0.9); 3.6916 (14.5); 3.6894 (16.0); 3.6750 (14.8); 3.6612 (11.6); 3.5570 (11.0); 3.5127 (7.0); 3.4968 (0.8); 2.7188 (4.2); 2.7071 (4.2); 2.6981 (4.3); 2.6863 (4.8); 2.6836 (4.9); 2.6718 (4.5); 2.6626 (5.0); 2.6511 (4.2);

1.8973 (2.8); 1.8857 (2.8); 1.8752 (2.9); 1.8633 (3.8); 1.8505 (2.7); 1.8400 (2.5); 1.8285 (2.5); 1.7288 (0.9); 1.7203 (1.7); 1.3060 (0.9); 1.2881 (1.2); 1.2738 (1.6); 1.2560 (4.3); 1.2382 (1.4); 0.8803 (1.3);

0.8529 (1.2); 0.0080 (3.8); -0.0002 (109.7); -0.0085 (4.1)

1-146: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6650 (1.5); 7.6607 (1.8); 7.6465 (1.4); 7.6408 (2.0); 7.5189 (0.7); 7.4331 (0.7); 7.4211 (3.0); 7.4031 (1.6); 7.2601 (113.7); 6.9960 (0.7); 6.2306 (1.1); 6.2039 (1.2); 6.1875 (1.3); 6.1607 (1.4); 5.9436 (0.9);

5.9376 (0.7); 5.8809 (0.8); 5.8753 (1.3); 5.8697 (0.8); 5.8615 (1.0); 5.8559 (0.6); 5.5613 (1.7); 5.5183 (1.6); 5.3235 (1.6); 5.2969 (1.4); 3.9845 (1.9); 3.9416 (2.3); 3.7290 (16.0); 3.5050 (0.5); 3.3961 (2.0);

3.3531 (1.8); 2.5180 (0.9); 2.5041 (0.6); 2.4969 (0.6); 2.4831 (1.1); 2.4620 (0.6); 1.8921 (0.9); 1.8821 (0.5); 1.8571 (0.8); 1.8471 (0.6); 1.7054 (4.6); 0.1461 (0.6); 0.0080 (4.9); -0.0002 (140.9); -0.0085 (4.9); 0.1498 (0.6)

1-147: ¹ H-NMR(400.0 MHz, CDC13):

- 118 044070 δ= 7.6588 (1.6); 7.6547 (1.7); 7.6506 (0.8); 7.6484 (0.7); 7.6450 (0.7); 7.6401 (1.4); 7.6347 (1.9); 7.4356 (0.5); 7.4321 (0.6); 7.4235 (1.4); 7.4194 (3.0); 7.4149 (1.4); 7.4130 (1.1); 7.4057 (0.9); 7.4017 (1.5);

7.4006 (1.4); 7.2609 (14.1); 6.2304 (1.0); 6.2036 (1.2); 6.1872 (1.3); 6.1605 (1.3); 5.9468 (0.5); 5.9427 (0.6); 5.9407 (0.6); 5.9366 (0.6); 5.9330 (0.7); 5.9289 (0.7); 5.9269 (0.7); 5.9228 (0.6); 5.8248 (0.6);

5.8191 (1.2); 5.8134 (0.7); 5.8111 (0.6); 5.8053 (1.0); 5.7997 (0.5); 5.5793 (1.7); 5.5774 (1.6); 5.5362 (1.5); 5.5343 (1.5); 5.3383 (1.5); 5.3365 (1.5); 5.3116 (1.4); 5.3098 (1.4); 3.9898 (2.0); 3.9469 (2.3);

3.7523 (0.8); 3.7464 (16.0); 3.7293 (0.6); 3.3934 (2.0); 3.3504 (1.7); 2.5609 (0.8); 2.5471 (0.6); 2.5398 (0.5); 2.5260 (0.9); 2.5049 (0.5); 1.9392 (0.8); 1.9044 (0.7); 0.0080 (0.6); -0.0002 (18.5); -0.0085 (0.7) 1-148: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9797 (7.7); 7.9762 (10.6); 7.9722 (8.2); 7.9680 (6.0); 7.9038 (2.1); 7.9006 (2.8); 7.8961 (2.9); 7.8919 (2.9); 7.8877 (2.6); 7.8806 (5.8); 7.8766 (4.9); 7.8721 (3.4); 7.8681 (2.6); 7.8599 (3.2); 7.7854 (2.9); 7.7825 (3.1); 7.7788 (3.7); 7.7757 (4.8); 7.7730 (4.5); 7.7694 (3.6); 7.7660 (3.9); 7.7630 (4.0);

7.7593 (4.4); 7.7563 (5.6); 7.7536 (5.1); 7.6131 (2.7); 7.6053 (4.4); 7.5942 (4.4); 7.5856 (7.1); 7.5748 (2.0); 7.5659 (3.1); 7.2626 (32.9); 7.2400 (2.0); 6.8252 (0.9); 6.8033 (1.4); 6.7812 (0.8); 6.1338 (0.7);

6.1238 (1.4); 6.1139 (0.8); 6.1076 (0.8); 6.0976 (1.5); 6.0932 (0.6); 6.0876 (0.9); 6.0831 (1.1); 6.0710 (0.9); 6.0504 (1.1); 6.0456 (1.5); 6.0394 (1.8); 6.0303 (3.3); 6.0262 (3.4); 6.0201 (3.1); 6.0154 (4.2);

6.0127 (4.2); 6.0097 (4.0); 6.0064 (3.7); 6.0018 (2.4); 5.9964 (3.4); 5.9920 (2.0); 5.9866 (3.2); 5.9766 (1.8); 5.9684 (2.6); 5.9610 (4.5); 5.9565 (3.1); 5.9496 (3.4); 5.9456 (2.9); 5.9335 (1.8); 5.9235 (1.0);

5.9188 (1.1); 5.9132 (1.8); 5.9072 (1.2); 5.8993 (3.0); 5.8937 (3.7); 5.8879 (2.0); 5.8800 (2.3); 5.8744 (1.3); 5.8627 (1.2); 5.8571 (2.2); 5.8493 (2.6); 5.8431 (1.9); 5.8387 (1.3); 5.8330 (0.9); 5.8229 (1.6);

5.8182 (0.6); 5.8130 (0.8); 5.8082 (1.0); 5.7962 (0.9); 5.3001 (16.0); 5.1841 (0.7); 5.1784 (0.8); 5.1723 (0.9); 5.1675 (0.9); 5.1557 (0.9); 5.1509 (1.1); 5.1455 (1.0); 5.1407 (0.8); 5.1352 (0.6); 5.1300 (0.7);

5.1242 (0.9); 5.1197 (1.0); 5.1001 (1.9); 5.0799 (2.0); 4.4328 (0.5); 4.3943 (2.9); 4.3843 (2.4); 4.3638 (2.4); 4.3600 (5.6); 4.3563 (3.0); 4.3541 (2.9); 4.3501 (5.2); 4.3443 (2.3); 4.3323 (5.7); 4.3257 (3.8);

4.3222 (5.5); 4.3160 (3.2); 4.3100 (3.9); 4.2984 (5.9); 4.2880 (4.6); 4.2758 (1.9); 4.2654 (2.3); 4.2537 (1.4); 4.0606 (2.2); 4.0502 (5.3); 4.0152 (3.2); 4.0051 (7.4); 3.8758 (0.6); 3.8696 (0.9); 3.8635 (1.0);

3.8574 (1.1); 3.8534 (1.4); 3.8476 (1.7); 3.8415 (1.8); 3.8355 (1.5); 3.8307 (1.1); 3.8253 (1.1); 3.8123 (7.4); 3.8072 (7.3); 3.8005 (6.4); 3.7927 (1.0); 3.7812 (2.3); 3.7670 (5.1); 3.7620 (5.0); 3.7553 (4.3);

3.7343 (2.0); 3.6409 (1.8); 3.6343 (2.2); 3.6274 (2.4); 3.6200 (2.3); 3.6137 (1.9); 3.6076 (1.4); 2.7795 (0.8); 2.7671 (0.8); 2.7590 (0.9); 2.7463 (1.1); 2.7441 (1.1); 2.7355 (0.8); 2.7315 (1.0); 2.7236 (1.6);

2.7147 (0.9); 2.7112 (1.0); 2.7031 (0.9); 2.7004 (0.9); 2.6886 (0.8); 2.6794 (0.8); 2.6677 (0.8); 2.6274 (1.2); 2.6063 (2.1); 2.5919 (1.4); 2.5852 (1.2); 2.5708 (2.3); 2.5524 (1.6); 2.5318 (2.4); 2.5173 (1.6);

2.5109 (1.4); 2.4964 (2.6); 2.4755 (1.3); 2.0361 (1.2); 2.0278 (2.2); 2.0186 (1.6); 2.0066 (1.4); 2.0002 (2.4); 1.9918 (4.2); 1.9835 (3.1); 1.9708 (1.0); 1.9645 (1.3); 1.9560 (2.3); 1.9476 (2.2); 1.9353 (0.8);

1.9248 (0.7); 1.9127 (1.1); 1.8998 (0.7); 1.8893 (0.6); 1.8778 (0.6); 1.5759 (2.6); 0.0080 (1.5); -0.0002 (39.7); -0.0080(1.4)

- 119 044070

1-149: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2602 (7.0); 7.1930 (0.7); 7.1873 (0.7); 7.1819 (0.7); 7.1761 (0.9); 7.1732 (0.9); 7.1674 (0.7); 7.1620 (0.6); 6.8898 (0.7); 4.0055 (0.9); 3.9869 (1.2); 3.9574 (1.7); 3.9274 (0.7); 3.7187 (0.5); 3.6748 (0.9);

3.6647 (0.7); 3.5579 (1.3); 3.5139 (0.7); 1.5524 (0.8); 1.4957 (0.5); 1.4842 (0.9); 1.4761 (12.9); 1.4418 (1.9); 1.4313 (16.0); -0.0002 (8.7)

1-150: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3854 (0.9); 7.3636 (0.9); 7.2608 (12.3); 7.2238 (4.8); 7.1960 (1.4); 7.0071 (1.4); 6.9839 (1.3);

6.0074 (1.1); 6.0040 (1.2); 6.0010 (1.2); 5.9975 (1.2); 5.9937 (1.5); 5.9902 (1.6); 5.9873 (1.6); 5.9839 (1.4); 5.9210 (1.4); 5.9155 (2.5); 5.9099 (1.6); 5.9018 (1.8); 5.8962 (1.0); 5.0862 (0.6); 5.0652 (1.1);

5.0456 (0.5); 4.2165 (2.2); 4.1986 (6.7); 4.1808 (6.9); 4.1630 (2.3); 4.0036 (2.0); 3.9585 (2.9); 3.7762 (4.7); 3.7312 (3.3); 3.5297 (1.0); 3.5269 (0.9); 3.5236 (1.0); 3.5155 (0.9); 3.5086 (1.0); 3.5056 (0.9);

3.5026 (1.0); 2.4954 (1.0); 2.4745 (1.8); 2.4602 (1.2); 2.4536 (1.1); 2.4393 (2.1); 2.4182 (1.3); 2.3863 (16.0); 1.9642 (1.0); 1.9558 (1.8); 1.9475 (1.1); 1.9290 (0.9); 1.9206 (1.6); 1.9122 (0.9); 1.5578 (5.9);

1.3024 (7.7); 1.2846 (15.3); 1.2667 (7.7); 0.0079 (0.7); -0.0002 (18.3); -0.0084 (0.8)

1-151: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3727 (0.9); 7.3503 (0.9); 7.2612 (10.0); 7.2148 (4.4); 7.1868 (1.4); 7.0061 (1.4); 6.9829 (1.3);

5.9976 (1.2); 5.9941 (1.3); 5.9911 (1.3); 5.9876 (1.3); 5.9839 (1.4); 5.9804 (1.5); 5.9774 (1.4); 5.9740 (1.3); 5.8512 (1.4); 5.8457 (2.4); 5.8400 (1.5); 5.8378 (1.4); 5.8319 (1.9); 5.8264 (1.1); 5.1078 (0.6);

5.0857 (1.1); 5.0650 (0.6); 4.2371 (2.3); 4.2192 (7.1); 4.2014 (7.3); 4.1835 (2.5); 4.0016 (2.0); 3.9566 (2.9); 3.7710 (4.8); 3.7260 (3.4); 3.5473 (0.5); 3.5411 (1.0); 3.5347 (1.0); 3.5273 (0.9); 3.5198 (1.0);

3.5136 (1.0); 2.5604 (1.0); 2.5394 (1.8); 2.5251 (1.2); 2.5183 (1.1); 2.5040 (2.0); 2.4830 (1.0); 2.3838 (16.0); 2.0047 (1.0); 1.9967 (1.8); 1.9888 (1.0); 1.9694 (0.9); 1.9614 (1.6); 1.9535 (0.9); 1.5633 (5.0);

1.3255 (7.9); 1.3076 (15.8); 1.2960 (0.8); 1.2897 (7.7); 1.2575 (0.8); 1.2528 (0.7); 0.0080 (0.6); -0.0002 (15.2); -0.0084 (0.6)

1-152: Ή-ΉΜΡ(400.0 MHz, CDC13):

δ= 7.2605 (20.1); 7.2107 (5.2); 7.1900 (1.4); 7.0210 (1.4); 6.9975 (1.4); 6.8092 (1.0); 6.7896 (0.9);

6.0269 (1.3); 6.0225 (1.6); 6.0210 (1.6); 6.0166 (1.5); 6.0131 (1.6); 6.0086 (1.8); 6.0071 (1.7); 6.0027 (1.4); 5.8702 (1.4); 5.8645 (2.5); 5.8586 (1.6); 5.8565 (1.4); 5.8506 (2.1); 5.8449 (1.2); 5.1827 (0.5);

5.1769 (0.6); 5.1723 (0.7); 5.1669 (0.9); 5.1620 (1.0); 5.1566 (1.0); 5.1512 (0.9); 5.1460 (0.7); 5.1415 (0.5); 5.1355 (0.5); 4.1677 (2.2); 4.1623 (0.6); 4.1499 (6.7); 4.1321 (6.7); 4.1143 (2.2); 4.0105 (1.9);

3.9653 (2.8); 3.7862 (4.6); 3.7522 (0.5); 3.7461 (1.2); 3.7409 (4.1); 3.7345 (1.4); 3.7286 (1.1); 3.7244 (1.2); 3.7184 (1.2); 3.7125 (1.1); 3.7065 (0.8); 2.7113 (1.1); 2.6994 (1.1); 2.6906 (1.2); 2.6785 (1.4);

2.6762 (1.4); 2.6642 (1.2); 2.6553 (1.1); 2.6434 (1.1); 2.3919 (16.0); 1.8873 (1.1); 1.8760 (1.1); 1.8654 (1.1); 1.8537 (1.5); 1.8408 (1.0); 1.8301 (1.0); 1.8188 (1.0); 1.5464 (11.0); 1.3255 (0.6); 1.3077 (1.1); 1.2959 (0.6); 1.2899 (0.9); 1.2817 (1.0); 1.2704 (7.9); 1.2639 (2.1); 1.2526 (15.7); 1.2347 (7.3); 0.0079 (1.4); -0.0002 (29.3); -0.0084 (1.0)

- 120 044070

1-153: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2609 (13.2); 7.2112 (4.4); 7.2086 (4.7); 7.1915 (1.1); 7.1872 (1.3); 7.0186 (1.4); 6.9967 (1.3);

6.9948 (1.3); 6.8319 (0.9); 6.8117 (0.9); 6.0372 (1.3); 6.0330 (1.6); 6.0313 (1.5); 6.0270 (1.4); 6.0233 (1.5); 6.0191 (1.7); 6.0174 (1.7); 6.0132 (1.5); 5.8166 (1.3); 5.8108 (2.4); 5.8048 (1.5); 5.8029 (1.4);

5.7969 (2.0); 5.7911 (1.1); 5.2993 (10.6); 5.1546 (0.6); 5.1488 (0.6); 5.1443 (0.7); 5.1386 (0.9); 5.1340 (1.0); 5.1283 (1.0); 5.1237 (0.8); 5.1180 (0.6); 4.1799 (2.1); 4.1620 (6.4); 4.1498 (0.9); 4.1442 (6.5);

4.1320 (0.6); 4.1264 (2.1); 4.0069 (1.8); 3.9617 (2.7); 3.7842 (4.6); 3.7701 (0.9); 3.7639 (1.1); 3.7576 (1.2); 3.7515 (1.1); 3.7483 (1.2); 3.7391 (3.5); 3.7297 (0.9); 2.7458 (1.0); 2.7332 (1.0); 2.7253 (1.1);

2.7125 (1.4); 2.7107 (1.4); 2.6979 (1.2); 2.6900 (1.2); 2.6774 (1.1); 2.3892 (15.0); 1.9665 (1.0); 1.9560 (1.0); 1.9447 (1.0); 1.9341 (1.2); 1.9313 (1.1); 1.9207 (1.0); 1.9094 (0.9); 1.8989 (0.9); 1.5524 (1.7);

1.2817 (7.7); 1.2701 (1.7); 1.2638 (16.0); 1.2526 (2.5); 1.2460 (7.6); 1.2347 (0.9); 0.8801 (0.6); 0.8533 (0.5); 0.0079 (0.8); -0.0002 (20.2); -0.0085 (0.7)

1-154: !H-NMR(400.0 MHz, CDC13):

δ= 7.6783 (2.8); 7.6748 (3.4); 7.6706 (1.6); 7.6637 (1.2); 7.6582 (3.9); 7.6541 (3.4); 7.5000 (0.5); 7.4817 (1.6); 7.4747 (0.7); 7.4682 (1.6); 7.4643 (2.7); 7.4599 (1.8); 7.4554 (2.9); 7.4535 (3.8); 7.4499 (1.8);

7.4407 (1.4); 7.4388 (1.6); 7.4353 (3.8); 7.4337 (2.4); 7.4300 (0.7); 7.4228 (0.6); 7.4188 (1.2); 7.4133 (1.0); 7.3963 (0.6); 7.3760 (0.6); 7.2604 (24.4); 6.0055 (0.9); 6.0020 (1.0); 5.9992 (1.0); 5.9957 (1.0);

5.9918 (1.2); 5.9883 (1.3); 5.9854 (1.3); 5.9819 (1.2); 5.9216 (1.2); 5.9162 (2.2); 5.9105 (1.3); 5.9080 (1.0); 5.9024 (1.6); 5.8968 (0.9); 5.0726 (0.8); 4.2138 (2.1); 4.1960 (6.8); 4.1781 (7.0); 4.1603 (2.3);

4.0401 (1.5); 3.9953 (2.3); 3.8204 (4.6); 3.7754 (3.1); 3.5277 (0.7); 3.5249 (0.7); 3.5221 (0.7); 3.5155 (0.7); 3.5131 (0.7); 3.5065 (0.8); 3.5037 (0.7); 3.5009 (0.7); 2.5052 (0.8); 2.4842 (1.6); 2.4701 (1.1);

2.4633 (0.9); 2.4491 (1.8); 2.4281 (0.9); 1.9629 (0.8); 1.9541 (1.5); 1.9453 (0.8); 1.9277 (0.7); 1.9189 (1.3); 1.9101 (0.7); 1.5512 (11.8); 1.2990 (7.8); 1.2811 (16.0); 1.2702 (0.8); 1.2633 (7.8); 1.2524 (1.2); 1.2346 (0.6); 0.0080 (0.9); -0.0002 (31.0); -0.0085 (1.1)

1-155: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6708 (2.9); 7.6673 (3.6); 7.6631 (1.8); 7.6561 (1.2); 7.6507 (4.2); 7.6466 (3.6); 7.4996 (0.6); 7.4813 (1.8); 7.4743 (0.8); 7.4677 (1.7); 7.4638 (2.8); 7.4595 (1.6); 7.4542 (3.0); 7.4524 (4.0); 7.4488 (1.8);

7.4395 (1.6); 7.4377 (1.8); 7.4343 (4.0); 7.4326 (2.5); 7.4289 (0.8); 7.4216 (0.6); 7.4175 (1.2); 7.4122 (0.9); 7.3843 (0.6); 7.3619 (0.6); 7.2608 (14.6); 5.9948 (1.0); 5.9912 (1.1); 5.9883 (1.1); 5.9848 (1.1);

5.9810 (1.2); 5.9775 (1.3); 5.9746 (1.2); 5.9710 (1.1); 5.8498 (1.2); 5.8442 (2.1); 5.8386 (1.3); 5.8362 (1.1); 5.8305 (1.7); 5.8249 (1.0); 5.0916 (0.8); 5.0898 (0.8); 4.2375 (2.2); 4.2197 (7.1); 4.2018 (7.3);

4.1840 (2.4); 4.0394 (1.6); 3.9936 (2.4); 3.8155 (4.6); 3.7705 (3.2); 3.5399 (0.8); 3.5372 (0.7); 3.5343 (0.8); 3.5271 (0.7); 3.5184 (0.8); 3.5154 (0.7); 3.5128 (0.8); 2.5693 (0.8); 2.5482 (1.6); 2.5340 (1.1);

2.5271 (0.9); 2.5129 (1.7); 2.4918 (0.9); 2.0062 (0.9); 1.9979 (1.5); 1.9896 (0.8); 1.9709 (0.7); 1.9626 (1.4); 1.9544 (0.8); 1.5608 (6.0); 1.3261 (7.8); 1.3083 (16.0); 1.2904 (7.7); 1.2629 (0.5); 0.0079 (0.5); 0.0002 (17.5); -0.0085 (0.7)

- 121 044070

1-156: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6706 (3.1); 7.6673 (4.0); 7.6632 (2.1); 7.6559 (1.4); 7.6505 (4.8); 7.6464 (4.0); 7.5138 (0.6); 7.4952 (2.1); 7.4887 (0.8); 7.4816 (1.8); 7.4778 (2.8); 7.4738 (1.5); 7.4702 (1.0); 7.4640 (4.4); 7.4607 (2.1);

7.4494 (2.0); 7.4459 (4.3); 7.4329 (0.8); 7.4286 (1.4); 7.4239 (1.0); 7.2605 (24.2); 6.8512 (0.8); 6.8316 (0.8); 6.0240 (1.3); 6.0196 (1.5); 6.0180 (1.6); 6.0136 (1.4); 6.0101 (1.6); 6.0058 (1.8); 6.0040 (1.7); 5.9997 (1.5); 5.8736 (1.4); 5.8679 (2.5); 5.8621 (1.5); 5.8598 (1.3); 5.8540 (2.1); 5.8482 (1.2); 5.1755 (0.7); 5.1700 (0.8); 5.1648 (0.9); 5.1595 (0.9); 5.1545 (0.8); 5.1490 (0.7); 5.1446 (0.5); 4.1657 (2.2); 4.1618 (0.7); 4.1479 (6.9); 4.1301 (7.0); 4.1122 (2.3); 4.0455 (1.8); 4.0002 (2.8); 3.8305 (4.8); 3.7854 (3.3); 3.7447 (0.8); 3.7387 (1.1); 3.7328 (1.2); 3.7268 (1.0); 3.7227 (1.0); 3.7168 (1.2); 3.7108 (1.1); 3.7048 (0.8); 2.7091 (1.1); 2.6972 (1.1); 2.6883 (1.1); 2.6764 (1.3); 2.6739 (1.4); 2.6619 (1.2); 2.6530 (1.1); 2.6412 (1.1); 1.8910 (1.0); 1.8797 (1.1); 1.8690 (1.1); 1.8575 (1.3); 1.8444 (1.0); 1.8337 (1.0); 1.8225 (1.0); 1.5467 (12.5); 1.3084 (0.6); 1.2815 (0.8); 1.2686 (7.8); 1.2637 (2.0); 1.2508 (16.0); 1.2330 (7.5); 0.0080 (0.9); -0.0002 (29.6); -0.0085 (1.1)

1-157: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6683 (3.0); 7.6649 (3.8); 7.6608 (1.9); 7.6535 (1.3); 7.6482 (4.5); 7.6441 (3.6); 7.5110 (0.6); 7.4925 (2.0); 7.4859 (0.8); 7.4788 (1.7); 7.4750 (2.7); 7.4709 (1.4); 7.4670 (1.0); 7.4629 (3.0); 7.4610 (4.1);

7.4575 (1.8); 7.4476 (1.9); 7.4463 (2.0); 7.4428 (4.1); 7.4412 (2.8); 7.4298 (0.7); 7.4257 (1.3); 7.4209 (0.9); 7.2604 (28.3); 6.8690 (0.7); 6.8497 (0.7); 6.0324 (1.2); 6.0282 (1.4); 6.0264 (1.4); 6.0222 (1.4); 6.0185 (1.5); 6.0143 (1.7); 6.0125 (1.6); 6.0083 (1.4); 5.8185 (1.2); 5.8127 (2.3); 5.8068 (1.4); 5.8048 (1.3); 5.7988 (2.1); 5.7930 (1.1); 5.1581 (0.5); 5.1523 (0.5); 5.1479 (0.7); 5.1421 (0.8); 5.1375 (0.9); 5.1318 (0.9); 5.1272 (0.8); 5.1214 (0.6); 4.1794 (2.0); 4.1616 (6.2); 4.1438 (6.5); 4.1260 (2.1); 4.0418 (1.7); 3.9972 (2.5); 3.8279 (4.6); 3.7828 (3.2); 3.7700 (0.8); 3.7638 (1.0); 3.7575 (1.1); 3.7513 (1.0); 3.7481 (1.0); 3.7420 (1.1); 3.7356 (1.0); 3.7295 (0.8); 2.7453 (1.0); 2.7327 (1.0); 2.7248 (1.1); 2.7120 (1.3); 2.7101 (1.4); 2.6974 (1.2); 2.6895 (1.1); 2.6768 (1.1); 1.9702 (1.0); 1.9598 (1.0); 1.9484 (1.0); 1.9378 (1.1); 1.9350 (1.1); 1.9244 (0.9); 1.9130 (0.9); 1.9026 (0.9); 1.5441 (8.2); 1.2815 (7.5); 1.2636 (16.0); 1.2508 (1.5); 1.2458 (7.5); 1.2330 (0.6); 0.0079 (1.0); -0.0002 (35.6); -0.0085 (1.4) 1-158: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.8680 (1.3); 7.8639 (1.9); 7.8592 (1.7); 7.8545 (1.4); 7.8504 (1.9); 7.8458 (1.6); 7.8187 (1.6); 7.8150 (2.6); 7.8113 (1.4); 7.8050 (1.7); 7.8014 (2.7); 7.7977 (1.4); 7.6749 (1.7); 7.6717 (2.9); 7.6701 (2.3);

7.6684 (2.3); 7.6668 (2.7); 7.6636 (1.5); 7.2619 (21.7); 7.1857 (0.8); 5.9800 (0.5); 5.9764 (0.6); 5.9736 (0.7); 5.9700 (0.7); 5.9664 (0.9); 5.9626 (1.0); 5.9597 (1.1); 5.9565 (1.3); 5.9536 (1.1); 5.9504 (0.8);

5.9469 (0.7); 5.9431 (0.7); 5.9394 (0.8); 5.9368 (0.7); 5.9331 (0.6); 5.9050 (0.8); 5.8995 (1.4); 5.8939 (0.8); 5.8915 (0.6); 5.8858 (0.9); 5.8802 (0.5); 5.8155 (0.6); 5.8099 (1.2); 5.8043 (0.7); 5.8019 (0.6);

5.7962 (1.0); 5.7905 (0.6); 5.7338 (0.6); 5.3289 (0.6); 5.0057 (0.8); 3.8330 (1.9); 3.8276 (2.0); 3.7898 (2.2); 3.7844 (2.3); 3.7703 (0.8); 3.7584 (15.9); 3.7315 (16.0); 3.7262 (6.4); 3.7009 (0.6); 3.5464 (0.6); 3.5401 (0.7); 3.5376 (0.7); 3.5310 (0.9); 3.5279 (0.9); 3.5252 (1.0); 3.5188 (0.8); 3.2073 (2.0); 3.1968

- 122 044070 (1.9); 3.1641 (1.7); 3.1536 (1.7); 2.5419 (0.8); 2.5279 (0.6); 2.5069 (0.9); 2.4859 (0.5); 2.4716 (0.9); 2.4576 (0.7); 2.4506 (0.5); 2.4366 (0.9); 1.9682 (2.2); 1.9658 (2.0); 1.9643 (2.0); 1.9619 (1.7); 1.9436 (0.6); 1.9340 (0.7); 1.8893 (0.5); 1.8802 (0.8); 1.8453 (0.7); 1.7419 (10.4); 1.7287 (10.6); 1.7117 (0.6); 1.5709 (10.0); 0.0079 (0.7); -0.0002 (21.4); -0.0085 (0.8)

1-159: ¹ H-NMR(400.0 MHz, CDC13):

δ= 8.1375 (3.6); 8.1338 (3.8); 8.1211 (3.7); 8.1173 (3.8); 7.9588 (1.0); 7.9553 (2.5); 7.9517 (2.4); 7.9481 (1.0); 7.2603 (55.0); 5.9705 (0.5); 5.9676 (0.5); 5.9639 (0.6); 5.9033 (0.8); 5.8977 (0.5); 5.8896 (0.6); 5.8102 (0.8); 5.7964 (0.7); 3.8686 (1.3); 3.8601 (1.3); 3.8254 (1.4); 3.8170 (1.5); 3.7619 (11.0); 3.7344 (10.6); 3.5294 (0.5); 3.2227 (1.3); 3.2095 (1.3); 3.1794 (1.2); 3.1662 (1.2); 2.5340 (0.5); 2.4990 (0.6); 2.4776 (0.6); 2.4563 (0.6); 2.4213 (0.6); 1.9754 (0.6); 1.8820 (0.6); 1.8473 (0.5); 1.7605 (7.0); 1.7468 (7.2); 1.5405 (16.0); 0.0080 (2.0); -0.0002 (69.4); -0.0085 (2.6)

1-160: !H-NMR(400.0 MHz, CDC13):

δ= 7.8495 (0.8); 7.8428 (1.7); 7.8388 (3.1); 7.8341 (3.5); 7.8298 (3.7); 7.8259 (4.9); 7.8220 (1.7); 7.8153 (0.7); 7.8116 (0.8); 7.8063 (1.1); 7.8018 (2.4); 7.7981 (3.6); 7.7944 (1.8); 7.6808 (0.7); 7.6686 (2.4);

7.6652 (3.4); 7.6634 (3.7); 7.6612 (3.2); 7.6579 (2.1); 7.2620 (27.6); 7.2372 (0.8); 7.2146 (1.4); 7.1929 (0.8); 6.0385 (0.8); 6.0349 (0.8); 6.0323 (1.0); 6.0285 (0.9); 6.0246 (1.1); 6.0211 (1.2); 6.0184 (1.4);

6.0148 (1.2); 6.0071 (1.0); 6.0034 (1.1); 6.0010 (1.1); 5.9971 (1.0); 5.9934 (1.0); 5.9874 (1.5); 5.9822 (2.3); 5.9400 (0.9); 5.9344 (1.7); 5.9287 (1.0); 5.9263 (0.9); 5.9206 (1.3); 5.9150 (0.8); 5.8569 (0.8); 5.8512 (1.6); 5.8454 (1.0); 5.8432 (1.0); 5.8374 (1.4); 5.8316 (0.8); 5.7264 (0.8); 5.7241 (1.0); 5.7216 (0.8); 5.3380 (0.7); 5.3346 (0.8); 5.3312 (0.7); 5.3000 (0.6); 5.0154 (1.0); 3.8341 (4.7); 3.8215 (0.6); 3.8093 (0.6); 3.7908 (5.5); 3.6069 (0.8); 3.6040 (0.9); 3.6010 (0.9); 3.5950 (1.3); 3.5895 (1.3); 3.5829 (1.0); 3.5709 (0.6); 3.5680 (0.6); 3.2255 (0.7); 3.2188 (2.6); 3.2092 (2.6); 3.1820 (0.7); 3.1755 (2.3); 3.1658 (2.2); 2.5862 (1.0); 2.5721 (0.7); 2.5650 (0.7); 2.5548 (0.7); 2.5510 (1.1); 2.5304 (1.0); 2.5197 (0.6); 2.5099 (1.0); 2.4959 (0.8); 2.4889 (0.6); 2.4748 (1.1); 2.4539 (0.5); 2.0466 (0.6); 2.0264 (0.6);

2.0168 (1.0); 2.0073 (0.6); 1.9919 (0.8); 1.9817 (1.0); 1.9721 (0.6); 1.9639 (0.7); 1.9577 (0.9); 1.9509 (2.5); 1.9485 (3.1); 1.9473 (3.1); 1.9449 (2.4); 1.9201 (0.7); 1.9110 (1.1); 1.9014 (0.7); 1.8850 (0.6); 1.8757 (0.9); 1.8665 (0.6); 1.7384 (16.0); 1.7308 (15.2); 1.7215 (2.3); 1.7121 (1.0); 1.2886 (0.7); 1.2610 (0.8); 0.0080 (1.0); -0.0002 (34.6); -0.0084 (1.3)

1-169: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2718 (1.1); 7.2612 (18.4); 7.2111 (1.9); 7.2094 (1.9); 7.1914 (1.2); 7.1679 (1.1); 6.9564 (0.8); 6.9329 (0.8); 6.2133 (1.1); 6.1866 (1.2); 6.1702 (1.3); 6.1434 (1.3); 5.9500 (0.7); 5.9460 (0.8); 5.9440 (0.8); 5.9399 (0.8); 5.9363 (0.8); 5.9323 (0.9); 5.9262 (0.7); 5.8256 (0.8); 5.8200 (1.3); 5.8143 (0.8); 5.8120 (0.8); 5.8062 (1.1); 5.8006 (0.6); 5.5707 (1.8); 5.5691 (1.7); 5.5275 (1.6); 5.5260 (1.5); 5.3423 (1.7); 5.3409 (1.7); 5.3154 (1.6); 5.0235 (0.5); 3.9487 (2.0); 3.9057 (2.3); 3.7679 (0.6); 3.7563 (1.1); 3.7511 (1.7); 3.7463 (16.0); 3.7334 (1.3); 3.5201 (0.5); 3.5168 (0.5); 3.3457 (2.2); 3.3028 (1.8); 2.7057 (0.6); 2.5739 (0.6); 2.5529 (1.0); 2.5390 (0.8); 2.5316 (0.7); 2.5179 (1.1); 2.4968 (0.6); 2.3983 (0.5);

- 123 044070

2.3689 (8.6); 1.9478 (0.6); 1.9376 (0.9); 1.9273 (0.5); 1.9128 (0.5); 1.9027 (0.8); 1.2564 (0.5); 0.0103 (1.1); 0.0079 (1.2); -0.0002 (21.0); -0.0084 (1.2)

1-170: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2626 (6.3); 7.2155 (2.2); 7.2006 (1.2); 7.1958 (1.1); 7.1724 (0.8); 6.9578 (0.8); 6.9345 (0.8); 6.2125 (1.1); 6.1857 (1.2); 6.1693 (1.3); 6.1426 (1.4); 5.9633 (0.6); 5.9593 (0.8); 5.9571 (0.8); 5.9533 (0.8);

5.9495 (0.9); 5.9455 (1.0); 5.9434 (1.0); 5.9395 (0.9); 5.8799 (0.8); 5.8744 (1.4); 5.8687 (0.9); 5.8664 (0.8); 5.8606 (1.1); 5.8550 (0.6); 5.5518 (1.7); 5.5504 (1.8); 5.5086 (1.5); 5.5073 (1.6); 5.3264 (1.7);

5.2996 (1.6); 5.0236 (0.5); 3.9453 (2.1); 3.9024 (2.4); 3.7529 (0.6); 3.7456 (1.2); 3.7332 (16.0); 3.5186 (0.5); 3.5150 (0.5); 3.5080 (0.6); 3.5041 (0.5); 3.3506 (2.2); 3.3076 (1.9); 2.5311 (0.6); 2.5100 (1.0);

2.4961 (0.7); 2.4889 (0.6); 2.4751 (1.1); 2.4540 (0.6); 2.3708 (8.9); 1.9046 (0.6); 1.8944 (1.0); 1.8841 (0.6); 1.8697 (0.6); 1.8595 (0.9); 1.8492 (0.5); 1.2558 (0.6); -0.0002 (7.1); -0.0081 (0.5)

1-171: ¹ H-NMR(400.0 MHz, CDC13):

δ= 8.4246 (0.6); 8.1386 (4.5); 8.1349 (4.8); 8.1244 (3.2); 8.1219 (5.6); 8.1183 (7.2); 8.1147 (3.0); 7.9709 (1.3); 7.9654 (1.4); 7.9617 (0.9); 7.9580 (1.5); 7.9545 (2.6); 7.9518 (2.6); 7.2616 (44.6); 7.1807 (0.8);

6.0124 (0.7); 6.0021 (1.0); 5.9983 (1.0); 5.9877 (1.0); 5.9087 (0.7); 5.9031 (1.1); 5.8973 (0.7); 5.8891 (0.8); 5.8839 (0.5); 5.8696 (0.6); 5.8558 (0.6); 5.8138 (0.6); 5.8083 (1.0); 5.7945 (0.9); 5.0152 (0.7);

4.3226 (1.0); 4.3106 (2.4); 4.2990 (2.5); 4.2905 (1.2); 4.2803 (1.4); 4.2670 (1.7); 4.2569 (1.4); 4.2527 (1.1); 4.2471 (1.2); 3.9781 (1.2); 3.8831 (0.9); 3.8747 (1.7); 3.8603 (1.6); 3.8399 (1.0); 3.8316 (2.0);

3.8173 (1.7); 3.7478 (0.5); 3.6472 (2.1); 3.6364 (2.4); 3.6238 (2.8); 3.6126 (2.1); 3.6058 (1.9); 3.5941 (2.3); 3.5895 (1.8); 3.5823 (2.1); 3.5777 (2.4); 3.5661 (1.4); 3.4327 (3.9); 3.4072 (16.0); 3.3894 (14.9);

3.3872 (11.0); 3.3825 (3.3); 3.3725 (7.8); 3.3699 (2.3); 3.2223 (2.1); 3.2067 (1.5); 3.1793 (1.7); 3.1635 (1.4); 2.5352 (0.7); 2.5002 (0.8); 2.4609 (0.7); 2.4259 (0.7); 1.9839 (0.7); 1.9490 (0.6); 1.9406 (0.5);

1.8911 (0.7); 1.8561 (0.7); 1.8471 (0.6); 1.7594 (8.6); 1.7543 (3.7); 1.7495 (9.1); 1.7441 (9.9); 1.5665 (2.1); 1.3434 (1.3); 0.0080 (2.4); -0.0002 (60.3); -0.0085 (2.4)

1-174: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2612 (16.3); 7.2091 (1.8); 7.2058 (2.4); 7.2033 (2.4); 7.2001 (2.4); 7.1895 (2.2); 7.1863 (2.1);

7.1838 (2.0); 7.1805 (1.4); 6.9232 (0.5); 6.9173 (0.9); 6.9115 (0.5); 6.9014 (1.1); 6.8956 (1.9); 6.8898 (1.0); 6.8797 (0.6); 6.8739 (1.0); 6.0224 (0.8); 6.0161 (0.9); 6.0123 (1.1); 6.0086 (1.3); 6.0026 (1.3);

5.9985 (0.8); 5.9728 (0.7); 5.9675 (1.2); 5.9619 (0.7); 5.9508 (1.3); 5.9453 (0.8); 5.9370 (0.8); 5.1010 (0.7); 3.8644 (3.1); 3.8191 (3.6); 3.6059 (0.7); 3.5997 (0.8); 3.5933 (0.7); 3.3645 (14.3); 3.3596 (16.0);

3.3136 (1.9); 3.3107 (2.0); 2.6014 (0.7); 2.5801 (0.5); 2.5764 (0.8); 2.5661 (0.8); 2.5624 (0.6); 2.5412 (0.8); 2.0303 (1.0); 2.0211 (1.0); 2.0082 (0.8); 1.9949 (0.9); 1.9858 (0.9); 0.0080 (0.8); -0.0002 (21.4); 0.0085 (1.0)

1-175: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6635 (3.6); 7.6578 (5.0); 7.6536 (4.8); 7.6497 (3.2); 7.6444 (3.9); 7.6394 (6.3); 7.6337 (4.1); 7.4503 (0.6); 7.4463 (0.8); 7.4338 (2.1); 7.4303 (2.8); 7.4217 (5.7); 7.4179 (11.6); 7.4136 (5.8); 7.4112 (5.1);

- 124 044070

7.4042 (3.9); 7.4001 (6.0); 7.3908 (1.4); 7.3865 (1.8); 7.3821 (0.9); 7.3778 (1.1); 7.2609 (29.9); 7.2283 (0.8); 7.2018 (1.2); 7.1756 (0.8); 6.2275 (3.3); 6.2008 (3.7); 6.1844 (3.9); 6.1577 (4.1); 5.9612 (1.1); 5.9551 (1.3); 5.9477 (2.0); 5.9431 (2.7); 5.9377 (2.2); 5.9313 (1.6); 5.9250 (1.3); 5.8739 (1.4); 5.8683 (2.5); 5.8627 (1.5); 5.8545 (1.9); 5.8489 (1.1); 5.8145 (1.3); 5.8088 (2.4); 5.8031 (1.4); 5.7951 (2.0); 5.7893 (1.0); 5.5755 (3.3); 5.5737 (3.3); 5.5579 (3.3); 5.5560 (3.4); 5.5324 (2.9); 5.5305 (2.9); 5.5147 (2.9); 5.5128 (2.9); 5.3344 (3.0); 5.3327 (3.0); 5.3204 (3.0); 5.3186 (2.9); 5.3077 (2.8); 5.3060 (2.9); 5.2937 (2.8); 5.2918 (2.8); 5.0298 (1.4); 4.2221 (2.1); 4.2043 (7.3); 4.1869 (9.4); 4.1698 (7.4); 4.1521 (2.3); 3.9908 (4.2); 3.9859 (4.3); 3.9479 (4.7); 3.9430 (4.8); 3.4928 (1.6); 3.3944 (4.3); 3.3899 (4.1); 3.3515 (3.6); 3.3469 (3.6); 2.5731 (0.8); 2.5520 (1.6); 2.5381 (1.3); 2.5307 (1.1); 2.5168 (2.1); 2.5009 (1.3); 2.4959 (1.2); 2.4936 (1.2); 2.4797 (1.8); 2.4587 (0.9); 1.9431 (1.0); 1.9328 (1.5); 1.9224 (0.9); 1.9084 (0.9); 1.8985 (1.9); 1.8890 (2.0); 1.8787 (1.0); 1.8652 (0.9); 1.8545 (1.5); 1.8441 (0.8); 1.3429 (0.6); 1.3251 (1.6); 1.3190 (7.7); 1.3012 (15.7); 1.2931 (8.2); 1.2833 (7.9); 1.2752 (16.0); 1.2574 (7.5); 0.0079 (1.6); -0.0002 (38.2); -0.0085 (1.6)

1-176: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6790 (1.0); 7.6637 (7.1); 7.6596 (8.4); 7.6574 (9.3); 7.6533 (10.4); 7.6495 (6.0); 7.6466 (7.3); 7.6447 (6.9); 7.6396 (12.5); 7.6333 (8.6); 7.4536 (1.3); 7.4495 (1.6); 7.4369 (4.2); 7.4334 (5.8); 7.4247 (10.7); 7.4206 (23.5); 7.4024 (11.1); 7.3886 (2.9); 7.3805 (1.8); 7.2610 (68.5); 7.1989 (1.7); 7.1809 (2.5); 6.2296 (4.8); 6.2273 (4.8); 6.2029 (5.4); 6.2005 (5.1); 6.1864 (5.8); 6.1841 (6.0); 6.1597 (5.9); 6.1574 (5.7); 5.9820 (2.3); 5.9782 (2.6); 5.9758 (2.6); 5.9720 (2.3); 5.9682 (3.2); 5.9643 (5.2); 5.9620 (4.1); 5.9581 (5.0); 5.9540 (2.6); 5.9504 (2.9); 5.9463 (2.9); 5.9443 (2.9); 5.9402 (2.6); 5.9014 (2.8); 5.8958 (5.0); 5.8901 (2.7); 5.8876 (2.2); 5.8820 (3.7); 5.8763 (2.2); 5.8434 (2.8); 5.8377 (4.9); 5.8321 (3.0); 5.8296 (2.8); 5.8239 (4.2); 5.8183 (2.1); 5.6173 (0.7); 5.5776 (6.9); 5.5758 (7.5); 5.5591 (7.3); 5.5572 (7.4); 5.5345 (6.2); 5.5327 (6.1); 5.5159 (6.4); 5.5140 (6.4); 5.4034 (0.7); 5.3767 (0.6); 5.3399 (6.2); 5.3381 (6.5); 5.3252 (5.9); 5.3233 (5.9); 5.3132 (6.0); 5.3114 (6.4); 5.2984 (5.4); 5.2966 (5.5); 5.0421 (2.8); 4.4837 (0.7); 4.4527 (0.7); 4.4459 (0.6); 4.4319 (1.2); 4.4163 (4.5); 4.4072 (4.8); 4.4023 (7.3);

4.3922 (6.7); 4.3874 (10.4); 4.3790 (5.5); 4.3751 (8.5); 4.3727 (7.0); 4.3713 (7.4); 4.3593 (8.1); 4.3465 (1.3); 4.3315 (1.2); 4.0129 (0.8); 3.9887 (13.8); 3.9705 (1.0); 3.9523 (1.6); 3.9457 (16.0); 3.7461 (6.0); 3.7442 (6.2); 3.7319 (9.4); 3.7300 (11.8); 3.7194 (12.4); 3.7155 (6.5); 3.7049 (10.0); 3.6909 (8.6); 3.6787 (1.4); 3.6648 (1.3); 3.6517 (0.5); 3.5906 (1.2); 3.5696 (2.6); 3.5659 (2.8); 3.5588 (2.7); 3.5552 (2.6); 3.4491 (0.8); 3.4066 (1.1); 3.3971 (8.6); 3.3943 (9.0); 3.3542 (7.4); 3.3513 (7.7); 2.6056 (1.8); 2.5844 (3.1); 2.5705 (2.4); 2.5631 (3.7); 2.5495 (3.5); 2.5417 (3.2); 2.5280 (3.9); 2.5206 (2.0); 2.5067 (3.5);

2.4855 (1.7); 1.9811 (1.8); 1.9709 (3.2); 1.9607 (1.7); 1.9462 (1.8); 1.9353 (4.0); 1.9244 (4.2); 1.9135 (2.2); 1.8992 (1.7); 1.8889 (3.0); 1.8785 (1.9); 0.0080 (2.9); -0.0002 (85.9); -0.0085 (3.7)

1-177: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6642 (1.8); 7.6577 (2.2); 7.6536 (2.5); 7.6401 (2.8); 7.6335 (2.0); 7.4302 (1.7); 7.4180 (5.6); 7.4002 (2.9); 7.3866 (0.8); 7.3779 (0.7); 7.2602 (61.1); 7.2137 (0.8); 6.2269 (1.0); 6.2001 (1.2); 6.1975 (1.1);

- 125 044070

6.1837 (1.2); 6.1811 (1.2); 6.1569 (1.3); 6.1544 (1.2); 5.9609 (1.0); 5.9566 (1.2); 5.9508 (1.1); 5.8724 (1.0); 5.8670 (0.7); 5.8585 (0.8); 5.8116 (1.1); 5.7978 (0.9); 5.5756 (1.5); 5.5554 (1.5); 5.5342 (1.4); 5.5142 (1.2); 5.3365 (1.4); 5.3211 (1.2); 5.3083 (1.2); 5.2943 (1.1); 5.0335 (0.7); 4.3064 (1.2); 4.3024 (1.2); 4.2954 (2.0); 4.2889 (2.0); 4.2785 (1.9); 4.2666 (1.2); 4.2568 (1.0); 3.9999 (0.5); 3.9894 (1.9); 3.9853 (1.7); 3.9576 (0.6); 3.9464 (2.1); 3.9424 (2.0); 3.6400 (2.6); 3.6268 (2.4); 3.6159 (2.5); 3.6019 (2.5); 3.5915 (1.5); 3.4115 (1.0); 3.4009 (16.0); 3.3951 (2.7); 3.3849 (1.5); 3.3745 (14.4); 3.3697 (4.8); 3.3522 (1.6); 3.3486 (1.8); 2.5665 (0.9); 2.5527 (0.7); 2.5456 (0.6); 2.5315 (0.9); 2.5265 (0.8); 2.5108 (0.5); 2.4914 (0.7); 1.9455 (0.7); 1.9102 (0.9); 1.9036 (1.0); 1.8691 (0.8); 0.9257 (0.6); 0.0080 (2.9); 0.0002 (79.0); -0.0085 (3.6)

1-178: ¹ H-NMR(400.0 MHz, CDC13): δ= 7.8970 (1.6); 7.8929 (2.5); 7.8883 (2.2); 7.8845 (2.0); 7.8804 (2.6); 7.8757 (1.9); 7.8574 (2.0); 7.8538 (2.9); 7.8502 (2.0); 7.8461 (2.3); 7.8425 (2.9); 7.7326 (3.6); 7.3978 (1.3); 7.3774 (1.3); 7.2621 (10.4); 6.0012 (1.8); 5.9371 (0.8); 5.9319 (1.3); 5.9260 (1.0); 5.9180 (1.0); 5.8657 (1.3); 5.8601 (1.0); 5.8521 (1.1); 5.3006 (1.0); 5.0832 (1.2); 5.0651 (1.1); 4.0395 (2.2); 3.9943 (3.0); 3.7775 (2.9); 3.7655 (16.0); 3.7457 (14.6); 3.7326 (2.2); 3.7237 (1.9); 3.5589 (1.3); 2.5517 (0.5); 2.5308 (0.9); 2.5165 (0.6); 2.5100 (0.6); 2.4955 (1.0); 2.4792 (0.6); 2.4747 (0.6); 2.4584 (0.9); 2.4440 (0.6); 2.4377 (0.5); 2.4233 (1.0); 2.0199 (0.6); 2.0127 (1.0); 2.0056 (0.6); 1.9778 (1.4); 1.9707 (1.6); 1.9355 (0.9); 1.9278 (0.6); -0.0002 (13.6)

1-184: Ή^ΜΡ(599.7 MHz, CDC13):

δ= 7.2625 (19.6); 7.2071 (8.8); 7.1841 (6.6); 7.1690 (7.9); 7.1518 (3.5); 7.1364 (2.0); 6.9536 (7.0); 6.9397 (5.2); 6.7989 (2.2); 6.7857 (2.2); 6.1980 (3.7); 6.1802 (4.0); 6.1696 (4.1); 6.1516 (4.1); 5.9779 (5.5); 5.9652 (4.3); 5.9541 (3.1); 5.8913 (3.2); 5.8635 (1.7); 5.8287 (3.9); 5.5618 (3.5); 5.5422 (7.2); 5.5337 (3.4); 5.5137 (6.4); 5.3369 (6.4); 5.3210 (8.1); 5.3053 (3.2); 5.1085 (1.9); 5.0395 (3.8); 4.4120 (2.2); 4.4027 (4.8); 4.3908 (6.7); 4.3798 (7.6); 4.3703 (4.2); 4.3566 (2.3); 4.3461 (5.0); 4.3360 (4.8); 3.9499 (3.4); 3.9426 (6.4); 3.9213 (3.7); 3.9143 (6.9); 3.7804 (1.9); 3.7390 (3.8); 3.7302 (6.6); 3.7200 (7.0); 3.7097 (7.3); 3.7010 (3.9); 3.6886 (2.4); 3.6794 (5.6); 3.6696 (5.3); 3.5685 (3.8); 3.3441 (8.2); 3.3155 (7.4); 2.7015 (0.8); 2.6885 (1.4); 2.6771 (1.4); 2.6654 (1.3); 2.6533 (0.7); 2.5870 (0.9); 2.5727 (1.7); 2.5615 (1.6); 2.5478 (2.2); 2.5324 (2.1); 2.5190 (1.6); 2.5075 (1.8); 2.4929 (0.9); 2.4767 (0.4); 2.3957 (2.0); 2.3718 (50.0); 1.9638 (1.9); 1.9387 (1.8); 1.9205 (2.4); 1.8973 (2.2); 1.8575 (0.9); 1.5871 (39.3); 1.2853 (0.5); 1.2571 (1.9); 0.8949 (0.5); 0.0704 (3.5); -0.0001 (14.0) 1-185: Q-NMR(400.0 MHz, CDC13):

δ= 7.2607 (75.8); 7.2098 (1.3); 7.1682 (0.8); 6.9548 (0.6); 6.2120 (0.5); 6.2093 (0.5); 6.1852 (0.6); 6.1826 (0.6); 6.1689 (0.7); 6.1662 (0.6); 6.1421 (0.7); 6.1395 (0.6); 5.9753 (0.5); 5.9722 (0.5); 5.9574 (0.6); 5.8714 (0.6); 5.8136 (0.7); 5.8081 (0.5); 5.7997 (0.6); 5.5687 (0.7); 5.5670 (0.8); 5.5464 (1.5); 5.5256 (0.7); 5.5239 (0.7); 5.5032 (1.3); 5.3377 (1.1); 5.3233 (0.7); 5.3109 (1.0); 5.2950 (0.6); 4.3061 (0.6); 4.3015 (0.6); 4.2952 (1.0); 4.2887 (1.0); 4.2826 (1.4); 4.2782 (0.7); 4.2694 (1.0); 4.2596 (0.7);

- 126 044070

4.2483 (0.6); 4.2397 (0.8); 4.2352 (0.6); 3.9554 (0.8); 3.9517 (1.0); 3.9476 (0.9); 3.9124 (1.0); 3.9089 (1.1); 3.9047 (1.0); 3.6380 (1.1); 3.6274 (0.9); 3.6249 (1.1); 3.6185 (0.9); 3.6145 (1.1); 3.6053 (1.2);

3.6003 (0.7); 3.5930 (0.8); 3.5884 (1.4); 3.5766 (1.4); 3.5649 (0.8); 3.4004 (8.6); 3.3840 (4.6); 3.3791 (8.0); 3.3728 (4.3); 3.3461 (1.0); 3.3421 (1.0); 3.3032 (1.0); 3.2991 (0.8); 2.3688 (6.5); 1.5479 (16.0);

0.0079 (1.6); -0.0002 (54.5); -0.0085 (1.6)

1-186: MHz, CDC13):

δ= 7.2609 (30.0); 7.2190 (1.6); 7.2107 (1.6); 7.2015 (1.7); 7.1827 (1.6); 7.1674 (1.5); 7.1208 (0.4);

7.1061 (0.8); 7.0900 (0.4); 7.0842 (0.3); 6.9554 (1.4); 6.9420 (1.1); 6.8020 (0.4); 6.7889 (0.4); 6.1964 (1.3); 6.1922 (0.8); 6.1785 (1.4); 6.1744 (0.9); 6.1676 (1.5); 6.1634 (0.9); 6.1498 (1.5); 6.1456 (0.8);

6.0798 (0.4); 6.0598 (0.4); 5.9948 (0.4); 5.9880 (0.8); 5.9811 (0.5); 5.9730 (0.9); 5.9676 (1.5); 5.9616 (1.5); 5.9507 (1.0); 5.9420 (0.8); 5.9355 (0.9); 5.9295 (0.3); 5.9240 (0.4); 5.9095 (0.5); 5.9059 (0.9);

5.9023 (0.8); 5.8966 (1.0); 5.8835 (0.4); 5.8803 (0.6); 5.8763 (0.7); 5.8707 (0.5); 5.8547 (0.5); 5.8510 (1.0); 5.8457 (0.9); 5.8417 (1.2); 5.8379 (0.8); 5.8322 (0.6); 5.5605 (1.4); 5.5420 (2.4); 5.5317 (1.3);

5.5132 (2.2); 5.3411 (1.5); 5.3363 (1.2); 5.3235 (1.7); 5.3185 (1.1); 5.3084 (1.3); 5.1051 (0.4); 5.0362 (0.7); 4.3624 (0.8); 4.3557 (0.8); 4.3399 (2.1); 4.3332 (2.0); 4.3173 (2.1); 4.3105 (2.0); 4.3042 (0.5);

4.2940 (1.2); 4.2872 (1.1); 4.2814 (0.8); 4.2746 (0.8); 4.2708 (0.4); 4.2641 (0.4); 4.2587 (0.4); 4.2519 (0.3); 3.9495 (0.8); 3.9460 (0.9); 3.9408 (1.5); 3.9383 (1.6); 3.9209 (0.9); 3.9174 (1.0); 3.9122 (1.7);

3.9098 (1.8); 3.8067 (0.4); 3.8027 (0.4); 3.5922 (0.7); 3.3475 (1.7); 3.3446 (1.8); 3.3414 (1.6); 3.3189 (1.5); 3.3161 (1.6); 3.3129 (1.4); 2.6821 (0.4); 2.6573 (0.3); 2.6101 (0.3); 2.5960 (0.6); 2.5866 (0.4);

2.5819 (0.4); 2.5726 (0.7); 2.5644 (0.4); 2.5584 (0.4); 2.5502 (0.6); 2.5409 (0.4); 2.5361 (0.4); 2.5268 (0.7); 2.5129 (0.3); 2.3983 (0.5); 2.3709 (13.0); 1.9550 (0.4); 1.9479 (0.7); 1.9409 (0.4); 1.9312 (0.5);

1.9242 (0.8); 1.9170 (0.7); 1.9097 (0.7); 1.9028 (0.4); 1.8936 (0.5); 1.8864 (0.8); 1.8795 (0.5); 1.8713 (0.3); 1.5586 (50.0); 1.2558 (0.3); 0.0694 (4.6); -0.0001 (22.8)

1-187: !H-NMR(599.7 MHz, CDC13):

δ= 7.2611 (23.0); 7.2113 (3.3); 7.1863 (2.2); 7.1724 (2.2); 6.9519 (2.2); 6.9367 (1.8); 6.1988 (1.3);

6.1813 (1.4); 6.1703 (1.5); 6.1524 (1.5); 5.9459 (2.0); 5.8655 (1.1); 5.8081 (1.1); 5.7995 (1.2); 5.5601 (1.5); 5.5412 (2.2); 5.5313 (1.5); 5.5124 (2.0); 5.3339 (2.1); 5.3179 (2.7); 5.3017 (1.4); 5.0286 (1.2);

4.2134 (1.0); 4.2014 (3.1); 4.1892 (4.3); 4.1770 (2.8); 4.1647 (0.8); 4.1491 (0.7); 4.1371 (1.0); 4.1254 (0.7); 3.9417 (2.2); 3.9132 (2.4); 3.4997 (1.3); 3.3395 (2.2); 3.3110 (1.9); 2.5520 (0.4); 2.5382 (0.7);

2.5279 (0.5); 2.5145 (1.1); 2.5002 (1.1); 2.4900 (0.5); 2.4767 (0.8); 2.4626 (0.4); 2.3944 (0.4); 2.3695 (16.4); 1.9268 (0.8); 1.9033 (0.8); 1.8952 (0.6); 1.8860 (0.8); 1.8798 (0.6); 1.8627 (0.8); 1.5620 (50.0); 1.3128 (2.7); 1.3009 (5.0); 1.2910 (4.4); 1.2795 (4.8); 1.2678 (3.1); 1.2565 (2.2); 1.2445 (1.6); 1.2333 (0.6); 0.0701 (3.8); -0.0001 (17.2)

1-188: ¹ H-NMR(400.0 MHz, CDC13):

- 127 044070 δ= 7.4124 (0.8); 7.4090 (1.0); 7.4076 (1.0); 7.4050 (1.1); 7.4026 (0.8); 7.3894 (1.6); 7.3876 (1.8); 7.3849 (1.4); 7.3830 (1.8); 7.3791 (3.7); 7.3767 (2.2); 7.3748 (2.7); 7.3723 (2.2); 7.3706 (1.6); 7.3668 (1.0);

7.3642 (1.5); 7.2627 (19.6); 7.2100 (0.5); 7.1885 (0.5); 7.1476 (0.5); 7.1409 (0.6); 7.1390 (0.5); 7.1332 (0.7); 7.1257 (0.8); 7.1180 (0.8); 5.9743 (0.8); 5.9704 (0.8); 5.9682 (0.8); 5.9643 (0.8); 5.9605 (1.0);

5.9566 (1.1); 5.9544 (1.0); 5.9505 (1.0); 5.8908 (1.0); 5.8853 (1.8); 5.8797 (1.0); 5.8771 (0.8); 5.8714 (1.3); 5.8659 (0.7); 5.0118 (0.5); 5.0077 (0.5); 4.0890 (3.1); 4.0721 (6.3); 4.0552 (3.1); 3.8201 (2.8);

3.7770 (3.2); 3.7233 (0.5); 3.5160 (0.5); 3.5103 (0.5); 3.5069 (0.6); 3.4999 (0.5); 3.4965 (0.5); 3.2291 (3.0); 3.1859 (2.6); 2.5248 (0.7); 2.5037 (1.2); 2.4900 (0.8); 2.4826 (0.7); 2.4689 (1.3); 2.4477 (0.6);

1.8855 (0.7); 1.8751 (1.2); 1.8647 (0.6); 1.8507 (0.6); 1.8402 (1.0); 1.8298 (0.6); 1.7231 (0.9); 1.7095 (16.0); 1.6915 (1.5); 1.6744 (2.7); 1.6560 (2.7); 1.6388 (1.4); 1.5989 (1.9); 0.9466 (4.8); 0.9281 (9.7);

0.9095 (4.3); -0.0002 (11.6)

1-189: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.4098 (1.0); 7.4058 (1.4); 7.3879 (2.2); 7.3863 (2.3); 7.3829 (2.2); 7.3781 (3.5); 7.3756 (2.8); 7.3738 (3.1); 7.3713 (2.9); 7.3664 (1.5); 7.3628 (1.9); 7.2616 (36.1); 7.1953 (0.7); 7.1729 (0.7); 7.1460 (0.6);

7.1395 (0.6); 7.1368 (0.7); 7.1316 (0.8); 7.1246 (1.0); 7.1169 (1.0); 7.1095 (0.7); 7.1046 (0.5); 7.1018 (0.6); 5.9563 (0.8); 5.9524 (0.9); 5.9502 (1.0); 5.9463 (0.9); 5.9425 (1.1); 5.9386 (1.2); 5.9363 (1.3);

5.9325 (1.2); 5.8825 (1.0); 5.8770 (1.8); 5.8714 (1.1); 5.8688 (0.9); 5.8632 (1.4); 5.8576 (0.8); 5.0533 (0.6); 5.0376 (1.5); 5.0219 (2.2); 5.0062 (2.0); 4.9905 (0.9); 3.8255 (2.8); 3.7824 (3.2); 3.7235 (0.7);

3.4695 (0.6); 3.4640 (0.6); 3.4607 (0.6); 3.4534 (0.7); 3.4477 (0.6); 3.4443 (0.6); 3.2296 (3.0); 3.1865 (2.7); 2.5087 (0.7); 2.4875 (1.3); 2.4739 (0.8); 2.4664 (0.8); 2.4527 (1.4); 2.4316 (0.7); 1.8648 (0.7);

1.8545 (1.2); 1.8442 (0.7); 1.8299 (0.7); 1.8196 (1.1); 1.8092 (0.7); 1.7251 (0.7); 1.7175 (1.2); 1.7098 (16.0); 1.5727 (2.9); 1.2835 (0.7); 1.2716 (0.6); 1.2673 (0.7); 1.2546 (8.3); 1.2488 (8.7); 1.2390 (8.7);

1.2331 (8.8); 1.2215 (1.4); 1.2059 (1.0); 0.0080 (0.6); -0.0002 (21.6); -0.0085 (1.3)

1-190: !H-NMR(400.0 MHz, CDC13):

δ= 7.3853 (0.7); 7.3754 (1.4); 7.3727 (1.1); 7.3708 (1.1); 7.3622 (0.6); 7.2636 (6.2); 7.2623 (6.3); 7.1161 (0.6); 5.8494 (0.6); 3.8223 (0.8); 3.7792 (0.9); 3.2292 (0.9); 3.1861 (0.8); 1.7080 (4.9); 1.4796 (0.8); 1.4400 (16.0); 1.4247 (1.0); 0.0009 (3.6); -0.0002 (3.7)

1-191: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.4073 (1.2); 7.4031 (1.2); 7.3914 (1.6); 7.3815 (4.5); 7.3761 (4.3); 7.3675 (2.2); 7.2628 (15.5); 7.1836 (0.7); 7.1622 (0.9); 7.1511 (0.7); 7.1433 (0.9); 7.1362 (0.9); 7.1286 (1.1); 7.1216 (1.1); 7.1153 (0.6); 5.9898 (0.8); 5.9852 (1.1); 5.9762 (1.2); 5.9715 (1.5); 5.9669 (1.2); 5.9195 (1.0); 5.9142 (1.8); 5.9077 (1.2); 5.9005 (1.3); 5.8949 (0.8); 5.0253 (0.8); 4.3819 (2.7); 4.3684 (3.8); 4.3665 (3.4); 4.3536 (3.0); 3.8262 (2.6); 3.7831 (3.0); 3.7222 (0.9); 3.7165 (3.1); 3.7018 (4.2); 3.6880 (2.8); 3.5663 (0.7); 3.5559 (0.7); 3.5508 (0.7); 3.5450 (0.7); 3.2313 (3.0); 3.1881 (2.6); 2.5485 (0.6); 2.5273 (1.2); 2.5136

- 128 044070 (0.8); 2.5062 (0.7); 2.4922 (1.4); 2.4711 (0.7); 1.9147 (0.7); 1.9047 (1.3); 1.8949 (0.7); 1.8797 (0.7); 1.8698 (1.3); 1.8598 (0.7); 1.7266 (0.7); 1.7128 (16.0); 1.5899 (3.7); -0.0002 (9.1); -0.0082 (0.6) 1-192: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.4078 (1.2); 7.3882 (2.2); 7.3793 (3.1); 7.3752 (3.1); 7.3733 (3.0); 7.3648 (1.7); 7.2637 (13.7); 7.2138 (0.6); 7.1924 (0.7); 7.1391 (0.6); 7.1329 (0.7); 7.1248 (0.9); 7.1182 (0.9); 7.1106 (0.6); 5.9776 (1.0); 5.9639 (1.3); 5.8979 (0.8); 5.8925 (1.5); 5.8855 (1.1); 5.8788 (1.2); 5.8733 (0.7); 5.0136 (0.7); 4.4460 (1.3); 4.4343 (1.5); 4.4225 (1.4); 4.2828 (1.2); 4.2730 (2.3); 4.2595 (2.4); 4.2503 (1.2); 3.8241 (2.2); 3.7810 (2.5); 3.6955 (1.4); 3.6835 (1.5); 3.6719 (1.4); 3.6091 (1.7); 3.5975 (3.1); 3.5881 (1.7); 3.5673 (0.8); 3.5573 (0.8); 3.5520 (0.7); 3.5488 (0.7); 3.3992 (8.4); 3.3860 (1.2); 3.3744 (16.0); 3.2277 (2.5); 3.1846 (2.2); 2.5309 (0.6); 2.5098 (1.0); 2.4960 (0.7); 2.4888 (0.6); 2.4750 (1.2); 2.4539 (0.6); 1.8934 (0.6); 1.8830 (1.1); 1.8727 (0.7); 1.8585 (0.6); 1.8481 (1.0); 1.8377 (0.6); 1.7535 (0.5); 1.7245 (0.6); 1.7093 (13.2); 1.6141 (1.8); -0.0002 (8.2); -0.0078 (0.5)

1-193: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.4717 (0.6); 7.4066 (1.7); 7.3887 (3.7); 7.3803 (5.1); 7.3747 (4.4); 7.3641 (2.7); 7.3543 (4.1); 7.3438 (16.0); 7.3361 (3.2); 7.3305 (1.8); 7.3142 (0.9); 7.2611 (17.4); 7.2257 (0.9); 7.2045 (0.8); 7.1492 (0.6); 7.1428 (0.7); 7.1379 (0.8); 7.1283 (1.1); 7.1212 (1.1); 7.1133 (0.8); 7.1059 (0.6); 5.9775 (1.0); 5.9732 (1.2); 5.9672 (1.1); 5.9636 (1.3); 5.9596 (1.6); 5.9541 (1.1); 5.8963 (1.2); 5.8910 (1.9); 5.8851 (1.3); 5.8773 (1.4); 5.8718 (0.8); 5.1843 (0.8); 5.1544 (6.4); 5.1503 (5.7); 5.0133 (0.8); 3.8252 (2.7); 3.7821 (3.1); 3.7231 (0.6); 3.5509 (0.8); 3.5451 (0.8); 3.5353 (0.7); 3.2323 (3.1); 3.1892 (2.7); 2.5372 (0.6); 2.5161 (1.2); 2.5023 (0.9); 2.4953 (0.7); 2.4814 (1.4); 2.4604 (0.7); 1.9116 (0.8); 1.9010 (1.4); 1.8901 (0.8); 1.8768 (0.8); 1.8662 (1.3); 1.8553 (0.7); 1.7278 (0.5); 1.7097 (16.0); 0.0004 (10.4); -0.0002 (10.4) 1-194: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.4087 (1.2); 7.4045 (1.2); 7.3925 (1.5); 7.3817 (4.2); 7.3783 (4.2); 7.3681 (2.4); 7.3488 (2.1); 7.3355 (2.3); 7.3278 (2.4); 7.3193 (1.1); 7.3143 (2.2); 7.2615 (17.9); 7.2064 (0.7); 7.1852 (0.7); 7.1543 (0.6); 7.1471 (0.8); 7.1399 (0.7); 7.1320 (1.0); 7.1249 (1.0); 7.1200 (0.6); 7.1150 (0.7); 7.1106 (0.5); 7.0564 (0.6); 7.0498 (2.5); 7.0449 (1.3); 7.0332 (1.2); 7.0282 (4.4); 7.0234 (1.2); 7.0116 (0.8); 7.0067 (2.0); 5.9553 (0.8); 5.9508 (1.0); 5.9456 (0.9); 5.9417 (1.2); 5.9369 (1.5); 5.9321 (1.2); 5.8953 (1.1); 5.8901 (2.0); 5.8843 (1.2); 5.8764 (1.3); 5.8710 (0.8); 5.1450 (0.6); 5.1155 (4.5); 5.1099 (4.6); 5.0098 (0.8); 5.0058 (0.8); 3.8247 (2.8); 3.7815 (3.2); 3.7230 (0.6); 3.5416 (0.7); 3.5365 (0.7); 3.5314 (0.8); 3.5255 (0.8); 3.5204 (0.7); 3.5152 (0.7); 3.2323 (3.1); 3.1892 (2.7); 2.5274 (0.6); 2.5063 (1.3); 2.4925 (0.8); 2.4853 (0.7); 2.4714 (1.4); 2.4504 (0.7); 1.8919 (0.7); 1.8815 (1.3); 1.8710 (0.8); 1.8571 (0.6); 1.8467 (1.2); 1.8361 (0.7); 1.7081 (16.0); 1.5867 (4.5); -0.0002 (10.8); -0.0084 (0.6)

1-199: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.8665 (1.2); 7.8618 (1.8); 7.8577 (1.5); 7.8212 (1.3); 7.8176 (2.4); 7.8139 (1.3); 7.6726 (1.2); 7.6690 (1.4); 7.6678 (1.6); 7.6642 (1.2); 7.2633 (5.4); 5.9888 (0.5); 5.9815 (0.6); 5.9778 (0.6); 5.9751 (0.6);

5.9715 (0.6); 5.9043 (0.6); 5.8988 (1.1); 5.8932 (0.6); 5.8907 (0.5); 5.8850 (0.8); 4.2883 (0.8); 4.2781

- 129 044070 (1.1); 4.2755 (1.8); 4.2647 (1.7); 4.2623 (1.3); 4.2524 (0.9); 3.8289 (1.7); 3.7857 (1.9); 3.6211 (1.1);

3.6181 (1.1); 3.6103 (1.2); 3.6071 (1.8); 3.5977 (1.0); 3.5946 (1.1); 3.3848 (16.0); 3.2053 (1.8); 3.1621 (1.5); 2.4765 (0.7); 2.4415 (0.8); 1.8899 (0.7); 1.8549 (0.6); 1.7254 (9.3); -0.0002 (7.2)

1-200: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.8527 (1.2); 7.8483 (2.1); 7.8440 (1.7); 7.8062 (1.5); 7.8026 (2.7); 7.7991 (1.6); 7.6704 (1.4); 7.6657 (1.9); 7.6621 (1.5); 7.2631 (6.9); 7.1684 (0.5); 7.1470 (0.5); 5.9721 (0.6); 5.9686 (0.6); 5.9660 (0.6);

5.9621 (0.6); 5.9585 (0.7); 5.9547 (0.7); 5.9520 (0.8); 5.9484 (0.7); 5.8128 (0.6); 5.8073 (1.1); 5.8016 (0.7); 5.7935 (1.0); 5.7879 (0.6); 4.3185 (1.0); 4.3070 (1.8); 4.2971 (1.8); 4.2952 (1.7); 4.2862 (1.0);

3.8393 (1.9); 3.7961 (2.2); 3.6449 (1.9); 3.6345 (2.2); 3.6321 (2.3); 3.6212 (1.7); 3.5939 (0.7); 3.5760 (0.6); 3.4052 (16.0); 3.3850 (2.0); 3.3716 (0.6); 3.1929 (1.9); 3.1497 (1.7); 2.5434 (0.8); 2.5294 (0.5);

2.5084 (0.9); 1.9773 (0.8); 1.9423 (0.7); 1.7412 (10.2); 1.7326 (1.1); 1.7255 (1.2); -0.0002 (9.0)

1-201: Ή-ΠΜΡ(400.0 MHz, CDC13):

δ= 7.8436 (1.2); 7.8391 (2.0); 7.8349 (1.7); 7.8053 (1.4); 7.8017 (2.6); 7.7980 (1.6); 7.6824 (1.3); 7.6778 (1.9); 7.6741 (1.5); 7.2615 (10.3); 6.7283 (0.5); 6.7075 (0.5); 6.0027 (0.6); 5.9968 (0.8); 5.9925 (0.7);

5.9889 (0.8); 5.9829 (0.9); 5.9787 (0.7); 5.7944 (0.6); 5.7887 (1.1); 5.7829 (0.8); 5.7748 (1.1); 5.7691 (0.6); 5.0857 (0.5); 4.2658 (0.9); 4.2547 (2.0); 4.2453 (1.8); 4.2423 (1.4); 4.2344 (1.0); 3.8391 (1.7);

3.8093 (0.5); 3.8028 (0.6); 3.7958 (2.3); 3.7873 (0.8); 3.7809 (0.6); 3.6045 (2.0); 3.5926 (3.1); 3.5811 (1.9); 3.3865 (16.0); 3.2099 (1.8); 3.1665 (1.6); 2.7126 (0.5); 2.6979 (0.7); 2.6855 (0.5); 2.6773 (0.6); 1.9042 (0.6); 1.7319 (9.5); -0.0002 (13.6)

Analytical data of examples P-01-P-63 (see Table 1.2)

P-01: ¹ H-NMR(400.6 MHz, CDC13):

δ= 9.2153 (1.0); 7.5272 (0.5); 7.3891 (2.1); 7.3818 (3.5); 7.3737 (6.2); 7.3675 (6.8); 7.3588 (3.0); 7.2686 (6.2); 7.1388 (0.8); 7.1303 (0.9); 7.1258 (1.0); 7.1177 (1.4); 7.1101 (1.4); 7.1028 (0.9); 7.0955 (0.9);

7.0883 (0.5); 5.8967 (1.0); 5.8353 (2.7); 4.9530 (0.6); 3.8217 (1.9); 3.8154 (3.0); 3.7890 (16.0); 3.7787 (2.6); 3.7723 (4.4); 3.7664 (15.8); 3.7452 (0.9); 3.2931 (0.6); 3.2196 (2.9); 3.2150 (2.3); 3.1766 (2.5);

3.1719 (2.0); 2.5155 (0.6); 2.0467 (1.3); 1.8834 (1.2); 1.7148 (12.8); 1.7021 (12.4); 1.3339 (0.5); 1.2834 (0.8); 1.2779 (0.6); 1.2599 (1.6); 1.2560 (1.8); -0.0002 (3.1)

P-02: ¹ H-NMR(400.6 MHz, CDC13):

δ= 7.3902 (1.4); 7.3831 (2.2); 7.3736 (4.4); 7.3678 (4.7); 7.3616 (2.1); 7.3583 (1.7); 7.2652 (8.1); 7.1401 (0.5); 7.1326 (0.6); 7.1272 (0.7); 7.1190 (1.0); 7.1114 (1.0); 7.1042 (0.6); 7.0975 (0.5); 5.8988 (0.7);

5.8383 (2.0); 3.8172 (1.5); 3.8120 (2.6); 3.7898 (10.1); 3.7741 (2.2); 3.7669 (16.0); 3.2179 (2.3); 3.2134 (1.5); 3.1749 (2.0); 3.1703 (1.3); 2.0463 (0.5); 1.7147 (9.9); 1.7024 (9.8); 1.2596 (0.8); 1.2556 (0.9); 0.0002 (3.6)

P-03: ¹ H-NMR(400.6 MHz, CDC13):

- 130 044070 δ= 9.0380 (1.4); 7.5374 (0.6); 7.5278 (0.6); 7.5157 (0.6); 7.3907 (2.5); 7.3812 (4.5); 7.3736 (7.0); 7.3679 (8.8); 7.2691 (10.0); 7.1375 (0.9); 7.1255 (1.3); 7.1164 (1.7); 7.1094 (1.7); 7.1021 (1.1); 7.0943 (1.1); 7.0872 (0.6); 5.8928 (1.2); 5.8296 (3.3); 4.9593 (0.7); 4.9417 (0.6); 4.1307 (0.7); 4.1128 (0.7); 3.9991 (1.5); 3.9744 (2.8); 3.9566 (2.4); 3.9393 (1.0); 3.8209 (2.0); 3.8129 (3.3); 3.7779 (2.2); 3.7699 (3.7);

3.2943 (0.8); 3.2170 (3.3); 3.2113 (2.8); 3.1740 (2.9); 3.1683 (2.4); 2.5140 (0.7); 2.4921 (0.6); 2.0463 (2.9); 1.8946 (2.1); 1.8590 (0.6); 1.7127 (16.0); 1.6988 (15.2); 1.2954 (2.4); 1.2777 (5.4); 1.2598 (6.5);

1.2421 (2.5); 1.2273 (0.6); -0.0002 (3.9)

P-04: ¹ H-NMR(400.6 MHz, CDC13):

δ= 7.5587 (0.5); 7.5376 (0.6); 7.5262 (0.6); 7.4269 (0.7); 7.4113 (0.5); 7.4082 (0.6); 7.3787 (4.0); 7.3685 (7.2); 7.3659 (6.9); 7.3631 (7.0); 7.3551 (4.3); 7.2677 (9.1); 7.1368 (0.9); 7.1303 (1.1); 7.1232 (1.2);

7.1157 (1.7); 7.1081 (1.6); 7.1003 (1.1); 7.0945 (0.9); 7.0871 (0.6); 5.8875 (1.0); 5.8263 (3.1); 4.9533 (0.6); 4.0135 (0.5); 3.9963 (1.5); 3.9872 (1.6); 3.9789 (1.9); 3.9703 (3.0); 3.9527 (2.8); 3.9350 (1.2);

3.8126 (1.8); 3.8054 (3.5); 3.7695 (2.1); 3.7624 (3.9); 3.3038 (0.8); 3.2142 (3.4); 3.2089 (2.8); 3.1711 (3.0); 3.1658 (2.4); 2.5129 (0.7); 2.4911 (0.5); 2.4813 (0.5); 2.0463 (1.0); 1.8733 (0.8); 1.7085 (15.6);

1.6961 (16.0); 1.2835 (2.5); 1.2694 (3.8); 1.2595 (4.2); 1.2567 (4.1); 1.2421 (2.6); 1.2324 (1.4); -0.0002 (4.0)

P-05: ¹ H-NMR(400.6 MHz, CDC13):

δ= 8.7642 (0.9); 8.7457 (0.9); 7.4812 (0.5); 7.3905 (2.2); 7.3811 (4.0); 7.3691 (8.2); 7.2679 (10.5); 7.1361 (0.8); 7.1264 (1.1); 7.1159 (1.5); 7.1094 (1.5); 7.0943 (0.9); 5.8883 (1.1); 5.8298 (3.1); 4.9617 (0.6); 4.9415 (0.5); 4.1684 (0.6); 4.1532 (0.6); 4.1485 (0.7); 4.1397 (0.5); 4.1306 (0.8); 4.1127 (0.7);

3.8195 (1.7); 3.8102 (2.6); 3.7766 (1.9); 3.7672 (3.0); 3.3009 (0.8); 3.2150 (2.8); 3.2079 (2.7); 3.1720 (2.5); 3.1649 (2.3); 2.5233 (0.6); 2.0459 (2.4); 1.9249 (0.5); 1.8892 (0.9); 1.8804 (0.9); 1.8486 (2.2);

1.7115 (15.3); 1.6969 (16.0); 1.2773 (4.5); 1.2654 (7.5); 1.2596 (8.4); 1.2505 (8.2); 1.2422 (6.6); 1.2299 (5.1); 1.2140(1.5); -0.0002 (4.7)

P-06: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.6251 (0.6); 7.6056 (0.6); 7.5477 (0.6); 7.5185 (3.2); 7.2924 (1.2); 7.2596 (533.2); 7.2500 (0.8);

7.2492 (0.8); 7.2476 (0.6); 7.2095 (1.1); 7.1982 (0.7); 7.1914 (2.1); 7.1856 (2.5); 7.1747 (2.4); 7.1712 (4.4); 7.1685 (3.7); 7.1655 (4.9); 7.1513 (3.0); 7.1490 (2.6); 7.1455 (2.4); 6.9956 (3.0); 6.9010 (0.5);

6.8830 (0.9); 6.8795 (1.6); 6.8736 (1.7); 6.8673 (0.9); 6.8577 (1.9); 6.8517 (2.6); 6.8461 (1.3); 6.8358 (0.8); 6.8299 (1.2); 5.9612 (0.7); 5.9570 (0.8); 5.9431 (0.6); 5.8986 (1.9); 5.8915 (1.8); 5.8867 (2.3);

5.8816 (1.8); 5.8741 (1.1); 5.8539 (0.8); 5.8401 (0.5); 5.7964 (0.8); 5.7910 (1.6); 5.7854 (1.5); 5.7772 (1.3); 5.7715 (1.0); 5.0162 (0.8); 4.9907 (0.8); 4.0808 (0.8); 4.0636 (1.2); 4.0466 (1.2); 4.0309 (1.8);

4.0237 (2.0); 4.0138 (2.7); 4.0096 (2.8); 4.0070 (3.3); 3.9972 (2.5); 3.9897 (2.0); 3.9799 (2.3); 3.9607 (1.8); 3.9479 (1.4); 3.9427 (1.6); 3.9298 (1.3); 3.8893 (1.9); 3.8203 (0.7); 3.8151 (1.3); 3.8016 (2.2);

3.7971 (3.4); 3.7929 (4.3); 3.7824 (2.0); 3.7717 (2.3); 3.7624 (2.0); 3.7542 (5.0); 3.7500 (3.9); 3.7451

- 131 044070 (1.5); 3.7365 (2.8); 3.7178 (1.7); 3.7096 (1.0); 3.6990 (0.8); 3.6912 (1.2); 3.6722 (0.8); 3.1958 (1.8);

3.1708 (3.0); 3.1581 (3.0); 3.1525 (1.7); 3.1278 (2.6); 3.1151 (2.5); 3.1022 (0.5); 2.6837 (0.7); 2.6480 (0.6); 2.4560 (0.6); 2.4350 (1.1); 2.4214 (0.9); 2.4143 (0.8); 2.4008 (2.1); 2.3803 (2.4); 2.3667 (3.3);

2.3596 (1.3); 2.3488 (4.8); 2.3316 (5.0); 2.3141 (3.4); 2.2965 (1.3); 2.0152 (0.7); 2.0072 (1.1); 1.9801 (0.6); 1.9726 (0.9); 1.9315 (0.7); 1.9235 (1.2); 1.9160 (0.7); 1.8971 (0.8); 1.8893 (1.2); 1.7856 (0.5); 1.7395 (3.6); 1.7264 (16.0); 1.7220 (7.6); 1.7159 (6.8); 1.7061 (1.9); 1.6961 (16.0); 1.5593 (11.7);

1.2559 (0.8); 0.3307 (0.6); 0.1573 (0.9); 0.1460 (0.7); 0.0080 (8.3); -0.0002 (234.3); -0.0085 (6.3); 0.1496 (0.7)

P-07: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5191 (1.2); 7.3110 (0.6); 7.2601 (216.8); 7.1915 (1.4); 7.1858 (1.8); 7.1827 (1.3); 7.1742 (1.9);

7.1709 (3.5); 7.1681 (3.6); 7.1652 (4.0); 7.1621 (2.5); 7.1539 (2.3); 7.1507 (2.8); 7.1483 (2.9); 7.1450 (2.2); 7.1424 (1.4); 6.9962 (1.2); 6.9016 (0.6); 6.8893 (0.5); 6.8837 (1.0); 6.8794 (1.4); 6.8731 (1.4);

6.8672 (0.8); 6.8620 (0.6); 6.8570 (1.6); 6.8511 (2.3); 6.8453 (1.1); 6.8351 (0.7); 6.8292 (1.1); 6.8236 (0.5); 5.9496 (0.5); 5.9413 (0.7); 5.9374 (1.1); 5.9317 (0.7); 5.9293 (0.6); 5.9252 (0.6); 5.9196 (0.6);

5.8910 (1.1); 5.8868 (1.8); 5.8831 (1.7); 5.8790 (1.9); 5.8737 (1.4); 5.8701 (0.9); 5.8663 (1.0); 5.8497 (0.8); 5.8358 (0.6); 5.7910 (0.8); 5.7857 (1.5); 5.7806 (1.4); 5.7722 (1.2); 5.7668 (1.1); 5.2986 (2.4);

5.0936 (0.5); 5.0884 (0.5); 5.0828 (0.5); 5.0175 (0.6); 4.9878 (0.6); 4.0818 (0.9); 4.0693 (1.2); 4.0556 (1.1); 4.0237 (1.4); 4.0131 (1.8); 4.0017 (1.6); 3.9949 (1.8); 3.9851 (1.9); 3.9771 (1.6); 3.9672 (2.2);

3.9573 (1.8); 3.9507 (1.8); 3.9398 (1.7); 3.9310 (1.1); 3.9061 (0.7); 3.8933 (0.6); 3.8801 (0.6); 3.8608 (0.5); 3.8475 (0.6); 3.8197 (1.6); 3.8014 (1.8); 3.7932 (2.9); 3.7906 (2.8); 3.7764 (1.6); 3.7581 (1.7);

3.7502 (3.0); 3.7476 (3.1); 3.6943 (1.1); 3.6792 (0.9); 3.6627 (0.9); 3.1983 (1.6); 3.1949 (1.7); 3.1714 (2.2); 3.1590 (2.6); 3.1549 (1.6); 3.1516 (1.6); 3.1284 (1.9); 3.1160 (2.1); 2.6736 (0.8); 2.6597 (0.5);

2.6372 (0.7); 2.4331 (0.9); 2.4195 (0.7); 2.4125 (0.6); 2.3990 (1.1); 2.3782 (0.6); 2.3741 (0.9); 2.3604 (0.5); 2.3399 (1.0); 2.0434 (0.5); 1.9976 (0.5); 1.9898 (0.9); 1.9822 (0.5); 1.9556 (0.8); 1.9205 (0.5);

1.9125 (0.9); 1.9052 (0.6); 1.8955 (0.6); 1.8861 (1.1); 1.8781 (1.4); 1.8705 (1.3); 1.8650 (1.4); 1.8572 (1.7); 1.8475 (2.1); 1.8372 (2.3); 1.8299 (2.2); 1.8243 (2.2); 1.8067 (1.8); 1.7968 (1.5); 1.7852 (1.3);

1.7757 (1.6); 1.7721 (1.4); 1.7629 (2.2); 1.7499 (3.2); 1.7353 (3.4); 1.7254 (16.0); 1.7227 (11.9); 1.7163 (8.8); 1.7094 (3.0); 1.7065 (2.6); 1.6958 (12.0); 1.5578 (7.5); 1.2586 (0.9); 0.0080 (3.2); -0.0002 (90.6); -0.0085 (2.6)

P-08: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5187 (1.1); 7.3381 (0.5); 7.2598 (194.2); 7.1811 (0.5); 7.1750 (1.2); 7.1689 (2.7); 7.1658 (2.5);

7.1631 (2.7); 7.1599 (2.3); 7.1548 (1.7); 7.1521 (1.9); 7.1490 (3.3); 7.1464 (2.3); 7.1432 (2.4); 6.9958 (1.1); 6.8938 (0.9); 6.8881 (1.7); 6.8842 (0.9); 6.8823 (0.9); 6.8722 (1.1); 6.8664 (2.0); 6.8606 (1.0);

6.8447 (0.8); 6.7572 (0.5); 5.9645 (0.5); 5.9556 (0.6); 5.9506 (1.2); 5.9457 (0.8); 5.9356 (0.8); 5.9320 (1.0); 5.9272 (1.0); 5.9227 (0.7); 5.9194 (0.8); 5.9139 (1.3); 5.9095 (1.2); 5.9051 (0.8); 5.8994 (0.7);

5.8950 (1.1); 5.8900 (0.6); 5.8854 (0.6); 5.8811 (0.9); 5.8759 (0.8); 5.8576 (3.9); 5.3512 (0.5); 5.2986

- 132 044070 (0.6); 5.0812 (0.5); 4.9382 (0.5); 4.9285 (0.5); 3.7992 (1.5); 3.7951 (1.3); 3.7741 (1.8); 3.7725 (1.6);

3.7559 (1.7); 3.7518 (1.5); 3.7310 (2.1); 3.7294 (1.9); 3.3064 (0.5); 3.2953 (0.7); 3.2849 (0.7); 3.2020 (1.4); 3.1995 (1.7); 3.1844 (1.4); 3.1753 (1.7); 3.1586 (1.3); 3.1561 (1.5); 3.1413 (1.2); 3.1322 (1.4);

2.5469 (0.6); 2.5420 (0.8); 2.5377 (0.5); 2.5283 (0.8); 2.5258 (0.6); 2.5234 (0.6); 2.5208 (0.5); 2.5115 (0.5); 2.5071 (1.3); 2.5029 (0.5); 2.4857 (0.7); 2.4720 (0.6); 2.0435 (1.4); 1.8929 (0.7); 1.8840 (0.6);

1.8584 (0.7); 1.8489 (0.6); 1.8238 (0.6); 1.7153 (16.0); 1.7133 (12.4); 1.7017 (7.7); 1.6109 (8.0); 1.5941 (3.7); 1.5785 (6.8); 1.5765 (7.2); 1.5638 (7.6); 1.5429 (13.9); 1.3214 (0.6); 1.3042 (1.3); 1.2649 (6.3); 1.2588 (4.5); 1.2408 (1.0); 0.8988 (3.4); 0.8819 (12.4); 0.8642 (4.6); 0.0080 (2.2); -0.0002 (74.7); 0.0085 (2.2)

P-09: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5189 (1.3); 7.3494 (0.5); 7.3094 (0.6); 7.2778 (0.5); 7.2770 (0.5); 7.2762 (0.6); 7.2754 (0.6); 7.2746 (0.6); 7.2738 (0.7); 7.2730 (0.8); 7.2722 (0.9); 7.2714 (1.0); 7.2706 (1.0); 7.2698 (1.1); 7.2690 (1.3);

7.2682 (1.5); 7.2674 (1.7); 7.2666 (1.9); 7.2658 (2.3); 7.2650 (2.9); 7.2641 (3.7); 7.2600 (230.6); 7.1705 (1.2); 7.1676 (2.2); 7.1649 (2.4); 7.1618 (2.7); 7.1554 (1.1); 7.1507 (2.3); 7.1478 (2.7); 7.1452 (2.4);

7.1420 (1.9); 6.9960 (1.3); 6.8924 (0.6); 6.8888 (0.9); 6.8867 (1.0); 6.8831 (1.4); 6.8773 (0.7); 6.8673 (1.0); 6.8649 (0.6); 6.8615 (1.6); 6.8557 (0.7); 6.8398 (0.6); 6.7549 (0.6); 6.7341 (0.6); 6.0524 (0.6); 6.0378 (0.6); 5.9563 (1.0); 5.9502 (2.5); 5.9472 (1.8); 5.9425 (1.1); 5.9378 (0.9); 5.9322 (0.8); 5.9294 (0.6); 5.9248 (0.8); 5.9206 (0.6); 5.9151 (0.5); 5.9120 (0.6); 5.8872 (0.8); 5.8818 (1.4); 5.8763 (0.6);

5.8677 (0.8); 5.8617 (0.9); 5.2987 (3.7); 5.0879 (0.5); 4.1306 (1.0); 4.1127 (1.0); 3.7989 (1.8); 3.7977 (1.8); 3.7872 (1.2); 3.7770 (1.2); 3.7701 (0.6); 3.7612 (10.6); 3.7556 (2.3); 3.7543 (2.5); 3.7430 (12.2); 3.7414 (15.3); 3.7339 (1.7); 3.7293 (14.2); 3.5647 (0.5); 3.1991 (2.4); 3.1745 (1.1); 3.1655 (1.2); 3.1557 (2.1); 3.1314 (1.0); 3.1224 (1.0); 2.5602 (0.7); 2.5440 (0.5); 2.5396 (0.8); 2.5276 (0.7); 2.5256 (0.6);

2.5093 (0.6); 2.5059 (0.6); 2.4928 (0.7); 2.0436 (4.9); 1.8668 (0.7); 1.8560 (0.7); 1.7159 (16.0); 1.7082 (6.7); 1.6978 (6.3); 1.5877 (5.4); 1.5807 (5.4); 1.5651 (5.4); 1.5506 (12.3); 1.5439 (11.0); 1.5376 (7.9); 1.5298 (7.1); 1.2766 (1.6); 1.2587 (3.3); 1.2408 (1.5); 0.0079 (2.6); 0.0062 (0.8); 0.0054 (1.0); 0.0045 (1.2); -0.0002 (89.6); -0.0028 (4.1); -0.0044 (1.6); -0.0052 (1.2); -0.0061 (0.9); -0.0069 (0.8); -0.0085 (2.5)

P-10: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5189 (1.3); 7.3016 (0.5); 7.2985 (0.5); 7.2953 (0.6); 7.2931 (0.8); 7.2897 (0.5); 7.2889 (0.6); 7.2865 (0.6); 7.2850 (0.6); 7.2818 (0.6); 7.2802 (0.6); 7.2778 (0.8); 7.2770 (0.8); 7.2762 (0.9); 7.2730 (1.1);

7.2714 (1.3); 7.2706 (1.4); 7.2682 (1.8); 7.2600 (227.8); 7.2098 (0.6); 7.1808 (1.1); 7.1781 (1.4); 7.1751 (1.6); 7.1723 (1.7); 7.1692 (1.6); 7.1664 (1.7); 7.1634 (2.2); 7.1609 (2.6); 7.1584 (2.2); 7.1554 (1.7);

7.1526 (1.7); 7.1496 (1.5); 7.1466 (1.5); 7.1437 (1.3); 7.1410 (0.9); 6.9960 (1.3); 6.9084 (0.7); 6.9025 (0.7); 6.8967 (0.7); 6.8910 (0.9); 6.8867 (1.3); 6.8808 (1.3); 6.8750 (0.7); 6.8650 (0.6); 6.8591 (0.6);

5.9811 (0.5); 5.9725 (0.5); 5.9672 (1.0); 5.9621 (0.6); 5.9431 (0.6); 5.9390 (0.7); 5.9338 (0.6); 5.9203 (0.8); 5.9159 (1.0); 5.9137 (1.4); 5.9104 (1.2); 5.9059 (0.6); 5.8988 (0.5); 5.8936 (0.8); 5.8849 (0.8);

- 133 044070

5.8799 (1.4); 5.8752 (1.0); 5.8611 (0.6); 5.8560 (1.2); 5.8498 (1.2); 5.8443 (0.6); 5.8423 (0.6); 5.8359 (0.6); 5.2987 (6.1); 4.1305 (1.2); 4.1126 (1.2); 3.7990 (1.3); 3.7949 (1.2); 3.7601 (1.4); 3.7556 (1.6); 3.7513 (2.6); 3.7170 (1.5); 3.7078 (1.6); 3.3871 (0.5); 3.2042 (1.6); 3.1943 (1.6); 3.1919 (1.6); 3.1608 (1.4); 3.1511 (1.4); 3.1487 (1.4); 2.6429 (0.6); 2.6313 (0.8); 2.6184 (0.6); 2.6073 (0.8); 2.5962 (0.7); 2.5823 (0.6); 2.5732 (0.6); 2.0437 (5.8); 1.9633 (0.6); 1.9326 (0.6); 1.9280 (0.6); 1.9210 (0.6); 1.9097 (0.6); 1.8981 (0.6); 1.8859 (0.6); 1.7512 (0.6); 1.7315 (7.4); 1.7241 (7.7); 1.7168 (15.8); 1.7142 (16.0); 1.7069 (2.8); 1.7031 (8.8); 1.6986 (14.3); 1.6858 (9.6); 1.5428 (17.1); 1.2766 (1.8); 1.2587 (4.0); 1.2409 (1.8); 0.0079 (2.4); 0.0062 (0.8); 0.0053 (0.9); 0.0045 (1.0); -0.0002 (89.7); -0.0052 (1.4); -0.0061 (1.1); -0.0069 (1.0); -0.0085 (2.7)

P-11: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5197 (1.4); 7.4953 (0.7); 7.2810 (0.6); 7.2802 (0.6); 7.2794 (0.6); 7.2786 (0.6); 7.2778 (0.6); 7.2770 (0.7); 7.2762 (0.8); 7.2754 (0.8); 7.2746 (0.9); 7.2738 (0.9); 7.2730 (1.0); 7.2722 (1.2); 7.2714 (1.2);

7.2706 (1.3); 7.2698 (1.6); 7.2690 (1.8); 7.2682 (2.0); 7.2674 (2.2); 7.2666 (2.6); 7.2658 (3.3); 7.2649 (4.2); 7.2608 (208.3); 7.2561 (2.6); 7.2553 (1.8); 7.2544 (1.4); 7.2536 (1.0); 7.2529 (0.7); 7.1803 (1.4); 7.1777 (1.7); 7.1740 (2.8); 7.1666 (3.2); 7.1636 (3.2); 7.1605 (3.5); 7.1576 (3.2); 7.1541 (3.3); 7.1479 (3.1); 7.1408 (1.3); 6.9968 (1.2); 6.9052 (0.5); 6.8922 (0.5); 6.8893 (0.7); 6.8849 (1.4); 6.8792 (1.7);

6.8734 (0.8); 6.8632 (1.9); 6.8574 (3.0); 6.8516 (1.4); 6.8415 (0.8); 6.8356 (1.4); 6.8298 (0.7); 6.7486 (0.5); 6.0862 (0.7); 5.9800 (0.6); 5.9756 (0.6); 5.9685 (2.5); 5.9633 (1.0); 5.9581 (0.7); 5.9498 (1.2); 5.9448 (1.5); 5.9399 (1.4); 5.9360 (1.4); 5.9312 (1.8); 5.9262 (1.4); 5.9105 (0.9); 5.9054 (1.3); 5.9032 (1.4); 5.9000 (1.4); 5.8921 (1.1); 5.8861 (0.8); 5.8777 (0.7); 5.8697 (1.2); 5.8617 (1.2); 5.2988 (3.0); 4.9842 (0.8); 4.6521 (0.8); 4.6398 (0.9); 4.6299 (0.9); 4.6178 (1.1); 4.6133 (1.0); 4.6072 (0.8); 4.6004 (1.4); 4.5973 (0.8); 4.5910 (1.0); 4.5879 (0.8); 4.5848 (0.8); 4.5782 (1.7); 4.5657 (1.0); 4.5628 (0.8);

4.5505 (0.7); 4.5408 (0.7); 4.5286 (0.6); 4.1484 (0.7); 4.1305 (2.2); 4.1127 (2.2); 4.0948 (0.7); 3.8166 (1.2); 3.8049 (0.8); 3.8016 (1.8); 3.7843 (1.9); 3.7811 (1.9); 3.7783 (1.6); 3.7736 (1.7); 3.7602 (15.0); 3.7538 (11.0); 3.7475 (11.6); 3.7422 (10.7); 3.7402 (16.0); 3.7333 (6.4); 3.7318 (7.0); 3.3897 (0.9);

3.2013 (2.2); 3.1718 (2.8); 3.1653 (1.8); 3.1583 (2.4); 3.1288 (2.5); 3.1222 (1.5); 3.1167 (1.1); 2.5605 (0.5); 2.5257 (0.7); 2.5044 (0.7); 2.4985 (0.6); 2.4829 (0.8); 2.4696 (0.6); 2.4637 (0.9); 2.4485 (0.7);

2.4413 (0.6); 2.4275 (0.7); 2.2063 (0.6); 2.1991 (0.6); 2.1939 (0.9); 2.1890 (0.9); 2.1819 (0.8); 2.1767 (1.3); 2.1712 (1.0); 2.1649 (0.8); 2.1594 (1.2); 2.1539 (0.8); 2.1479 (0.7); 2.1419 (0.8); 2.0436 (10.7); 1.9396 (0.7); 1.9132 (0.7); 1.9048 (0.6); 1.8764 (0.6); 1.8640 (0.7); 1.8380 (0.7); 1.8290 (0.7); 1.7187 (14.5); 1.7120(10.1); 1.7081 (7.8); 1.7002 (7.6); 1.6947 (9.4); 1.5719(2.0); 1.2765 (3.2); 1.2587 (6.7); 1.2408 (3.1); 0.9713 (3.6); 0.9542 (3.8); 0.9435 (7.1); 0.9348 (4.4); 0.9313 (3.4); 0.9265 (10.8); 0.9207 (8.3); 0.9177 (9.1); 0.9143 (3.9); 0.9095 (4.6); 0.9070 (3.5); 0.9033 (7.7); 0.9008 (9.7); 0.8964 (3.4);

0.8864 (4.1); 0.8839 (5.4); 0.8790 (2.5); 0.8694 (3.1); 0.0080 (2.2); -0.0002 (77.8); -0.0085 (2.3) P-12: ¹ H-NMR(400.0 MHz, CDC13):

- 134 044070 δ= 7.5187 (1.3); 7.4241 (0.7); 7.4031 (0.5); 7.3255 (0.6); 7.3100 (0.8); 7.2598 (223.5); 7.1920 (1.2); 7.1875 (1.6); 7.1825 (1.7); 7.1766 (2.0); 7.1655 (3.2); 7.1625 (3.0); 7.1566 (1.8); 7.1487 (2.3); 7.1451 (2.1); 7.1396 (0.9); 6.9958 (1.3); 6.9127 (0.8); 6.8940 (1.3); 6.8911 (1.6); 6.8882 (1.4); 6.8854 (1.3);

6.8824 (1.0); 6.8725 (1.2); 6.8693 (1.4); 6.8637 (0.8); 6.7904 (0.6); 6.7693 (0.6); 5.9956 (0.8); 5.9905 (0.8); 5.9594 (0.5); 5.9384 (1.2); 5.9358 (1.3); 5.9312 (1.2); 5.9285 (1.2); 5.9222 (0.7); 5.9064 (0.6);

5.8920 (1.4); 5.8824 (3.5); 5.8718 (1.3); 5.8670 (1.6); 5.8633 (1.2); 5.2985 (1.9); 4.8577 (0.8); 4.8418 (0.9); 4.8333 (1.0); 4.8281 (1.1); 4.8186 (1.6); 4.8106 (1.8); 4.8029 (1.8); 4.7957 (1.2); 4.7882 (1.4);

4.7801 (1.4); 4.7639 (0.8); 3.9508 (0.9); 3.8435 (1.1); 3.7998 (1.7); 3.7969 (1.7); 3.7770 (1.2); 3.7731 (1.2); 3.7670 (1.2); 3.7593 (0.9); 3.7534 (1.8); 3.7339 (1.2); 3.7299 (1.3); 3.7240 (1.3); 3.4194 (0.8);

3.4144 (0.9); 3.2092 (1.6); 3.2010 (1.3); 3.1919 (1.1); 3.1827 (1.3); 3.1793 (1.4); 3.1659 (1.5); 3.1615 (0.9); 3.1576 (1.2); 3.1487 (1.0); 3.1391 (1.1); 3.1363 (1.2); 2.6519 (0.5); 2.6391 (0.5); 2.6164 (0.9);

2.5941 (0.8); 2.5814 (0.6); 2.5760 (0.8); 2.5590 (0.8); 2.5495 (0.6); 2.5404 (0.8); 2.0918 (0.6); 2.0750 ( 1.1); 2.0689 (0.8); 2.0585 (1.4); 2.0519 (1.1); 2.0436 (3.0); 2.0351 (1.0); 2.0251 (0.8); 2.0184 (0.7);

.0033 (0.5); 1.9696 (0.6); 1.9450 (0.6); 1.9353 (0.6); 1.9214 (0.9); 1.9108 (1.3); 1.9006 (0.6); 1.8859 (0.6); 1.8752 (0.9); 1.7562 (0.5); 1.7278 (7.0); 1.7204 (16.0); 1.7142 (8.1); 1.6934 (5.8); 1.5510 (5.9); 1.2765 (0.8); 1.2586 (2.0); 1.2407 (0.7); 1.1320 (3.6); 1.1133 (8.1); 1.0964 (7.5); 1.0916 (6.1); 1.0837 (4.9); 1.0741 (10.6); 1.0712 (7.2); 1.0676 (5.0); 1.0626 (3.1); 1.0564 (8.2); 1.0542 (8.2); 1.0456 (2.1); 1.0373 (2.7); 0.0080 (3.3); -0.0002 (95.1); -0.0085 (3.0)

P-13: ¹ H-NMR(400.6 MHz, CDC13):

δ= 7.4158 (1.8); 7.3963 (4.7); 7.3873 (2.8); 7.3827 (4.2); 7.3782 (6.6); 7.3736 (6.1); 7.3702 (7.5); 7.3669 (7.3); 7.2641 (15.3); 7.1590 (1.1); 7.1536 (1.4); 7.1411 (1.4); 7.1344 (1.8); 7.1322 (1.7); 7.1303 (1.7);

7.1243 (1.2); 7.1165 (1.3); 7.1092 (0.6); 5.9624 (1.9); 5.9403 (1.3); 5.9323 (1.7); 5.9269 (1.9); 5.9239 (1.7); 5.9190 (1.9); 5.9141 (1.1); 5.8928 (1.3); 5.8879 (2.5); 5.8830 (2.3); 5.8743 (1.5); 5.8692 (1.3);

4.7835 (0.9); 4.1316 (0.7); 4.1137 (0.7); 3.8381 (2.5); 3.8258 (2.2); 3.7946 (2.8); 3.7824 (2.5); 3.5727 (0.8); 3.5603 (1.0); 3.5555 (1.0); 3.5443 (0.8); 3.2886 (9.1); 3.2672 (11.9); 3.2492 (4.0); 3.2459 (3.2);

3.2057 (3.2); 3.2023 (2.6); 2.7107 (0.6); 2.6877 (1.1); 2.6742 (1.0); 2.6647 (0.9); 2.6520 (1.3); 2.6293 (0.7); 2.2836 (0.5); 2.0478 (3.6); 2.0389 (0.9); 2.0341 (0.7); 2.0264 (0.7); 2.0211 (1.1); 2.0154 (0.7);

2.0083 (0.7); 2.0031 (1.0); 1.9982 (0.7); 1.9905 (0.7); 1.9853 (1.0); 1.9727 (0.6); 1.7198 (13.1); 1.7162 (16.0); 1.7110 (8.0); 1.6950 (0.7); 1.3326 (1.6); 1.2983 (0.6); 1.2836 (2.5); 1.2779 (1.8); 1.2599 (5.4);

1.2557 (6.8); 1.2422 (1.6); 0.8962 (0.6); 0.8799 (1.4); 0.8621 (0.7); -0.0002 (7.8)

Π-14: Ή-ΉΜΡ(400.0 MHz, CDC13):

δ= 9.5942 (0.8); 9.5645 (0.9); 7.3118 (1.7); 7.2971 (1.9); 7.2786 (1.6); 7.2618 (76.0); 7.2014 (0.7); 7.1972 (0.8); 7.1887 (3.1); 7.1848 (5.0); 7.1829 (4.9); 7.1792 (5.2); 7.1760 (3.0); 7.1722 (3.1); 7.1690 (5.2); 7.1652 (5.1); 7.1634 (5.0); 7.1595 (3.3); 7.1526 (0.8); 7.1471 (0.6); 6.9172 (1.1); 6.9153 (1.1);

6.9114 (1.7); 6.9097 (1.6); 6.9056 (1.0); 6.8955 (2.0); 6.8937 (2.1); 6.8897 (3.2); 6.8880 (3.1); 6.8840 (1.8); 6.8738 (1.0); 6.8721 (1.0); 6.8680 (1.6); 6.8663 (1.5); 6.8623 (0.8); 6.1922 (2.5); 6.1846 (2.5);

- 135 044070

6.1654 (2.8); 6.1578 (2.8); 6.1491 (3.1); 6.1414 (2.9); 6.1222 (3.0); 6.1147 (3.0); 5.9398 (1.0); 5.9347 (1.6); 5.9321 (1.5); 5.9264 (2.5); 5.9209 (3.2); 5.9182 (2.8); 5.9163 (3.0); 5.9135 (3.5); 5.9092 (2.5);

5.9025 (4.2); 5.8978 (6.5); 5.8926 (3.2); 5.8887 (1.5); 5.8838 (2.8); 5.8787 (1.7); 5.5695 (4.4); 5.5682 (4.9); 5.5665 (4.8); 5.5652 (4.5); 5.5264 (3.9); 5.5250 (4.3); 5.5234 (4.2); 5.5220 (3.8); 5.3657 (3.8);

5.3649 (3.8); 5.3569 (4.0); 5.3389 (3.5); 5.3379 (3.6); 5.3301 (3.7); 5.3291 (3.6); 5.2991 (8.6); 4.8195 (0.5); 4.8002 (1.1); 4.7937 (1.2); 4.7888 (1.3); 4.7833 (1.2); 4.7787 (1.1); 4.7706 (1.0); 3.9516 (4.0);

3.9401 (4.2); 3.9082 (4.6); 3.8967 (4.8); 3.5617 (1.0); 3.5571 (1.4); 3.5523 (1.4); 3.5491 (1.5); 3.5443 (1.9); 3.5392 (2.0); 3.5341 (1.9); 3.5292 (1.5); 3.5259 (1.4); 3.5214 (1.6); 3.5168 (1.0); 3.4518 (0.6);

3.4357 (3.8); 3.4259 (2.6); 3.4228 (3.3); 3.4170 (5.7); 3.4121 (3.4); 3.4065 (2.9); 3.4046 (3.1); 3.3966 (4.3); 3.3872 (2.2); 3.3761 (0.9); 3.3699 (0.6); 3.3512 (0.5); 3.3392 (4.5); 3.3315 (4.3); 3.2958 (3.8);

3.2881 (3.8); 2.7259 (1.0); 2.7232 (1.0); 2.7029 (2.1); 2.7002 (2.0); 2.6898 (1.4); 2.6870 (1.4); 2.6799 (1.3); 2.6772 (1.2); 2.6668 (2.3); 2.6641 (2.2); 2.6437 (1.1); 2.6413 (1.1); 2.0357 (1.0); 2.0273 (1.2);

2.0233 (1.9); 2.0154 (1.9); 2.0109 (1.2); 2.0030 (1.1); 1.9999 (1.1); 1.9912 (1.2); 1.9872 (1.8); 1.9793 (1.7); 1.9748 (1.1); 1.9671 (0.9); 1.8925 (0.9); 1.8767 (3.0); 1.8736 (2.7); 1.8578 (5.7); 1.8547 (4.4); 1.8467 (1.9); 1.8387 (6.0); 1.8352 (4.5); 1.8280 (2.1); 1.8196 (3.9); 1.8160 (3.4); 1.8008 (1.8); 1.7973 (1.7); 1.0983 (1.0); 1.0899 (7.6); 1.0814 (1.8); 1.0746 (9.0); 1.0714 (16.0); 1.0630 (1.6); 1.0561 (15.4);

.0527 (8.1); 1.0374 (6.2); 0.9033 (1.0); 0.8932 (0.5); 0.8875 (1.0); 0.0080 (1.4); -0.0002 (44.4); -0.0085 (1.7)

P-15: ¹ H-NMR(400.0 MHz, d ₆ -DMSO):

δ= 7.8906 (0.9); 7.8742 (1.5); 7.8548 (1.4); 7.7920 (1.1); 7.7714 (1.1); 7.5229 (3.9); 7.5034 (4.0); 7.4859 (2.8); 7.3286 (1.2); 7.3093 (2.2); 7.2914 (1.0); 5.8650 (2.6); 5.6779 (1.8); 5.6699 (1.2); 5.6643 (1.6);

5.6195 (1.6); 5.6058 (1.3); 4.7403 (1.1); 4.0385 (1.2); 4.0205 (1.3); 3.7633 (4.3); 3.7195 (5.2); 3.3720 (3.4); 3.3677 (2.9); 3.3572 (1.2); 3.3434 (0.8); 3.3282 (3.9); 3.3235 (4.0); 3.3093 (256.8); 2.6743 (3.3);

2.6694 (4.4); 2.6650 (3.3); 2.5508 (3.5); 2.5461 (3.4); 2.5227 (14.0); 2.5094 (278.6); 2.5050 (564.2);

2.5005 (753.6); 2.4961 (546.5); 2.4918 (270.3); 2.4474 (4.0); 2.3318 (3.5); 2.3272 (4.5); 2.3228 (3.5);

2.2409 (0.6); 2.2213 (1.3); 2.2030 (0.9); 2.1835 (1.5); 2.1703 (1.2); 2.1502 (1.5); 2.1303 (0.7); 2.0724 (1.5); 1.9878 (5.0); 1.7952 (0.9); 1.7835 (1.1); 1.7606 (0.7); 1.7506 (1.0); 1.7392 (1.2); 1.7273 (1.3);

1.7154 (0.8); 1.6943 (1.2); 1.6821 (0.8); 1.5556 (12.0); 1.5325 (16.0); 1.2377 (2.2); 1.1923 (1.4); 1.1745 (2.9); 1.1567 (1.4); 0.8539 (0.6); 0.1464 (0.6); -0.0002 (147.9); -0.0085 (6.8); -0.1496 (0.6)

P-16: ¹ H-NMR(400.0 MHz, d ₆ -DMSO):

δ= 7.8755 (1.8); 7.8505 (1.7); 7.7928 (1.4); 7.5227 (5.8); 7.5027 (5.6); 7.4864 (4.2); 7.3083 (2.9); 5.8644 (3.4); 5.6720 (2.4); 5.6195 (1.8); 4.7574 (1.6); 3.7626 (4.2); 3.7196 (5.2); 3.3712 (4.4); 3.3078 (485.4);

2.6699 (7.9); 2.5039 (1088.6); 2.5004 (1306.5); 2.3938 (2.6); 2.3271 (8.4); 2.2218 (2.2); 2.1868 (2.0);

2.1701 (2.0); 2.0727 (1.2); 1.9884 (2.2); 1.7277 (1.6); 1.5554 (12.9); 1.5325 (16.0); 1.2374 (2.2); 1.1744 (1.7); -0.0002 (90.9)

P-17: ¹ H-NMR(400.0 MHz, CDC13):

- 136 044070 δ= 7.5187 (1.8); 7.4267 (1.0); 7.3105 (1.4); 7.2956 (1.1); 7.2598 (331.5); 7.2117 (0.5); 7.1955 (2.4); 7.1906 (2.4); 7.1844 (2.6); 7.1798 (3.4); 7.1748 (3.7); 7.1693 (2.8); 7.1648 (2.0); 7.1549 (1.8); 6.9958 (1.8); 6.8999 (1.1); 6.8953 (1.3); 6.8893 (1.2); 6.8837 (1.6); 6.8784 (1.8); 6.8735 (1.6); 6.8676 (1.0); 6.8566 (0.8); 6.1977 (1.1); 6.1935 (1.8); 6.1807 (1.0); 6.1709 (1.3); 6.1668 (2.0); 6.1543 (2.0); 6.1504 (2.1); 6.1376 (1.1); 6.1277 (1.3); 6.1236 (2.1); 6.1108 (1.0); 5.9507 (0.9); 5.9010 (1.0); 5.8836 (6.3); 5.8728 (1.9); 5.8686 (2.0); 5.5795 (1.4); 5.5717 (1.5); 5.5668 (1.7); 5.5653 (1.7); 5.5502 (1.4); 5.5454 (1.6); 5.5439 (1.6); 5.5364 (1.3); 5.5287 (1.3); 5.5237 (1.5); 5.5070 (1.1); 5.5023 (1.3); 5.3713 (1.4); 5.3595 (2.1); 5.3471 (1.8); 5.3448 (1.6); 5.3331 (3.1); 5.3217 (1.4); 5.3065 (1.2); 4.8516 (1.2); 4.8353 (3.0); 4.8293 (1.4); 4.8189 (2.4); 4.8128 (3.0); 4.7965 (2.2); 4.7769 (0.6); 4.1485 (0.6); 4.1306 (1.8); 4.1127 (2.0); 4.0949 (0.6); 3.9786 (1.6); 3.9417 (1.0); 3.9353 (2.0); 3.9226 (1.5); 3.9179 (1.7); 3.9106 (1.5); 3.8986 (1.1); 3.8796 (1.7); 3.8748 (1.9); 3.8676 (1.6); 3.5411 (0.9); 3.5269 (0.8); 3.4112 (1.2); 3.3368 (1.2); 3.3324 (1.8); 3.3171 (3.0); 3.3122 (1.7); 3.2895 (1.7); 3.2738 (2.5); 3.2694 (1.5); 2.6500 (0.8); 2.6373 (0.5); 2.6277 (0.7); 2.6143 (0.9); 2.6058 (0.8); 2.5920 (1.1); 2.5838 (0.5); 2.5702 (1.6); 2.5597 (0.7); 2.5566 (0.7); 2.5481 (0.9); 2.5349 (1.0); 2.0841 (0.9); 2.0673 (1.6); 2.0505 (1.8); 2.0436 (9.4); 2.0336 (1.3); 2.0156 (0.6); 1.9641 (1.0); 1.9564 (1.2); 1.9460 (0.6); 1.9228 (1.6); 1.9125 (1.4); 1.8876 (0.9); 1.8770 (0.9); 1.5444 (16.0); 1.2765 (2.8); 1.2587 (5.6); 1.2408 (2.6); 1.1280 (5.5); 1.1173 (6.1); 1.1150(6.8); 1.1107 (8.4); 1.0978 (10.4); 1.0928 (6.6); 1.0891 (11.1); 1.0805 (10.1); 1.0704 (13.0); 1.0632 (5.8); 1.0531 (9.2); 1.0439 (1.5); 1.0402 (1.4); 0.9977 (0.6); 0.8819 (0.7); 0.1460 (0.6); 0.0505 (0.6); 0.0080 (6.6); -0.0002 (169.8); -0.0085 (6.8); -0.1495 (0.6)

P-18: ¹ H-NMR(400.6 MHz, CDC13):

δ= 7.3653 (0.5); 7.3554 (0.6); 7.3475 (0.6); 7.3377 (0.6); 7.2620 (30.5); 7.1972 (1.1); 7.1914 (1.4); 7.1885 (0.8); 7.1779 (2.1); 7.1753 (1.6); 7.1723 (2.2); 7.1619 (0.9); 7.1588 (1.6); 7.1531 (1.3); 6.9144 (0.8); 6.9086 (0.7); 6.8986 (0.6); 6.8928 (1.6); 6.8870 (1.4); 6.8811 (0.5); 6.8712 (0.8); 6.8653 (0.7); 6.1988 (1.1); 6.1912 (1.0); 6.1720 (1.3); 6.1645 (1.1); 6.1557 (1.4); 6.1482 (1.2); 6.1289 (1.4); 6.1214 (1.2); 5.9786 (0.6); 5.9700 (0.9); 5.9648 (1.5); 5.9598 (0.9); 5.9562 (0.7); 5.9510 (1.1); 5.9461 (0.7); 5.9276 (0.7); 5.9224 (1.4); 5.9191 (1.6); 5.9138 (1.1); 5.9086 (0.9); 5.9052 (0.9); 5.5807 (1.8); 5.5794 (1.9); 5.5618 (1.6); 5.5605 (1.6); 5.5376 (1.6); 5.5363 (1.6); 5.5187 (1.4); 5.5174 (1.4); 5.3609 (1.5); 5.3598 (1.5); 5.3520 (1.7); 5.3512 (1.7); 5.3341 (1.4); 5.3330 (1.4); 5.3253 (1.6); 5.3243 (1.7); 4.7652 (0.5); 4.7586 (0.6); 4.7532 (0.6); 4.4965 (1.4); 4.4652 (1.4); 4.4584 (2.3); 4.4280 (3.0); 4.3818 (3.1); 4.3504 (2.4); 4.3446 (1.4); 4.3124 (1.5); 4.1314 (0.5); 4.1136 (0.6); 3.9916 (1.6); 3.9481 (1.9); 3.9413 (2.0); 3.8980 (2.2); 3.7724 (16.0); 3.6914 (13.4); 3.5917 (0.5); 3.5850 (0.6); 3.5800 (0.6); 3.5746 (0.6); 3.5681 (0.6); 3.5625 (0.6); 3.3294 (2.2); 3.3278 (2.1); 3.2861 (1.9); 3.2841 (1.8); 2.7413 (0.6); 2.7354 (0.7); 2.7222 (0.5); 2.7047 (0.7); 2.6988 (0.8); 2.1548 (0.7); 2.1182 (0.7); 2.1021 (0.7); 2.0655 (0.6); 2.0467 (2.6); 1.5910 (1.9); 1.2779 (1.0); 1.2601 (2.3); 1.2532 (1.1); 1.2422 (0.9); 0.8819 (1.6); 0.8642 (0.6); 0.0693 (1.4); 0.0079 (0.7); -0.0002 (27.3); -0.0085 (0.9)

P-27: ¹ H-NMR(400.0 MHz, CDC13):

- 137 044070 δ= 7.6172 (1.7); 7.5974 (1.6); 7.5544 (3.6); 7.5320 (3.1); 7.3116 (1.8); 7.2797 (11.7); 7.2607 (138.2); 7.2109 (3.1); 7.1920 (7.6); 7.1800 (12.1); 7.1752 (12.6); 7.1601 (9.0); 7.1426 (1.1); 6.9970 (0.8); 6.8847 (3.4); 6.8791 (4.6); 6.8628 (5.5); 6.8573 (7.3); 6.8516 (4.0); 6.8412 (2.7); 6.8356 (3.4); 6.2130 (4.8);

6.1978 (2.8); 6.1863 (5.3); 6.1704 (6.7); 6.1547 (3.0); 6.1432 (5.4); 6.1280 (2.3); 5.8981 (7.2); 5.8705 (2.8); 5.8653 (3.4); 5.8513 (1.9); 5.8145 (5.0); 5.8092 (6.7); 5.8034 (4.7); 5.7955 (4.4); 5.5878 (9.4);

5.5448 (9.2); 5.5049 (3.5); 5.3405 (9.5); 5.3142 (10.7); 5.2987 (1.8); 5.2897 (3.6); 5.0311 (5.0); 5.0125 (3.4); 4.0475 (2.5); 4.0283 (8.6); 4.0206 (7.4); 4.0114 (13.1); 4.0038 (10.2); 3.9945 (7.3); 3.9865 (6.4);

3.9643 (4.8); 3.9327 (16.0); 3.8899 (13.3); 3.8158 (2.3); 3.7966 (4.6); 3.7884 (5.1); 3.7698 (8.0); 3.7561 (5.3); 3.7507 (5.4); 3.7374 (7.3); 3.7189 (5.6); 3.7104 (3.4); 3.6991 (2.0); 3.6913 (2.3); 3.6710 (0.6);

3.3094 (6.2); 3.3022 (9.6); 3.2667 (5.3); 3.2593 (8.3); 2.4465 (2.5); 2.4259 (4.8); 2.4120 (4.3); 2.4051 (3.7); 2.3914 (7.2); 2.3831 (5.0); 2.3658 (10.8); 2.3538 (9.6); 2.3478 (12.8); 2.3301 (8.8); 2.3173 (3.8);

2.2994 (1.1); 1.9934 (3.5); 1.9858 (5.0); 1.9778 (3.0); 1.9589 (3.6); 1.9516 (5.5); 1.9441 (4.3); 1.9178 (1.4); 1.9103 (1.8); 1.9026 (1.0); 1.5907 (5.6); -0.0002 (79.8); -0.0500 (0.7)

Π-28: Ή-ΉΜΡ(400.0 MHz, CDC13):

δ= 7.5183 (9.0); 7.3731 (1.4); 7.3097 (12.2); 7.2881 (3.0); 7.2594 (1582.1); 7.2109 (3.7); 7.1847 (12.4);

7.1791 (19.2); 7.1747 (19.4); 7.1650 (16.0); 7.1596 (17.5); 6.9954 (8.9); 6.9053 (3.9); 6.8976 (5.4);

6.8911 (4.6); 6.8821 (6.1); 6.8762 (8.9); 6.8702 (5.0); 6.8607 (2.9); 6.8546 (4.3); 6.7435 (1.9); 6.1965 (10.3); 6.1698 (11.6); 6.1534 (12.8); 6.1266 (12.9); 6.0151 (6.5); 6.0092 (6.6); 6.0014 (8.5); 5.9957 (8.4); 5.9914 (6.1); 5.9107 (4.5); 5.9053 (8.5); 5.8995 (5.0); 5.8914 (6.7); 5.8858 (4.1); 5.8687 (2.6);

5.8613 (3.3); 5.8464 (3.5); 5.8317 (1.8); 5.6515 (2.7); 5.6084 (2.5); 5.5642 (4.4); 5.5510 (16.0); 5.5213 (3.9); 5.5079 (13.6); 5.4650 (2.6); 5.4379 (2.5); 5.3557 (8.2); 5.3436 (11.7); 5.3291 (7.5); 5.3167 (11.0);

5.1225 (1.7); 5.0099 (3.9); 3.9857 (1.7); 3.9523 (4.5); 3.9480 (3.8); 3.9344 (6.3); 3.9306 (13.4); 3.9091 (5.0); 3.9046 (4.4); 3.8913 (6.8); 3.8876 (15.4); 3.7886 (2.4); 3.5799 (4.1); 3.4260 (3.8); 3.3824 (2.9);

3.3368 (7.5); 3.3305 (15.1); 3.3256 (6.3); 3.2936 (6.5); 3.2874 (13.2); 3.2823 (5.6); 3.2404 (1.5); 2.7040 (3.0); 2.6933 (2.7); 2.6815 (2.6); 2.6175 (2.1); 2.5964 (3.1); 2.5697 (4.1); 2.5607 (3.2); 2.5485 (6.8);

2.5345 (4.8); 2.5271 (4.0); 2.5135 (6.8); 2.4922 (3.5); 2.0047 (1.8); 1.9891 (1.9); 1.9588 (3.6); 1.9487 (6.6); 1.9388 (3.6); 1.9231 (3.0); 1.9135 (6.1); 1.9031 (3.5); 1.8794 (1.6); 1.8669 (1.6); 1.6309 (1.7);

1.3486 (1.4); 1.3304 (2.7); 1.3116 (1.3); 0.1460 (3.5); 0.0501 (6.4); 0.0079 (30.9); -0.0002 (897.7); 0.0085 (29.5); -0.0495 (1.9); -0.0849 (1.5); -0.1497 (3.2)

P-29: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5187 (3.7); 7.3605 (1.4); 7.3499 (0.6); 7.3103 (3.2); 7.2599 (652.6); 7.2261 (1.2); 7.2111 (1.2);

7.1957 (1.9); 7.1899 (2.6); 7.1833 (8.3); 7.1776 (16.0); 7.1720 (11.6); 7.1678 (9.3); 7.1633 (12.1);

7.1610 (11.6); 7.1578 (15.5); 7.1521 (8.2); 7.1456 (2.6); 7.1397 (1.8); 6.9958 (3.6); 6.9153 (2.0); 6.9096 (3.9); 6.9059 (4.0); 6.9002 (2.1); 6.8936 (4.3); 6.8879 (7.7); 6.8843 (7.8); 6.8785 (3.9); 6.8720 (2.5);

6.8663 (3.9); 6.8625 (3.9); 6.8569 (1.7); 6.7382 (2.9); 6.7194 (5.0); 6.7019 (3.0); 6.2089 (6.3); 6.1941 (6.4); 6.1821 (7.1); 6.1660 (9.5); 6.1509 (7.8); 6.1390 (7.7); 6.1242 (7.8); 5.9475 (8.3); 5.9437 (5.6);

- 138 044070

5.9417 (5.5); 5.9392 (6.3); 5.9336 (10.2); 5.9298 (6.7); 5.8412 (3.9); 5.8355 (7.3); 5.8296 (4.4); 5.8215 (5.7); 5.8159 (3.1); 5.8027 (3.7); 5.7969 (6.8); 5.7910 (4.2); 5.7830 (5.6); 5.7772 (3.1); 5.5543 (10.7); 5.5528 (10.7); 5.5471 (11.4); 5.5457 (11.2); 5.5111 (9.3); 5.5097 (9.2); 5.5039 (9.8); 5.5026 (9.5);

5.3497 (11.0); 5.3473 (11.4); 5.3230 (10.2); 5.3206 (10.7); 5.1241 (2.4); 5.1086 (4.1); 5.1031 (4.4); 5.0989 (4.4); 5.0942 (4.0); 4.0926 (4.1); 4.0348 (1.6); 4.0201 (4.6); 4.0090 (5.3); 3.9957 (5.9); 3.9878 (7.3); 3.9823 (4.8); 3.9716 (7.5); 3.9639 (14.1); 3.9558 (4.9); 3.9459 (16.0); 3.9348 (2.0); 3.9278 (2.1); 3.9208 (13.4); 3.9028 (13.1); 3.8899 (1.8); 3.8772 (3.1); 3.8650 (3.2); 3.8566 (3.0); 3.8434 (4.4); 3.8325 (4.4); 3.7073 (2.0); 3.6934 (4.7); 3.6778 (4.8); 3.6612 (3.7); 3.6440 (2.8); 3.6322 (1.3); 3.3306 (13.5); 3.3279 (13.3); 3.2874 (11.9); 3.2848 (11.8); 2.6995 (2.8); 2.6861 (2.8); 2.6784 (5.1); 2.6650 (8.4);

2.6569 (3.5); 2.6515 (3.6); 2.6436 (8.1); 2.6302 (5.4); 2.6222 (3.1); 2.6089 (2.9); 2.0046 (1.0); 1.8846 (5.6); 1.8748 (6.1); 1.8631 (6.7); 1.8535 (8.4); 1.8501 (8.3); 1.8395 (13.3); 1.8281 (15.5); 1.8167 (11.3); 1.8035 (7.8); 1.7940 (6.0); 1.7819 (4.5); 1.7721 (4.2); 1.7611 (3.8); 1.7479 (8.7); 1.7340 (11.2); 1.7225 (9.7); 1.7114 (5.2); 1.7004 (3.5); 1.6879 (1.5); 1.5844 (1.1); 1.5413 (1.6); 1.2541 (1.3); 0.9018 (0.8); 0.8971 (0.8); 0.8813 (0.8); 0.1462 (1.3); 0.1005 (0.8); 0.0503 (1.7); 0.0079 (12.1); -0.0002 (388.3); 0.0085 (15.0); -0.0339 (0.9); -0.0491 (0.9); -0.0992 (0.6); -0.1494 (1.3)

Π-30: Ή-ΉΜΡ(400.0 MHz, CDC13):

δ= 7.6666 (2.3); 7.6446 (2.3); 7.5963 (2.3); 7.5743 (2.4); 7.5192 (2.0); 7.3107 (0.6); 7.2914 (0.7); 7.2604 (343.8); 7.2157 (0.8); 7.2101 (1.6); 7.2043 (1.3); 7.1978 (7.4); 7.1921 (9.5); 7.1890 (5.5); 7.1797 (11.0); 7.1777 (12.6); 7.1740 (12.6); 7.1721 (11.4); 7.1628 (5.4); 7.1597 (9.5); 7.1540 (7.4); 7.1477 (1.3);

7.1419 (1.2); 7.1364 (0.5); 6.9963 (2.0); 6.8848 (3.1); 6.8791 (5.5); 6.8733 (3.0); 6.8631 (6.2); 6.8573 (10.9); 6.8515 (5.6); 6.8413 (3.2); 6.8356 (5.4); 6.8298 (2.7); 6.2128 (5.9); 6.1975 (5.9); 6.1860 (6.6); 6.1702 (10.7); 6.1544 (7.0); 6.1429 (7.3); 6.1276 (7.1); 5.9028 (2.5); 5.8997 (2.6); 5.8889 (7.2); 5.8859 (7.8); 5.8827 (7.7); 5.8797 (7.0); 5.8751 (4.8); 5.8720 (4.5); 5.8689 (4.2); 5.8622 (4.5); 5.8572 (6.9);

5.8520 (4.1); 5.8434 (3.6); 5.8382 (2.3); 5.8097 (3.5); 5.8043 (6.1); 5.7987 (3.9); 5.7905 (4.5); 5.7852 (2.6); 5.5871 (10.0); 5.5855 (9.8); 5.5475 (10.5); 5.5457 (11.8); 5.5441 (10.9); 5.5425 (9.3); 5.5044 (8.6); 5.5028 (8.3); 5.3406 (9.5); 5.3393 (8.9); 5.3176 (9.8); 5.3159 (10.7); 5.3141 (10.6); 5.2985 (0.8); 5.2909 (8.6); 5.2894 (8.2); 5.0296 (4.0); 5.0109 (4.1); 4.9894 (1.5); 4.0486 (2.1); 4.0225 (5.5); 4.0178 (6.1); 4.0089 (6.7); 4.0013 (5.9); 3.9916 (5.2); 3.9813 (6.7); 3.9694 (8.4); 3.9605 (6.8); 3.9486 (8.0); 3.9299 (16.0); 3.9274 (15.6); 3.9156 (4.8); 3.9022 (4.3); 3.8871 (15.6); 3.8845 (14.8); 3.7150 (1.8);

3.7031 (2.8); 3.6964 (3.5); 3.6854 (3.1); 3.6634 (2.8); 3.6553 (2.2); 3.3131 (11.6); 3.3053 (11.8); 3.2703 (10.1); 3.2624 (10.4); 2.4455 (2.5); 2.4249 (4.8); 2.4112 (3.4); 2.4048 (4.2); 2.3906 (5.8); 2.3853 (5.2); 2.3710 (4.8); 2.3648 (3.1); 2.3510 (5.5); 2.3305 (2.7); 2.2067 (0.7); 2.0050 (0.7); 1.9770 (2.7); 1.9694 (4.7); 1.9616 (2.7); 1.9421 (4.4); 1.9345 (8.0); 1.9268 (4.6); 1.9074 (2.6); 1.8997 (4.6); 1.8920 (3.3); 1.8683 (3.3); 1.8578 (4.6); 1.8497 (6.2); 1.8375 (7.3); 1.8258 (6.4); 1.8146 (4.0); 1.8011 (2.5); 1.7884 (2.2); 1.7766 (3.7); 1.7636 (6.9); 1.7505 (8.9); 1.7399 (8.8); 1.7294 (6.0); 1.7109 (2.8); 1.6985 (1.2);

- 139 044070

1.2556 (1.3); 0.8901 (0.7); 0.8767 (0.9); 0.8612 (0.7); 0.1460 (0.8); 0.0079 (7.0); -0.0002 (201.5); 0.0084 (7.7); -0.1495 (0.7)

P-31: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9871 (0.8); 7.5185 (0.8); 7.2596 (134.0); 7.2152 (1.8); 7.2096 (2.4); 7.2054 (1.4); 7.1957 (3.2);

7.1919 (3.0); 7.1901 (2.8); 7.1810 (1.6); 7.1781 (2.3); 7.1724 (1.8); 6.9956 (0.8); 6.9380 (0.6); 6.9339 (1.0); 6.9281 (0.6); 6.9163 (1.2); 6.9122 (1.8); 6.9105 (1.8); 6.9064 (1.0); 6.8947 (0.6); 6.8906 (0.9);

5.9428 (0.6); 5.9387 (0.6); 5.9290 (1.1); 5.9248 (1.6); 5.9086 (1.0); 5.9042 (1.7); 5.8993 (1.6); 5.8939 (0.9); 5.8856 (0.7); 5.8802 (0.5); 5.8422 (0.8); 5.8371 (1.2); 5.8317 (0.8); 5.8233 (0.9); 5.8181 (0.6);

5.2982 (4.1); 5.0733 (0.7); 5.0591 (0.6); 5.0387 (0.8); 4.0583 (0.6); 4.0430 (1.0); 4.0296 (1.8); 4.0192 (2.3); 4.0132 (2.0); 4.0009 (2.5); 3.9945 (2.0); 3.9911 (2.3); 3.9813 (3.2); 3.9574 (0.9); 3.9364 (3.0);

3.8919 (0.6); 3.7561 (0.7); 3.7352 (3.1); 3.7212 (3.3); 3.7107 (1.0); 3.6903 (2.9); 3.6762 (2.9); 3.6611 (0.7); 2.4027 (1.0); 2.3885 (0.6); 2.3823 (0.6); 2.3682 (1.1); 2.3480 (0.6); 2.3305 (1.0); 2.3163 (0.7);

2.3102 (0.6); 2.2960 (1.2); 2.2757 (0.6); 2.0261 (1.1); 2.0209 (0.6); 2.0014 (1.1); 1.9963 (1.1); 1.9914 (1.0); 1.9669 (0.8); 1.9614 (0.5); 1.8777 (0.7); 1.8527 (1.3); 1.8423 (1.6); 1.8323 (1.6); 1.8206 (1.1);

1.8088 (0.7); 1.7962 (0.6); 1.7809 (0.8); 1.7675 (1.8); 1.7541 (2.2); 1.7404 (1.7); 1.7314 (1.3); 1.5465 (16.0); 1.2584 (0.7); 0.8819 (0.6); 0.0080 (2.6); -0.0002 (77.7); -0.0085 (2.7)

P-32: Ή-ΉΜΡ(400.0 MHz, CDC13):

δ= 7.9588 (1.6); 7.9382 (1.0); 7.5190 (0.9); 7.2601 (154.0); 7.2288 (0.6); 7.2162 (3.3); 7.2105 (4.3);

7.2071 (2.4); 7.1987 (4.8); 7.1965 (5.6); 7.1931 (5.4); 7.1910 (5.0); 7.1823 (2.5); 7.1791 (4.1); 7.1735 (3.2); 7.1667 (0.5); 7.1609 (0.5); 6.9960 (0.9); 6.9405 (1.0); 6.9385 (1.1); 6.9348 (1.7); 6.9328 (1.7);

6.9290 (1.0); 6.9189 (2.0); 6.9169 (2.1); 6.9131 (3.4); 6.9111 (3.3); 6.9074 (1.9); 6.9054 (1.7); 6.8973 (1.0); 6.8952 (1.1); 6.8915 (1.7); 6.8895 (1.6); 6.8858 (0.9); 5.9552 (1.1); 5.9486 (1.1); 5.9394 (2.1);

5.9337 (3.1); 5.9201 (1.7); 5.9133 (3.2); 5.9080 (2.7); 5.9027 (1.7); 5.8943 (1.4); 5.8891 (1.0); 5.8490 (1.4); 5.8439 (2.2); 5.8383 (1.6); 5.8301 (1.6); 5.8247 (1.0); 5.2984 (6.4); 5.0944 (0.7); 5.0743 (1.4);

5.0546 (1.2); 5.0382 (1.4); 5.0180 (0.7); 4.0615 (0.7); 4.0419 (3.7); 4.0359 (2.3); 4.0254 (7.5); 4.0188 (4.6); 4.0087 (6.8); 4.0016 (3.5); 3.9863 (5.5); 3.9724 (2.0); 3.9416 (5.1); 3.8390 (0.8); 3.8204 (1.1);

3.8119 (1.4); 3.8017 (1.0); 3.7930 (2.8); 3.7867 (0.8); 3.7752 (2.2); 3.7573 (3.6); 3.7515 (1.6); 3.7387 (3.9); 3.7340 (7.7); 3.7206 (7.3); 3.7137 (2.0); 3.6891 (4.4); 3.6757 (4.2); 2.4277 (1.0); 2.4072 (1.9);

2.3927 (2.4); 2.3869 (1.9); 2.3834 (1.2); 2.3730 (4.6); 2.3666 (2.9); 2.3570 (5.3); 2.3496 (4.5); 2.3461 (2.4); 2.3376 (4.9); 2.3326 (3.1); 2.3290 (2.1); 2.3221 (2.2); 2.3164 (1.8); 2.3023 (2.4); 2.2821 (1.1);

2.0426 (1.4); 2.0362 (2.0); 2.0307 (1.2); 2.0224 (1.2); 2.0169 (2.1); 2.0113 (1.4); 2.0070 (1.1); 2.0015 (1.7); 1.9961 (1.0); 1.9879 (1.0); 1.9823 (1.7); 1.9771 (1.0); 1.5632 (16.0); 1.2845 (0.6); 1.2583 (1.3); 0.8818 (0.8); 0.0080 (2.8); -0.0002 (91.2); -0.0085 (3.2)

P-33: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5185 (0.9); 7.4005 (0.5); 7.3769 (0.5); 7.2596 (167.8); 7.2007 (2.6); 7.1906 (2.5); 7.1856 (2.6);

6.9956 (1.2); 6.9574 (0.8); 6.9515 (1.0); 6.9409 (0.9); 6.9368 (1.0); 6.9303 (0.8); 5.9650 (2.2); 5.9409

- 140 044070 (1.0); 4.5183 (1.2); 4.1066 (0.9); 4.0005 (0.8); 3.9905 (0.9); 3.9554 (1.2); 3.9453 (1.2); 3.9355 (0.7); 3.7755 (0.8); 3.7672 (1.2); 3.7579 (1.4); 3.7478 (1.3); 3.7309 (0.6); 3.7221 (0.8); 3.7128 (1.0); 3.7027 (0.9); 3.5481 (0.6); 3.5072 (0.5); 3.4930 (1.0); 3.4867 (0.9); 3.4678 (1.6); 3.4559 (1.4); 3.4489 (1.8); 3.4355 (1.6); 3.4310 (1.6); 3.4243 (1.2); 3.4108 (1.7); 3.3970 (1.0); 3.3781 (0.5); 3.3707 (0.6); 3.1249 (3.5); 3.1112 (2.2); 3.1052 (3.5); 3.0988 (2.1); 3.0856 (3.8); 2.6306 (0.5); 2.6036 (0.6); 2.0460 (0.6); 2.0096 (0.5); 1.9419 (3.8); 1.9284 (2.5); 1.9228 (4.8); 1.9165 (2.9); 1.9101 (3.2); 1.9031 (4.2); 1.8841 (2.7); 1.8762 (1.3); 1.8655 (1.3); 1.8568 (1.4); 1.8374 (1.1); 1.8194 (0.7); 1.7260 (1.4); 1.7175 (2.0); 1.7068 (1.7); 1.6931 (1.8); 1.6828 (2.3); 1.6738 (1.7); 1.6152 (1.2); 1.5835 (1.5); 1.5473 (16.0); 1.4023 (0.6); 1.3934 (0.9); 1.3726(1.4); 1.3641 (2.3); 1.3324 (2.2); 1.3091 (1.0); 1.3010(1.4); 1.2925 (1.0); 1.2577 (3.0); 1.2096 (0.8); 1.2009 (1.0); 1.1925 (0.7); 1.1716 (1.5); 1.1559 (1.3); 1.1473 (1.6); 1.1253 (2.4); 1.1077 (7.3); 1.0972 (4.4); 1.0891 (14.7); 1.0788 (4.6); 1.0703 (7.4); 1.0602 (2.7); 1.0491 (1.7); 1.0346 (0.6); 0.8799 (1.0); 0.1456 (0.6); 0.0080 (4.4); -0.0002 (125.5); -0.0085 (5.1)

P-34: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5189 (0.7); 7.2600 (94.7); 7.2093 (1.5); 7.1962 (2.4); 7.1832 (1.9); 6.9959 (0.6); 6.9475 (0.8); 6.9399 (0.7); 6.9338 (0.9); 6.9299 (0.9); 6.9182 (0.5); 5.9697 (1.0); 5.9183 (2.0); 5.8964 (0.7); 5.2984 (0.5); 3.9522 (1.0); 3.9235 (0.7); 3.9050 (0.9); 3.7625 (1.4); 3.7556 (1.3); 3.7470 (1.1); 3.7370 (0.6);

3.7321 (0.5); 3.7172 (1.0); 3.7106 (0.9); 3.7019 (0.7); 3.3862 (0.5); 3.1389 (0.8); 3.1203 (2.6); 3.1091 (2.8); 3.1022 (2.8); 3.0908 (2.6); 3.0727 (1.0); 2.9561 (2.3); 2.8831 (1.9); 2.5466 (0.5); 1.9957 (0.6);

1.9851 (0.7); 1.9750 (0.6); 1.9592 (0.6); 1.9490 (0.8); 1.9397 (0.6); 1.7717 (4.5); 1.7552 (0.8); 1.7433 (4.0); 1.7262 (4.0); 1.7075 (5.1); 1.7046 (5.6); 1.6981 (7.3); 1.5520 (3.7); 1.4316 (8.8); 1.4132 (16.0);

1.3948 (7.4); 1.2548 (0.6); 0.0080 (3.7); -0.0002 (120.0); -0.0085 (4.5)

P-35: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2603 (69.8); 7.2197 (0.7); 7.1951 (2.4); 7.1865 (1.7); 7.1822 (1.9); 6.9548 (0.7); 6.9489 (1.0); 6.9343 (0.8); 6.9298 (1.0); 6.9186 (0.5); 5.9954 (1.0); 5.9521 (0.7); 5.9448 (0.8); 5.9261 (1.4); 5.9092 (0.7); 5.8917 (0.7); 5.2987 (3.3); 4.8485 (0.5); 4.0009 (0.6); 3.9767 (0.9); 3.9558 (0.8); 3.9306 (0.8); 3.9263 (0.5); 3.7658 (1.3); 3.7549 (0.9); 3.7465 (0.9); 3.7384 (1.2); 3.7206 (1.0); 3.7098 (0.7); 3.7014 (0.6); 3.6934 (1.1); 3.6562 (0.8); 3.4420 (1.7); 3.4227 (1.2); 3.1428 (0.7); 3.1246 (1.9); 3.1133 (1.9); 3.1062 (2.0); 3.0950 (2.0); 3.0784 (0.9); 3.0535 (1.2); 3.0030 (0.9); 2.9955 (1.1); 2.9581 (2.9); 2.9420 (0.6); 2.8846 (2.3); 2.0637 (0.9); 2.0471 (1.4); 2.0413 (1.0); 2.0303 (1.7); 2.0241 (1.3); 2.0148 (1.8); 2.0101 (1.4); 1.9980 (1.1); 1.9933 (0.8); 1.9809 (0.7); 1.4320 (1.4); 1.4240 (5.3); 1.4057 (11.0); 1.3873 (5.3); 1.2557 (0.8); 1.1413 (8.1); 1.1308 (9.3); 1.1245 (8.7); 1.1129 (16.0); 1.1076 (13.5); 1.0955 (13.0); 1.0909 (13.1); 1.0804 (4.3); 1.0775 (4.5); 1.0718 (2.9); 1.0684 (2.3); 1.0634 (3.2); 1.0606 (4.0); 1.0549 (2.4); 1.0514 (1.9); 1.0469 (1.5); 1.0437 (1.5); 0.0978 (2.4); 0.0690 (1.4); 0.0648 (0.7); 0.0080 (2.1); 0.0002 (90.0); -0.0085 (3.9)

P-36: Ή-ΉΜΡ(400.0 MHz, CDC13):

- 141 044070 δ= 7.2597 (60.0); 7.1944 (1.4); 7.1836 (1.1); 7.1804 (1.2); 7.1749 (1.1); 5.9553 (0.7); 5.9470 (0.5); 5.2984 (13.2); 3.9288 (0.6); 3.9249 (0.7); 3.7660 (13.5); 3.7493 (5.3); 3.7456 (4.2); 3.7369 (3.4); 3.7334 (1.1); 3.7249 (0.8); 3.7116 (0.5); 3.6883 (0.5); 3.1050 (0.8); 3.0919 (0.8); 2.9553 (0.7); 2.8840 (0.5); 1.6105 (1.2); 1.5977 (16.0); 1.5902 (5.8); 1.5697 (3.3); 1.5549 (4.8); 1.5520 (4.4); 1.5482 (4.8); 1.5410 (8.9); 1.4346 (2.8); 1.4163 (5.4); 1.3979 (2.6); 0.0079 (2.6); -0.0002 (76.9); -0.0085 (2.6)

P-37: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2612 (34.4); 7.2101 (0.7); 7.2041 (1.4); 7.1963 (1.8); 7.1906 (1.6); 7.1850 (1.8); 7.1800 (1.4); 7.1773 (1.3); 7.1714 (0.6); 6.9448 (0.6); 6.9387 (0.6); 6.9220 (0.7); 6.9161 (0.9); 5.9626 (1.6); 5.9532 (0.7); 5.9488 (0.6); 5.9387 (0.6); 5.9351 (0.6); 5.9076 (1.3); 5.2988 (3.8); 4.6423 (0.5); 4.6306 (0.8); 4.6188 (0.6); 4.5688 (0.6); 4.5114 (1.0); 4.5074 (1.0); 4.4986 (1.0); 4.4946 (1.0); 4.4880 (1.0); 4.4841 (1.0); 4.4752 (1.0); 4.4712 (1.0); 3.9574 (0.6); 3.9388 (0.6); 3.9266 (0.5); 3.9217 (0.7); 3.7660 (7.6);

3.7644 (15.3); 3.7573 (16.0); 3.7542 (6.9); 3.7477 (3.7); 3.7458 (8.0); 3.7389 (4.4); 3.7295 (1.1); 3.7270 (1.1); 3.7224 (1.2); 3.7151 (0.6); 3.6911 (0.7); 3.6846 (0.8); 3.6820 (0.8); 3.6776 (0.7); 3.4105 (0.6);

3.3902 (0.7); 3.1272 (0.6); 3.1090 (1.9); 3.0906 (1.9); 3.0722 (0.7); 2.9559 (2.5); 2.8845 (2.0); 2.8831 (2.1); 2.2519 (0.6); 2.2457 (0.6); 2.2393 (0.6); 2.2331 (0.7); 2.2285 (0.5); 2.2221 (0.6); 2.2158 (0.6); 2.1925 (0.5); 2.1755 (0.6); 2.1582 (0.5); 1.5762 (0.7); 1.4333 (3.8); 1.4151 (7.5); 1.3967 (3.5); 0.9857 (4.8); 0.9755 (5.8); 0.9683 (6.3); 0.9664 (6.6); 0.9580 (7.5); 0.9565 (8.4); 0.9490 (5.6); 0.9429 (3.4); 0.9391 (6.2); 0.9328 (4.8); 0.9261 (3.3); 0.9159 (7.0); 0.9090 (2.2); 0.9049 (2.6); 0.8992 (3.8); 0.8945 (2.0); 0.8877 (2.2); 0.8773 (1.4); 0.0079 (1.2); -0.0002 (43.6); -0.0085 (1.7)

P-38: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2595 (87.1); 7.1926 (1.2); 7.1819 (1.1); 7.1740 (0.8); 6.9955 (0.5); 6.9457 (0.5); 6.9245 (0.6); 5.9609 (0.9); 5.9017 (1.2); 5.2982 (16.0); 3.7589 (0.8); 3.7417 (0.7); 3.7339 (0.7); 3.7138 (0.7); 3.6968 (0.5); 1.9468 (0.7); 1.9249 (0.9); 1.7145 (0.7); 1.7042 (0.6); 1.6808 (0.8); 1.6708 (0.6); 1.6131 (2.5); 1.5833 (4.5); 1.5731 (2.0); 1.5418 (5.9); 1.3771 (0.6); 1.3685 (0.8); 1.3352 (0.8); 1.3054 (0.6); 1.2587 (2.4); 1.1672 (0.5); 1.1444 (0.6); 1.1359 (0.7); 1.1072 (0.8); 1.0795 (0.6); 0.8804 (0.8); 0.0079 (1.9); 0.0002 (62.8); -0.0085 (2.3)

P-40: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7425 (2.3); 7.7396 (2.7); 7.7366 (1.5); 7.6488 (0.8); 7.6449 (1.1); 7.6427 (1.0); 7.6391 (0.8); 7.6271 (0.8); 7.6231 (1.1); 7.6210 (0.9); 7.6173 (0.8); 7.4992 (0.6); 7.4964 (1.0); 7.4933 (1.1); 7.4903 (1.0);

7.4873 (0.7); 7.4802 (0.6); 7.4775 (1.1); 7.4743 (1.2); 7.4713 (1.0); 7.4683 (0.7); 7.2619 (27.7); 6.7355 (0.6); 5.9963 (0.5); 5.9919 (0.7); 5.9908 (0.7); 5.9865 (0.6); 5.9823 (0.8); 5.9781 (1.0); 5.9769 (1.0);

5.9726 (0.8); 5.9634 (3.5); 5.9094 (0.7); 5.9039 (1.3); 5.8983 (0.7); 5.8956 (0.6); 5.8899 (1.0); 5.8844 (0.5); 5.4066 (0.9); 5.3907 (0.6); 5.2991 (1.6); 5.1520 (0.5); 5.1420 (0.5); 5.1374 (0.6); 5.1318 (0.6);

4.0485 (1.1); 4.0032 (1.5); 3.7811 (3.3); 3.7358 (2.5); 3.5919 (0.6); 3.5862 (0.6); 3.5825 (0.6); 3.5769

- 142 044070 (0.7); 3.5702 (0.7); 3.5645 (0.6); 2.6340 (0.5); 2.6216 (0.6); 2.6194 (0.7); 2.6069 (0.6); 2.5989 (0.6); 2.5865 (0.6); 2.0055 (16.0); 1.9990 (0.9); 1.9875 (0.6); 1.9770 (0.6); 1.9741 (0.6); 1.9415 (0.6); 1.5828 (7.5); 1.5727 (7.8); -0.0002 (15.8); -0.0085 (0.7)

P-41: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.7407 (1.2); 7.7374 (2.3); 7.7334 (2.0); 7.7290 (2.1); 7.7256 (1.2); 7.6722 (0.6); 7.6684 (0.7); 7.6659 (0.8); 7.6640 (0.8); 7.6623 (0.8); 7.6604 (0.7); 7.6579 (0.7); 7.6541 (0.6); 7.6502 (0.7); 7.6464 (0.7); 7.6439 (0.8); 7.6420 (0.8); 7.6403 (0.8); 7.6384 (0.7); 7.6359 (0.6); 7.6321 (0.5); 7.4773 (0.8); 7.4743 (1.0); 7.4715 (1.1); 7.4685 (0.9); 7.4659 (0.6); 7.4583 (0.8); 7.4553 (1.0); 7.4526 (1.1); 7.4494 (0.9); 7.4469 (0.6); 7.2628 (15.9); 5.9653 (0.5); 5.9567 (0.6); 5.9516 (1.0); 5.9467 (0.7); 5.9293 (0.7); 5.9267 (0.8); 5.9233 (0.8); 5.9205 (0.8); 5.9128 (0.5); 5.9058 (3.5); 5.9034 (3.2); 5.6381 (1.1); 5.2995 (16.0); 4.0136 (1.0); 4.0109 (0.9); 3.9685 (1.4); 3.9659 (1.3); 3.7672 (2.0); 3.7580 (1.7); 3.7221 (1.5); 3.7128 (1.3); 3.3100 (0.8); 3.3052 (0.8); 3.2894 (0.8); 2.4646 (0.6); 2.4297 (0.7); 2.4059 (0.8); 2.3710 (0.8); 2.1701 (0.6); 1.9317 (0.9); 1.9246 (0.9); 1.8968 (0.8); 1.8897 (0.8); 1.6175 (5.1); 1.6139 (5.2); 1.5878 (5.4); 1.5809 (5.5); -0.0002 (9.1)

P-42: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5941 (2.1); 7.5730 (2.1); 7.2603 (74.4); 7.2459 (0.7); 7.2400 (1.2); 7.2341 (1.0); 7.2273 (6.2); 7.2216 (7.6); 7.2185 (4.6); 7.2110 (4.7); 7.2079 (7.6); 7.2022 (6.3); 7.1953 (1.1); 7.1894 (1.2); 7.1836 (0.6); 6.9586 (1.6); 6.9528 (2.8); 6.9470 (1.5); 6.9369 (3.2); 6.9312 (5.5); 6.9254 (2.8); 6.9153 (1.8); 6.9095 (3.0); 6.9036 (4.9); 6.8972 (3.9); 6.8898 (4.2); 6.8850 (4.1); 6.6724 (2.8); 6.6687 (3.0); 6.6643 (3.1); 6.6601 (4.3); 6.6555 (2.8); 6.6511 (2.6); 6.6474 (2.4); 5.9795 (2.5); 5.9727 (2.7); 5.9657 (3.8); 5.9609 (3.8); 5.9160 (3.3); 5.9105 (5.4); 5.9048 (3.5); 5.8968 (3.7); 5.8913 (2.2); 5.2985 (16.0); 5.2861 (1.0); 5.0450 (1.5); 5.0247 (2.9); 5.0046 (1.5); 4.5206 (1.2); 4.5149 (3.0); 4.5091 (3.0); 4.5017 (1.9); 4.4947 (3.0); 4.4889 (2.9); 4.4833 (1.2); 4.0017 (4.7); 3.9567 (6.7); 3.7501 (11.3); 3.7051 (8.2); 3.4874 (3.4); 3.4832 (4.6); 3.4814 (5.0); 3.4795 (4.6); 3.4753 (3.4); 2.3485 (3.8); 2.3455 (3.8); 2.3411 (2.3); 2.3278 (7.0); 2.3233 (5.9); 2.3192 (3.6); 2.3134 (3.1); 2.3076 (2.4); 2.2930 (4.7); 2.2726 (2.3); 2.2592 (3.8); 2.2556 (6.5); 2.2520 (3.9); 2.2372 (2.4); 2.2335 (4.1); 2.2300 (2.4); 2.0052 (2.5); 1.9996 (4.3); 1.9941 (2.5); 1.9702 (2.0); 1.9647 (3.5); 1.9591 (2.1); 0.0079 (2.1); -0.0002 (62.8); -0.0085 (2.3)

P-43: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.4903 (0.7); 7.4824 (0.8); 7.4721 (0.8); 7.4638 (0.7); 7.2611 (54.2); 7.1986 (1.6); 7.1928 (1.8);

7.1896 (1.5); 7.1854 (2.3); 7.1822 (2.5); 7.1794 (3.6); 7.1735 (2.1); 7.1696 (1.8); 7.1660 (2.4); 7.1603 (1.8); 6.9359 (0.6); 6.9304 (0.9); 6.9250 (0.8); 6.9195 (0.6); 6.9143 (1.1); 6.9088 (1.8); 6.9034 (1.6);

6.8978 (0.8); 6.8927 (0.6); 6.8872 (0.9); 6.8818 (0.8); 6.0096 (1.8); 6.0013 (1.0); 5.9970 (1.3); 5.9922 (1.6); 5.9874 (1.4); 5.9825 (1.3); 5.9776 (0.8); 5.9581 (1.0); 5.9529 (1.8); 5.9504 (1.3); 5.9449 (1.9);

5.9392 (1.6); 5.9337 (0.8); 5.9311 (1.0); 5.9256 (0.5); 5.2990 (7.0); 4.8212 (0.7); 4.8165 (0.7); 4.8091 (0.7); 4.8037 (0.7); 4.4992 (1.5); 4.4671 (1.7); 4.4609 (2.8); 4.4295 (3.0); 4.4156 (1.9); 4.4056 (1.2);

- 143 044070

4.4014 (1.1); 4.3862 (2.9); 4.3594 (3.0); 4.3479 (1.6); 4.3218 (1.6); 4.0736 (1.9); 4.0649 (2.0); 4.0437 (2.9); 4.0348 (2.8); 4.0140 (0.7); 3.9266 (2.6); 3.9160 (0.9); 3.9114 (2.4); 3.8965 (1.8); 3.8861 (0.6);

3.8814 (1.7); 3.8051 (4.9); 3.8005 (2.4); 3.7963 (4.9); 3.7797 (16.0); 3.7559 (2.5); 3.7374 (15.5); 3.7325 (2.2); 3.7083 (1.2); 3.6880 (2.3); 3.6128 (0.6); 3.6074 (0.7); 3.6010 (0.8); 3.5958 (0.9); 3.5904 (0.9);

3.5846 (0.7); 3.5783 (0.7); 3.5445 (0.7); 3.5395 (2.2); 3.5204 (0.6); 3.5116 (2.0); 3.5002 (0.5); 3.4950 (1.4); 3.4669 (1.5); 2.7727 (0.8); 2.7596 (0.6); 2.7495 (0.6); 2.7439 (0.8); 2.7363 (0.9); 2.7307 (0.7);

2.7208 (0.6); 2.7131 (0.6); 2.7075 (0.9); 2.6843 (0.5); 2.1611 (0.8); 2.1245 (0.8); 2.1203 (0.7); 2.1123 (0.6); 2.1080 (0.8); 2.0715 (0.7); 1.2556 (0.5); 0.0079 (1.0); -0.0002 (30.6); -0.0085 (1.0)

P-44: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9734 (5.0); 7.8730 (2.4); 7.8707 (2.7); 7.8662 (1.8); 7.8532 (2.6); 7.8509 (3.0); 7.8464 (1.8); 7.7827 (2.6); 7.7792 (2.8); 7.7763 (1.5); 7.7632 (3.2); 7.7597 (3.4); 7.7568 (1.8); 7.6099 (2.3); 7.5901 (3.8);

7.5705 (1.7); 7.5181 (0.6); 7.2593 (103.2); 6.9953 (0.5); 6.7782 (0.9); 6.7569 (1.4); 6.7342 (0.7); 5.9912 (1.1); 5.9859 (1.4); 5.9815 (1.4); 5.9773 (1.6); 5.9722 (2.2); 5.9674 (3.6); 5.9641 (8.0); 5.9131 (1.4);

5.9075 (2.6); 5.9020 (1.6); 5.8937 (2.0); 5.8881 (1.1); 5.3761 (1.9); 5.1679 (0.8); 5.1568 (1.1); 5.1473 (1.1); 5.1415 (1.1); 5.1369 (1.2); 5.1317 (1.1); 5.1270 (0.9); 5.1211 (0.6); 5.1169 (0.5); 4.0547 (2.4);

4.0094 (3.3); 3.8011 (7.2); 3.7559 (5.4); 3.6006 (0.8); 3.5948 (0.9); 3.5882 (1.2); 3.5826 (1.3); 3.5790 (1.6); 3.5732 (1.5); 3.5668 (1.6); 3.5607 (1.2); 3.5575 (0.9); 3.5458 (0.7); 2.6516 (0.9); 2.6392 (0.9);

2.6312 (1.0); 2.6188 (1.7); 2.6078 (0.8); 2.6039 (1.2); 2.5959 (1.2); 2.5838 (1.7); 2.5726 (0.7); 2.5634 (0.8); 2.5518 (0.7); 2.0120 (1.0); 2.0018 (1.0); 1.9903 (1.0); 1.9798 (1.2); 1.9770 (1.1); 1.9666 (0.9); 1.9551 (0.9); 1.9445 (1.4); 1.9328 (0.7); 1.9222 (0.7); 1.9092 (0.9); 1.8976 (0.7); 1.8870 (0.6); 1.8757 (0.6); 1.6283 (0.5); 1.5834 (16.0); 1.5719 (15.7); 1.5388 (1.1); 1.2574 (0.8); 1.2397 (0.9); 1.2275 (0.8); 1.1291 (0.7); 1.1071 (0.6); 0.0080 (4.0); -0.0002 (124.2); -0.0084 (4.5)

P-45: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9710 (1.9); 7.9670 (3.2); 7.9628 (3.0); 7.9587 (2.8); 7.9547 (1.8); 7.8978 (1.3); 7.8949 (1.7); 7.8935 (1.6); 7.8909 (2.0); 7.8884 (1.7); 7.8840 (1.2); 7.8780 (1.6); 7.8750 (1.9); 7.8736 (1.9); 7.8710 (2.3);

7.8686 (1.8); 7.8642 (1.3); 7.7642 (1.7); 7.7599 (2.7); 7.7447 (2.2); 7.7407 (3.3); 7.7364 (1.9); 7.6984 (0.7); 7.6770 (0.7); 7.5920 (3.2); 7.5723 (5.0); 7.5526 (2.2); 7.2597 (53.0); 5.9692 (0.7); 5.9640 (1.1);

5.9589 (0.7); 5.9554 (1.2); 5.9503 (1.9); 5.9453 (1.3); 5.9247 (1.3); 5.9219 (1.4); 5.9189 (1.6); 5.9011 (6.6); 5.6102 (1.9); 5.0443 (0.8); 5.0380 (0.8); 5.0181 (0.8); 4.9977 (0.9); 4.0248 (1.7); 4.0204 (1.6);

3.9798 (2.4); 3.9757 (2.2); 3.7858 (4.0); 3.7771 (3.5); 3.7408 (2.8); 3.7321 (2.5); 3.3042 (1.4); 3.2831 (1.6); 2.5012 (0.6); 2.4805 (1.2); 2.4663 (0.8); 2.4597 (0.7); 2.4456 (1.9); 2.4248 (2.0); 2.4106 (0.9);

2.4040 (0.8); 2.3898 (1.5); 2.3691 (0.7); 1.9367 (0.7); 1.9303 (1.7); 1.9238 (1.9); 1.9169 (0.8); 1.9018 (0.6); 1.8953 (1.5); 1.8889 (1.6); 1.8821 (0.7); 1.6171 (10.7); 1.6146 (10.8); 1.5830 (16.0); 0.0080 (2.0); -0.0002 (67.4); -0.0085 (2.3)

P-46: ¹ H-NMR(400.0 MHz, CDC13):

- 144 044070 δ= 7.9420 (2.1); 7.9380 (2.1); 7.8514 (0.7); 7.8487 (1.1); 7.8468 (1.2); 7.8446 (1.0); 7.8423 (0.7); 7.8315 (0.8); 7.8288 (1.2); 7.8270 (1.3); 7.8248 (1.1); 7.8224 (0.7); 7.7281 (0.6); 7.7247 (1.3); 7.7213 (1.3);

7.7180 (0.6); 7.7087 (0.8); 7.7052 (1.6); 7.7019 (1.5); 7.6986 (0.7); 7.5680 (0.9); 7.5667 (1.0); 7.5642 (0.9); 7.5471 (1.6); 7.5445 (1.5); 7.5287 (0.6); 7.5274 (0.7); 7.5249 (0.6); 7.2620 (12.6); 6.7675 (0.7); 6.7470 (0.7); 5.9683 (0.6); 5.9594 (0.7); 5.9543 (1.3); 5.9495 (0.8); 5.9379 (0.8); 5.9339 (1.0); 5.9289 (1.0); 5.9240 (0.7); 5.9201 (0.7); 5.9151 (1.0); 5.9102 (0.8); 5.9063 (0.7); 5.8947 (0.6); 5.8899 (1.1); 5.8847 (0.6); 5.8760 (0.5); 5.3830 (0.6); 5.3638 (0.6); 5.2992 (1.6); 5.0901 (0.5); 5.0850 (0.5); 3.8578 (1.6); 3.8530 (1.4); 3.8145 (1.8); 3.8097 (1.6); 3.5542 (0.6); 3.5485 (0.6); 3.2396 (1.8); 3.2366 (1.8); 3.1962 (1.6); 3.1932 (1.6); 2.5600 (0.5); 2.5393 (0.5); 2.5271 (0.5); 2.5248 (0.6); 1.8574 (0.5); 1.7291 (16.0); 1.7209 (1.5); 1.5788 (8.0); 1.5770 (8.1); 1.5623 (8.6); 1.3049 (0.5); 1.2847 (0.6); -0.0002 (16.2); -0.0085 (0.6)

P-47: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9338 (1.4); 7.9297 (3.2); 7.9254 (3.4); 7.9213 (1.6); 7.8750 (1.0); 7.8719 (1.2); 7.8680 (1.6); 7.8653 (1.4); 7.8610 (1.0); 7.8551 (1.1); 7.8509 (1.4); 7.8482 (1.9); 7.8454 (1.5); 7.8412 (1.0); 7.7081 (1.7);

7.7048 (2.4); 7.7013 (1.7); 7.6887 (2.2); 7.6852 (3.0); 7.6819 (1.9); 7.5487 (2.5); 7.5291 (4.0); 7.5094 (1.7); 7.3762 (0.6); 7.3639 (0.8); 7.3440 (0.7); 7.2618 (18.6); 5.9352 (0.6); 5.9300 (0.9); 5.9248 (0.6); 5.9215 (0.9); 5.9162 (1.6); 5.9111 (1.0); 5.8870 (1.0); 5.8831 (1.1); 5.8775 (1.0); 5.8733 (0.8); 5.8695 (0.8); 5.8561 (5.6); 5.8509 (1.5); 5.7297 (0.8); 5.7031 (0.9); 5.2991 (2.1); 4.9427 (0.9); 4.9334 (0.9); 4.9215 (0.8); 4.9184 (0.7); 4.9127 (0.7); 3.8297 (3.0); 3.8272 (2.7); 3.7866 (3.4); 3.7841 (3.1); 3.3205 (0.5); 3.3102 (0.7); 3.3073 (0.7); 3.2988 (1.0); 3.2887 (1.1); 3.2753 (0.5); 3.2720 (0.5); 3.2228 (2.5); 3.2129 (2.8); 3.1796 (2.2); 3.1697 (2.4); 2.5579 (0.6); 2.5366 (1.1); 2.5231 (0.8); 2.5158 (0.8); 2.5020 (1.3); 2.4960 (1.1); 2.4821 (0.9); 2.4747 (0.6); 2.4613 (1.1); 2.4400 (0.5); 1.9068 (0.6); 1.8969 (1.0); 1.8871 (0.6); 1.8722 (0.5); 1.8623 (1.0); 1.8525 (0.5); 1.8376 (0.5); 1.8276 (1.0); 1.8176 (0.5); 1.7930 (0.9); 1.7830 (0.5); 1.7269 (14.7); 1.7153 (13.4); 1.6140 (15.8); 1.6121 (16.0); 1.5916 (7.0); 1.5707 (6.8); 0.0079 (0.7); -0.0002 (23.8); -0.0085 (0.9)

P-48: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5674 (0.6); 7.5434 (1.0); 7.5200 (0.9); 7.2612 (45.9); 7.1974 (0.6); 7.1922 (2.1); 7.1851 (2.9); 7.1821 (2.4); 7.1791 (2.6); 7.1758 (2.4); 7.1725 (2.7); 7.1697 (2.4); 7.1666 (2.9); 7.1655 (2.8); 7.1595 (2.0); 7.1544 (0.6); 6.9151 (0.9); 6.9093 (1.6); 6.9035 (0.8); 6.8934 (1.8); 6.8876 (3.1); 6.8818 (1.6); 6.8717 (0.9); 6.8658 (1.6); 6.8600 (0.8); 5.9417 (0.6); 5.9366 (1.0); 5.9315 (0.6); 5.9279 (1.1); 5.9227 (1.9); 5.9178 (1.3); 5.9003 (1.2); 5.8949 (1.6); 5.8913 (1.3); 5.8864 (0.8); 5.8774 (7.0); 5.8733 (1.8); 5.6760 (1.1); 5.6592 (1.1); 5.2988 (2.3); 4.9670 (1.0); 4.9596 (1.0); 4.9453 (0.9); 4.9419 (0.9); 4.9389 (1.0); 4.0257 (2.0); 4.0116 (2.0); 3.9957 (4.1); 3.9816 (4.7); 3.9474 (6.1); 3.9176 (2.5); 3.6992 (2.2); 3.6931 (2.0); 3.6553 (3.9); 3.6492 (3.6); 3.5539 (3.8); 3.5499 (3.6); 3.5100 (2.2); 3.5059 (2.0); 3.3135 (0.6); 3.3058 (1.0); 3.2991 (0.9); 3.2925 (1.3); 3.2845 (1.2); 3.2781 (0.8); 2.5298 (0.6); 2.5088 (1.2); 2.4951 (0.8); 2.4877 (0.8); 2.4849 (0.8); 2.4741 (1.3); 2.4638 (1.3); 2.4530 (0.7); 2.4501 (0.9); 2.4428

- 145 044070 (0.7); 2.4290 (1.4); 2.4080 (0.6); 1.9360 (0.6); 1.9272 (1.1); 1.9185 (0.6); 1.9012 (0.5); 1.8925 (1.0); 1.8835 (1.2); 1.8744 (1.2); 1.8654 (0.6); 1.8485 (0.6); 1.8396 (1.1); 1.8307 (0.6); 1.6082 (15.6); 1.6064 (16.0); 1.5858 (2.5); 1.5757 (8.7); 1.5621 (8.5); 0.0079 (0.8); -0.0002 (26.7); -0.0085 (0.9)

P-49: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9778 (4.3); 7.9737 (4.2); 7.8872 (2.8); 7.8701 (2.5); 7.8672 (2.8); 7.7779 (2.3); 7.7750 (2.3); 7.7669 (1.2); 7.7584 (2.8); 7.7554 (2.7); 7.6160 (0.7); 7.6090 (1.7); 7.6051 (1.7); 7.5965 (1.3); 7.5893 (2.8);

7.5854 (2.9); 7.5697 (1.2); 7.5656 (1.5); 7.4731 (0.8); 7.4515 (1.4); 7.4290 (0.9); 7.2616 (25.1); 6.0269 (1.0); 6.0096 (2.4); 6.0047 (2.8); 6.0004 (3.6); 5.9959 (2.2); 5.9859 (1.7); 5.9811 (2.3); 5.9759 (1.2);

5.9672 (1.4); 5.9224 (0.8); 5.2999 (8.0); 4.9617 (1.1); 4.4817 (2.7); 4.4438 (5.5); 4.4162 (2.2); 4.4089 (3.6); 4.4006 (1.1); 4.3707 (1.2); 4.3562 (3.0); 4.3187 (1.7); 4.0943 (1.3); 4.0778 (0.6); 4.0611 (1.4);

4.0 488 (1.8); 4.0318 (1.0); 4.0158 (1.9); 3.8409 (0.6); 3.8217 (1.6); 3.8066 (5.8); 3.7966 (6.2); 3.7861 (16.0); 3.7759 (1.3); 3.7587 (2.1); 3.7506 (2.3); 3.7426 (14.9); 3.5981 (1.1); 3.5928 (1.0); 3.5749 (1.1);

3.1497 (2.1); 3.0019 (1.7); 2.9853 (1.5); 2.7547 (0.7); 2.7322 (1.0); 2.7186 (0.8); 2.7092 (0.6); 2.6953 (1.2); 2.6714 (1.1); 2.6568 (0.6); 2.6484 (0.6); 2.6346 (1.0); 2.1748 (0.5); 2.1650 (0.9); 2.1545 (0.5);

2.1286 (0.9); 2.1176 (0.9); 2.1065 (0.9); 2.0962 (0.5); 2.0805 (0.6); 2.0701 (1.1); 2.0601 (0.7); 2.0464 (0.9); 2.0084 (1.7); 1.6197 (0.8); 1.2596 (0.6); 0.0079 (1.3); -0.0002 (32.2); -0.0083 (1.1)

P-50: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9473 (4.8); 7.8521 (2.7); 7.8332 (2.8); 7.7236 (2.6); 7.7056 (3.1); 7.5659 (2.1); 7.5479 (3.1); 7.5297 (1.6); 7.4110 (2.3); 7.2628 (9.6); 5.9575 (3.2); 5.9172 (3.4); 5.3009 (0.6); 4.7708 (1.8); 4.4562 (1.5);

4.4196 (3.3); 4.3636 (3.3); 4.3253 (1.5); 3.8539 (2.5); 3.8102 (3.2); 3.7623 (14.8); 3.5826 (2.0); 3.2448 (3.1); 3.2016 (2.5); 2.7205 (1.3); 2.6847 (1.6); 2.1275 (1.6); 2.0919 (1.5); 1.9501 (0.6); 1.7317 (16.0);

1.5064 (0.7); 1.2571 (3.7); 0.8572 (1.5); -0.0002 (10.9)

P-51: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9615 (5.2); 7.8558 (3.8); 7.7053 (4.0); 7.5436 (3.6); 7.4247 (3.8); 7.2645 (8.2); 5.9678 (4.4); 5.9162 (4.4); 5.3020 (1.1); 4.7727 (2.8); 4.4788 (1.9); 4.4410 (3.4); 4.3703 (3.5); 3.9090 (2.5); 3.8679 (3.2);

3.7078 (14.1); 3.5852 (3.4); 3.3643 (0.7); 3.2400 (3.1); 3.1968 (2.7); 2.6985 (2.3); 2.0728 (2.5); 1.7380 (16.0); 1.4947 (1.3); 1.2575 (10.2); 0.8679 (4.8); -0.0002 (9.7)

P-52: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.9376 (4.4); 7.8587 (2.3); 7.8381 (2.5); 7.7254 (2.5); 7.7058 (3.0); 7.5681 (2.5); 7.5480 (3.7); 7.5282 (1.7); 7.5193 (1.5); 7.2604 (229.7); 7.1779 (1.6); 6.9963 (1.4); 6.8500 (1.7); 5.9791 (2.0); 5.9229 (1.5);

5.1059 (1.4); 4.3559 (4.3); 4.1853 (0.7); 4.0492 (0.8); 4.0191 (1.3); 3.9349 (1.4); 3.9050 (0.9); 3.8640 (2.6); 3.8205 (3.7); 3.7954 (9.6); 3.6996 (1.4); 3.6862 (2.1); 3.6718 (1.2); 3.5303 (1.2); 3.3670 (3.2);

3.2495 (2.9); 3.2064 (2.6); 2.9122 (0.7); 2.6865 (1.1); 2.6205 (1.4); 2.0075 (1.8); 1.9879 (1.4); 1.7294

- 146 044070 (16.0); 1.6024 (5.1); 1.5640 (4.4); 1.2848 (5.7); 1.2556 (15.0); 0.8802 (5.8); 0.1465 (1.1); 0.0078 (13.4); -0.0002 (286.4); -0.0082 (15.4); -0.1497 (1.3)

P-53: ¹ H-NMR(400.0 MHz, CDC13): δ= 7.9380 (4.9); 7.8611 (2.7); 7.8458 (3.1); 7.7251 (2.7); 7.7092 (3.4); 7.5699 (2.2); 7.5514 (3.2); 7.2607 (80.9); 6.8473 (2.0); 5.9782 (3.8); 5.1087 (1.7); 4.3183 (3.6); 3.8732 (2.0); 3.8288 (2.6); 3.7738 (9.7); 3.7004 (1.9); 3.2452 (2.6); 3.2032 (2.2); 2.6199 (1.5); 1.8699 (1.8); 1.7262 (16.0); 1.5647 (3.4); 1.2579 (11.5); 0.8590 (5.2); -0.0002 (102.1); -0.1500 (1.0)

P-54: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2611 (59.3); 7.1908 (0.5); 7.1825 (2.1); 7.1781 (3.3); 7.1769 (3.1); 7.1726 (3.2); 7.1677 (1.9); 7.1629 (3.3); 7.1586 (3.2); 7.1574 (3.2); 7.1530 (2.0); 6.9392 (0.5); 6.9358 (0.6); 6.9334 (0.9); 6.9301 (1.0); 6.9278 (0.6); 6.9243 (0.5); 6.9175 (1.0); 6.9142 (1.3); 6.9118 (1.9); 6.9085 (1.9); 6.9061 (1.1);

6.9028 (1.0); 6.8959 (0.6); 6.8926 (0.7); 6.8901 (1.0); 6.8869 (1.0); 6.8522 (0.8); 6.8407 (0.9); 6.8320 (0.9); 6.8213 (0.8); 5.9682 (0.6); 5.9634 (0.9); 5.9566 (1.1); 5.9542 (1.7); 5.9495 (3.0); 5.9454 (2.2);

5.9419 (2.6); 5.9385 (3.4); 5.9375 (3.4); 5.9334 (2.6); 5.9236 (0.6); 5.9196 (0.6); 5.9018 (1.2); 5.8964 (2.1); 5.8910 (1.2); 5.8879 (0.8); 5.8825 (1.3); 5.8771 (0.7); 5.3811 (1.4); 5.3699 (1.2); 5.1332 (0.5);

5.1288 (0.8); 5.1240 (0.8); 5.1187 (0.9); 5.1140 (0.9); 5.1083 (1.0); 5.1036 (0.9); 5.0981 (0.9); 5.0935 (0.8); 5.0878 (0.6); 4.0436 (2.5); 4.0261 (2.2); 4.0137 (4.0); 3.9961 (4.0); 3.9362 (3.7); 3.9266 (3.7);

3.9061 (2.0); 3.8966 (2.3); 3.7288 (2.4); 3.7246 (2.2); 3.6847 (3.6); 3.6805 (3.4); 3.5853 (0.6); 3.5795 (0.7); 3.5731 (0.8); 3.5674 (0.8); 3.5633 (1.0); 3.5577 (1.2); 3.5461 (3.7); 3.5391 (1.0); 3.5330 (0.8);

3.5223 (3.5); 3.5019 (1.9); 3.4782 (2.0); 2.6213 (0.7); 2.6090 (0.7); 2.6009 (0.8); 2.5888 (1.2); 2.5863 (1.1); 2.5781 (0.8); 2.5739 (0.9); 2.5690 (0.9); 2.5659 (0.9); 2.5573 (0.9); 2.5543 (1.3); 2.5430 (0.8);

2.5340 (0.7); 2.5224 (0.7); 2.0149 (0.7); 2.0044 (0.7); 1.9930 (0.8); 1.9825 (0.9); 1.9800 (0.8); 1.9694 (0.7); 1.9580 (0.6); 1.9475 (0.6); 1.9160 (0.7); 1.9046 (0.7); 1.8939 (0.7); 1.8821 (1.0); 1.8696 (0.7);

1.8588 (0.6); 1.8475 (0.6); 1.5798 (14.5); 1.5673 (16.0); 0.0079 (1.1); -0.0002 (34.0); -0.0085 (1.2) P-55: Ή-ΉΜΡ(400.6 MHz, CDC13):

δ= 7.8433 (1.2); 7.8393 (2.0); 7.8385 (1.9); 7.8370 (1.9); 7.8346 (1.8); 7.8321 (1.4); 7.8110 (1.4); 7.8075 (2.9); 7.8045 (2.6); 7.8010 (1.2); 7.6898 (1.3); 7.6863 (2.5); 7.6852 (1.8); 7.6826 (1.6); 7.6815 (2.4);

7.6779 (1.1); 7.2634 (13.2); 6.7266 (0.6); 6.7066 (0.6); 5.9660 (0.5); 5.9570 (0.7); 5.9520 (1.4); 5.9476 (0.9); 5.9414 (0.9); 5.9367 (1.2); 5.9326 (0.9); 5.9220 (0.8); 5.9177 (0.9); 5.9164 (0.9); 5.9124 (0.7);

5.8928 (0.7); 5.8876 (1.1); 5.8823 (0.6); 5.8737 (0.6); 5.3904 (0.7); 5.3729 (0.7); 5.3012 (1.8); 3.8426 (1.6); 3.8371 (1.4); 3.7993 (1.8); 3.7938 (1.6); 3.2154 (1.6); 3.2123 (1.7); 3.1721 (1.4); 3.1690 (1.5);

2.5656 (0.8); 2.5451 (0.8); 2.5309 (0.5); 1.8509 (0.6); 1.7308 (16.0); 1.7144 (1.0); 1.5947 (0.9); 1.5795 (8.3); 1.5779 (8.7); 1.5647 (8.5); -0.0002 (16.7); -0.0084 (0.5)

P-56: ¹ H-NMR(400.6 MHz, CDC13):

δ= 7.8646 (1.8); 7.8605 (2.7); 7.8560 (3.8); 7.8521 (2.8); 7.8475 (2.2); 7.8043 (2.1); 7.8006 (3.8); 7.7974 (3.5); 7.7941 (4.0); 7.7904 (2.0); 7.6683 (3.6); 7.6644 (4.4); 7.6599 (3.3); 7.3915 (1.0); 7.3709 (1.0);

- 147 044070

7.2632 (20.5); 5.9377 (0.6); 5.9325 (1.0); 5.9274 (0.6); 5.9239 (1.0); 5.9187 (1.7); 5.9136 (1.1); 5.8898 (1.0); 5.8861 (1.1); 5.8842 (1.1); 5.8804 (1.0); 5.8763 (0.8); 5.8725 (0.8); 5.8665 (0.8); 5.8583 (6.0); 5.8535 (1.6); 5.7132 (0.9); 5.6836 (0.9); 5.3012 (5.0); 4.9472 (0.9); 4.9388 (0.8); 4.9261 (0.9); 4.9234 (0.8); 4.9178 (0.7); 3.8102 (2.9); 3.8071 (2.8); 3.7672 (3.3); 3.7641 (3.3); 3.3159 (0.5); 3.3086 (0.7); 3.3013 (0.5); 3.2944 (1.0); 3.2874 (1.0); 3.2728 (0.5); 3.1981 (2.7); 3.1869 (2.8); 3.1550 (2.4); 3.1438 (2.5); 2.5344 (0.6); 2.5133 (1.2); 2.4997 (0.8); 2.4918 (1.0); 2.4787 (1.2); 2.4700 (1.1); 2.4568 (1.1); 2.4488 (0.6); 2.4353 (1.2); 2.4142 (0.6); 1.9106 (0.6); 1.9015 (1.1); 1.8923 (0.6); 1.8760 (0.6); 1.8669 (1.0); 1.8579 (0.5); 1.8351 (0.6); 1.8260 (1.0); 1.8168 (0.6); 1.7913 (0.9); 1.7821 (0.5); 1.7294 (15.2); 1.7179 (14.6); 1.7117 (1.2); 1.6999 (0.5); 1.6145 (16.0); 1.5940 (7.6); 1.5766 (7.6); 0.0080 (0.7); -0.0002 (25.9); -0.0085 (0.7)

P-57: ¹ H-NMR(400.6 MHz, CDC13):

δ= 7.8503 (1.2); 7.8457 (2.7); 7.8415 (3.1); 7.8368 (1.4); 7.8139 (1.4); 7.8101 (3.4); 7.8063 (3.4); 7.8024 (1.4); 7.6897 (1.3); 7.6860 (2.8); 7.6812 (2.6); 7.6775 (1.3); 7.2631 (20.2); 6.7397 (0.6); 6.7209 (0.7); 6.0096 (0.6); 5.9983 (0.8); 5.9945 (0.8); 5.9844 (1.5); 5.9798 (2.0); 5.9769 (1.6); 5.9749 (1.6); 5.9712 (2.1); 5.9663 (1.5); 5.9605 (0.8); 5.9009 (0.6); 5.8954 (1.1); 5.8900 (0.6); 5.8816 (0.8); 5.1156 (0.5);

5.1103 (0.5); 5.1050 (0.6); 5.1004 (0.5); 4.0504 (2.9); 4.0366 (4.1); 4.0227 (2.8); 3.8464 (1.6); 3.8426 (1.6); 3.8031 (1.8); 3.7993 (1.9); 3.7889 (1.2); 3.7814 (0.5); 3.7749 (1.3); 3.7690 (12.2); 3.7598 (12.0); 3.6643 (0.6); 3.6587 (0.5); 3.2137 (2.7); 3.1704 (2.4); 2.6246 (0.5); 2.6051 (0.6); 2.5933 (0.6); 1.9718 (0.5); 1.8806 (0.6); 1.7334 (16.0); 1.7268 (1.5); 1.7166 (0.9); 0.0080 (0.7); -0.0002 (26.3); -0.0085 (0.8) P-58: ¹ H-NMR(400.6 MHz, CDC13):

δ= 7.8724 (1.6); 7.8684 (2.4); 7.8637 (3.2); 7.8598 (2.3); 7.8550 (1.8); 7.8215 (1.8); 7.8179 (3.1); 7.8140 (2.0); 7.8124 (2.0); 7.8087 (3.1); 7.8050 (1.6); 7.6629 (2.4); 7.6621 (2.3); 7.6583 (3.7); 7.6546 (2.4);

7.6309 (0.6); 7.6183 (0.7); 7.6102 (0.7); 7.5968 (0.6); 7.2646 (15.8); 6.1914 (0.5); 5.9549 (0.5); 5.9461 (0.8); 5.9412 (1.4); 5.9368 (1.0); 5.9288 (1.1); 5.9268 (1.0); 5.9238 (1.0); 5.9211 (0.8); 5.9073 (0.8); 5.8937 (0.8); 5.8908 (0.9); 5.8880 (1.0); 5.8854 (1.0); 5.8737 (0.9); 5.8691 (1.3); 5.8640 (0.8); 5.8552 (0.6); 5.3019 (3.6); 4.9973 (0.7); 4.9895 (0.7); 4.1128 (1.9); 4.1054 (2.0); 4.0997 (2.0); 4.0926 (2.0); 4.0862 (2.7); 4.0733 (2.6); 3.8395 (2.1); 3.8234 (2.2); 3.7965 (2.4); 3.7882 (15.6); 3.7777 (16.0); 3.7630 (0.8); 3.4174 (0.5); 3.4083 (0.7); 3.4037 (0.9); 3.3975 (0.8); 3.3899 (0.6); 3.1884 (2.2); 3.1774 (2.2); 3.1453 (2.0); 3.1344 (1.9); 2.5059 (0.8); 2.4922 (0.6); 2.4713 (0.9); 2.4424 (0.8); 2.4285 (0.6); 2.4078 (0.9); 1.9490 (0.8); 1.9144 (0.7); 1.8723 (0.8); 1.8378 (0.8); 1.7337 (11.7); 1.7184 (11.7); 1.7006 (0.6); 1.6503 (1.0); 0.0080 (0.5); -0.0002 (20.2); -0.0084 (0.6)

P-59: ¹ H-NMR(400.6 MHz, CDC13):

δ= 7.8604 (1.2); 7.8564 (2.2); 7.8515 (2.6); 7.8488 (1.7); 7.8448 (2.5); 7.8407 (2.7); 7.8373 (3.1); 7.8336 (1.4); 7.8263 (2.1); 7.8226 (3.6); 7.8188 (2.0); 7.6932 (0.5); 7.6896 (0.7); 7.6865 (2.2); 7.6825 (3.5); 7.6781 (3.0); 7.6739 (1.5); 7.3462 (0.8); 7.3333 (0.8); 7.3274 (0.7); 7.2630 (22.6); 6.0064 (1.7); 5.9941 (0.7); 5.9889 (0.9); 5.9832 (0.8); 5.9803 (0.8); 5.9753 (1.3); 5.9696 (1.2); 5.9639 (1.2); 5.9589 (0.8);

- 148 044070

5.9301 (1.3); 5.9247 (2.2); 5.9192 (1.2); 5.9163 (0.8); 5.9107 (1.4); 5.9055 (0.8); 5.3014 (13.1); 4.7960 (0.5); 4.7908 (0.6); 4.7836 (0.6); 4.7786 (0.6); 4.7737 (0.5); 4.4997 (1.5); 4.4771 (1.5); 4.4617 (2.8);

4.4397 (2.8); 4.4179 (1.0); 4.4155 (1.0); 4.4051 (1.1); 4.4015 (1.1); 4.3933 (2.9); 4.3781 (2.9); 4.3553 (1.5); 4.3406 (1.5); 3.8942 (1.7); 3.8505 (2.1); 3.8402 (1.8); 3.8188 (0.7); 3.8049 (4.2); 3.7949 (5.2);

3.7784 (15.8); 3.7520 (0.7); 3.7376 (15.3); 3.6771 (0.7); 3.6058 (0.6); 3.5994 (0.6); 3.5937 (0.7); 3.5883 (0.7); 3.5829 (0.6); 3.5767 (0.6); 3.2350 (0.5); 3.2306 (0.6); 3.2231 (1.9); 3.2152 (1.9); 3.1871 (0.6);

3.1794 (1.7); 3.1714 (1.7); 2.7425 (0.7); 2.7302 (0.9); 2.7179 (0.7); 2.7066 (1.0); 2.6947 (0.8); 2.1242 (0.7); 2.0879 (0.6); 2.0718 (0.7); 2.0354 (0.7); 1.7373 (11.8); 1.7345 (16.0); 1.7209 (0.9); 1.7177 (1.0); 0.0079 (0.7); -0.0002 (29.7); -0.0085 (0.8)

P-60: ¹ H-NMR(400.0 MHz, CDC13):

δ= 8.1441 (6.0); 8.1404 (6.6); 8.1340 (6.2); 8.1303 (6.5); 7.9457 (3.9); 7.6763 (1.3); 7.6544 (1.4); 7.2756 (0.6); 7.2643 (13.3); 6.2546 (0.7); 6.1913 (0.7); 5.9576 (0.7); 5.9487 (1.0); 5.9439 (1.7); 5.9398 (1.4);

5.9324 (1.5); 5.9281 (1.4); 5.9089 (0.7); 5.9026 (0.7); 5.8922 (1.2); 5.8886 (1.2); 5.8713 (1.1); 5.8664 (1.5); 5.8616 (1.0); 5.8529 (0.8); 5.8479 (0.6); 5.3016 (10.2); 4.9998 (1.2); 4.1491 (0.7); 4.1310 (1.8);

4.1169 (2.4); 4.1133 (2.6); 4.1067 (2.7); 4.1041 (2.7); 4.0945 (2.9); 4.0858 (4.6); 4.0730 (4.4); 3.9750 (1.6); 3.8752 (2.1); 3.8576 (2.1); 3.8321 (2.3); 3.8145 (2.4); 3.8042 (1.0); 3.7930 (16.0); 3.7847 (15.7);

3.7772 (1.9); 3.4207 (0.8); 3.4060 (1.4); 3.3895 (0.8); 3.2065 (2.3); 3.1934 (2.3); 3.1633 (2.0); 3.1502 (2.0); 2.4898 (0.9); 2.4759 (0.7); 2.4689 (0.6); 2.4549 (1.0); 2.4412 (0.6); 2.4341 (0.6); 2.4204 (0.9);

2.4064 (0.6); 2.3996 (0.6); 2.3857 (1.0); 2.0457 (7.7); 1.9612 (0.6); 1.9545 (1.0); 1.9474 (0.6); 1.9264 (0.6); 1.9199 (0.9); 1.9127 (0.6); 1.8772 (0.6); 1.8705 (1.0); 1.8635 (0.6); 1.8424 (0.5); 1.8359 (0.9);

1.8289 (0.5); 1.7519 (12.0); 1.7363 (11.9); 1.2777 (2.0); 1.2598 (4.1); 1.2420 (2.1); 0.0112 (0.8); 0.0080 (1.0); -0.0002 (17.4); -0.0081 (1.0)

P-61: ¹ H-NMR(400.6 MHz, CDC13):

δ= 8.1254 (5.3); 8.1222 (8.0); 8.1187 (5.1); 7.9784 (1.4); 7.9748 (3.5); 7.9712 (3.3); 7.9675 (1.2); 7.2637 (14.2); 6.7054 (0.5); 6.6983 (0.6); 6.6853 (0.6); 6.6776 (0.5); 5.9596 (0.7); 5.9548 (1.5); 5.9506 (1.0);

5.9461 (1.0); 5.9428 (1.6); 5.9379 (1.2); 5.9330 (0.5); 5.9289 (1.0); 5.9242 (1.1); 5.9193 (0.7); 5.8858 (0.6); 5.8805 (1.1); 5.8752 (0.6); 5.8667 (0.7); 5.3937 (0.7); 5.3758 (0.7); 5.3015 (14.2); 5.0945 (0.5);

5.0892 (0.6); 5.0846 (0.6); 3.8853 (1.5); 3.8787 (1.5); 3.8420 (1.7); 3.8353 (1.7); 3.5653 (0.5); 3.5594 (0.6); 3.5542 (0.6); 3.2328 (1.7); 3.2296 (1.7); 3.1895 (1.5); 3.1862 (1.5); 2.5739 (0.5); 2.5365 (0.5);

1.9438 (0.5); 1.8435 (0.6); 1.7481 (16.0); 1.6125 (0.5); 1.5800 (9.0); 1.5650 (8.6); -0.0002 (19.8); 0.0085 (0.6)

P-62: ¹ H-NMR(400.6 MHz, CDC13):

δ= 8.1314 (6.8); 8.1277 (7.4); 8.1232 (7.1); 8.1194 (7.4); 7.9555 (2.9); 7.9518 (5.3); 7.9481 (2.8); 7.4298 (0.6); 7.4197 (0.7); 7.4083 (0.8); 7.3992 (0.7); 7.2644 (15.4); 5.9439 (0.6); 5.9388 (0.9); 5.9338 (0.6);

5.9302 (0.9); 5.9250 (1.5); 5.9200 (1.0); 5.8953 (0.8); 5.8918 (1.0); 5.8895 (1.0); 5.8860 (1.0); 5.8783 (0.9); 5.8722 (0.7); 5.8598 (4.2); 5.8539 (1.2); 5.6768 (1.4); 5.3019 (16.0); 4.9537 (0.8); 4.9457 (0.7);

- 149 044070

4.9344 (0.8); 4.9281 (0.6); 3.9831 (0.6); 3.9814 (0.6); 3.9773 (1.9); 3.8480 (2.2); 3.8419 (2.4); 3.8049 (2.5); 3.7989 (2.6); 3.3096 (0.6); 3.3065 (0.5); 3.2934 (1.0); 3.2885 (1.0); 3.2802 (0.6); 3.2722 (0.6);

3.2158 (2.4); 3.2028 (2.3); 3.1727 (2.1); 3.1597 (2.0); 2.4928 (0.9); 2.4791 (0.6); 2.4719 (0.5); 2.4628 (0.6); 2.4582 (1.0); 2.4418 (1.0); 2.4374 (0.6); 2.4281 (0.6); 2.4208 (0.6); 2.4071 (1.0); 1.9095 (0.9);

1.8749 (0.8); 1.8272 (1.0); 1.8188 (0.5); 1.7925 (0.9); 1.7841 (0.6); 1.7469 (12.8); 1.7353 (12.8); 1.6183 (13.5); 1.6165 (14.0); 1.5898 (7.1); 1.5823 (7.6); 1.5643 (0.9); 0.0079 (0.5); -0.0002 (20.7); -0.0085 (0.6) P-63: ¹ H-NMR(400.6 MHz, CDC13):

δ= 8.1537 (1.8); 8.1499 (1.9); 8.1461 (0.5); 8.1424 (0.6); 8.1383 (1.9); 8.1346 (1.9); 7.9725 (0.6); 7.9691 (1.2); 7.9658 (1.2); 7.9623 (0.5); 7.2618 (10.4); 5.9727 (0.5); 5.9352 (0.5); 5.9332 (0.5); 5.3011 (16.0);

4.4548 (0.9); 4.4481 (0.8); 4.4143 (0.9); 4.3766 (1.1); 3.8936 (0.6); 3.8751 (0.5); 3.8315 (0.6); 3.8056 (1.1); 3.7947 (1.2); 3.7910 (4.5); 3.7613 (4.6); 3.2406 (0.5); 3.2271 (0.5); 1.7520 (4.8); -0.0002 (13.6)

Analytical data of examples 1H-01-1H-28 (see Table 1.1)

Ш-01: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.5186 (1.1); 7.4156 (0.6); 7.3960 (2.5); 7.3913 (2.0); 7.3836 (4.1); 7.3791 (4.3); 7.3763 (4.7);

7.3703 (4.9); 7.3680 (5.6); 7.2597 (200.4); 7.1603 (0.9); 7.1543 (1.3); 7.1497 (0.8); 7.1422 (1.0);

7.1393 (1.1); 7.1356 (1.2); 7.1307 (1.4); 7.1252 (1.2); 7.1171 (1.2); 7.1095 (0.7); 7.0532 (1.0); 7.0352 (1.0); 6.9957 (1.1); 6.8617 (1.1); 6.8568 (1.5); 6.8351 (1.1); 6.8299 (1.5); 6.8250 (1.1); 4.6414 (0.8);

4.6310 (1.2); 4.6214 (1.4); 4.6113 (1.4); 4.6017 (1.1); 4.5913 (0.7); 3.8286 (2.7); 3.8202 (2.6); 3.7853 (3.1); 3.7769 (3.1); 3.2432 (2.9); 3.2356 (3.0); 3.1999 (2.5); 3.1923 (2.6); 3.0747 (0.7); 3.0638 (0.6);

3.0417 (1.2); 3.0363 (0.9); 3.0216 (1.0); 3.0066 (0.9); 2.9932 (1.0); 2.9875 (1.0); 2.5412 (0.6); 2.5369 (0.6); 2.5311 (0.6); 2.4989 (0.9); 2.4934 (1.0); 2.4694 (0.6); 2.4543 (0.8); 2.4329 (0.6); 2.4266 (0.7);

2.4156 (0.8); 2.3569 (0.6); 1.7191 (16.0); 1.7118 (15.6); 1.2555 (1.5); 0.0080 (2.1); -0.0002 (67.7); 0.0084 (2.2)

Ш-02: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.5187 (1.0); 7.3959 (2.4); 7.3914 (2.0); 7.3835 (4.0); 7.3790 (4.3); 7.3763 (4.9); 7.3703 (5.1);

7.3680 (5.7); 7.2598 (180.1); 7.2100 (0.5); 7.1603 (1.0); 7.1542 (1.3); 7.1496 (0.9); 7.1423 (1.1);

7.1392 (1.1); 7.1356 (1.3); 7.1309 (1.5); 7.1252 (1.3); 7.1170 (1.2); 7.1096 (0.8); 7.0523 (1.0); 7.0406 (1.1); 6.9957 (1.1); 6.8622 (1.1); 6.8570 (1.5); 6.8359 (1.1); 6.8305 (1.5); 6.8255 (1.1); 4.6414 (0.7);

4.6309 (1.2); 4.6215 (1.4); 4.6111 (1.4); 4.6017 (1.1); 4.5913 (0.7); 3.8289 (2.7); 3.8206 (2.6); 3.7856 (3.0); 3.7773 (3.1); 3.2433 (2.9); 3.2357 (2.8); 3.2000 (2.6); 3.1924 (2.6); 3.0626 (0.6); 3.0412 (1.2);

3.0355 (1.0); 3.0209 (0.9); 3.0063 (0.9); 2.9931 (1.0); 2.9868 (1.0); 2.9589 (0.5); 2.9342 (0.5); 2.5463 (0.5); 2.5412 (0.6); 2.5360 (0.6); 2.4987 (0.9); 2.4930 (1.1); 2.4691 (0.7); 2.4641 (0.6); 2.4339 (0.7);

2.4264 (0.7); 2.4157 (0.8); 2.3623 (0.5); 1.7191 (15.6); 1.7118 (16.0); 1.4468 (1.4); 1.4318 (0.6);

1.2553 (1.4); 1.2433 (0.5); 0.0079 (1.9); -0.0002 (62.7); -0.0085 (2.2)

- 150 044070

Ш-03: 1Н-NMR(400.0 MHz, d6-DMS0):

δ= 8.3222 (1.1); 8.3041 (1.1); 7.5252 (2.2); 7.5160 (2.8); 7.4971 (1.8); 7.4908 (1.2); 7.4652 (1.0); 7.4619 (0.8); 7.3384 (0.7); 7.3307 (0.7); 7.3232 (1.0); 7.3175 (0.8); 7.3124 (0.5); 7.2993 (0.6); 6.6795 (0.9); 6.6747 (1.3); 6.6686 (1.0); 6.6634 (0.7); 6.6572 (0.9); 6.6524 (0.5); 4.4258 (0.7); 4.4053 (0.7);

3.7794 (2.4); 3.7356 (2.8); 3.6626 (9.0); 3.6449 (16.0); 3.3703 (2.7); 3.3584 (0.7); 3.3264 (3.1); 3.3086 (119.5); 2.7817 (0.8); 2.7606 (0.8); 2.7449 (0.6); 2.7241 (0.5); 2.6741 (0.8); 2.6695 (1.1); 2.6649 (0.8); 2.5502 (1.1); 2.5229 (5.4); 2.5182 (7.3); 2.5095 (63.0); 2.5050 (127.5); 2.5004 (173.8); 2.4958 (120.3);

2.4913 (55.7); 2.4646 (1.2); 2.4616 (1.3); 2.4559 (1.0); 2.4480 (0.7); 2.4420 (0.6); 2.4195 (0.5); 2.4141 (0.6); 2.4072 (0.6); 2.3319 (0.8); 2.3271 (1.1); 2.3226 (0.8); 1.5450 (7.2); 1.5404 (11.0); 0.0080 (1.1); 0.0002 (32.1); -0.0085 (1.0)

Ш-04: 1Н-NMR(400.0 MHz, d6-DMS0):

δ= 8.3218 (1.0); 8.3041 (1.0); 7.5155 (2.3); 7.4952 (1.5); 7.4647 (1.0); 7.3157 (0.9); 6.6572 (1.6); 3.7787 (2.1); 3.7345 (2.5); 3.6625 (16.0); 3.6449 (4.4); 3.3694 (2.3); 3.3251 (2.5); 3.3088 (186.6); 2.7615 (0.8); 2.6694 (1.2); 2.5228 (4.6); 2.5182 (6.4); 2.5094 (83.3); 2.5049 (176.8); 2.5003 (247.5); 2.4957 (172.4); 2.4912 (79.4); 2.3269 (1.5); 1.5449 (10.8); 0.0080 (1.4); -0.0002 (39.9); -0.0086 (1.2) Ш-05: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.5184 (4.3); 7.3764 (4.6); 7.3675 (5.2); 7.2595 (761.0); 7.1539 (1.5); 7.1301 (1.6); 7.1245 (1.3); 6.9955 (4.7); 6.7228 (2.0); 6.6957 (1.5); 4.6043 (1.3); 4.5942 (1.5); 4.5845 (1.6); 4.5746 (1.6); 4.5644 (1.0); 4.2408 (1.1); 4.2225 (3.3); 4.2025 (3.9); 4.1843 (3.5); 4.1654 (1.2); 3.8201 (2.6); 3.8148 (2.7);

3.7771 (2.8); 3.7714 (3.3); 3.2355 (3.0); 3.2287 (2.7); 3.1921 (2.7); 3.1855 (2.4); 3.0062 (1.2); 2.9651 (1.2); 2.4446 (1.5); 2.4053 (1.2); 1.7137 (13.9); 1.7055 (16.0); 1.5332 (206.1); 1.3216 (4.4); 1.3036 (9.3); 1.3008 (6.2); 1.2857 (5.3); 1.2829 (11.2); 1.2651 (5.3); 0.1462 (1.3); 0.0080 (9.1); -0.0002 (261.5); -0.0085 (7.0); -0.1492 (1.1)

Ш-06: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.5184 (1.5); 7.3955 (2.5); 7.3833 (2.2); 7.3764 (4.2); 7.3723 (4.1); 7.3677 (4.9); 7.3656 (4.5); 7.2880 (0.6); 7.2596 (271.7); 7.1591 (0.8); 7.1535 (1.1); 7.1488 (0.8); 7.1299 (1.5); 7.1241 (0.9);

7.1160 (0.8); 7.1084 (0.6); 7.0045 (0.9); 6.9956 (2.2); 6.9860 (1.0); 6.7229 (1.6); 6.7009 (1.0); 6.6955 (1.4); 6.6904 (1.0); 4.6143 (0.8); 4.6044 (1.3); 4.5945 (1.7); 4.5845 (1.6); 4.5746 (1.4); 4.5645 (0.8);

4.2404 (1.0); 4.2226 (3.3); 4.2047 (3.7); 4.2025 (3.5); 4.1843 (3.3); 4.1663 (1.0); 3.8203 (2.5); 3.8148 (2.8); 3.7770 (2.8); 3.7715 (3.3); 3.2353 (3.0); 3.2286 (2.7); 3.1920 (2.6); 3.1853 (2.4); 3.0311 (0.6);

3.0258 (0.8); 3.0205 (0.7); 3.0112 (0.9); 3.0067 (1.1); 3.0011 (0.8); 2.9838 (0.6); 2.9790 (0.6); 2.9595 (1.1); 2.9461 (0.6); 2.9410 (0.7); 2.5163 (0.6); 2.5110 (0.6); 2.4684 (0.5); 2.4447 (1.2); 2.4055 (0.8); 2.3952 (1.0); 2.3892 (0.6); 2.3562 (0.6); 1.7137 (14.1); 1.7055 (16.0); 1.5347 (49.7); 1.3214 (4.5);

1.3036 (9.7); 1.3007 (5.9); 1.2857 (5.2); 1.2828 (11.0); 1.2650 (5.1); 1.2547 (0.7); 0.0080 (3.2); -0.0002 (101.2); -0.0085 (3.2)

Ш-07: 1Н-NMR(400.0 MHz, CDC13):

- 151 044070 δ= 7.2618 (43.0); 7.1694 (2.0); 7.1666 (2.9); 7.1637 (3.3); 7.1609 (3.2); 7.1497 (3.1); 7.1469 (3.2);

7.1440 (2.9); 7.1412 (2.0); 6.9655 (1.0); 6.9465 (1.0); 6.9114 (0.6); 6.9094 (0.6); 6.9056 (1.0); 6.9036 (1.0); 6.8999 (0.6); 6.8979 (0.5); 6.8897 (1.1); 6.8876 (1.1); 6.8839 (1.9); 6.8819 (1.8); 6.8781 (1.0);

6.8761 (1.0); 6.8680 (0.6); 6.8659 (0.6); 6.8622 (0.9); 6.8602 (0.9); 6.7281 (0.9); 6.7233 (1.5); 6.7192 (1.0); 6.7033 (1.1); 6.6983 (1.4); 6.6930 (1.1); 5.2988 (5.2); 4.6136 (0.8); 4.6037 (1.4); 4.5937 (1.7);

4.5838 (1.7); 4.5737 (1.4); 4.5638 (0.8); 4.2409 (1.1); 4.2232 (4.4); 4.2053 (6.6); 4.1873 (4.3); 4.1693 (1.1); 3.7912 (2.8); 3.7863 (2.8); 3.7480 (3.2); 3.7431 (3.2); 3.2021 (2.8); 3.1958 (3.0); 3.1588 (2.5);

3.1525 (2.6); 3.0337 (0.7); 3.0286 (0.9); 3.0232 (0.7); 3.0193 (0.7); 3.0142 (0.9); 3.0090 (1.1); 3.0039 (0.7); 2.9994 (0.5); 2.9905 (0.6); 2.9874 (0.6); 2.9820 (0.6); 2.9724 (0.5); 2.9671 (1.1); 2.9620 (1.1);

2.9547 (0.6); 2.9481 (0.7); 2.9426 (0.6); 2.5214 (0.5); 2.5161 (0.7); 2.5113 (0.7); 2.5060 (0.5); 2.4737 (0.6); 2.4689 (0.6); 2.4521 (0.6); 2.4449 (1.1); 2.4419 (0.9); 2.4345 (0.9); 2.4053 (0.7); 2.3992 (0.9);

2.3952 (0.9); 2.3891 (0.6); 2.3625 (0.6); 2.3567 (0.6); 2.3156 (0.5); 2.3097 (0.5); 1.7241 (0.6); 1.7143 (16.0); 1.7063 (15.7); 1.5698 (2.4); 1.3216 (5.5); 1.3037 (15.2); 1.2855 (14.9); 1.2675 (5.3); 0.0079 (0.7); -0.0002 (23.7); -0.0085 (0.9)

Ш-08: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.2600 (56.1); 7.1756 (2.2); 7.1721 (2.8); 7.1563 (2.8); 7.1526 (2.3); 6.9242 (0.9); 6.9084 (1.6);

6.8944 (1.1); 6.8923 (1.2); 6.8886 (1.7); 6.8867 (1.6); 6.8829 (1.0); 6.8709 (0.5); 6.8668 (0.8); 6.7312 (1.0); 6.7251 (1.2); 6.7208 (1.3); 6.7149 (1.2); 6.7095 (1.3); 6.7042 (1.0); 6.1885 (1.1); 6.1805 (1.1);

6.1617 (1.2); 6.1537 (1.2); 6.1454 (1.4); 6.1373 (1.3); 6.1186 (1.4); 6.1106 (1.4); 5.5461 (2.2); 5.5402 (2.2); 5.5030 (1.9); 5.4971 (1.8); 5.3537 (2.0); 5.3434 (2.0); 5.3268 (1.9); 5.3166 (1.8); 4.6304 (0.5);

4.6202 (0.9); 4.6085 (1.0); 4.6001 (1.0); 4.5886 (1.0); 4.5784 (0.6); 3.9363 (2.1); 3.9267 (2.2); 3.8934 (2.3); 3.8836 (2.5); 3.7539 (15.2); 3.7418 (16.0); 3.3321 (2.3); 3.3251 (2.3); 3.2890 (2.0); 3.2820 (2.0);

3.0327 (0.6); 3.0276 (0.6); 3.0226 (0.7); 3.0172 (0.6); 3.0124 (0.9); 3.0070 (0.9); 2.9945 (0.7); 2.9738 (0.7); 2.9638 (0.8); 2.9590 (0.7); 2.9531 (0.6); 2.5042 (0.6); 2.4991 (0.6); 2.4741 (0.6); 2.4672 (0.7);

2.4566 (0.6); 2.4336 (1.0); 2.4268 (0.9); 2.4234 (1.0); 2.3890 (0.8); 1.5747 (2.1); 0.0079 (1.4); -0.0002 (40.7); -0.0084(1.8)

Ш-09: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.5184 (1.3); 7.2596 (202.0); 7.2255 (2.5); 7.1914 (3.4); 7.1792 (13.1); 7.1736 (16.0); 7.1627 (10.3);

7.1594 (15.9); 7.1539 (12.9); 7.1415 (2.9); 6.9956 (1.4); 6.9611 (4.2); 6.9481 (4.4); 6.9161 (4.2);

6.9104 (6.5); 6.9047 (4.1); 6.8945 (8.1); 6.8887 (12.2); 6.8829 (7.2); 6.8728 (5.0); 6.8670 (7.9); 6.8612 (6.9); 6.8575 (8.4); 6.8479 (6.3); 6.8425 (6.4); 6.8376 (4.5); 6.7697 (0.8); 6.1941 (5.8); 6.1839 (5.2);

6.1673 (6.4); 6.1570 (6.4); 6.1509 (7.0); 6.1407 (6.4); 6.1241 (7.1); 6.1139 (6.5); 5.6506 (0.7); 5.6076 (0.7); 5.5505 (10.7); 5.5462 (10.9); 5.5074 (9.0); 5.5043 (9.7); 5.4579 (0.8); 5.4315 (0.6); 5.3592 (8.7);

5.3490 (9.3); 5.3324 (8.4); 5.3230 (8.9); 5.2982 (16.0); 4.7429 (0.8); 4.7235 (0.7); 4.7131 (0.6); 4.6652 (1.4); 4.6562 (2.1); 4.6456 (3.8); 4.6335 (4.5); 4.6255 (4.4); 4.6137 (4.2); 4.6031 (2.5); 4.5936 (1.7);

3.9451 (9.2); 3.9340 (10.3); 3.9271 (1.7); 3.9252 (2.5); 3.9239 (1.6); 3.9195 (0.6); 3.9083 (1.6); 3.9020

- 152 044070 (10 .5); 3.8908 (12.0); 3.7542 (1.1); 3.4180 (0.9); 3.3771 (2.1); 3.3621 (1.8); 3.3394 (11.0); 3.3314 (10.4); 3.3189 (2.2); 3.3118 (2.8); 3.2962 (9.6); 3.2882 (8.8); 3.0814 (1.9); 3.0611 (3.1); 3.0496 (5.1);

3.0 292 (5.6); 3.0104 (5.6); 2.9904 (4.7); 2.9740 (2.6); 2.9537 (1.8); 2.5710 (1.2); 2.5214 (3.3); 2.5160 (3.0); 2.4815 (5.8); 2.4746 (5.4); 2.4437 (4.3); 2.4393 (4.5); 2.4286 (4.0); 2.3852 (2.2); 2.3538 (1.1);

2.3450 (0.9); 1.5524 (1.3); 1.5361 (1.3); 1.2560 (2.1); 0.9050 (4.3); 0.9016 (4.6); 0.8893 (4.4); 0.8858 (4.6); 0.1459 (0.9); 0.0080 (9.2); -0.0002 (251.2); -0.0085 (10.8); -0.0499 (1.3); -0.1497 (0.9) Ш-10: 1Н-NMR(599.7 MHz, CDC13):

δ= 7.2876 (0.6); 7.2666 (2.5); 7.2610 (48.2); 7.2400 (0.6); 7.2205 (0.4); 7.1842 (0.3); 7.1568 (15.6);

7.1460 (14.8); 7.0839 (0.3); 6.9510 (5.7); 6.9390 (5.6); 6.8928 (3.9); 6.8786 (7.4); 6.8643 (3.8); 6.7278 (6.5); 6.7032 (6.4); 5.2959 (8.9); 4.5993 (4.0); 4.5926 (4.9); 4.5862 (5.1); 4.5795 (4.4); 4.0394 (2.2);

3.7809 (7.0); 3.7747 (6.9); 3.7562 (39.3); 3.7460 (9.4); 3.7370 (38.2); 3.7173 (1.0); 3.6965 (0.8);

3.6806 (0.6); 3.4847 (3.5); 3.1906 (7.2); 3.1848 (8.5); 3.1619 (6.6); 3.1560 (7.7); 3.0597 (2.0); 3.0464 (2.0); 3.0311 (2.3); 3.0174 (3.5); 3.0013 (3.7); 2.9861 (3.6); 2.9717 (4.0); 2.9559 (3.3); 2.9394 (1.9);

2.9209 (2.2); 2.9080 (2.1); 2.5087 (3.2); 2.4801 (2.9); 2.4376 (5.8); 2.4064 (5.0); 2.3552 (3.2); 2.3239 (2.9); 2.0397 (0.3); 1.9435 (6.9); 1.9225 (7.2); 1.8108 (0.3); 1.7367 (0.3); 1.7101 (45.0); 1.7039 (50.0); 1.6823 (7.8); 1.6077 (4.0); 1.5859 (6.4); 1.3825 (2.2); 1.3621 (6.4); 1.3404 (7.1); 1.3204 (3.0); 1.2594 (3.3); 1.1846 (1.7); 1.1636 (3.6); 1.1431 (3.2); 1.1231 (3.8); 1.1042 (7.1); 1.0858 (6.7); 1.0654 (2.4);

0.8907 (0.8); 0.8807 (1.5); 0.8690 (1.0); -0.0001 (22.5); -0.0218 (0.4)

Ш-11: 1Н-NMR(599.7 MHz, CDC13):

δ= 7.2592 (50.0); 7.1594 (5.5); 7.1482 (5.4); 6.9514 (1.8); 6.9392 (1.8); 6.8931 (1.4); 6.8787 (2.8);

6.8643 (1.4); 6.6923 (2.3); 6.6672 (2.3); 5.2954 (21.2); 5.0969 (0.5); 5.0865 (1.4); 5.0763 (2.0); 5.0662 (2.2); 5.0565 (1.9); 5.0468 (1.3); 5.0365 (0.5); 4.6000 (0.8); 4.5935 (1.3); 4.5870 (1.6); 4.5806 (1.9);

4.5743 (1.6); 4.5678 (1.3); 4.5615 (0.8); 4.0336 (0.5); 3.7792 (3.9); 3.7504 (4.3); 3.5007 (0.8); 3.4835 (1.6); 3.4663 (0.9); 3.1900 (3.0); 3.1842 (3.2); 3.1613 (2.8); 3.1555 (3.0); 3.0528 (0.7); 3.0393 (0.8);

3.0 247 (0.8); 3.0100 (1.2); 2.9909 (1.2); 2.9774 (1.4); 2.9626 (1.2); 2.9445 (1.2); 2.9306 (0.7); 2.9097 (0.8); 2.8992 (0.8); 2.4911 (1.0); 2.4658 (1.0); 2.4233 (1.8); 2.3915 (1.6); 2.3399 (1.0); 2.3069 (0.9);

1.9430 (3.0); 1.9275 (3.2); 1.9222 (3.1); 1.7776 (1.0); 1.7656 (1.0); 1.7128 (19.7); 1.7036 (18.8);

1.6897 (2.9); 1.6829 (3.5); 1.6768 (2.4); 1.6087 (1.8); 1.6019 (1.6); 1.5936 (1.8); 1.5866 (2.2); 1.3827 (1.3); 1.3769 (0.9); 1.3681 (2.8); 1.3625 (3.3); 1.3580 (3.1); 1.3404 (3.8); 1.3260 (1.0); 1.3200 (1.9);

1.3082 (0.8); 1.2818 (13.5); 1.2713 (13.8); 1.2669 (11.4); 1.2613 (10.9); 1.2561 (10.6); 1.2511 (9.8);

1.2366 (0.9); 1.2199 (0.6); 1.2095 (0.6); 1.1849 (1.0); 1.1788 (0.8); 1.1645 (2.0); 1.1439 (1.8); 1.1296 (1.6); 1.1238 (1.8); 1.1087 (3.0); 1.0866 (2.7); 1.0715 (1.0); 1.0656 (1.0); 0.8913 (0.4); 0.8806 (0.6);

0.8685 (0.5); -0.0001 (25.6)

Ш-12: 1Н-NMR(599.7 MHz, CDC13):

δ= 7.4289 (0.4); 7.4021 (1.1); 7.3746 (9.5); 7.3704 (17.8); 7.3606 (10.1); 7.3517 (7.2); 7.3306 (1.5);

7.3239 (1.5); 7.3163 (1.3); 7.3078 (1.5); 7.3030 (1.6); 7.2982 (1.7); 7.2932 (1.9); 7.2884 (1.6); 7.2838

- 153 044070 (1.6); 7.2572 (41.5); 7.1535 (3.0); 7.1439 (2.7); 6.9493 (1.2); 6.9367 (1.1); 6.8913 (0.9); 6.8769 (1.4); 6.8626 (0.7); 6.7722 (1.5); 6.7481 (1.2); 5.2940 (50.0); 5.2216 (0.5); 5.2009 (4.0); 5.1921 (2.0); 5.1829 (3.0); 5.1768 (2.8); 5.1560 (0.4); 4.7023 (9.4); 4.6007 (0.9); 4.5936 (1.0); 4.5874 (0.9); 3.7731 (1.6);

3.7663 (1.6); 3.7443 (1.8); 3.7374 (1.6); 3.4806 (0.8); 3.1838 (1.9); 3.1778 (1.6); 3.1550 (1.6); 3.1491 (1.4); 3.0765 (0.5); 3.0616 (0.6); 3.0446 (0.8); 3.0297 (0.4); 3.0021 (0.8); 2.9748 (0.6); 2.9611 (0.7);

2.9434 (0.4); 2.9253 (0.4); 2.9122 (0.4); 2.5316 (0.6); 2.5031 (0.5); 2.4618 (0.7); 2.4355 (1.2); 2.4032 (0.5); 2.3561 (0.6); 2.3247 (0.5); 1.9480 (1.5); 1.9273 (1.4); 1.7044 (11.1); 1.6976 (10.0); 1.6836 (1.7); 1.6090 (1.4); 1.5870 (1.5); 1.5489 (1.9); 1.3824 (0.6); 1.3626 (1.5); 1.3412 (1.4); 1.3202 (0.7); 1.2579 (0.8); 1.1852 (0.5); 1.1654 (0.8); 1.1443 (0.8); 1.1298 (0.9); 1.1243 (0.9); 1.1094 (1.5); 1.0912 (1.3);

.0719(0.5); -0.0001 (15.1)

Ш-13: 1Н-NMR(400.6 MHz, CDC13):

δ= 7.5195 (1.4); 7.2898 (0.6); 12151 (0.5); 7.2734 (0.7); 7.2709 (0.7); 7.2693 (0.8); 7.2611 (264.4); 7.1805 (2.4); 7.1777 (2.7); 7.1748 (3.4); 7.1720 (2.7); 7.1638 (1.7); 7.1609 (3.4); 7.1583 (2.9); 7.1552 (3.0); 7.1526 (1.5); 6.9974 (1.5); 6.9441 (0.9); 6.9253 (1.0); 6.9179 (1.2); 6.9121 (1.4); 6.9063 (0.7);

6.8962 (1.3); 6.8904 (2.2); 6.8847 (1.2); 6.8746 (0.7); 6.8688 (1.1); 6.8630 (0.6); 6.6986 (1.4); 6.6938 (1.6); 6.6882 (1.6); 6.6823 (0.9); 6.6766 (1.0); 6.6715 (0.7); 6.1900 (2.0); 6.1855 (1.1); 6.1632 (2.3);

6.1587 (1.3); 6.1469 (2.5); 6.1424 (1.4); 6.1201 (2.5); 6.1156 (1.4); 5.5500 (1.9); 5.5487 (2.0); 5.5421 (3.3); 5.5407 (3.3); 5.5069 (1.6); 5.5057 (1.7); 5.4990 (2.8); 5.4976 (2.8); 5.3570 (1.6); 5.3461 (2.9);

5.3448 (2.9); 5.3312 (1.5); 5.3193 (2.7); 5.3181 (2.7); 5.0928 (0.7); 5.0893 (1.0); 5.0772 (1.8); 5.0736 (1.4); 5.0616 (2.4); 5.0581 (1.1); 5.0460 (1.8); 5.0303 (0.7); 4.6133 (0.7); 4.6103 (0.8); 4.6003 (1.2);

4.5934 (0.8); 4.5905 (1.2); 4.5806 (1.2); 4.5705 (0.7); 3.9366 (2.0); 3.9308 (3.7); 3.8936 (2.3); 3.8878 (4.2); 3.3367 (3.6); 3.3303 (2.0); 3.3118 (0.6); 3.2936 (3.1); 3.2872 (1.8); 3.0253 (0.6); 3.0200 (0.6);

3.0151 (0.6); 3.0095 (0.7); 3.0048 (0.8); 3.0001 (0.8); 2.9958 (0.8); 2.9878 (0.8); 2.9824 (0.9); 2.9768 (0.8); 2.9674 (0.9); 2.9615 (0.9); 2.9545 (0.8); 2.9497 (0.6); 2.9350 (0.6); 2.4660 (0.5); 2.4605 (0.8);

2.4562 (0.9); 2.4518 (0.8); 2.4467 (0.6); 2.4236 (0.9); 2.4199 (1.4); 2.4132 (1.2); 2.4098 (1.3); 2.3725 (0.9); 2.3661 (0.8); 2.3624 (0.5); 1.6425 (5.8); 1.2844 (5.8); 1.2810 (5.8); 1.2731 (11.2); 1.2691 (16.0); 1.2655 (6.9); 1.2575 (10.9); 1.2536 (10.8); 1.2247 (0.7); 1.2092 (0.7); 0.0080 (3.5); -0.0002 (135.6); 0.0085 (4.1)

Ш-14: 1Н-NMR(599.7 MHz, CDC13):

δ= 7.2575 (50.0); 7.1688 (2.7); 7.1576 (2.6); 6.9144 (1.0); 6.9013 (0.9); 6.8862 (1.3); 6.8719 (0.7);

6.7941 (1.5); 6.7814 (0.7); 6.1771 (0.7); 6.1594 (0.8); 6.1489 (1.0); 6.1305 (0.8); 5.5373 (1.7); 5.5086 (1.5); 5.3510 (0.7); 5.3409 (1.6); 5.3230 (1.5); 4.6102 (0.8); 4.4145 (0.7); 4.4029 (2.4); 4.3923 (3.2);

4.3833 (1.5); 3.9288 (0.7); 3.9208 (1.5); 3.9000 (0.7); 3.8921 (1.7); 3.7251 (0.7); 3.7136 (2.7); 3.7038 (3.5); 3.6941 (1.6); 3.3250 (1.7); 3.2964 (1.5); 3.0474 (0.7); 3.0338 (0.6); 3.0182 (1.0); 3.0051 (1.0);

- 154 044070

2.9844 (0.7); 2.9719 (0.7); 2.5126 (0.3); 2.4826 (1.0); 2.4440 (0.8); 2.4063 (0.9); 1.5549 (3.5); -0.0001 (16.1)

Ш-15: 1Н-NMR(599.7 MHz, CDC13):

δ= 7.2939 (0.3); 7.2832 (0.4); 7.2721 (0.4); 7.2575 (50.0); 7.2487 (0.4); 7.1705 (1.9); 7.1586 (1.9);

7.0806 (0.3); 6.8988 (1.0); 6.8840 (1.1); 6.8695 (0.5); 6.7628 (1.0); 6.7465 (0.8); 6.1751 (0.6); 6.1675 (0.5); 6.1573 (0.7); 6.1465 (0.8); 6.1387 (0.5); 6.1285 (0.7); 6.1208 (0.6); 5.5407 (1.1); 5.5341 (1.4);

5.5118 (1.0); 5.5053 (1.2); 5.3472 (1.0); 5.3368 (1.3); 5.3294 (1.0); 5.3190 (1.3); 4.6222 (0.3); 4.6153 (0.5); 4.6087 (0.7); 4.6021 (0.8); 4.5955 (0.7); 4.5891 (0.6); 4.5823 (0.4); 4.3069 (1.2); 4.3026 (1.7);

4.2954 (2.0); 4.2904 (1.4); 4.2833 (0.8); 3.9256 (1.0); 3.9174 (1.3); 3.8970 (1.1); 3.8887 (1.5); 3.6408 (1.1); 3.6326 (2.0); 3.6296 (1.9); 3.6216 (2.5); 3.6137 (1.4); 3.3960 (6.8); 3.3843 (8.7); 3.3218 (1.5);

3.3144 (1.1); 3.2931 (1.3); 3.2857 (1.1); 3.0420 (0.5); 3.0287 (0.5); 3.0110 (0.3); 2.9976 (0.6); 2.9642 (0.5); 2.9513 (0.5); 2.5103 (0.3); 2.4824 (0.7); 2.4548 (0.4); 2.4230 (0.4); 2.3885 (0.6); 2.3522 (0.3); 0.0001 (25.2)

Ш-16: 1Н-NMR(599.7 MHz, CDC13):

δ= 7.2579 (50.0); 7.1702 (2.2); 7.1602 (2.1); 6.8984 (1.1); 6.8836 (1.3); 6.8692 (0.6); 6.7563 (1.2);

6.7404 (0.8); 6.1765 (0.8); 6.1684 (0.5); 6.1586 (0.8); 6.1478 (1.0); 6.1396 (0.6); 6.1298 (0.9); 6.1216 (0.6); 5.5409 (1.2); 5.5348 (1.7); 5.5121 (1.1); 5.5060 (1.6); 5.3469 (1.2); 5.3371 (1.6); 5.3290 (1.1);

5.3192 (1.6); 4.6225 (0.3); 4.6156 (0.6); 4.6093 (0.7); 4.6026 (0.9); 4.5961 (0.8); 4.5895 (0.7); 4.5827 (0.4); 4.3071 (0.8); 4.3043 (0.7); 4.2993 (1.3); 4.2955 (1.9); 4.2880 (2.3); 4.2828 (1.7); 4.2753 (0.9);

3.9271 (1.2); 3.9182 (1.6); 3.8984 (1.3); 3.8896 (1.8); 3.6774 (1.2); 3.6690 (2.2); 3.6658 (2.1); 3.6575 (3.1); 3.6495 (1.7); 3.5637 (0.6); 3.5519 (2.7); 3.5402 (4.4); 3.5285 (3.2); 3.5168 (0.9); 3.3220 (1.7);

3.3146 (1.2); 3.2933 (1.6); 3.2859 (1.1); 3.0388 (0.6); 3.0254 (0.6); 3.0077 (0.4); 2.9972 (0.6); 2.9648 (0.6); 2.9519 (0.5); 2.5043 (0.4); 2.4795 (0.8); 2.4763 (0.8); 2.4517 (0.4); 2.4224 (0.5); 2.3882 (0.7);

2.3528 (0.3); 1.5720 (1.6); 1.2274 (1.8); 1.2155 (6.0); 1.2035 (6.9); 1.1918 (2.7); -0.0001 (16.3)

Ш-17: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.5181 (2.9); 7.3094 (1.6); 7.2592 (503.4); 7.2480 (3.3); 7.2092 (0.8); 7.1764 (3.7); 7.1708 (4.3);

7.1568 (4.5); 6.9953 (2.7); 6.9076 (2.7); 6.8921 (2.0); 6.8863 (2.8); 6.8645 (1.5); 6.7114 (1.8); 6.7050 (1.8); 6.6998 (2.2); 6.6946 (1.6); 6.2184 (1.8); 6.1893 (1.7); 6.1829 (2.0); 6.1625 (1.8); 6.1562 (2.4);

6.1462 (1.9); 6.1397 (2.4); 6.1193 (2.0); 6.1130 (2.5); 5.8282 (2.1); 5.5474 (3.7); 5.5418 (2.8); 5.5042 (3.3); 5.4987 (2.4); 5.3541 (3.3); 5.3439 (2.4); 5.3279 (3.1); 5.3159 (2.3); 4.6282 (1.1); 4.6175 (1.8);

4.6076 (1.5); 4.5978 (1.8); 4.5872 (1.3); 4.5757 (0.8); 4.2370 (1.9); 4.2192 (5.6); 4.2072 (4.1); 4.2014 (6.0); 4.1895 (4.1); 4.1837 (2.1); 4.1718 (1.4); 3.9366 (3.7); 3.9287 (3.0); 3.8935 (4.3); 3.8855 (3.3);

3.7938 (12.5); 3.3318 (3.0); 3.3252 (3.9); 3.2887 (2.7); 3.2821 (3.3); 3.0645 (0.8); 3.0227 (1.2); 3.0079 (1.2); 3.0018 (1.2); 2.9746 (1.3); 2.9078 (0.7); 2.5006 (1.0); 2.4629 (1.2); 2.4195 (1.4); 2.3765 (1.2);

2.3412 (0.8); 1.5342 (10.7); 1.4033 (5.8); 1.3871 (5.8); 1.3825 (1.2); 1.3285 (0.7); 1.3175 (7.6); 1.3105 (2.0); 1.3056 (6.3); 1.2997 (16.0); 1.2878 (11.9); 1.2819 (8.0); 1.2699 (5.6); 0.9005 (1.0); 0.8851 (1.1);

- 155 044070

0.1461 (1.1); 0.1032 (1.1); 0.0985 (0.9); 0.0955 (0.7); 0.0919 (1.1); 0.0775 (1.2); 0.0696 (0.8); 0.0501 (0.9); 0.0080 (10.3); -0.0002 (282.2); -0.0085 (10.1); -0.1493 (1.0)

Ш-18: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.3780 (11.2); 7.3749 (8.0); 7.3668 (35.5); 7.3558 (31.0); 7.3483 (6.7); 7.3397 (6.1); 7.3342 (2.8);

7.3319 (3.4); 7.3289 (2.6); 7.3268 (3.4); 7.3184 (2.6); 7.3116 (1.1); 7.3056 (0.9); 7.2593 (73.6); 7.1854 (1.4); 7.1727 (6.9); 7.1675 (8.7); 7.1567 (5.6); 7.1527 (8.4); 7.1478 (6.6); 7.1411 (1.1); 7.1353 (1.2);

6.9330 (2.4); 6.9112 (3.7); 6.9070 (4.0); 6.9011 (2.0); 6.8909 (3.0); 6.8894 (3.1); 6.8851 (5.1); 6.8837 (4.9); 6.8793 (2.7); 6.8692 (1.6); 6.8678 (1.6); 6.8634 (2.5); 6.8577 (1.3); 6.7818 (1.0); 6.7757 (2.8);

6.7698 (3.4); 6.7656 (3.8); 6.7597 (3.0); 6.7547 (3.6); 6.7496 (2.6); 6.7434 (0.9); 6.1840 (3.8); 6.1750 (3.7); 6.1572 (4.3); 6.1482 (4.2); 6.1409 (4.6); 6.1318 (4.4); 6.1141 (4.6); 6.1050 (4.4); 5.5416 (6.5);

5.5402 (6.8); 5.5369 (6.6); 5.5354 (6.5); 5.4984 (5.7); 5.4971 (5.8); 5.4938 (5.8); 5.4923 (5.5); 5.3479 (5.7); 5.3467 (5.6); 5.3400 (5.8); 5.3387 (5.5); 5.3211 (5.3); 5.3200 (5.2); 5.3132 (5.3); 5.3119 (5.1);

5.2164 (0.9); 5.1963 (16.0); 5.1853 (13.2); 5.1817 (13.0); 5.1681 (0.5); 5.1650 (0.5); 5.1505 (0.7);

5.1168 (0.5); 4.6412 (0.9); 4.6317 (1.4); 4.6213 (2.7); 4.6096 (2.8); 4.6012 (2.9); 4.5898 (2.6); 4.5795 (1.4); 4.5699 (0.9); 3.9311 (6.4); 3.9209 (6.5); 3.8880 (7.2); 3.8778 (7.5); 3.3337 (1.9); 3.3292 (6.9);

3.3222 (6.6); 3.2861 (6.0); 3.2791 (5.6); 3.2730 (0.8); 3.2507 (0.5); 3.0967 (1.0); 3.0917 (1.1); 3.0767 (1.1); 3.0713 (1.3); 3.0652 (1.4); 3.0596 (1.6); 3.0543 (1.7); 3.0494 (1.7); 3.0444 (1.7); 3.0395 (1.6);

3.0342 (1.6); 3.0288 (1.5); 3.0229 (1.5); 3.0165 (1.9); 3.0079 (1.3); 3.0026 (1.5); 2.9969 (1.9); 2.9884 (1.0); 2.9799 (1.1); 2.9733 (1.2); 2.9669 (1.5); 2.9608 (1.8); 2.9553 (1.4); 2.9477 (1.3); 2.9417 (1.2);

2.9329 (1.2); 2.9275 (1.1); 2.9184 (0.6); 2.9129 (1.0); 2.9076 (1.0); 2.5323 (1.2); 2.5271 (1.5); 2.5222 (1.6); 2.5167 (1.3); 2.5018 (1.4); 2.4967 (1.6); 2.4909 (2.2); 2.4859 (2.0); 2.4799 (1.6); 2.4745 (1.1);

2.4599 (1.1); 2.4550 (1.4); 2.4492 (1.5); 2.4444 (1.5); 2.4375 (1.3); 2.4325 (1.3); 2.4261 (1.4); 2.3942 (1.8); 2.3884 (2.2); 2.3841 (2.2); 2.3781 (1.6); 2.3518 (0.9); 2.3468 (1.2); 2.3413 (1.2); 2.3366 (0.8);

1.7792 (0.7); 0.8777 (0.5); 0.0079 (3.0); -0.0002 (93.3); -0.0085 (3.0)

Ш-19: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.2609 (16.0); 7.2019 (1.8); 7.1992 (2.5); 7.1963 (2.6); 7.1938 (2.3); 7.1830 (2.5); 7.1803 (2.5);

7.1775 (2.0); 7.1747 (1.3); 6.9733 (1.0); 6.9676 (1.1); 6.9619 (0.8); 6.9518 (1.0); 6.9460 (1.6); 6.9404 (1.0); 6.9245 (1.0); 6.9188 (0.9); 6.7538 (0.7); 6.7475 (1.1); 6.7430 (0.6); 6.7266 (0.7); 6.7216 (0.9);

6.7162 (0.7); 5.2988 (8.3); 4.6740 (0.8); 4.6636 (0.9); 4.6539 (0.9); 4.6436 (0.8); 4.6337 (0.5); 3.9905 (1.2); 3.9436 (1.3); 3.9404 (1.3); 3.7649 (16.0); 3.7612 (3.9); 3.7529 (14.0); 3.7417 (0.6); 3.7297 (1.0);

3.7199 (1.6); 3.7160 (1.6); 3.6852 (0.8); 3.0616 (0.6); 3.0562 (0.8); 3.0367 (0.6); 3.0165 (0.6); 3.0128 (0.6); 2.9971 (0.8); 2.9930 (0.6); 2.5182 (0.7); 2.5140 (0.7); 2.5083 (0.8); 2.4801 (0.6); 2.4748 (0.5);

2.4707 (0.5); 2.4382 (0.7); 2.4344 (0.7); 2.4281 (0.5); 1.4321 (2.7); 0.0079 (0.6); -0.0002 (20.5); 0.0085 (0.8)

Ш-20: 1Н-NMR(400.0 MHz, CDC13):

- 156 044070 δ= 7.2600 (12.6); 7.1697 (0.7); 7.1663 (1.0); 7.1635 (0.9); 7.1605 (1.1); 7.1561 (0.7); 7.1499 (1.0); 7.1465 (0.9); 7.1441 (0.8); 7.1408 (0.6); 6.8666 (0.6); 3.8038 (0.5); 3.7982 (0.6); 3.7963 (0.6); 3.7605 (0.6); 3.7549 (0.7); 3.7532 (0.7); 3.7479 (0.5); 3.1958 (0.8); 3.1913 (0.5); 3.1525 (0.7); 1.7219 (2.9); 1.7151 (4.3); 1.7072 (2.6); 1.5457 (0.6); 1.4790 (10.7); 1.4408 (16.0); 1.4257 (11.4); -0.0002 (14.6); 0.0085 (0.6)

Ш-21: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.2595 (81.0); 7.1805 (0.7); 7.1699 (2.5); 7.1677 (3.0); 7.1643 (3.6); 7.1620 (3.4); 7.1503 (3.2); 7.1481 (3.5); 7.1446 (2.9); 7.1425 (2.2); 7.1321 (0.5); 6.9955 (0.5); 6.9725 (1.1); 6.9537 (1.1); 6.9115 (0.7); 6.9055 (1.1); 6.9015 (0.7); 6.8914 (1.2); 6.8896 (1.4); 6.8857 (2.0); 6.8839 (2.0); 6.8799 (1.2); 6.8680 (0.7); 6.8639 (1.0); 6.8581 (0.6); 6.8074 (1.7); 6.7945 (0.6); 6.7881 (1.1); 6.7830 (1.5); 6.7780 (1.1); 4.6250 (0.8); 4.6146 (1.2); 4.6053 (1.4); 4.5948 (1.5); 4.5855 (1.2); 4.5750 (0.8); 4.5390 (0.5);

4.5244 (0.7); 4.4253 (2.9); 4.4112 (3.9); 4.4088 (3.0); 4.4000 (1.2); 4.3966 (3.9); 4.3938 (3.4); 4.3916 (2.8); 4.3782 (2.3); 3.7881 (3.0); 3.7829 (2.8); 3.7714 (0.8); 3.7567 (0.7); 3.7534 (0.7); 3.7448 (3.4); 3.7395 (4.2); 3.7377 (4.6); 3.7230 (4.6); 3.7198 (4.4); 3.7088 (4.4); 3.7051 (4.7); 3.6910 (3.3); 3.2049 (2.9); 3.1987 (3.0); 3.1616 (2.5); 3.1554 (2.6); 3.0750 (0.6); 3.0553 (1.2); 3.0485 (0.8); 3.0358 (1.0);

3.0162 (0.6); 3.0118 (0.7); 3.0062 (1.1); 2.9920 (1.1); 2.9874 (1.2); 2.9730 (0.7); 2.9683 (0.7); 2.5420 (0.6); 2.5369 (0.7); 2.5320 (0.7); 2.5269 (0.6); 2.4945 (0.6); 2.4897 (0.6); 2.4838 (0.6); 2.4689 (1.1);

2.4628 (1.0); 2.4582 (0.9); 2.4289 (0.8); 2.4245 (0.8); 2.4183 (1.1); 2.4142 (0.8); 2.3894 (0.6); 2.3836 (0.6); 1.7768 (0.6); 1.7257 (1.8); 1.7151 (16.0); 1.7074 (15.4); 1.5369 (6.1); 1.4511 (3.8); 0.0080 (3.5); -0.0002 (105.7); -0.0085 (3.4)

Ш-22: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.2611 (21.8); 7.2160 (0.6); 7.2136 (0.7); 7.2031 (3.1); 7.2005 (4.1); 7.1974 (4.8); 7.1949 (4.4); 7.1840 (4.4); 7.1815 (4.7); 7.1784 (3.9); 7.1759 (2.8); 7.1652 (0.5); 6.9719 (2.0); 6.9663 (2.5); 6.9607 (1.7); 6.9503 (2.1); 6.9448 (3.2); 6.9392 (1.7); 6.9293 (1.1); 6.9234 (1.6); 6.9177 (0.8); 6.7486 (0.6); 6.7430 (1.5); 6.7367 (2.0); 6.7284 (0.7); 6.7210 (0.6); 6.7149 (1.5); 6.7097 (2.0); 6.7046 (1.5); 5.2986 (8.4); 4.6911 (0.6); 4.6812 (1.1); 4.6712 (2.0); 4.6613 (2.2); 4.6514 (2.4); 4.6414 (1.8); 4.6316 (1.2);

4.6216 (0.6); 4.2468 (1.6); 4.2347 (1.8); 4.2292 (5.2); 4.2171 (5.4); 4.2114 (5.6); 4.1993 (5.8); 4.1936 (2.1); 4.1814 (2.2); 3.9868 (2.2); 3.9416 (3.3); 3.7650 (4.7); 3.7614 (4.9); 3.7198 (3.2); 3.7162 (3.4); 3.1176 (0.6); 3.1126 (0.6); 3.0977 (0.6); 3.0925 (0.6); 3.0750 (0.7); 3.0699 (0.8); 3.0604 (0.8); 3.0553 (1.5); 3.0502 (1.2); 3.0449 (0.7); 3.0334 (1.0); 3.0174 (0.6); 3.0137 (1.0); 3.0088 (0.8); 3.0033 (0.9);

2.9980 (1.3); 2.9937 (1.5); 2.9785 (0.7); 2.9727 (0.6); 2.9510 (0.6); 2.9456 (0.6); 2.9312 (0.6); 2.9259 (0.6); 2.5578 (0.7); 2.5526 (0.9); 2.5478 (0.9); 2.5425 (0.7); 2.5190 (0.8); 2.5147 (1.5); 2.5103 (1.5);

2.5049 (1.5); 2.5004 (0.9); 2.4773 (1.4); 2.4736 (1.3); 2.4676 (1.2); 2.4635 (0.9); 2.4424 (0.6); 2.4358 (1.0); 2.4318 (1.4); 2.4263 (1.4); 2.4217 (1.0); 2.3899 (0.5); 2.3852 (0.7); 2.3794 (0.7); 1.3237 (7.5); 1.3139 (7.4); 1.3059 (16.0); 1.2961 (15.1); 1.2881 (7.9); 1.2783 (7.3); 1.2717 (0.8); 1.2680 (0.9); 1.2646 (1.1); 1.2556 (1.9); 1.2468 (0.5); 0.0080 (0.7); -0.0002 (26.3); -0.0085 (1.0)

- 157 044070

Ш-23: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.5185 (0.5); 7.2596 (87.9); 7.2026 (3.1); 7.1998 (4.2); 7.1969 (4.9); 7.1941 (4.8); 7.1836 (4.7); 7.1808 (4.7); 7.1780 (4.3); 7.1751 (3.1); 6.9955 (0.8); 6.9718 (1.9); 6.9671 (2.6); 6.9613 (1.9); 6.9513 (2.6); 6.9454 (3.4); 6.9397 (2.0); 6.9299 (1.3); 6.9240 (1.6); 6.9184 (1.0); 6.7161 (1.4); 6.7102 (2.0);

6.6890 (1.3); 6.6839 (1.7); 6.6787 (1.3); 5.2984 (2.4); 5.1143 (0.7); 5.0986 (1.7); 5.0830 (2.5); 5.0694 (2.8); 5.0538 (2.1); 5.0381 (1.0); 4.6751 (0.9); 4.6644 (1.4); 4.6556 (1.6); 4.6454 (1.6); 4.6361 (1.3);

4.6264 (0.9); 3.9857 (2.5); 3.9570 (0.6); 3.9403 (3.6); 3.7635 (4.3); 3.7600 (4.4); 3.7510 (0.9); 3.7461 (1.1); 3.7347 (1.7); 3.7183 (3.0); 3.7148 (3.2); 3.7061 (0.6); 3.7010 (0.7); 3.1089 (0.5); 3.1037 (0.5);

3.0887 (0.6); 3.0835 (0.5); 3.0662 (0.6); 3.0609 (0.8); 3.0462 (1.6); 3.0262 (1.1); 3.0067 (1.1); 2.9963 (0.9); 2.9872 (1.4); 2.9790 (0.9); 2.9708 (0.6); 2.9650 (0.5); 2.9432 (0.6); 2.9379 (0.6); 2.9233 (0.6);

2.9183 (0.6); 2.5372 (0.8); 2.5324 (0.8); 2.5275 (0.6); 2.5001 (1.4); 2.4957 (1.3); 2.4902 (1.3); 2.4619 (1.3); 2.4194 (1.3); 2.4138 (1.2); 2.3726 (0.7); 1.7120 (0.5); 1.5828 (0.6); 1.3639 (0.7); 1.3481 (0.9);

1.2881 (14.6); 1.2813 (13.4); 1.2768 (14.2); 1.2727 (16.0); 1.2657 (14.0); 1.2614 (12.0); 1.2524 (2.7); 1.2489 (2.3); 1.2419 (1.5); 1.2302 (1.5); 1.2261 (1.2); 1.2184 (0.9); 0.0080 (2.9); -0.0002 (107.2); 0.0084 (4.6)

Ш-24: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.2598 (60.4); 7.2025 (2.2); 7.2002 (2.8); 7.1969 (3.5); 7.1947 (3.1); 7.1836 (3.0); 7.1813 (3.4); 7.1779 (2.7); 6.9957 (0.8); 6.9739 (1.5); 6.9682 (1.9); 6.9624 (1.3); 6.9525 (1.7); 6.9467 (2.5); 6.9410 (1.4); 6.9310 (0.8); 6.9250 (1.2); 6.9193 (0.7); 6.8287 (1.0); 6.8228 (1.4); 6.7989 (1.0); 6.7938 (1.4);

6.7888 (1.0); 4.6948 (0.6); 4.6841 (1.0); 4.6775 (1.0); 4.6744 (0.9); 4.6674 (1.0); 4.6642 (1.0); 4.6578 (0.9); 4.6479 (0.6); 4.5686 (12.9); 4.5541 (15.8); 4.5523 (9.8); 4.5393 (13.9); 4.4313 (2.0); 4.4194 (4.8); 4.4057 (3.8); 4.4032 (4.7); 4.3912 (3.1); 3.9874 (1.7); 3.9415 (2.4); 3.9301 (0.7); 3.7889 (14.0); 3.7759 (10.1); 3.7741 (16.0); 3.7669 (4.1); 3.7628 (4.7); 3.7597 (13.4); 3.7396 (3.3); 3.7298 (3.9);

3.7250 (4.6); 3.7219 (3.4); 3.7177 (4.8); 3.7155 (4.4); 3.7110 (3.7); 3.7013 (3.1); 3.1003 (0.5); 3.0953 (0.6); 3.0803 (1.2); 3.0602 (0.8); 3.0547 (0.7); 3.0410 (0.8); 3.0312 (0.6); 3.0253 (0.8); 3.0211 (1.1);

3.0071 (0.9); 2.5750 (0.7); 2.5698 (0.6); 2.5643 (0.5); 2.5360 (0.9); 2.5321 (1.1); 2.5263 (0.9); 2.5219 (0.7); 2.4985 (0.9); 2.4942 (0.8); 2.4883 (0.7); 2.4601 (0.9); 2.4547 (1.0); 1.5359 (5.9); 0.0080 (2.4); 0.0002 (74.2); -0.0085 (2.5)

Ш-25: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.3806 (8.4); 7.3774 (6.2); 7.3694 (24.6); 7.3599 (21.6); 7.3515 (4.5); 7.3425 (4.2); 7.3353 (2.9); 7.3315 (2.0); 7.3293 (2.3); 7.3243 (1.4); 7.3221 (1.7); 7.3172 (0.9); 7.3145 (1.0); 7.3078 (0.6); 7.2586 (30.8); 7.2082 (1.0); 7.2023 (1.1); 7.1952 (5.0); 7.1905 (6.5); 7.1800 (4.3); 7.1759 (6.3); 7.1713 (4.9);

7.1643 (0.9); 7.1582 (0.9); 6.9681 (2.9); 6.9623 (3.5); 6.9568 (2.5); 6.9465 (2.9); 6.9408 (4.6); 6.9351 (2.4); 6.9250 (1.5); 6.9192 (2.2); 6.9136 (1.2); 6.8010 (0.7); 6.7950 (2.0); 6.7902 (2.4); 6.7847 (2.1);

6.7711 (0.7); 6.7650 (1.9); 6.7598 (2.6); 6.7548 (1.9); 6.7487 (0.7); 5.3025 (0.6); 5.2965 (12.6); 5.2380 (0.6); 5.2069 (9.3); 5.2033 (9.2); 5.1905 (16.0); 5.1722 (0.6); 4.6924 (0.7); 4.6833 (1.3); 4.6727 (2.0);

- 158 044070

4.6637 (2.4); 4.6534 (2.3); 4.6441 (1.9); 4.6341 (1.2); 4.6245 (0.6); 3.9815 (2.3); 3.9757 (2.4); 3.9363 (3.3); 3.9304 (3.5); 3.7588 (6.6); 3.7556 (6.4); 3.7136 (4.5); 3.7104 (4.4); 3.1428 (0.7); 3.1379 (0.7);

3.1228 (0.8); 3.1177 (0.8); 3.1002 (0.9); 3.0952 (0.9); 3.0899 (0.7); 3.0847 (1.1); 3.0797 (1.5); 3.0748 (1.2); 3.0699 (0.8); 3.0643 (1.2); 3.0595 (1.2); 3.0506 (0.6); 3.0419 (1.6); 3.0368 (1.6); 3.0274 (0.5);

3.0215 (1.0); 3.0156 (1.3); 3.0084 (1.2); 3.0025 (1.1); 2.9959 (1.2); 2.9888 (1.1); 2.9827 (0.8); 2.9767 (0.7); 2.9549 (0.8); 2.9497 (0.8); 2.9350 (0.8); 2.9298 (0.7); 2.5837 (0.9); 2.5785 (1.1); 2.5735 (1.1);

2.5682 (0.9); 2.5410 (1.6); 2.5361 (2.0); 2.5311 (2.0); 2.5261 (1.5); 2.4989 (0.9); 2.4932 (1.0); 2.4899 (1.6); 2.4846 (1.5); 2.4801 (1.8); 2.4748 (1.1); 2.4692 (0.8); 2.4470 (0.5); 2.4365 (1.7); 2.4305 (1.8);

2.4270 (1.6); 2.3940 (0.6); 2.3892 (0.9); 2.3835 (0.8); 2.3787 (0.6); 2.0424 (1.7); 1.2757 (0.8); 1.2578 (2.6); 1.2399 (0.6); 0.8818 (0.9); 0.0080 (1.2); -0.0002 (36.3); -0.0085 (1.2)

Ш-26: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.2607 (9.4); 7.2048 (0.9); 7.1991 (1.6); 7.1953 (1.5); 7.1898 (1.3); 7.1839 (1.4); 7.1799 (1.5);

6.9668 (0.6); 6.9502 (0.8); 6.9450 (0.9); 6.9286 (0.8); 6.9229 (0.6); 3.9865 (0.8); 3.9547 (0.5); 3.9412 (1.2); 3.7642 (1.1); 3.7604 (1.0); 3.7494 (0.6); 3.7442 (0.7); 3.7189 (0.7); 3.7152 (0.7); 1.5551 (0.6);

1.4993 (13.0); 1.4900 (16.0); 1.4794 (12.2); 1.4497 (10.6); 1.4452 (5.7); 1.4339 (4.2); 1.2864 (0.6);

1.2647 (1.9); 0.8986 (1.0); 0.8818 (3.2); 0.8640 (1.3); -0.0002 (12.1)

Ш-27: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.2609 (15.6); 7.2044 (1.2); 7.2011 (1.9); 7.1985 (2.0); 7.1955 (2.1); 7.1852 (1.9); 7.1820 (2.0);

7.1796 (1.8); 7.1763 (1.3); 6.9718 (1.0); 6.9661 (1.2); 6.9602 (0.8); 6.9503 (1.2); 6.9445 (1.6); 6.9388 (0.8); 6.9288 (0.5); 6.9230 (0.8); 6.7948 (0.6); 6.7905 (0.7); 6.7846 (0.6); 6.7642 (0.7); 6.7590 (1.0);

6.7539 (0.7); 5.2985 (7.5); 4.6725 (0.8); 4.6628 (0.9); 4.6528 (0.9); 4.6431 (0.7); 4.4442 (0.6); 4.4324 (0.6); 4.4205 (0.7); 4.3295 (1.0); 4.3267 (1.1); 4.3181 (1.5); 4.3147 (2.3); 4.3058 (2.0); 4.3031 (2.0);

4.3001 (1.1); 4.2915 (1.3); 3.9840 (1.0); 3.9388 (1.4); 3.7645 (1.8); 3.7601 (2.2); 3.7193 (1.2); 3.7149 (1.5); 3.6937 (0.7); 3.6817 (0.7); 3.6700 (0.7); 3.6512 (2.0); 3.6462 (0.6); 3.6414 (2.9); 3.6394 (2.5);

3.6323 (1.4); 3.6275 (2.9); 3.6179 (1.5); 3.4000 (16.0); 3.3979 (6.0); 3.3897 (12.4); 3.3842 (1.3);

3.0721 (0.5); 3.0087 (0.6); 2.5327 (0.6); 2.5272 (0.6); 2.5227 (0.5); 2.4902 (0.6); 2.4805 (0.6); 2.4374 (0.6); 2.4323 (0.6); 1.5584 (1.2); 0.0080 (0.6); -0.0002 (19.0); -0.0085 (0.6)

Ш-28: 1Н-NMR(400.0 MHz, CDC13):

δ= 7.2627 (6.0); 7.1713 (0.8); 7.1675 (1.4); 7.1654 (1.4); 7.1620 (1.4); 7.1546 (0.8); 7.1513 (1.4);

7.1479 (1.4); 7.1459 (1.4); 7.1422 (0.9); 6.9639 (0.5); 6.9443 (0.5); 6.8879 (0.5); 6.8836 (0.8); 6.8823 (0.9); 6.7747 (0.7); 6.7699 (0.5); 6.7493 (0.7); 5.2993 (16.0); 4.6060 (0.6); 4.5960 (0.7); 4.5861 (0.7); 4.5761 (0.6); 4.3233 (0.7); 4.3212 (0.8); 4.3121 (1.0); 4.3089 (1.0); 4.3068 (1.0); 4.3053 (1.2); 4.3021 (1.0); 4.2995 (1.1); 4.2976 (1.2); 4.2947 (1.2); 4.2888 (0.9); 4.2813 (0.8); 4.2787 (0.8); 3.7887 (1.2);

3.7837 (1.2); 3.7455 (1.3); 3.7404 (1.4); 3.6503 (1.2); 3.6383 (1.4); 3.6330 (1.6); 3.6266 (1.4); 3.6211 (1.5); 3.6094 (1.2); 3.4005 (9.4); 3.3841 (9.5); 3.2025 (1.2); 3.1956 (1.2); 3.1591 (1.1); 3.1523 (1.1);

1.7133 (6.7); 1.7055 (6.8); -0.0002 (7.8)

- 159 044070

Analytical data of examples IV-01-IV-07 (see Table 1.2)

IV-01: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5185 (3.2); 7.3946 (2.9); 7.3751 (5.2); 7.3667 (5.3); 7.3183 (1.0); 7.2822 (1.9); 7.2595 (613.7);

7.2269 (1.1); 7.1511 (1.1); 7.1282 (1.3); 7.1147 (1.0); 7.0275 (1.1); 6.9955 (3.5); 5.8829 (1.6); 5.8591 (1.7); 4.5792 (1.1); 4.5682 (1.3); 4.5600 (1.2); 4.5481 (1.4); 3.8296 (2.3); 3.8108 (2.5); 3.7864 (2.4);

3.7678 (2.7); 3.2319 (2.8); 3.2262 (2.5); 3.1886 (2.4); 3.1828 (2.3); 2.9973 (3.5); 1.7137 (16.0); 1.7109 (15.6); 1.5423 (20.1); 1.3324 (1.2); 1.2841 (1.8); 1.2556 (4.3); 0.1458 (0.9); 0.0081 (7.0); -0.0002 (213.1); -0.0084 (6.3); -0.1499 (0.8)

IV-02: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.8094 (0.7); 7.6103 (0.7); 7.5185 (2.4); 7.5098 (0.6); 7.4131 (0.6); 7.3945 (2.8); 7.3809 (3.5); 7.3756 (5.0); 7.3703 (4.0); 7.3669 (5.3); 7.3641 (4.0); 7.3573 (1.6); 7.3090 (0.9); 7.3051 (0.9); 7.2970 (1.4);

7.2922 (1.9); 7.2852 (1.1); 7.2822 (1.1); 7.2788 (1.1); 7.2752 (3.3); 7.2696 (3.5); 7.2671 (5.5); 7.2597 (437.4); 7.2510 (2.6); 7.2469 (2.1); 7.2419 (1.9); 7.2388 (0.8); 7.2249 (0.9); 7.2084 (0.8); 7.1572 (0.9);

7.1512 (1.2); 7.1333 (1.3); 7.1297 (1.4); 7.1236 (1.0); 7.1146 (1.1); 7.1076 (1.0); 7.0597 (0.8); 7.0267 (0.9); 7.0118 (1.0); 7.0072 (1.0); 6.9957 (2.6); 5.8883 (1.1); 5.8832 (1.5); 5.8783 (1.1); 5.8642 (1.2);

5.8594 (1.6); 4.5800 (1.1); 4.5681 (1.2); 4.5597 (1.2); 4.5483 (1.1); 4.5398 (0.6); 3.8298 (2.3); 3.8110 (2.5); 3.7867 (2.6); 3.7678 (2.9); 3.2322 (2.6); 3.2263 (2.6); 3.1889 (2.3); 3.1830 (2.2); 3.0504 (1.9);

3.0018 (3.3); 2.8947 (0.5); 2.5923 (1.1); 2.5346 (0.5); 2.4876 (0.6); 2.4567 (0.6); 2.4132 (0.6); 2.3693 (0.7); 2.3526 (0.7); 2.3025 (0.5); 1.7327 (0.8); 1.7140 (16.0); 1.7110 (15.5); 1.5481 (6.3); 1.4445 (1.6); 1.3330 (2.9); 1.2843 (4.0); 1.2551 (7.8); 0.8958 (0.6); 0.8803 (1.2); 0.8626 (0.5); 0.0154 (1.0); 0.0079 (4.8); -0.0002 (151.0); -0.0086 (4.7); -0.0180 (0.8)

IV-03: ¹ H-NMR(400.0 MHz, CDC13):

δ= 8.2043 (0.8); 8.1666 (0.8); 7.5187 (1.7); 7.3829 (3.9); 7.3780 (3.7); 7.3731 (4.1); 7.3701 (3.8); 7.3662 (3.3); 7.2598 (298.6); 7.2297 (0.5); 7.1733 (0.8); 7.1581 (1.6); 7.1342 (1.2); 7.1288 (0.9); 7.1206 (0.7);

7.0164 (0.8); 6.9958 (2.5); 6.5143 (1.0); 6.4858 (1.0); 4.6151 (0.7); 4.6052 (1.2); 4.5946 (1.2); 4.5853 (1.3); 4.5749 (0.9); 3.8758 (3.1); 3.8379 (3.3); 3.8199 (16.0); 3.8094 (2.5); 3.7952 (15.8); 3.7805 (0.6);

3.7737 (2.5); 3.7661 (2.7); 3.2397 (2.1); 3.2334 (2.2); 3.1964 (1.9); 3.1900 (2.0); 3.1790 (0.5); 3.0021 (0.8); 2.9664 (0.6); 2.9560 (0.8); 2.9507 (1.1); 2.9307 (0.7); 2.4963 (0.5); 2.4456 (0.6); 2.4245 (0.6);

2.3810 (0.7); 1.7129 (12.1); 1.7074 (14.6); 1.5415 (26.6); 1.2842 (0.8); 1.2559 (1.6); 0.0080 (3.1); 0.0002 (102.3);-0.0085 (3.1)

IV-04: ¹ H-NMR(400.0 MHz, CDC13):

δ= 8.1901 (1.0); 8.1543 (1.0); 7.5185 (1.9); 7.3866 (2.7); 7.3830 (4.3); 7.3781 (4.3); 7.3732 (4.6); 7.3702 (4.6); 7.3663 (4.1); 7.2943 (0.7); 7.2596 (343.5); 7.1718 (1.0); 7.1565 (1.8); 7.1346 (1.4); 7.1205 (0.8);

7.1113 (0.6); 7.0138 (1.0); 6.9956 (3.0); 6.5139 (1.2); 6.4855 (1.1); 4.6250 (0.5); 4.6149 (0.9); 4.6053 (1.4); 4.5953 (1.4); 4.5857 (1.5); 4.5753 (1.0); 4.5656 (0.5); 3.8759 (3.0); 3.8381 (3.0); 3.8202 (15.8);

3.8093 (2.9); 3.7955 (15.6); 3.7805 (0.7); 3.7737 (2.6); 3.7661 (3.0); 3.2397 (2.4); 3.2333 (2.4); 3.2222

- 160 044070 (0.5); 3.1964 (2.0); 3.1901 (2.1); 3.0020 (0.9); 2.9829 (0.7); 2.9613 (0.7); 2.9563 (0.9); 2.9512 (1.2); 2.9459 (1.0); 2.9366 (0.8); 2.9311 (0.8); 2.8996 (0.6); 2.5013 (0.5); 2.4957 (0.5); 2.4406 (0.6); 2.4169 (0.7); 2.3736 (0.8); 2.3200 (0.6); 2.1359 (0.6); 1.7131 (13.1); 1.7075 (16.0); 1.5386 (24.0); 1.4428 (1.2); 1.3326 (0.5); 1.3051 (0.6); 1.2843 (1.2); 1.2650 (2.7); 0.8986 (1.4); 0.8819 (4.3); 0.8641 (1.8); 0.1459 (0.5); 0.0079 (4.2); -0.0002 (125.5); -0.0085 (4.4); -0.1498 (0.5)

IV-05: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3960 (1.7); 7.3910 (2.0); 7.3862 (3.0); 7.3834 (4.1); 7.3786 (4.6); 7.3739 (3.8); 7.3703 (5.0); 7.3670 (3.9); 7.3639 (2.4); 7.2620 (87.0); 7.1609 (0.7); 7.1558 (1.1); 7.1510 (0.7); 7.1419 (1.0); 7.1323 (1.4);

7.1260 (0.9); 7.1172 (0.9); 7.1102 (0.5); 7.0242 (0.8); 7.0064 (0.7); 6.9980 (1.0); 6.4684 (0.7); 6.4395 (0.7); 4.5935 (0.8); 4.5836 (0.8); 4.5744 (0.8); 4.5638 (0.6); 3.8179 (2.6); 3.8155 (2.4); 3.7746 (3.0);

3.7723 (2.7); 3.2377 (2.8); 3.2334 (2.9); 3.1945 (2.4); 3.1902 (2.6); 2.9779 (0.6); 2.9578 (0.6); 2.9321 (0.7); 2.9128 (0.7); 2.6484 (6.7); 2.6229 (6.9); 2.4992 (0.5); 2.4184 (0.9); 2.3714 (0.7); 2.3481 (0.6);

2.3430 (0.6); 1.7146 (15.5); 1.7079 (16.0); 1.6088 (0.7); 1.2580 (0.6); 0.8817 (0.9); 0.0079 (0.9); -0.0002 (31.0); -0.0085 (0.9)

IV-06: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.3961 (1.8); 7.3911 (2.2); 7.3836 (4.3); 7.3787 (4.7); 7.3741 (4.1); 7.3705 (5.1); 7.3672 (4.2); 7.3640 (2.6); 7.2622 (81.8); 7.1612 (0.7); 7.1560 (1.1); 7.1510 (0.7); 7.1418 (1.0); 7.1326 (1.5); 7.1262 (0.9);

7.1174 (0.9); 7.1104 (0.6); 7.0226 (0.8); 7.0055 (0.8); 6.9982 (1.0); 6.4689 (0.8); 6.4390 (0.8); 4.6039 (0.6); 4.5940 (0.9); 4.5843 (0.9); 4.5745 (0.9); 4.5641 (0.6); 3.8181 (2.8); 3.7748 (3.2); 3.2380 (2.7);

3.2338 (3.1); 3.1947 (2.3); 3.1905 (2.7); 2.9784 (0.7); 2.9585 (0.6); 2.9328 (0.8); 2.9180 (0.6); 2.9129 (0.8); 2.9085 (0.6); 2.8873 (0.5); 2.8820 (0.5); 2.6490 (7.8); 2.6237 (7.4); 2.4998 (0.6); 2.4231 (0.9);

2.4128 (0.8); 2.3715 (0.8); 2.3534 (0.5); 2.3485 (0.6); 2.3431 (0.6); 2.3022 (0.5); 2.2975 (0.5); 1.7148 (16.0); 1.7081 (15.0); 1.6149 (0.6); 1.4442 (1.6); 1.2562 (1.5); 0.0079 (0.9); -0.0002 (25.8); -0.0084 (1.0) IV-07: ¹ H-NMR(400.0 MHz, CDC13):

δ= 8.2847 (1.2); 8.2381 (1.1); 7.4014 (1.5); 7.3870 (3.2); 7.3812 (4.7); 7.3773 (3.8); 7.3731 (4.4); 7.3674 (3.0); 7.3626 (2.2); 7.3598 (2.3); 7.2606 (78.9); 7.1662 (0.8); 7.1610 (1.1); 7.1553 (0.7); 7.1451 (1.2);

7.1387 (1.7); 7.1327 (0.8); 7.1292 (0.6); 7.1220 (1.0); 7.1157 (0.6); 7.0540 (1.2); 7.0363 (1.2); 6.6811 (1.0); 6.6765 (1.4); 6.6648 (0.6); 6.6579 (1.0); 6.6529 (1.4); 6.6484 (1.0); 4.6340 (0.5); 4.6245 (0.9);

4.6144 (1.4); 4.6045 (1.3); 4.5946 (1.4); 4.5844 (0.9); 3.8252 (2.3); 3.8139 (2.3); 3.7819 (2.6); 3.7706 (2.6); 3.3685 (16.0); 3.3485 (15.7); 3.2511 (2.5); 3.2408 (2.6); 3.2078 (2.2); 3.1975 (2.2); 3.0867 (0.6); 3.0821 (0.6); 3.0607 (1.1); 3.0370 (1.1); 3.0188 (0.9); 3.0138 (1.0); 2.5832 (0.6); 2.5783 (0.6); 2.5468 (0.9); 2.5417 (1.0); 2.5367 (0.9); 2.5117 (0.6); 2.5052 (0.8); 2.4877 (0.5); 2.4755 (0.9); 2.4701 (1.0);

2.4652 (0.8); 1.7158 (14.0); 1.7085 (13.7); 1.5737 (5.3); 1.2651 (0.9); 0.8820 (1.3); 0.8643 (0.5); 0.0080 (0.9); -0.0002 (28.1); -0.0084 (0.9)

- 161 044070

IV-08: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5184 (3.1); 7.2596 (547.1); 7.2473 (0.8); 7.1773 (2.1); 7.1714 (2.4); 7.1604 (3.6); 7.1575 (3.8); 7.1516 (2.9); 7.1460 (2.5); 7.0590 (0.7); 6.9956 (3.0); 6.9084 (1.3); 6.8868 (2.3); 6.8650 (1.2); 6.6661 (1.0); 5.4101 (1.2); 5.2985 (2.0); 4.6118 (0.8); 3.8159 (2.6); 3.8038 (1.0); 3.7912 (1.6); 3.7727 (3.0);

3.7606 (1.2); 3.7481 (1.8); 3.2199 (3.8); 3.2090 (1.2); 3.1813 (1.9); 3.1768 (3.1); 3.1657 (1.3); 3.0441 (2.4); 3.0284 (1.4); 2.9399 (0.6); 2.5382 (0.8); 2.4685 (0.8); 2.0498 (1.5); 1.9543 (1.0); 1.7916 (1.0);

1.7583 (16.0); 1.7179 (8.0); 1.7104 (10.7); 1.2553 (1.0); 0.1459 (1.1); 0.0079 (10.7); -0.0002 (307.0); 0.0085 (9.4); -0.1495 (1.0)

IV-09: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5189 (1.0); 7.2600 (181.8); 7.1973 (2.5); 7.1829 (2.5); 6.9960 (1.5); 6.9702 (1.2); 6.9541 (1.2); 6.9485 (1.7); 6.9268 (0.8); 6.8632 (0.8); 6.8333 (0.9); 5.2995 (16.0); 4.6882 (0.8); 4.6681 (0.8); 3.9862 (0.9); 3.9395 (1.2); 3.7702 (2.0); 3.7654 (1.7); 3.7250 (1.4); 3.0349 (0.8); 2.5744 (2.4); 2.4870 (1.6); 2.0065 (1.0); 1.6417 (0.7); 1.2555 (1.8); 1.0166 (1.4); 0.1460 (1.1); 0.0079 (8.0); -0.0002 (226.2); 0.0083 (9.4); -0.1493 (0.9)

IV-11: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.5183 (8.4); 7.2594 (1381.5); 7.2096 (12.1); 7.1794 (16.2); 7.1737 (19.7); 7.1597 (20.3); 7.1540 (15.8); 6.9954 (8.3); 6.9569 (5.2); 6.9170 (5.2); 6.9113 (7.7); 6.9058 (4.2); 6.8954 (9.2); 6.8896 (16.0); 6.8839 (8.1); 6.8736 (4.9); 6.8680 (8.2); 6.8619 (5.7); 6.8497 (10.1); 6.8351 (7.5); 6.1938 (8.4); 6.1832 (6.7); 6.1668 (9.3); 6.1564 (7.7); 6.1506 (10.4); 6.1400 (7.8); 6.1238 (10.4); 6.1132 (8.3); 5.5505 (13.4); 5.5477 (14.8); 5.5074 (11.0); 5.5046 (13.1); 5.3602 (11.1); 5.3494 (12.5); 5.3326 (10.0); 5.3238 (11.8); 4.6458 (4.5); 4.6331 (5.2); 4.6260 (5.5); 4.6137 (5.5); 4.6041 (3.2); 3.9429 (11.1); 3.9312 (14.2); 3.8999 (13.5); 3.8880 (16.0); 3.3394 (14.0); 3.3313 (12.6); 3.2963 (12.6); 3.2883 (10.6); 3.0848 (2.5); 3.0528 (5.8); 3.0327 (6.2); 3.0129 (6.0); 2.9925 (5.7); 2.5120 (3.3); 2.4821 (6.9); 2.4390 (5.6); 2.3922 (2.7);

2.0052 (2.4); 0.1459 (4.1); 0.0079 (37.0); -0.0002 (1177.9); -0.0085 (41.1); -0.0501 (10.1); -0.1495 (3.6) IV-12: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2617 (46.8); 7.1803 (0.5); 7.1702 (2.2); 7.1676 (3.0); 7.1646 (3.5); 7.1620 (3.3); 7.1507 (3.2); 7.1480 (3.4); 7.1451 (3.0); 7.1425 (2.1); 6.9976 (1.2); 6.9807 (1.0); 6.9153 (0.5); 6.9129 (0.6); 6.9095 (1.0); 6.9072 (1.0); 6.9039 (0.6); 6.9013 (0.5); 6.8936 (1.1); 6.8912 (1.2); 6.8878 (1.9); 6.8855 (1.9); 6.8821 (1.1); 6.8798 (1.0); 6.8719 (0.6); 6.8695 (0.6); 6.8661 (1.0); 6.8638 (0.9); 6.8605 (0.5); 6.4181 (1.1); 6.4127 (1.8); 6.4021 (0.8); 6.3960 (1.2); 6.3910 (1.6); 6.3862 (1.1); 5.5605 (1.2); 5.5351 (1.1); 5.2987 (1.3); 4.6152 (0.6); 4.6080 (1.0); 4.6043 (1.0); 4.5975 (1.0); 4.5883 (1.1); 4.5845 (1.0); 4.5778 (0.7); 3.7901 (2.8); 3.7862 (2.8); 3.7468 (3.2); 3.7429 (3.2); 3.2106 (2.8); 3.2044 (2.9); 3.1672 (2.5); 3.1611 (2.5); 3.0222 (0.6); 3.0157 (0.9); 3.0101 (1.1); 3.0025 (0.8); 2.9956 (0.9); 2.9902 (1.0); 2.9712 (1.0); 2.9677 (1.0); 2.9634 (1.0); 2.9514 (1.1); 2.9437 (0.9); 2.4940 (0.6); 2.4890 (0.7); 2.4838 (0.7); 2.4787 (0.6); 2.4426 (1.1); 2.4286 (0.6); 2.4187 (0.8); 2.4144 (0.7); 2.4078 (0.8); 2.3991 (0.6); 2.3951 (0.6); 2.3875 (0.7); 2.3825 (0.8); 2.3698 (1.0); 2.3644 (0.9); 2.3235 (0.6); 2.3183 (0.6); 1.7196 (15.0);

1.7091 (15.1); 1.6382 (14.5); 1.6195 (15.6); 1.6180 (16.0); 1.5765 (0.6); 1.5641 (0.5); 0.0079 (0.9); 0.0002 (26.2); -0.0084 (1.0)

IV-13: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2609 (6.7); 7.2013 (0.6); 7.1982 (0.8); 7.1847 (0.7); 7.1826 (0.8); 7.1795 (0.6); 6.9492 (0.6); 5.2996 (16.0); 3.9379 (0.6); 3.7701 (0.8); 3.7249 (0.6); 1.6404 (3.8); 1.6391 (3.8); 1.6295 (3.8); -0.0002 (8.2)

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Analytical data of examples V-01-V-04 (see Table 1.1)

V-01: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2607 (29.8); 7.1733 (1.8); 7.1675 (2.2); 7.1644 (1.3); 7.1566 (1.3); 7.1535 (2.2); 7.1478 (1.8); 6.9165 (1.2); 6.9109 (1.3); 6.9051 (0.7); 6.8949 (1.7); 6.8892 (2.0); 6.8834 (0.9); 6.8733 (0.6); 6.8675 (0.8); 6.6565 (0.8); 6.6519 (2.1); 6.6465 (1.8); 6.6420 (0.8); 5.2999 (2.6); 5.1266 (0.5); 5.1212 (0.6);

5.1061 (0.6); 3.8051 (2.6); 3.7617 (3.0); 3.2223 (2.8); 3.1789 (2.4); 2.7298 (0.6); 2.7242 (0.5); 2.5871 (0.7); 2.5674 (0.9); 2.5486 (1.0); 2.5451 (1.5); 2.5380 (0.7); 2.5249 (0.6); 2.5165 (0.6); 1.7523 (0.8); 1.7447 (0.9); 1.7294 (16.0); 1.7126 (0.6); 1.4322 (0.7); 0.0079 (1.2); -0.0002 (38.1); -0.0085 (1.4) V-05: ¹ H-NMR(400.6 MHz, CDC13):

δ= 7.2615 (30.2); 7.2051 (1.2); 7.1994 (1.5); 7.1962 (0.9); 7.1892 (0.9); 7.1859 (1.5); 7.1803 (1.3); 6.9720 (0.6); 6.9562 (0.6); 6.9505 (1.1); 6.9448 (0.6); 6.9290 (0.6); 6.5558 (1.5); 6.5504 (1.3); 6.5456 (0.6); 3.9927 (0.9); 3.9474 (1.3); 3.7747 (3.3); 3.7575 (16.0); 3.7293 (1.7); 2.5863 (0.6); 2.5831 (0.5); 2.5665 (0.8); 2.5637 (1.0); -0.0002 (17.8); -0.0085 (0.6)

V-02: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2625 (20.6); 7.1731 (1.2); 7.1700 (0.8); 7.1674 (1.4); 7.1643 (0.8); 7.1564 (0.8); 7.1533 (1.4); 7.1476 (1.2); 6.9111 (0.6); 6.8952 (0.6); 6.8894 (1.1); 6.8836 (0.5); 6.8677 (0.6); 6.5394 (0.5); 6.5341 (1.4); 6.5291 (1.1); 5.3005 (1.8); 3.7930 (2.0); 3.7681 (0.7); 3.7496 (2.4); 3.7427 (16.0); 3.2154 (2.0); 3.1721 (1.8); 2.6219 (1.0); 2.5432 (0.6); 2.5263 (0.8); 2.5230 (0.5); 1.7330 (0.5); 1.7237 (11.9); 0.0002 (12.6)

V-03: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2633 (20.6); 7.1798 (1.0); 7.1740 (1.2); 7.1710 (0.7); 7.1631 (0.7); 7.1600 (1.2); 7.1542 (1.0); 6.8951 (0.5); 6.8893 (0.9); 6.8676 (0.5); 6.5767 (1.1); 6.5715 (0.9); 4.4461 (0.6); 4.4343 (0.5); 4.4224 (0.6); 4.3059 (1.8); 4.2995 (0.6); 4.2974 (0.9); 4.2943 (1.7); 4.2908 (0.9); 4.2887 (0.6); 4.2824 (1.9); 3.7952 (1.6); 3.7519 (1.9); 3.6955 (0.6); 3.6836 (0.5); 3.6718 (0.6); 3.6266 (1.8); 3.6203 (0.6); 3.6182 (0.9); 3.6147 (1.7); 3.6116 (0.9); 3.6096 (0.6); 3.6030 (1.7); 3.4040 (0.8); 3.3991 (4.4); 3.3947 (0.7);

3.3746 (16.0); 3.2173 (1.7); 3.1740 (1.5); 2.6163 (2.2); 2.5451 (0.7); 1.7238 (9.5); 1.7134 (0.8); 1.6802 (0.7); -0.0002(12.2)

V-04: ¹ H-NMR(400.0 MHz, CDC13):

δ= 7.2601 (32.7); 7.2062 (0.6); 7.2004 (0.7); 7.1870 (0.6); 7.1814 (0.5); 6.9786 (1.0); 5.2997 (0.6);

5.0059 (0.5); 3.7802 (0.8); 3.7350 (0.6); 2.2715 (1.7); 1.4789 (0.6); 1.4322 (16.0); 1.4218 (0.7); 1.2812 (0.8); 1.2546 (1.0); 1.2436 (0.6); 1.2228 (3.0); 0.0080 (1.3); -0.0002 (40.1); -0.0085 (1.4)

Analogously to the above-mentioned preparation examples, as well as other examples where appropriate, taking into account the general data for the preparation of the substituted isoxazoline carboxamide, the following compounds can be prepared.

In table 2.1 shows the compounds according to the invention 2.1-1-2.1-240 of the general formula (1.1), wherein Z-(C=W)-OR ⁴ has the meanings as defined below.

ABOUT

(II),

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Table 2.1

No. -. О 4 γ γ ^R w No. w 2.1-1 γ< ^Ζ ' ¹ >γ% 2.1-2 γ ^(Ζ - ¹⁾ γ ^%Η 3 O 2.1-3 ^(zp^o^c n ₃ o 2.1-4 γ ^(ζ -ΐ)γ°^ _0Η3 2.1-5 (Z-1 )^0^0 H ₃ 0 CH ₃ 2.1-6 γ-1 ΐγΟχ/hL Η ₃ 0 2.1-7 CH _{3 V} (Z-1) _Y O^A _CH3 ' 0 2.1-8 -^(Ζ-Ι )χ.Ο C Η ₃ 5 Π dch ₃ 0 CH ₃ ^d 2.1-9 2.1-10 (ζ-υγ ⁰ ^ ⁰ 2.1-11 ^Ί O 2.1-12 <sn (z-n^o^co O 2.1-13 _v <zD _Y ojO o 2.1-14 yy°^ _cn O 2.1-15 γζ-1) _γ θ^ _α 0 2.1-16 _γ (Ζ-1) _Y °^^o' ^{c Нз} О

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2.1-17 (Ζ-2) _γ <γ ' o 2.1-18 _ν < ^ζ - ² )γ%Η ₃ ^Ί O 2.1-19 _γ (Ζ-2) _γ Ο^_ΟΗ ₃ ⁴ О 2.1-20 (Ζ-2) _γ Ο^ _οΗ3 О 2.1-21 ^(2-2)^0^0 Η ₃ ' O sn ₃ 2.1-22 _γ (Ζ-2) ⁿ z O 2.1-23 sn ₃ (Ζ-2) _γ Ο^Αθ _Η3 ^Ί O 2.1-24 ^.(2-2)^0 СН ₃ 5 П 1^сн ₃ о сн ₃ ⁰ 2.1-25 ν'Ύ’Ό 2.1-26 (Ζ.2 _)γ ο _γ ⁰ 2.1-27 /!2-2)^О^ _СНг 'О 2.1-28 <sn (Ζ-2) _γ Ο^Ο<' O 2.1-29 N o y 2.1-30 (Ζ-2) _γ Ο^ _0Ν ³ O 2.1-31 (Ζ-2) _γ Ο^ _α ' O 2.1-32 _γ (Ζ-2) _γ Ο^-- _ο -Ο Н ₃ 2.1-33 (Ζ-3) _γ Ο. _Η 'O 2.1-34 _ν < ^ζ - ³ )γ%Η ₃ ^Ί 0

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2.1-35 (Ζ-3)γΟ^ΟΗ ₃ 0 2.1-36 γ^γ ⁰ ^^ 2.1-37 ^(2-3)^O^CH ₃ 0 CH ₃ 2.1-38 γζ-з Η ₃ ^Ί 0 2.1-39 dn ₃ 0 2.1-40 _,(Ζ-3)γ/ΟγγΟΗ ₃ 5 Π 1^сн ₃ о сн ₃ ^ό 2.1-41 Ό°Ό 2.1-42 -,......(Ζ-3) ........0 .......-..... ° 0 2.1-43 ' 0 2.1-44 <sn (2-3)^0^0' Ο 2.1-45 4 o >° Ν 2.1-46 γ^'γ ⁰ ^—^ ^0Ν ' 0 2.1-47 γ< ^ζ · ³ )γ ^ο ^>α ⁴ 0 2.1-48 Η ₃ ' 0 2.1-49 γ< ^ζ - ⁴ >γ% ^Ί 0 2.1-50 γ< ^ζ - ⁴ >γ%Η ₃ ^Ί 0 2.1-51 -^(2-4)^0^0 Η ₃ 0 2.1-52 γ(Ζ-4)γΟ^ _ΟΗ3 ' 0

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2.1-53 _γ (Ζ 4) _γ 0 CH ₃ 0 сн ₃ 2.1-54 -^(2-4)^0^^^^0 Η ₃ 0 2.1-55 CH ₃ ' 0 2.1-56 ^.(2-4)^0 СН ₃ 5 П 1%н ₃ о сн ₃ ³ 2.1-57 PGO 2.1-58 (ζ-4 _)γ <γ. ⁰ 2.1-59 γ(«)γ°^ _0Η! ^Ί 0 2.1-60 <sn -^(^4)^0^0^ ' ABOUT 2.1-61 P 0 2.1-62 _γ (Ζ-4) _γ θ^ _0Ν 0 2.1-63 _ν <Ζ-4) _γ 0^ _0| 2.1-64 Y^yO^/s^c n ₃ o 2.1-65 _γ ( _Ζ - ₅ ) _γ % ' 0 2.1-66 V-< ^z - ⁵ >Y%h ₃ O 2.1-67 (Ζ-5) _γ θ^ΟΗ ₃ ⁴ 0 2.1-68 _ν ( _Ζ -5) _γ Ο^ _οΗ3 О 2.1-69 _^(Ζ-5) ^O^CH3 O CH ₃ 2.1-70 yfz-siyO^^^c n ₃ ' O

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2.1-71 CH _{3 V} ( ^Z -5) _Y °^ _CH3 0 2.1-72 (ζ-δ^ο сн ₃ V Π 1%η ₃ 0 ΟΗ ₃ ³ 2.1-73 ν ^ζ ΎΧ) 2.1-74 (Ζ-5) _γ Ο^ ⁰ 2.1-75 ' 0 2.1-76 ,sn (2-5)^0^0^ ' 0 2.1-77 ο >° N 2.1-78 ' 0 2.1-79 (Ζ-5) _γ Ο^ _ο| ' 0 2.1-80 -^(/-5)^0^^^^0 Η ₃ ' 0 2.1-81 ' 0 2.1-82 _ν < ^ζ - ⁶ > γ%Η ₃ 2.1-83 Η ₃ ' 0 2.1-84 ' 0 2.1-85 _Υ Ζ-6)γΟγθ Η ₃ 0 0Η ₃ 2.1-86 Η ₃ ' ο 2.1-87 CH ₃ Y~Y^ _CHs ' 0 2.1-88 V Π 1^сн ₃ 0 сн ₃ ³

- 168 044070

2.1-89 2.1-90 ( ^ζ - _8)γ ο^ ⁰ 2.1-91 y<«)y°^ _C n ₂ 0 2.1-92 <sn (z-e^o^c- ' 0 2.1-93 I'm about >° !H 2.1-94 _Y <z-6)yO^ _CN ' 0 2.1-95 y(Z-6)yO^ _c| ^Ί 0 2.1-96 ^(Z-6)^O^^ _Q ^CH ₃ ' 0 2.1-97 γ< ^ζ -7) _γ % ' 0 2.1-98 _ν < ^{ζ 7} >γ%Η ₃ 2.1-99 (Ζ-7) _γ Ο^ΟΗ ₃ ⁴ 0 2.1-100 уИ _¥ °^ _СНз 0 2.1-101 ^(2-7)^0^0 Η ₃ 0 CH ₃ 2.1-102 _γ (Ζ-7) Η ₃ ^Ί O 2.1-103 CH _{3 ν} (Ζ-7) _γ Ο _χ Υ _οΗ3 2.1-104 (Z-7)^O CH ₃ 5 Υ 1%H ₃ 0 CH ₃ ⁰ 2.1-105 χ ^α ΎΌ 2.1-106 ^(Ζ - ⁷⁾ _Υ °^ ⁰

- 169 044070

2.1-107 uIu°^ _CIS 2.1-108 .sn (Z-7)^O^C> ' 0 2.1-109 γ-γθΧ ¹ o 2.1-110 Τ/(Ζ-7) _γ Ο^θ _Ν ² 0 2.1-111 ' ABOUT 2.1-112 Τ/(Ζ-7) _γ °---^ ₀ - ^{С Н} з ^Ί 0 2.1-113 ' 0 2.1-114 γ ^(Ζ - ⁸⁾ γ%Η ₃ ^Ί ο 2.1-115 ^(Ζ-8)γΟ _ν ΟΗ ₃ ' 0 2.1-116 γ-«>γ ^ο ^ _Ο Η ₃ 0 2.1-117 _γ (Μ)γθ sn ₃ o sn ₃ 2.1-118 ^(Z-8)^.O^^^C Η ₃ ^Ί 0 2.1-119 CH _{3 ν} (Ζ-8) _γ θΥ _οΗ3 0 2.1-120 ^.(2-8)^.0 CH ₃ V Π 1^сн ₃ 0 СН ₃ ^ό 2.1-121 γ^γθγκ 0 '—/ 2.1-122 _τ ........(Ζ-8)........0....................... ³ ......Q 2.1-123 ' 0 2.1-124 <sn (Ζ-8)γΟ^Ο- ^Ί Ο

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2.1-125 Ν ώ ο ь 2.1-126 ^(Z-8)yO^ _CN ' 0 2.1-127 _γ (Ζ-8) _γ Ο^ _α 2.1-128 _γ (Ζ-8) Η ₃ ⁷ 0 2.1-129 γ( ^Ζ -9)γ°^Η ' 0 2.1-130 _ν ( ^ζ - ⁹ )γ%Η ₃ ^Ί 0 2.1-131 (Z-9)^O^CH ₃ 0 2.1-132 _ν (Ζ-9) _γ 0^ _0Η3 2.1-133 - ₁ /(Ζ-9)γΟ^ _/ ΟΗ ₃ 0 CH ₃ 2.1-134 _γ (Ζ-9) Η ₃ ' 0 2.1-135 сн _{3 v} <^) _Y o^A _CHj 2.1-136 .^.(2-9)^.0 0 Η ₃ 5 Π l^c η ₃ 0 сн ₃ ^ό 2.1-137 _ν -γ° _η 2.1-138 ^(Ζ - ⁹⁾ _Υ °^ ⁰ 2.1-139 ^(Z-9)^O^ _ch2 ' 0 2.1-140 <sn (Z-9)^O^C- ' ABOUT 2.1-141 Ν ώ °Α ο ь 2.1-142 V' ^(Z ' ⁹⁾ Y°'^^ ^cn o

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2.1-143 (Ζ-9) _γ Ο^ _ο| 0 2.1-144 Η ₃ ' 0 2.1-145 (Ζ- ¹ 0)^ ^ο . _Η ' 0 2.1-146 _ν < ^ζ - ¹⁰ >γ%Η ₃ ^Ί 0 2.1-147 -^(Z-10)^O^CH ₃ ' 0 2.1-148 T/(Z-10)^O^ _cH3 ' ο 2.1-149 -^(Ζ-1 ο)γ°γ ^{0 Nz} 0 CH ₃ 2.1-150 _γ (Ζ-10) _Y °xX\/C Η ₃ ' ο 2.1-151 sn ₃ (ζ-ιο _)γ ο^θ _Η3 ' 0 2.1-152 •^(Ζ-ΙΟ^Ο CH ₃ V Π Г^СНз О сн ₃ 2.1-153 (ζ-ιοκ^ο^^ ' oh Gy 2.1-154 (Ζ-10)γΟ^^ ⁰ 2.1-155 T/(Z-10) _Y 0^ _CH2 0 2.1-156 <sn (2-10)^0^0^ ' Ο 2.1-157 Ν Ο °4 ο ь 2.1-158 (Z-10) _Y O^ _cN 0 2.1-159 ^(Ζ-10) _γ Ο^ _α ' 0 2.1-160 _γ (Ζ-10) γ°\/Χ _ο ζ ^{Ο N} z ⁴ Ο

- 172 044070

2.1-161 ⁷ 0 2.1-162 γ^γ ⁰ '^ O 2.1-163 ⁷ O 2.1-164 γζ-ιιγο^^ ^Ί o 2.1-165 τ^ζ-ιγ ch _s O CH ₃ 2.1-166 ' O 2.1-167 CH ₃ O 2.1-168 •^(Z-HJ^O sn ₃ h P 1xn ₃ o sn ₃ ⁰ 2.1-169 (z-id^o^^ o Gy 2.1-170 O L___) 2.1-171 γζ-ιιγο^^ o 2.1-172 .sn (Z-11)^O^C* ' O 2.1-173 (Ζ-11)γΟ^ίθ ' O 2.1-174 γζ-ιιγ°^ _0Ν ' O 2.1-175 ^(Ζ-11) _γ Ο^ _α ⁴ O 2.1-176 V p ABOUT 2.1-177 (Ζ-12)^Ο^ ⁷ O 2.1-178 γ< ^ζ - ¹² >γ%Η ₃ ' O

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2.1-179 ^(2-12)^0^0 H ₃ ' 0 2.1-180 (Ζ-12) _γ Ο^ _εΗ3 0 2.1-181 -^(2-12)^0^0 H ₃ O CH ₃ 2.1-182 -^(2-12)^0^^^0 Η ₃ ' 0 2.1-183 CH _{3 ν} <Ζ-12) _γ Ο^θ _Η3 ⁴ O 2.1-184 -7/(2-12)^0 0Η ₃ V Π Υοη ₃ 0 CH ₃ 2.1-185 ΥΥΌ 2.1-186 γΖ-ΙΣγΟ^^. ⁰ 2.1-187 (Ζ-12) _γ Ο^^ ^Ί O 2.1-188 <sn -^^,(2-12)^^0^^0^ ' 0 2.1-189 ΐΓ^Ί (Ζ-12)γΟ^>1^ ' O 2.1-190 (Z-12)^O^ _cn ' ο 2.1-191 (Ζ-12) _γ 0^ _α ^Ί 0 2.1-192 _γ (Ζ-12) _γ Ο^^θ,ΟΗ ₃ ' 0 2.1-193 ' 0 2.1-194 (ζ-13)^ο^ _η3 ² 0 2.1-195 _ /(Z-13R/0 0Η ₃ V Υ 0 2.1-196 (Ζ-13) _γ Ο^θ _Η3 0

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2.1-197 -^(Ζ-13)γΟ^ΟΗ ₃ 0 CH ₃ 2.1-198 Υ Υ 0 2.1-199 dn ₃ 0 2.1-200 _ν (Ζ-13) _ν Ο сн ₃ V π YcH ₃ 0 сн ₃ 2.1-201 ¢-13)^0^^ 0 I--/ 2.1-202 _γ (Ζ-13) _γ Ο^^ ⁰ 2.1-203 Τ/(Ζ-13) _γ Ο^ _ο ^ ' 0 2.1-204 <sn (Z-13)^O^C ^Ί o 2.1-205 (Ζ-13)γΟ^ίθ ' O 2.1-206 t/(z-i3)^o^ _cn ' O 2.1-207 (Ζ-13) _γ Ο^ _ο| 0 2.1-208 _ _/ (Z-13) _4/ O^ ₄ CH ₃ YY ⁰ o 2.1-209 γ^Υ'Η ⁴ 0 2.1-210 0 2.1-211 (Z-14)^O^CH ₃ ' 0 2.1-212 _ν (Ζ-14) _γ Ο^θ _Η3 ^Ί O 2.1-213 -^(2-14)^0^0 Η ₃ 0 CH ₃ 2.1-214 Υ Υ 0

- 175 044070

2.1-215 (2-14)^0^ O CH ₃ ^CH ₃ 2.1-216 -^,(2-14)^0 0 x ^СНз Ych ₃ СНз 2.1-217 ' ABOUT '--/ 2.1-218 γΖ-14)γΟγκ ⁰ 2.1-219 ^(Ζ-14) _γ Ο^ _οΗ2 ' O 2.1-220 1/(2-14)^,0^ 0 <sn 2.1-221 (Z-14)^0^1^ ' ABOUT 2.1-222 (Ζ-14)γΟ ₄ ' 0 2.1-223 ^(Ζ-14) _γ Ο^ _α ' O 2.1-224 1/(2-14)^0^ ' 0 /\ ₀ ΛΗ ₃ 2.1-225 _ν ⁽ ^- ¹⁵⁾ _Ύ O '% 2.1-226 (Z-15)^ 0 CH ₃ 2.1-227 (2-15)^0, O ^CH ₃ 2.1-228 1/(Ζ-15)γΟ _χ ' 0 ^^CH ₃ 2.1-229 1/(2-15)^0О ^ ^sn z CH ₃ 2.1-230 (Ζ-15Κ/Ο V Y 0 /\//СНз 2.1-231 ^(Z-15)^O^ ' ABOUT CH ₃ ^CH ₃ 2.1-232 1/(2-15)^,0 0 HF ^CH3 Ych ₃ CH ₃ 2.1-233 1/(Ζ-15)γΟ_/ ' O '--/ 2.1-234 1^/(2-15)^^0-^^ ⁰ 2.1-235 ^Ί 0 2.1-236 _-φΖ-15)^0^ ' 0 <sn 2.1-237 (Ζ-15)γΟ^ O ABOUT 2.1-238 (2-15)^0. 0 2.1-239 (Ζ-15) _γ Ο^ _ο| ' 0 2.1-240 (Ζ-15)γΟ^ ' 0 /F ₀ /CH ₃

Table 2.2: compounds according to the invention 2.2-1-2.2-240 of general formula (I.2), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

ABOUT

Table 2.3: compounds according to the invention 2.3-1-2.3-240 of general formula (I.3), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

- 176 044070

Table 2.4: compounds according to Z-(C=W)-OR ⁴ as defined in table. 2.1.

invention 2.4-1-2.4-240 of general formula (I.4), and

invention 2.5-1-2.5-240

Table 2.5: compounds according to Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.5), and

invention 2.6-1-2.6-240

Table 2.6: compounds according to Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (1.6), and

invention 2.7-1-2.7-240

Table 2.7: compounds according to Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.7), and

invention 2.8-1-2.8-240

Table 2.8: compounds according to Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.8), and

invention

2.9-1-2.9-240

Table 2.9: compounds according to Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.9), and

2.10-1-2.10-240

Table 2.10: compounds according to the invention Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.10), and

2.11-1-2.11-240

Table 2.11: compounds according to the invention Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.11), and

- 177 044070

Table 2.12: compounds according to the invention 2.12-1-2.12-240 of the general formula (I.12), wherein

Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.13: compounds according to the invention 2.13-1-2.13-240 of general formula (I.13), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

O

(113),

Table 2.14: compounds according to the invention 2.14-1-2.14-240 of general formula (I.14), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

(1.14),

Table 2.15: compounds according to the invention 2.15-1-2.15-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.15), and

2.16-1-2.16-240

Table 2.16: compounds according to the invention Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.16), and

Table 2.17: compounds according to the invention 2.17-1-2.17-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.17), and

2.18-1-2.18-240

Table 2.18: compounds according to the invention Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.18), and

2.19-1-2.19-240

Table 2.19: compounds according to the invention Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.19), and

- 178 044070

Table 2.20: compounds according to the invention 2.20-1-2.20-240 total Z-(C=W)-OR ⁴ as defined in table. 2.1.

formulas (I.20), and

Table 2.21: compounds according to the invention 2.21-1-2.21-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.21), and

Table 2.22: compounds according to the invention 2.22-1-2.22-240 total Z-(C=W)-OR ⁴ as defined in table. 2.1.

formulas (I.22), and

Table 2.23: compounds according to the invention 2.23-1-2.23-240 total Z-(C=W)-OR ⁴ as defined in table. 2.1.

formulas (I.23), and

Table 2.24: compounds according to the invention 2.24-1-2.24-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.24), and

Table 2.25: compounds according to the invention 2.25-1-2.25-240 total Z-(C=W)-OR ⁴ as defined in table. 2.1.

formulas (I.25), and

(125),

Table 2.26: compounds according to the invention 2.26-1-2.26-240 total Z-(C=W)-OR ⁴ as defined in table. 2.1.

formulas (I.26), and

- 179 044070

Table 2.27: compounds according to the invention 2.27-1-2.27-240 of the general formula (I.27), wherein

Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.28: compounds according to the invention 2.28-1-2.28-240 of general formula (I.28), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.29: compounds according to the invention 2.29-1-2.29-240 of general formula (I.29), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

ABOUT

(129),

Table 2.30: compounds according to the invention 2.30-1-2.30-240 of general formula (I.30), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

ABOUT

(1.30),

Table 2.31: compounds according to the invention 2.31-1-2.31-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.31), and

Table 2.32: compounds according to the invention 2.32-1-2.32-240 of general formula (I.32), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.33: compounds according to the invention 2.33-1-2.33-240 of general formula (I.33), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

- 180 044070

Table 2.34: compounds according to the invention 2.34-1-2.34-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.34), and

Table 2.35: compounds according to the invention 2.35-1-2.35-240 of general formula (I.35), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.36: compounds according to the invention 2.36-1-2.36-240 of general formula (I.36), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.37: compounds according to the invention 2.37-1-2.37-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.37), and

Table 2.38: compounds according to the invention 2.38-1-2.38-240 of general formula (I.38), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.39: compounds according to the invention 2.39-1-2.39-240 of general formula (I.39), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.40: compounds according to the invention 2.40-1-2.40-240 of the general formula (I.40), wherein

- 181 044070

Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.41: compounds according to the invention 2.41-1-2.41-240 of general formula (I.41), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.42: compounds according to the invention 2.42-1-2.42-240 of general formula (I.42), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.43: compounds according to the invention 2.43-1-2.43-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.43), and

Table 2.44: compounds according to the invention 2.44-1-2.44-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.44), and

Table 2.45: compounds according to the invention 2.45-1-2.45-240 of general formula (I.45), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

O

Table 2.46: compounds according to the invention 2.46-1-2.46-240 of general formula (I.46), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.47: compounds according to the invention 2.47-1-2.47-240 of the general formula (I.47), wherein

- 182 044070

Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 2.48: compounds according to the invention 2.48-1-2.48-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.48), and

2.49-1—2.49—240

Table 2.49: compounds according to the invention Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.49), and

Table 2.50: compounds according to the invention 2.50-1-2.50-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.50), and

Table 2.51: compounds according to the invention 2.51-1-2.51-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.51), and

Table 2.52: compounds according to the invention 2.52-1-2.52-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.52), and

Table 2.53: compounds according to the invention 2.53-1-2.53-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.53), and

Table 2.54: compounds according to the invention 2.54-1-2.54-240 of general formula (I.54), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

- 183 044070

Table 2.55: compounds according to the invention 2.55-1-2.55-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.55), and

Table 2.56: compounds according to the invention 2.56-1-2.56-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.56), and

Table 2.57: compounds according to the invention 2.56-1-2.56-240 Z-(C=W)-OR ⁴ as defined in table. 2.1.

general formula (I.57), and

Table 2.58: compounds according to the invention 2.56-1-2.56-240 of general formula (I.58), with Z-(C=W)-OR ⁴ as defined in table. 2.1.

Table 3.1: compounds according to the invention 3.1-1-3.1-390 of general formula (II.1), Z-(C=W)-N(R ¹¹ )-R ¹² has the meanings as defined below.

and

- 184 044070

Table 3.1

No. r ¹¹ w No. R ^11w 3.1-1 (Ζ-1)γΝΗ ₂ ' 0 3.1-2 Η ' O 3.1-3 Η ' 0 3.1-4 Η Τ/(Ζ-1)γΝχ ' 0^ 3.1-5 СНз ^^СНз ' 0 3.1-6 γ(Ζ-ΐ)γίΟ ⁴ ο 3.1-7 ^(Z-IJ^nA ⁷ O 3.1-8 ο 3.1-9 Н τ> ^{ζ 1} >γ% _Η 0 3.1-10 Η (ζ-ι^Κθ^ ' ο 3.1-11 n -ΛΖ-1 h P ° ^SMz 'o 3.1-12 Η ?· uIuChLi ⁴ ο 3.1-13 СНз γΖ-ΐγ%^Η ₃ о 3.1-14 Η (Ζ-1)^Ν^ СНз Π ο θ θ 3.1-15 n (ZD^N^ CF ₃ 5 Π 'I' ^Ί LLC 3.1-16 Η ^.(Ζ-1)^Ν V V A ' ο θ θ 3.1-17 Q.. '° >° Ν 3.1-18 СНз (Ζ-Ι)^,Ν^ CF ₃ V π A ο Ο ο

- 185 044070

3.1-19 -^(ZD^N nh ₂ V π Λ 0 ^{0 0} 3.1-20 Η? ^NZ (Ζ-1Κ ^Ν. ,Ν. Υ 3.1-21 H ν-< ^ζ ·”γ ^Ν 'ΝΗ _! ' O 3.1-22 Η γ ^(Ζ - ¹⁾ γ ^Ν γ ^0Η3 o sn ₃ 3.1-23 Η γ^γ^Ν0 sn ₃ 3.1-24 Η? ^NZ γ-ΐ)γΛ _Η3 3.1-25 n _V < ^Z -1)T%^CH3 ⁰ ^CH3 3.1-26 Η I 3.1-27 (Ζ-2)γΝΗ ₂ ' O 3.1-28 Η _ν ' ^Ζ - ^2| γ ^Ν ^Η, ' 0 3.1-29 n (2-2)^1^0^ ' O 3.1-30 Η -,γΖ-2Κ .γ ο ν 3.1-31 CH3( ^z - ^{2 )} _YN.CH3'O 3.1-32 γζ-ζγ,ίΟ ο 3.1-33 _γ (Ζ-2)γΥ ' o 3.1-34 (Ζ- ² )^ί^ 0 3.1-35 n γ^γ^ΟΗ ' o 3.1-36 Η (Ζ-2) _γ Ν^0Η ₃ ' ο 3.1-37 n Y^^^O^CHa ' o 3.1-38 Η ϊ· < _Z .2) _y K ₀ A _C h, ^Ί ο 3.1-39 СНз γγθΜ О 3.1-40 Η ^.(Ζ-2)^Ν^ СНз V Π /ν' ο θ θ 3.1-41 n (Z-2)^^ CF ₃ ^Ί LLC 3.1-42 Η ₍ ^ζ . _2)γ ^Ν . ^I ^{3 Ί} Ο Ο Ο 3.1-43 ,,(2-2)...1. _Ξ Τθ Υ ΪΑ 3.1-44 СНз (Ζ- ² )γΝ^ΟΡ ₃ ' ο θ'ο

- 186 044070

3.1-45 Η _.(Ζ-2)^Ν^ ΝΗ ₂ V Υ ^Ί 0 0 0 3.1-46 Η? ⁿ s γ ^(Ζ_2) γ ^Ν γ ^Ν ^ ^Η 3 ' 0 θ θ 3.1-47 Η γγ,,, 0 3.1-48 Η Υ ^(Ζ ' ²⁾ Υ ^Ν Υ° ^Η3 0 сн ₃ 3.1-49 Η γ^γΥ^ СНз ^Ί 0 сн ₃ 3.1-50 Η? ^Η 3 -τ/(Ζ-2)γ^Ν^ Λ Υ Υ η ^СНз 3.1-51 Η _ν ^)γ ^Ν ^ N^CH3 ⁰ ^CH3 3.1-52 γ^γΜ^ 3.1-53 (Ζ-3)γΝΗ ₂ ' 0 3.1-54 Η γΎ% _Η , ' 0 3.1-55 Η -, >Ζ-3)^Ν CH ₃ 5 Υ 0 3.1-56 Η _π ^(Ζ-3)γγΝ Ο * 3.1-57 CH ₃ (Z-3) _Y ^N .CH ₃ ' 0 3.1-58 (g-z^gC/* ο 3.1-59 _ν (ζ-3 _)γ Ο ο 3.1-60 (z- ₃ )^nC^ ' 0 3.1-61 Η (Ζ-γ,οΗ ' ο 3.1-62 Η ( _Z -3) _Y ^N . _O , ^CH3'o 3.1-63 Η ' 0 3.1-64 Η? ^Η 3 ν< ^ζ - ³ )γ^οΥθΗ ₃ 0 3.1-65 sn ₃ (Z-3)^N^. _{CH 3} 0 3.1-66 Η (Z-3).W _,CH ₃ 5 π & Ο Ο 0 3.1-67 Η (Ζ-3)γ.Ν CF ₃ V Υ A ο 0 0 3.1-68 Η (Z-3)^.N^ _s ^Y^CH ₃ ' Ο Ο ^Μ Ο 3.1-69 ο ο'ο 3.1-70 ΟΗ ₃ (ZS^N CF ₃ ν Υ ₀ Α

- 187 044070

3.1-71 Η (Z-SJ^N νη ₂ V Π 0 θ 0 3.1-72 n? ^Nz (ZS^N Ν ν UL ^СНз 3.1-73 Η γί^γ^ΝΗ, ' ο 3.1-74 Η (Z-SJ^N CH ₃ ^γ ϊ k 3.1-75 Η (Z-3)^N^^ _cH3 0 сн ₃ 3.1-76 Η? ^Η 3 γ ^ζ - ³ γ%Λ _ΟΗ3 3.1-77 Η γ ^ζ - ³ )γ%^0Η ₃ ⁰ ^gn СНз 3.1-78 Η I _ν <«>γΥΑ^ 3.1-79 (Ζ-4)γΝΗ ₂ ' 0 3.1-80 Η ' 0 3.1-81 Η -g/(2-4)^^sn ₃ ' 0 3.1-82 Η 1/(Ζ-4)γΝ\ ' Ο 3.1-83 СНз γ< ^ζ - ⁴ γ ^Ν ΑΗ ₃ 3.1-84 γζ-4)γθ* ’ Ο 3.1-85 γ ⁽ ~'γθ ο 3.1-86 γζ^γίΥ ⁴ 0 3.1-87 γ^γ^ΟΗ ' Ο 3.1-88 Η γί^γ^ο-^ ³ ' ο 3.1-89 Η (Ζ-4) _η /\ _ΓΗ s Π ° ^SMz ' 0 3.1-90 Η? ^Η Y^Y^AcH, ' 0 3.1-91 СНз Υ^γ^Ο^ ⁴ 0 3.1-92 Η Ι/ίΖ^ίγ/Ν^ СНз 5 Π А ^Ί Ο Ο Ο 3.1-93 Η £-4)^,^ CF ₃ 5 Π Λ' ^Ί 0 0 0 3.1-94 Η ^Ί 0 0 Ο 3.1-95 to o=/ >w °b 3.1-96 sn ₃ (Ζ-4)^,Ν^ CF ₃ ν Υ _Ο Α

- 188 044070

3.1-97 Η Τ>Ζ·4)^/Ν Νη ₂ ν τ _ο '% 3.1-98 Η? ' Ο Ο ο 3.1-99 Η 0 3.1-100 Η about sn ₃ 3.1-101 Η (Ζ-4)^^ СНз ^Ί 0 сн ₃ 3.1-102 Η? ^Η 3 3.1-103 Η N^CH ₃ ⁰ ^CH ₃ 3.1-104 η 2? ^NZ 3.1-105 (Ζ-5) _γ ΝΗ ₂ ' 0 3.1-106 Η _V < ^Z - ⁵ >Y%H3 ' 0 3.1-107 Η -, /(Ζ-5)χ^Ν CH ₃ 5 Π 0 3.1-108 Η ^.(Ζ-5) γχΝ._ ' Ο * 3.1-109 sn ₃ (Ζ-5)γ ^Ν ^Η ₃ ' 0 3.1-110 (zs^nO* ³ ο 3.1-111 [^Ό _γ (Ζ-5) _γ Ν^Ι ' Ο 3.1-112 (ζ-δ^ίγ* 0 3.1-113 Η γ^Ύ'ΟΗ ' ο 3.1-114 Η (Ζ-5)γΝ^,ΟΗ3 Ο 3.1-115 Η (Ζ-5)^^ Υ Π ° ^СНз ' 0 3.1-116 Η ?· ³ 0 3.1-117 СНз (Ζ-5) _γ Ν^ΟΗ ₃ ' O 3.1-118 Η -..(Ζ-δΙ^Ν^ СНз 5 Π Λ ^Ί ο ο ο 3.1-119 Η -,ΜΖ-δ^Ν CF ₃ V π Λ ο Ο Ο 3.1-120 Η _Ί /(Ζ-5)^,Ν^^^ΟΗ ₃ V π ο Ο Ο 3.1-121 ⁿ G ⁴ ! (Ζ-5) ο ο'ο 3.1-122 СНз (Z-5) _v N^CF ₃ О о'Ъ

- 189 044070

3.1-123 ^(Z-5)^^ NH ₂ V p & 0 ^{0 0} 3.1-124 n (Ζ-δ^Ν N V UL ^СНз 3.1-125 Η γ^Ιγ^ΝΗ, 'o 3.1-126 n υ^υΥ* O СНз 3.1-127 Η _V (Z-5) _V %^cH ₃ O сн ₃ 3.1-128 N? ^Н з ^)у%Л _СНз 3.1-129 n (ζ^γκ^ ⁰ k _C Ne 3.1-130 n I γ^ΥγΜ^ 3.1-131 (Ζ-6)γΝΗ ₂ ' O 3.1-132 n γ^γ^οΗ, 'o 3.1-133 n _p ΛΖ-6)^Ν CH ₃ 5 p o 3.1-134 n ^(Ζ-6)γ^.Ν ' O V 3.1-135 dn ₃ 'O 3.1-136 (g-b^gSu* o 3.1-137 O 3.1-138 (g-b)^SU o 3.1-139 n <ζ^) _γ N. _0Η ³ O 3.1-140 n ' O 3.1-141 n γ^γΧο^ΟΗ, 'o 3.1-142 N? ^H 3 ν( ^ζ -β)γ%-4 _Η3 o 3.1-143 СНз -^(Z-6)>^,N _Xo ^CH3 'О 3.1-144 n (Ζ-6)^.Ν CH ₃ ^Ί LLC 3.1-145 n (Ζ-β)^^ CF ₃ 5 P 'Zh ^Ί οοο 3.1-146 n Y^'Y^r ^Ί LLC 3.1-147 ⁿ (G ⁴ ] V T _o '% 3.1-148 СНз (Ζ-δ^Ν CF ₃ V p A ' o O O

- 190 044070

3.1-149 Η (Ζ-6)^Ν^ ΝΗ ₂ V π Λ 0 θ 0 3.1-150 n? ⁿ z (Ζ-Θ^Ν N V UL ^СНз 3.1-151 Η γ^γ^ΝΗ, ^Ζ 0 3.1-152 n (Ζ-6)^Ν^ΟΗ ₃ O sn ₃ 3.1-153 Η (ζ-βγ-γ^ ^Ί o sn ₃ 3.1-154 N? ^Н з ^)у%Л _СНз 3.1-155 Η _V (Z-6) _Y %^CH ₃ ⁰ ^CH ₃ 3.1-156 n I γγΛΑζ* 3.1-157 (Ζ-7)γΝΗ ₂ ' 0 3.1-158 n γ< ^ζ - ⁷ >γ%Η, ' o 3.1-159 Η -l/(Z-7) _x ^N _x/ CH ₃ ' 0 3.1-160 n ,/(Ζ-7)γΝ. ' ABOUT * 3.1-161 CH _{3 ν} ^)γ ^Ν ΥΗ ₃ 3.1-162 O 3.1-163 O 3.1-164 _γ (Ζ-7)γθ O 3.1-165 γ^γ^ΟΗ ' o 3.1-166 (Z-7)^N, _O ,CH3 ^Ί O 3.1-167 Η (Ζ-7)^,Ν h P ° ^cm z ' o 3.1-168 n ?· Υ^Υ^οΝη, o 3.1-169 СНз (Z-7)^N^ _o ^CH ₃ О 3.1-170 n Τ/(Ζ-7)^χΝ^ CH ₃ V p L ¹ O ^{0 0} 3.1-171 LL? ^О \хО ωί l/ ° >° & 3.1-172 n Y ^(Z - ⁷⁾ Y ^N ^r- ^{CH3 Ί} LLC 3.1-173 °=/ >t°b 3.1-174 СНз ^(Z-TJsxN^ xCF, V p A ' o θ θ

- 191 044070

3.1-175 Η νη ₂ ^Ί 0 0 0 3.1-176 Η ?· ' Ο θ Ο 3.1-177 Η γ< ^ζ · ⁷ 'γ ^Ν 'Ν _Ηι ⁷ 0 3.1-178 Η Ο 0¾ 3.1-179 Η (Ζ-7)^^ сНз ^Ί 0 сн ₃ 3.1-180 Η? ^NZ ,ΛΖ-ηνΛ γ γ Ν СНз 3.1-181 Η _ν (Ζ-7)γ%^οΗ3 ⁰ ^CH ₃ 3.1-182 Η I Y^Y^A^ 3.1-183 (Ζ-8)γΝΗ ₂ ' 0 3.1-184 Η γ<«>γ%Η ₃ 0 3.1-185 Η γ(ζ-8)γ%/Η ₃ ' 0 3.1-186 Η γΖ-8)γγΝ ' ο ν 3.1-187 sn ₃ t^y'Chnz ' 0 3.1-188 (Ζ-8)^νΟ ⁴ Ο 3.1-189 [^Ό γ^’γ^ ο 3.1-190 (Z-8)^nC^ 0 3.1-191 Η γ< ^Μ >γ ^Ν '0Η ' ο 3.1-192 Η _ν (Ζ-8) _γ Ν. _οΧ ΟΗ ₃ ' Ο 3.1-193 Η (Ζ-β^Ν 'Л Τ ° ^СНз ' ο 3.1-194 Η ?· y^ysAch, ' ο 3.1-195 СНз ^(Z^^N^AHa O 3.1-196 Η (Ζ-β)^Ν^ СНз ^Ί Ο Ο 0 3.1-197 Η (Ζ-δ)χ,Ν CF ₃ s Π Λ* ^Ί ο Ο 0 3.1-198 Η ^Ί 0 0 ο 3.1-199 ^Η G ⁴ ! (Ζ-8)^Ν^ V ΤΑ 3.1-200 сн ₃ (Ζ-δ^Ν CF ₃ V π A ' 0 θ θ

- 192 044070

3.1-201 Η (Ζ-δ^Ν ΝΗ ₂ V Π & ¹ 0 ^{0 0} 3.1-202 Η? ^Нз (Ζ-β^Ν Ν ν UL ^СНз 3.1-203 Η JZ-8K ^ΝΗ 2 ' Ο 3.1-204 Η (Ζ-8)^Ν^ СНз О сн ₃ 3.1-205 Η _V (Z-8) _V %^CH ₃ Ο сн ₃ 3.1-206 Η? ^NZ ο 3.1-207 Η _v (zb> _yYcHj ° ^СНз 3.1-208 Η I 3.1-209 (Ζ-9)γΝΗ ₂ ' 0 3.1-210 Η ' 0 3.1-211 Η -, >Ζ-9)^Ν CH ₃ 5 Π 0 3.1-212 Η ^(Ζ-9)^^.Ν ' O V 3.1-213 sn ₃ γ^γ ¹ ^ ' 0 3.1-214 (Z-9)yO* ⁴ Ο 3.1-215 |^Ό _γ (Ζ-9) _γ Ν^Ι ' Ο 3.1-216 -γζ-θγΐζ^ 0 3.1-217 Η γ^γ^ΟΗ ' ο 3.1-218 Η ^Ί ο 3.1-219 Η (Ζ-9)^,Ν^ Π ° ^СНз ' ο 3.1-220 Η ?· _ν < ^ζ · ⁹ 'γ ^Ν 'οΥ ⁴ ο 3.1-221 dc ₃ ο 3.1-222 Η _,(Ζ-9)^.Ν^ CH ₃ V π γ' Ο Ο 0 3.1-223 Η .,ΛΖ-θγΝ CF ₃ V π 'γ 3.1-224 Η (Z-gi^/N^^^^CHa V π γ' Ο Ο ο 3.1-225 τΛΖ-9>γ>< jQ X ΪΑ 3.1-226 СНз (Z-9) _V ^CF ₃ V π A ' o O O

- 193 044070

3.1-227 Η (g-9 _)x D _x νη ₂ V Υ Λ ο ο ο 3.1-228 n? ^N z (Ζ-Θ^Ν Ν γ ³ 3.1-229 Η ' o 3.1-230 Η ^(Z-9)^N^^CH ₃ Ο CH ₃ 3.1-231 Η ο CH, 3.1-232 Η? ^Η 3 (Ζ-Θ^Ν _V Υ Ν _СНз 3.1-233 Η _ν (Ζ-9) _γ %^οΗ ₃ ⁰ ^CH ₃ 3.1-234 η I ^3 Y^ysA^ 3.1-235 _ ,(Ζ-10)^,ΝΗ ₂ V Υ 0 3.1-236 Η Υ ^Ζ - ¹ Υ%Η ₃ 0 3.1-237 Η (Z-IOJ^N^CHg ' Ο 3.1-238 Η _π ^(Ζ-ΙΟΚ^Ν ' Ο * 3.1-239 dn ₃ ' 0 3.1-240 -^(Z-IOJ^nC^ ' ο 3.1-241 D'o (Ζ-ΙΟ)^Ν^Ι ' Ο 3.1-242 -γΖ-ΙΟί^Ν^Υ 0 3.1-243 Η _γ (Ζ·10) _γ % _Η ' 0 3.1-244 Η (Z-10)^N^ _oX CH ₃ ' ο 3.1-245 Η (Z.1O) _Y% ^CH, ' ο 3.1-246 Η? ^Η v< ³ -»Y%+ch, ο 3.1-247 CH ₃ (Z-10)^N^ _q ^CH ₃ O 3.1-248 Η _π (Ζ-10) /Ν CH ₃ X IT A o O O 3.1-249 Η ΥΖ-ΙΟ^Ν CF ₃ ^Ί oooh 3.1-250 n ₍ ^Ζ .Ό _Υ ^{Ν Ί} LLC 3.1-251 ⁿ A (Ζ-10)^Ν^Α>' o Ο ^Μ θ 3.1-252 sn ₃ (Z-IOJ^N^ CF ₃ ν Y «A,

- 194 044070

3.1-253 Η -, lg-yuk/ νη ₂ V π A ¹ 0 0 0 3.1-254 Η? ⁿ z V Τ A ^СНз οοο 3.1-255 Η ⁷ 0 3.1-256 Η -^(Z-10)^,N _x ^CH ₃ O sn ₃ 3.1-257 Η ⁷ 0 dn ₃ 3.1-258 n? ^Nz (Z-IO^N A Υ t ^{th he} · 3.1-259 Η _V (Z-1O) _T K ^сн° ^СН ₃ 3.1-260 n Η | ^NZ sn 5 Η n 3.1-261 0 3.1-262 n V ^z - ¹¹ >Y%h ₃ ' o 3.1-263 Η -ΐ /(Ζ-11)χ^Ν CH ₃ V π 0 3.1-264 n -,γΖ-ΙΙΚ^Ν ' O * 3.1-265 СНз (Ζ-11) _γ ^Ν _Υ Η ₃ ' 0 3.1-266 ^(z-id^-nC^ ⁷ o 3.1-267 ^0 (Ζ-11) _γ Ν^Ι ο 3.1-268 -^(z-ip^nC^ o 3.1-269 Η (ζ.ιυ _γ χ _οΗ ' 0 3.1-270 n T/lZ-ID^N^CHa ' O 3.1-271 Η yz-n> _Y %^ _cHi ⁷ 0 3.1-272 n P* ⁷ o 3.1-273 СНз (Z-11)^N^CH ₃ 0 3.1-274 n (Z-11)^N CH ₃ V p /I' LLC 3.1-275 Η .(Ζ-ΐη^,Ν^ CF ₃ % Π 'F ^Ί 0 0 0 3.1-276 n ooo 3.1-277 ,ΛΖ-ιιιΥ!, _S O γ ΤΑ 3.1-278 sn ₃ -^(Z-ID-^N CF ₃ ' LLC

- 195 044070

3.1-279 Η (Z-ID^N^ νη ₂ V π Α ¹ 0 0 0 3.1-280 Η? ⁿ z -^(Z-ID^N Ν V ΤΑ ³ ' ο Ο Ο 3.1-281 Η _γ < ^{ζ 11} >γ ^Ν 'ΝΗ ₂ 7 0 3.1-282 Η About SNz 3.1-283 Η СНз ^Ί Ο СН ₃ 3.1-284 Η? ^Η 3 V ^(z - ¹¹⁾ yX ^Ach ₃ 3.1-285 Η _ν (Ζ- ¹¹ )γ%^ΟΗ ₃ ° Chi sn ₃ 3.1-286 η I? ⁿ z yvA* 3.1-287 _^(Ζ-12)^ΝΗ ₂ ' 0 3.1-288 Η γ·< ^ζ <γ ^Ν Μ ' 0 3.1-289 Η -^(Z-IZ^N^CHg ' 0 3.1-290 Η ^(Ζ-ΙΖΚ^Ν ' Ο * 3.1-291 СНз ' ABOUT 3.1-292 _γ (Ζ-12) _γ Ν^ 3.1-293 ^(ζ-ιζ^ν^Χ o 3.1-294 γ(Ζ-12) _γ θ Ο 3.1-295 N (Ζ-12) _γ ^Ν . _ΟΗ 'O 3.1-296 Η (Ζ-12) _γ Ν^θ _χ ΟΗ ₃ ' Ο 3.1-297 (Z-12) _Y ^ _sn3'O 3.1-298 Η ΐ· Υ< ^Ζ ·'«Υ<οΧη3 ο 3.1-299 sn ₃ (Ζ-12) _γ Ν^γΗ ₃ O 3.1-300 Η (Ζ-ΙΖΙ^,Ν^ ΟΗ ₃ V π Α ¹ 0 Ο Ο 3.1-301 n ¢-12)./ 0^ 5 Π 'Λ OOO 3.1-302 Η _V < ^z - ¹² Y<s^ ^c * ο θ Ο 3.1-303 ^Η ίι T^Z-IZRJX γ Uo'o 3.1-304 sn ₃ (Ζ-12)^.Ν _Χ CF ₃ V Υ Α ' ο Ο Ο

- 196 044070

3.1-305 Η _,(Ζ-12)^,Ν^ ΝΗ ₂ ^Ί ο ο ο 3.1-306 Η? ^NZ (Ζ-12) ^ν _>Υ η ₃ ο ο' ⁴ ο 3.1-307 Η (Ζ-12) _γ Κ _ΝΗ! ' o 3.1-308 Η _γ (Ζ-12) _γ Ν^ΟΗ ₃ 0 сн ₃ 3.1-309 Η γζ-ιγγ ⁵ 0 СНз 3.1-310 Η? ^NZ ν ^(ζ - ¹²⁾ γ%ΛΟΗ3 3.1-311 Η (Ζ-Ι^Ν^^ ⁰ ΟΗ ₃ 3.1-312 Η I 3.1-313 _ ,(Ζ-13Κ,ΝΗ ₂ V Υ 0 3.1-314 Η _Υ ^Ζ - ¹³ _Υ %Η ₃ ' 0 3.1-315 Η (Z-ISJ^N^CHa ' 0 3.1-316 Η ^(Ζ-13) _γ ,Ν ' Ο * 3.1-317 СНз (Ζ-13) _γ Ν _χ θ _Η3 ' 0 3.1-318 .^(Ζ-13)^νΟ ⁴ ο 3.1-319 (Ζ-13)^Ν _Υ ' ο 3.1-320 ^¢-13)^0 ο 3.1-321 Η (Ζ-13) _γ Ν3 _0Η ' ο 3.1-322 Η <Ζ.13) _γ Ν^ΟΗ, Ο 3.1-323 ^-13)^^ sn ₃ ' Ο 3.1-324 Η? ^NZ V( ^Z -13)Y%A _C H ₃ ⁴ o 3.1-325 СНз _γ ( _Ζ -13) _γ Ν^ΟΗ ₃ О 3.1-326 Η (Ζ-13)^,Ν^ CH ₃ Π 'Μ' ^Ί Ο Ο Ο 3.1-327 Η (Ζ-ηΐ^,Ν^ CF ₃ 5 Π 'I' 0 0 0 3.1-328 Η UZ-13R,N /^CH ₃ V Υ A o O O 3.1-329 Ν ω >ω ъ 3.1-330 СНз (Z-13) _V ^CF ₃ ^Ί LLC

- 197 044070

3.1-331 Η Τ_ .(Ζ-13) _Χ .Ν^ ΝΗ ₂ V π Λ 0 θ Ο 3.1-332 n? ^Nz ( ^Ζ -13) ν θ ν _snz ' LLC 3.1-333 Η _γ < ^ζ ·'3> _γ %Η ₂ ^Ί 0 3.1-334 Η γ(Ζ-13)γΝ^^ΟΗ ₃ O sn ₃ 3.1-335 Η _V (Z-13) _V %^CH ₃ 0 сн ₃ 3.1-336 Η? ^Η Υ^Ύ^ΟΗ, 3.1-337 Η γ( ^ζ -ΐ3)γ%^ _Η3 νΗ ₃ 3.1-338 Η Am I? ^Η 3 3.1-339 -^(Ζ-14)γΝΗ ₂ 0 3.1-340 Η 0 3.1-341 Η -1 /(Ζ-14) _Χ .Ν CH ₃ V π 0 3.1-342 Η ^(Ζ-14) _γ .ν Ο 3.1-343 sn ₃ (Ζ-14) _γ Ν _ΧοΗ3 0 3.1-344 _γ .4 _)γ Ο Ο 3.1-345 (Ζ-14) _γ ί^ Ο 3.1-346 γ(Ζ-14)γθ 0 3.1-347 Η _γ <Ζ·14) _γ % _Η ' 0 3.1-348 Η (Ζ-14)γΝ^θ _χ ΟΗ ₃ ' Ο 3.1-349 Η _ν < ^ζ ·14> _τ %^ΟΗ, ' ο 3.1-350 Η ^ ³ V( ^z -14)Y%A _C h ₃ ⁴ Ο 3.1-351 СНз ^(Z-14)^N^ _o ^CH ₃ О 3.1-352 Η .(Ζ-14)^.Ν^ CH ₃ ^Ί ο ο ο 3.1-353 Η (Z-14)^.N^ CF ₃ V π · 0 ^{0 0} 3.1-354 Η ^(Z-14)^N^ _s y^CH ₃ 0 0'ο 3.1-355 η П ^-14кЛ<А> Уо'-ь 3.1-356 сн ₃ (Z-MJ^N^ CF ₃ V π A ο ο Ο

- 198 044070

3.1-357 N -,(Z-14).,N _X NH ₂ o o O 3.1-358 n? ^NZ (Z-14)^,h< N V T & ^{3 1} 000 3.1-359 n (Ζ-14) _γ Ν^ _ΝΗ3 O 3.1-360 n -γ(Ζ-14)γ.Ν _χ ^ΟΗ ₃ o sn ₃ 3.1-361 n O sn ₃ 3.1-362 n? ^NZ η/(Ζ-14)χ,Ν^ А Υ Υ th ^СНз 3.1-363 n γ'Ζ· ^,4 > _γ ^ - n, ⁰ Υη, 3.1-364 n? ? ^NZ 3.1-365 _γ (Ζ-15) _γ ΝΗ ₂ ^Ί O 3.1-366 n (Z.15) _y ⁿ . _c h ₃ O 3.1-367 Η π ^(Z-15)^N CH ₃ V Υ O 3.1-368 n _ ,(Ζ-15)γ,Ν ___ V Υ ν o ^ν 3.1-369 sn ₃ (Ζ-15) _γ Ν _γΗ3 ' O 3.1-370 (Ζ-15)^νΟ ' ABOUT 3.1-371 (Ζ-Ιδ^Ν^ O 3.1-372 _γ ( ^Ζ ' ¹ 5) _γ θ O 3.1-373 n (Ζ.15) _γ Ν^ _Η ' O 3.1-374 n -^(Ζ-ΙδΚ^θ,Ο^ O 3.1-375 n _γ (Ζ-15) _γ %^ΟΗ ₃ O 3.1-376 n G ^{3 Ί} O 3.1- 377 СНз -,(Ζ-15)^Ν _γ ^ΟΗ ₃ О 3.1-378 n - ,(z-15R,n ch ₃ S Υ Υ o θ θ 3.1-379 n - ,(Z-15)x,N CF ₃ 5 Υ ' o O O 3.1-380 n _ ΛΖ-15)^,ν x^СНз ъ Υ А ¹ 000 3.1-381 n G ⁴ ] ν y o- 3.1-382 СНз ,(Ζ-15)γ,Ν^ CF ₃ VY А о О О 3.1-383 n _Ί ,(ζ-15Κ,ν νη ₂ ^Ί o O O 3.1-384 n o O 0 3.1-385 n (Ζ-15) _γ N. _ΝΗ! ' O 3.1-386 n _γ (Ζ-15) _γ Ν^ CH ₃ O CH ₃ 3.1-387 n (Ζ-Ι^^,Ν 5 Υ 1 ^{СНз Ί} О сн ₃ 3.1-388 N? ^Нз ^ζ- ¹ ^ А _СНз ' 0 3.1-389 n _V ( ^Z -'S>Y^N-^CH, ⁰ ^CH ₃ 3.1-390 n I? ^N s

Table 3.2: compounds according to the invention 3.2-1-3.2-390 of general formula (II.2), with Z-(C=W)-N(R ⁿ )-R ¹² as defined in table. 3.1.

(P.2),

Table 3.3: compounds according to the invention 3.3-1-3.3-390 of general formula (II.3), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

- 199 044070

Table 3.4: compounds according to the invention 3.4-1-3.4-390 Z-(C=W)-N(R11)-R ¹² as defined in table. 3.1.

general formula (II.4), and

3.5-1-3.5-390

Table 3.5: compounds according to the invention Z-(C=W)-N(R11)-R ¹² as defined in table. 3.1.

general formula (II.5), and

3.6-1-3.6-390

Table 3.6: compounds according to the invention Z-(C=W)-N(R11)-R ¹² as defined in table. 3.1.

general formula (II.6), and

3.7-1-3.7-390

Table 3.7: compounds according to the invention Z-(C=W)-N(R11)-R ¹² as defined in table. 3.1.

general formula (II.7), and

3.8-1-3.8-390

Table 3.8: compounds according to the invention Z-(C=W)-N(R11)-R ¹² as defined in table. 3.1.

general formula (II.8), and

invention

Table 3.9: connections according to

Z-(C=W)-N(R11)-R ¹² , as defined in table. 3.1.

general formula (II.9), and

3.9-1-3.9-390

Table 3.10: compounds according to the invention Z-(C=W)-N(R11)-R ¹² as defined in table. 3.1.

general formula (II.10), and

3.10-1-3.10-390

Table 3.11: compounds according to the invention 3.11-1-3.11-390 of general formula (II.11), with Z-(C=W)-N(R11)-R ¹² as defined in table. 3.1.

- 200 044070

Table 3.12: compounds according to the invention 3.12-1-3.12-390 Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.12), and

3.13-1-3.13-390

Table 3.13: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.13), and

3.14-1-3.14-390

Table 3.14: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.14), and

3.15-1-3.15-390

Table 3.15: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.15), and

3.16-1-3.16-390

Table 3.16: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.16), and

3.17-1-3.17-390

Table 3.17: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.17), and

Table 3.18: compounds according to the invention 3.18-1-3.18-390 of the general formula (II. 18), Z-(C=W)-N(R ¹¹ )-R ¹² , as defined in table. 3.1.

and

Table 3.19: compounds according to the invention 3.19-1-3.19-390 of general formula (II.19), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

- 201 044070

H ₃ C (II. 19),

Table 3.20: compounds according to the invention 3.20-1-3.20-390 of general formula (II.20), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

N-q

I] n ₂ s ^: (P.20),

Table 3.21: compounds according to the invention 3.21-1-3.21-390 of general formula (II.21), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P.21),

Table 3.22: compounds according to the invention 3.22-1-3.22-390 of general formula (II.22), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P.22),

Table 3.23: compounds according to the invention 3.23-1-3.23-390 of general formula (II.23), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P 23),

Table 3.24: compounds according to the invention 3.24-1-3.24-390 of general formula (II.24), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P.24),

Table 3.25: compounds according to the invention 3.25-1-3.25-390 of general formula (II.25), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P 25),

Table 3.26: compounds according to the invention 3.26-1-3.26-390 of general formula (II.26), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

- 202 044070 (11.26),

Table 3.27: compounds according to the invention 3.27-1-3.27-390 of general formula (II.27), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P.27),

Table 3.28: compounds according to the invention 3.28-1-3.28-390 of general formula (II.28), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P.28),

Table 3.29: compounds according to the invention 3.29-1-3.29-390 of general formula (II.29), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P 29),

Table 3.30: compounds according to the invention 3.30-1-3.30-390 of general formula (II.30), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P.30),

Table 3.31: compounds according to the invention 3.31-1-3.31-390 of general formula (II.31), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P.31),

Table 3.32: compounds according to the invention 3.32-1-3.32-390 of general formula (II.32), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P 32),

Table 3.33: compounds according to the invention 3.33-1-3.33-390 of general formula (II.33), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

- 203 044070 (P.ZZ),

Table 3.34: compounds according to the invention 3.34-1-3.34-390 of general formula (II.34), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P.34),

Table 3.35: compounds according to the invention 3.35-1-3.35-390 of general formula (II.35), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

(P.35),

Table 3.36: compounds according to the invention 3.36-1-3.36-390 of general formula (II.36), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

Table 3.37: compounds according to the invention 3.37-1-3.37-390 of general formula (II.37), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

CH ₃ (P.37),

Table 3.38: compounds according to the invention 3.38-1-3.38-390 of general formula (II.38), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

Table 3.39: compounds according to the invention 3.39-1-3.39-390 of general formula (II.39), with Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

- 204 044070

Table 3.40: compounds according to the invention 3.40-1-3.40-390 Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.40), and

Table 3.41: compounds according to the invention 3.41-1-3.41-390 of the general formula (II.41), Z-(C=W)-N(R ¹¹ )-R ¹² , as defined in table. 3.1.

and

Table 3.42: compounds according to the invention 3.42-1-3.42-390 of the general formula (II.42), Z-(C=W)-N(R ¹¹ )-R ¹² , as defined in table. 3.1.

and

Table 3.43: compounds according to the invention 3.43-1-3.43-390 of the general formula (II.43), Z-(C=W)-N(R ¹¹ )-R ¹² , as defined in table. 3.1.

and

Table 3.44: compounds according to the invention 3.44-1-3.44-390 of the general formula (II.44), Z-(C=W)-N(R ¹¹ )-R ¹² , as defined in table. 3.1.

and

Table 3.45: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.45), and (A.44),

3.45-1-3.45-390

- 205 044070

Table 3.46: compounds according to the invention 3.46-1-3.46-390 of the general formula (II.46), wherein

Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

Table 3.47: compounds according to the invention 3.47-1-3.47-390 Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.47), and

3.48-1-3.48-390

Table 3.48: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.48), and

Table 3.49: compounds according to the invention 3.49-1-3.49-390 Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.49), and

(P.49),

Table 3.50: compounds according to the invention 3.50-1-3.50-390 Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.50), and

He·

Table 3.51: compounds according to the invention 3.51-1-3.51-390 Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.51), and

Table 3.52: compounds according to the invention 3.52-1-3.52-390 Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.52), and

- 206 044070

Table 3.53: compounds according to the invention 3.53-1-3.53-390 Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.53), and

3.54-1-3.54-390

Table 3.54: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.54), and

3.55-1-3.55-390

Table 3.55: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.55), and

3.56-1-3.56-390

Table 3.56: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.56), and

3.56-1-3.56-390

Table 3.57: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.57), and

3.56-1-3.56-390

Table 3.58: compounds according to the invention Z-(C=W)-N(R ¹¹ )-R ¹² as defined in table. 3.1.

general formula (II.58), and

B. Examples of compositions.

1. Pollination products.

The pollination agent can be obtained by mixing 10 wt. including compounds of general formula (I) and 90 wt. including talc as an inert substance and crushed in a hammer crusher.

2. Dispersible powder.

Water-dispersible, wettable powder is obtained by mixing 25 wt. including compounds of general formula (I), 64 wt. including quartz containing kaolin as an inert substance, 10 wt. including potassium lignin sulfonic acid and 1 wt. including sodium oleoylmethyl taurine as a wetting agent and dispersant and crushed in a pin crusher.

- 207 044070

3. Dispersed concentrate.

A dispersion concentrate that is easily dispersible in water is obtained by mixing 20 wt. including compounds of general formula (I), 6 wt. including alkylphenol polyglycol ether (© Triton X 207), 3 wt. including isotridecanol polyglycol ether (8 EO) and 71 wt. including paraffinic mineral oil (boiling range, for example, approximately 255-277 ° C) and grinding in a ball grinder to a grinding fineness of 5 microns.

4. Emulsifiable concentrate.

The emulsifiable concentrate is obtained from 15 wt. including compounds of general formula (I), 75 wt. including cyclohexanone as a solvent and 10 wt. including oxoethylated nonylphenol as an emulsifier.

5. Water-dispersible granulate.

The granulate dispersible in water is obtained by mixing 75 wt. including a compound of formula (I), calcium lignin sulfonic acid, sodium lauryl sulfate, polyvinyl alcohol, and kaolin, grinding in a pin crusher and granulating the powder in a fluidized bed by spraying water as a granulating liquid.

Water-dispersible granulate can also be obtained by homogenizing 25 wt. including compounds of formula (I),

2,2'-dinaphthylmethane-6,6'-disulfonic acid sodium, oleoylmethyl taurine acid, polyvinyl alcohol, calcium carbonate, and water in a colloid mill and by preliminary grinding, subsequent grinding in a bead mill and spraying the thus obtained suspension in a scrubber using a mononozzle and drying.

C. Biological examples.

Description of experiments.

1. Herbicidal effect on harmful plants in the pre-emergence period and compatibility with cultivated plants.

Seeds of mono- or bicotyledonous weeds or cultivated plants were placed in plastic or wood fiber pots and covered with soil. The compounds according to the invention, represented by a wettable powder (WP) or an emulsion concentrate (EC), were applied to the surface of the earth in the form of an aqueous suspension or emulsion with the addition of 0.5% additives at a water consumption rate calculated as 600 l/ha. After treatment, the pots were placed in a greenhouse and good growing conditions were created for the test plants. Approximately 3 weeks, the effect of the drugs was visually assessed, compared with the untreated control group in percentage terms. For example, 100% effect = plants died, 0% effect = like control plants.

The following abbreviations have been used in the following table.

Unwanted plants/weeds.

ABUTH: Abutilon theophrasti ALOMY: Alopecurus myosuroides AMARE: Amaranthus retroflexus AVEFA: Avena fatua ECHCG: Echinochloa crus-galli HORMU: Hordeum murinum LOLRI: Lolium rigidum MATIN: Matricaria inodora PHBPU: Pharbitis purpurea POLCO: Polygonum convolvulus SETVI: Setaria viridis STEME: Stellaria media VERPE: Veronica persica VIOTR: Viola tricolor

- 208 044070

Table 4.1

Herbicidal effect against ALOMY in % in the pre-emergence period Herbicidal effect against [%]

Example Application rate [g/ha] ALOMY 1-002 80 90 1-004 80 100 1-006 80 100 1-012 80 100 1-013 80 100 P-02 80 90 P-04 80 100 P-06 80 90 P-07 80 100 II-12 80 90 II-16 80 100 Ш-02 80 100 Ш-04 80 100 Ш-06 80 100 IV-01 80 90 IV-02 80 100 IV-03 80 90 IV-04 80 90 IV-05 80 80 IV-06 80 100 IV-07 80 100

Table 4.2 Herbicidal effect against AVEFA in % in the pre-emergence period Herbicidal effect against [%]

Example Application rate [g/ha] AVEFA 1-002 80 80 1-004 80 90 1-006 80 90 1-012 80 90 1-013 80 100 P-02 80 90 P-04 80 80 P-06 80 90 P-07 80 80 II-12 80 80 II-16 80 80 Ш-02 80 80 Ш-04 80 90

- 209 044070

Table 4.3

Herbicidal effect against CYPRES in % in the pre-emergence period

Herbicidal effect against [%] Example Application rate [g/ha] CYPES 1-003 80 100 1-006 80 100 II-16 80 100

Table 4.4

Herbicidal effect against ECHCG in % in the pre-emergence period Herbicidal effect against [%]

Example Application rate [g/ha] ECHCG 1-002 80 90 1-004 80 100 1-006 80 100 1-012 80 100 1-013 80 100 P-02 80 80 P-04 80 90 P-06 80 90 P-07 80 90 II-16 80 100 Ш-04 80 90 Ш-06 80 90 IV-02 80 90 IV-04 80 90 IV-06 80 90

- 210 044070

Table 4.5

Herbicidal effect against LOLRI in % in the pre-emergence period Herbicidal effect against [%]

Example Application rate [g/ha] LOLRI 1-002 80 100 1-004 80 90 1-006 80 100 1-012 80 100 1-013 80 100 P-02 80 90 P-04 80 90 P-06 80 100 P-07 80 100 II-12 80 90 II-16 80 100 Ш-02 80 100 Ш-04 80 100 Ш-06 80 100 IV-01 80 100 IV-02 80 100 IV-04 80 100 IV-06 80 100 IV-07 80 90

- 211 044070

Table 4.6

Herbicidal action against

- 212 044070

Table 4.8

Herbicidal action against

- 213 044070

Table 4.10

Herbicidal effect against PHBPU in % in the pre-emergence period Herbicidal effect against [%]

Example Application rate [g/ha] PHBPU 1-002 80 90 1-004 80 90 1-006 80 90 1-012 80 90 1-013 80 90 P-02 80 90 Ш-02 80 80 Ш-04 80 90 Ш-06 80 80 IV-02 80 80 IV-06 80 90 IV-07 80 90

Table 4.11

Herbicidal effect against POLCO in % in the pre-emergence period

Herbicidal effect against [%] Example- Norm Oh and number consumption [g/ha] Oh Ri 1-002 80 90 1-003 80 80 1-004 80 100 1-006 80 80 1-012 80 90 1-013 80 90 P-02 80 100 P-04 80 90 P-06 80 80 P-07 80 100 II-12 80 100 II-16 80 90 Ш-04 80 100 Ш-06 80 100 IV-01 80 90 IV-02 80 100 IV-06 80 80 IV-07 80 80

- 214 044070

Table 4.12

Herbicidal action against

- 215 044070

Table 4.13

Herbicidal action against

- 216 044070

Table 4.15

Herbicidal action against

As the results show, the compounds according to the invention, such as compounds No. I-002 and other compounds from tables (I-004, I-006, I-012, I-013, II-02, II-04, II-06 , II-07, II-12, II-16, III-02, III-04, III-06, IV-01, IV-02, IV-04, IV-06, IV-07) when processed in the post-emergence period show very good effectiveness (80-100% herbicidal effect) against such harmful plants as Abutilon theophrasti, Alopecurus myosuroides, Amaranthus retroflexus, Echinochloa crus-galli, Hordeum murinum, Lolium rigidum, Matricaria inodora, Pharbitis purpurea, Polygonum convolvulus, Setaria viridis, Stellaria media, Veronica persica and Viola tricolor, at a rate of 0.08 kg of active ingredient or less per hectare.

2. Herbicidal effect on harmful plants in the pre-emergence period and compatibility with cultivated plants.

Seeds of mono- or dicotyledonous weeds or cultivated plants were placed in plastic or wooden pots in sandy loam, covered with soil and grown in a greenhouse under controlled growth conditions. 2-3 weeks after sowing, the test plants were treated at the first leaf stage. The green parts of the plants were sprayed with the compounds according to the invention, represented by a wetting powder (WP) or an emulsion concentrate (EC), in the form of an aqueous suspension or emulsion with the addition of 0.5% additives at a water consumption rate calculated as 600 l/ha. The test plants were kept in a greenhouse for approximately 3 weeks, under optimal growth conditions, and the effect of the drugs was visually assessed in comparison with the untreated control group. For example, 100% effect = plants died, 0% effect = like control plants.

- 217 044070

Table 5.1

Herbicidal action against

- 218 044070

- 219 044070

- 220 044070

- 221 044070

Table 5.2

Herbicidal effect against AVEFA in % in the post-emergence period

Herbicidal effect against [%] Example Application rate [g/ha] AVEFA 1-002 80 80 1-004 80 90 1-006 80 80 1-007 80 90 1-008 80 90 1-009 80 90 1-010 80 90 1-011 80 90 1-012 80 100 1-013 80 90 1-014 80 90 1-015 80 100 1-016 80 90 1-017 80 100 1-018 80 100 1-019 80 100 1-020 80 100 1-021 80 100 1-022 80 100 1-023 80 90 1-024 80 100 1-025 80 90 1-026 80 100 1-027 80 90 1-028 80 100 1-029 80 80 1-030 80 100 1-031 80 90 1-032 80 100 1-033 80 90 1-034 80 90 1-035 80 90

- 222 044070

- 223 044070

- 224 044070

- 225 044070

Table 5.3

Herbicidal action against

- 226 044070

- 227 044070

- 228 044070

- 229 044070

Table 5.4

Herbicidal effect against LOLRI in % in the post-emergence period Herbicidal effect against [%]

Example Application rate [g/ha] LOLRI 1-002 80 80 1-004 80 80 1-006 80 80 1-007 80 90 1-008 80 90 1-009 80 90 1-010 80 90 1-011 80 90 1-012 80 90 1-013 80 90 1-014 80 90 1-015 80 100 1-016 80 100 1-017 80 100 1-018 80 100 1-019 80 90 1-020 80 90 1-021 80 90 1-022 80 100 1-023 80 90 1-024 80 90 1-025 80 90 1-026 80 90 1-027 80 90 1-028 80 90 1-029 80 90 1-030 80 100 1-031 80 100 1-032 80 90 1-033 80 90 1-034 80 100 1-035 80 90

- 230 044070

- 231 044070

- 232 044070

- 233 044070

- 234 044070

Table 5.5

Herbicidal action against

- 235 044070

- 236 044070

- 237 044070

- 238 044070

Table 5.6

Herbicidal effect against ABUTH in % in the post-emergence period Herbicidal effect against

[%]

Example Application rate [g/ha] ABUTH 1-007 80 80 1-008 80 90 1-009 80 90 1-010 80 80 1-012 80 80 1-013 80 80 1-015 80 90 1-016 80 90 1-017 80 100 1-018 80 90 1-019 80 80 1-020 80 80 1-021 80 80 1-022 80 90 1-023 80 80 1-024 80 80 1-027 80 80 1-028 80 80 1-033 80 80 1-034 80 80 1-035 80 80 1-036 80 80 1-037 80 90 1-038 80 80 1-039 80 80 1-040 80 80 1-041 80 80 1-042 80 80 1-043 80 80 1-044 80 90 1-045 80 80 1-046 80 90 1-048 80 80 1-050 80 80 1-051 80 80 1-052 80 90 1-055 80 80

- 239 044070

- 240 044070

- 241 044070

Table 5.7

Herbicidal action against

- 242 044070

- 243 044070

1-064 80 90 1-065 80 80 1-066 80 90 1-067 80 80 1-068 80 80 1-069 80 80 1-070 80 90 1-071 80 80 1-072 80 80 1-073 80 80 1-075 80 90 1-076 80 90 1-077 80 80 1-079 80 90 1-080 80 90 1-081 80 80 1-082 80 90 1-083 80 90 1-084 80 90 1-085 80 90 1-086 80 90 1-087 80 90 1-088 80 90 1-089 80 90 1-090 80 90 1-092 80 90 1-093 80 80 P-38 80 90 P-39 80 80 Ш-02 80 80 Ш-04 80 80 Ш-06 80 80 Ш-07 80 90 Ш-08 80 80 Ш-09 80 90 III-10 80 90 III-12 80 90 III-13 80 90 III-16 80 90 III-17 80 90 IV-04 80 80 IV-06 80 80 IV-07 80 80 IV-10 80 80 V-01 80 80 V-04 80 80

-244044070

Table 5.8

Herbicidal effect against MATIN in % in the post-emergence period Herbicidal effect against [%]

Example Application rate [g/ha] MATIN 1-002 80 80 1-008 80 90 1-009 80 90 1-011 80 80 1-012 80 90 1-013 80 90 1-015 80 80 1-016 80 80 1-017 80 80 1-018 80 80 1-019 80 90 1-020 80 90 1-022 80 80 1-023 80 90 1-024 80 80 1-027 80 90 1-028 80 80 1-031 80 80 1-032 80 80 1-033 80 90 1-036 80 80 1-037 80 80 1-038 80 90 1-039 80 80 1-040 80 80

- 245 044070

- 246 044070

Table 5.9

Herbicidal effect against PHBPU in % in the post-emergence period Herbicidal effect against [%]

Example Application rate [g/ha] PHBPU 1-002 80 80 1-006 80 80 1-007 80 90 1-008 80 90 1-009 80 90 1-010 80 90 1-012 80 90 1-013 80 80 1-020 80 80 1-021 80 80 1-023 80 80 1-026 80 80 1-030 80 80 1-031 80 80 1-033 80 80 1-037 80 80 1-038 80 80 1-039 80 80 1-044 80 80 1-045 80 80 1-048 80 80 1-049 80 90 1-051 80 80 1-052 80 80 1-053 80 80

- 247 044070

- 248 044070

- 249 044070

Table 5.10

Herbicidal action against

- 250 044070

- 251 044070

- 252 044070

Table 5.11

Herbicidal action against

- 253 044070

- 254 044070

- 255 044070

- 256 044070

Table 5.12

Herbicidal effect against VIOTR in % in the post-emergence period Herbicidal effect against [%]

Example Application rate [g/ha] VIOTR 1-012 80 80 1-013 80 80 1-014 80 90 1-015 80 90 1-016 80 80 1-017 80 80 1-019 80 80 1-020 80 100 1-022 80 80 1-023 80 80 1-024 80 80 1-027 80 80 1-028 80 80 1-029 80 80 1-032 80 80 1-036 80 90 1-037 80 90 1-038 80 80 1-052 80 80 1-055 80 90 1-057 80 80 1-058 80 90 1-060 80 80 1-061 80 80 1-062 80 80 1-063 80 80 1-064 80 80 1-065 80 90 1-067 80 80 1-068 80 90 1-071 80 80 1-072 80 80 1-075 80 90 1-076 80 80 1-077 80 80 1-080 80 80 1-082 80 90 1-083 80 90 1-084 80 90 1-085 80 80

- 257 044070

1-087 80 90 1-088 80 90 1-089 80 90 1-090 80 90 1-092 80 80 1-093 80 80 1-094 80 90 1-096 80 90 1-097 80 80 1-098 80 80 1-099 80 80 I-100 80 80 P-07 80 80 II-10 80 90 II-I 80 90 II-14 80 90 P-31 80 90 P-33 80 90 P-34 80 90 P-35 80 90 P-36 80 90 P-37 80 90 P-38 80 80 Ш-07 80 90 Ш-08 80 80 Ш-09 80 90 III-10 80 90 III-12 80 90 III-16 80 90 III-17 80 80 IV-04 80 80 IV-06 80 90 IV-07 80 80 V-01 80 90 V-04 80 80

- 258 044070

Table 5.13

Herbicidal action against

- 259 044070

1-043 80 80 1-046 80 80 1-048 80 80 1-049 80 80 1-051 80 80 1-052 80 80 1-053 80 80 1-054 80 90 1-055 80 80 1-056 80 80 1-057 80 80 1-058 80 80 1-059 80 80 1-061 80 90 1-062 80 90 1-063 80 80 1-064 80 80 1-065 80 80 1-066 80 80 1-067 80 80 1-068 80 80 1-069 80 80 1-070 80 80 1-071 80 80 1-072 80 80 1-073 80 80 1-075 80 90 1-076 80 80 1-077 80 90 1-079 80 90 1-080 80 90 1-081 80 80 1-082 80 90 1-083 80 90 1-084 80 90 1-085 80 90

- 260 044070

- 261 044070

III-13 80 80 III-16 80 80 III-17 80 90 IV-07 80 80 V-01 80 80 V-04 80 80

Table 5.14

Herbicidal effect against HORMU in % in the post-emergence period Herbicidal effect against [%]

Example Application rate [g/ha] HORMU 1-006 80 80 1-007 80 90 1-008 80 90 1-009 80 90 1-010 80 90 1-011 80 80 1-012 80 100 1-013 80 90 1-014 80 80 1-015 80 100 1-016 80 90 1-017 80 100 1-018 80 90 1-019 80 90 1-020 80 80 1-021 80 90 1-022 80 80 1-023 80 80 1-024 80 80 1-025 80 80 1-026 80 90 1-027 80 80 1-028 80 80 1-029 80 80 1-030 80 90

- 262 044070

- 263 044070

- 264 044070

- 265 044070

As the results show, the compounds according to the invention, such as compounds No. I-002 and other compounds from tables (I-004, I-006, I-007, I-008, I-009, I-010, I-011 , I-012, I-013, I-014, I-015,

I-016, I-017, I-018, I-019, I-020, I-021, I-022, I-023, I-024, I-025, I-026, I-027, I- 028, I-029, I-030, I-031, I-032,

I-033, I-034, I-035, I-036, I-037, I-038, I-039, I-040, I-041, I-042, I-043, I-044, I- 045, I-046, I-047, I-048, I-049,

I-050, I-051, I-052, I-053, I-054, I-055, I-056, I-057, I-058, I-059, I-060, I-061, I- 062, I-063, I-064, I-065, I-066,

I-067, I-068, I-069, I-070, I-071, I-072, I-073, I-074, I-075, I-076, I-077, I-078, I- 079, I-080, I-081, I-082, I-083,

I-084, I-085, I-086, I-087, I-088, I-089, I-090, I-091, I-092, I-093, I-094, I-095, I- 096, I-097, I-098, I-099, I-100,

I-104, II-02, II-04, II-06, II-07, II-08, II-09, II-10, II-11, II-12, II-14, II-15, II- 16, II-18, II-22, II-25, II-26, II-27, II-28, II-29, II-30, II-31, II-32, II-33, II-34, II-35, II-36, II-37, II-39, III-02, III-06, III-07, III-08, III-09, III-10, III-12, III-13, III- 16, III-17, IV-02, IV-04, IV-06, IV-07, IV-10, V-01, V-04) when treated in the post-emergence period show very good efficiency (80-100% herbicidal effect ) against such harmful plants as Abutilon theophrasti, Alopecurus myosuroides, Avena fatua, Echinochloa crus-galli, Hordeum murinum, Lolium rigidum, Pharbitis purpurea, Polygonum convolvulus, Setaria viridis, Stellaria media, Veronica persica and Viola tricolor, at an application rate of 0, 08 kg of active ingredient or less per hectare.

Claims (9)

1. 3-Phenylisoxazoline-5-carboxamide of general formula (I) or its agrochemically acceptable salts, in which G is a group of the formula OR ⁴ or NR11R ¹² ; R ¹ and R ² are in each case hydrogen; R ³ means (C1- _C3 )-alkyl, ( _C3 - _C4 )-cycloalkyl, ( _C2 - _C3 )-alkenyl or (C1- _C3 )-alkoxy, substituted by m residues from the group consisting of halogen and cyano; R ⁴ means hydrogen or (C1-C ₆ )-alkyl, (C ₃ -C ₆ )-cycloalkyl, (C ₃ -C ₆ )-cycloalkyl-(C ₁ -C ₆ )-alkyl, (C ₂ -C ₆ )-alkenyl, (C ₅ -C ₆ )-cycloalkenyl or (C ₂ -C ₆ )-alkynyl, in each case substituted by m residues from the group consisting of halogen, cyano, (C1-C ₆ )-alkoxy, phenyl; Y is for oxygen; W stands for oxygen; Z means group Z-1, Z-4 and Z-6: Z-1 Z-4 Z-6, with the arrow respectively indicating the connection with the C=W group of formula (I); R ¹¹ and R ¹² mean independently in each case hydrogen, OR ⁷ , S(O)nR ⁵ , SO2NR6R ⁷ , CONR6R ⁸ , NR ⁶ R ⁸ , NR6CO2R 8 , NR6SO2R ⁸ , NR ⁶ SO2NR ⁶ R ⁸ or ⁽ C1-C6)-alkyl, in each case substituted by m residues from the group consisting of halogen, cyano, OR ⁷ , S(O)nR ⁵ , SO2NR6R ⁷ , CONR6R ⁸ , NR ⁶ R ⁸ , NR ⁶ CO2R ⁸ , NR ⁶ SO2R ⁸ , NR ⁶ SO2NR ⁶ R ⁸ ; or R ¹¹ and R ¹² together with the nitrogen atom to which they are attached form an unsubstituted or one to two times substituted by residues from the group consisting of (C1- _C3 )-alkyl and oxo, saturated or partially unsaturated five- or six-membered ring which in addition to said nitrogen atom contains r carbon atoms, o oxygen atoms as ring atoms; X ² , X ⁴ and X ⁶ each mean, independently of each other, hydrogen or fluorine; X ³ and X ⁵ mean, independently of each other, in each case hydrogen, fluorine, chlorine, cyano or (C1-C ₃ )-alkyl or (C1-C ₃ )-alkoxy, in each case substituted by m radicals from the group consisting of fluorine; R ⁵ is (C1-C ₆ )-alkyl, in each case substituted by m residues from the group consisting of halogen; R ⁶ is hydrogen or R ⁵ ; R ⁷ is hydrogen or (C1- _C6 )-alkyl, in each case substituted by m residues from the group consisting of halogen, cyano and (C1- _C2 )-alkoxy; R ⁸ is hydrogen or (C1-C ₆ )-alkyl, in each case substituted by m residues from the group consisting of halogen, cyano and (C1-C ₂ )-alkoxy; m means the ordinal number 0, 1, 2 or 3; n means the ordinal number 0, 1 or 2; o means the ordinal number 0 or 1; And - 266 044070 r means the ordinal number 3, 4 or 5. 2. The compound of general formula (I) according to claim 1, in which G means a group of the formula OR ⁴ ; R ¹ and R ² are in each case hydrogen; R ³ is (C ₁ -C ₃ )-alkyl, (C ₃ -C ₄ )-cycloalkyl, (C ₂ -C ₃ )-alkenyl or (C ₁ -C ₃ )-alkoxy; R ⁴ means hydrogen or (C1-C6)-alkyl, (C ₃ -C6)-cycloalkyl, (C ₃ -C ₆ )-cycloalkyl-(C1-C ₆ )-alkyl, (C ₂ -C ₆ )-alkenyl , (C ₅ -C ₆ )-cycloalkenyl or (C ₂ -C ₆ )-alkynyl; Y is for oxygen; W stands for oxygen; Z means group Z-1: wherein the arrow in each case denotes a connection with the C=W group of formula (I); X ² , X ⁴ and X ⁶ each mean, independently of each other, hydrogen or fluorine; X ³ and X ⁵ are independently in each case hydrogen, fluorine, chlorine, CF ₃ , CHF ₂ or methyl. 3. The compound of general formula (I) according to claim 1, in which G represents a group of the formula NR11R ¹² ; R ¹ and R ² are in each case hydrogen; R ³ means (C ₁ -C ₃ )-alkyl, (C ₃ -C ₄ )-cycloalkyl, (C ₂ -C ₃ )-alkenyl or (C1-C ₃ )-alkoxy, in each case substituted by m residues from the group , consisting of fluorine, chlorine and (C1- _C2 )-alkoxy; Y is for oxygen; W stands for oxygen; Z means group Z-1, Z-4 and Z-6: wherein the arrow in each case denotes a connection with the C=W group of formula (I); X ² , X ⁴ and X ⁶ each mean, independently of each other, hydrogen or fluorine; X ³ and X ⁵ are, independently of each other, hydrogen, fluorine, chlorine, CF ₃ , CHF 2 or methyl; R ⁵ is (C1-C ₆ )-alkyl, in each case substituted by m residues from the group consisting of fluorine and chlorine; R ⁶ is hydrogen or R ⁵ ; R ⁷ is hydrogen or (C ₁ -C ₆ )-alkyl, in each case substituted by m residues from the group consisting of fluorine, chlorine and (C1-C ₂ )-alkoxy; R ⁸ is hydrogen or (C 1 -C ₆ )-alkyl or (C ₃ -C ₆ )-cycloalkyl, in each case substituted by m residues from the group consisting of fluorine, chlorine and (C ₁ -C ₂ )-alkoxy; R ¹¹ is hydrogen or (C1- _C3 )-alkyl, in each case substituted by m residues from the group consisting of fluorine and chlorine; R ¹² is hydrogen, OR ⁷ , S(O)nR ⁵ , SO2NR6R ⁷ , NR6R ⁸ or NR6SO2R ⁸ or (C1-C ₆ )-alkyl, in each case substituted by m radicals from the group consisting of fluorine, chlorine, cyano, OR ⁷ , S(O)nR ⁵ , NR ⁶ R ⁸ , NR ⁶ CO2R ⁸ ; or R ¹¹ and R ¹² together with the nitrogen atom to which they are attached form an unsubstituted or one to two times substituted by residues from the group consisting of (C ₁ -C ₃ )-alkyl and oxo, saturated or partially unsaturated five- or six-membered a ring which, in addition to said nitrogen atom, contains r carbon atoms, o oxygen atoms as ring atoms; m means the ordinal number 0, 1, 2 or 3; n means the ordinal number 0, 1 or 2; o means ordinal number 0 or 1; r means ordinal number 3, 4 or 5. 4. Herbicidal agent, characterized in that it contains one or more compounds of general formula (I) or their salts according to one of claims 1-3. 5. The herbicidal agent according to claim 4, which additionally contains a formulation auxiliary. 6. A method for controlling unwanted plants, characterized in that an effective amount of at least one compound of formula (I) according to one of paragraphs. 1-3 or one herbicidal agent according to claim 4 or 5 is applied to plants or to the place where unwanted plants grow. - 267 044070 7. Use of compounds of formula (I) according to one of claims 1 to 3 or a herbicidal agent according to claim 4 or 5 for the control of unwanted plants. 8. Use according to claim 7, characterized in that the compounds of formula (I) are used to control unwanted plants in crops of useful plants. 9. Use according to claim 8, characterized in that the useful plants are transgenic useful plants.