EA021808B1 - Производные фенил(окси/тио)алканола, способ борьбы с фитопатогенными вредными грибами, средство для борьбы с фитопатогенными вредными грибами и способы получения производных фенил(окси/тио)алканола - Google Patents

Производные фенил(окси/тио)алканола, способ борьбы с фитопатогенными вредными грибами, средство для борьбы с фитопатогенными вредными грибами и способы получения производных фенил(окси/тио)алканола Download PDF

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EA021808B1
EA021808B1 EA201270136A EA201270136A EA021808B1 EA 021808 B1 EA021808 B1 EA 021808B1 EA 201270136 A EA201270136 A EA 201270136A EA 201270136 A EA201270136 A EA 201270136A EA 021808 B1 EA021808 B1 EA 021808B1
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thio
formula
oxy
phenyl
alkanol
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EA201270136A
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EA201270136A1 (ru
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Карл Фридрих Низинг
Клаус Кунц
Йорг Нико Гройль
Хендрик Хельмке
Горка Перис
Юрген Бентинг
Петер Дамен
Изольде ХОЙЗЕР-ХАН
Инес Хайнеманн
Кристиан Паулитц
Дирк Шмутцлер
Ульрике Вахендорфф-Нойманн
Томоки Тсучиа
Кристоф Андреас Браун
Рут Майсснер
Томас Кноблох
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Байер Интеллектуэль Проперти Гмбх
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Publication of EA201270136A1 publication Critical patent/EA201270136A1/ru
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Abstract

Настоящее изобретение касается новых производных фенил(окси/тио)алканола формулы (I)в которой Y означает О, S или СН, Z означает бром или йод, R означает трет-бутил, изопропил, 1-галогенциклопропил или 1-(С-С-алкил)циклопропил, и их агрохимически активных солей, способов получения указанных соединений, средств, содержащих указанные соединения, а также их применения в качестве биологически активных соединений, в частности, для борьбы с вредными микроорганизмами для защиты растений и защиты материалов и в качестве регуляторов роста растений.

Description

(57) Настоящее изобретение касается новых производных фенил(окси/тио)алканола формулы (I)
в которой Υ означает О, δ или СН2, Ζ означает бром или йод, К означает трет-бутил, изопропил, 1-галогенциклопропил или 1-(С1-С4-алкил)циклопропил, и их агрохимически активных солей, способов получения указанных соединений, средств, содержащих указанные соединения, а также их применения в качестве биологически активных соединений, в частности, для борьбы с вредными микроорганизмами для защиты растений и защиты материалов и в качестве регуляторов роста растений.

Claims (7)

1. Производные фенил(окси/тио)алканола формулы (I) в которой
Υ означает О, δ или СН2,
- 26 021808
Ζ означает бром или йод,
К означает трет-бутил, изопропил, 1-галогенциклопропил или 1-(С1-С4-алкил)циклопропил, или их агрохимически активные соли.
2. Производные фенил(окси/тио)алканола формулы (I) по п.1, в которой
Υ означает О, δ или СН2,
Ζ означает бром или йод, которые находятся в 4 положении,
К означает трет-бутил, изопропил, 1-хлорциклопропил или 1-метилциклопропил.
3. Способ борьбы с фитопатогенными вредными грибами, отличающийся тем, что производные фенил(окси/тио)алканола формулы (I) по п.1 или 2 наносят на фитопатогенные вредные грибы и/или среду их обитания.
4. Средство для борьбы с фитопатогенными вредными грибами, отличающееся содержанием по меньшей мере одного из производных фенил(окси/тио)алканола формулы (I) по п.1 или 2, наряду с наполнителями и/или поверхностно-активными веществами.
5. Способ получения производных фенил(окси/тио)алканола формулы (I) по п.1 или 2, отличающийся тем, что (В) производное оксирана формулы (IV) (V) в которой К имеет значения, указанные в п.1 или 2, подвергают реакции с (тио)фенолом формулы в которой Υ и Ζ имеют значения, указанные в п.1 или 2, в присутствии разбавителя.
6. Способ получения производных фенил(окси/тио)алканола формулы (I) по п.1 или 2, отличающийся тем, что (С) фенил(окси/тио)кетоны формулы (VI) в которой Υ, Ζ и К имеют значения, указанные в п.1 или 2, подвергают реакции с галогенидом формулы (VII) в которой На1 означает галоген, в присутствии разбавителя и в присутствии органического соединения щелочных металлов.
7. Способ получения производных фенил(окси/тио)алканола формулы (I) по п.1 или 2, отличающийся тем, что (Ό) на первой ступени бромид формулы (VIII) подвергают реакции с (тио)фенолом формулы (V) в которой Υ и Ζ имеют значения, указанные в п.1 или 2, в присутствии разбавителя, и полученные таким образом фенил(окси/тио)кетоны формулы (IX) в которой Υ и Ζ имеют значения, указанные в п.1 или 2, на второй ступени подвергают реакции с металлоорганическими соединениями формулы (X)
- 27 021808
EA201270136A 2009-07-08 2010-06-25 Производные фенил(окси/тио)алканола, способ борьбы с фитопатогенными вредными грибами, средство для борьбы с фитопатогенными вредными грибами и способы получения производных фенил(окси/тио)алканола EA021808B1 (ru)

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EP09164928 2009-07-08
PCT/EP2010/003908 WO2011003527A1 (de) 2009-07-08 2010-06-25 Phenyl(oxy/thio)alkanol-derivate

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EA201270136A1 EA201270136A1 (ru) 2012-07-30
EA021808B1 true EA021808B1 (ru) 2015-09-30

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TW201110883A (en) 2011-04-01
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US9051277B2 (en) 2015-06-09
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US9321732B2 (en) 2016-04-26
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