DE69906170T2 - Ungesättigte Oxim-Ether und ihre Verwendung als Fungizide oder Insectizide - Google Patents

Ungesättigte Oxim-Ether und ihre Verwendung als Fungizide oder Insectizide

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Publication number
DE69906170T2
DE69906170T2 DE69906170T DE69906170T DE69906170T2 DE 69906170 T2 DE69906170 T2 DE 69906170T2 DE 69906170 T DE69906170 T DE 69906170T DE 69906170 T DE69906170 T DE 69906170T DE 69906170 T2 DE69906170 T2 DE 69906170T2
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DE
Germany
Prior art keywords
alkyl
methyl
chlorophenyl
compound
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69906170T
Other languages
English (en)
Other versions
DE69906170D1 (de
Inventor
Bin
Liu Changling
Zhang Hong
Zhang Lixin
Steven Howard Shaber
Zhinian
Zongcheng
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Corteva Agriscience LLC
Original Assignee
Dow AgroSciences LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN98113756A external-priority patent/CN1062711C/zh
Application filed by Dow AgroSciences LLC filed Critical Dow AgroSciences LLC
Application granted granted Critical
Publication of DE69906170D1 publication Critical patent/DE69906170D1/de
Publication of DE69906170T2 publication Critical patent/DE69906170T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
    • C07D213/53—Nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/50—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
    • C07C251/60—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals of hydrocarbon radicals substituted by carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/52—Radicals substituted by nitrogen atoms not forming part of a nitro radical

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pyridine Compounds (AREA)
  • Furan Compounds (AREA)

Claims (10)

1. Verbindung der Formel:
worin X N oder CH ist; Y O, S oder NR&sub6; ist;
A Wasserstoff, Halogen, Cyano, (C&sub1;-C&sub1;&sub2;)Alkyl oder (C&sub1;-C&sub1;&sub2;)Alkoxy ist;
R&sub1; und R&sub6; unabhängig Wasserstoff oder (C&sub1;-C&sub4;)Alkyl sind;
R&sub2; Wasserstoff, (C&sub1;-C&sub1;&sub2;)Alkyl, Halo(C&sub1;-C&sub1;&sub2;)Alkyl, (C&sub3;-C&sub7;)Cycloalkyl, (C&sub2;- C&sub8;)-Alkenyl, Halo(C&sub2;-C&sub8;)Alkenyl, (C&sub2;-C&sub8;)Alkinyl, Halo(C&sub2;-C&sub8;)Alkinyl, Aryl oder Aralkyl ist;
worin die oben genannten (C&sub1;-C&sub4;)Alkyl-, (C&sub1;-C&sub1;&sub2;)Alkyl-, (C&sub2;-C&sub8;)Alkenyl, (C&sub2;- C&sub8;)Alkinyl- und (C&sub2;-C&sub8;)Cycloalkyl-Gruppen optional substituiert sein können mit bis zu drei Substituenten, ausgewählt aus der Gruppe, bestehend aus Nitro, Halomethyl, (C&sub1;-C&sub4;)Alkoxycarbonyl und Cyano und worin der Ausdruck Alkyl sowohl verzweigte als auch geradkettige Alkylkgruppen mit von 1 bis 12 Kohlenstoffatomen umfasst, und der Ausdruck Alkenyl eine ethylenisch ungesättigte Kohlenwasserstoffgruppe, gerad- oder verzweigtkettig, mit einer Kettenlänge von 2 bis 8 Kohlenstoffatomen und 1 oder 2 ethylenischen Bindungen betrifft, der Ausdruck Alkinyl eine ungesättigte Kohlenwasserstoffgruppe, gerad- oder verzweigtkettig, mit einer Kettenlänge von 2 bis 12 Kohlenstoffatomen und 1 oder 2 acetylenischen Bindungen betrifft, und der Ausdruck Arylphenyl oder Naphthyl umfasst, welche substituiert sein können mit bis zu drei Substituenten, unabhängig ausgewählt aus der Gruppe, bestehend aus Halogen, Cyano, Trihalomethyl, Phenyl, Phenoxy, (C&sub1;-C&sub3;)Alkyl, (C&sub1;- C&sub4;)Alkylthio, (C&sub1;-C&sub4;)Alkylsulfoxid und Halo(C&sub1;-C&sub4;)Alkyl und worin der Ausdruck Aralkyl verwendet wird, um eine Gruppe zu beschreiben, worin die Alkylkette von 1 bis 10 Kohlenstoffatomen aufweist und verzweigt oder geradkettig sein kann;
R&sub2; Wasserstoff ist;
R&sub4; Phenyl ist, das substituiert ist mit bis zu drei Substituenten, unabhängig ausgewählt aus der Gruppe, bestehend aus Halogen, Trihalomethyl und Halo(C&sub1;-C&sub4;)Alkyl, und R&sub5; Wasserstoff ist, und Enantiomere, Stereoisomere und landwirtschaftlich verträgliche Salze davon.
2. Verbindung nach Anspruch 1, X CH ist, Y O ist, R&sub2; (C&sub1;-C&sub1;&sub2;)Alkyl ist.
3. Verbindung nach Anspruch 2, worin R&sub4; ausgewählt ist aus der Gruppe, bestehend aus 2-Chlorphenyl, 2-Fluorphenyl, 2-Trifluormethylphenyl, 3- Chlorphenyl, 3-Fluorphenyl, 3-Trifluormethylphenyl, 4-Chlorphenyl, 4- Fluorphenyl, 4-Trifluormethylphenyl und 2,4-Dichlorphenyl.
4. Verbindung nach Anspruch 1, worin X N ist, Y O oder NH ist, R&sub2; (C&sub1;-C&sub1;&sub2;)- Alkyl ist.
5. Verbindung nach Anspruch 4, worin R&sub4; ausgewählt ist aus der Gruppe, bestehend aus 2-Chlorphenyl, 2-Fluorphenyl, 2-Trifluormethylphenyl, 3- Chlorphenyl, 3-Fluorphenyl, 3-Trifluormethylphenyl, 4-Chlorphenyl, 4- Fluorphenyl, 4-Trifluormethylphenyl und 2,4-Dichlorphenyl.
6. Verbindung nach Anspruch 1, worin die Verbindung Methyl-3-methoxy-2- [2-((((1-methyl-3-(2'-chlorphenyl)-2- propenyliden)amino)oxy)methyl)phenyl]propenoat ist.
7. Verbindung nach Anspruch 1, worin die Verbindung Methyl-3-methoxy-2- [2-((((1-methyl-3-(4'chlorphenyl)-2- propenyliden)amino)oxy)methyl)phenyl]propenoat ist.
8. Fungizide Zusammensetzung zum Bekämpfen phytopathogener Pilze, umfassend einen landwirtschaftlich verträglichen Träger und die Verbindung von Anspruch 1, worin das Verhältnis der Verbindung zu dem Träger zwischen 99 : 1 und 1 : 4 ist.
9. Verfahren zum Bekämpfen phytopathogener Pilze, umfassend das Anwenden der Verbindung nach Anspruch 1 in einer Menge von 0,005 bis 50 Kilogramm pro Hektar auf den Ort, an welchem eine Bekämpfung gewünscht ist.
10. Verfahren zum Bekämpfen von Insekten, umfassend das Anwenden einer Menge von 0,0005 bis 10 Kilogramm pro Hektar der Verbindung nach Anspruch 1 auf den Lebensraum der Insekten.
DE69906170T 1998-02-10 1999-01-26 Ungesättigte Oxim-Ether und ihre Verwendung als Fungizide oder Insectizide Expired - Lifetime DE69906170T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN98113756A CN1062711C (zh) 1998-02-10 1998-02-10 不饱和肟醚类杀虫、杀真菌剂
US10601398P 1998-10-28 1998-10-28

Publications (2)

Publication Number Publication Date
DE69906170D1 DE69906170D1 (de) 2003-04-30
DE69906170T2 true DE69906170T2 (de) 2003-10-23

Family

ID=25744701

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69906170T Expired - Lifetime DE69906170T2 (de) 1998-02-10 1999-01-26 Ungesättigte Oxim-Ether und ihre Verwendung als Fungizide oder Insectizide

Country Status (6)

Country Link
EP (1) EP0936213B1 (de)
JP (1) JPH11315057A (de)
KR (1) KR19990046320A (de)
AU (1) AU1544899A (de)
BR (1) BR9900561A (de)
DE (1) DE69906170T2 (de)

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KR100379761B1 (ko) * 2000-11-23 2003-04-11 한국화학연구원 옥심기를 측쇄로 하는 신규의 프로페노익 에스테르 및아미드 유도체, 이의 제조방법 그리고 이를 함유하는살균제 조성물
CN1293046C (zh) * 2003-08-12 2007-01-03 沈阳化工研究院 具有杀真菌、杀虫活性的不饱和肟醚类化合物
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GB0422401D0 (en) 2004-10-08 2004-11-10 Syngenta Participations Ag Fungicidal compositions
PE20060801A1 (es) * 2004-12-23 2006-10-03 Basf Ag Mezclas fungicidas
BRPI0519234A2 (pt) * 2004-12-23 2009-01-06 Basf Ag misturas fungicidas para combater fungos nocivos fitopatogÊnicos, agente, processo para combater fungos nocivos fitopatogÊnicos, sementes, e, uso dos compostos
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US8349877B2 (en) 2007-09-26 2013-01-08 Basf Se Ternary fungicidal compositions comprising boscalid and chlorothalonil
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CN103153958A (zh) 2010-07-02 2013-06-12 先正达参股股份有限公司 新颖的杀微生物的二肟醚衍生物
CN102308799A (zh) * 2010-07-02 2012-01-11 海利尔药业集团股份有限公司 一种含有烯肟菌酯和溴菌腈的杀菌组合物
TW201211005A (en) 2010-07-29 2012-03-16 Syngenta Participations Ag Novel microbiocidal dioxime ether derivatives
AR083112A1 (es) 2010-10-01 2013-01-30 Syngenta Participations Ag Metodo para controlar enfermedades fitopatogenas y composiciones fungicidas utiles para dicho control
WO2012066122A1 (en) 2010-11-18 2012-05-24 Syngenta Participations Ag 2 - (pyridin- 2 -yl) -quinazoline derivatives and their use as microbicides
WO2012069652A2 (en) 2010-11-26 2012-05-31 Syngenta Participations Ag Fungicide mixtures
EP2481284A3 (de) 2011-01-27 2012-10-17 Basf Se Pestizidgemische
JP6049684B2 (ja) 2011-03-23 2016-12-21 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ イミダゾリウム基を含むポリマーのイオン性化合物を含有する組成物
CN102204552A (zh) * 2011-04-09 2011-10-05 陕西汤普森生物科技有限公司 一种含烯肟菌酯与抗生素类化合物的杀菌组合物
JP5997931B2 (ja) * 2011-05-25 2016-09-28 石原産業株式会社 農園芸用殺菌剤組成物及び植物病害の防除方法
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AR087609A1 (es) 2011-08-23 2014-04-03 Syngenta Participations Ag Microbiocidas
US20150257383A1 (en) 2012-10-12 2015-09-17 Basf Se Method for combating phytopathogenic harmful microbes on cultivated plants or plant propagation material
CN105050406B (zh) 2012-12-20 2017-09-15 巴斯夫农业公司 包含三唑化合物的组合物
EP2783569A1 (de) 2013-03-28 2014-10-01 Basf Se Zusammensetzungen mit einer Triazol-Verbindung
EP2835052A1 (de) 2013-08-07 2015-02-11 Basf Se Fungizide Mischungen mit Pyrimidinfungiziden
CN105722833A (zh) 2013-09-16 2016-06-29 巴斯夫欧洲公司 杀真菌的嘧啶化合物
WO2015036059A1 (en) 2013-09-16 2015-03-19 Basf Se Fungicidal pyrimidine compounds
WO2015119099A1 (ja) * 2014-02-05 2015-08-13 日本曹達株式会社 ピリジン化合物およびその用途
CN106132202B (zh) 2014-03-20 2021-12-31 三井化学Agro株式会社 植物病害防除组合物及应用该组合物以防除植物病害的方法
EP2979549A1 (de) 2014-07-31 2016-02-03 Basf Se Verfahren zur verbesserung der gesundheit einer pflanze
EP3209818B1 (de) 2014-10-24 2019-12-11 Basf Se Organische pestizid-teilchen

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Also Published As

Publication number Publication date
DE69906170D1 (de) 2003-04-30
AU1544899A (en) 1999-08-26
BR9900561A (pt) 2000-05-16
KR19990046320A (ko) 1999-07-05
EP0936213B1 (de) 2003-03-26
EP0936213A1 (de) 1999-08-18
JPH11315057A (ja) 1999-11-16

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