CN205351624U - Water hydrogen humidifier - Google Patents
Water hydrogen humidifier Download PDFInfo
- Publication number
- CN205351624U CN205351624U CN201520867139.6U CN201520867139U CN205351624U CN 205351624 U CN205351624 U CN 205351624U CN 201520867139 U CN201520867139 U CN 201520867139U CN 205351624 U CN205351624 U CN 205351624U
- Authority
- CN
- China
- Prior art keywords
- hydrogen
- gas
- water
- humidifier
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 330
- 239000001257 hydrogen Substances 0.000 title claims abstract description 288
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 288
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229910001868 water Inorganic materials 0.000 title claims abstract description 61
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 189
- 238000000926 separation method Methods 0.000 claims abstract description 71
- 238000004519 manufacturing process Methods 0.000 claims abstract description 70
- 239000012528 membrane Substances 0.000 claims abstract description 38
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 16
- SWELZOZIOHGSPA-UHFFFAOYSA-N palladium silver Chemical compound [Pd].[Ag] SWELZOZIOHGSPA-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000007789 gas Substances 0.000 claims description 88
- 238000002309 gasification Methods 0.000 claims description 75
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 58
- 239000001301 oxygen Substances 0.000 claims description 58
- 229910052760 oxygen Inorganic materials 0.000 claims description 58
- 239000000446 fuel Substances 0.000 claims description 41
- 238000010438 heat treatment Methods 0.000 claims description 39
- 239000003054 catalyst Substances 0.000 claims description 37
- 239000007788 liquid Substances 0.000 claims description 36
- 230000006835 compression Effects 0.000 claims description 34
- 238000007906 compression Methods 0.000 claims description 34
- 239000002994 raw material Substances 0.000 claims description 34
- 230000001105 regulatory effect Effects 0.000 claims description 27
- 239000007787 solid Substances 0.000 claims description 19
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 239000003595 mist Substances 0.000 claims description 12
- 239000006200 vaporizer Substances 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 230000007246 mechanism Effects 0.000 claims description 8
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000003990 capacitor Substances 0.000 claims description 6
- 238000002485 combustion reaction Methods 0.000 claims description 6
- 229910001882 dioxygen Inorganic materials 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 238000001771 vacuum deposition Methods 0.000 claims description 3
- 230000005611 electricity Effects 0.000 abstract description 9
- 238000002360 preparation method Methods 0.000 abstract description 2
- 238000001651 catalytic steam reforming of methanol Methods 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 12
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 10
- 239000010949 copper Substances 0.000 description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 description 6
- 239000001569 carbon dioxide Substances 0.000 description 6
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 6
- 229910000314 transition metal oxide Inorganic materials 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 238000001514 detection method Methods 0.000 description 4
- 238000010304 firing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 230000003139 buffering effect Effects 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010970 precious metal Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 238000002407 reforming Methods 0.000 description 3
- 230000002269 spontaneous effect Effects 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000012295 chemical reaction liquid Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Hydrogen, Water And Hydrids (AREA)
- Fuel Cell (AREA)
Abstract
The utility model discloses a water hydrogen humidifier, the humidifier includes: humidifier body, methyl alcohol hydrogen production system, hydrogen generates electricity system, methyl alcohol hydrogen production system, hydrogen generates electricity system, humidifier body connect gradually, the humidifier body includes casing, flourishing water receptacle, controller, transducer, fog quantity adjustor, fan, and controller, transducer, fog quantity adjustor, fan set up in the casing, and the work of transducer, fog quantity adjustor, fan is controlled to the controller, methyl alcohol hydrogen production system utilizes methanol steam reforming preparation hydrogen, and hydrogen obtains the hydrogen of high -purity through the membrane separation device who plates palladium -silver, and the hydrogen that acquires passes through the electricity generation of hydrogen generates electricity system, and the electric energy that sends supplies the work of humidifier body. The utility model provides a water hydrogen humidifier, usable methyl alcohol make hydrogen generates electricity as the energy of humidifier body, can be used for the humidifier body not have the place of alternating current.
Description
Technical field
This utility model belongs to articles for daily use technical field, relates to a kind of humidifier, particularly relates to a kind of water hydrogen humidifier.
Background technology
Humidifier is with whole ground for radiator, by the heating agent in flooring radiation layer, uniformly heats whole ground, utilizes the rule that the accumulation of heat on ground self and heat upwards radiate to conduct from the bottom to top, reaches the purpose of heating.
Existing humidifier is it is generally required to plug alternating current and could work.And in some cases, it is desirable to could be used that humidifier when there is no alternating current.Existing humidifier cannot complete this work.
In view of this, nowadays in the urgent need to designing a kind of new humidifier, in order to overcome the drawbacks described above that existing humidifier exists.
Utility model content
Technical problem to be solved in the utility model is: providing a kind of water hydrogen humidifier, available methanol prepares the hydrogen gas generation energy as humidifier body, it is possible to humidifier body is used for the place not having alternating current.
For solving above-mentioned technical problem, this utility model adopts the following technical scheme that
A kind of water hydrogen humidifier, described humidifier includes: humidifier body, hydrogen production by methanol system, hydrogen gas generating system, and hydrogen production by methanol system, hydrogen gas generating system, humidifier body are sequentially connected with；Described humidifier body includes housing, water container, controller, transducer, mist amount actuator, fan, and controller, transducer, mist amount actuator, fan are arranged in housing, and controller controls the work of transducer, mist amount actuator, fan；Humidifier body is provided with connection cable, connects cable and is connected with hydrogen gas generating system；
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, and hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes solid hydrogen and stores container, liquid container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, and separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen stores container, liquid container is connected with hydrogen producer respectively；Liquid container stores the first alcohol and water of liquid；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes the first startup device, the second startup device；Described first starts device includes the first heating arrangements, the first gasification pipe, and the internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；One end of described first gasification pipe connects liquid container, is sent in the first gasification pipe by methanol by raw material conveying device；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition；Or, the other end of the first gasification pipe exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, and methanol is direct spontaneous combustion after exporting from the first gasification pipe；Described second starts device includes the second gasification pipe, the main body of the second gasification pipe is arranged at described reformer chamber, first gasification pipe is or/and the methanol of the second gasification pipe output heats the second gasification pipe while being reformer chamber heating, by the methanol gasifying in the second gasification pipe；Described reformer chamber inwall is provided with and adds pipe line, adds and is placed with catalyst in pipe line；Described device for rapidly starting by heat described in add pipe line attach most importance to whole room heating；After described hydrogen generating system starts, hydrogen generating system is provided by the hydrogen that hydrogen producer prepares and runs the required energy；
The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual generator, and the electric energy sent is stored in battery by manual generator；
Described catalyst includes the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, the oxide of Zn, rare-earth oxide, transition metal oxide；Wherein, precious metals pt content accounts for the 0.6%～1.8% of catalyst gross mass, Pd content accounts for the 1.1%～4% of catalyst gross mass, the oxide of Cu accounts for the 6%～12% of catalyst gross mass, the oxide of Fe accounts for the 3%～8% of catalyst gross mass, the oxide of Zn accounts for the 8%～20% of catalyst gross mass, and rare-earth oxide accounts for the 6%～40% of catalyst gross mass, and all the other are transition metal oxide；
Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the Al of ZrO, 55-80 part of ZnO, 0.5-3 part of CuO, 3-18 part of 3-17 part2O3, the CeO of 1-3 part2, the La of 1-3 part2O3；
Described solid hydrogen stores and stores solid hydrogen in container, and when hydrogen generating system starts, by gasifying, solid hydrogen is converted to gaseous hydrogen by module, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer and starts heat energy, as the startup energy of hydrogen producer；
First alcohol and water in described liquid container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange；Methanol vapor and steam after gasification enter reformer chamber, and it is 300 DEG C～420 DEG C that reformer chamber is provided with catalyst, reformer chamber bottom and middle portion temperature；The temperature on described reformer chamber top is 400 DEG C～570 DEG C；Reformer chamber is connected by connecting line with separation chamber, all or part of top being arranged at reformer chamber of connecting line, and the high temperature that can pass through reformer chamber top continues the heating gas from reformer chamber output；Described connecting line is as the buffering between reformer chamber and separation chamber so that identical or close with the temperature of separation chamber from the temperature of the gas of reformer chamber output；Temperature in described separation chamber is set as 350 DEG C～570 DEG C；It is provided with membrane separator in separation chamber, obtains hydrogen from the aerogenesis end of membrane separator；
Described raw material conveying device provides power, by the feedstock transportation in liquid container to hydrogen producer；Described raw material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that hydrogen producer prepares has enough pressure；
After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is run by the maintenance hydrogen producer that burns；
The hydrogen that described hydrogen producer prepares is delivered to membrane separation device and is easily separated, for the difference of inside and outside pressure of membrane separation device of separating hydrogen gas be more than or equal to 0.7MPa；Described membrane separation device is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, and silver accounts for 22%～25%；
Described hydrogen manufacturing subsystem by prepared hydrogen by transfer conduit real-time Transmission to hydrogen gas generating system；Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares；
Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor；This barometric information received from gas pressure sensor is compared by described microprocessor with setting threshold interval；When the pressure data received is higher than the maximum setting threshold interval, microprocessor controls valve positioner and opens the air outlet valve setting time, air pressure in transfer conduit is made to be in set point, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, is that the firing equipment that needs of hydrogen manufacturing subsystem is heated by burning；When the pressure data received is lower than the minima setting threshold interval, microprocessor controls described hydrogen manufacturing subsystem and accelerates the transporting velocity of raw material；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, hydrogen, oxygen gas and water is collected respectively from expellant gas, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generating system, the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycling；
Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve, by hydrogen and oxygen separation, is then separated from water by hydrogen respectively, oxygen is separated from water；
Described hydrogen producer also includes electric energy estimation block, hydrogen prepares detection module, electric energy memory module；The electric energy that when whether the electric energy that described electric energy estimation block sends in real time in order to estimate hydrogen gas generation device can meet reformation, separation, needs consume；If it is satisfied, then closedown device for rapidly starting；
Whether hydrogen prepares the hydrogen that detection module prepared in real time for detecting hydrogen producer stable；If hydrogen prepared by hydrogen producer is unstable, then controls device for rapidly starting and be again started up, and the electric energy obtained is partially stored in electric energy memory module, use when electric energy is not enough to the consumption providing hydrogen producer；
Described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, pile；Described gas supply device utilizes the gas of compression as power, and automatic transport is to pile；Described pile includes some sub-fuel cell modules, and each sub-fuel cell module includes at least one super capacitor；
Described fuel cell system also includes air intake conduit, outlet pipe；The gas of described compression is mainly oxygen；Air enters pile with oxygen after mixing container mixing；
Described fuel cell system also includes gas regulating system；Described gas regulating system includes valve regulated and controls device, and oxygen content sensor is or/and compress gas compression ratio sensor；
Described oxygen content sensor is in order to sense the air of mixing and the content of oxygen in oxygen in mixing container, and the data sensed is sent to valve regulated control device；
Described compression gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data sensed is sent to valve regulated control device；
Described valve regulated controls device according to oxygen content sensor or/and the sensing result of compression gas compression ratio sensor regulates oxygen delivery valve door, air entrainment valve door, controls the conveying ratio of compressed oxygen, air；Mixing gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container；
Described fuel cell system also includes humidification system, and humidification system includes humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is a part for air intake conduit；After described reaction, gas outlet pipe is delivered to humidity exchanging container,
The material of described humidity exchange pipeline is only permeable airtight so that after reaction, gas and natural air carry out humidity exchange, and cannot circulate between gas.
A kind of water hydrogen humidifier, described humidifier includes: humidifier body, hydrogen production by methanol system, hydrogen gas generating system, and hydrogen production by methanol system, hydrogen gas generating system, humidifier body are sequentially connected with；Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, and described hydrogen manufacturing subsystem includes hydrogen producer, membrane separation device；Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber.
Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen obtains highly purified hydrogen by being coated with the membrane separation device of palladium-silver, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system, and the electric energy sent is for humidifier body work.
As a kind of preferred version of the present utility model, described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, and hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes solid hydrogen and stores container, liquid container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, and separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen stores container, liquid container is connected with hydrogen producer respectively；Liquid container stores the first alcohol and water of liquid；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes the first startup device, the second startup device；Described first starts device includes the first heating arrangements, the first gasification pipe, and the internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；One end of described first gasification pipe connects liquid container, is sent in the first gasification pipe by methanol by raw material conveying device；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition；Or, the other end of the first gasification pipe exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, and methanol is direct spontaneous combustion after exporting from the first gasification pipe；Described second starts device includes the second gasification pipe, the main body of the second gasification pipe is arranged at described reformer chamber, first gasification pipe is or/and the methanol of the second gasification pipe output heats the second gasification pipe while being reformer chamber heating, by the methanol gasifying in the second gasification pipe；Described reformer chamber inwall is provided with and adds pipe line, adds and is placed with catalyst in pipe line；Described device for rapidly starting by heat described in add pipe line attach most importance to whole room heating；After described hydrogen generating system starts, hydrogen generating system is provided by the hydrogen that hydrogen producer prepares and runs the required energy；
Described solid hydrogen stores and stores solid hydrogen in container, and when hydrogen generating system starts, by gasifying, solid hydrogen is converted to gaseous hydrogen by module, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer and starts heat energy, as the startup energy of hydrogen producer；
First alcohol and water in described liquid container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange；Methanol vapor and steam after gasification enter reformer chamber, and it is 300 DEG C～420 DEG C that reformer chamber is provided with catalyst, reformer chamber bottom and middle portion temperature；The temperature on described reformer chamber top is 400 DEG C～570 DEG C；Reformer chamber is connected by connecting line with separation chamber, all or part of top being arranged at reformer chamber of connecting line, and the high temperature that can pass through reformer chamber top continues the heating gas from reformer chamber output；Described connecting line is as the buffering between reformer chamber and separation chamber so that identical or close with the temperature of separation chamber from the temperature of the gas of reformer chamber output；Temperature in described separation chamber is set as 350 DEG C～570 DEG C；It is provided with membrane separator in separation chamber, obtains hydrogen from the aerogenesis end of membrane separator；
Described raw material conveying device provides power, by the feedstock transportation in liquid container to hydrogen producer；Described raw material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that hydrogen producer prepares has enough pressure；
After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is run by the maintenance hydrogen producer that burns；
The hydrogen that described hydrogen producer prepares is delivered to membrane separation device and is easily separated, for the difference of inside and outside pressure of membrane separation device of separating hydrogen gas be more than or equal to 0.7MPa；Described membrane separation device is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, and silver accounts for 22%～25%；
Described hydrogen manufacturing subsystem by prepared hydrogen by transfer conduit real-time Transmission to hydrogen gas generating system；Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares；
Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor；This barometric information received from gas pressure sensor is compared by described microprocessor with setting threshold interval；When the pressure data received is higher than the maximum setting threshold interval, microprocessor controls valve positioner and opens the air outlet valve setting time, air pressure in transfer conduit is made to be in set point, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, is that the firing equipment that needs of hydrogen manufacturing subsystem is heated by burning；When the pressure data received is lower than the minima setting threshold interval, microprocessor controls described hydrogen manufacturing subsystem and accelerates the transporting velocity of raw material；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, hydrogen, oxygen gas and water is collected respectively from expellant gas, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generating system, the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycling；
Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve, by hydrogen and oxygen separation, is then separated from water by hydrogen respectively, oxygen is separated from water.
As a kind of preferred version of the present utility model, the initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual generator, and the electric energy sent is stored in battery by manual generator.
As a kind of preferred version of the present utility model, described catalyst includes the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, the oxide of Zn, rare-earth oxide, transition metal oxide；
Wherein, precious metals pt content accounts for the 0.6%～1.8% of catalyst gross mass, Pd content accounts for the 1.1%～4% of catalyst gross mass, the oxide of Cu accounts for the 6%～12% of catalyst gross mass, the oxide of Fe accounts for the 3%～8% of catalyst gross mass, the oxide of Zn accounts for the 8%～20% of catalyst gross mass, and rare-earth oxide accounts for the 6%～40% of catalyst gross mass, and all the other are transition metal oxide.
As a kind of preferred version of the present utility model, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the Al of ZrO, 45-95 part of ZnO, 0.1-5 part of CuO, 2-20 part of 2-20 part2O3, the CeO of 0-5 part2, the La of 0-5 part2O3。
As a kind of preferred version of the present utility model, described hydrogen gas generating system includes fuel cell, and fuel cell includes some sub-fuel cell modules, and each sub-fuel cell module includes at least one super capacitor.
As a kind of preferred version of the present utility model, described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, pile；Described gas supply device utilizes the gas of compression as power, and automatic transport is to pile；Described pile includes some sub-fuel cell modules, and each sub-fuel cell module includes at least one super capacitor；
Described fuel cell system also includes air intake conduit, outlet pipe；The gas of described compression is mainly oxygen；Air enters pile with oxygen after mixing container mixing.
As a kind of preferred version of the present utility model, described fuel cell system also includes gas regulating system；Described gas regulating system includes valve regulated and controls device, and oxygen content sensor is or/and compress gas compression ratio sensor；
Described oxygen content sensor is in order to sense the air of mixing and the content of oxygen in oxygen in mixing container, and the data sensed is sent to valve regulated control device；
Described compression gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data sensed is sent to valve regulated control device；
Described valve regulated controls device according to oxygen content sensor or/and the sensing result of compression gas compression ratio sensor regulates oxygen delivery valve door, air entrainment valve door, controls the conveying ratio of compressed oxygen, air；Mixing gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container.
As a kind of preferred version of the present utility model, described fuel cell system also includes humidification system, and humidification system includes humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is a part for air intake conduit；After described reaction, gas outlet pipe is delivered to humidity exchanging container,
The material of described humidity exchange pipeline is only permeable airtight so that after reaction, gas and natural air carry out humidity exchange, and cannot circulate between gas.
The beneficial effects of the utility model are in that: the water hydrogen humidifier that the utility model proposes, and available methanol prepares the hydrogen gas generation energy as humidifier body, it is possible to humidifier body is used for the place not having alternating current.
Accompanying drawing explanation
Fig. 1 is the composition schematic diagram of this utility model water hydrogen humidifier.
Fig. 2 is the composition schematic diagram of hydrogen production by methanol system in this utility model system.
Fig. 3 is the structural representation of device for rapidly starting in hydrogen producer
Fig. 4 is hydrogen producer and the structural representation adding pipe line thereof.
Fig. 5 is the composition schematic diagram of the hydrogen producer being provided with relief valve.
Fig. 6 is the schematic diagram under the another kind of state of the hydrogen producer being provided with relief valve.
Fig. 7 is the composition schematic diagram of fuel cell system in this utility model system.
Fig. 8 is the structural representation of liquid container.
Detailed description of the invention
Preferred embodiment of the present utility model is described in detail below in conjunction with accompanying drawing.
Embodiment one
Referring to Fig. 1, this utility model discloses a kind of water hydrogen humidifier, and described humidifier includes: humidifier body, hydrogen production by methanol system, hydrogen gas generating system, and hydrogen production by methanol system, hydrogen gas generating system, humidifier body are sequentially connected with；Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen obtains highly purified hydrogen by being coated with the membrane separation device of palladium-silver, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system, and the electric energy sent is for humidifier body work.
Described humidifier body includes housing, water container, controller, transducer, mist amount actuator, fan, and controller, transducer, mist amount actuator, fan are arranged in housing, and controller controls the work of transducer, mist amount actuator, fan；Humidifier body is provided with connection cable, connects cable and is connected with hydrogen gas generating system.Described humidifier body can directly use the unidirectional current that hydrogen gas generating system sends.
In the present embodiment, referring to Fig. 2, hydrogen production by methanol system is small portable hydrogen producer, including: liquid container 10, raw material conveying device 50, device for rapidly starting 40, device for producing hydrogen 20, membrane separation device 30, hydrogen delivery tube road 60.
As it is shown on figure 3, described device for rapidly starting 40 includes housing 41, heating arrangements 42, gasification pipe 43, the internal diameter of gasification pipe 43 is 1～2mm, and gasification pipe 43 is wound on heating arrangements 42；Described heating arrangements can be electrically heated rod, utilizes alternating current or accumulator, aneroid battery.
One end of described gasification pipe 43 connects liquid container 10, is sent into by methanol in gasification pipe 43；The other end of gasification pipe 43 exports vaporized methanol, then by ignition mechanism ignition；Or, the other end of gasification pipe 43 exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, and methanol is direct spontaneous combustion after exporting from gasification pipe 43；Described device for rapidly starting 40 is that device for producing hydrogen (in other words whole hydrogen producer) provides the startup energy.
Referring to Fig. 4, in order to improve the firing rate of device for producing hydrogen, the reformer chamber inwall at described device for producing hydrogen 20 is provided with and adds pipe line 21, adds and is placed with catalyst (as can by heating and temperature control at 380 DEG C～480 DEG C) in pipe line 21；Described device for rapidly starting 40 adds pipe line 21 for reformer chamber heating described in heating, it is possible to improve the efficiency of heating surface.
As shown in Figure 2, device for producing hydrogen 20 can also arrange the second startup device 70, described second starts device 70 includes the second gasification pipe, and the main body of the second gasification pipe is arranged at reformer chamber, and the second gasification pipe is reformer chamber heating (can also be the heating of other unit of hydrogen producer).First gasification pipe is or/and the methanol of the second gasification pipe output heats the second gasification pipe while being reformer chamber heating, by the methanol gasifying in the second gasification pipe.When the second startup device sets the time after can persistently preparing the methanol of gasification, it is possible to close above-mentioned device for rapidly starting, thus reducing the dependence to extra powers such as electric energy further.
In addition, described device for producing hydrogen 20 includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, and separation chamber is arranged at the top of reformer chamber.Described liquid container is connected with device for producing hydrogen；Liquid container stores the first alcohol and water of liquid.
First alcohol and water in described liquid container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange；Methanol vapor and steam after gasification enter reformer chamber, and it is 300 DEG C～420 DEG C that reformer chamber is provided with catalyst, reformer chamber bottom and middle portion temperature.The temperature on described reformer chamber top is 400 DEG C～570 DEG C；Reformer chamber is connected by connecting line with separation chamber, all or part of top being arranged at reformer chamber of connecting line, and the high temperature that can pass through reformer chamber top continues the heating gas from reformer chamber output；Described connecting line is as the buffering between reformer chamber and separation chamber so that identical or close with the temperature of separation chamber from the temperature of the gas of reformer chamber output.Temperature in described separation chamber is set as 350 DEG C～570 DEG C；It is provided with membrane separator in separation chamber, obtains hydrogen from the aerogenesis end of membrane separator.By above-mentioned improvement, it is possible to ensure the low temperature requirements of reformer chamber catalyst and the high temperature requirement of separation chamber respectively, and then improve hydrogen preparation efficiency；Meanwhile, preheating method of the present utility model (separation chamber is arranged at the top of reformer chamber) is very convenient.
Described catalyst includes the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, the oxide of Zn, rare-earth oxide, transition metal oxide；Wherein, precious metals pt content accounts for the 0.6%～1.8% of catalyst gross mass, Pd content accounts for the 1.1%～4% of catalyst gross mass, the oxide of Cu accounts for the 6%～12% of catalyst gross mass, the oxide of Fe accounts for the 3%～8% of catalyst gross mass, the oxide of Zn accounts for the 8%～20% of catalyst gross mass, and rare-earth oxide accounts for the 6%～40% of catalyst gross mass, and all the other are transition metal oxide；
Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the Al of ZrO, 55-80 part of ZnO, 0.5-3 part of CuO, 3-18 part of 3-17 part2O3, the CeO of 1-3 part2, the La of 1-3 part2O3。
Additionally, described raw material conveying device provides power, by the feedstock transportation in liquid container to device for producing hydrogen；Described raw material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that device for producing hydrogen prepares has enough pressure.The hydrogen that described device for producing hydrogen prepares is delivered to membrane separation device and is easily separated, for the difference of inside and outside pressure of membrane separation device of separating hydrogen gas be more than or equal to 0.7MPa.By this improvement so that the hydrogen that device for producing hydrogen prepares has enough pressure, can improve hydrogen production efficiency and the purity of prepared hydrogen.
After described hydrogen producer starts, hydrogen producer is provided by the hydrogen that device for producing hydrogen prepares and runs the required energy；At this point it is possible to closedown device for rapidly starting.The hydrogen partial prepared due to device for producing hydrogen is or/and residual air maintains hydrogen producer operation by burning, such that it is able to reduce the dependence to extra power, adaptive ability is strong.
Additionally, refer to Fig. 5, Fig. 6, described hydrogen delivery tube road 60 is provided with spring safety valve 61, and spring safety valve 61 includes valve body, spring mechanism, end of upspringing；Described raw material conveying device 50 includes delivery pump, and end of upspringing arranges (certain raw material conveying device 50 can also be other power set) near the switch of delivery pump, can disconnect the switch of raw material conveying device when end of upspringing is upspring.By arranging mechanical safety valve on hydrogen delivery tube road, when air pressure reaches setting value, mechanical safety valve is opened, and can control raw material conveying device stopping transferring raw material.Such that it is able to improve the safety that equipment runs, it is prevented that hydrogen leak and blast.
Specifically, in the present embodiment, the switch of described delivery pump includes contact-segment 62 and three ports, three port respectively first port the 63, second port the 64, the 3rd ports 65.One end of described contact-segment 62 is rotationally arranged at the first port 63, and the first port 63 connects delivery pump；The other end of contact-segment 62 can contact the second port 64 or the 3rd port 65.
Described second port 64 connects power supply, when the first port 63 connects the second port 64, can control delivery pump work.Described 3rd port 65 connects alarm transmitting device, when the first port connects three ports 65, energy controls conveying air pump inoperative, and alarm transmitting device sends the extremely corresponding server of warning message (as by the mode of note) or client simultaneously, it is possible to notify corresponding personnel.
Described hydrogen gas generation device connects hydrogen producer, and the Partial DC electricity sent is delivered to hydrogen producer；Hydrogen producer drives electromagnetic heater to be reformer chamber, separation chamber's heating by the unidirectional current oneself prepared；Meanwhile, also the unidirectional current sent is delivered to the deep sea water extracting device of system, sea water purifying plant, oxygen delivery devices, water generation equipment, runs for these equipment, go back hydrogen supply gas electric generating apparatus self-operating simultaneously.
Described hydrogen producer includes electromagnetic heater；Electromagnetic heater includes forming the reformation cylinder body of reformer chamber, forming the separation cylinder body of separation chamber, it is arranged at the first heating coil outside reformation cylinder body, the second heating coil that splitter cylinder is external, the temperature sensor in reformation cylinder body, splitter cylinder body, pressure transducer, and electromagnetic controller；Electromagnetic controller heats the electric current of coil, the second heating coil according to the Data Control first that temperature sensor, pressure transducer sense, reformer chamber, separation chamber can be made moment to reach design temperature.
Described hydrogen producer also includes electric energy estimation block, hydrogen prepares detection module, electric energy memory module；The electric energy that when whether the electric energy that described electric energy estimation block sends in real time in order to estimate hydrogen gas generation device can meet reformation, separation, needs consume；If it is satisfied, then closedown device for rapidly starting.
Whether hydrogen prepares the hydrogen that detection module prepared in real time for detecting hydrogen producer stable；If hydrogen prepared by hydrogen producer is unstable, then controls device for rapidly starting and be again started up, and the electric energy obtained is partially stored in electric energy memory module, use when electric energy is not enough to the consumption providing hydrogen producer.
Referring to Fig. 7, in the present embodiment, described hydrogen gas generation device 200 is fuel cell system, and fuel cell system includes: gas supply device, pile 201；Described gas supply device utilizes the gas of compression as power, and automatic transport is to pile 201.
In the present embodiment, gas supply device is compressed gas body feeding 202, and described compression gas enters pile 201 after being delivered to a mixing container 203, one end of mixing container 203 connects air；Natural air is reacted by the power that compression gas produces after entering mixing container 203 in setting ratio inspiration pile, regulates oxygen content.
Described fuel cell system also includes air intake conduit, outlet pipe, and air intake conduit, outlet pipe are all through humidification system 204.The gas of described compression is mainly oxygen (can also be air)；Natural air enters pile 201 with compressed oxygen after mixing container mixing.
Described fuel cell system also includes gas regulating system, and gas regulating system is arranged in mixing container 203；Described gas regulating system includes valve regulated and controls device, and oxygen content sensor is or/and compress gas compression ratio sensor.
Described oxygen content sensor is in order to sense the air of mixing and the content of oxygen in oxygen in mixing container, and the data sensed is sent to valve regulated control device.
Described compression gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data sensed is sent to valve regulated control device.
Described valve regulated controls device according to oxygen content sensor or/and the sensing result of compression gas compression ratio sensor regulates oxygen delivery valve door, air entrainment valve door, controls the conveying ratio (if natural air ratio can be 0-70%) of compressed oxygen, natural air；Mixing gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container, utilizes natural air to do dilution decompression.
Described humidification system 204 includes humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is a part for air intake conduit；After described reaction, gas outlet pipe is delivered to humidity exchanging container.
The material of described humidity exchange pipeline is only permeable airtight so that after reaction, gas and natural air carry out humidity exchange, and cannot circulate between gas.Humidity exchange pipeline spiral in humidity exchanging container is arranged, it is possible to sufficiently conducted humidity exchanges.
Embodiment two
The present embodiment and embodiment one are distinctive in that, in the present embodiment, described humidifier also includes air pressure adjustment subsystem, Collection utilization subsystem.
Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor；This barometric information received from gas pressure sensor is compared by described microprocessor with setting threshold interval；When the pressure data received is higher than the maximum setting threshold interval, microprocessor controls valve positioner and opens the air outlet valve setting time, air pressure in transfer conduit is made to be in set point, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, is that the firing equipment that needs of hydrogen manufacturing subsystem is heated by burning；When the pressure data received is lower than the minima setting threshold interval, microprocessor controls described hydrogen manufacturing subsystem and accelerates the transporting velocity of raw material.
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, hydrogen, oxygen gas and water is collected respectively from expellant gas, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generating system, the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycling.Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve, by hydrogen and oxygen separation, is then separated from water by hydrogen respectively, oxygen is separated from water.
Embodiment three
This utility model discloses a kind of water hydrogen humidifier, and described humidifier includes: humidifier body, hydrogen production by methanol system, hydrogen gas generating system, and hydrogen production by methanol system, hydrogen gas generating system, humidifier body are sequentially connected with；Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen obtains highly purified hydrogen by being coated with the membrane separation device of palladium-silver, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system, and the electric energy sent is for humidifier body work.
Embodiment four
The present embodiment and embodiment one are distinctive in that, in the present embodiment, referring to Fig. 8, the middle part of liquid container is provided with dividing plate 101, the side of dividing plate 101 arranges reaction liquid, and opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state.Dividing plate 101 is connected to pushing mechanism, and when the liquid stored in container reduces or carbon dioxide increases up to impose a condition, pushing mechanism drives dividing plate action, reduces the volume of storage reaction liquid regions, increases the volume in storage carbon dioxide region.So while preparing hydrogen, can collecting the carbon dioxide of release, reduce the discharge of carbon dioxide, the carbon dioxide of collection is also used as the raw material of subsequent handling.The two ends of dividing plate 101 are arranged in chute 102, can slide along chute 102.
In sum, the water hydrogen humidifier that the utility model proposes, available methanol prepares the hydrogen gas generation energy as humidifier body, it is possible to humidifier body is used for the place not having alternating current.
Here description of the present utility model and application is illustrative, is not wishing to limit in the above-described embodiments scope of the present utility model.The deformation of embodiments disclosed herein and change are possible, for those skilled in the art embodiment replace and the various parts of equivalence are known.It should be appreciated by the person skilled in the art that when without departing from spirit of the present utility model or substitutive characteristics, this utility model can in other forms, structure, layout, ratio, and realize with other assembly, material and parts.When without departing from this utility model scope and spirit, it is possible to embodiments disclosed herein is carried out other deformation and changes.
Claims (9)
1. a water hydrogen humidifier, it is characterised in that described humidifier includes: humidifier body, hydrogen production by methanol system, hydrogen gas generating system, and hydrogen production by methanol system, hydrogen gas generating system, humidifier body are sequentially connected with；
Described humidifier body includes housing, water container, controller, transducer, mist amount actuator, fan, and controller, transducer, mist amount actuator, fan are arranged in housing, and controller controls the work of transducer, mist amount actuator, fan；Humidifier body is provided with connection cable, connects cable and is connected with hydrogen gas generating system；
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, and hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes solid hydrogen and stores container, liquid container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, and separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen stores container, liquid container is connected with hydrogen producer respectively；Liquid container stores the first alcohol and water of liquid；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes the first startup device, the second startup device；Described first starts device includes the first heating arrangements, the first gasification pipe, and the internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；One end of described first gasification pipe connects liquid container, is sent in the first gasification pipe by methanol by raw material conveying device；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition；Described second starts device includes the second gasification pipe, the main body of the second gasification pipe is arranged at described reformer chamber, first gasification pipe is or/and the methanol of the second gasification pipe output heats the second gasification pipe while being reformer chamber heating, by the methanol gasifying in the second gasification pipe；Described reformer chamber inwall is provided with and adds pipe line, adds and is placed with catalyst in pipe line；Described device for rapidly starting by heat described in add pipe line attach most importance to whole room heating；
The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual generator, and the electric energy sent is stored in battery by manual generator；
Described solid hydrogen stores and stores solid hydrogen in container, and when hydrogen generating system starts, by gasifying, solid hydrogen is converted to gaseous hydrogen by module, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer and starts heat energy, as the startup energy of hydrogen producer；
Described hydrogen manufacturing subsystem by prepared hydrogen by transfer conduit real-time Transmission to hydrogen gas generating system；Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares；
Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, collects hydrogen, oxygen gas and water from expellant gas respectively；
Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve；
Described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, pile；Described pile includes some sub-fuel cell modules, and each sub-fuel cell module includes at least one super capacitor；
Described fuel cell system also includes air intake conduit, outlet pipe；The gas of compression is mainly oxygen；Air enters pile with oxygen after mixing container mixing；
Described fuel cell system also includes gas regulating system；Described gas regulating system includes valve regulated and controls device, and oxygen content sensor is or/and compress gas compression ratio sensor；
Described oxygen content sensor is in order to sense the air of mixing and the content of oxygen in oxygen in mixing container, and the data sensed is sent to valve regulated control device；
Compression gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data sensed is sent to valve regulated control device；
Described fuel cell system also includes humidification system, and humidification system includes humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is a part for air intake conduit；After reaction, gas is delivered to humidity exchanging container by outlet pipe,
The material of described humidity exchange pipeline is only permeable airtight so that after reaction, gas and natural air carry out humidity exchange, and cannot circulate between gas.
2. a water hydrogen humidifier, it is characterised in that described humidifier includes: humidifier body, hydrogen production by methanol system, hydrogen gas generating system, and hydrogen production by methanol system, hydrogen gas generating system, humidifier body are sequentially connected with；
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, and described hydrogen manufacturing subsystem includes hydrogen producer, membrane separation device；Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber.
3. water hydrogen humidifier according to claim 2, it is characterised in that:
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, and hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes solid hydrogen and stores container, liquid container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, and separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen stores container, liquid container is connected with hydrogen producer respectively；Liquid container stores the first alcohol and water of liquid；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes the first startup device, the second startup device；Described first starts device includes the first heating arrangements, the first gasification pipe, and the internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；One end of described first gasification pipe connects liquid container, is sent in the first gasification pipe by methanol by raw material conveying device；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition；Described second starts device includes the second gasification pipe, the main body of the second gasification pipe is arranged at described reformer chamber, first gasification pipe is or/and the methanol of the second gasification pipe output heats the second gasification pipe while being reformer chamber heating, by the methanol gasifying in the second gasification pipe；Described reformer chamber inwall is provided with and adds pipe line, adds and is placed with catalyst in pipe line；Described device for rapidly starting by heat described in add pipe line attach most importance to whole room heating；
Described solid hydrogen stores and stores solid hydrogen in container；First alcohol and water in described liquid container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange；Vaporizer is connected with reformer chamber, and reformer chamber is provided with catalyst；It is provided with membrane separation device in separation chamber, obtains hydrogen from the aerogenesis end of membrane separation device；Described membrane separation device is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver；
Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, collects hydrogen, oxygen gas and water from expellant gas respectively；
Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve.
4. water hydrogen humidifier according to claim 3, it is characterised in that:
The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual generator, and the electric energy sent is stored in battery by manual generator.
5. water hydrogen humidifier according to claim 2, it is characterised in that:
Described humidifier body includes housing, water container, controller, transducer, mist amount actuator, fan, and controller, transducer, mist amount actuator, fan are arranged in housing, and controller controls the work of transducer, mist amount actuator, fan；Humidifier body is provided with connection cable, connects cable and is connected with hydrogen gas generating system.
6. water hydrogen humidifier according to claim 2, it is characterised in that:
Described hydrogen gas generating system includes fuel cell, and fuel cell includes some sub-fuel cell modules, and each sub-fuel cell module includes at least one super capacitor.
7. water hydrogen humidifier according to claim 2, it is characterised in that:
Described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, pile；Described gas supply device utilizes the gas of compression as power, and automatic transport is to pile；Described pile includes some sub-fuel cell modules, and each sub-fuel cell module includes at least one super capacitor；
Described fuel cell system also includes air intake conduit, outlet pipe；The gas of compression is mainly oxygen；Air enters pile with oxygen after mixing container mixing.
8. water hydrogen humidifier according to claim 7, it is characterised in that:
Described fuel cell system also includes gas regulating system；Described gas regulating system includes valve regulated and controls device, and oxygen content sensor is or/and compress gas compression ratio sensor.
9. water hydrogen humidifier according to claim 7, it is characterised in that:
Described fuel cell system also includes humidification system, and humidification system includes humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is a part for air intake conduit；After reaction, gas is delivered to humidity exchanging container by outlet pipe；
The material of described humidity exchange pipeline is only permeable airtight so that after reaction, gas and natural air carry out humidity exchange, and cannot circulate between gas.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520867139.6U CN205351624U (en) | 2015-11-03 | 2015-11-03 | Water hydrogen humidifier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520867139.6U CN205351624U (en) | 2015-11-03 | 2015-11-03 | Water hydrogen humidifier |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN205351624U true CN205351624U (en) | 2016-06-29 |
Family
ID=56166300
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201520867139.6U Active CN205351624U (en) | 2015-11-03 | 2015-11-03 | Water hydrogen humidifier |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN205351624U (en) |
-
2015
- 2015-11-03 CN CN201520867139.6U patent/CN205351624U/en active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105261772A (en) | Water-to-hydrogen charging pile | |
| CN105261775A (en) | Water-to-hydrogen charging device for electric automobile | |
| CN105169559A (en) | Water hydrogen defibrillator | |
| CN105752311A (en) | Carbon dioxide cycled water-hydrogen-powered hot-air balloon | |
| CN205429080U (en) | Electric automobile water hydrogen charging device | |
| CN105244518A (en) | Water hydrogen monitoring equipment | |
| CN105276662A (en) | Water hydrogen geothermal system | |
| CN105305545A (en) | Water-hydrogen mobile charger | |
| CN105289355A (en) | Water-hydrogen stirrer | |
| CN105298188A (en) | Water-hydrogen three-dimensional parking device | |
| CN205231182U (en) | Water hydrogen power industrial installation | |
| CN205145496U (en) | Water hydrogen sport equipment , treadmill | |
| CN205564876U (en) | Water hydrogen room heater | |
| CN205351624U (en) | Water hydrogen humidifier | |
| CN205429076U (en) | Water hydrogen fills electric pile | |
| CN205560395U (en) | Water hydrogen searchlight | |
| CN205039206U (en) | Water hydrogen computer | |
| CN105169531A (en) | Water hydrogen injection pump | |
| CN205083854U (en) | Electronic sick bed of water hydrogen ICU | |
| CN205550075U (en) | Water hydrogen mixer | |
| CN205369251U (en) | Water hydrogen pile driver | |
| CN205348883U (en) | Water hydrogen three - dimensional parking equipment | |
| CN205641127U (en) | Water hydrogen geothermal system | |
| CN105258265A (en) | Water hydrogen humidifier | |
| CN205565757U (en) | Water hydrogen removes charger |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20210918 Granted publication date: 20160629 |
|
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20240918 Granted publication date: 20160629 |
|
| PP01 | Preservation of patent right |
Effective date of registration: 20240918 Granted publication date: 20160629 |