CN202905908U - Lithium ion secondary battery adopting coiled cell - Google Patents

Lithium ion secondary battery adopting coiled cell Download PDF

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Publication number
CN202905908U
CN202905908U CN2012205312171U CN201220531217U CN202905908U CN 202905908 U CN202905908 U CN 202905908U CN 2012205312171 U CN2012205312171 U CN 2012205312171U CN 201220531217 U CN201220531217 U CN 201220531217U CN 202905908 U CN202905908 U CN 202905908U
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pole piece
barrier film
current collector
negative
battery
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Expired - Lifetime
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CN2012205312171U
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谢皎
王瑨
胡蕴成
廖小东
梁孜
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Dongfang Electric Co ltd
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Dongfang Electric Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Abstract

The utility model relates to a lithium ion secondary battery adopting a coiled cell, and belongs to the technical field of manufacture of cells of lithium ion secondary batteries. The structure of the lithium ion secondary battery adopting the coiled cell is that the coiling lengths of a first diaphragm (7), a cathode current collector (12) and a second diaphragm (8) of the cell are arranged to be one more circle than the coiling lengths of an anode piece (9) and a cathode piece (10), so that the cathode current collector is wrapped in a circle at the outer layer of the cell; once an outer metal object is pierced into the battery, a housing of the battery is contacted with the cathode current collector first, and a high current discharging process is instantaneously caused, therefore, the electrical charge state (SOC (System on a Chip)) of the cathode can be reduced, on the other hand, a short circuit point is enlarged, and as a result, the probability that the battery meets thermal runaway can be greatly reduced; the cathode piece and the anode piece can be most effectively insulated and separated at the same time through the structure of the lithium ion secondary battery adopting the coiled cell, so that the capacity of the cell to resist disturbance is improved, the phenomenon of short circuit or puncturing can be avoided, and the stability of the whole battery can be improved.

Description

A kind of lithium rechargeable battery that uses the takeup type battery core
Technical field
The utility model relates to a kind of lithium rechargeable battery, and more particularly, the utility model relates to a kind of lithium rechargeable battery that uses the takeup type battery core, belongs to the manufacturing technology field of lithium rechargeable battery battery core.
Background technology
Compare with other chemical power source, lithium ion battery has the performance of many excellences, high such as energy density, have extended cycle life, open circuit voltage is high, memory-less effect, safety non-pollution etc., develop rapidly through recent two decades is applied in the field of portable devices such as mobile phone, notebook computer, digital camera widely.In recent years, along with the further raising of lithium ion battery energy density, its application just progressively is extended to the high-tech sectors such as Aero-Space, satellite, guided missile electric automobile.
As everyone knows, lithium ion battery some unpredictable abuse condition can occur unavoidably in the process of using, as: overcharge, push, pierce through etc., serious threat consumer's safety.Can the fail safe and the fail safe under abuse condition that therefore, how to improve lithium ion battery be used most important for lithium ion battery on a large scale.Current, for the fail safe that how to improve lithium ion battery, a large amount of research has all been done by each large research institution and enterprise, is mainly manifested in the following aspects:
(1) the thermally-stabilised and fail safe of raising battery material is such as the diaphragm material of exploitation Heat stability is good, constitutionally stable electrode active material etc.;
(2) reliability and stability of raising battery all parts;
(3) design safety starting drive is such as CID, impression, FUSE, explosion-proof valve etc.
With upper type for lithium ion battery in the situation that slow abuse; can play certain safety protective effect, still, for extruding or the situation about being abused fast such as pierce through; all have little time response with upper type, can't be to lithium ion battery realization safeguard protection truly.
The utility model content
The purpose of this utility model is to solve in the prior art under abuse condition, and especially in extruding or pierce through and wait situation about abusing fast, the defective that lithium ion battery security is poor provides a kind of novel high security lithium ion secondary battery.
For realizing order of the present utility model, its concrete technical scheme is as follows:
A kind of lithium rechargeable battery that uses the takeup type battery core comprises battery case, battery core, positive pole ear, negative lug, positive terminal and negative pole end, and wherein battery core is from inside to outside reeled by anode pole piece, cathode pole piece and two-layer barrier film and formed, and is the coiling layer structure; The positive electrode that described anode pole piece comprises plus plate current-collecting body and is coated in the anode collection surface, the negative material that described cathode pole piece comprises negative current collector and is coated in the negative pole currect collecting surface, it is characterized in that: begin the place at coiling, from inside to outside be followed successively by the first barrier film, cathode pole piece, the second barrier film and anode pole piece; In coiling end, from inside to outside be followed successively by anode pole piece, the first barrier film, negative current collector and the second barrier film; The many circles of the coiling Length Ratio anode pole piece of described the first barrier film, negative current collector and the second barrier film and cathode pole piece.
Negative current collector described in the utility model is Copper Foil.
Plus plate current-collecting body described in the utility model is aluminium foil.
Negative material described in the utility model is to be coated at least one side of negative current collector.
Above-mentioned negative material is conventional negative material well known in the art, such as in Delanium, native graphite, hard charcoal, the agraphitic carbon one or more.
Positive electrode described in the utility model is to be coated at least one side of plus plate current-collecting body.
Above-mentioned positive electrode is conventional negative material well known in the art, such as one or more of cobalt acid lithium, LiFePO 4, LiMn2O4, ternary material.
The first barrier film described in the utility model and the second barrier film are polypropylene micro-porous film (PP), microporous polyethylene film (PE), glass mat or trilamellar membrane (PP/PE/PP), polyamide membrane (PI).
Useful technique effect:
Compare with traditional lithium ion battery, the battery core skin of the utility model lithium ion battery has wrapped up a circle negative current collector (Copper Foil), when having the external metallization object to thrust inside battery, battery case (being equivalent to anode) at first contacts with negative current collector (Copper Foil), moment produces a heavy-current discharge process, can reduce on the one hand negative pole state-of-charge (SOC), increased short dot on the other hand, greatly reduce the probability of battery thermal runaway.In order to improve self antijamming capability of battery core, structure of the present utility model simultaneously can the anticathode pole piece and the anode pole piece blocking-up of the most effectively insulating, and short circuit or punch-through can not occur, improves cell integrated stability.
Description of drawings
Fig. 1 is the utility model lithium ion battery structure schematic diagram.
Fig. 2 is traditional electrical cored structure generalized section.
Fig. 3 is the pond core strueture generalized section of the utility model lithium-ion electric.
Reference numeral: 1 is that battery case, 2 is that battery core, 3 is that positive pole ear, 4 is that negative lug, 5 is that positive terminal, 6 is that negative pole end, 7 is that the first barrier film, 8 is that the second barrier film, 9 is that anode pole piece, 10 is that cathode pole piece, 11 is that plus plate current-collecting body, 12 is negative current collector.
Embodiment
Embodiment 1
A kind of lithium rechargeable battery that uses the takeup type battery core, comprise battery case 1, battery core 2, positive pole ear 3, negative lug 4, positive terminal 5 and negative pole end 6, wherein battery core 2 is from inside to outside reeled by anode pole piece 9, cathode pole piece 10 and two-layer barrier film and is formed, and is the coiling layer structure; Described anode pole piece 3 comprises plus plate current-collecting body 11 and the positive electrode that is coated in plus plate current-collecting body 11 surfaces, described cathode pole piece 10 comprises negative current collector 12 and the negative material that is coated in negative current collector 12 surfaces, begin the place at coiling, from inside to outside be followed successively by the first barrier film 7, cathode pole piece 10, the second barrier film 8 and anode pole piece 9; In coiling end, from inside to outside be followed successively by anode pole piece 9, the first barrier film 7, negative current collector 12 and the second barrier film 8; The coiling Length Ratio anode pole piece 5 of described the first barrier film 7, negative current collector 12 and the second barrier film 8 and cathode pole piece more than 10 one circles.
Embodiment 2
On the basis of embodiment 1, preferred:
A kind of lithium rechargeable battery that uses the takeup type battery core, comprise battery case 1, battery core 2, positive pole ear 3, negative lug 4, positive terminal 5 and negative pole end 6, wherein battery core 2 is from inside to outside reeled by anode pole piece 9, cathode pole piece 10 and two-layer barrier film and is formed, and is the coiling layer structure; Described anode pole piece 3 comprises plus plate current-collecting body 11 and the positive electrode that is coated in plus plate current-collecting body 11 surfaces, described cathode pole piece 10 comprises negative current collector 12 and the negative material that is coated in negative current collector 12 surfaces, begin the place at coiling, from inside to outside be followed successively by the first barrier film 7, cathode pole piece 10, the second barrier film 8 and anode pole piece 9; In coiling end, from inside to outside be followed successively by anode pole piece 9, the first barrier film 7, negative current collector 12 and the second barrier film 8; The coiling Length Ratio anode pole piece 9 of described the first barrier film 7, negative current collector 12 and the second barrier film 8 and cathode pole piece more than 10 one circles.
Described negative current collector 12 is Copper Foil.
Described plus plate current-collecting body 11 is aluminium foil.
Described negative material is to be coated at least one side of negative current collector 12.
Described positive electrode is to be coated at least one side of plus plate current-collecting body 11.
Described the first barrier film 7 and the second barrier film 8 are polypropylene micro-porous film, microporous polyethylene film, glass mat, PP/PE/PP trilamellar membrane or polyamide membrane.
Embodiment 3
A kind of novel high-safety lithium battery core strueture comprises that anode pole piece 9, cathode pole piece 10 and two-layer membrane layer form; Two-layer membrane layer is enclosed within on the U-shaped volume pin first, rotate half-turn, insert cathode pole piece 10, rotate again half-turn, insert again anode pole piece 9, after the design number of turns of again anode pole piece 9, two-layer membrane layer and cathode pole piece 10 being reeled together again with negative current collector 12(Copper Foil) and the two-layer membrane layer circle of reeling together, form at last the high-safety lithium battery core strueture.
Further, above-mentioned high-safety lithium battery core strueture, wherein, 10 are extended with negative pole end on the described cathode pole piece; Above-mentioned cathode pole piece 10 refers to negative material evenly is coated at least one side of Copper Foil; Described negative material is one or more in Delanium, native graphite, hard charcoal, the agraphitic carbon.
Further, above-mentioned high-safety lithium battery core strueture wherein, is extended with positive terminal 5 on the described anode pole piece 9; Above-mentioned anode pole piece 9 refers to positive electrode evenly is coated at least one side of aluminium foil; Described positive electrode is one or more of cobalt acid lithium, LiFePO 4, LiMn2O4, ternary material.
Further, above-mentioned high-safety lithium battery core strueture, wherein, described two-layer membrane layer is polypropylene micro-porous film (PP), microporous polyethylene film (PE), glass mat, trilamellar membrane (PP/PE/PP) or polyamide membrane (PI).
Embodiment 4
The security performance test
Experimental group 1~8 and control group 1~8 prepared battery capacity are 750mAh(0.1C).Under the room temperature, the lithium ion battery that respectively selects 6 experimental group 1~8 and control group 1~8 to make, and battery charged with 0.1mAh/cm2, upper voltage limit 4.2V, cut-off current is 0.05C, does respectively acupuncture and impact test after being full of electricity.Testing standard is with reference to U.S. UL standard, by standard for not on fire, do not explode (*: expression is not passed through; Zero: expression is passed through).Experimental group 1~8 adopts the battery of the utility model core strueture, and control group is not for using the battery of the utility model core strueture.
Experimental result is as shown in table 1.
Table 1
Figure 318585DEST_PATH_IMAGE001
Can find out that from experimental group 1~8 and control group 1~8 battery core of the utility model structure can significantly improve the fail safe of battery.

Claims (6)

1. lithium rechargeable battery that uses the takeup type battery core, comprise battery case (1), battery core (2), positive pole ear (3), negative lug (4), positive terminal (5) and negative pole end (6), wherein battery core (2) is from inside to outside reeled by anode pole piece (9), cathode pole piece (10) and two-layer barrier film and is formed, and is the coiling layer structure; The positive electrode that described anode pole piece (3) comprises plus plate current-collecting body (11) and is coated in plus plate current-collecting body (11) surface, the negative material that described cathode pole piece (10) comprises negative current collector (12) and is coated in negative current collector (12) surface, it is characterized in that: begin the place at coiling, from inside to outside be followed successively by the first barrier film (7), cathode pole piece (10), the second barrier film (8) and anode pole piece (9); In coiling end, from inside to outside be followed successively by anode pole piece (9), the first barrier film (7), negative current collector (12) and the second barrier film (8); The coiling Length Ratio anode pole piece (9) of described the first barrier film (7), negative current collector (12) and the second barrier film (8) and cathode pole piece (10) Duo Yiquan.
2. a kind of lithium rechargeable battery that uses the takeup type battery core according to claim 1, it is characterized in that: described negative current collector (12) is Copper Foil.
3. a kind of lithium rechargeable battery that uses the takeup type battery core according to claim 1, it is characterized in that: described plus plate current-collecting body (11) is aluminium foil.
4. a kind of lithium rechargeable battery that uses the takeup type battery core according to claim 1 is characterized in that: described negative material is at least one side that is coated in negative current collector (12).
5. a kind of lithium rechargeable battery that uses the takeup type battery core according to claim 1 is characterized in that: described positive electrode is at least one side that is coated in plus plate current-collecting body (11).
6. a kind of lithium rechargeable battery that uses the takeup type battery core according to claim 1 is characterized in that: described the first barrier film (7) and the second barrier film (8) are polypropylene micro-porous film, microporous polyethylene film, glass mat, PP/PE/PP trilamellar membrane or polyamide membrane.
CN2012205312171U 2012-10-17 2012-10-17 Lithium ion secondary battery adopting coiled cell Expired - Lifetime CN202905908U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105576190A (en) * 2014-11-04 2016-05-11 三星Sdi株式会社 Rechargeable battery
KR20190039641A (en) * 2017-10-05 2019-04-15 로베르트 보쉬 게엠베하 Battery cell for a lithium-ion-battery
CN112490493A (en) * 2021-01-19 2021-03-12 郭彬彬 Safe square metal shell lithium ion battery
CN113571777A (en) * 2021-07-19 2021-10-29 恒大新能源汽车投资控股集团有限公司 Winding type battery cell and lithium ion battery

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105576190A (en) * 2014-11-04 2016-05-11 三星Sdi株式会社 Rechargeable battery
US10454091B2 (en) 2014-11-04 2019-10-22 Samsung Sdi Co., Ltd. Rechargeable battery comprising first and second electrodes each comprising uncoated regions and coated regions
CN105576190B (en) * 2014-11-04 2021-06-01 三星Sdi株式会社 Rechargeable battery
KR20190039641A (en) * 2017-10-05 2019-04-15 로베르트 보쉬 게엠베하 Battery cell for a lithium-ion-battery
CN109638217A (en) * 2017-10-05 2019-04-16 罗伯特·博世有限公司 Battery cell for Li-ion batteries piles
CN109638217B (en) * 2017-10-05 2023-04-07 罗伯特·博世有限公司 Battery cell for lithium ion battery pack
KR102643404B1 (en) * 2017-10-05 2024-03-07 로베르트 보쉬 게엠베하 Battery cell for a lithium-ion-battery
CN112490493A (en) * 2021-01-19 2021-03-12 郭彬彬 Safe square metal shell lithium ion battery
CN113571777A (en) * 2021-07-19 2021-10-29 恒大新能源汽车投资控股集团有限公司 Winding type battery cell and lithium ion battery

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GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20180423

Address after: 610000, No. 18, West core road, hi tech West District, Sichuan, Chengdu

Patentee after: DONGFANG ELECTRIC Co.,Ltd.

Address before: Jinniu District Chengdu City, Sichuan province 610036 Shu Road No. 333

Patentee before: DONGFANG ELECTRIC Corp.

CX01 Expiry of patent term
CX01 Expiry of patent term

Granted publication date: 20130424