CN1986738A - Combined oil-metal polymer solution and its application - Google Patents

Combined oil-metal polymer solution and its application Download PDF

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CN1986738A
CN1986738A CNA2005101350944A CN200510135094A CN1986738A CN 1986738 A CN1986738 A CN 1986738A CN A2005101350944 A CNA2005101350944 A CN A2005101350944A CN 200510135094 A CN200510135094 A CN 200510135094A CN 1986738 A CN1986738 A CN 1986738A
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fermentation
polymer solution
oil
acid
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张才腾
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Abstract

The present invention relates to a kind of combined oil-metal polymer solution and its application. The metal polymer is mixture of oil, water, soluble R-COOH carbohydrate and/or carbohydrate polymer and metal salt and/or amine, and may be esterified and fermented to produce diesel oil. The combined oil-metal polymer solution may be used in producing biodiesel oil solution through a special fermentation process. During the said reaction, organic waste may be treated into fertilizer, feed, etc.

Description

Combined oil-metal polymer solution and application thereof
Technical field
The present invention relates to a kind of combined oil-metal polymer solution and application thereof, particularly relate to a kind of oil product through being combined as metal-dislocated polymer solution and esterification fermentation reaction thereof, can extract diesel oil behind the oil product metal-dislocated polymer esterification fermentation reaction wherein.This metal esterification ferment biological catalyzer is used for oil product, increases diesel oil matter solution and can increase combustion heat value.Its fungi and/or algae in above-mentioned reaction grow up through having the molten equipment of air/water and/or oil phase, absorb gas or reclaim combustion gases, the bioprotein esterification treatment of deriving becomes solvent slop liquid etc., in addition with processing organic waste and the application that becomes in fertilizer, feed and food fermentation and the generation organic gas (methane-containing gas).
Background technology
In general, esterification is chemical industry processing procedure significant element, and is well known, oil and alcohol become transesterificationization, and oil, carbonyl compound become fatty acid ester, are all the effect of esterification polyreaction, but the esterification polyreaction also needs the catalyst catalyzed reaction to arrange in pairs or groups, and could react successfully.The catalyst structure of early stage esterification very is complicated, and esterification is separated with other chemical reactions, can one react unlike invention metal esterification ferment biological catalyzer now, also can one react for stability high oil, carbonyl compound, just can reach unlike former some taller temperature reaction under high pressure, the cost of being invested, financial resource and material resource are great well imagines, but the present invention now simply just can reach.Moreover, esterification and other reactivity worth handling oil with metal esterification ferment biological catalyzer, carbonyl compound becomes fatty acid ester, also be rare, utilization has the class (as lichensization) of mixture and/or algaeization can be applied to absorb Carbon Dioxide in Air and water reaction through fungi and marine alga symbiosis, the absorbed nitrogen condensation reaction forms carbohydrate, protein, usnic acid, fatty acids products (kind difference, purposes is not quite similar, some lichens kind can produce more lipid acid) and can further carry out esterification fermentation reaction or other esterifications, manually copy diesel oil matter solution and produce, also be rare, has only the oil product upgrading in early days, directly can not increase the processing of diesel oil matter solution, the early stage reaction carriers life-span is very of short duration, but forming the special fermentation reaction of metal-dislocated polymer solution because of oil product now can make the quality of material increase and upgrading, and can develop into artificial imitated diesel oil matter solution, become high-level efficiency, high-density, high-quality solvent liquid.Utilize metal-dislocated polymer solution to make up oil product and become metal ferment biological catalyzer to increase the matter modifying oil also be rare.
As seen, existing technology is still demanded the present invention urgently and is further improved in addition.In order to solve existing technological deficiency, relevant manufacturer there's no one who doesn't or isn't seeks solution painstakingly, but does not see always that for a long time suitable design finished by development, and this obviously is the problem that the anxious desire of relevant dealer solves.
Have and state the defective that existing technology exists in view of this, the present invention is based on and be engaged in this type of product design manufacturing practical experience and expertise for many years, actively studied innovation, in the hope of founding a kind of new oil product upgrading is diesel oil and the method that increases biodiesel (combustion heat value), can improve general existing on the market conventional technology, make it have more practicality.Through constantly research, design, and repetitiousness studies sample and improvement, creates the present invention who has practical value finally.
Summary of the invention
The objective of the invention is to, overcome the defective that existing technology exists, is diesel oil and the method that increases biodiesel (combustion heat value) and a kind of new oil product upgrading is provided, and technical problem underlying to be solved is to make it have the good matter modifying oil ability that increases.
Another object of the present invention is to, provide a kind of oil product to form metal-dislocated polymer solution, technical problem to be solved is to make it be applied to metal ferment biological catalyzer to increase technical fields such as matter modifying oil, and the present invention proposes metal-dislocated polymer solution that oil product forms to have in above-mentioned reaction and increase matter fungi and marine alga symbiosis and the class of mixture such as the technical field of lichensization and/or algaeization are arranged.
A further object of the present invention, it is diesel oil and the method that increases biodiesel (combustion heat value) that a kind of oil product upgrading is provided, and technical problem to be solved is to make it have more practicality, and can increase economic efficiency, have the effect of enhancement on the whole, and have the utility value on the energy industry.
A further object of the present invention, provide a kind of metal-dislocated polymer solution handle organic waste and become application in fertilizer, feed and food fermentation and the generation organic gas (methane-containing gas) and the new technology of other extensions in application.
A kind of oil product upgrading is that diesel oil and the method that increases biodiesel (combustion heat value) are oil product and/or material through general growth or fermentation lichensization and/or algaeization and/or metal esterification ferment biological catalyzer esterification (or general esterification), more progressive if be combined as metal-dislocated polymer solution through fermentation lichensization and/or algaeization and/or esterification and/or other application by oil product, its characteristic and each constituent quality per-cent ratio range: by oil (fatty acids and/or its reversible transformation substance): about 20-99% and/or water: about 0.1-99.87% and/or R-COOH and/or its reversible transformation substance: about 0.01-40% dissolves carbohydrate (containing sugar-metal) and/or its reversible transformation substance such as starch: about 0.01-30%, and/or polymkeric substance (containing polymeric material) and/or usnic acid (cooperation carbohydrate) and/or other metal chelators (cooperation carbohydrate) of tool hydroxyl or hydroxyl and amino and/or carboxyl and/or carbohydrate (containing glycan-metal): about 0.01-30%, and/or metal-salt and/or ore and/or bone (containing sugar-metal and/or glycan-metal need not add): about 0.01-30%, with ammonia or amine substance and/or reversible several times mutually transformation substance of NH2 such as protein: about 0.01-30%, comprise above-mentioned two or more composition composition such as soybean fatty acids and protein or contain the similar close composition of above-mentioned composition: about 0.01-70%, and/or the bacterium of the bacterium of the bacterium of generation carboxylic acid and material such as milk-acid bacteria and material replacement carboxylic acid and/or generation ammonia or amine and material replacement ammonia or amine and/or generation carbohydrate and bacterium and material replacement lipid acid and/or Pepsin and/or the bacterium and/or the cell of material replacement carbohydrate and/or generation lipid acid thereof, add the solution that stirring or heating mix according to a conventional method, has the protein fermentation multiplication characteristic, wherein R-COOH is organic acid or organic acid thing, comprises one or more combined oil-metal dislocated polymers.
Aforesaid combined oil-metal polymer solution, described oil product are lipid acid oil product, cracking oil product, the oil product that is rich in the oH base, mineral wet goods, and described ore is sand, rock, bone, various metallic ore, ore deposit soil, ore deposit soil agglomerating ceramic tile.Its characteristic is wherein to contain fungi and/or algae and/or liver moss and/or tealeaves cell and/or other microorganisms or esterification ferment and/or wine canal ferment and/or is allocated as composite bacteria and/or function yeast by the metal-dislocated polymer solution principle of fermentation
Aforesaid combined oil-metal polymer solution reaction process, described lichens turn to fungi and the marine alga symbiosis is grown up as various lichens, moss, liver moss.Described algae turns to algae and grows up as spirulina, chlorella, green alga.
Aforesaid combined oil-metal polymer solution reaction process, described lichensization and/or algaeization and/or other plant biological and/or other use substratum and be suitably for humic acids (or other) metal-dislocated polymer solution, it is that air (contains nitrogen that food comes in the source, oxygen), organic and inorganic dust, grease in the air, carbonic acid gas (or carbanion, bicarbonate ion) and water, rock and ore (being laid in the equipment), bone, phosphate fertilizer, potash fertilizer, the acid of quantitative dosing titration trace ore deposit soil and/or metal-salt and/or inorganic salt and/or carbohydrate and/or carboxyl and/or urea and/or ammonia and/or amine substance and/or discarded proteic substance or according to aforementioned combined oil-metal polymer solution nutritive medium or according to aforementioned (being fit to plant such as EM bacterium) combined oil-metal polymer solution nutritive medium or the fertilizer according to claim 11 or precedingly supply fungi and/or algae and/or other after when the acid that adds carboxyl or amine substance are arranged to use composition be that to meet that combined oil-metal polymer solution lacks or supply fungi and/or algae and/or other plant biological nutrition composition during the breeding fermentation be to meet combined oil-metal polymer solution to lack of fermenting, and/or wood dust, the ceramic tile that ore deposit soil burns, paddy, sunlight (and/or equipment contains light irradiation apparatus such as bulb).
Aforementioned combined oil-metal polymer solution reaction process, described lichensization and/or algaeization stages of labor and thing edible, pharmacy, feed, microbiotic, sterilization, weedicide, dyestuff, purification algae kind, cultivation lipid acid, esterification are diesel oil
Aforesaid combined oil-metal polymer solution reaction process, described lichensization and/or algaeization and/or other the photosynthetic plant biologicals equipment used of just growing is preposition air disinfection and/or film filter purification of carbon dioxide/nitrogen, general gas-liquid mixes or has air/water and/or oil (refuel attitude its be the oil whip shape after mixing) and mixes and form the vortex board device by prolong row, utilize air revolution and water conservancy diversion metal plate to produce the rinse bath (application) of whirlpool water and/or oil but other gas-liquids mix, the heat exchange condenser that utilize to produce the prolong row usefulness of vortex promotes gas-liquid mix equipment and bioreactor, be respectively other, pipe circles round into the channeltype of circle pillar from top to down, the straight bent-tube boiler of manifold (" order " word shape manifold is arranged in the straight bend pipe of " W " shape), straight bent plate face formula (straight plate face and bent plate face are connected in series formation " traverse W " shape at interval) and be all transparent material light-permeable and/or translucent material (can open the light lead shield light) and contain light irradiation apparatus, receiving tank is set up circulation device and is installed additional and stir masher and blend, first and/or the middle growth of decomposing machine cracking plant biological, set up again and stir breeding fermentation holding tank (containing heat exchange heating tube row or warming apparatus), adding is according to the batching that nutrition-allocated proportion lacked of metal-dislocated polymer solution, allow and stir a large amount of cultivation propagation kind of the bacterium of the quick fermentation of heating after grinding cracking through stirring, so bacterium is molten in the carbon dioxide gas liquid phase, photosynthetic production is cultivated, circulation fluid stirs and grinds cracking and mix (duplicated hyperplasia grow up to just maybe need stir grind cracking), stir four steps of breeding fermentation holding tank and repeat the continuous hyperplasia that circulates back and forth, equipment drawing such as Fig. 1 to Fig. 5.The lichens absorbing carbon dioxide is that to be pH value be 3.5-7.5 (the algae pH value is 6-11.5) to usnic acid, solution cooperates air/water mix equipment a large amount absorbing carbon dioxide such as Fig. 7, and Fig. 7 is the percentage ratio of carbonate, bicarbonate ion and carbonic acid gas in the different PH aqueous solution.Know the reaction consumes amount of dissolved carbon dioxide with the pH value monitoring, and then how much control air quantity, make dissolved carbon dioxide thickness consistent with the reaction consumes amount.When the reaction consumes amount is known the growth velocity speed, transfer the circulation fluid flow velocity, the photosynthesis light requirement is many or can wait and regulate as LED lamp, the luminous light lead of optical fiber by including light irradiation apparatus less.
Aforesaid general gas-liquid mixes or has air/water and/or the molten equipment of oil phase is a large amount absorbing carbon dioxide, titration carboxylic acid or ammonia or amine substance and/or salt make to be acid or alkalescence and/or to produce mix equipment and/or preceding equipment tool heat exchange condenser (containing condenser) urge molten carbonic acid gas and/or thermal stimulation is grown of vortex.
Aforesaid combined oil-metal polymer solution reaction process, described lichensization and/or algaeization and/or other plant biologic shift need do to stir for esterification and grind cracking and/or mix carboxylic acid and/or carbohydrate and sterilization sterilising treatment such as high temperature, radio radiation.
Aforesaid combined oil-metal polymer solution reaction process, described esterification be titanium (or other, the suggestion of the metal ion of the inside wrong fount is with cobalt and/or aluminium or antimony) metal esterification ferment (as lipase esterification ferment and/or sneak into a little wine canals) biological catalyst come esterification or esterification treatment.
Aforesaid combined oil-metal polymer solution reaction process, described reactant of esterification is the acid of oil, carbonyl compound, lipid acid, carboxyl, weak polyphenolic acid, carbohydrate alcohols or the general alcohols through the wine canalization, and esterification process can add gases such as negative oxygen ion o-2, o2-or nascent oxygen in good time and strengthen the upgrading ester solvent.
Aforesaid combined oil-metal polymer solution reaction process, described esterification fermentation equipment used be for having stirring and/or aerated fermentation equipment such as Fig. 6, through settling agent glue coagulation two be separated (solvent with non-solvent mutually) or fractionation by distillation.
Aforesaid combined oil-metal polymer solution, its characteristic adds amino after dislocated polymer solution adds metal-salt and/or metallic ore can be changed to reversible several times mutually transformation substance of NH2 such as protein, thereafter mat has grinding and/or dissolving and/or cracking and/or ferment (as the hydrolysis bacterium) fermented protein becomes amine and Amino acid, and/or add a small amount of Ammonia when above-mentioned solution fermentation initiator, above-mentioned or carbohydrate or carboxylic acid or lipid acid can use according to above-mentioned grinding and/or dissolving and/or cracking and/or ferment conversion method, and/or a small amount of above-mentioned transformation substance is when above-mentioned solution fermentation initiator.
Aforementioned grinding and/or dissolving and/or cracking are used in the plant cultivation growth, are fit to the first and/or middle utilization in vegetative period of algae and/or lichens and/or other photosynthetic plant biologicals.
Aforementioned its reaction process of combined oil-metal dislocated polymer and conversion unit and reaction soln add sterilization factors in like manner to be prevented living contaminants and promotes utilization in the propagation producing algae and/or lichens and/or other photosynthetic plant biologicals and/or other substratum and/or purification.
Aforesaid combined oil-metal polymer solution is being handled (adding according to the proportioning of coming that combined oil-metal polymer solution lacked) organic waste (curable or liquefaction) and/or is being become application in fertilizer, feed, food fermentation and/or generation { substratum (contain hydrolysis, produce hydrogen and produce bacterium such as acetate, methane as metal-dislocated polymer) and the metal ion suggestion of nutrition (aforesaid metal-dislocated polymer matter does not contain bacterium) the inside wrong fount adopt nickel or molybdenum, and both materials mix and the generation } organic gas (methane-containing gas).
Aforesaid combined oil-metal polymer solution oxidative condensation/condensation reaction, fermentation with biochemical reaction, metal ferment biological catalyzer, bacterium culture medium and saved system, food health care, plant in chemical substance production, oil prod handle that nano material is made in application, nanofiltration, nano-inorganic substance, fermentation, nanometer is moulded rubber, nanofiber, nano ceramic material manufacturing, made extension The application of new technique such as liquid crystal and semi-conductor.
The present invention compared with prior art has tangible advantage and beneficial effect.In order to reach goal of the invention, major technique of the present invention thes contents are as follows:
A kind of combined oil-metal polymer solution that the present invention proposes, be with No. 094103202 application case of inventor's TaiWan, China patent, title: metal-dislocated polymer solution, relevant oil product is used and is further developed, case was used for the metal-dislocated polymer solution best group of oil product and is oil (lipid acid) before we knew, mineral substance (metal ion), protein (amino source), ferment, carbohydrate, acid (organic acid of carboxyl) constitutes lipid acid-this class fermentation system of M-NH2-Pepsin-sugar, lichens (fungi and marine alga symbiosis growth lichensization) just, its mutual symbiosis material produces lipid acid, carbohydrate, protein, usnic acid, the acid etching ore, the acid etching rock, fungi and marine alga symbiosis thalline, lipid acid-M-protein-Pepsin-carbohydrate seemingly for formation, when changing (becoming amine and Amino acid) and above-mentioned formation lipid acid-when this class fermentation system of M-NH2-Pepsin-sugar is the same with fermentation and/or grinding and/or dissolving and/or crack protein matter, be newly grown up and be easy to quick breeding, it is vigorous to grow, algae photosynthesis absorbs air (containing nitrogen), organic dust, inorganic dust, carbonic acid gas and water, utilize and the air equipment illumination reaction fermentation that mixes, produce carbohydrate, protein, fungi absorbs the candy that marine alga produces, oxygen, the organic salt that rock is come, water and produce the dissolving rock usnic acid, also has weak polyphenolic acid, lipid acid etc., the carbohydrate nutrition source supports the generation of lipid acid, so strengthen the growth fermentation and make lipid acid be rich in nutrition source with sucrose during fermentation.Lichens can be solvent and oil dissolving; usnic acid has sequestering action again; after grinding lichens dissolving ore deposit soil (metal), be the usnic acid metal-dislocated polymer solution just; perhaps usnic acid (or other metal chelators) cooperates carbohydrate and the acid that adds carboxyl is arranged and amino material is arranged separately; above-mentionedly all can do next step fermentation action; just can the derive method of quality and energy of life and growth in nature, this dependence air the Nature, real is the energy dilemma a great discovery.
At first, after making up metal-dislocated polymer solution in proportion, add lichens (fungi and marine alga symbiosis thalline) and carry out fermentation culture, put into the air/water chemical industry equipment that mixes, as with No. 094125197 application case of inventor's TaiWan, China patent, title: the air/water that the retaining metal plate is combined in the application of revolving (whirlpool) eddy current chemical industry equipment that mixes attracts use, one side input air, producing vortex with water cycle through the air swirl metal plate on one side mixes, stirring fermentation when raw material mixes, under sunshine, promote propagation to derive with air.
Purpose of the present invention and to solve its technical problem underlying be to adopt following technical scheme to realize.Proposing a kind of oil product upgrading according to the present invention is that diesel oil and the method that increases biodiesel (combustion heat value) are metal-dislocated polymer solution, by oil and/or water and/or R-COOH, carbohydrate (containing sugar-metal) molecule and/or have hydroxyl or the polymkeric substance of hydroxyl and amino and/or carboxyl and/or carbohydrate (containing glycan-metal) and/or metal-salt and ammonia or amine substance mix, wherein each constituent quality per-cent ratio range is: oil: 20-99% water: 0.1-99.87%; R-COOH:0.01-40%; Carbohydrate (containing sugar-metal) molecule and/or have hydroxyl or the polymkeric substance of hydroxyl and amino and/or carboxyl and/or carbohydrate (containing glycan-metal): 0.01-30%; Metal-salt: 0.01-30%; Add with ammonia or amine substance and to stir or heating forms, R-COOH wherein is organic acid or organic acid thing.Just having begun to be fit to the humic acids metal-dislocated polymer solution is the fermented substrate fixation support, and it be the easy extinction of black liquor, itself derives from mud coal and piles up after death with lichens that to become mud coal approximate, breeds from this system's fermentation hyperplasia.
The object of the invention and solve its technical problem and can adopt following technology to realize.
At first, do an experiment, win some mosses, add a rice syrup mixed grinding and stir, be applied to and contain on the peat soil stone, normal watering, moss (itself contains lipid acid) longer again (do not have the dissolving of oiling also can) soon.Some mosses are won in another experiment, and oil adds the grinding of rice syrup mixed dissolution with the oil pool and stirs, and are applied to contain on the peat soil stone normal watering, moss longer again (similar lipid acid-M-NH2-protein-this spline structure of sugar itself) soon.Proof moss nutrition stirs through mixed grinding or dissolving or cracking, be applied to stone, soon moss is longer again, and its nutrition just is being fit to culture system (lipid acid-this class fermentation system of M-NH2-Pepsin-sugar), can cultivate own bacterial classification own and bacterial strain.The inventor designs the machine of a cover by above-mentioned principle, absorb our carbonic acid gas/other gases of wanting of the Nature air (can pass through air disinfection such as ultraviolet ray earlier) or membrane filtration technique purifying, do not stop to circulate the capable photosynthesis of this nutritive medium by its propagation procreation, life and growth in nature, wherein the air equipment of mixing has and mixes, the acid such as the citric acid of elder generation's titration carboxyl make easy absorbing carbon dioxide, fueling state is arranged, and it is the oil whip shape after mixing, become at the bioreactor lichens and to contact water ingress of air once, to contain air very fast near lichens self-sow state propagation because of the pipe the inside.The capable photosynthesis lichens of nutritive medium turns to that to be pH value approximately behind usnic acid and the absorbing carbon dioxide be 3.5 to 7 left and right sides solution, lichens fearness alkalescence is fit to acidic system, acidic system is that 3.5 times dissolved carbon dioxide efficient can reach 100% at most at pH value again, cooperate air/water and/or oil (warp and the heat exchange of stirring breeding fermentation holding tank turn cold) to mix, the cold more acidity that mixes a large amount absorbing carbon dioxide more and have, usnic acid is water-soluble relatively poor, but be dissolved in oil, solvent, usnic acid is acidic leach rock absorbing carbon dioxide again, understand the bioreactor reaction consumes amount of dissolved carbon dioxide with the pH value monitoring, and then how much control air quantity, make the thickness of dissolved carbon dioxide consistent with the reaction consumes amount.Lichensization only needs medium luminosity, and when the reaction consumes amount learnt that growth velocity is slow, the photosynthesis light requirement can include light irradiation apparatus by equipment too much or very little, and, optical fiber light lead luminous as LED lamp, optical fiber waits and regulate subsidy.The capable photosynthesis quality of nutritive medium is to allow its propagation procreation key factor, poor growth in lichens the Nature, growing up after the moulding is slowly, but be combined into nutritive medium at substratum each time, when fermentation strain just grows into type, complexed metal dislocated polymer solution and dietetic alimentation system ferment, its speed can be fast, so photosynthesis just utilizes this period of time to quicken to cultivate propagation, propagation can be copied the shower of growing in the Nature at stone or ceramic tile or carrier, perhaps closed conduct formula, flat or semi-enclosed or by by way of example or other mode bioreactors, allow mycelia have and to add a little wood dusts with adhering to, (being fit to plant) metal-dislocated polymer solution nutritive medium or precedingly supply of the promote growth of lichens nutrition after when the acid that adds carboxyl such as citric acid material are arranged but the acid of above-mentioned all quantitative dosings titration trace ore deposit soil and/or metal-salt and/or inorganic salt and/or carboxyl such as citric acid and/or sucrose and/or urea and/or ammonia and/or amine substance and/or discarded proteic substance or composition metal-dislocated polymer solution nutritive medium or form ferments for more meeting the grease combination metal-dislocated polymer solution lacking, reaction times is the light compositing speed of the synthetic carbohydrate of carbonic acid gas, and lichens is exposed in the air in the Nature, so the bioreactor pipeline has half to contain air, in order to the oxygen and carbon dioxide convective exchange, the algae absorbing carbon dioxide also has nitrogenase and chlorophyll, fungi absorbs oxygen, so circulation fluid gives the enough reaction times at this section bioreactor, the circulation fluid flow rate control will cooperate, when the light compositing speed of synthetic carbohydrate is slack-off, flow velocity will slow down, and flow velocity will be put soon when fast.We are behind nutritive medium dissolved air/water and/or the molten a large amount absorbing carbon dioxide of oil phase, before bioreactor, understand acidity with the pH value monitoring, monitor circulation fluid acidity after bioreactor again, what reduce, just know the reaction consumes amount of carbonic acid gas from front and back acidity, and then know the light compositing speed speed of synthetic carbohydrate, can transfer the circulation fluid flow velocity, as mentioned above, can light modulation, transfer wind speed.
Circulating fluid is to receiving tank, receiving tank is set up circulation device and is installed additional and stir masher and blend cracking moss, lichens (contain protein in making and resolve into amine and Amino acid), and circulation fluid is with down fungi and marine alga proliferative cell to blend cracking and be mixed into nutritive medium (substratum) state to stirring breeding fermentation holding tank through stirring masher.Flow back to the molten conversion unit of previous air/water and/or oil phase again, do second leg and duplicate (asexual reproduction) cultivation, so bacterium is dissolved in carbon dioxide absorption, photosynthetic production is duplicated, circulation fluid stirs and grinds the cracking mixing, stir four steps of breeding fermentation holding tank and repeat the continuous hyperplasia that circulates back and forth, but plant has temperature difference stimulating growth like this, circulation fluid is not all will stir lichens to grind the cracking mixing at every turn, but how long see circulation (about three days or more of a specified duration) lichens has duplicated hyperplasia, just need do to stir and grind the action of cracking blended, all to arrive one after grinding cracking and stir breeding fermentation holding tank through stirring, come a large amount of cultivation kind bacterium fast, stir and suitably heat (the high slightly replicate faster of bacterium temperature), this heats can be from air/water and/or the next thermal source of the molten conversion unit heat exchange of oil phase, and suitably add and meet the batching that fermentation system (according to the nutrition-allocated proportion of metal-dislocated polymer solution) is lacked, at this moment add the lichens kind, pH value is about 6.5, make kind of bacterium propagation that last thousands of times be arranged, plant bacterium quick fermentation propagation and at least also take three days, so the storage capability of reaction nutritive medium more than a times is arranged, above-mentioned continuing just arrived previous air/water and/or the molten conversion unit of oil phase, do photosynthetic production again and duplicate (asexual reproduction) cultivation, this non-succeeding transfer culture mode (but also can succeeding transfer culture), generation incubation time and traditional way are suitable, but monobasic propagation kind of bacterium is so that grow up, the many of original thousands of times are but arranged, so output is huge again fast surprising.When circulation fluid thickness more and more thicker, thick in nearly saturation value, outgrowth all having stirred ground cracking (also can not stir grind cracking flow out to do other utilizations), flow out and partly do esterification treatment (this situation need not stir breeding fermentation storage), remaining add sterilized water and/or oil again, add the humic acids metal-dislocated polymer solution (if do not add also can) and be the fermented substrate dilution, enter stir breeding fermentation holding tank begin under bout duplicate.The algae that cultivation contains lichens can purify the algae kind and prevents to pollute because of containing antibiotics, and the green alga of contained immobilization (not flowing) lichens can be cultivated (using the green alga culture systems) safely
Various culture systems in addition, such as make the dietetic alimentation system with metal-dislocated polymer solution and come fermentation culture propagation, the control of assorted bacterium can also can cooperate sterilization factors to prevent assorted bacterium as adding micro-chlorine as above-mentioned method, just can not influence and make proliferating system at fermentation culture propagation metal-dislocated polymer solution, because prevent to pollute and powerful propagation as long as this system copies ability greater than the sterilization ability of sterilization factors, just can reach to purify.
Again, the training method of algae is also similar in appearance to this type systematic separately, adopt lipid acid-M-NH2-Pepsin-sugar and/or sucrose-M-NH2-Pepsin fermentation system, self-operation and/or mixed battalion are all suitable, be newly grown up and be easy to quick breeding, it is vigorous to grow, algae photosynthesis absorbs air (containing nitrogen), organic dust, inorganic dust, carbonic acid gas and water, sucrose, the acid of carboxyl, metal-salt, ammonia and/or amine substance, utilize and the air equipment illumination reaction fermentation that mixes, produce carbohydrate, protein, lipid acid, mineral substance etc., product characteristics are the more acid that does not have carboxyl of protein.Cooperate sucrose after grinding cracking and the acid that adds carboxyl is arranged and the material of amino is arranged when algae stirs, just can do next step fermentation action, strengthen the growth fermentation and make partly protein resolve into amine and Amino acid is rich in amino material (when bioreactor so fermentation adds the acid of a little sugar, some more carboxyls when duplicating kind of bacterium, the acid of sucrose, carboxyl can become algae carbonaceous nutrition source, the quality of deriving).Just begin metal-dislocated polymer solution adding marine alga thalline and bred fermentation culture, put into air film filter plant and the air/water chemical industry equipment that mixes, one side input air, producing vortex with water cycle through the air swirl metal plate on one side mixes, stirring fermentation when raw material mixes, under sunshine, promote propagation to derive with air.Being fit to the humic acids metal-dislocated polymer solution is the fermented substrate fixation support, and it is the easy extinction of black liquor, from this system's fermentation and then hyperplasia propagation.Air (can pass through air disinfection such as ultraviolet ray earlier), the capable photosynthesis of this nutritive medium that do not stop to circulate be by its propagation procreation, and wherein the air equipment of mixing has and mixes.Air mix add in the equipment alkali (containing Ke Xingjia) and/or amine substance such as urea join with nutritive medium in be carbonate behind the reacting metal salt absorbing carbon dioxide, bicarbonate ion and free amine group and salt, being pH value approximately is 6.5 to 11.5 left and right sides solution, algae (as spirulina) is fit to alkaline system, alkaline system is that 8.5 or 10.5 times dissolved carbon dioxides are that various carbonic acid ion can reach 100% or 50% at most separately at pH value again, cooperate air/water (warp and the heat exchange of stirring fermentation holding tank turn cold) to mix, the cold more highly basic that mixes a large amount absorbing carbon dioxide more and have is understood the bioreactor reaction consumes amount of dissolved carbon dioxide with the pH value monitoring, and then how much control air quantity, make the thickness of dissolved carbon dioxide consistent with the reaction consumes amount.Algae only needs medium luminosity during the capable photosynthesis of nutritive medium, and when the reaction consumes amount learnt that growth velocity is slow, the photosynthesis light requirement can include light irradiation apparatus by equipment too much or very little, and, optical fiber light lead luminous as LED lamp, optical fiber waits and regulate subsidy.The capable photosynthesis quality of nutritive medium is to allow its propagation procreation key factor, algae is combined into nutritive medium at substratum each time, when fermentation strain just grows into type, complexed metal dislocated polymer solution and dietetic alimentation system ferment, its speed can be fast, so photosynthesis just utilizes this period of time to quicken to cultivate propagation, propagation can be copied the shower of growing in the Nature at carrier, perhaps closed conduct formula, flat or semi-enclosed or by by way of example or other mode bioreactors, above-mentioned all can be according to the nutritional needs quantitative dosing titration trace metal salts of algae and/or the acid such as the acetic acid of inorganic salt and/or carboxyl, ferment (being fit to plant) metal-dislocated polymer solution nutritive medium or precedingly supply of the promote reaction of algae nutrition after having when adding amine substance of citric acid and/or sucrose and/or urea and/or ammonia and/or amine substance and/or discarded proteic substance or composition metal-dislocated polymer solution nutritive medium or form for more meeting the grease combination metal-dislocated polymer solution lacking, reaction times is the light compositing speed of the synthetic carbohydrate of carbonic acid gas, and algae is exposed in the air in the Nature, so the bioreactor pipeline has half to contain air, release in order to oxygen, the algae absorbing carbon dioxide also has nitrogenase and chlorophyll, so circulation fluid gives the enough reaction times at this section bioreactor, the circulation fluid flow rate control will cooperate, when the light compositing speed of synthetic carbohydrate is slack-off, flow velocity will slow down, and flow velocity will be put soon when fast.We are behind the molten a large amount absorbing carbon dioxide of nutritive medium dissolved air/water, before bioreactor, understand basicity with the pH value monitoring, monitor circulation fluid basicity after bioreactor again, what reduce from front and back basicity, just know the reaction consumes amount of carbonic acid gas, and then know the light compositing speed speed of synthetic carbohydrate, adjustable flow velocity, light modulation, wind speed.
Circulating fluid is to receiving tank, receiving tank is set up circulation device and is installed additional and stir masher and blend cracking algae (contain protein in making and resolve into amine and Amino acid), circulation fluid is with down the marine alga proliferative cell to blend cracking and be mixed into nutritive medium (substratum) state through stirring masher, to stirring breeding fermentation holding tank.Flow back to the previous air/water conversion unit that mixes again, do second leg and duplicate (asexual reproduction) cultivation, so bacterium is dissolved in carbon dioxide absorption, photosynthetic production is duplicated, circulation fluid stirs and grinds the cracking mixing, stir four steps of breeding fermentation holding tank and repeat the continuous hyperplasia that circulates back and forth, but plant has temperature difference stimulating growth like this, circulation fluid is not all will stir algae to grind the cracking mixing at every turn, but how long see circulation (about three days or more of a specified duration) algae has been duplicated hyperplasia, just need do to stir and grind the action of cracking blended, all to arrive one after grinding cracking and stir breeding fermentation holding tank through stirring, come a large amount of cultivation kind bacterium fast, stir and suitably heat (the high slightly replicate faster of bacterium temperature), this heats can be from the air/water thermal source that the conversion unit heat exchange comes that mixes, and suitably add and meet the batching that fermentation system (according to the nutrition-allocated proportion of metal-dislocated polymer solution) is lacked, at this moment add the algae kind, pH value is about 7, make kind of bacterium propagation that the thousands of times of last time be arranged, plant bacterium quick fermentation propagation and at least also take three days, so the storage capability of reaction nutritive medium more than a times is arranged, the above-mentioned previous air/water that continues the just conversion unit that mixes, do photosynthetic production again and duplicate (asexual reproduction) and cultivate, this is non-succeeding transfer culture mode (but also can succeeding transfer culture).When circulation fluid thickness more and more thicker, thick in nearly saturation value, outgrowth all having stirred ground cracking (also can not stir grind cracking flow out to do other utilizations), flow out some and do esterification treatment (this situation need not stir breeding fermentation storage), remaining add sterilized water again, add the humic acids metal-dislocated polymer solution (if do not add also can) and be the fermented substrate dilution, enter and stir the breeding holding tank that ferments and begin second leg and duplicate.In like manner also can use at other photosynthetic plant biologicals of production.
Other purposes can be done after the effusive part sterilization of above-mentioned fungi and/or the algae sterilising treatment and also next step esterification treatment can be done, mixing sucrose also has the acid that adds carboxyl to sneak in the fresh culture, the non-refuelling of refueling all can, supply fungi and/or algae nutrition like this for more meeting the grease combination metal-dislocated polymer solution lacking, the usnic acid metal-dislocated polymer solution if air/water and/or the molten equipment of oil phase all section be incorporated as titanium ore soil, be the titanium metal dislocated polymer solution just, after adding the fermentation of esterification ferment, just titanium (or other, cobalt and/or aluminium or antimony are adopted in the metal ion suggestion of the inside wrong fount) metal esterification ferment (as lipase esterification ferment and/or or sneak into a little wine canals) biological catalyst takes esterification nutritive medium (moss is sterilized), reactant of esterification is an oil, carbonyl compound, lipid acid, the acid of carboxyl, weak polyphenolic acid, carbohydrate is through the alcohols or the general alcohols of wine canalization, esterification process can add negative oxygen ion o-2 in good time, o2-or nascent oxygen are strengthened upgrading, product is the fatty acid ester equal solvent, esterification fermentation equipment used for having stirring and/or aerated fermentation chemical industry equipment stirring reaction after two be separated (solvent phase with non-solvent mutually).Titanium metal esterification ferment biological catalyzer own takes the nutritive medium of esterification own, do not need solid immobilization catalyst, because of being the reaction of fermentation and catalyst medium, do not need ultra high temp, sneak into a little wine canals in the esterification, be to make carbohydrate transfer alcohols to, transfer the fatty acid ester equal solvent in order to lipid acid and alcohols, with settling agent such as iron(ic) chloride, lipid acid-M-NH2-Pepsin-sugared structural collapse, make two-phase last itself can the branch, and fatty acid ester equal solvent one floats mutually, water and albumen precipitation thing one not necessarily need fractionation mutually.
Or adopt falling-film distillation to send out device and send out the device series connection, low-boiling point materials such as the sherwood oil that utilizes falling-film distillation to send out device to separate thick product, methyl alcohol, water together with wiped-film.Utilizing wiped-film to send out device, to come the separation of fatty acids methyl esters be biofuel.Methyl esters content was greater than 96% in the product after this method was separated, and the rate of recovery is greater than 85%.Separate the every index of back product and can meet German production of biodiesel standard.But faster and better, surprise and happy at the same time, simple just energy recovery.
In like manner, the esterification of pure fatty acid, reinforced make meet lipid acid-M-NH2-Pepsin-sugared structure (metal-dislocated polymer solution), for metal esterification ferment (as lipase esterification ferment and/or or sneak into a little wine canals) biological catalyst comes esterification emulsification fluid, adding water as lipid acid adds titanium sulfate with vinegar with sucrose and adds ammoniacal liquor and mix, lipase esterification ferment and sneak into the fermentation of a little wine canals after, sneak into stirring/less aerated reaction in the lipid acid when catalyst, fatty acid ester both generated.
On the other hand, lipid acid-M-NH2-Pepsin-sugared structure is in the surplus processing of offal treatment such as kitchen, the leftovers leftovers are spread its nutrition out, do not meet the nutrition of above-mentioned lipid acid-M-NH2-Pepsin-sugared structure, can add batching and make the nutrition that meets above-mentioned lipid acid-M-NH2-Pepsin-sugared structure, as the oil-mineral substance-protein-surplus bacterium in decomposition kitchen or ferment-carbohydrate, further enlarge spoken parts in an opera a bit, be exactly animal-plant oil--leaf vegetables, nuts mineral substance--flesh of fish class, egg, shrimp, marine products proteinoid--the decomposition surplus bacterium in kitchen or ferment such as EM bacterium--rice and flour, potato, the carbohydrate of ground melon starch cooperates the acidic substance ocean Cong of carboxyl again, lemon, the acid of plum etc. or carboxyl, do the surplus processing in kitchen, see that class material of above-mentioned shortage, can with similar chemical feedstocks in proportion the deficient patients proportioning add, add when mixing and decompose surplus bacterium in kitchen or ferment, just be easy to fermentation.General fermentation will be heated and be promoted reaction, but mix with the proportioning additive process, Ammonia is not also run out and can be added a small amount of Ammonia when above-mentioned solution fermentation initiator, in like manner other class compositions too, as long as ratio is formed according to composition classification difference and to stir order progressive, the quick fermentation reaction just can be arranged, reach the surplus fast processing in waste kitchen, close material or contain the similar substance of composition in this structure beyond lipid acid-M-NH2-Pepsin-sugared structure that Here it is, the success of can fermenting, water for example, Ku Wei broken weeds (carboxylic acid in after soaked several days) do not mix leftovers (starch carbohydrate), sucrose (direct fermentation promotor), add oil meal class (oil is not essential) again, gypsum (mineral substance), bean dregs (acid of protein amino-contained), order is progressive mixes (if solids just grinds to form powdery) for urine (NH2 and ferment), just fermentation has got up to become fertilizer, this only should want combinations of substances to become the metalloid dislocated polymer solution to add suitable bacterium in organic agricultural naturally method, ferment, be fermented into plant and easily absorb dissociant, but being again metal-dislocated polymer solution, this dissociant assembled state can promote plant materials endo enzyme system (plant has antibody in the species diversity Shen), fast-developing so that growth is vigorous, so can work as fertilizer.In addition with No. 094103202 application case of inventor's TaiWan, China patent, title: metal-dislocated polymer solution sucrose-M-NH2-Pepsin system and/or other fermentation systems, can handle or handle organic waste with other kind of bacterium according to aforesaid method, make to solidify or liquefy to be other kind of purposes material, this formal a kind of metal-dislocated polymer solution is being handled organic waste and is being become Application in Fertilizer.The liquid manure waste deodorizing of dwelling house manure pit, building is handled in addition, every day, fecaluria was come in always, fecaluria contains organic hydrocarbon (excrement) and Ammonia (urine), can copy processing by metal dislocated polymer solution sucrose-M-NH2-Pepsin system and/or other fermentation systems, at first add bacterium and material such as milk-acid bacteria and material replacement carboxylic acid thereof that produces carboxylic acid and/or the bacterium that produces carbohydrate and material replacement carbohydrate thereof to decompose organic hydrocarbon (excrement), Ammonia (urine) is come in every day always, the metal ion urine has just had, so just become a fermentation system easily, add bacterium such as the methanobacteria of wanting de-odorised bacterium or other functions again, the bacterium of principal reaction is greater than other assorted bacterium in the system, deodorizing bacterium (methanobacteria) fermentation propagation function just can constantly be brought into play, metal-dislocated polymer solution principle by fermentation is allocated as composite bacteria like this, the application of deodorizing that but deodorizing or aerogenesis body also are a kind of metal-dislocated polymer solutions in handling organic waste or aerogenesis.
With No. 094103202 application case of inventor's TaiWan, China patent, title: metal-dislocated polymer solution sucrose-M-NH2-Pepsin system and/or other fermentation systems, also can handle feed according to aforesaid method, not necessarily need fermentation, as long as by trophic component, can do by myself in the body and transform each material and decomposing protein is amino fermentation voluntarily, this formal a kind of metal-dislocated polymer solution application in feed.
Lipid acid-M-NH2-Pepsin-sugar-fermenting system is also creative in the making of food such as bean curd with odor on the other hand, fatty acids, protein in the soybean, add some points water, lactic acid and sucrose, gypsum, add some human body internal protein hydrolytic enzymes and a large amount of main fermentation ferment (to the human body beneficial) at last, when protein decompose become amino and the ferment that mainly ferments from Primary Fermentation.In addition also can sneak into gravy and replace NH2 and promote fermentation, also can sneak into oil and ferment and differ from traditional zymotic and well infiltrate with oil again in soya-bean milk and aforementioned substances at soya-bean milk.The and for example fermentation of bread, flour Jia Shui, oil, sugar, lactic acid, micro-gypsum, mushroom juice or gravy or protein (containing some human body internal protein hydrolytic enzymes) mix, add main fermentation ferment (to the human body beneficial) again and just can ferment, this fermentation mode differs from traditional bread fermentation mode.Again with no-salt soy sauce, general soy sauce is that vexed slowly fermentation under the salt state is being arranged, need repeatedly complicated formality, but no-salt soy sauce can soybean in fatty acids, protein add milk-acid bacteria (replacing the acid of carboxyl) with sucrose and add edible wild herbs juice (mineral substance) or micro-gypsum, fermentation earlier produces some lactic acid in above-mentioned soy formulations, adding from the comprehensive enzyme that has the salt soy sauce to cultivate out again and ferment energetically, and have the same taste of salt soy sauce just to come out, but is no-salt soy sauce.So lipid acid-M-NH2-Pepsin-sugar or lipid acid-this system of M-protein-Pepsin-sugar can be used for the application in the food fermentation.
Lipid acid-M-NH2-Pepsin-sugar and/or sucrose-M-NH2-Pepsin system and/or other fermentation system structures application in producing organic gas on the other hand again, for example handle waste as stated above and add hydrolytic bacteria, hydrogen-producing acetogenic bacteria, methanobacteria etc., hydrolytic bacteria can resolve into polypeptide and Amino acid to protein, steatolysis becomes glycerine and chain fatty acids, polysaccharide resolves into monose and disaccharide, further produce hydrogen and produce acetate, behind the fermenting-ripening, bacterium can continue attack earlier toward chemical substance beyond lipid acid-M-NH2-Pepsin-sugar or the sucrose-M-NH2-Pepsin structure, anaerobically fermenting continues to carry out, methane just constantly produces, utilize this method, just can produce methane gas.From the above, bacterium culture medium and nutrition (ratio as stated above, but-NH2 builds bridge and partly changes into-mutual transformation substance of NH2 such as protein, form and stir according to composition classification difference) combine and add a little water, just begin by the bacterium specific function, do the decomposing and fermenting action, produce methane gas, till exhausting, when nutrition is lipid acid-M-protein-(Pepsin does not also add)-sugar or sucrose-M-protein-(Pepsin does not also add) structure, protein replaces NH2, when be-several making do not add Pepsin and is easy in the absorbing environmental free bacterium yet and ferments during NH2, so adding protein replaces, Pepsin does not yet add, and just can at will not ferment easily, comes in case bacterium culture medium contains methane fungus strain hydrolytic bacteria over there, protein resolves into amine and Amino acid, have-NH2 just accompany methanobacteria and ferment.So we can design a kind of product, be portable type gas holder (powder), divide and make two bags, one bag is a bacterium culture medium if adopt the Vltra tears system of having fermented, one bag comes the nutrition that ratio forms (adopt stability height do than the without putrefaction material the freezing universe is dry to come sterile vacuum to pack) to be sayed trophic component as above-mentioned for stirring according to composition classification difference, in the time will producing coal gas, two bag mixing add a little sterilized waters and place the coal gas culture tank, this culture tank is salable to be opened, (pipeline is short more good more to have ventilating pit to connect gas line, because of culture tank does not have too big pressure) guiding, cause to gas range, igniting is ignited till exhausting, and has only decomposed defective materials such as remaining mineral substance.If nutrition one bag design flammable ten minutes, need 20 minutes if boil thing, adding two bag nutrition with regard to an available bag bacterium culture medium adds a little sterilized waters and is mixed in the coal gas culture tank, nickel or molybdenum are adopted in the metal ion suggestion of substratum and nutrition the inside wrong fount, because of catalysis is arranged, can promote methane to produce fast, but these function modes also design automation machine become coal gas generation machine or gasworks or give birth to mass-energy gas power plant, coal gas produces machine can install a leakage explosion-proof equipment, do not use up the bacterium alive gas reforming Carbon emission fast that methane gas can be in liver moss, this Biomass Energy Utilization, produce other organic gass and also can copy processing, the application of this formal a kind of metal-dislocated polymer solution in producing organic gas (methane-containing gas).
Making R-metal ion-protein-protein fungus in fermentation into each fermentation system the inside R-metal ion-NH2-Pepsin of biochemical reaction in addition is hydrolytic bacteria, because hydrolytic bacteria resolves into amine and Amino acid to protein, have-after NH2 replaced protein, the sterilization sterilization was eliminated the required again again purposes of hydrolytic bacteria and is added other Pepsin and/or bacterium and/or cell fermentation.
Another way other fermentation system or Vltra tears fermentation system the inside R-metal ion-NH2-Pepsin to make R-metal ion-protein-protein fungus into be hydrolytic bacteria, become the interlock state to draw mutually, because hydrolytic bacteria resolves into amine and Amino acid to protein, have-NH2 then protein fungus fermentation enter in the metal-dislocated system, become organo-metallic, forward magnetism and reverse (negative sense) magnetism are constantly moved mutually and are drawn in the solution, and make the metal ion microminiaturization, also and then become nano-scale.Stir combination with each single original mixture and plastic polymer (or carboxylic resin such as AmberliteIRC-50) or monomer whose before the not fermentation of nano metal dislocated polymer solution (lipid acid-this system of M-protein-Pepsin-sugar), again with (the inner protein hydrolytic enzyme is protein decomposition becoming amino) and above-mentioned feasible dispersing method (fermentation is interference-free) or ferment also polyaddition reaction or condensation polymerization reaction or the crosslinking curing (under the interference-free situation that refers to ferment) of fermenting, and the mixing moulding that makes of heating evaporation. and for example metal-dislocated polymer solution (lipid acid-this system of M-protein-Pepsin-sugar) fermentation (in add proteolysis ferment protein is decomposed become amino) back metal reaches nanometer, directly sneak into the metal-dislocated polymer solution that fermented in the ceramic process, in sintering process, obtain nanocomposite ceramic material.Become amino above-mentioned all protein the decomposition, so the fermentation nanometer is no problem, be added into after the fermentation and mould rubber, fiber or pottery are all no problem, and formal a kind of metal-dislocated polymer solution is in oxidative condensation and condensation reaction, the fermentation biochemical reaction, metal ferment biological catalyzer, bacterium culture medium and saved system, the food health care, chemical substance production in the plant, oil prod is handled and is used, nanofiltration, nano material is made in fermentation, make liquid crystal and semi-conductor, nanometer is moulded rubber and fiber, The application of new technique is extended in nano-inorganic substance and stupalith manufacturing.(in like manner, the above-mentioned protein of saying all can make the reversible several times mutually transformation substance of NH2 into, such as protein decomposition becoming amino, amino form Amino acid so that protein, or carbohydrate or carboxylic acid or lipid acid mat have grinding and/or dissolving and/or cracking and/or ferment conversion or milk-acid bacteria and material thereof and replace carboxylic acid or other bacterium and thing thereof to replace the method for above-mentioned thing to can be applicable to various embodiments of the present invention and No. 094103202 each embodiment of application case of TaiWan, China patent).
By technique scheme, the present invention compares with conventional art, and following advantage is arranged:
1, that carbon dioxide is dissolved in liquid reactions speed is fast for biodiesel solution processing procedure of the present invention, must not add carbonic acid, and imitative the Nature normality just can make lichens and/or algal grown breed, and must not expend a large amount of financial resource and material resource, and is economical and practical.
2, diesel oil matter solution of the present invention is safe, and production process must Pintsch process, the worry of no industrial safety.Created the new photosynthetic reactor and the new technology of culture systems, do not occupied cultivated land, on a large scale the advantage of automatization control cultivation.
3, the present invention innovates lichensization and/or algae and/or esterification mode and produces diesel fuel applications, has solved the problem that processing carbonic acid gas, gas holder (powder) long preservative period are not fragile, produce the easy to use and fermented manure of methane.
4, the present invention innovate metal-dislocated polymer liquid handle waste and become fertilizer, feed and food fermentation and generation organic gas (containing methane) in application.
5, the present invention innovates fermentation and makes nano material, nanometer with biochemical reaction, fermentation and mould rubber and fiber, nano-inorganic substance stupalith manufacturing extension new technology.
Above-mentioned is the general introduction of technical solution of the present invention, can be implemented according to description, below with preferred embodiment of the present invention and conjunction with figs. describe in detail as after
Description of drawings
The synoptic diagram of Fig. 1 air/water and/or the molten equipment of oil phase.
Fig. 2 bioreactor pipe circles round into the side-view of the channeltype of circle pillar from top to down.
The synoptic diagram of the straight bend pipe of Fig. 3 bioreactor manifold.
The synoptic diagram of the straight bent plate face of Fig. 4 bioreactor formula.
Fig. 5 receiving tank, stir the synoptic diagram of masher (tool pumping function), decomposing machine, stirring breeding fermentation holding tank, heat exchange heating tube row (or warming apparatus), circulation line (containing radiating pipe) etc.
Fig. 6 stirs and/or aeration esterification fermentation chemical industry equipment.
Seeing also shown in Figure 7ly, is the percentage ratio of carbonate, bicarbonate ion and carbonic acid gas in the different PH aqueous solution.
The 1 pipe 2 fixed support bars that circle round
3 fixing support racks, 4 light irradiation apparatus
5 windmill 6PH value meters
7 nutritive mediums, 8 photosynthesis
9 air disinfections and/or membrane filter plant 10 air/water and/or the molten equipment of oil phase
11 inlet mouths, 12 air outlets
13 whirlpool water and/or oil wash groove 14 mist eliminators
131 whirlpool water and/or oil wash groove water conservancy diversion metal plate
15 prolongs row forms vortex plate 16 heat exchange condensers
The 17 cold insulation devices 18 conversion unit pump that mixes
19 bioreactors (being many W type shape)
The main pipe of 20 bioreactors
The straight tube of 21 optical-biological reaction utensil manifolds
The bend pipe of 22 optical-biological reaction utensil manifolds
The straight plate face of 23 bioreactors
The bent plate face of 24 bioreactors
25 quantitative dosing titration apparatuss, 26 circulation fluids
27 receiving tanks, 28 receiving tanks are set up circulation device
29 stir masher (tool pumping function)
30 decomposing machines 40 stir breeding fermentation holding tank
41 stir breeding fermentation holding tank sets up circulation device
42 heat exchange heating tubes rows (or warming apparatus)
The 43 attemperators 44 conversion unit circulation line that mixes
45 receiving tank circulation lines
46 stir breeding fermentation holding tank circulation line (containing radiating pipe)
47 electric switching valves (control valve), 48 sterilization sterilising treatment machines
49 stir esterification treatment reacts the fermentation of 50 esterification ferment
51 negative oxygen ion o-2, o2-or nascent oxygen produce machine (containing pneumatic pump)
52 stir and/or the aerated fermentation chemical industry equipment
53 aerators 54 drop into influx
Embodiment
The inventor designs the machine of a cover by above-mentioned principle, windmill 5 absorbs natural air from inlet mouth 11 process air disinfection and/or membrane filter plant 9 as ultraviolet ray earlier, this nutritive medium 7 row photosynthesis 8 that do not stop to circulate allow its propagation procreation, life and growth in nature, wherein the air equipment 10 that mixes has and mixes, nutritive medium 7 cooperates air/water and/or the molten equipment 10 of oil phase (heat exchange condenser 16 turns cold between warp and the stirring breeding fermentation holding tank 40) to mix from quantitative dosing titration apparatus 25 acid adjustment alkali, the cold more soda acid that mixes a large amount absorbing carbon dioxide more and have, the guiding of the equipment mat vortex type that mixes retaining metal plate, cause gas to produce eddy current, and the gas washing is concentrated on water whirlpool portion, and can guide regularly, cause water flow to produce the whirlpool effect, utilize the whirlwind temperature and pressure to promote cold and hot air inerchange principle to form vortex plate 15 in most prolong rows, also there is cold insulation device 17 outside, this stage and prolong row forms that vortex plate 15 carries out heat exchange so that coldly more mix more, carry out the whirlpool reaction that mixes toward next stage and whirlpool gas/water and/or oil wash groove 13 again, this is because of big the circling round and another ripple gas-liquid effect that mixes takes place of air zig zag and 131 generations of water conservancy diversion metal plate, the pump 18 of this conversion unit that mixes can be repeated to air/water and/or molten equipment 10 of oil phase and watering (or being disposed to bioreactor 19) through the conversion unit circulation line 44 that mixes, satisfy saturated until dissolved carbon dioxide, just stop or nutritive medium 7 is disposed to bioreactor 19, air is discharged atmosphere by air outlet 12 behind mist eliminator 14 above whirlpool gas/water and/or oil wash groove 13 in addition, with No. 094125197 application case of inventor's TaiWan, China patent, title: the air/water equipment that mixes that the retaining metal plate is combined in the application of revolving (whirlpool) eddy current progresses greatly and attracts use as shown in Figure 1.Capable photosynthesis 8 quality of nutritive medium are to allow its propagation procreation key factor, and branch is arranged: pipe circles round into bioreactors 19 such as the channeltype of circle pillar, the straight bend pipe of manifold, straight bent plate face formula from top to down.Pipe circles round into the channeltype of circle pillar from top to down:
With made printing opacity pipeline pipes of light-transmissive resin such as plastics or transparent adhesive tape materials, the pipe 1 that circles round from top to down forms a circle circle circle and repeats to pile up, the circumference of circle can three or four sides fixing support rack 3 be connected on the ground, can three fixed support bars 2 insertions make the generation gap and strengthen fixing between last circle and the following circle, form a circle pillar, can contain light irradiation apparatus 4 in the circle post,, optical fiber light lead luminous as LED lamp, optical fiber waits and regulates subsidy.This light pipe road is provided with one and helps the opening position to its uppermost component, injects this nutrient solution, regulates the pressure in this printing opacity pipeline or cleans this printing opacity pipeline with quantitative dosing titration apparatus 25.As shown in Figure 2.In like manner also can use at other photosynthetic plant biologicals of production.
The straight bend pipe of manifold:
The photosynthetic response pipeline, the made printing opacity pipelines of light-transmissive resin such as one glass or acryl are used for nutrient solution to flow in it.This photosynthetic response pipeline comprises that a main pipe 20 is communicated with many (a plurality of) straight tubes 21 and Duo Zhi (plural number) bend pipe 22, become similar " order " word shape rectangle or square, these straight tubes and these bend pipes are connected in series at interval and form " traverse W " shape 19 that several rows of both forward and reverse directions in succession tilts, three-dimensional manifold printing opacity pipeline, make nutrient solution of flowing in it circulation and down and absorb light fully and carry out photosynthesis, the interior light irradiation apparatus 4 that contains in proper order.This light pipe road is provided with one and helps the opening position to its uppermost component, injects this nutrient solution, regulates the pressure in this printing opacity pipeline or cleans this printing opacity pipeline with quantitative dosing titration apparatus 25, as shown in Figure 3.
Straight bent plate face formula (the same produce other photosynthetic plant biologicals also can use):
This photosynthetic response pipeline comprises that a main is communicated with straight plate face 23 and bent plate face 24, become a similar rectangle or square plate face, in the plate face hollow, these straight plate faces and bent plate face are connected in series at interval and form " traverse W " shape 19 that several rows of both forward and reverse directions in succession tilts, three-dimensional many plates face printing opacity pipeline, make nutrient solution of flowing in it circulation and down and absorb light fully and carry out photosynthesis, the interior light irradiation apparatus 4 that contains in proper order.This light pipe road is provided with one and helps the opening position to its uppermost component, injects this nutrient solution, regulates the pressure in this printing opacity pipeline or cleans this printing opacity pipeline with quantitative dosing titration apparatus 25, as shown in Figure 4.
It is funnel-forms that the photosynthetic response pipeline flow to receiving tank 27, in order to collecting fungi and/or frond or removing heavier settling, can design from side inflow 54 generations and circle round, when need discharging oxygen, algae disengages (discharging oxygen less from flowing directly into 54 when cultivating lichens) easily, so air is discharged from this upside venting port, but this pressure regulation opening exhaust is to keep the pressure in this liquid level regulation apparatus, it is that general circulation connects whirlpool water and/or the oil wash groove 13 that receiving tank circulation line 45 can arrive air/water and/or the molten equipment 10 of oil phase that last supernatant liquid receiving tank is set up circulation device 28, stir masher (tool pumping function) 29 and be located at receiving tank 27 belows, do not stir when grinding, there is control valve 47 directly to discharge, stir masher (tool pumping function) 29 and discharge connection decomposing machine 30, cracking is intact to stirring breeding fermentation holding tank 40, in (or warming apparatus) 42 from the heat exchange heating tube of condenser 16 row arranged, there is attemperator 43 to make stirring breeding fermentation holding tank 40 keep comparatively high temps outward, when fermenting-ripening or next circulation cultivate beginning, starting stirring fermentation holding tank sets up circulation device 41 and adjusts electric switching valve 47, allow stir fermentation holding tank circulation line (containing radiating pipe) 46 nutritive medium 7 is delivered to the whirlpool water and/or the oil wash groove 13 of air/water and/or the molten equipment 10 of oil phase, as shown in Figure 5.
We behind nutritive medium 7 dissolved airs/water and/or the molten equipment 10 a large amount absorbing carbon dioxides of oil phase shown in the 7th figure, without the position before the bioreactor 19, understand potential of hydrogen with 6 monitorings of pH value meter, monitor circulation fluid 26 potential of hydrogen after bioreactor 19 again, what reduce from the front and back acidity or alkalinity, just know the reaction consumes amount of carbonic acid gas, and then know the light compositing speed speed of synthetic carbohydrate, can transfer circulation fluid 26 flow velocitys, nutritive medium 7 row photosynthesis 8 as mentioned above, understand the bioreactor 19 reaction consumes amount of dissolved carbon dioxide with 6 monitorings of pH value meter, and then how much control air quantity (windmill rotating speed), make the thickness of dissolved carbon dioxide consistent with the reaction consumes amount, 8 medium luminosity of need of photosynthesis, when the reaction consumes amount learnt that growth velocity is slow, light requirement can include light irradiation apparatus by bioreactor 19 too much or very little, as the LED lamp, optical fiber is luminous, the optical fiber light lead waits regulates subsidy, so adjustable wind speed, light modulation.
To sum up state all, in like manner also can use at other photosynthetic plant biologicals of production.
Nutritive medium 7 below bioreactor 19 receiving tank 27 effusive parts behind sterilization sterilising treatment machine 48, can do other purposes and also can do next step stirring esterification treatment reaction 49, the reaction container groove is airtight but can opens, middle frame person stirrer, nutritious liquid 7 input ports, the 54 double exhausts in next door, mixing sucrose also has the acid that adds carboxyl to sneak in the fresh culture, supplying fungi and/or algae nutrition like this is more to meet metal-dislocated polymer solution to be lacked, after the titanium metal dislocated polymer solution adds esterification ferment fermentation 50, just titanium (or other, cobalt and/or aluminium or antimony are adopted in the metal ion suggestion of the inside wrong fount) metal esterification ferment (as lipase esterification ferment and/or sneak into a little wine canals) biological catalyst takes esterification nutritive medium 7, esterification process can add negative oxygen ion o-2 in good time, o2-or nascent oxygen 51 are strengthened upgrading, product is the fatty acid ester equal solvent, esterification fermentation equipment used for having stirring and/or aerated fermentation chemical industry equipment 52 stirring reactions after two be separated (solvent phase with non-solvent mutually).With settling agent such as iron(ic) chloride, lipid acid-M-NH2-Pepsin-sugared structural collapse, make two-phase last itself can the branch, side extracts but fatty acid ester equal solvent one floats mutually, and water flows out with albumen precipitation thing one is following mutually, not necessarily needs fractionation, as shown in Figure 6.
The embodiment that the present invention proposes: oil product (fatty acids) and/or leftovers (starch), sucrose, cellulosic powder 1～4%, insert in the mixing solutions that contains 1～4% weeds (oxalic acid) or other acid (comprise and have-the organic and/or inorganicss such as acid of COOH carboxyl) and 97～88% water, in the time of 20 ℃, make thick thick slurries. with these slurries and 1～4% gypsum, the bone powder, acidifying or chlorination or hydroxide or inorganic polymer monovalence, two valencys or trivalent metal ion and the fermentation of algae protein powder and/or grinding and/or dissolving and/or crack protein matter become amine and Amino acid, filling part mixes, mixing speed changes at per minute 200, just becomes fermentation reaction solution and other purposes reaction solutions.Embodiment as following each reaction solution:
Embodiment 1 lichens is cultivated (in like manner also available at other photosynthetic plant biologicals of production)
Pick up from air suction nutrient mode and cultivate lichens, system forms the about 150 milliliters substratum of metal-dislocated polymer solution with humic acids and calcium chloride and ammoniacal liquor and packs in 500 milliliters the vibration bottle, add an amount of 3-4-5 milliliter lichens in substratum, 25 ℃ of shaking culture at room temperature, irradiation was penetrated two days continuously, the kind quick fermentation of lichens is duplicated, become ten million lichens kind cell, the acid such as the citric acid of elder generation's titration carboxyl make easy absorbing carbon dioxide, powerful then the stirring pours into carbon dioxide for acid, with intensity of illumination irradiation 4800 diligent grams this and rotating speed is that per minute 120 revolutions stir photosynthetic cultivation, and then titration is to meet grease combination (nutrient except that acid that before added carboxyl such as citric acid) that metal-dislocated polymer solution lacked, as sucrose, ammonia or amine, metal-salt, oil, dosage is approximately as acid, use 680 millimicrons of lichens optics degree values of measuring growth of spectrophotometer wavelength, with geodetic clothing somatocyte degree, every 24 hours geodetic clothing optical density (OD) values, record cell density, when lichens bulk-growth to cell is grown the back logarithmic phase, can carry out next time and cultivate.
Earlier go into new humic acids metal-dislocated polymer solution substratum with another vibration is bottled, then drawing part lichens cell gives grinding and/or dissolving and/or crack protein matter and becomes amine and Amino acid, other compositions also transform, mix a little sugar and have the acid that adds carboxyl to sneak in the fresh culture, supplying lichens nutrition like this is more to meet metal-dislocated polymer solution to be lacked, with 100 times of dilution fermentations, cultivate with same culture condition, add nutritive medium then, promote reaction for titration citric acid and/or sucrose and/or inorganic salt and/or metal-salt and/or urea and/or ammonia and/or amine substance and/or discarded proteic substance or according to claim 1 described composition metal-dislocated polymer solution nutritive medium or according to claim 1 described composition (being fit to plant such as EM bacterium) the metal-dislocated polymer solution nutritive medium that ferments, after mixing just three days, the thallus cell regrows to logarithmic phase, and so repetitiousness carries out cultivation next time.
Embodiment 2 algae culture (in like manner also available) at other photosynthetic plant biologicals of production
Pick up from battalion and/or mixed battalion mode and cultivate algae (as spirulina), system forms the about 150 milliliters substratum of metal-dislocated polymer solution with humic acids and calcium chloride and ammoniacal liquor and packs in 500 milliliters the vibration bottle, add an amount of 3～4-5 milliliter frond in substratum, 25 ℃ of shaking culture at room temperature, irradiation was penetrated two days continuously, the kind quick fermentation of algae is duplicated, become ten million algae kind cell, titration potassium hydroxide and/or amine substance such as urea and powerful the stirring pour into carbon dioxide and become carbonate then, bicarbonate ion and Repone K and free amine group are alkalescence, with intensity of illumination irradiation 4800 diligent grams this and rotating speed is that per minute 120 revolutions stir photosynthetic cultivation, and then titration is to meet grease combination (nutrient except that before adding amine substance such as urea) that metal-dislocated polymer solution lacked, sucrose, acetic acid, metal-salt dosage is askd to join one amine, add phosphate fertilizer in good time, small amount of potassium, use 680 millimicrons of algae optics degree values of measuring growth of spectrophotometer wavelength, to survey frond cell degree.Surveyed algae optical density (OD) value every 24 hours, record the frond cell density, when frond grows to cell growth back logarithmic phase, can carry out next time and cultivate.
Go into new humic acids metal-dislocated polymer solution substratum with another vibration is bottled, then drawing the part alga cells gives grinding and/or dissolving and/or crack protein matter and becomes amine and Amino acid, other compositions also transform, mixing sucrose also has the acid that adds carboxyl to sneak in the fresh culture, supplying algae nutrition like this is to meet metal-dislocated polymer solution to lack, with 100 times of dilution fermentations, cultivate with same culture condition, add nutritive medium then, be the titration citric acid, acetic acid and/or sucrose and/or inorganic salt and/or metal-salt and/or urea and/or ammonia and/or amine substance and/or discarded proteic substance or promote reaction according to aforesaid composition metal-dislocated polymer solution nutritive medium or the aforesaid composition metal-dislocated polymer solution nutritive medium that fermented, after mixing just three days, the frond cell regrows to logarithmic phase, and so repetitiousness is cultivated
Embodiment 3
Oil product and/or material esterification fermentation that the present invention contains fungi and/or algae are the embodiment of diesel oil method, fungi and/or alga cells body stirred grind cracking, sneak into and close sucrose and the acid that adds carboxyl is arranged, the non-refuelling of refueling all can, supplying fungi and/or algae nutrition like this is more to meet combined oil-metal polymer solution to be lacked, contain each composition quality about 2% such as 1 liter of lichens, add 1% sucrose again and adding citric acid 1% is arranged, become the titanium metal dislocated polymer solution, after adding esterification ferment (as lipase esterification ferment 0.1% and sneak into a little wine canals 0.01%) fermentation, be that titanium metal esterification ferment biological catalyzer takes the esterification nutritive medium, the esterification fermentation is through stirring a week and adding a little negative oxygen ion o-2, o2-or nascent oxygen are strengthened the upgrading aerated fermentation, stirring reaction is after two be separated, and utilizing the wiped-film device to be separated into fatty acid methyl ester is biofuel.
Embodiment 4
The esterification of pure fatty acid of the present invention fermentation for the example of diesel oil method pure fatty acid reinforced make meet lipid acid-M-NH2-Pepsin-sugared structure (metal-dislocated polymer solution), be mixed into emulsification fluid, its mass percent consists of:
Sterilized water 30%
Vinegar (carboxylic acid) 10%
Lipid acid (or technical oils is crossed in cracking) 20%
Titanium sulfate 10%
Ammoniacal liquor 10%
Sucrose 20%
Lipase esterification ferment and sneak into a little wine canal trace
Lipid acid adds water and adds titanium sulfate with vinegar with sucrose and add ammoniacal liquor and mix, lipase esterification ferment and sneak into a little wine canals fermentations after, sneak into stirring/less aerated reaction in the lipid acid when catalyst, fatty acid ester both generated.
Embodiment 5
A kind of metal-dislocated polymer solution becomes in processing organic waste and the quality group that becomes Application in Fertilizer:
Oil meal (can have more nutritious also can not have) 2%
Weeds (oxalic acid) 2%
(or wood dust and milk-acid bacteria Mixed Lactobacilli and yeasts thereof)
Leftovers (starch), sucrose 3%
Water 90%
Gypsum, bone powder 2%
Urine (NH2 initiator), surplus meat (the reversible several times mutually transformation substance of NH2) 2%
Other leftovers (mineral substance) 1%
Fermentation ferment (useful) to human body environment, plant
Ferment after a week, become the complete metal dislocated polymer solution and ferment that more shape is quick, last compost becomes fertilizer, and this mode does not need thermophilic fermentation just to reach fast.
Embodiment 6
The application quality of a kind of metal-dislocated polymer solution in feed consists of:
Grease 1%
Herbage (lucky oxalic acid) 2%
W-Gum end 3%
Water 90%
Edible wild herbs (mineral substance) 2%
Algae protein powder 2% (the reversible several times mutually transformation substance of NH2)
Make the ferment that ferments voluntarily in the body
Embodiment 7
The application (quality composition) of a kind of metal-dislocated polymer solution in food fermentation
Soya-bean milk 2%
Lactic acid (can ferment by milk-acid bacteria in advance and replace) 1%
Sucrose powder 3%
Water 90%
Gypsum 1%
Less ammonia is when initiator, gravy (the reversible several times mutually transformation substance of NH2) 2%
Main fermentation ferment (to the human body beneficial) 1%
Embodiment 8
The quality group of the applied nutrition of a kind of metal-dislocated polymer solution in producing organic gas (methane-containing gas) becomes:
South East Asia tart fruit powder 2%
Sucrose powder 3%
Water 90%
Single nickel salt 1%
Algae protein powder 2% (the reversible several times mutually transformation substance of NH2)
Grease 2%
The dry sterile vacuum packing of the freezing universe of above-mentioned prescription
The quality group of bacterium culture medium becomes:
Sterilized water 94%
Vinegar or carboxylic sour 2%
Vltra tears 2%
Single nickel salt 2%
Ammoniacal liquor 2%
Trace such as hydrolytic bacteria, hydrogen-producing acetogenic bacteria, methanobacteria.Adding a bag nutrition with a bag bacterium culture medium adds a little sterilized waters and is mixed in the coal gas culture tank, nickel is adopted in the suggestion of the metal ion of wrong fount in substratum and the nutrition, because of catalysis is arranged, two bags are harmonious and can promote methane to result from the coal gas culture tank fast so that be communicated with gas range.
Embodiment 9
The application quality of a kind of metal-dislocated polymer solution in the new technology of moulding rubber, nanofiber, nano ceramic material manufacturing extension with biochemical reaction, nanofiltration, nano-inorganic substance, fermentation manufacturing nano material, manufacturing liquid crystal and semi-conductor, nanometer of fermenting formed:
It is hydrolytic bacteria that R-metal ion-NH2-Pepsin makes R-metal ion-protein-protein fungus into
Sterilized water 86%
Vinegar or contain carboxylic acid 2% (in addition milk-acid bacteria and material thereof such as sugar replace carboxylic acid also can)
Vltra tears 2%
Titanium sulfate 10%
Ammoniacal liquor makes protein 2% (the reversible several times mutually transformation substance of NH2) into
Hydrolysis bacterium trace
The hydrolysis bacterium is protein decomposition becoming amino, and the above-mentioned nano metal dislocated polymer solution that fermented is molten to shorten gel state into, pours into 600 ℃ of following sintering of titanium oxide biscuit
In like manner, other oxidative condensations and condensation reaction, the fermentation biochemical reaction, metal ferment biological catalyzer, bacterium culture medium and saved system, the food health care, chemical substance production in the plant, oil prod is handled and is used, nanofiltration, nano-inorganic substance, nano material is made in fermentation, make liquid crystal and semi-conductor, nanometer is moulded rubber, nanofiber is copied the said hydrolyzed ferment that protein is decomposed to become amino (or carbohydrate or carboxylic acid or lipid acid mat have grinding and/or dissolving and/or cracking and/or ferment use according to above-mentioned method like this) or milk-acid bacteria and material thereof and replace carboxylic acid or other bacterium and thing thereof to replace the method for above-mentioned thing also can reach fermentation purposes, from last method, can be used for No. 094103202 each embodiment of application case of each preferred embodiment and TaiWan, China patent, content and method is not in order to limit claim of the present invention, all in not breaking away from the technical solution of the present invention scope, utilize the technology contents of above-mentioned announcement to make a little change or be modified to the equivalent embodiment of equivalent variations, to present technique and any simple modification that embodiment did, equivalent variations and modification all still belong in the scope of technical solution of the present invention.

Claims (12)

1. a combined oil-metal polymer solution is used for through fermentation lichensization and/or algaeization and/or esterification (metal esterification ferment biological catalyzer) increase biodiesel and/or other application, and the mass percent proportioning of its each component is as follows:
By water: 0.1-79.4%;
And/or the oil product of fatty acids and/or its reversible transformation substance formation: 20-99%;
And/or R-COOH and/or its reversible transformation substance: 0.01-40%;
Dissolving carbohydrate (containing sugar-metal) and/or its reversible transformation substance: 0.01-30%;
Have hydroxyl or hydroxyl and amino and/or carboxyl and/or carbohydrate polymkeric substance of (containing glycan-metal) (containing polymeric material) and/or usnic acid (cooperation carbohydrate) and/or other metal chelators (cooperation carbohydrate): 0.01-30%;
And/or metal-salt and/or ore and/or bone (containing sugar-metal and/or glycan-metal need not add): 0.01-30%;
Ammonia or amine substance and/or NH 2Reversible several times mutually transformation substance such as protein: 0.01-30%;
Comprise above-mentioned two or more the composition composition or contain the similar close combination material of above-mentioned composition: 0.01-70%;
And/or the bacterium of the bacterium of the bacterium of generation carboxylic acid and material replacement carboxylic acid and/or generation ammonia or amine and material replacement ammonia or amine and/or generation carbohydrate and bacterium and material replacement lipid acid and/or Pepsin and/or the bacterium and/or the cell of material replacement carbohydrate and/or generation lipid acid thereof, R-COOH wherein is an organic acid, add according to a conventional method to stir or heat to mix and form solution, have the protein fermentation multiplication characteristic, comprise one or more combined oil-metal dislocated polymer.
2. combined oil-metal polymer solution according to claim 1, wherein said:
Lichens turns to fungi and the marine alga symbiosis is grown up as lichens, moss or liver moss;
Algae turns to algae and grows up as spirulina, green alga;
Described oil product is lipid acid, cracking oil product, contain OH base oil product or mineral oil;
Described ore is sand, skeleton, each metallic ore, rock, ore deposit soil or ceramic tile;
Wherein contain fungi and/or algae and/or liver moss and/or tealeaves cell and/or other microorganisms or esterification ferment and/or wine canal ferment and/or be allocated as composite bacteria and/or function yeast by the metal-dislocated polymer solution principle of fermenting.
3. combined oil-metal polymer solution according to claim 1 is characterized in that: wherein said lichensization and/or algaeization and/or other plant substratum biological and/or other application are: humic acids " or other " metal-dislocated polymer solution;
Food source is: air contains nitrogen, oxygen, organic and inorganic dust, grease in the air, carbonic acid gas or carbanion and/or bicarbonate ion and water, rock and ore are laid in the equipment, skeleton, phosphate fertilizer, potash fertilizer, the acid of quantitative dosing titration trace ore deposit soil and/or metal-salt and/or inorganic salt and/or carbohydrate and/or carboxyl and/or urea and/or ammonia and/or amine substance and/or discarded proteic substance or according to aforesaid combined oil-metal polymer solution nutritive medium or supply fungi and/or algae and/or other after when handling fertilizer that organic waste becomes or the acid that is added with carboxyl or ammonia or amine substance according to aforesaid ferment " being fit to plant such as EM bacterium " combined oil-metal polymer solution nutritive medium or combined oil-metal polymer solution to use composition be that to meet that combined oil-metal polymer solution lacks or supply fungi and/or algae and/or other plant biological nutrition composition during the breeding fermentation be to meet combined oil-metal polymer solution to lack, and/or wood dust, ore deposit soil agglomerating ceramic tile, paddy, sunlight and/or equipment contain light irradiation apparatus as bulb, the LED lamp, luminous and/or the light lead of optical fiber waits to be regulated.
4, the preparation equipment of the described combined oil-metal polymer solution of a kind of claim 1, it is characterized in that wherein said lichensization and/or algaeization and/or other the photosynthetic plant biological junior middle schools equipment used of growing is: preposition air disinfection and/or film filter purification of carbon dioxide/nitrogen, mix equipment or have air/water and/or oil phase is molten and form the vortex board device by prolong row of general gas-liquid, utilize air revolution and water conservancy diversion metal plate to produce the rinse bath " application " of whirlpool water and/or oil but other gas-liquids mix, the heat exchange condenser that utilize to produce the prolong row usefulness of vortex promotes gas-liquid mix equipment and bioreactor: " being respectively the channeltype that pipe circles round into the circle pillar from top to down; the straight bent-tube boiler of manifold is arranged in the straight bend pipe of " W " shape for " order " word shape manifold; directly bent plate face formula is that straight plate face and bent plate face are connected in series formation " traverse W " shape at interval; other modes " and receiving tank are set up circulation device and are installed additional and stir masher and blend, decomposing machine cracking plant biological is set up again and is stirred breeding fermentation holding tank for containing heat exchange heating tube row or warming apparatus.
5. the preparation equipment of combined oil-metal polymer solution according to claim 4, it is characterized in that mix equipment or have air/water and/or the molten equipment of oil phase is a large amount absorbing carbon dioxide of wherein said gas-liquid, the acid of titration carboxyl or ammonia or amine substance and/or salt are acid or alkalescence and/or produce mix equipment and/or aforementioned device of vortex and have and promote carbon dioxide absorption, nitrogen to absorb and/or have the heat exchange condenser of thermal stimulation growth and/or light to regulate.
6. the preparation method of claim 1 or 2 described combined oil-metal polymer solutions, it is characterized in that described lichensization and/or algaeization and/or other plant biologic shift is esterification, includes fungi and/or algae and/or other plant biology and need do to stir and grind cracking and/or mix carboxylic acid and/or carbohydrate and sterilization sterilising treatment such as high-temperature sterilization, radiating spokes ray are handled.
7. the preparation method of the described combined oil-metal polymer solution of claim 1, it is characterized in that wherein said esterification be titanium or cobalt and/or aluminium or antimony metal esterification ferment " as lipase esterification ferment and/or sneak into a little wine canals " biological catalyst come esterification or esterification treatment; Reactant of esterification is oil, carbonyl compound, lipid acid, carboxylic acid, carbohydrate alcohols or the general alcohols through the wine canalization, and esterification process can add negative oxygen ion O in good time -2, O 2-Or gas such as nascent oxygen is strengthened upgrading.
8. the preparation method of combined oil-metal polymer solution according to claim 7, described esterification fermentation equipment used is for having stirring and/or aerated fermentation chemical industry equipment, makes gelling coagulating sedimentation person come two to be separated solvent and non-solvent mutually or fractionation by distillation through settling agent such as iron(ic) chloride or other.
9. the preparation method of combined oil-metal polymer solution according to claim 1, interpolation amino can be changed to reversible several times mutually transformation substance of NH2 such as protein after described polymers soln added metal-salt and/or metallic ore, thereafter mat has grinding and/or dissolving and/or cracking and/or ferment " as the hydrolysis bacterium " fermented protein becomes amine and Amino acid and/or a small amount of Ammonia when above-mentioned solution fermentation initiator, above-mentioned or carbohydrate or carboxylic acid or lipid acid can use according to above-mentioned grinding and/or dissolving and/or cracking and/or ferment conversion method, and/or a small amount of above-mentioned transformation substance is when above-mentioned solution fermentation initiator.
10. according to claim 1 or 3 or 4 or 5 or 9 its reaction process of described combined oil-metal polymer solution and conversion units: " comprise grinding and/or dissolving and/or cracking use " and reaction soln in plant cultivation growth and/or add sterilization factors in like manner bacterium exist: the carbon dioxide gas liquid phase is molten, photosynthetic production is cultivated, circulation fluid stirs and grinds cracking and mix " duplicated hyperplasia grow up to just maybe need stir grind cracking ", stir four steps of breeding fermentation holding tank and repeat the continuous hyperplasia that circulates back and forth, be adapted at producing the first and/or middle utilization in vegetative period of the photosynthetic plant biological of algae and/or lichens and/or other and/or other substratum, and growth just can be quickened soon to cultivate; And/or when purifying the algae kind and preventing that living contaminants is in lichens is immobilized onto in good and promote to breed in utilization.
11. come proportioning to add according to combined oil-metal polymer solution lacked to handle organic waste for solidifying or liquefaction and/or become fertilizer, feed, food fermentation and/or generation according to claim 1 or 3 or 9 described combined oil-metal polymer solutions: substratum " contain hydrolysis, produce hydrogen and produce bacterium such as acetate, methane " as metal-dislocated polymer and the nutrition the inside wrong fount metal ion suggestion that " do not contain bacterium " according to aforesaid metal-dislocated polymer matter with nickel or molybdenum, both materials mixing and giving birth to; Application in the organic gas " application of methane-containing gas ".
12. according to claim 1 or 9 described combined oil-metal polymer solutions oxidative condensation and condensation reaction, fermentation with biochemical reaction, metal ferment biological catalyzer, bacterium culture medium and saved system, food health care, plant in chemical substance production, oil prod handle application, nanofiltration, fermentation and make nano material, make liquid crystal and semi-conductor, nanometer are moulded rubber and The application of new technique is extended in fiber, nano-inorganic substance and stupalith manufacturing.
CNA2005101350944A 2005-12-23 2005-12-23 Combined oil-metal polymer solution and its application Pending CN1986738A (en)

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