CN1397632A - Process for extracting from flax seeds by supercritical CO2 - Google Patents
Process for extracting from flax seeds by supercritical CO2 Download PDFInfo
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- CN1397632A CN1397632A CN 01120529 CN01120529A CN1397632A CN 1397632 A CN1397632 A CN 1397632A CN 01120529 CN01120529 CN 01120529 CN 01120529 A CN01120529 A CN 01120529A CN 1397632 A CN1397632 A CN 1397632A
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Abstract
A supercritical CO2 extraction process of flax seeds includes drying in the air, sieving by 12 meshes, pre-treating, supercritical CO2 extracting, vacuum separation, and screening. Its advantages are high output rate and purity of product and no pollution.
Description
Technical field:
The invention belongs to a kind of is raw material with the linseed oil, passes through supercritical CO
2Extraction directly obtains oil, glue and nutrition in the linseed oil or the method for medicinal products.
Background technology:
Linseed oil claims flaxseed again, this seed oil-containing 30-48%, and protein 18-38%, cement 5-12%,
Class 12-26%, also organic acid and vitamin A, 53% is alpha-linolenic acid in the linseed oil, contain the lignanoid that is known as (SDG) such as the different pinoresinol disaccharide glycosides that falls of open loop in a large number in the linseed oil fiber, linseed oil also contains natural gum and mucilage in addition, and these materials provide beneficial effect at aspects such as treatment cancer, systemic lupus erythematosus (SLE), hyperlipidaemia and rheumatic arthritis.The 75-800 that contains abundant SDG in the linseed oil and be other food doubly, about 527mg/g, and SDG average content instrument is 0.84mg/g in 27 kinds of fruit.So be the herbal medicine in ancient times, be again modern medicine.China's flax resource is not only abundant, and among the people medicinal also with a long history.Since the nineties, states such as America and Europe to the new therapeutic action of mute fiber crops day by day deeply radiate the vigour of youth in the hope of making these herbal medicine in ancient times, become modern doctor's grass.At present domesticly from linseed oil, extract greasy method two kinds of physical method and chemical processes are arranged.
Described physics method, promptly general milling process wraps in the porous utensil with linseed oil, after the pressurization, oil is separated with slag.The oil product color that this method such as (as the workshop of present township and village enterprises) obtains is muddy deeply, and color and taste is strange, the character instability, and the productive rate of oil is not high yet.The slag of de-oiling is mostly as cheap feed.
Also can directly be processed into flaxseed gum to linseed oil, this method complex process needs to fall behind art breading through water logging, degreasing, decolouring etc., and product yield is low, and is of poor quality, unstable properties.
Described chemical method is that solvent extraction process (small and medium-sized cities grease factory at present) solvent commonly used has ethanol, ether and sherwood oil etc.The oil product that this method is used and other product all contain the residue of solvent, can not guarantee its purity and quality, thereby have influenced the exploitation of their widespread use, also can be used as fodder additives.
Summary of the invention:
The objective of the invention is to develop that a kind of technology is simple, product yield is high, purity is high, the linseed oil supercritical CO of wide in variety, stable performance
2Extracting process.Can obtain linseed oil, glue, powder from one step of linseed oil with this method, can directly be used as healthcare products and medicine.
Method of the present invention divided for three steps carried out, and existing division is as follows:
(1) raw material linseed oil drying, pulverizing and screening
Is 2-8% with the linseed oil natural air drying to moisture content, with frosted type pulverizer, by suitable dish clearance gap, linseed oil wiped to expose to seed benevolence get final product,, pay special attention to not excessively friction therebetween then by 12 mesh sieves, make the material bonding agglomerating, influence is processing further, sieves;
(2) linseed oil supercritical CO
2Extraction
CO
2Flow 10-100Kg/hr, extracting pressure is 20-35Mpa, extraction temperature is 35-55 ℃, extracts time 2-8 hour;
(3) product separation
Behind the materials abstraction, carry out decompression separation, get linseed oil through separator I and II.The pressure of separator I is 10-15Mpa, and temperature 40-50 ℃, the pressure of separator II is 6-8Mpa, and temperature is 45～55 ℃, opens the residual powder of emitting after the extractor decompression, behind sifting screen, gets other products such as glue, powder, and product is tephrosious loose fine powder.
The conspicuous advantage of the present invention is as follows:
(1) technology is simple.Only as long as handle and supercritical CO through raw material
2Extracting and separating gets final product.
(2) product yield height.The extraction yield of linseed oil (refers to oil length) more than 98% actual oily yield 35% (weight), the yield of linseed oil dry glue powder is to take out more than 99% of excess.
(3) the purity height of product, autoclaving, stable performance.Oil colours is pale yellow, transparent, does not contain remaining solvent, and long-term storage is never degenerated.
(4) purposes of product is wide.Both can be used as healthcare products, also can be used as medicine.Linseed oil can be used as high-class healthy oil, and＞100 purpose powder are as the linseed oil rubber powder, and 40-100 purpose fine powder makes to contain the binding agent of product additive or Chinese-western medicine, and the 12-40 order is made fodder additives.
Embodiment:
Embodiment 1
With nine, sophisticated linseed oil in October (flaxseed) through natural air drying moisture content about 2-8%, adopt frosted type pulverizer to regulate suitable dish clearance gap, even extremely inferior (recklessly) numb seed skin frays sub-benevolence and exposed 10-20 purpose sieve, this operation must be grasped and not make the numb seed in Asia (recklessly) produce the sticking agglomeration of oil and excessively friction generates heat, the difficulty of sieving.Get and pulverize material 500g and pack in the extractor of 2 liters, with whole extracting system CO
2Displacement also is full of the adjustment extraction plant parameters at different levels of boosting, extractor extracting pressure 25-30Mpa, and temperature 35-45 ℃, I level separator pressure 10-11Mpa, temperature 40-45 ℃, II level separator pressure 6-8Mpa, mixes up CO by temperature 45-50 ℃
2Flow 10-20Kg/h, extraction 2.5-4hr, emit the material weighing meter by separator I, II and weigh per therebetween half an hour, finally can receive to such an extent that 175g oil light golden rod yellow is limpid transparent, tasteless, odorless, acid number＜2g KOH/100g after testing, peroxide value＜3, alpha-linolenic acid content＞55% in the oil, open the extractor loam cake behind the system decompression, emit canescence and do loose powder 325g and be Asia (recklessly) numb seed rubber powder spent meal preferably through sieve classification＞100 order 82g fine powders.40-100 order fine powder 125g can be as foodstuff additive and Chinese-western medicine tackiness agent, 12-40 order belt leather meal additive capable of using as feed.So far supercritical CO
2The processing of extraction single stage method obtains the product linseed oil, and multiclass byproducts such as linseed oil rubber powder and nutritive food interpolation have been accomplished the brand-new processing method of zero-emission, and whole wheel operation is 6-8hr only.
Embodiment 2
Step is with embodiment 1, the raw material consumption 250g supercritical CO of packing into
2Extractor is 2 liters, the same operational condition, with upward pressure at 25Mpa, 37 ℃ of temperature, the extracting time, 2.5h got oily 98g, acid number＜2, extractor is emitted residual powder 150g after the step-down of peroxide value＜3 (linolenic acid in the oil＞55%), and through dry screening＞100 orders, 40g is a degreasing linseed oil rubber powder, 40-100 order powder 50g fine powder is foodstuff additive and Chinese-western medicine tackiness agent, and remainder＜40 order 60g belt leather flours are done the feed blender.Count 3-5hr during full wheel operation.
Embodiment 3
Step is with embodiment 1, and the raw material consumption is 4000g, and it is the same to carry out operational condition in pilot scale 24 liter extractors, pressure 30Mpa, 45 ℃ of temperature, separator I pressure 11Mpa, 40 ℃ of temperature, separator II8.5Mpa, 45 ℃ of temperature, CO
2Flow 120Kg/hr, 6hr when extracting is total, get oily 1475g, oil quality acid number＜2, peroxide value＜3, alpha-linolenic acid in the oil product＞55%, step-down is opened extractor and is poured out residual powder 2520g, through sieve classification＞100 orders, and foodstuff additive and the Chinese-western medicine tackiness agent remainder of the 620g degreasing numb seed rubber powder 750g of industry (40-100 order), 1145g belt leather meal can be joined feed usefulness, takes turns process 8-10hr process period entirely.
Claims (2)
1. linseed oil supercritical CO
2Extraction green processing method is given processing, supercritical CO by raw material
2Extraction and separate screening and constitute is characterized in that described raw material gives to be treated to: the linseed oil natural air drying to moisture 2-8%, is pulverized by 12 orders with frosted type pulverizer, controlled that its skin is broken, benevolence is revealed, not conglomeration.
2. extracting process as claimed in claim 1 is characterized in that described extraction process parameter is: CO
2Flow is 10-100Kg/hr, and extracting pressure is 20-35Mpa, and extraction temperature is 35-55 ℃, and the extraction time is 2-8 hour; The processing parameter of the decompression separation of described extraction is: the pressure that gets the separator I of oil product is 10-15Mpa, and temperature is 40-50 ℃, separator II, pressure is 6-8Mpa, temperature is 60 ℃, extracts residual powder and is emitted by extractor, is divided into rubber powder, fine powder, meal multiple product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011205296A CN1136301C (en) | 2001-07-19 | 2001-07-19 | Process for extracting from flax seeds by supercritical CO2 |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011205296A CN1136301C (en) | 2001-07-19 | 2001-07-19 | Process for extracting from flax seeds by supercritical CO2 |
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| CN1397632A true CN1397632A (en) | 2003-02-19 |
| CN1136301C CN1136301C (en) | 2004-01-28 |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1973812B (en) * | 2006-11-03 | 2010-12-08 | 谭登平 | Method of powdering supercritical CO2 solid extract |
| CN102433361A (en) * | 2011-10-13 | 2012-05-02 | 上海中沛生物科技有限公司 | Continuous high-quality ethyl linolenate preparation method |
| CN101658211B (en) * | 2009-09-15 | 2012-05-23 | 中国农业科学院油料作物研究所 | Edible linseed oil extraction debitterizing method |
| CN103333740A (en) * | 2013-07-16 | 2013-10-02 | 河北农业大学 | Flaxseed oil and supercritical CO thereof2Extraction method |
| CN104126678A (en) * | 2014-07-30 | 2014-11-05 | 徐州享康食品有限公司 | Good-flavored plant blend oil rich in omega-3 polyunsaturated fatty acids and production method thereof |
| CN104194925A (en) * | 2014-07-31 | 2014-12-10 | 濮阳市天行健生物科技有限公司 | Method for extracting abelmoschus manihot L.Medic. oil with supercritical CO2 |
| CN104194924A (en) * | 2014-07-31 | 2014-12-10 | 濮阳市天行健生物科技有限公司 | Method for extracting linseed oil with supercritical CO2 |
| CN105199831A (en) * | 2015-09-06 | 2015-12-30 | 江苏江大源生态生物科技股份有限公司 | Supercritical extraction method of linseed oil |
| CN106085594A (en) * | 2016-06-22 | 2016-11-09 | 新疆天然芳香农业科技有限公司 | Semen Lini oil and preparation method thereof |
| CN106854491A (en) * | 2016-12-07 | 2017-06-16 | 宁夏农林科学院固原分院 | A kind of selenium-rich linseed oil and preparation method thereof |
| CN108477574A (en) * | 2018-03-30 | 2018-09-04 | 广州利众生物科技有限公司 | A kind of preparation method and its usage of degreasing linseed meal |
| CN108566995A (en) * | 2017-03-07 | 2018-09-25 | 长沙思麦食品开发有限公司 | A kind of Tea oil special for children ready-mixed oil |
| CN115669842A (en) * | 2022-11-07 | 2023-02-03 | 中科京川(四川)生物科技有限公司 | Unsaturated fatty acid-nervonic acid compound solid beverage and preparation method thereof |
-
2001
- 2001-07-19 CN CNB011205296A patent/CN1136301C/en not_active Expired - Fee Related
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1973812B (en) * | 2006-11-03 | 2010-12-08 | 谭登平 | Method of powdering supercritical CO2 solid extract |
| CN101658211B (en) * | 2009-09-15 | 2012-05-23 | 中国农业科学院油料作物研究所 | Edible linseed oil extraction debitterizing method |
| CN102433361A (en) * | 2011-10-13 | 2012-05-02 | 上海中沛生物科技有限公司 | Continuous high-quality ethyl linolenate preparation method |
| CN103333740A (en) * | 2013-07-16 | 2013-10-02 | 河北农业大学 | Flaxseed oil and supercritical CO thereof2Extraction method |
| CN104126678A (en) * | 2014-07-30 | 2014-11-05 | 徐州享康食品有限公司 | Good-flavored plant blend oil rich in omega-3 polyunsaturated fatty acids and production method thereof |
| CN104126678B (en) * | 2014-07-30 | 2016-06-29 | 徐州享康食品有限公司 | A kind of rich in omega-3 polyunsaturated fatty acids and sapid plant blend oil and preparation method thereof |
| CN104194924A (en) * | 2014-07-31 | 2014-12-10 | 濮阳市天行健生物科技有限公司 | Method for extracting linseed oil with supercritical CO2 |
| CN104194925A (en) * | 2014-07-31 | 2014-12-10 | 濮阳市天行健生物科技有限公司 | Method for extracting abelmoschus manihot L.Medic. oil with supercritical CO2 |
| CN105199831A (en) * | 2015-09-06 | 2015-12-30 | 江苏江大源生态生物科技股份有限公司 | Supercritical extraction method of linseed oil |
| CN106085594A (en) * | 2016-06-22 | 2016-11-09 | 新疆天然芳香农业科技有限公司 | Semen Lini oil and preparation method thereof |
| CN106854491A (en) * | 2016-12-07 | 2017-06-16 | 宁夏农林科学院固原分院 | A kind of selenium-rich linseed oil and preparation method thereof |
| CN108566995A (en) * | 2017-03-07 | 2018-09-25 | 长沙思麦食品开发有限公司 | A kind of Tea oil special for children ready-mixed oil |
| CN108477574A (en) * | 2018-03-30 | 2018-09-04 | 广州利众生物科技有限公司 | A kind of preparation method and its usage of degreasing linseed meal |
| CN115669842A (en) * | 2022-11-07 | 2023-02-03 | 中科京川(四川)生物科技有限公司 | Unsaturated fatty acid-nervonic acid compound solid beverage and preparation method thereof |
| CN115669842B (en) * | 2022-11-07 | 2023-12-01 | 中科京川(四川)生物科技有限公司 | Unsaturated fatty acid-nervonic acid compound solid beverage and preparation method thereof |
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|---|---|
| CN1136301C (en) | 2004-01-28 |
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