CN118266467A - Insecticidal bait containing piperic acid derivative compounds and application thereof - Google Patents
Insecticidal bait containing piperic acid derivative compounds and application thereof Download PDFInfo
- Publication number
- CN118266467A CN118266467A CN202211647666.7A CN202211647666A CN118266467A CN 118266467 A CN118266467 A CN 118266467A CN 202211647666 A CN202211647666 A CN 202211647666A CN 118266467 A CN118266467 A CN 118266467A
- Authority
- CN
- China
- Prior art keywords
- bait
- acid derivative
- compound
- piperic acid
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 piperic acid derivative compounds Chemical class 0.000 title claims abstract description 48
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 20
- 241001674044 Blattodea Species 0.000 claims abstract description 18
- 241000736128 Solenopsis invicta Species 0.000 claims abstract description 12
- 241000257303 Hymenoptera Species 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims description 39
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 33
- 238000002156 mixing Methods 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 235000000346 sugar Nutrition 0.000 claims description 13
- 239000004512 granular bait Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims description 8
- 239000005667 attractant Substances 0.000 claims description 8
- 230000031902 chemoattractant activity Effects 0.000 claims description 8
- 235000013312 flour Nutrition 0.000 claims description 8
- 239000003906 humectant Substances 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 7
- 239000000499 gel Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 239000008159 sesame oil Substances 0.000 claims description 6
- 235000011803 sesame oil Nutrition 0.000 claims description 6
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 5
- 229930091371 Fructose Natural products 0.000 claims description 5
- 239000005715 Fructose Substances 0.000 claims description 5
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 5
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 5
- 235000014121 butter Nutrition 0.000 claims description 5
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- 239000002285 corn oil Substances 0.000 claims description 5
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 claims description 5
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 claims description 5
- 235000012141 vanillin Nutrition 0.000 claims description 5
- 239000000230 xanthan gum Substances 0.000 claims description 5
- 235000010493 xanthan gum Nutrition 0.000 claims description 5
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- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims description 4
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
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- 239000006188 syrup Substances 0.000 claims description 4
- 235000020357 syrup Nutrition 0.000 claims description 4
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 claims description 3
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- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims description 3
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- 235000015278 beef Nutrition 0.000 claims description 3
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- 239000003760 tallow Substances 0.000 claims description 3
- SJDSOBWGZRPKSB-UHFFFAOYSA-N tricos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCCCCC=C SJDSOBWGZRPKSB-UHFFFAOYSA-N 0.000 claims description 3
- RHBGITBPARBDPH-ZPUQHVIOSA-N (E,E)-piperic acid Chemical class OC(=O)\C=C\C=C\C1=CC=C2OCOC2=C1 RHBGITBPARBDPH-ZPUQHVIOSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 2
- 150000001720 carbohydrates Chemical class 0.000 claims description 2
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- 235000013336 milk Nutrition 0.000 claims description 2
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- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- RHBGITBPARBDPH-UHFFFAOYSA-N (2E,4E)-5-(3,4-methylenedioxyphenyl)-2,4-pentadienoic acid Natural products OC(=O)C=CC=CC1=CC=C2OCOC2=C1 RHBGITBPARBDPH-UHFFFAOYSA-N 0.000 claims 1
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- 239000000796 flavoring agent Substances 0.000 claims 1
- 235000019634 flavors Nutrition 0.000 claims 1
- 230000000361 pesticidal effect Effects 0.000 claims 1
- WVWHRXVVAYXKDE-UHFFFAOYSA-N piperine Natural products O=C(C=CC=Cc1ccc2OCOc2c1)C3CCCCN3 WVWHRXVVAYXKDE-UHFFFAOYSA-N 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 abstract description 8
- 239000000575 pesticide Substances 0.000 abstract description 4
- 239000004480 active ingredient Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 36
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- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 3
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- 241000254173 Coleoptera Species 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
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- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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- XINCECQTMHSORG-UHFFFAOYSA-N Isoamyl isovalerate Chemical compound CC(C)CCOC(=O)CC(C)C XINCECQTMHSORG-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
- A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
- A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aldehyde or keto groups, or thio analogues thereof, directly attached to an aromatic ring system, e.g. acetophenone; Derivatives thereof, e.g. acetals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
- A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/10—Animals; Substances produced thereby or obtained therefrom
- A01N63/14—Insects
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/34—Rosaceae [Rose family], e.g. strawberry, hawthorn, plum, cherry, peach, apricot or almond
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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Abstract
The invention discloses an insecticidal bait containing piperic acid derivative compounds and application thereof, wherein the active ingredient of the bait is the piperic acid derivative compounds, and the bait contains 0.01 to 20 percent of piperic acid derivative compounds by weight. Because the piperic acid derivative compound is a brand new pesticide component, the action mechanism is novel, the piperic acid derivative compound is effective on cockroaches, ants and solenopsis invicta, and bait products containing the piperic acid derivative compound are also effective on resistance targets, thus being important products for pest resistance management. Wherein the structural formula of the piperic acid derivative compound is as follows:
Description
Technical Field
The invention relates to an insecticidal bait, in particular to an insecticidal bait containing piperic acid derivative compounds and application thereof, and belongs to the technical field of pesticides.
Background
The cockroaches are widely distributed, have strong reproductive capacity and great hazard. Cockroaches can carry a variety of bacteria, such as plague, escherichia coli, and other pathogenic microorganisms. In addition, cockroaches have a feeding habit, which can cause short circuits of wires, electric appliances and other equipment, and indirectly harm personal safety.
Ants can be seen everywhere in life, and the hazard liquid caused by the ants is not quite small, and is specifically expressed as follows: when stimulated, bites attack humans; carrying various bacteria and viruses, and spreading in the crawling process around; the food is polluted, the wood is damaged and the environment is polluted while foraging; and the building construction is damaged, especially the brick and wood structure construction is seriously damaged.
The native americas of solenopsis invicta are the quarantine harmful organisms of agriculture, forestry and inbound plants in China, are recognized as one of hundreds of most dangerous invasive species worldwide, and eating seeds, fruits and root systems of agricultural crops, nesting can cause short circuit of wires or facility faults, and stings of stings and stings of people and animals can cause burning pain, shock and death. In recent years, solenopsis invicta spread rapidly in a plurality of provinces in China, and epidemic situation occurrence degree is aggravated and influence is large.
Cockroaches, ants and solenopsis invicta are taken as pests which bring long-term trouble and harm to the life of residents, and the human society invests a great deal of manpower and financial resources for killing the pests, so that the drug resistance of the cockroaches, ants and solenopsis invicta is enhanced.
The Chinese patent CN112457288 discloses a piperic acid derivative and application thereof, wherein the compound I-72 has contact killing and stomach poisoning activities and good conduction activities, and can be used for preventing and controlling various pests such as lepidoptera, hemiptera, thysanoptera, coleoptera and the like. Meanwhile, the application of the compound I-72 to the sanitary targets is not seen so far, so that the insecticidal variety is also effective, and the success rate of pest killing is increased. The structural formula of the compound is as follows:
Disclosure of Invention
Aiming at the defects existing in the prior art, the invention provides the insecticidal bait containing the piperic acid derivative compound (compound I-72) and the application thereof, which have better killing effect on cockroaches, ants and solenopsis invicta and better killing effect on resistance targets based on the increase of control difficulty caused by the damage of cockroaches, ants and solenopsis invicta and the generation of drug-resistant pests.
In order to achieve the above purpose, the present invention adopts the following technical scheme:
the invention firstly provides an insecticidal bait containing piperic acid derivative compounds (compound I-72), which comprises the following components in parts by weight:
0.01 to 20 percent of piperic acid derivative compound (compound I-72), 0.1 to 20 percent of sugar, 0.1 to 20 percent of humectant, 0.1 to 15 percent of grease, 0.01 to 5 percent of attractant additive, 2 to 50 percent of carrier and 5 to 75 percent of water; wherein the structural formula of the piperic acid derivative compound is as follows:
In the technical scheme, the content of the piperic acid derivative compound (compound I-72) is preferably 0.1% -10%.
In the technical scheme, the sugar is a mixture formed by mixing any one, two or more of white granulated sugar, glucose, sucrose, maltose, honey, lactose, galactose, fructose, corn syrup, brown sugar and caramel in any proportion.
In the technical scheme, the humectant is glycerol.
In the technical scheme, the grease is a mixture formed by mixing any one, two or more than two of soybean oil, sesame oil, peanut oil, corn oil, butter and beef tallow in any proportion.
In the technical scheme, the attractant additive is a mixture formed by mixing one or two or more of indole, tricosene, fruit essence, milk essence, vanillin, brown sugar essence, cockroach pheromone, soy sauce ketone and onion extract in any proportion.
In the technical scheme, the carrier is any one or a mixture of two or more of dextrin, flour, soybean powder, oat powder, fish meal, meat meal, cellulose derivatives, xanthan gum, gelatin, polyethylene glycol, polyvinylpyrrolidone and carboxyvinyl copolymer in any proportion.
In the above technical scheme, the insecticidal bait containing the piperic acid derivative compound (compound I-72) comprises the following components: granular bait, bait blocks, gel bait or bait boxes.
The invention also provides application of the insecticidal bait containing the piperic acid derivative compound (compound I-72) in preventing and treating cockroaches, ants or solenopsis invicta.
Compared with the prior art, the method has the following characteristics: the compound I-72 has contact poisoning and stomach poisoning activities and good conduction activities, and can be used for preventing and treating various pests such as lepidoptera, hemiptera, thysanoptera, coleoptera and the like. Meanwhile, the compound I-72 is not applied to sanitary targets such as cockroaches, ants, solenopsis invicta and the like, is effective on resistant varieties, and has important significance on killing the resistant varieties.
Detailed Description
The following detailed description of the technical scheme of the present invention is provided, but the present invention is not limited to the following descriptions:
The preparation method of the bait in each embodiment of the invention comprises the following steps:
the preparation method of the granular bait comprises the following steps: mixing sugar, humectant and attractant additive with water, stirring thoroughly to obtain uniform liquid phase, mixing oil, carrier and compound I-72, stirring to obtain solid phase, adding liquid phase into solid phase, stirring, granulating with granulator, and oven drying to obtain granular bait.
The preparation method of the bait blocks comprises the following steps: mixing sugar, humectant, attractant additive and water, stirring thoroughly to obtain uniform liquid phase, mixing oil, carrier and compound I-72, stirring to obtain solid phase, adding liquid phase into solid phase, stirring uniformly, using to form block, and oven drying to obtain bait block.
The preparation method of the gel bait comprises the following steps: mixing saccharide, humectant, attractant additive, carrier and water, stirring thoroughly, adding oil and fat and compound I-72 after becoming uniform phase, stirring continuously, shearing with high-speed shearing emulsifying machine if necessary, mixing uniformly, and packaging to obtain gel bait.
The preparation method of the bait box comprises the following steps: mixing sugar, humectant and attractant with water, stirring thoroughly to obtain uniform liquid phase, mixing oil, carrier and compound I-72, stirring to obtain solid phase, adding liquid phase into solid phase, stirring, and making into specific shape or directly extruding into specific box.
The following is set forth in connection with specific examples:
Preparation example 1
Mixing 10% of white granulated sugar, 0.1% of glycerol and 0.1% of brown sugar essence with 24.79% of water, fully stirring, standing by after becoming a uniform liquid phase, mixing and stirring 15% of sesame oil, 50% of flour and 0.01% of compound I-72 to form a solid phase, adding the liquid phase into the solid phase, stirring uniformly, granulating by using a granulator, granulating, finishing granules, and drying to obtain the granular bait.
Preparation example 2
Mixing 5% maltose, 3% brown sugar, 5% glycerol, 0.1% apple essence, 4.9% onion extract with 31.9% water, stirring thoroughly, standing to obtain uniform liquid phase, mixing 5% butter, 5% dextrin, 40% soybean powder and 0.1% compound I-72, stirring to obtain solid phase, adding the liquid phase into the solid phase, stirring, granulating with a granulator, grading, and oven drying to obtain granular bait.
Preparation example 3
Mixing 1% of honey, 6% of fructose, 5% of corn syrup, 3% of glycerol and 0.01% of indole with 33.99% of water, fully stirring, preparing into a uniform liquid phase for later use, mixing and stirring 8% of peanut oil, 5% of meat meal, 15% of fish meal, 20% of flour, 1% of xanthan gum and 2% of compound I-72 into a solid phase, adding the liquid phase into the solid phase, stirring, uniformly stirring, preparing into blocks, and drying to obtain the bait blocks.
Preparation example 4
Mixing 5% lactose, 1% galactose, 2% caramel, 5% glycerol and 1% vanillin with 21% water, stirring thoroughly until a uniform liquid phase is obtained, mixing 10% beef tallow, 5% corn oil, 20% flour, 5% oat flour, 15% fish meal and 10% compound I-72, stirring to obtain a solid phase, adding the liquid phase into the solid phase, stirring uniformly, making into blocks, and oven drying to obtain the bait blocks.
Preparation example 5
Mixing 5% glucose, 2% maltose, 1% glycerol, 0.1% soy sauce ketone and 0.01% cockroach pheromone with 28.89% water, fully stirring, standing by after becoming a uniform liquid phase, mixing and stirring 5% sesame oil, 5% butter, 2% corn oil, 15% fish meal, 1% polyethylene glycol, 15% oat flour and 20% compound I-72 to form a solid phase, adding the liquid phase into the solid phase, stirring uniformly, granulating by using a granulator, granulating, and drying to obtain the granular bait.
Preparation example 6
Mixing 5% fructose, 6% corn syrup, 12% glycerol, 0.1% pineapple essence, 1% polyvinylpyrrolidone, 1% gelatin, 1% xanthan gum and 74.3% water, stirring thoroughly, adding 0.1% butter and 0.5% compound I-72 after being uniform phase, heating continuously for stirring at 40 ℃, shearing by using a high-speed shearing emulsifying machine if necessary, mixing uniformly, and packaging to obtain the gel bait.
Preparation example 7
Mixing 0.1% of honey, 15% of glycerol, 0.05% of tricosene, 1% of vanillin, 1% of carboxymethyl cellulose and 1% of xanthan gum with 68.8% of water, fully stirring, adding 0.1% of corn oil and 5% of compound I-72 after the mixture becomes a uniform phase, continuously stirring, shearing by using a high-speed shearing emulsifying machine if necessary, and packaging after the mixture is uniformly mixed to obtain the gel bait.
Preparation example 8
Mixing 5% of white granulated sugar, 5% of maltose, 5% of fructose, 12% of glycerol, 0.1% of brown sugar essence, 0.1% of soy sauce ketone and 2% of carboxyl ethylene copolymer with 62.2% of water, fully stirring, adding 0.1% of sesame oil and 8% of compound I-72 after the mixture becomes a uniform phase, continuously stirring, shearing by using a high-speed shearing emulsifying machine if necessary, adding 0.5% of PH regulator, uniformly mixing, and packaging to obtain the gel bait.
Preparation example 9
Mixing 2% of honey, 13% of white granulated sugar, 10% of glycerol, 0.1% of vanillin and 0.05% of indole with 18.85% of water, fully stirring, standing by after becoming a uniform liquid phase, mixing and stirring 5% of sesame oil, 10% of peanut oil, 40% of flour and 1% of compound I-72 to form a solid phase, adding the liquid phase into the solid phase, stirring, preparing into a specific shape, and then filling into a specific box or directly extruding into the specific box to obtain the bait box.
Comparative example 1
2.15% Formica Fusca hydrazone bait (prepared by the method of preparation example 6)
Comparative example 2
0.05% Fipronil granule bait (prepared by the method of preparation example 1)
Comparative example 3
1% Flumizone granular bait (prepared by the method of preparation example 2)
Application examples
The bait provided by the invention adopts cockroaches, ants and solenopsis invicta as targets or control objects, and performs indoor activity and field application research, and compared with the conventional bait, the bait has excellent insecticidal activity and remarkable control effect. It should be apparent to those skilled in the art that the examples are merely provided to aid in understanding the present invention and should not be construed as limiting the invention in any way.
Application example 1 cockroach efficacy experiment
Referring to GB/T13917.7-2009 indoor efficacy test of hygienic insecticide for pesticide registration and evaluation part 7: bait, put 30 male and female german cockroaches of each half into square box, add 2g of bait (preparation examples 1-9), use comparative example 1 (2.15% fluorine ant hydrazone glue bait) as control, test temperature is 25 ℃, humidity 70%, three are repeated, after 120h, check death, living insect number, calculate mortality.
TABLE 1 killing effect of bait containing Compound I-72 on German cockroach
As can be seen from Table 1, the bait containing 0.01% -20% of compound I-72 has a good killing effect on cockroaches, wherein 0.1% -10% of compound I-72 has a better killing effect on cockroaches.
Application example 2 Ant efficacy experiment
Referring to GB/T13917.7-2009 indoor efficacy test of hygienic insecticide for pesticide registration and evaluation part 7: bait, 100 yellow ant workers are placed into an enamel square tray with a circle of Vaseline strips coated on the edge of the inner wall, 2g of bait (preparation example 1, preparation example 2 and preparation example 5) is added, the bait of comparative example 2 (0.05% fipronil particles) is used as a control, the test temperature is 25 ℃, the humidity is 70%, and the three steps are repeated, and after 96 hours, the death rate is calculated by checking the number of dead insects and alive insects.
TABLE 2 killing Effect of bait containing Compound I-72 on Formica Fusca
| Sample of | Content of | Mortality rate of 96h |
| Comparative example 2 | 0.05% Fipronil particles | 100％ |
| Preparation example 1 | 0.01% Compound I-72 granular bait | 93.3％ |
| Preparation example 2 | 0.1% Compound I-72 granular bait | 100％ |
| Preparation example 5 | 20% Compound I-72 pellet bait | 100％ |
As can be seen from Table 2, the bait containing 0.01% -20% of compound I-72 has good killing effect on the yellow ant workers.
Application example 3 solenopsis invicta efficacy experiment
The method comprises the steps of trapping workers in the same nest from outdoor fresh ham sausage slices, putting 40 captured workers into a 500ml beaker with a circle of Vaseline strips coated on the edge of the inner wall, adding 2g of bait (preparation example 1, preparation example 2 and preparation example 5), taking the bait of comparative example 3 (1% of the fluorine ant hydrazone particle bait) as a control, testing at 25 ℃ and 70% of humidity, repeating the steps three times, checking the death and living insect numbers after 72 hours, and calculating the death rate.
TABLE 3 killing effect of bait containing Compound I-72 on Formica Fusca
| Sample of | Content of | Mortality rate of 96h |
| Comparative example 3 | 1% Flumetzonum particulate bait | 100％ |
| Preparation example 1 | 0.01% Compound I-72 granular bait | 94.7％ |
| Preparation example 2 | 0.1% Compound I-72 granular bait | 100％ |
| Preparation example 5 | 20% Compound I-72 pellet bait | 100％ |
As can be seen from Table 3, the bait containing 0.01% -20% of compound I-72 has good killing effect on termite workers.
The foregoing examples are merely illustrative of the technical concept and technical features of the present invention, and are not intended to limit the scope of the present invention. All equivalent changes or modifications made according to the essence of the present invention should be included in the scope of the present invention.
Claims (9)
1. An insecticidal bait containing piperic acid derivative compounds, which is characterized in that: comprises the following components in parts by weight:
0.01 to 20 percent of piperic acid derivative compound (compound I-72), 0.1 to 20 percent of sugar, 0.1 to 20 percent of humectant, 0.1 to 15 percent of grease, 0.01 to 5 percent of attractant additive, 2 to 50 percent of carrier and 5 to 75 percent of water; wherein the structural formula of the piperic acid derivative compound is as follows:
2. the insecticidal bait according to claim 1 wherein: the content of the piperic acid derivative compound is 0.1% -10%.
3. The insecticidal bait according to claim 1 wherein: the saccharide is one or more of white sugar, glucose, sucrose, maltose, mel, lactose, galactose, fructose, corn syrup, brown sugar and caramel, and the mixture of two or more of them at random ratio.
4. The insecticidal bait according to claim 1 wherein: the humectant is glycerol.
5. The insecticidal bait according to claim 1 wherein: the grease is a mixture formed by mixing any one, two or more than two of soybean oil, sesame oil, peanut oil, corn oil, butter and beef tallow in any proportion.
6. The insecticidal bait according to claim 1 wherein: the attractant additive is a mixture formed by mixing one or two or more of indole, tricosene, fruit essence, milk flavor essence, vanillin, brown sugar essence, cockroach pheromone, soy sauce ketone and onion extract according to any proportion.
7. The insecticidal bait according to claim 1 wherein: the carrier is one or a mixture of two or more of dextrin, flour, soybean powder, oat powder, fish powder, meat powder, cellulose derivative, xanthan gum, gelatin, polyethylene glycol, polyvinylpyrrolidone and carboxyvinyl copolymer in any proportion.
8. The insecticidal bait according to claim 1 wherein: the insecticidal bait containing the piperic acid derivative compound comprises the following components in a dosage form of but not limited to: granular bait, bait blocks, gel bait and bait boxes.
9. Use of a pesticidal baits containing a piperic acid derivative-like compound as defined in any one of claims 1 to 8 for controlling cockroaches, ants or solenopsis invicta.
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