CN114956710A - High-performance fly ash sprayed concrete for mudstone tunnel and preparation method thereof - Google Patents

High-performance fly ash sprayed concrete for mudstone tunnel and preparation method thereof Download PDF

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Publication number
CN114956710A
CN114956710A CN202210193900.7A CN202210193900A CN114956710A CN 114956710 A CN114956710 A CN 114956710A CN 202210193900 A CN202210193900 A CN 202210193900A CN 114956710 A CN114956710 A CN 114956710A
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fly ash
mass
parts
mudstone
tunnel
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Inventor
刘小飞
刘广华
陈立
高凌泉
温永贵
曹东磊
韩海龙
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China Construction Eighth Engineering Bureau Testing Technology Co ltd
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China Construction Eighth Engineering Bureau Testing Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/08Flue dust, i.e. fly ash
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00724Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Lining And Supports For Tunnels (AREA)

Abstract

The invention discloses high-performance fly ash sprayed concrete for a mudstone tunnel and a preparation method thereof, and the high-performance fly ash sprayed concrete comprises basic concrete, fly ash, steel fibers and a mixed admixture, wherein the basic concrete comprises 372 parts by mass of cement, 929 parts by mass of medium sand, 929 parts by mass of broken stone, 177 parts by mass of water, 4.13 parts by mass of a water reducing agent and 11.6-24.78 parts by mass of an alkali-free liquid accelerating agent, the volume ratio of the steel fibers is 1-2%, and the mixed admixture comprises 25 parts by mass of fly ash, 10.5 parts by mass of slag powder and 5.5 parts by mass of gypsum. The invention solves the problems that the stability of surrounding rocks of the mudstone tunnel is poor, and the primary support of the mudstone tunnel adopts the traditional concrete and cannot provide higher strength and overall mechanical performance.

Description

High-performance fly ash sprayed concrete for mudstone tunnel and preparation method thereof
Technical Field
The invention relates to the technical field of tunnel construction, in particular to high-performance fly ash sprayed concrete for a mudstone tunnel and a preparation method thereof.
Background
Mudstone is mainly composed of clay minerals and contains a part of clastic minerals such as feldspar, quartz and the like. The shale of the mudstone tunnel is cemented, the rock is soft, and the mudstone tunnel has the characteristics of dehydration cracking, water absorption softening and the like, and the rock core is mostly in a broken shape and a short column shape. The ultimate displacement of the mudstone tunnel has small difference, the distribution of surrounding rock and primary support pressure has the characteristic of nonuniformity, the contact pressure between the primary lining is increased rapidly firstly and then reduced gradually, and then the stability tends to be stable, and the stability value is small as a whole. The obvious rheological property of the mudstone tunnel causes the stability of the surrounding rock of the mudstone tunnel to be poor, the stress of the surrounding rock is released quickly in the early stage, and the deformation pressure in the later stage lasts for a long time.
Therefore, the initial support of the mudstone tunnel needs to adopt concrete with high working performance. Therefore, aiming at the characteristics of the mudstone tunnel, the high-working-performance shotcrete for the mudstone tunnel needs to be designed and developed urgently.
Disclosure of Invention
In order to overcome the defects in the prior art, the high-performance fly ash sprayed concrete for the mudstone tunnel and the preparation method thereof are provided, so that the problems that the stability of surrounding rocks of the mudstone tunnel is poor, and the conventional concrete for primary support of the mudstone tunnel cannot provide high strength and overall mechanical performance are solved.
In order to achieve the purpose, the high-performance fly ash sprayed concrete for the mudstone tunnel comprises basic concrete, fly ash, steel fibers and a mixed admixture, wherein the basic concrete comprises 372 parts by mass of cement, 929 parts by mass of medium sand, 929 parts by mass of broken stone, 177 parts by mass of water, 4.13 parts by mass of a water reducing agent and 11.6-24.78 parts by mass of an alkali-free liquid accelerator, the volume ratio of the steel fibers is 1-2%, and the mixed admixture comprises 25 parts by mass of fly ash, 10.5 parts by mass of slag powder and 5.5 parts by mass of gypsum.
Further, the base concrete includes 24.78 parts by mass of an alkali-free liquid accelerator.
Further, the volume fraction of the steel fiber is 2%.
Further, it is characterized byThe fineness of the fly ash is less than 12, the water requirement of the fly ash is less than or equal to 95 percent, the ignition loss of the fly ash is less than or equal to 5 percent, the water content of the fly ash is less than or equal to 1 percent, and the SO of the fly ash 3 The content is less than or equal to 3 percent.
Further, the water reducing agent is a polycarboxylic acid high-performance water reducing agent.
The invention provides a preparation method of high-performance fly ash sprayed concrete for a mudstone tunnel, which comprises the following steps:
respectively weighing basic concrete, fly ash, steel fiber and mixed admixture;
uniformly mixing cement, medium sand, gravel, a water reducing agent and water in the basic concrete with a mixed admixture, and adding the steel fiber in the mixing process to obtain a mixed admixture;
before wet-spraying and spraying the primary support of the construction tunnel on the mudstone surrounding rock, adding the alkali-free liquid accelerator of the basic concrete into the mixed material and uniformly stirring to prepare the high-performance fly ash sprayed concrete for the mudstone tunnel.
The high-performance fly ash shotcrete for the mudstone tunnel has the beneficial effects that the mechanical property and the filling effect of the concrete are greatly improved, the setting time is further shortened, the rebound rate is further reduced, the workability and the slump are increased, and the overall working performance of the shotcrete is improved. On the other hand, the mixed admixture of the high-performance fly ash shotcrete for mudstone tunnel of the present invention comprises a mixture containing at least oxides of Si, Al, Fe, Ca, S and inorganic acid salt. The mineral admixtures are combined into different oxides, have different activities, surface effects, filling effects or pozzolana effects, and when the mineral admixtures are mixed into concrete, the slump, workability, cohesiveness, segregation resistance and later strength of the sprayed concrete can be improved, so that the concrete has better fluidity, compactness and uniformity, and the production requirement of the solid square pile is met.
Detailed Description
The present application will be described in further detail with reference to examples. It is to be understood that the specific embodiments described herein are merely illustrative of the relevant invention and not restrictive of the invention.
It should be noted that the embodiments and features of the embodiments in the present application may be combined with each other without conflict. The present application will be described in detail with reference to examples.
The invention provides high-performance fly ash sprayed concrete for a mudstone tunnel, which comprises base concrete, fly ash, steel fiber and a mixed admixture.
The base concrete comprises 372 parts by mass of cement, 929 parts by mass of medium sand, 929 parts by mass of broken stone, 177 parts by mass of water, 4.13 parts by mass of a water reducing agent and 11.6-24.78 parts by mass of an alkali-free liquid accelerator.
The volume ratio of the steel fiber is 1-2%.
The mixed admixture comprises 25 parts by mass of fly ash, 10.5 parts by mass of slag powder and 5.5 parts by mass of gypsum.
Wherein, the chemical composition of the fly ash is required to be as the following table 1:
TABLE 1 chemical composition of fly ash
Figure BDA0003526148900000031
When the fly ash is used for replacing mineral admixtures in cement materials and concrete, the invention adopts I-grade ash, the fly ash with few particles, few sponge bodies and low carbon content can be maximally filled into cement particles and aggregate pores, the porosity of the concrete is reduced, and the filling effect is improved.
As a preferred embodiment, the fineness of the fly ash is less than 12, the water requirement of the fly ash is less than or equal to 95%, the loss on ignition of the fly ash is less than or equal to 1%, the water content of the fly ash is less than or equal to 1%, and the SO of the fly ash is 3 The content is less than or equal to 3 percent. The specific indexes are as follows: the fineness of fly ash (the screen residue of 45 mu m square-hole sieve is not more than%) is less than 12, the water requirement is not more than 95%, the ignition loss is not more than 5%, the water content is not more than 1%, and SO is 3 Not more than 3%.
The fly ash disclosed by the invention is few in particles, few in sponge and low in carbon content, so that the filling effect of the fly ash is increased, the water absorption capacity and the adsorption capacity are reduced, and the working performance is improved.
In the invention, the mixing amount of the fly ash is 6 percent. Test results show that the compressive strength of the sprayed concrete is highest in 1 day and 7 days when the mixing amount is 6%, and the highest compressive strength is 24.1 MPa.
According to the high-performance fly ash sprayed concrete for the mudstone tunnel, the fly ash volcanic ash activity effect is utilized, SiO and a cement hydration product CH are subjected to secondary reaction to generate C-S-H gel filling aggregate and cement slurry interface layer pores, so that the concrete interface structure is changed, the strength and the durability are improved, and meanwhile, the optimal mixing amount of the fly ash is adjusted to meet the optimal strength requirement.
The high-performance fly ash sprayed concrete for the mudstone tunnel disclosed by the invention has the advantages that the fly ash particles are filled into the pores of the cement particles and the aggregate to the maximum extent by utilizing the particle size difference among the fly ash, the cement particles and the aggregate, the porosity of the concrete is reduced, and the filling effect is improved.
In a preferred embodiment, the base concrete includes 24.78 parts by mass of an alkali-free liquid accelerator.
In a preferred embodiment, the steel fibers have a volume fraction of 2%. The length of the steel fiber is 20-40mm, and the diameter is 0.5 mm. The steel fiber must not have obvious rust, oil stain and other impurities which prevent the steel fiber from bonding with cement, and the total weight of the impurities such as adhesion sheets caused by poor processing, fibers with seriously rusted surfaces, iron rust powder and the like contained in the steel fiber should not exceed 1 percent of the weight of the steel fiber. Through the steel fiber tests of different volume ratios, the test aims at the steel fiber fly ash sprayed concrete with the volume ratios of 1%, 1.25%, 1.5%, 1.75% and 2%, and the test result shows that the tensile strength, the bending strength, the shearing strength and the compressive strength of the steel fiber fly ash sprayed concrete with the volume ratio of 2% are the highest, and the tests of four parameters are increased positively along with the increase of four volume ratios.
In a preferred embodiment, the water reducing agent is a polycarboxylic acid high-performance water reducing agent.
In a preferred embodiment, the cement is p.o42.5 portland cement.
The invention provides a preparation method of high-performance fly ash sprayed concrete for a mudstone tunnel, which comprises the following steps:
s1: respectively weighing basic concrete, fly ash, steel fiber and mixed admixture;
s2: uniformly mixing cement, medium sand, gravel, a water reducing agent and water in the basic concrete with a mixed admixture, and adding the steel fiber in the mixing process to obtain a mixed material;
s3: and before primary support of the mudstone surrounding rock jet construction tunnel, adding the alkali-free liquid accelerator of the basic concrete into the mixed material and uniformly stirring to prepare the high-performance fly ash jet concrete for the mudstone tunnel.
The high-performance fly ash sprayed concrete for the mudstone tunnel is sprayed on mudstone surrounding rocks by a wet spraying process of a spraying construction process to construct a primary tunnel support, and the spraying rebound rate of the concrete is low due to the adoption of high-quality cement.
The cement, coarse and fine aggregates, the water reducing agent, the mixed mineral admixture and the water are stirred firstly, the steel fibers are added in a dispersing way in the stirring process, the stirring time is determined by a field homogeneity test, and the stirring time is prolonged by 1-2 mim compared with the stirring time specified by common concrete. The accelerator was added during spraying, the shotcrete was forced through a wet sprayer to a spray head, and the compounded concrete was sprayed onto the mudstone tunnel and into the mold of the test.
The high-performance fly ash shotcrete for the mudstone tunnel is prepared by matching basic concrete components, steel fibers, additives (a water reducing agent and an accelerating agent) and a mixed admixture, so that the mechanical property and the filling effect of the concrete are greatly improved, the setting time is further shortened, the rebound rate is further reduced, the workability and the slump are increased, and the overall working performance of the shotcrete is improved.
The high-performance fly ash sprayed concrete for the mudstone tunnel has high mechanical property and is quickly condensed to solve the problems that rheological characteristics cause poor stability of surrounding rocks of the mudstone tunnel, the concrete condensation time needs to be shortened and the strength of the concrete needs to be enhanced, after steel fibers are added, the tensile strength, the bending strength, the shearing strength, the compressive strength and the compressive toughness are greatly improved, and the rebound rate is greatly reduced. The curing speed and the strength increasing speed of the high-performance fly ash sprayed concrete for the mudstone tunnel reduce the curing time of the concrete.
The mixed admixture of the high-performance fly ash sprayed concrete for the mudstone tunnel comprises a mixture at least containing oxides of Si, Al, Fe, Ca and S and inorganic acid salt. The mineral admixtures are combined into different oxides, have different activities, surface effects, filling effects or pozzolana effects, and when the mineral admixtures are mixed into concrete, the slump, workability, cohesiveness, segregation resistance and later strength of the sprayed concrete can be improved, so that the concrete has better fluidity, compactness and uniformity, and the production requirement of the solid square pile is met.
In order to clearly show the properties of the high-performance fly ash shotcrete for mudstone tunnel of the present invention, the following examples 1 to 20 are particularly mentioned, and are compared with comparative examples.
Specifically, the raw material mixing ratios of the concrete of examples 1 to 20, and the comparative example are shown in table 2 below.
TABLE 2 high-performance fly ash shotcrete mix ratio for mudstone tunnel
Figure BDA0003526148900000051
Table 2 shows the mixing ratio of the high-performance fly ash shotcrete for the mudstone tunnel
Figure BDA0003526148900000061
Examples 1 to 20, and comparative examples were prepared using the preparation method of the high performance fly ash shotcrete for mudstone tunnel of the present invention, respectively, and test measurement samples were left.
The mechanical property detection of the high-performance fly ash sprayed concrete for the mudstone tunnel is carried out according to the invention, namely, the performance detection reference standard GB/T50107-. Examples 1 to 20, and comparative examples the test measured the properties of the samples as shown in tables 3 and 4 below.
Table 3 working performance table for high performance fly ash shotcrete of mudstone tunnel
Figure BDA0003526148900000062
Table 3 working performance table for high-performance fly ash shotcrete in mudstone tunnel
Figure BDA0003526148900000071
TABLE 4 mechanical Properties of high-Performance fly ash shotcrete for mudstone tunnel
Figure BDA0003526148900000072
TABLE 4 table of mechanical properties of high-performance fly ash sprayed concrete for mudstone tunnel
Figure BDA0003526148900000081
As can be seen from tables 3 and 4, the working performance of the shotcrete produced by the method for preparing high-performance fly ash shotcrete for mudstone tunnel according to the present invention is greatly improved, mainly:
1. the strength of the fly ash sprayed concrete is improved, and the mechanical property is greatly improved;
2. the concrete setting time is shortened, so that a supporting system closed loop is quickly formed;
3. the filling effect of the sprayed concrete is improved; the concrete aggregate and the crushed and short columnar rock burst gaps are fully filled, and the aggregate particles are lubricated;
4. the cohesiveness, plasticity and workability of the sprayed concrete are improved;
5. the problem of too high rebound rate of the sprayed concrete is solved.
Besides, the invention carries out a plurality of experimental descriptions of the embodiment for clearly explaining the working performance of the concrete, and the experimental descriptions of the embodiment do not exist independently but are a whole set of technical scheme.
The above description is only a preferred embodiment of the application and is illustrative of the principles of the technology employed. It will be appreciated by a person skilled in the art that the scope of the invention as referred to in the present application is not limited to the embodiments with a specific combination of the above-mentioned features, but also covers other embodiments with any combination of the above-mentioned features or their equivalents without departing from the inventive concept. For example, the above features may be replaced with (but not limited to) features having similar functions disclosed in the present application.

Claims (6)

1. The high-performance fly ash sprayed concrete for the mudstone tunnel is characterized by comprising basic concrete, fly ash, steel fibers and a mixed admixture, wherein the basic concrete comprises 372 parts by mass of cement, 929 parts by mass of middlings, 929 parts by mass of broken stones, 177 parts by mass of water, 4.13 parts by mass of a water reducing agent and 11.6-24.78 parts by mass of an alkali-free liquid accelerator, the volume ratio of the steel fibers is 1-2%, and the mixed admixture comprises 25 parts by mass of fly ash, 10.5 parts by mass of slag powder and 5.5 parts by mass of gypsum.
2. The high-performance fly ash shotcrete for a mudstone tunnel according to claim 1, wherein the base concrete includes 24.78 parts by mass of an alkali-free liquid accelerator.
3. The high-performance fly ash shotcrete for mudstone tunnels as claimed in claim 1, wherein the volume fraction of the steel fibers is 2%.
4. The high-performance fly ash shotcrete for mudstone tunnel according to claim 1, wherein the fineness of the fly ash is less than 12, the water demand of the fly ash is less than or equal to 95%, the loss on ignition of the fly ash is less than or equal to 5%, the water content of the fly ash is less than or equal to 1%, and the SO of the fly ash is less than or equal to 1% 3 The content is less than or equal to 3 percent.
5. The high-performance fly ash shotcrete for a mudstone tunnel according to claim 1, wherein the water reducing agent is a polycarboxylic acid high-performance water reducing agent.
6. A preparation method of the high-performance fly ash shotcrete for the mudstone tunnel as claimed in any one of claims 1 to 5, comprising the following steps:
respectively weighing basic concrete, fly ash, steel fiber and mixed admixture;
uniformly mixing cement, medium sand, gravel, a water reducing agent and water in the basic concrete with a mixed admixture, and adding the steel fiber in the mixing process to obtain a mixed admixture;
before wet-spraying and spraying the primary support of the construction tunnel on the mudstone surrounding rock, adding the alkali-free liquid accelerator of the basic concrete into the mixed material and uniformly stirring to prepare the high-performance fly ash sprayed concrete for the mudstone tunnel.
CN202210193900.7A 2022-03-01 2022-03-01 High-performance fly ash sprayed concrete for mudstone tunnel and preparation method thereof Pending CN114956710A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116283145A (en) * 2023-03-14 2023-06-23 西南交通大学 High-strength and high-toughness heat-insulation functional sprayed concrete for high-temperature hot water tunnel
CN116354664A (en) * 2023-03-07 2023-06-30 中南大学 Composition for sprayed concrete, preparation method and application thereof
CN116425485A (en) * 2023-04-17 2023-07-14 燕山大学 Steel fiber cement-based spraying mortar and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103626444A (en) * 2012-08-27 2014-03-12 沈保国 Construction process of steel fiber shotcrete
CN113968714A (en) * 2021-09-29 2022-01-25 宿州市健生矿山设备有限公司 Aluminate cement-based spraying mortar and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103626444A (en) * 2012-08-27 2014-03-12 沈保国 Construction process of steel fiber shotcrete
CN113968714A (en) * 2021-09-29 2022-01-25 宿州市健生矿山设备有限公司 Aluminate cement-based spraying mortar and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116354664A (en) * 2023-03-07 2023-06-30 中南大学 Composition for sprayed concrete, preparation method and application thereof
CN116283145A (en) * 2023-03-14 2023-06-23 西南交通大学 High-strength and high-toughness heat-insulation functional sprayed concrete for high-temperature hot water tunnel
CN116425485A (en) * 2023-04-17 2023-07-14 燕山大学 Steel fiber cement-based spraying mortar and preparation method thereof

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