CN113913690B - Steel for offshore wind power flange and preparation method thereof - Google Patents

Steel for offshore wind power flange and preparation method thereof Download PDF

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CN113913690B
CN113913690B CN202111114011.9A CN202111114011A CN113913690B CN 113913690 B CN113913690 B CN 113913690B CN 202111114011 A CN202111114011 A CN 202111114011A CN 113913690 B CN113913690 B CN 113913690B
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CN113913690A (en
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袁淑君
赵新华
闫志华
张鹏
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Shandong Iron and Steel Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • C22C33/06Making ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/005Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention discloses steel for an offshore wind power flange and a preparation method thereof, wherein the yield strength R of the steel eL Not less than 460MPa, tensile strength R m : the elongation A after fracture of 530-680MPa is more than or equal to 25 percent, the performance in the thickness direction is Z35 level, and the low-temperature impact absorption energy KV is below-60 DEG C 2 The mass is more than or equal to 50J. The composition comprises the following components in percentage by mass: c: 0.05-0.08%, Si: 0.30 to 0.50%, Mn: 0.50-0.80%, P: less than or equal to 0.012%, S: less than or equal to 0.003 percent, Cr: 1.20 to 1.40%, Cu: 0.10 to 0.30%, Ni 0.05 to 0.20%, V: 0.040 to 0.060%, Nb: 0.010-0.030%, N: 0.0120-0.0180%, RE: 0.0010 to 0.0030%, As: less than or equal to 0.015 percent, Sn: less than or equal to 0.015%, Pb: less than or equal to 0.0025%, Sb: less than or equal to 0.0025 percent, Bi: less than or equal to 0.0025 percent, (As + Sn + Pb + Sb + Bi): less than or equal to 0.025 percent and [ O ]]Less than or equal to 0.0012 percent, and the balance of Fe and inevitable impurities; and the chemical composition satisfies the carbon equivalent CEV less than or equal to 0.47%; the crack sensitivity coefficient Pcm is less than or equal to 0.22 percent; the corrosion resistance index I is more than or equal to 6.0. The steel for the offshore wind power flange, which is prepared by the invention, has the excellent performances of high corrosion resistance, high low temperature resistance, high strength, easy welding performance, high lamellar tearing resistance and the like.

Description

Steel for offshore wind power flange and preparation method thereof
Technical Field
The invention belongs to the technical field of ferrous metallurgy, and particularly relates to steel for an offshore wind power flange and a preparation method thereof.
Background
Wind power generation is the most mature power generation mode with the best scale development conditions and commercial development prospects in the renewable energy field, and has become the second largest power source of thermal power and hydropower. Offshore wind power generation is used as an important component of wind power generation, and has become an important means for changing the national energy structure and realizing green and low-carbon development in recent years due to the advantages of abundant wind resources, stable wind source, larger wind speed than on the land, stable signal leading direction, small annual utilization time, no land resource occupation, proximity to coastal power load centers and the like. Meanwhile, under the support of wind power equipment manufacturing technology and national industrial policies, domestic offshore wind power generation is rapidly developed, in 2020, the newly added capacity of domestic wind power generation is 3.06GW, and the accumulated installed capacity is 12.05 GW.
The service life of the offshore wind power generation equipment can reach more than 50 years in severe environments such as typhoon on the sea surface, severe cold and freezing, seawater splashing and high salt fog and the like, the unit is large as the universal capacity of a single offshore wind power generator is developed from 1-2MW to 5-8MW at present, and the quality and the performance of the flange, the tower barrel, the wind wheel and other parts used by the offshore wind power generator are strictly improved. The flange has higher requirements on various performances of the offshore wind power flange, such as corrosion resistance, low temperature resistance, strength level, welding performance, lamellar tearing resistance and the like.
Chinese patent CN102517494B discloses a steel material for wind power flanges and a preparation method thereof, and the steel material mainly comprises C: 0.15 to 0.19%, Si 0.17 to 0.35%, Mn: 1.45-1.55%, V: 0.060 to 0.090%, Nb 0.02 to 0.04%, Al: 0.015-0.040%, Ti is less than or equal to 0.005%, O is less than or equal to 0.0015%, N is less than or equal to 0.012%, S is less than or equal to 0.005%, P is less than or equal to 0.012%, As is less than or equal to 0.04%, H is less than or equal to 0.00015%, and the balance is Fe. The carbon equivalent of the steel in the invention is 0.41-0.46%; the tensile strength Rm is 580-720 MPa; the yield strength Rel is 470-500 MPa; elongation A5 is 22-26%; the reduction of area Z is 66-72%; and at the temperature of 20 ℃ below zero, the impact energy Akv of the V-shaped notch is 60-90J. The invention only ensures the impact performance of the material at the temperature of-20 ℃, can not meet the use requirement of offshore wind power at the low temperature of-50 ℃, has the requirement that [ O ] is less than or equal to 0.0015 percent, and is difficult to ensure the excellent cleanliness of steel, thereby reducing the low-temperature performance of the steel.
The Chinese patent application CN112342459A discloses a low-temperature resistant wind power flange steel and a rolling method thereof, and the provided low-temperature resistant wind power flange steel comprises the following chemical components in percentage by mass: 0.15 to 0.20 percent of C, 0.15 to 0.35 percent of Si, 1.25 to 1.50 percent of Mn, less than or equal to 0.020 percent of P, less than or equal to 0.015 percent of S, less than or equal to 0.020 to 0.050 percent of Al, less than or equal to 0.30 percent of Cr, less than or equal to 0.30 percent of Cu, less than or equal to 0.30 percent of Ni, less than or equal to 2.0ppm of [ H ], lessthan or equal to 20ppm of [ O ], lessthan or equal to 120ppm of [ N ], [ Al/N more than or equal to 2, less than or equal to 0.43 percent of CE, and the balance of Fe and inevitable impurities. The yield strength Rp0.2 of the steel is more than or equal to 360MPa, and the tensile strength is as follows: 512-540 MPa, the elongation A is more than or equal to 30.5%, the Z is more than or equal to 33.0%, and the low-temperature impact toughness meets the following requirements (50 ℃ below zero): the mass is more than or equal to 68J. The steel has low strength and is difficult to meet the use requirement of large offshore wind power; the S is less than or equal to 0.015 percent, and the requirement of the lamellar tearing resistance of the steel cannot be met; the requirement that [ O ] is less than or equal to 20ppm is difficult to ensure the excellent cleanliness of steel. Meanwhile, the method discloses a rolling method, the specification of hot-rolled round steel is regulated to phi 100 mm-phi 200mm, and the steel is not used as steel for large-scale wind power flanges.
In both of the above patents, the corrosion resistance of steel is not required; in the invention, the influence of marine corrosion in the offshore wind power operation environment needs to be fully considered. The invention provides steel for an offshore wind power flange and a preparation method thereof by reasonable component design and process control aiming at service conditions of the offshore wind power flange and excellent performance requirements such as high corrosion resistance, high low temperature resistance, high strength, easy welding performance, high lamellar tearing resistance and the like.
Disclosure of Invention
Aiming at the conditions that the existing steel for the wind power flange is poor in corrosion resistance, poor in low-temperature performance, low in strength, poor in welding performance and lamellar tearing resistance and difficult to meet the use requirement of the offshore wind power flange, one of the purposes of the invention is to provide the steel for the offshore wind power flange, and the steel has excellent performances such as high corrosion resistance, high low-temperature resistance, high strength, easy welding performance and high lamellar tearing resistance.
In order to achieve the purpose, the technical scheme of the invention is as follows:
steel for offshore wind power flange with yield strength R eL Greater than or equal to 460MPa, tensile strength R m : the elongation A after fracture of 530-680MPa is more than or equal to 25 percent, the performance in the thickness direction is Z35 level, and the low-temperature impact absorption energy KV is below-60 DEG C 2 The mass is more than or equal to 50J. To meet the above performance index requirements, the following aspects are emphasizedMaking a scheme:
1. the steel for the offshore wind power flange comprises the following chemical components in percentage by mass: c: 0.05 to 0.08%, Si: 0.30 to 0.50%, Mn: 0.50-0.80%, P: less than or equal to 0.012%, S: less than or equal to 0.003 percent, Cr: 1.20 to 1.40%, Cu: 0.10 to 0.30%, Ni 0.05 to 0.20%, V: 0.040 to 0.060%, Nb: 0.010-0.030%, N: 0.0120-0.0180%, RE: 0.0010-0.0030%, As: less than or equal to 0.015%, Sn: less than or equal to 0.015%, Pb: less than or equal to 0.0025%, Sb: less than or equal to 0.0025%, Bi: less than or equal to 0.0025 percent, (As + Sn + Pb + Sb + Bi): less than or equal to 0.025 percent, less than or equal to 0.0012 percent of [ O ], and the balance of Fe and inevitable impurities.
The carbon equivalent CEV of the steel for the offshore wind power flange is equal to C + Mn/6+ (Cr + Mo + V)/5+ (Ni + Cu)/15 and is less than or equal to 0.47 percent; the crack sensitivity coefficient Pcm is equal to or less than 0.22 percent of C + Si/30+ Mn/20+ Cu/20+ Ni/60+ Cr/20+ Mo/15+ V/10+ 5B; corrosion resistance index I ═ 26.01 (% Cu) +3.88 (% Ni) +1.20 (% Cr) +1.49 (% Si) +17.28 (% P) -7.29 (% Cu) (% Ni) -9.10 (% Ni) (% P) -33.39 (% Cu) 2 ≥6.0。
The design principle of each chemical element of the steel for the offshore wind power flange is that the steel is combined with the requirements of comprehensive properties such as high corrosion resistance, high low temperature resistance, high strength, easy welding performance, high lamellar tearing resistance and the like, the corrosion resistance of the steel is improved mainly by compounding low carbon, high chromium and copper-nickel, the strength of the steel is improved by microalloying the vanadium, niobium and nitrogen, and the RE rare earth element is used for purifying, modifying and microalloying molten steel to ensure the excellent corrosion resistance, low temperature resistance and toughness of the steel; meanwhile, the contents of harmful elements such as phosphorus, sulfur, arsenic, tin, lead, antimony, bismuth, oxygen and the like are strictly controlled, so that the corrosion resistance and the lamellar tearing resistance of the steel are improved; the content of each alloy element is finely adjusted, and the requirements of carbon equivalent, crack sensitivity coefficient and corrosion resistance coefficient are met, so that the good welding performance and corrosion resistance of the steel are guaranteed. The design principle analysis of each element is as follows:
carbon: the element C is an indispensable element in steel materials, so that the corrosion resistance and low-temperature resistance of steel are important to be considered, and meanwhile, the continuous casting production difficulty is reduced in order to avoid the scope of peritectic steel (the content of C is 0.08-0.17%), so that the content of the element C is limited to 0.080%; in order to ensure certain strength of steel and difficulty of electric furnace steelmaking decarburization, the lower limit of the content of the C element is positioned at 0.050%.
Silicon: si is a main deoxidizer in the steelmaking process, and when the Si is used as an alloy element, the Si exists in a solid solution state in ferrite or austenite, so that the yield strength and the tensile strength of steel can be remarkably improved, and therefore, the lower limit of the content of the Si is 0.30%; however, the poor heat conductivity of Si element causes a large temperature difference between the core and the surface of the ingot, which makes it easy to cause forging cracks, and promotes decarburization of the steel surface, thereby deteriorating the surface quality of the forged part, so that the Si element content is limited to 0.50%.
Manganese: mn is a common element in steel materials, and when the content of Mn is less than 0.80%, the strength of steel can be better improved, the toughness of the steel is not reduced, and the welding performance of the steel is not deteriorated, so the upper limit of the content of Mn is limited to 0.80%; however, when the Mn element content is less than 0.50%, the stable austenite structure is insufficient, and the corrosion resistance of the steel material is lowered, so the lower limit of the Mn element content is set to 0.50%.
Chromium: in marine environment, the surface of the steel can be formed by Fe due to the existence of Cr element 3 O 4 FeOOH and Cr 2 O 3 The oxidizing protective film can prevent Cl - And SO 4 2- When corrosive anions in the marine environment permeate into the steel, the marine corrosion resistance of the steel can be improved, and the strength of the steel can be improved better, so that the lower limit of the content of the Cr element is 1.20%; however, since too high Cr content seriously affects the weldability and toughness of the steel, the Cr content is limited to 1.80%.
Copper, nickel: cu is one of the elements which can effectively improve the corrosion resistance of steel, but the melting point of Cu is 1085 ℃, so that surface quality defects such as surface microcracks, warping and the like are easily caused by copper brittleness in the continuous casting and subsequent forging processing processes, and the corrosion resistance of steel is not facilitated. And a certain amount of Ni is added to form a Cu-Ni binary alloy phase with high melting point with copper, so that the phenomenon of copper brittleness can be avoided. Comprehensively considering the problems of production control difficulty and production cost, controlling the content range of Cu element to be 0.10-0.30% and the content range of Ni element to be 0.05-0.15%; and simultaneously controlling the mass ratio of Ni to Cu to be not less than 0.5.
Vanadium, niobium, nitrogen: v, Nb is a microalloying element which can obviously improve the strength of steel, Nb is mainly used for fine crystal, V is mainly used for precipitation strengthening, and the composite effect of the two elements is far higher than that of a single element. When the content of Nb in steel is low, the yield strength of the steel is increased rapidly and is in proportion to the content, and when the content of Nb reaches 0.030%, the strengthening effect begins to be reduced, so that the content range of Nb is controlled to be 0.010% -0.030% for best exerting the strengthening effect of Nb element. The precipitation strengthening effect of the V element is mainly that a V (C, N) compound is formed by the V element and C, N element and is separated out from ferrite of an austenite crystal boundary to achieve the strengthening effect, so a certain N content must be ensured in steel; according to the strength requirement of the steel, the content range of the V element is controlled to be 0.040-0.060%, and the content range of the N element is controlled to be 0.0120-0.0180%.
Rare earth: RE rare earth elements have the functions of purifying molten steel, modifying inclusions and microalloying in steel, and can well improve the corrosion resistance, low temperature resistance and toughness of steel. When the RE content is lower than 0.0010%, the RE mainly plays a role in purifying molten steel, and the microalloying effect is poor; when the RE content is higher than 0.0030 percent, the RE is easy to oxidize in the continuous casting process, and oxides are easy to block a water gap to influence the smooth running of continuous casting production; therefore, the content range of RE is controlled to be 0.0010-0.0030 percent.
Phosphorus: p element in the steel is easy to accumulate at grain boundaries to cause grain boundary brittle fracture, so that the low-temperature impact performance of the steel is rapidly deteriorated, and the lower the P element is, the better the P element is; however, the content of P element is limited to 0.012% because of difficulty in dephosphorization in the electric furnace smelting process and cost increase.
Sulfur: the S element is a harmful element in steel, is easy to form nonmetallic inclusions such as MnS, FeS and the like, causes hot brittleness, deteriorates corrosion resistance and lamellar tearing resistance of steel, and simultaneously considers the requirements of a desulphurization process and production cost in an LF refining process in an electric furnace flow, and limits the content of the S element to 0.003%.
Five harmful elements: five harmful elements in steel refer to arsenic, tin, lead, antimony and bismuth, and the oxidation sites of the five elements are lower than that of iron, so that the five elements cannot be removed in the smelting process and are continuously accumulated in steel. The five-harmful elements are harmful to the low temperature resistance and the corrosion resistance of the steel, so the content of the five-harmful elements is reduced as much as possible; by combining the conditions of smelting raw materials and controlling the production cost, the upper limit of the content of As and Sn is required to be 0.015 percent, the upper limit of the content of Pb, Sb and Bi is required to be 0.0025 percent, and the upper limit of the total amount of harmful elements is required to be 0.025 percent.
Oxygen: in order to avoid formation of large-particle oxide inclusions in the steel and deterioration of the corrosion resistance, low-temperature resistance, and the like of the steel, the upper limit of the O content is required to be 0.0012%.
The preferable steel comprises the following chemical components in percentage by mass: c: 0.06-0.07%, Si: 0.40 to 0.48%, Mn: 0.55-0.65%, P: less than or equal to 0.011 percent, S: less than or equal to 0.003 percent, Cr: 1.30-1.40%, Cu: 0.15 to 0.25%, Ni 0.08 to 0.15%, V: 0.040 to 0.060%, Nb: 0.020-0.030%, N: 0.0140-0.0170%, RE: 0.0010 to 0.0030%, As: less than or equal to 0.015 percent, Sn: less than or equal to 0.015%, Pb: less than or equal to 0.0025%, Sb: less than or equal to 0.0025 percent, Bi: less than or equal to 0.0025 percent, (As + Sn + Pb + Sb + Bi): less than or equal to 0.025 percent, less than or equal to 0.0012 percent of [ O ], and the balance of Fe and inevitable impurities.
The preferable control range of the carbon equivalent CEV is 0.43-0.47%, and the crack sensitivity coefficient Pcm is less than or equal to 0.20%.
2. The preparation method of the steel for the offshore wind power flange mainly comprises the following steps: electric furnace smelting, LF refining, VD vacuum treatment and continuous casting. The specific process steps comprise:
(1) electric furnace smelting: the raw materials of the furnace are molten iron and scrap steel, wherein As in the molten iron is less than or equal to 0.010 percent, the scrap steel adopts self-circulation scrap steel of low alloy series and high carbon series, and the scrap steel with high Ti, slag steel, ladle wall iron and other high P, S scrap steel cannot be used; electric furnace tapping terminal [ C ]: 0.02-0.04%, and [ P ] is less than or equal to 0.007%, and the tapping temperature of molten steel is controlled to be 1640-1680 ℃; adding metal manganese, micro-carbon ferrochromium, silicomanganese and ferrosilicon to carry out steel ladle alloying, so that Si is controlled to be 0.15-0.30%, Mn is controlled to be 0.40-0.50%, and Cr is controlled to be 0.40-0.50%.
(2) LF refining + VD vacuum treatment: controlling the alkalinity of refining slag of the LF furnace to be 3.2-3.5, and adopting a process of strong deoxidation and desulfurization with large slag amount and aluminum wire feeding; adding metal manganese, micro-carbon ferrochrome, nickel plates, ferrosilicon, copper particles, ferrochrome nitride, ferrovanadium and ferroniobium alloy for fine adjustment of alloy components, and controlling C, Si, Mn, P, S, Cr, Ni, Cu, Nb and V to meet component requirements. After arriving at a VD station, adding rare earth alloy by adopting a wire feeding process, keeping the vacuum degree of less than 67Pa for more than or equal to 15 minutes; and after the air is broken, sampling and inspecting molten steel components, properly feeding rare earth alloy and blowing nitrogen in combination with the inspection results of the rare earth content and the nitrogen content, so that RE and N meet the component requirements.
(3) Continuous casting: the superheat degree of the tundish is controlled to be 20-25 ℃, namely the temperature of molten steel in the tundish is controlled to be 1540-1545 ℃; the special continuous casting covering slag for low-carbon steel is adopted, the alkalinity is 1.10-1.20, the viscosity is 0.30-0.50 Pa.s, and the melting temperature is 1050-1090 ℃; controlling the electromagnetic stirring current of the crystallizer to be 350-400A, controlling the frequency to be 2.5-3.. 5HZ, controlling the electromagnetic stirring current at the tail end to be 50-80A, and controlling the frequency to be 1.0-1.2 HZ; the blank shape is phi 800mm, and the pulling speed is 0.16-0.18 m/min.
The process conditions not limited in the above preparation method can be referred to the conventional techniques in the art.
Detailed Description
The specific embodiments of the present invention are further described in conjunction with examples 1-3.
Examples 1-3 production procedure control parameters are shown in Table 1; the LF refining tapping and the chemical components of the finished product are shown in a table 2; the content of harmful elements, the carbon equivalent CEV, the crack sensitivity coefficient Pcm and the corrosion resistance coefficient I of the finished product are shown in a table 3.
According to the continuous casting round billet produced in the embodiment 1-3, the mechanical property test result of the wind power flange forging produced by adopting the normal wind power flange production process, namely blanking → heating furnace heating → blank making → secondary heating → rolling ring → stacking slow cooling → rough machining → heat treatment → fine machining → flaw detection → finished product, is shown in table 4, wherein 2 samples are taken for tensile property and thickness direction property, and 3 samples are taken for impact property test.
Table 1 examples 1-3 production run control parameters
Figure BDA0003274645890000061
Figure BDA0003274645890000071
TABLE 2 LF refining tapping and finished product chemistry (%)
Figure BDA0003274645890000072
TABLE 3 content (%) of harmful elements, CEV (%), Pcm (%), I values
Figure BDA0003274645890000073
TABLE 4 mechanical properties of wind power flange forgings
Figure BDA0003274645890000074
The method can be realized by upper and lower limit values and interval values of intervals of process parameters (such as temperature, time and the like), and embodiments are not listed.
Conventional technical knowledge in the art can be used for the details which are not described in the present invention.
Finally, it should be noted that the above embodiments are only used for illustrating the technical solutions of the present invention and are not limited. Although the present invention has been described in detail with reference to the embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted without departing from the spirit and scope of the invention as defined in the appended claims.

Claims (3)

1. Offshore wind power methodThe steel for the flange is characterized by having the yield strength R eL Not less than 460MPa, tensile strength R m : 530-680MPa, elongation A after fracture of more than or equal to 20 percent, performance in the thickness direction of Z35 level, and low-temperature impact absorption energy KV at-60 DEG C 2 The mass percentage of the alloy is more than or equal to 50J, and the alloy comprises the following components in percentage by mass:
c: 0.05 to 0.08%, Si: 0.30 to 0.50%, Mn: 0.50-0.80%, P: less than or equal to 0.012%, S: less than or equal to 0.003 percent, Cr: 1.20 to 1.40%, Cu: 0.10 to 0.30%, Ni 0.05 to 0.20%, V: 0.040 to 0.060%, Nb: 0.010-0.030%, N: 0.0120-0.0180%, RE: 0.0010 to 0.0030%, As: less than or equal to 0.015 percent, Sn: less than or equal to 0.015%, Pb: less than or equal to 0.0025%, Sb: less than or equal to 0.0025%, Bi: less than or equal to 0.0025 percent, (As + Sn + Pb + Sb + Bi): less than or equal to 0.025 percent, less than or equal to 0.0012 percent of [ O ], and the balance of Fe and inevitable impurities;
the carbon equivalent CEV of the steel for the offshore wind power flange is equal to C + Mn/6+ (Cr + Mo + V)/5+ (Ni + Cu)/15 and is less than or equal to 0.47 percent; the crack sensitivity coefficient Pcm is equal to or less than 0.22 percent of C + Si/30+ Mn/20+ Cu/20+ Ni/60+ Cr/20+ Mo/15+ V/10+ 5B; corrosion resistance index I ═ 26.01 (% Cu) +3.88 (% Ni) +1.20 (% Cr) +1.49 (% Si) +17.28 (% P) -7.29 (% Cu) (% Ni) -9.10 (% Ni) (% P) -33.39 (% Cu) 2 ≥6.0;
The preparation method of the steel for the offshore wind power flange comprises the following steps:
1) electric furnace smelting
The raw materials of the furnace are molten iron and scrap steel, As in the molten iron is less than or equal to 0.010 percent, and the tapping end point [ C ] of the electric furnace: 0.02-0.04%, and [ P ] is less than or equal to 0.007%, and the tapping temperature of molten steel is controlled at 1640-1680 ℃; adding manganese metal, micro-carbon ferrochromium, silicomanganese and ferrosilicon to perform ladle alloying, wherein Si is controlled to be 0.15-0.30%, Mn is controlled to be 0.40-0.50%, and Cr is controlled to be 0.40-0.50%;
2) LF refining + VD vacuum treatment
Controlling the alkalinity of refining slag of the LF furnace to be 3.2-3.5, and adopting a process of strong deoxidation and desulfurization with large slag amount and aluminum wire feeding; adding metal manganese, micro-carbon ferrochrome, nickel plates, ferrosilicon, copper particles, ferrochrome nitride, ferrovanadium and ferroniobium to carry out alloy component fine adjustment, and controlling C, Si, Mn, P, S, Cr, Ni, Cu, Nb and V to meet component requirements; after arriving at a VD station, adding rare earth alloy by adopting a wire feeding process, wherein the vacuum degree is less than 67Pa, and the holding time is more than or equal to 15 minutes; after the air is broken, sampling and inspecting molten steel components, properly feeding rare earth alloy and blowing nitrogen in combination with the inspection results of rare earth content and nitrogen content, so that RE and N meet the component requirements;
3) continuous casting
The superheat degree of the tundish is controlled to be 20-25 ℃, namely the temperature of molten steel in the tundish is controlled to be 1540-1545 ℃; the special continuous casting covering slag for low-carbon steel is adopted, the alkalinity is 1.10-1.20, the viscosity is 0.30-0.50 Pa.s, and the melting temperature is 1050-1090 ℃; controlling the electromagnetic stirring current of the crystallizer to be 350-400A, controlling the frequency to be 2.5-3.5 Hz, controlling the electromagnetic stirring current at the tail end to be 50-80A, and controlling the frequency to be 1.0-1.2 HZ; the blank shape is phi 800mm, and the drawing speed is 0.16-0.18 m/min.
2. The steel for offshore wind power flanges according to claim 1, characterized by comprising the following components in percentage by mass:
c: 0.06-0.07%, Si: 0.40-0.48%, Mn: 0.55-0.65%, P: less than or equal to 0.011 percent, S: less than or equal to 0.003 percent, Cr: 1.30-1.40%, Cu: 0.15 to 0.25%, Ni 0.08 to 0.15%, V: 0.040 to 0.060%, Nb: 0.020-0.030%, N: 0.0140-0.0170%, RE: 0.0010-0.0030%, As: less than or equal to 0.015%, Sn: less than or equal to 0.015%, Pb: less than or equal to 0.0025 percent, Sb: less than or equal to 0.0025%, Bi: less than or equal to 0.0025 percent, (As + Sn + Pb + Sb + Bi): less than or equal to 0.025 percent, less than or equal to 0.0012 percent of [ O ], and the balance of Fe and inevitable impurities;
the control range of the carbon equivalent CEV of the steel for the offshore wind power flange is 0.43-0.47%, the crack sensitivity coefficient Pcm is less than or equal to 0.20%, and the corrosion resistance index I is greater than or equal to 6.0.
3. The steel for offshore wind power flanges according to claim 1, wherein the scrap steel is low alloy series self-circulation scrap steel and/or carbon-rich series self-circulation scrap steel.
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