CN112277311A - 3D printing method and application of negative Poisson ratio honeycomb type composite energy-absorbing material - Google Patents

3D printing method and application of negative Poisson ratio honeycomb type composite energy-absorbing material Download PDF

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CN112277311A
CN112277311A CN201911243374.5A CN201911243374A CN112277311A CN 112277311 A CN112277311 A CN 112277311A CN 201911243374 A CN201911243374 A CN 201911243374A CN 112277311 A CN112277311 A CN 112277311A
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negative poisson
printing
hexagonal
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honeycomb
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张雪霞
严鹏飞
严彪
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Tongji University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/106Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/112Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/30Auxiliary operations or equipment
    • B29C64/386Data acquisition or data processing for additive manufacturing
    • B29C64/393Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y50/00Data acquisition or data processing for additive manufacturing
    • B33Y50/02Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y80/00Products made by additive manufacturing
    • GPHYSICS
    • G10MUSICAL INSTRUMENTS; ACOUSTICS
    • G10KSOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
    • G10K11/00Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/16Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/162Selection of materials

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  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
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Abstract

The invention relates to a 3D printing method of a negative Poisson ratio-honeycomb type composite energy absorption material, which comprises the following steps of: the basic layer structure setting process comprises the steps of setting an inflected hexagonal negative Poisson ratio area and a honeycomb structure area in each layer in a printing model, wherein the inflected hexagonal negative Poisson ratio area is provided with inflected hexagonal hollowed-out repeating units which are arranged in rows, and an included angle alpha between two adjacent inner folds is 225-plus-one 245 degrees, the honeycomb structure area is provided with hexagonal hollowed-out repeating units which are arranged in rows, and the included angle alpha between two adjacent side edges is 115-plus-one 135 degrees; a printer setting process; in the printing material selection process, the printing material is selected from nylon or PC high-molecular printing silk; and (4) printing. Compared with the prior art, the negative Poisson's ratio-honeycomb type two structures are compounded together, and the composite energy-absorbing material such as nylon or PC is applied to the performance improvement of the honeycomb structure material, so that the energy-absorbing performance of the existing honeycomb material is remarkably improved.

Description

3D printing method and application of negative Poisson ratio honeycomb type composite energy-absorbing material
Technical Field
The invention relates to the technical field of 3D printing, in particular to a 3D printing method and application of a negative Poisson's ratio-honeycomb type composite energy-absorbing material.
Background
The honeycomb structure material has many excellent performances, and from the analysis of mechanics, the best mechanical property can be obtained with the least material compared with other structures in a closed hexagonal equilateral honeycomb structure, and when the honeycomb structure plate is subjected to a load perpendicular to the plate surface, the bending rigidity of the honeycomb structure plate is almost the same as that of a solid plate made of the same material and having the same thickness, even higher, but the weight of the honeycomb structure plate is 70-90% lighter, and the honeycomb structure plate is not easy to deform and break, and has the advantages of shock absorption, sound insulation, heat insulation and the like.
The two materials are produced by simple preparation methods such as die pressing in the current preparation process, the material has high production cost and low product yield due to the structural particularity of the honeycomb gaps, and a large-scale special die needs to be designed in the die pressing process, but the difficulty of the material in the die opening process is high. In addition, the honeycomb structure material has the defect of insufficient rigidity in practical engineering application, but a new rigid structure unit needs to be added into the existing honeycomb structure material to improve the defect, and the development and production of a new structure are limited by the design of a mold and cannot be realized.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a 3D printing method and application of a negative Poisson ratio honeycomb type short fiber composite high-strength material, which breaks through the limitation of die design on further structural improvement of a honeycomb structure material in the prior art, in the invention, the negative Poisson ratio-honeycomb type composite energy absorption structure is formed by directly applying the short fiber composite high-strength material such as nylon or PC and the like to the performance improvement of the honeycomb structure material, wherein the composite structure is a three-dimensional structure obtained by plane two-dimensional stretching and is a laminated composite structure of an inward-folded hexagonal negative Poisson ratio structure and a honeycomb structure, and the structure mainly comprises 4 characteristics: the composite material has a honeycomb structure area, an inflected hexagonal negative Poisson ratio structure area, a negative Poisson ratio-honeycomb composite structure interface area and a composite mode, and achieves remarkable performance improvement through the design of a process method.
The purpose of the invention can be realized by the following technical scheme:
the 3D printing method of the negative Poisson's ratio-honeycomb type composite energy-absorbing material comprises the following steps:
in the setting process of the base layer structure, an inflected hexagonal negative Poisson ratio area and a honeycomb structure area in each layer are set in a printing model,
the inward folding hexagonal hollow-out repeating units are arranged in rows in the inward folding hexagonal negative Poisson ratio area, each inward folding hexagonal hollow-out unit is in an axisymmetric structure, and the included angle alpha' between two adjacent inward folding edges is 225-.
Wherein the honeycomb structure area is provided with hexagonal hollowed-out repeating units which are arranged in rows, each hexagonal hollowed-out unit is of an axisymmetric structure, and the included angle alpha between two adjacent side edges is 115-135 degrees;
setting a printer, wherein the thickness of a printing layer is set to be 0.1-0.4mm, the aperture of a nozzle is set to be 0.4-0.8mm, the printing temperature is 235-260 ℃, and the temperature of a hot bed is 80-110 ℃;
in the printing material selection process, the printing material is selected from nylon or PC high-molecular printing silk; the design of a slightly larger angle alpha and the selection of materials of nylon or PC are the basis of the high energy absorption design of the structure, the slightly larger angle alpha increases the buffer stroke of the whole structure, but the rigidity and the impact strength of the whole structure are influenced by overlarge angle alpha, and the angle alpha is selected to be 115-plus 135 degrees in the invention, so that the buffer and energy absorption performance of the structure is ensured to be increased as much as possible on the premise of having sufficient rigidity and impact strength.
And in the printing process, the base material is taken as an XY plane, and the printing is carried out layer by layer in the Z direction, so that the negative Poisson's ratio-honeycomb type composite energy-absorbing material is obtained.
Further, in the setting process of the base layer structure, the inflected hexagonal negative poisson's ratio region comprises 2 or more rows of inflected hexagonal hollowed-out repeating units;
the honeycomb structure area comprises 2 or more rows of inward-folded hexagonal hollowed-out repeating units; at least two layers of corresponding layered monomers are arranged in the honeycomb structural area and the inflected hexagonal negative Poisson ratio structural area to exert respective effects.
The inflected hexagonal negative Poisson ratio areas and the honeycomb structural areas are alternately arranged.
Furthermore, the included angle α '+ α is 360 °, and the lengths of the two inner folded edges of the inner folded hexagonal hollow unit are both b';
the lengths of two adjacent side edges in the hexagonal hollow-out unit are both b, and b' is b.
Furthermore, the distance between the inward-folding angle end points in the inward-folding hexagonal hollow units is a';
the length of the bottom edge in the inflected hexagonal hollow unit is a, and a is 4-6 mm.
Further, the length of the bottom edge in the inward-folded hexagonal hollowed-out unit is c';
the maximum width of the inflected hexagonal hollow unit is c, and c' is 6-9 mm.
Furthermore, in the setting process of the base layer structure, the adjacent inflected hexagonal negative Poisson ratio areas and the honeycomb structure areas are mutually arranged in a slot manner.
Further, the bottom edges of the hexagonal hollow units are aligned with the side folding recesses of the inward-folded hexagonal hollow units in the mutual slot arrangement process. The two layers of monomers can be naturally transited to form a zero-thickness zigzag section.
Further, the bordering end plate layer is characterized in that: if the honeycomb hexagon is adjacent to the end plate layer, the period is continued for a half, namely a vertical edge with the length close to a/2 is extended, preferably (0.85-1.12) multiplied by a/2, as shown by a thick edge at the upper part of the figures 1 and 2; for example, the inner folded hexagon is connected with the end plate layer, and the half period is also continued, namely, a vertical edge with the length close to c '/2, preferably (0.88-1.17) multiplied by c'/2, is extended, as shown by a thick edge at the lower part of the figures 1 and 2. Thus, the energy absorption effect of the respective structures can be better exerted.
Further, in the setting process of the base layer structure, the edge width t is set to be 0.8-1.5 mm.
Furthermore, the diameter of the spinning jet in the printing process is 1.75-3.0mm, and the printing speed is 40-60 mm/s.
Further, the printing temperature is set to 200-230 ℃ in the printing process, which is a suitable range, so that bubbles mixed in the extruded fuse wire due to over-high temperature can be avoided, the phenomena of material collapse and wire drawing and wrinkling on the surface of the product are avoided, and the phenomena of nozzle blockage or interlayer peeling, cracking, warping, deformation and the like caused by insufficient temperature are also avoided in the range.
Further, the layer thickness refers to the distance between layers when the three-dimensional data model is sliced by using slicing software, namely, when the layer thickness of each layer during printing is smaller than the range of 0.1-0.4mm, the layer thickness is more appropriate, and better precision and higher processing efficiency can be ensured.
Further, during printing, the cross-sectional direction shown in fig. 1 and 2 is parallel to the base plate (i.e., XY plane), and the stretching direction is the Z-axis direction. The surface profile accuracy and surface roughness quality perpendicular to the Z-direction is high due to the weak strength in the vertical direction (Z-direction). Therefore, during the molding process, it is preferable to mold the cross section where the energy absorption shrinkage mainly occurs along the XY plane to ensure the quality of the product in an optimum state.
The negative Poisson's ratio-honeycomb type composite energy-absorbing material obtained by the preparation method disclosed by the invention has wide application in compression/impact resistant materials.
When the negative Poisson ratio-honeycomb type composite energy-absorbing material prepared by the invention is subjected to external pressure, the honeycomb structure firstly generates yield deformation, and the negative Poisson ratio structure also generates yield deformation along with the increase of the force. Secondly, the honeycomb structure area is relatively flexible and bears the function of large deformation energy absorption; and the inflected hexagonal negative Poisson ratio structural region has stronger structural rigidity due to larger deformation-resistant internal force and bears a relatively rigid impact-resistant function.
Compared with the prior art, the invention has the following advantages:
1) the invention combines the two structures of negative Poisson's ratio and honeycomb type together, and applies short fiber composite high-strength material such as nylon or PC and the like to the performance improvement of the honeycomb structure material, thereby realizing the ' stiffness and softness ' of the energy-absorbing structure, realizing the buffering efficiency more efficiently, remarkably improving the performance of the existing honeycomb material, and expanding the application of the material in the existing engineering technology.
2) According to the invention, the production and preparation of the negative Poisson ratio honeycomb type short fiber composite high-strength material are realized by adopting a 3D printing process method, the layer-by-layer incremental production of two complicated configuration materials is realized, the utilization rate of raw materials is 100%, and the large-batch industrial popularization can be realized.
Drawings
FIG. 1 is a diagram of an alternate arrangement of honeycomb structural regions and inflected hexagonal negative Poisson's ratio structural regions;
FIG. 2 is a diagram of an alternative arrangement of honeycomb structural regions and inflected hexagonal negative Poisson's ratio structural regions;
FIG. 3 is a schematic structural view of the folded hexagonal hollow unit;
FIG. 4 is a schematic structural diagram of a hexagonal hollow unit;
fig. 5 is a schematic structural diagram of a finished product of a negative poisson ratio honeycomb type short fiber composite high-strength material.
Detailed Description
The invention is described in detail below with reference to the figures and specific embodiments.
Example 1
The 3D printing method of the negative Poisson's ratio-honeycomb type composite energy-absorbing material in the embodiment comprises the following steps:
infrastructure setup process: and arranging an inflected hexagonal negative Poisson ratio region and a honeycomb structure region in each layer in the printing model, wherein inflected hexagonal hollowed-out repeating units which are arranged in rows are arranged in the inflected hexagonal negative Poisson ratio region. The inflected hexagonal negative Poisson ratio region comprises 2 or more rows of inflected hexagonal hollowed-out repeating units; the honeycomb structure area comprises 2 or more rows of inward-folded hexagonal hollowed-out repeating units; at least two layers of corresponding layered monomers are arranged in the honeycomb structural area and the inflected hexagonal negative Poisson ratio structural area to exert respective effects. The inflected hexagonal negative Poisson ratio areas and the honeycomb structural areas are alternately arranged. In the setting process of the base layer structure, the adjacent inflected hexagonal negative Poisson ratio areas and the honeycomb structure areas are mutually arranged in a slot way. The bottom edges of the hexagonal hollow units are rightly aligned with the side folding sunken parts of the inward folding hexagonal hollow units in the mutual slot arrangement process. The two layers of monomers can be naturally transited to form a zero-thickness zigzag section.
The specific size and structure design process: referring to fig. 3 and 4, each inward-folded hexagonal hollow unit is of an axisymmetric structure, and an included angle α' between two adjacent inward-folded edges is 225-. The included angle alpha '+ alpha is 360 degrees, the length of two inner folding edges of the inner folding hexagonal hollow unit is equal to b, the length of two adjacent side edges in the hexagonal hollow unit is equal to b, and b' is equal to b. The distance between the inward-folding angle end points in the inward-folding hexagonal hollow units is a'. The length of the bottom edge in the inflected hexagonal hollow unit is a, and a is a'. The length of base is c' among the infolding hexagon fretwork unit, and the maximum width of infolding hexagon fretwork unit is c, and c ═ c. The characteristics of the soil-covered end plate layer are as follows: if the honeycomb hexagon is adjacent to the end plate layer, the period is continued for a half, namely a vertical edge with the length close to a/2 is extended, preferably (0.85-1.12) multiplied by a/2, as shown by a thick edge at the upper part of the figures 1 and 2; for example, the inner folded hexagon is connected with the end plate layer, and the half period is also continued, namely, a vertical edge with the length close to c '/2, preferably (0.88-1.17) multiplied by c'/2, is extended, as shown by a thick edge at the lower part of the figures 1 and 2. Thus, the energy absorption effect of the respective structures can be better exerted.
The thickness of the printing layer is set to be 0.1-0.4mm, the aperture of the nozzle is set to be 0.4-0.8mm, the printing temperature is 235-260 ℃, and the temperature of the hot bed is 80-110 ℃. The printing temperature is set to be 235-260 ℃ in the printing process, which is a suitable range, so that bubbles mixed in extruded fuses due to overhigh temperature can be avoided, the phenomena of material collapse and wire drawing and wrinkling on the surface of a product are avoided, and the phenomena of nozzle blockage or interlayer stripping, cracking, warping, deformation and the like due to insufficient temperature are also avoided in the range. The layer thickness refers to the distance between layers when slicing is carried out on the three-dimensional data model by using slicing software, namely, when the thickness of each layer is smaller than the range of 0.1-0.4mm during printing, the thickness is more appropriate, and better precision and higher processing efficiency can be ensured.
And in the printing material selection process, the printing material is selected from nylon or PC high-molecular printing silk. In the printing process, the base material is used as an XY plane, and the printing is carried out layer by layer in the Z direction, so that the negative Poisson's ratio-honeycomb type composite energy-absorbing material is obtained. In the setting process of the base layer structure, the edge width t is set to be 0.8-1.5 mm. The diameter of the spinning jet in the printing process is 1.75mm, and the printing speed is 40-60 mm/s. During printing, the cross-sectional direction shown in fig. 1 and 2 is parallel to the base plate (i.e., XY plane), and the stretching direction is the Z-axis direction. The surface profile accuracy and surface roughness quality perpendicular to the Z-direction is high due to the weak strength in the vertical direction (Z-direction). Therefore, during the molding process, it is preferable to mold the cross section where the energy absorption shrinkage mainly occurs along the XY plane to ensure the quality of the product in an optimum state.
Carrying out primary processing according to the implementation steps:
the material is as follows: nylon
The composite structure has two monomer size parameters of a ═ a ', i.e. c ═ c', wherein the size range of a ═ 4mm, c ═ 8mm, and the included angle between two adjacent side walls is 125 °. The edge width/wall thickness t is 1.0mm, see fig. 5.
Layer thickness: 0.2-0.4mm.
The diameter of the filament is 1.75mm
Nozzle aperture: 0.4mm
Printing speed: 40-60mm/s
Printing temperature: 235 ℃ and 260 ℃, and the temperature of the hot bed: 60-80 ℃.
Performing compression and impact tests on the structure to obtain a stress-strain curve, wherein the obtained platform stress range is-3.0-3.5 MPa, the platform end strain range is 52-57%, and the specific energy absorption value Es range is 13.2-17.8KJ/m3And the energy absorption efficiency is 70-78%.
Example 2
The implementation steps are the same as the embodiment, and the difference is that different implementation process parameters are adopted:
the material is as follows: polycarbonate (PC)
The composite structure has two monomer size parameters of a ═ a ', that is, c ═ c', wherein the size range a is 4.25mm, c ═ 8.5mm, and the included angle between two adjacent side walls is α ═ 120 degrees. The edge width/wall thickness t is 1.0mm, see fig. 5.
Layer thickness: 0.2-0.4mm.
The diameter of the filament is 1.75mm
Nozzle aperture: 0.4mm
Printing speed: 40-50mm/s
Printing temperature: 235 ℃ and 260 ℃, and the temperature of the hot bed: 80-110 deg.C
Performing compression and impact tests on the structure to obtain a stress-strain curve, wherein the obtained platform stress range is-5.0-8.0 MPa, the platform end strain range is 53-58%, and the specific energy absorption value Es range is 32.0-35.0KJ/m3. The energy absorption efficiency is 70-75%.
The embodiments described above are described to facilitate an understanding and use of the invention by those skilled in the art. It will be readily apparent to those skilled in the art that various modifications to these embodiments may be made, and the generic principles described herein may be applied to other embodiments without the use of the inventive faculty. Therefore, the present invention is not limited to the above embodiments, and those skilled in the art should make improvements and modifications within the scope of the present invention based on the disclosure of the present invention.

Claims (10)

1. A3D printing method of a negative Poisson ratio-honeycomb type composite energy absorption material is characterized by comprising the following steps:
in the setting process of the base layer structure, an inflected hexagonal negative Poisson ratio area and a honeycomb structure area in each layer are set in a printing model,
wherein the inflected hexagonal hollow repeating units which are arranged in rows are arranged in the inflected hexagonal negative Poisson ratio area, each inflected hexagonal hollow unit is in an axisymmetric structure, the included angle alpha between two adjacent inflected edges is 225 plus 245 degrees,
wherein the honeycomb structure area is provided with hexagonal hollowed-out repeating units which are arranged in rows, each hexagonal hollowed-out unit is of an axisymmetric structure, and the included angle alpha between two adjacent side edges is 115-135 degrees;
setting a printer, wherein the thickness of a printing layer is set to be 0.1-0.4mm, the aperture of a nozzle is set to be 0.4-0.8mm, the printing temperature is 235-260 ℃, and the temperature of a hot bed is 80-110 ℃;
in the printing material selection process, the printing material is selected from nylon or PC high-molecular printing silk;
and in the printing process, the base material is taken as an XY plane, and the printing is carried out layer by layer in the Z direction, so that the negative Poisson's ratio-honeycomb type composite energy-absorbing material is obtained.
2. The 3D printing method of the negative Poisson's ratio-honeycomb type composite energy absorbing material as claimed in claim 1, wherein in the setting process of the base layer structure, the inflected hexagonal negative Poisson's ratio region comprises 2 or more rows of inflected hexagonal hollowed-out repeating units;
the honeycomb structure area comprises 2 or more rows of inward-folded hexagonal hollowed-out repeating units;
the inflected hexagonal negative Poisson ratio areas and the honeycomb structural areas are alternately arranged.
3. The 3D printing method of the negative Poisson's ratio-honeycomb type composite energy absorption material as claimed in claim 2, wherein an included angle α ' + α ═ 360 °, the lengths of two inner folded edges of the inner folded hexagonal hollowed-out unit are both b ';
the lengths of two adjacent side edges in the hexagonal hollow-out unit are both b, and b' is b.
4. The 3D printing method of the negative Poisson's ratio-honeycomb type composite energy absorption material as claimed in claim 3, wherein the distance between the inward-folded angle end points in the inward-folded hexagonal hollowed-out units is a';
the length of the bottom edge in the inflected hexagonal hollow unit is a, and a is 4-6 mm.
5. The 3D printing method of the negative Poisson ratio-honeycomb type composite energy absorption material as claimed in claim 4, wherein the length of the bottom edge in the folded hexagonal hollowed-out unit is c';
the maximum width of the inflected hexagonal hollow unit is c, and c' is 6-9 mm.
6. The 3D printing method of the negative Poisson ratio-honeycomb type composite energy absorption material as claimed in claim 5, wherein in the setting process of the base layer structure, the adjacent inflected hexagonal negative Poisson ratio regions and honeycomb structure regions are mutually arranged in a slot manner.
7. The 3D printing method of the negative Poisson ratio-honeycomb type composite energy absorption material as claimed in claim 6, wherein the bottom edges of the hexagonal hollow units are aligned with the side folding edge recesses of the inward-folded hexagonal hollow units in the mutual slot arrangement process.
8. The 3D printing method of a negative poisson's ratio-honeycomb type composite energy absorbing material as claimed in claim 1, wherein in the setting process of the base layer structure, the side width t is set to be 0.8-1.5 mm.
9. The 3D printing method of the negative Poisson ratio-honeycomb type composite energy absorbing material as claimed in claim 6, wherein the diameter of a spinneret in the printing process is 1.75-3.0mm, and the printing speed is 40-60 mm/s.
10. Use of the negative poisson's ratio-honeycomb type composite energy absorbing material prepared in claim 1 in compression/impact resistant materials.
CN201911243374.5A 2019-12-06 2019-12-06 3D printing method and application of negative Poisson ratio honeycomb type composite energy-absorbing material Pending CN112277311A (en)

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Publication number Priority date Publication date Assignee Title
CN115139512A (en) * 2022-07-26 2022-10-04 西北工业大学 Three-dimensional negative Poisson ratio structure 3D printing method and system
CN115139512B (en) * 2022-07-26 2023-05-02 西北工业大学 Three-dimensional negative poisson ratio structure 3D printing method and system

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