CN111960433A

CN111960433A - CHA type molecular sieve synthesized by using bicyclic group-containing quaternary ammonium onium template agent, and preparation and application of catalyst

Info

Publication number: CN111960433A
Application number: CN202010797165.1A
Authority: CN
Inventors: 王志光; 李小龙; 李进; 王炳春; 柳海涛
Original assignee: China Catalyst New Material Co ltd
Current assignee: China Catalyst New Material Co ltd
Priority date: 2020-08-10
Filing date: 2020-08-10
Publication date: 2020-11-20

Abstract

The invention discloses a CHA type molecular sieve synthesized by using a bicyclic group-containing quaternary ammonium onium template agent, and preparation and application of a catalyst, and belongs to the field of chemical synthesis technology and application thereof. The CHA-type zeolite molecular sieve is synthesized by adopting a composite organic template agent formed by a bicyclic group-containing quaternary ammonium onium compound and alkyl substituted quaternary ammonium base, wherein the molar ratio of the product silicon dioxide to alumina is 5-80, the average grain diameter is less than or equal to 500nm, the total specific surface area is more than or equal to 400m2/g, the total pore volume is more than or equal to 0.20ml/g, and the micropore volume is more than or equal to 0.10 ml/g; the crystal grain diameter size in the (-210) crystal plane direction is 50-160 nm. The molecular sieve of the invention has high hydrothermal stability without large grain diameter, and shows high nitrogen oxide reduction characteristics after high-temperature and high-humidity exposure, particularly shows high nitrogen oxide reduction characteristics in a temperature range of 200-550 ℃.

Description

CHA type molecular sieve synthesized by using bicyclic group-containing quaternary ammonium onium template agent, and preparation and application of catalyst

Technical Field

The invention relates to a CHA type molecular sieve synthesized by using a bicyclic group-containing quaternary ammonium onium template agent, and preparation and application of a catalyst, and belongs to the field of chemical synthesis technology and application thereof.

Background

The silicon-aluminum zeolite molecular sieve is a CHA type topological structure, has a three-dimensional pore structure and orthogonal symmetry, a one-dimensional main channel is formed by double eight-membered rings, the pore size is 0.38nm multiplied by 0.38nm, and the framework density is 14.5. The CHA molecular sieve topological structure is formed by connecting double 6 circular rings (d6r) through 4-membered rings to form a CHA big cage, the crystal face of the d6r faces the CHA big cage, Cu ions can be stabilized in the d6r at high temperature, and the Cu ions are allowed to migrate, so that the CHA molecular sieve has unique physicochemical characteristics of SCR reaction potential. Analysis of dehydrated Cu-SSZ-13 molecular sieves by Rietveld structural refinement in the literature (J.Phys.chem.C 2010,114,1633-²⁺Unique to the face of d6 r. In subsequent studies dehydrated Cu ions ([ CuOH ] located near the 8-membered ring were also confirmed]Presence of a + active site. The SSZ-13 and SSZ-62 molecular sieves are typical CHA-structure silicoaluminophosphate molecular sieves, and are widely used as cracking catalysts, MTO reaction catalysts, nitrogen oxide reduction catalysts, and as nitrogen oxide reduction catalysts using Selective Catalytic Reduction (SCR). The characteristics of the active sites of the molecular sieve frameworks of the Cu-SSZ-13 molecular sieve catalyst in the NH3-SCR reaction have been widely researched, and the active sites of the molecular sieve frameworks of the SSZ-13 molecular sieve are all equivalent, so that the active sites of the molecular sieve frameworks of the SSZ-13 molecular sieve are all equivalentThe catalyst is easier to characterize.

CN201611070989 discloses a molecular sieve material with CHA topology formed by self-assembly of silica tetrahedron and alumina tetrahedron, wherein the Si/Al molar ratio is between 4 and 8, the BET specific surface area is 400 to 800m2/g, and the crystal grain size is 0.8 to 20 μm. In the preparation of the molecular sieve, alkyl ammonium hydroxide and adamantyl ammonium hydroxide are used as double templates, and the molecular sieve can be applied to the technical field of separation of CO2/N2 and N2/O2 mixed gas. Patent CN201780032379 discloses synthesis of CHA-type zeolite with a silica/alumina molar ratio of 10.0 to 55.0 using N, N-trialkyl adamantyl ammonium salt and N, N-trialkyl cyclohexyl ammonium salt as composite templates. In the literature (Microporous and Mesoporous Materials 255(2018)192-199), an SSZ-13 molecular sieve with the particle size of 50-300 nm is synthesized by crystallization at low (95 ℃) and high (210 ℃) temperature sections, has obvious hydrothermal stability and has equivalent catalytic performance in the aspect of ammonia selective catalytic reduction (NH3-SCR) nitrogen oxide (NOx).

The synthesis method of SSZ-13 molecular sieve with CHA structure and the catalytic performance of the SSZ-13 molecular sieve as SCR catalyst are disclosed in many documents above, which shows that the catalyst with good thermal stability and good dispersion of supported metal is preferable, and the conventional method adopts N, N, N-trialkyl-1-adamantyl ammonium salt and alkaline combination thereof as template agent, which is expensive, low in utilization rate and difficult to recycle, and needs template agent with low cost and easy post-treatment to synthesize the silicon-aluminum zeolite molecular sieve with small crystal grain, large specific surface area, large pore volume and good thermal stability.

Disclosure of Invention

The invention aims to provide a CHA type molecular sieve synthesized by using a bicyclic group-containing quaternary ammonium onium template agent and a preparation method of a catalyst, which are used as a catalyst carrier for removing NOx by selective reduction. The present invention relates to removal of nitrogen oxides emitted from internal combustion engines, and provides a nitrogen oxide removal catalyst composed of a silicoaluminophosphate zeolite molecular sieve having a CHA structure, a production method of the catalyst, and a nitrogen oxide removal method in which nitrogen oxides are reacted with at least one of ammonia water, urea, and an organic amine using the catalyst.

The invention aims to solve the technical problem of overcoming the defect that the activity of an SCR catalyst for synthesizing a molecular sieve by using loaded copper is lower at low temperature through a hydrothermal durability test in the prior art, and provides a copper-based SCR catalyst which still has higher activity at low temperature after the hydrothermal durability test and a preparation method thereof.

The invention provides a CHA-type molecular sieve synthesized by using a composite template agent containing bicyclic group quaternary ammonium onium, which is synthesized by mixing a bicyclic group quaternary ammonium compound OSDA1 and alkyl substituted quaternary ammonium base OSDA2, wherein the molar ratio of silica to alumina of the CHA-type molecular sieve is 5-80, the average grain diameter is less than or equal to 500nm, and the total specific surface area (S) is measured by a BET method_BET) Not less than 400m2/g, total pore volume (V)_total) Not less than 0.20ml/g, micropore volume (V)_micro) Not less than 0.10 ml/g; the molecular sieve has at least one XRD diffraction peak in each range of the following table within the range of 4-40 degrees of 2 theta, and has the characteristics of the following table:

relative intensity is intensity relative to peak intensity of 20.40-20.90 [ theta ]

The molecular sieve has a CHA topological structure, the range of the half-value width (FWHM) of a crystal plane of X-ray crystal diffraction (-210) is 0.1-0.2 degrees, and the diameter size of a crystal grain in the crystal plane (-210) direction is 50-160 nm calculated by a Debye-Scherrer formula. After the molecular sieve is treated by saturated steam at the temperature of 600-850 ℃, the four-coordination aluminum accounts for more than or equal to 90 percent of the total aluminum content, and the six-coordination aluminum accounts for less than or equal to 10 percent of the total aluminum content.

The structural formula of the bicyclic group-containing quaternary ammonium onium compound is shown as the formula I:

wherein R1 and R2 are independently selected from methyl or deuterated methyl, C2-C4 straight-chain or branched-chain alkyl; r3 is selected from C1-C5 straight chain or branched chain alkyl; r4 is a bicyclic group, specifically selected from bicyclo [2.2.2]Octane, quinuclidine, indane, decalin, tetralin, naphthalene, quinoline, indole, benzofuran, norbornane, and indanone; x^-A counter anion which is a quaternary ammonium onium ion including any of hydroxide, halide, sulfate, bisulfate, carbonate, bicarbonate, oxalate, phosphate, carboxylate, alkyl-substituted sulfate, carbonate or oxalate;

the alkyl substituted quaternary ammonium hydroxide is any one of tetramethyl ammonium hydroxide, tetraethyl ammonium hydroxide, tetrapropyl ammonium hydroxide or dimethyl diethyl ammonium hydroxide, triethyl methyl ammonium hydroxide and trimethyl hydroxyethyl ammonium hydroxide.

Further, in the above technical solution, the halide includes chloride ion, bromide ion, or iodide ion; carboxylates include formate, acetate, propionate; alkyl substituted sulphate, carbonate or oxalate includes methyl sulphate, ethyl sulphate, methyl carbonate, ethyl carbonate, methyl oxalate or ethyl oxalate.

The pore structure data of the molecular sieve was determined using a Micromeritics ASAP 2460 model static nitrogen adsorption apparatus. And (3) testing conditions are as follows: the sample was placed in a sample handling system and evacuated to 1.33X 10 at 350 deg.C^-2Pa, keeping the temperature and the pressure for 15h, and purifying the sample. Measuring the specific pressure p/p of the purified sample at-196 deg.C under liquid nitrogen₀And (3) obtaining a nitrogen adsorption-desorption isothermal curve according to the adsorption quantity and the desorption quantity of the nitrogen under the condition. Then, the BET total specific surface area (S) is calculated using the BET equation_BET) Calculating the specific surface area (S) of the sample micropore by adopting a t-plot method_micro) And micropore volume (V)_micro) Total pore volume in P/P₀Calculated as adsorption at 0.98: specific surface area of outer pores (S)_exter)＝S_BET–S_micro(ii) a External pore volume (V)_exter)＝V_total-V_micro)。

The invention also provides a synthesis method of the CHA-type molecular sieve, which comprises the following steps:

1) fully dissolving and dispersing zeolite molecular sieve, NaOH and deionized water in the molar ratio of 2-30 of silicon dioxide to aluminum oxide to obtain slurry with the component molar ratio of nNa₂O:nSiO₂:nAl₂O₃:nH₂Aging the product (0.5-2.5) of O and (0.0333-0.5) and (5-20) in a crystallization kettle at 60-120 ℃ for 6-48 hours to obtain silicon-aluminum gel;

2) adding a silicon source, a bicyclic group-containing quaternary ammonium onium compound OSDA1, an alkyl-substituted quaternary ammonium base OSDA2, a metal salt M and deionized water into the silicon-aluminum gel obtained in the step 1), fully and uniformly mixing, supplementing NaOH according to the alkalinity requirement of a system, and enabling the component molar ratio of the mixed slurry to be nNa₂O:nSiO₂:nA1₂O₃:nOSDA1:nOSDA2:nM:nH₂O is (0.05-0.5) 1.0, (0.0125-0.20), (0.01-0.5), (0.05-0.5), (0.01-0.25) and (5-100); adding acid solution to control alkali hydroxyl OH in mixed slurry^-With SiO₂In a molar ratio of nOH-/nSiO₂0.1 to 1.0; adding CHA molecular sieve seed crystal with SiO in the slurry₂And A1₂O₃0.5-15% of the total mass; molar ratio nOSDA1 of bicyclic group-containing quaternary ammonium compound OSDA1 to alkyl-substituted quaternary ammonium base OSDA 2: nOSDA2 (0.5-50): 1;

wherein the CHA molecular sieve seed crystal is a CHA molecular sieve synthesized by adopting N, N, N-trimethyl-1-adamantyl ammonium hydroxide as a template according to the method of an example of a patent US 6709644.

3) Stirring the mixture obtained in the step 2), transferring the mixture into a hydrothermal crystallization reaction kettle, crystallizing for 8-120 hours at the autogenous pressure and the temperature of 125-200 ℃, and filtering, washing, drying and roasting the obtained crystallized product to obtain molecular sieve raw powder;

4) mixing the molecular sieve raw powder obtained in the step 3) with an ammonium salt solution with the concentration of 0.1-5.0 mol/L according to a solid-liquid mass ratio of 1: (5-50) carrying out ion exchange at 60-100 ℃, wherein each time of exchange is 0.5-6 hours, and repeatedly exchanging the obtained filter cake with an ammonium ion solution for 1-3 times until the Na ion content in the molecular sieve sample is lower than 500 ppm; and then filtering and separating out a solid product, repeatedly washing the solid product by using deionized water until the solid product is neutral, drying a filter cake at the temperature of 100-130 ℃ for 12-48 hours, and roasting the filter cake at the temperature of 400-600 ℃ for 2-16 hours to obtain the CHA-type molecular sieve. After the molecular sieve raw powder prepared in the step 3) and the CHA type molecular sieve are treated by saturated steam at 600-850 ℃, the content of tetra-coordinated aluminum in the total aluminum is more than or equal to 90 percent, and the content of hexa-coordinated aluminum in the total aluminum is less than or equal to 10 percent.

The invention adopts²⁷The Al MAS NMR characterization method observed the formation of non-framework aluminum and the reduction of framework aluminum, as well as the discrimination of the coordination state of aluminum. In the zeolite molecular sieve aluminum spectrum, signals between 55 and 65ppm come from framework four-coordinate aluminum, signals at 0ppm come from non-framework six-coordinate aluminum, and resonance peaks of non-framework four-coordinate aluminum and non-framework five-coordinate aluminum belonging to signals about 30 to 45ppm are superposed. For characterizing molecular sieves in the invention²⁷Fitting the peaks of the Al MAS NMR spectrogram into a Gaussian curve by using a generally adopted Gaussian fitting mode, wherein the abscissa position represents the chemical shift of the four-coordinate aluminum, namely the four-coordinate aluminum in different chemical environments; and the corresponding peak areas represent the amount of the corresponding tetracoordinated aluminum. It is composed of²⁷In the Al MAS NMR spectrum, characteristic peaks are all at 55-65ppm, while no characteristic peaks of hexacoordinated aluminum are present at 0ppm, which indicates that the coordination of Al exists in a four-coordinate form, Al is connected with four surrounding Si through O, and no connection of Al with Al through O (hexacoordinated aluminum) or Al with a terminal hydroxyl group (defect) occurs.

In the technical scheme, the organic template in the step 1) is a bicyclic group-containing quaternary ammonium onium compound OSDA1, and the structural formula is characterized in that:

r1, R2 are independently selected from methyl or deuterated methyl, C2-C4 straight-chain or branched-chain alkyl; r3 is selected from C1-C5 straight chain or branched chain alkyl; r4 bicyclic group selected from bicyclo [2.2.2]Octane

Quinuclidine derivatives

Indane

Decalin

Tetralin

Naphthalene

Quinolines

Indoles

Benzofuran derivatives

Norbornane and its preparing process

Indanones

Any of the above. X^-A counter anion which is a quaternary ammonium onium ion including any of hydroxide, halide, sulfate, bisulfate, carbonate, bicarbonate, oxalate, phosphate, carboxylate, alkyl-substituted sulfate, carbonate or oxalate; the halide comprises chloride, bromide or iodide; carboxylates include formate, acetate, propionate; alkyl substituted sulphate, carbonate or oxalate includes methyl sulphate, ethyl sulphate, methyl carbonate, ethyl carbonate, methyl oxalate or ethyl oxalate. The alkyl-substituted quaternary ammonium base OSDA2 is tetramethylammonium hydroxide, tetraethylammonium hydroxide, tetrapropylammonium hydroxide or dipropylammonium hydroxideAny one of methyldiethylammonium hydroxide, triethylmethylammonium hydroxide and trimethylhydroxyethylammonium hydroxide.

Further, in the above technical means, the zeolite molecular sieve in the molar ratio range of 2 to 30 of silica to alumina in step 1) is any one of FAU type zeolite, MFI type zeolite, BEA type zeolite, MOR type zeolite, LTA type zeolite, and EMT type zeolite, preferably any one of FAU type zeolite, MFI type zeolite, BEA type zeolite, and MOR type zeolite, and more preferably any one of X molecular sieve, Y molecular sieve, and USY molecular sieve having FAU type structure; in the step 2) of the synthesis method, the silicon source is selected from one or more of silica sol, water glass, white carbon black, sodium metasilicate, column chromatography silica gel, macroporous silica gel, fine pore silica gel, amorphous silica gel, B-type silica gel, methyl silicate, ethyl silicate, propyl silicate, butyl silicate, ultrafine silica powder, activated clay, organosilicon, diatomite and gas phase method silica gel, and preferably any one or more of silica sol, water glass, column chromatography silica gel, white carbon black, macroporous silica gel, coarse pore silica gel, microporous silica gel, amorphous silica gel, B-type silica gel, methyl silicate and ethyl silicate. The metal salt M is NaCl and NaNO₃、Na₂SO₄、Na₃PO₄、NaBr、NaF、KCl、KNO₃、K₂SO₄、KBr、KF、K₃PO₄Any of them, preferably NaCl and NaNO₃、Na₂SO₄、Na₃PO₄Any of the above.

Further, in the above technical solution, the acid solution in step 2) is selected from any one or more of hydrochloric acid, nitric acid, sulfuric acid, phosphoric acid, formic acid, acetic acid, propionic acid, citric acid, carbolic acid, oxalic acid, and benzoic acid.

Further, in the above technical solution, the kind of the ammonium salt in step 4) is any one of ammonium chloride, ammonium sulfate, ammonium nitrate, ammonium carbonate and ammonium acetate, or a mixture of two or more of them mixed at any ratio.

The invention provides an SCR catalyst for denitration, wherein a CHA-type molecular sieve is subjected to ion exchange with a soluble metal salt solution, then forms slurry with the solid content of 25.0-48.0 wt% with a binder and deionized water, and is coated on a carrier of a porous regular material or an integral filter substrate to form a proper coating, so that the SCR catalyst of the CHA molecular sieve promoted by metal is obtained.

Further, in the above technical solution, the soluble copper salt is selected from one or more of copper nitrate, copper chloride, copper acetate or copper sulfate; the concentration of copper ions in the copper salt aqueous solution is 0.1-0.5 mol/L.

Further, in the above technical solution, the binder is selected from any one or a mixture of several of silica sol, aluminum sol or pseudo-boehmite; the porous regular material or the monolithic filter base material is prepared from any one of cordierite, alpha-alumina, silicon carbide, aluminum titanate, silicon nitride, zirconia, mullite, spodumene, alumina-silica-magnesia or zirconium silicate.

The invention also provides the application of the SCR catalyst, which is applied to the selective catalyst reduction process of nitrogen oxides in the tail gas of the internal combustion engine, the purification of the gas containing nitrogen oxides generated in the refining industrial process, and the purification treatment of the gas containing nitrogen oxides from a refining heater and a boiler, a furnace, the chemical processing industry, a coke oven, a municipal waste treatment device and an incinerator.

Nitrogen oxides (NOx) according to the present invention include a variety of compounds, such as nitrous oxide (N)₂O), Nitric Oxide (NO), nitrogen dioxide (NO)₂) Dinitrogen trioxide (N)₂O₃) Dinitrogen tetroxide (N)₂O₄) And dinitrogen pentoxide (N)₂O₅) And the like.

The process for treating a gas stream comprising NOx wherein prior to contacting the catalyst with the gas stream, NO2 is present in an amount of 80 wt.% or less, based on NOx, based on 100 wt.% and preferably comprising 5 to 70 wt.%, more preferably 10to 60 wt.%, more preferably 15 to 55 wt.%, even more preferably 20 to 50 wt.% NO₂And (4) content. An oxidation catalyst located upstream of the catalyst oxidizes nitrogen monoxide in the gas to nitrogen dioxide and the resulting mixture is then passed to a zeolite catalystThe gas is mixed with a nitrogenous reductant, wherein the oxidation catalyst is adapted to produce a gas stream into the zeolite catalyst, the gas stream having a ratio of 4: 1 to 1: 3 NO: NO2 volume ratio.

Reducing agents (urea, NH) are generally used₃Etc.), several chemical reactions occur, all of which represent reactions that reduce NOx to elemental nitrogen. In particular, the dominant reaction mechanism at low temperature is represented by formula (1).

4NO+4NH₃+O₂→4N2+6H₂O (1)

Non-selective reaction with competing oxygen, or formation of 2-fold products, or non-productive consumption of NH₃. As such a non-selective reaction, for example, NH represented by the formula (2)₃Is completely oxidized.

4NH₃+5NO₂→4NO+6H₂O (2)

Furthermore, NO present in NOx₂And NH₃The reaction of (3) is considered to proceed by means of the reaction formula.

3NO₂+4NH₃→(7/2)N₂+6H₂O (3)

And NH₃With NO and NO₂The reaction between (a) and (b) is represented by the reaction formula (4).

NO+NO₂+2NH₃→2N₂+3H₂O (4)

The reaction rates of the reactions (1), (3) and (4) are greatly different depending on the reaction temperature and the kind of the catalyst used, and the rate of the reaction (4) is usually 2 to 10 times the rate of the reactions (1) and (3).

In the SCR catalyst, in order to improve NOx purification ability at low temperature, it is necessary to make the reaction of formula (4) dominant, not the reaction of formula (1). The reaction of formula (4) is dominant at low temperatures, preferably increasing NO₂This is obvious.

Therefore, at a low temperature of 150-300 ℃, copper has excellent adsorption capacity to NO and has stronger NO oxidation capacity. The oxidation reaction of NO is represented by formula (5).

NO+1/2O₂→NO₂ (5)

The invention relates to an SCR catalyst for denitration, which is an SCR catalyst for obtaining a metal-promoted SSZ-13 eutectic molecular sieve by carrying out ion exchange on synthesized silicon-aluminum zeolite molecular sieve raw powder and a soluble metal salt solution.

The soluble copper salt used in the preparation process of the catalyst is selected from one or more of copper nitrate, copper chloride, copper acetate or copper sulfate; the concentration of copper ions in the copper salt aqueous solution is 0.1-1.5 mol/L.

The amount of Cu in the copper-based SCR molecular sieve catalyst is 0.03 to 20 wt%, based on the weight of the copper-based SCR catalyst, wherein the amount of Cu is preferably 0.2 to 15 wt%, more preferably 0.5 to 10 wt%, more preferably 1.0 to 8.0 wt%, more preferably 1.5 to 5.0 wt%, more preferably 2.0 to 4.0 wt%, more preferably 2.5 to 3.5 wt%, more preferably 2.7 to 3.3 wt%, more preferably 2.9 to 3.1 wt%.

In certain embodiments of the invention, the washcoat of the eutectic molecular sieve SCR catalyst is preferably a solution, suspension or slurry that is applied to a porous structured material (i.e., a honeycomb monolithic catalyst support structure having a plurality of parallel channels running axially through the entire assembly) or a monolithic filter substrate, such as a wall-flow filter, etc., with suitable coatings including a surface coating, a coating that penetrates a portion of the substrate, a coating that penetrates the substrate, or some combination thereof.

The porous regular material comprises a honeycomb flow-through regular carrier which is prepared from cordierite, alpha-alumina, silicon carbide, aluminum titanate, silicon nitride, zirconia, mullite, spodumene, alumina-silica-magnesia or zirconium silicate materials; the carrier is preferably a cordierite porous honeycomb flow-through type monolith carrier, and the carrying capacity of the carrier is 170-270 g/L.

The two most common substrate designs to which the SCR catalyst of the invention can be applied are plate and honeycomb. Preferred substrates, particularly for mobile applications, include flow-through monoliths having a so-called honeycomb geometry comprising a plurality of adjacent, parallel channels that are open at both ends and generally extend from an inlet face to an outlet face of the substrate, and that result in a high surface area to volume ratio. For certain applications, the honeycomb flow-through monolith preferably has a high pore density, for example, about 600 to 800 pores per square inch, and/or an average internal wall thickness of about 0.18 to 0.35mm, preferably about 0.20 to 0.25 mm. For certain other applications, the honeycomb flow-through monolith preferably has a low pore density of about 150 to 600 pores per square inch, more preferably about 200 to 400 pores per square inch.

The catalyst in the embodiments of the invention shows that high NOx conversion is obtained in a much wider temperature window. The temperature range for improving the conversion efficiency may be about 150 to 650 ℃, preferably 200 to 500 ℃, more preferably 200 to 450 ℃, or most significantly 200 to 400 ℃. Within these temperature ranges, the conversion efficiency after exposure to a reducing atmosphere, even after exposure to a reducing atmosphere and high temperatures (e.g., up to 850 ℃) can be greater than 55% to 100%, more preferably greater than 90% efficiency, and even more preferably greater than 95% efficiency.

The SCR catalyst prepared by the CHA-structure molecular sieve has better hydrothermal stability and wider ignition activity window temperature (200-500 ℃), has good low-temperature and high-temperature ignition activity, has a more proper pore structure and grain size distribution, is beneficial to the diffusion of NOx molecules, enhances the adhesion of metal copper ions, and reduces the possibility of aggregation caused by the hydrothermal action.

The molecular sieve has more reasonably distributed acidity and good hydrothermal stability, overcomes the limitations of the components, and has excellent NOx reducibility particularly at low temperature after the provided SCR catalyst is subjected to durable treatment at high temperature in the atmosphere containing hydrothermal steam. Better meets the requirements of industrial application and has wide application prospect.

The silicoaluminophosphate zeolite molecular sieve of the present invention is more suitable for a high-crystallinity CHA-type zeolite as a catalyst or a catalyst carrier than a conventional CHA-type zeolite, and particularly suitable for a nitrogen oxide reduction catalyst or a carrier thereof, and further a nitrogen oxide reduction catalyst or a carrier thereof in the presence of ammonia or urea.

The molecular sieve of the present invention is a silicoaluminophosphate zeolite molecular sieve having high heat resistance without having a large crystal grain size, and is a catalyst which exhibits high nitrogen oxide reduction characteristics even after exposure to high temperature and high humidity, particularly high nitrogen oxide reduction characteristics at a temperature range of 200 to 550 ℃.

Drawings

FIG. 1 is an XRD diffractogram of the SSZ-13 molecular sieve synthesized in example 1.

FIG. 2 is an XRD diffractogram of the SSZ-13 molecular sieve synthesized in example 2.

FIG. 3 is an XRD diffractogram of the SSZ-13 molecular sieve synthesized in example 3.

FIG. 4 is an SEM topography of the SSZ-13 molecular sieve synthesized in example 1.

FIG. 5 is an SEM topography of the SSZ-13 molecular sieve synthesized in example 2.

FIG. 6 is an SEM topography of the SSZ-13 molecular sieve synthesized in example 3.

Detailed Description

The embodiments and the effects of the present invention are further illustrated by examples and comparative examples, but the scope of the present invention is not limited to the contents listed in the examples.

The eutectic molecular sieve of the present invention is identified by finding the lattice plane spacing (d) from the XRD pattern by the Powder method of X-ray Diffraction (X-ray Diffraction) analysis, and comparing the obtained Data with Data collected from the XRD database of the International society for synthetic zeolites or the PDF (Powder Diffraction File) of ICDD (International Centre for Diffraction Data). As XRD measurement conditions in the embodiment of the present invention, the following conditions may be mentioned:

ray source: CuK α ray λ 1.540598, measurement mode: step scan 2 θ step scan scale: 0.02626 °, measurement range: 2 theta is 5-60 degrees.

And substituting X-ray diffraction data into a Debye-Scherrer formula to calculate the grain size Dhkl, wherein the Debye-Scherrer formula is as follows: d (hkl) ═ k λ/β cos θ; wherein D (hkl) is the grain diameter along the direction vertical to the crystal face hkl, and the unit is nm; k is the Scherrer constant; λ is the incident X-ray wavelength in nm; theta is the Bragg diffraction angle in degrees; beta is the half-peak broadening of the diffraction peak. The wavelength λ is 0.15406nm when Cuka is used as the X-ray source and 0.15418nm when Cuka1 is used as the X-ray source. The measurement was carried out by a PANalytical X-ray diffractometer under CuK alpha monochromatic light irradiation at a tube voltage of 45kV and a current of 40mA in a2 theta range of 15 to 35 degrees.

Example 1

A CHA type SSZ-13 molecular sieve and a catalyst preparation method are disclosed:

1) mixing 45.59g HY molecular sieve (Si/Al to nSiO)₂/nAl₂O₃5.20 dry basis, 78.1 percent of dry basis), 26.68g of NaOH flake caustic soda and 69.98g of deionized water are fully dissolved and dispersed to obtain slurry with the molar ratio of nNa₂O:nSiO₂:nAl₂O₃:nOH^-:nH₂Aging in a crystallization kettle at 85 ℃ for 36 hours to obtain silicon-aluminum gel, wherein O is 0.75:1.0:0.192:1.5: 10;

2) to the mixed silica-alumina gel mixture obtained in step 1) was added 507.51g of a silica gel solution (Na 2O: 0.24 wt%, SiO 2: 30.36 wt%), 227.30g N, N-dimethyl-N' -ethyl- (decahydronaphthalen-1-yl) ammonium hydroxide (concentration 20 wt%, expressed as OSDA 1), 14.61g tetramethylammonium hydroxide (concentration 25 wt%, expressed as OSDA 2), 56.31g NaOH flake caustic soda, 21.25g NaCl and 183.53g deionized water were thoroughly and ultrasonically mixed well so that the mixed slurry components had a molar ratio of nNa₂O:nSiO₂:nA1₂O₃:nOSDA:nNaCl:nH₂O ═ 0.35:1.0:0.0286:0.08:0.12: 15; adding 5% HCl solution to adjust nOH in the system^-/nSiO₂Adding SiO into the mixed slurry with the ratio of 0.78₂And A1₂O₃Taking 9.45g of CHA molecular sieve accounting for 5.0 percent of the total mass as seed crystal; stirring the mixture, transferring the mixture into a hydrothermal crystallization reaction kettle, crystallizing for 36 hours at the self-generated pressure and the temperature of 140 ℃, then quenching to stop crystallization, filtering and washing the product until the pH value is nearly neutral, drying for 12 hours at the temperature of 120 ℃, and roasting for 4 hours at the temperature of 540 ℃ to obtain SSZ-13 molecular sieve raw powder;

3) mixing the SSZ-13 molecular sieve raw powder obtained in the step 2) with 1.0mol/L of concentrateAnd performing ion exchange on the ammonium nitrate solution at 70 ℃ for 2 hours according to the solid-liquid mass ratio of 1:10, and then repeatedly exchanging the filter cake obtained by filtering with a fresh ammonium nitrate solution twice under the same condition to ensure that the Na ion content in the sample is lower than 500 ppm. Then filtering and separating the solid product, repeatedly washing the solid product to be neutral by using deionized water, and drying the obtained filter cake at 110 ℃ for 12h to obtain the ammonium type molecular sieve NH₄SSZ-13, then heating to 450 ℃ and roasting for 16 hours to obtain the H-type SSZ-13 molecular sieve (namely the CHA-type molecular sieve).

4) Adding 50.0g of the H-type SSZ-13 molecular sieve obtained in the step 3) into a copper nitrate aqueous solution with the concentration of 0.15mol/L, dropwise adding dilute nitric acid into the solution to adjust the pH value to 6.5, uniformly stirring, placing into a heat-resistant container, and placing into a dryer with a pressure reducing valve; vacuumizing the pressure in the dryer to be below 10Torr by using a vacuum pump, degassing at room temperature for 1 hour, heating to 90 ℃, drying for 12 hours, and roasting the dried sample at the temperature of 500 ℃ for 4 hours under normal atmospheric pressure; the copper-modified SSZ-13 molecular sieve was obtained, and the catalyst prepared according to XRF analysis results had copper (II) ions accounting for 2.7% of the total weight of the molecular sieve catalyst, i.e., copper loading was 2.7 wt%.

5) Taking 40.0g of the copper-modified molecular sieve obtained in the above 4), and 20.0g of silica Sol (SiO)₂The content is as follows: 30.0 wt%) and 88.87g of deionized water are uniformly mixed to prepare a catalyst slurry with a solid content of 30.9 wt%, the catalyst slurry is coated on a cordierite honeycomb porous regular material (#400cpsi, 20mm in diameter and 40mm in length) by an impregnation method, redundant slurry droplets are blown off by compressed air, the catalyst slurry is dried at 105 ℃ for 24 hours, the catalyst slurry is coated for 2 times under the same condition and is calcined at 500 ℃ for 2 hours to prepare the SCR catalyst, the loading on the regular material is 212.1g/L (the weight of the weight increased by the regular material after calcination is divided by the space volume occupied by the regular material, the definitions of the subsequent examples and comparative examples on the loading are the same), and the obtained SCR catalyst is marked as A, and the relevant preparation parameters and the species are shown in tables 1, 2, 3 and 4.

Example 2

Process for synthesizing CHA-type SSZ-13 molecular sieveThe procedure is as in example 1, except that the molar proportions of the components of the slurry in stage 1) (nNa)₂O:nSiO₂:nAl₂O₃:nH₂O), zeolite molecular sieve type, zeolite silicon-aluminum ratio, aging temperature and aging time, the mol ratio of the mixed sol, the type of the organic template agent, the type of the silicon source, the adding amount of the seed crystal, the type of the added acid, the type of the metal salt M, the crystallization temperature, the crystallization time and the like in the step 2), 50.0g of the H-type SSZ-13 molecular sieve is taken in the step 4), different soluble metal salt types, concentrations, solution volumes and metal loading amounts are adopted, 40.0g of the copper modified CHA-type SSZ-13 molecular sieve is taken in the step 5), and 20.0g of the silica Sol (SiO) is taken in the step 5)₂The content is as follows: 30.0 wt%) and 91.82g of deionized water are mixed uniformly to prepare catalyst slurry with the solid content of 30.3 wt%, and the catalyst slurry is coated on the cordierite regular material by an impregnation method. Specific parameters in this example are shown in tables 1, 2, 3 and 4.

Example 3

The process for synthesizing the CHA-type SSZ-13 molecular sieve is similar to that of example 1, except that the slurry components in step 1) are present in a molar ratio (nNa)₂O:nSiO₂:nAl₂O₃:nH₂O), zeolite molecular sieve type, zeolite silicon-aluminum ratio, aging temperature and aging time, the mol ratio of the mixed sol, the type of the organic template agent, the type of the silicon source, the adding amount of seed crystal, the type of the added acid, the type of the metal salt M, the crystallization temperature, the crystallization time and the like in the step 2), 50.0g of H-type SSZ-13 molecular sieve is taken in the step 4), different soluble metal salt types, concentrations, solution volumes and metal loading amounts are adopted, and 40g of copper modified CHA-type SSZ-13 molecular sieve and 20.0g of silica Sol (SiO) are taken in the step 5)₂The content is as follows: 30.0 wt%) and 64.66g of deionized water, and the catalyst slurry with the solid content of 36.9 wt% is prepared and coated on the cordierite regular material by an impregnation method. Specific parameters in this example are shown in tables 1, 2, 3 and 4.

Example 4

The process for synthesizing the CHA-type SSZ-13 molecular sieve is similar to that of example 1, except that the slurry components in step 1) are present in a molar ratio (nNa)₂O:nSiO₂:nAl₂O₃:nH₂O), zeolite molecular sieve type, zeolite silicon-aluminum ratio, aging temperature and aging time, the mol ratio of the mixed sol, the type of the organic template agent, the type of the silicon source, the adding amount of seed crystal, the type of the added acid, the type of the metal salt M, the crystallization temperature, the crystallization time and the like in the step 2), 50.0g of H-type SSZ-13 molecular sieve is taken in the step 4), different soluble metal salt types, concentrations, solution volumes and metal loading amounts are adopted, and 5) 40g of copper modified CHA-type SSZ-13 molecular sieve and 20.0g of silica Sol (SiO) are taken in the step 5)₂The content is as follows: 30.0 wt%) and 63.66g of deionized water were mixed uniformly to prepare a catalyst slurry having a solid content of 37.2 wt%, and the catalyst slurry was coated on a cordierite structured material by an impregnation method. Specific parameters in this example are shown in tables 1, 2, 3 and 4.

Example 5

The process for synthesizing the CHA-type SSZ-13 molecular sieve is similar to that of example 1, except that the slurry components in step 1) are present in a molar ratio (nNa)₂O:nSiO₂:nAl₂O₃:nH₂O), zeolite molecular sieve type, zeolite silicon-aluminum ratio, aging temperature and aging time, the mol ratio of the mixed sol, the type of the organic template agent, the type of the silicon source, the adding amount of seed crystal, the type of the added acid, the type of the metal salt M, the crystallization temperature, the crystallization time and the like in the step 2), 50.0g of H-type SSZ-13 molecular sieve is taken in the step 4), different soluble metal salt types, concentrations, solution volumes and metal loading amounts are adopted, 40g of copper modified CHA-type SSZ-13 molecular sieve is taken in the step 5), and 30.0g of aluminum sol (Al) is taken₂O₃The content is as follows: 20.0 wt%) and 125.22g of deionized water were mixed uniformly to prepare a catalyst slurry having a solid content of 25.1 wt%, and the catalyst slurry was coated on a cordierite structured material by an impregnation method. Specific parameters in this example are shown in tables 1, 2, 3 and 4.

Example 6

The process for synthesizing the CHA-type SSZ-13 molecular sieve is similar to that of example 1, except that the slurry components in step 1) are present in a molar ratio (nNa)₂O:nSiO₂:nAl₂O₃:nH₂O), zeolite molecular sieve type, zeolite silicon-aluminum ratio, aging temperature and aging time, and the molar ratio of the mixed sol and the organic mold in the step 2)The method comprises the following steps of (1) selecting 50.0g of H-type SSZ-13 molecular sieve in step 4), adopting different soluble metal salt types, concentrations, solution volumes and metal loading amounts, and selecting 40g of copper modified CHA-type SSZ-13 molecular sieve in step 5) and 30.0g of aluminum sol (Al) in step 5₂O₃The content is as follows: 20.0 wt%) and 72.41g of deionized water were mixed uniformly to prepare a catalyst slurry having a solid content of 32.3 wt%, and the catalyst slurry was coated on a cordierite structured material by an impregnation method. Specific parameters in this example are shown in tables 1, 2, 3 and 4.

Example 7

The process for synthesizing the CHA-type SSZ-13 molecular sieve is similar to that of example 1, except that the slurry components in step 1) are present in a molar ratio (nNa)₂O:nSiO₂:nAl₂O₃:nH₂O), zeolite molecular sieve type, zeolite silicon-aluminum ratio, aging temperature and aging time, the mol ratio of the mixed sol, the type of the organic template agent, the type of the silicon source, the adding amount of seed crystal, the type of the added acid, the type of the metal salt M, the crystallization temperature, the crystallization time and the like in the step 2), 50.0g of H-type SSZ-13 molecular sieve is taken in the step 4), different soluble metal salt types, concentrations, solution volumes and metal loading amounts are adopted, 40g of copper modified CHA-type SSZ-13 molecular sieve is taken in the step 5), and 30.0g of aluminum sol (Al) is taken₂O₃The content is as follows: 20.0 wt%) and 49.79g of deionized water were mixed uniformly to prepare a catalyst slurry having a solid content of 38.4 wt%, which was coated on a cordierite structured material by an impregnation method. Specific parameters in this example are shown in tables 1, 2, 3 and 4.

Example 8

The process for synthesizing the CHA-type SSZ-13 molecular sieve is similar to that of example 1, except that the slurry components in step 1) are present in a molar ratio (nNa)₂O:nSiO₂:nAl₂O₃:nH₂O), zeolite molecular sieve type, zeolite silicon-aluminum ratio, aging temperature and aging time, the molar ratio of the mixed sol, the type of the organic template agent, the type of the silicon source, the adding amount of the seed crystal, the type of the added acid, the type of the metal salt M, the crystallization temperature, the crystallization time and the like in the step 2), and the stepsStep 4) taking 50.0g of H-type SSZ-13 molecular sieve, adopting different soluble metal salt types, concentrations, solution volumes and metal loading amounts, and step 5) taking 40g of copper modified CHA-type SSZ-13 molecular sieve and 30.0g of aluminum sol (Al)₂O₃The content is as follows: 20.0 wt%) and 105.57g of deionized water were mixed uniformly to prepare a catalyst slurry having a solid content of 26.2 wt%, and the catalyst slurry was coated on a cordierite structured material by an impregnation method. Specific parameters in this example are shown in tables 1, 2, 3 and 4.

TABLE 1 selection of parameters in step 1) and selection of organic template in step 2) for molecular sieve synthesis

TABLE 2 selection of parameters in molecular Sieve Synthesis step 2)

TABLE 3 tables of molecular sieve performance parameters obtained in examples 1 to 8

*: the sample is used after the hydrothermal treatment for 16 hours by saturated water vapor at 800 DEG C²⁷And testing the aluminum proportioning ratio by Al MAS NMR solid nuclear magnetic resonance.

Table 4 SCR catalyst metal ion parameters and metal loadings prepared in examples 1-8

Comparative example 1

17.0g of SB powder was dissolved in 50.0g of a 50 wt% aqueous NaOH solution, and 200.0g of white carbon was then added thereto and mixed thoroughly. An aqueous solution of N, N, N-trimethyladamantane ammonium hydroxide (TMADA +) (25 wt% concentration) was slowly added to the mixture while mixing. 80.0g of deionized water was slowly added and the resulting mixture was mixed well for 1 hour. The molar composition of the synthesis mixture was:

0.21Na₂O：SiO₂：0.0286Al₂O₃：0.18TMADa⁺：26.8H₂O

and then transferring the obtained gel into a stainless steel reaction kettle to crystallize at 170 ℃ for 168 hours, after the reaction is finished, washing the product with deionized water, drying at 120 ℃ for 12 hours, and roasting at 540 ℃ for 4 hours to obtain the SSZ-13 molecular sieve raw powder. The molecular sieve raw powder and ammonium nitrate solution with the concentration of 1.0mol/L are subjected to ion exchange for 2 hours at the temperature of 80 ℃ according to the solid-liquid mass ratio of 1:10, and then filter cakes obtained by filtration are repeatedly exchanged with fresh ammonium nitrate solution twice under the same condition, so that the Na ion content is lower than 500 ppm. The filter cake obtained by subsequent filtration is dried at 110 ℃ overnight to obtain ammonium type molecular sieve NH₄Heating to 450 ℃ and roasting for 16 hours to obtain the H-type SSZ-13 molecular sieve.

10g of SSZ-13 molecular sieve raw powder was added to 100g of Cu (NO) having a concentration of 0.3mol/L₃)₂·3H₂And (3) dripping dilute nitric acid into the O aqueous solution to adjust the pH value to 5.8, and uniformly stirring. After stirring was stopped for 1 hour, the supernatant was siphoned off when SSZ-13 zeolite settled. The exchange with fresh copper nitrate solution was repeated once, and finally the exchanged SSZ-13 zeolite was filtered and washed with deionized water. Drying at 90 ℃ for 12 hours under the low pressure of 10Torr, and then roasting at 500 ℃ for 4 hours under normal atmospheric pressure to obtain the copper modified SSZ-13 molecular sieve powder. According to XRF analysis, copper (II) ions accounted for 2.9% of the total weight of the molecular sieve catalyst.

15g of the resulting copper-modified SSZ-13 min were takenSub-sieves, with 5.56g of silica sol (30% by weight SiO)₂) And 22.80g of deionized water are uniformly mixed to prepare catalyst slurry with the solid content of 38.44 wt%, the catalyst slurry is coated on a honeycomb-shaped porous regular material (400 cpsi, the diameter of 20mm and the length of 40mm) made of cordierite through an impregnation method, redundant slurry drops are blown off by compressed air, the drying is carried out for 12 hours at the temperature of 110 ℃, then, the slurry is coated again, the SCR catalyst is prepared after the calcination is carried out for 2 hours at the temperature of 500 ℃, and the measured catalyst loading capacity on the regular material is 228.4g/L and is marked as VS-1.

Comparative example 2

The SSZ-13 molecular sieve is synthesized and the SCR catalyst is prepared according to the method in CN 103328385:

to 13.9g N, N-trimethylamantadine ammonium hydroxide solution (TMADAOH, 25%), pure water 31.4g, an aqueous potassium hydroxide solution (concentration 48%), and an amorphous aluminosilicate gel 9.0g prepared from sodium silicate and aluminum sulfate were added and mixed thoroughly to obtain a raw material composition. The composition of the raw material composition is SiO 2: 0.048Al2O 3: 0.124 TMADAOH: 0.054Na 2O: 0.081K 2O: 18H 2O. The raw material composition was sealed in an 80ml stainless steel autoclave and crystallized at 150 ℃ for 72 hours at a rotation speed of 55 rpm. And (3) carrying out suction filtration or centrifugal separation on the crystallized product, washing the crystallized product with deionized water to be nearly neutral, and drying the product at 110 ℃ to obtain the SSZ-13 molecular sieve product, wherein the SiO2/Al2O3 molar ratio is 14.9, and the particle size is 1.0-3.0 mu m.

And carrying out ion exchange on the SSZ-13 molecular sieve raw powder and an ammonium nitrate solution with the concentration of 1.0mol/L for 2 hours at 90 ℃ according to the solid-liquid mass ratio of 1:10, and then repeatedly exchanging the filter cake obtained by filtering with a fresh ammonium nitrate solution twice under the same condition so as to enable the Na ion content to be lower than 500 ppm. The filter cake obtained by subsequent filtration is dried at 110 ℃ overnight to obtain ammonium type molecular sieve NH₄Heating to 450 ℃ and roasting for 16 hours to obtain the H-type SSZ-13 molecular sieve.

10g of SSZ-13 molecular sieve raw powder was added to 100g of Cu (NO) having a concentration of 0.3mol/L₃)₂·3H₂And (3) dripping dilute nitric acid into the O aqueous solution to adjust the pH value to 5.8, and uniformly stirring. After stirring was stopped for 1 hour, the supernatant was siphoned off when SSZ-13 zeolite settledAnd (4) liquid. The exchange with fresh copper nitrate solution was repeated once, and finally the exchanged SSZ-13 zeolite was filtered and washed with deionized water. Drying at 90 ℃ for 12 hours under the low pressure of 10Torr, and then roasting at 500 ℃ for 4 hours under normal atmospheric pressure to obtain the copper modified SSZ-13 molecular sieve powder. According to XRF analysis, copper (II) ions accounted for 3.0% of the total weight of the molecular sieve catalyst.

15g of the resulting copper-modified SSZ-13 molecular sieve were taken and mixed with 5.56g of silica sol (30 wt% SiO)₂) And 22.80g of deionized water are uniformly mixed to prepare catalyst slurry with the solid content of 38.44 wt%, the catalyst slurry is coated on a honeycomb-shaped porous regular material (400 cpsi, the diameter of 20mm and the length of 40mm) made of cordierite through an impregnation method, redundant slurry drops are blown off by compressed air, the drying is carried out for 12 hours at the temperature of 110 ℃, then, the slurry is coated again, the SCR catalyst is prepared after the calcination is carried out for 2 hours at the temperature of 500 ℃, and the measured catalyst loading capacity on the regular material is 216.6g/L and is marked as VS-2.

Examples 9 to 14

Testing of the SCR catalyst:

SCR catalysts prepared in examples 1 to 6 and comparative examples 1 to 2 were installed in a reactor

160mL/min of a mixed gas stream containing 500ppm of NO, 500ppm of NH3, 10 vol% of O2, 5 vol% of steam and Ar as a balance gas firstly passes through a preheater (set at 250 ℃) and then enters an SCR reactor. At a reaction temperature of 150-650 ℃ for 48000h^-1The test specimens were tested at a volumetric gas hourly space velocity. The temperature is monitored by an internal thermocouple located at the sample site.

The used fresh SCR catalysts of the above examples and comparative examples were subjected to a hydrothermal durability treatment under the conditions of the hydrothermal durability treatment test to obtain aged SCR catalysts:

space velocity SV: 30000/h, temperature: 800 ℃, time: 16 hours, water concentration: 10%, oxygen concentration: 10%, nitrogen concentration: and (4) balancing.

After hydrothermal aging treatment is carried out according to the parameters, the catalyst is continuously used as an SCR catalyst for NOx catalytic reduction reaction evaluation test:

NO conversion or "denox" activity was determined under steady state conditions by measuring NOx, NH3, and N2O concentrations at the outlet using a Bruker EQUINOX model 55 FT-IR spectrometer.

The SCR catalyst activity laboratory evaluation device described above was used to evaluate the selective catalytic reduction performance of NOx on the Cu-supported SCR catalysts prepared in examples and comparative examples, and the results are shown in table 5.

TABLE 5 preparation of catalyst NO for examples 1-6 and comparative examples 1-2_xEvaluation index of Selective reduction Performance

800 ℃ in an atmosphere of 10% moisture + 10% oxygen concentration, at a space velocity of 30000/h, for 16 hours.

As can be seen from Table 5, the Cu-SSZ-13 or Fe-SSZ-13 catalysts obtained in examples 1 to 6 evaluated in examples 9 to 14 showed better low-temperature ignition properties and high-temperature activity, and the SCR activity was significantly better than the catalytic performance of catalysts VS-1 and VS-2 obtained in comparative example 1 shown in examples 15 to 16, regardless of their "fresh" state or "aged" state. Thus, the results obtained from examples 9-14 clearly show that the Cu-SSZ-13 or Fe-SSZ-13 catalyst materials of the present invention and the catalysts obtained therewith have improved SCR catalytic activity, especially at low conversion temperatures characteristic of cold start conditions when treating NOx, for example, in diesel locomotive applications. For other SCR applications, the Cu-SSZ-13 or Fe-SSZ-13 catalyst materials of the present invention allow for higher conversion at lower temperatures, thus allowing for higher efficiency and thus, at comparable conversion, high energy efficiency in the treatment of NOx-containing exhaust gases, such as exhaust gases obtained from industrial processes.

The above-mentioned embodiments are only for illustrating the technical idea and features of the present invention, and the purpose of the present invention is to enable those skilled in the art to understand the content of the present invention and implement the present invention, and not to limit the protection scope of the present invention. All equivalent changes and modifications made according to the spirit of the present invention should be covered within the protection scope of the present invention.

Claims

1. A CHA-type molecular sieve synthesized by using a bicyclic group-containing quaternary ammonium onium composite template agent is characterized in that: the CHA-type molecular sieve is synthesized by a composite organic template agent formed by mixing a bicyclic group-containing quaternary ammonium onium compound OSDA1 and an alkyl substituted quaternary ammonium base OSDA2, wherein the molar ratio of silica to alumina of the CHA-type molecular sieve is 5-80, the average grain diameter is less than or equal to 500nm, and the total specific surface area is more than or equal to 400m²The total pore volume is more than or equal to 0.20ml/g, and the micropore volume is more than or equal to 0.10 ml/g; the molecular sieve has a CHA topological structure, the range of the half-value width (FWHM) of a crystal face of the X-ray crystal diffraction (-210) is 0.1-0.2 degrees, and the diameter size of crystal grains in the crystal face (-210) direction is 50-160 nm; after the molecular sieve is treated by saturated steam at 600-850 ℃, the four-coordination aluminum accounts for more than or equal to 90 percent of the total aluminum content, and the six-coordination aluminum accounts for less than or equal to 10 percent of the total aluminum content;

2. The CHA-type molecular sieve of claim 1, wherein: the molecular sieve has at least one XRD diffraction peak in each range of the following table within the range of 4-40 degrees of 2 theta, and has the characteristics of the following table:

the relative intensity is an intensity relative to a peak intensity of 20.40 to 20.90 in terms of 2 θ.

3. The CHA-type molecular sieve of claim 1, wherein: the halide comprises chloride, bromide or iodide; carboxylates include formate, acetate, propionate; alkyl substituted sulphate, carbonate or oxalate includes methyl sulphate, ethyl sulphate, methyl carbonate, ethyl carbonate, methyl oxalate or ethyl oxalate.

4. The method of synthesizing the CHA-type molecular sieve of any of claims 1 to 3, wherein: the method comprises the following steps:

1) fully dissolving and dispersing zeolite molecular sieve with the molar ratio of silicon dioxide to aluminum oxide of 2-30, NaOH and deionized water to obtain slurry with the molar ratio of nNa₂O:nSiO₂:nAl₂O₃:nH₂Aging the product (0.5-2.5) of O and (0.0333-0.5) and (5-20) in a crystallization kettle at 60-120 ℃ for 6-48 hours to obtain silicon-aluminum gel;

2) adding a silicon source, a bicyclic group-containing quaternary ammonium onium compound OSDA1, an alkyl-substituted quaternary ammonium base OSDA2, a metal salt M and deionized water into the silicon-aluminum gel obtained in the step 1), fully and uniformly mixing, supplementing NaOH according to the alkalinity requirement of a system, and enabling the components of the mixed slurry to be in a molar ratio of nNa₂O:nSiO₂:nA1₂O₃:nOSDA1:nOSDA2:nM:nH₂O is (0.05-0.5) 1.0, (0.0125-0.20), (0.01-0.5), (0.05-0.5), (0.01-0.25) and (5-100); adding acid solution to control alkali hydroxyl OH in mixed slurry^-With SiO₂In a molar ratio of nOH^-/nSiO₂0.1 to 1.0; adding CHA molecular sieve seed crystal with SiO in the slurry₂And A1₂O₃0.5-15% of the total mass; molar ratio nOSDA1 of bicyclic group-containing quaternary ammonium compound OSDA1 to alkyl-substituted quaternary ammonium base OSDA 2: nOSDA2 (0.5-50): 1;

4) mixing the molecular sieve raw powder obtained in the step 3) with an ammonium salt solution with the concentration of 0.1-5.0 mol/L according to a solid-liquid mass ratio of 1: (5-50) carrying out ion exchange at 60-100 ℃, wherein each time of exchange is 0.5-6 hours, and repeatedly exchanging the obtained filter cake with an ammonium ion solution for 1-3 times until the Na ion content in the molecular sieve sample is lower than 500 ppm; and then filtering and separating out a solid product, repeatedly washing the solid product by using deionized water until the solid product is neutral, drying a filter cake at the temperature of 100-130 ℃ for 12-48 hours, and roasting the filter cake at the temperature of 400-600 ℃ for 2-16 hours to obtain the CHA-type molecular sieve.

5. The synthesis method according to claim 2, wherein the zeolite molecular sieve in the molar ratio of silica to alumina in step 1) is any one of FAU type zeolite, MFI type zeolite, BEA type zeolite, MOR type zeolite, LTA type zeolite and EMT type zeolite, preferably any one of FAU type zeolite, MFI type zeolite, BEA type zeolite and MOR type zeolite, and more preferably any one of X molecular sieve, Y molecular sieve and USY molecular sieve having FAU type structure; in the step 2), the silicon source is selected from silica sol, water glass, white carbon black, sodium metasilicate, column chromatography silica gel, macroporous silica gel, coarse pore silica gel, fine pore silica gel, amorphous silica, B-type silica gel, methyl silicate, ethyl silicate, propyl silicate, butyl silicate, sodium metasilicate, sodium,One or more of superfine silica powder, activated clay, organic silicon, diatomite and gas-phase silica gel, preferably any one or more of silica sol, water glass, column chromatography silica gel, white carbon black, macroporous silica gel, coarse porous silica gel, fine porous silica gel, amorphous silica, B-type silica gel, methyl silicate and ethyl silicate; the metal salt M is NaCl and NaNO₃、Na₂SO₄、Na₃PO₄、NaBr、NaF、KCl、KNO₃、K₂SO₄、KBr、KF、K₃PO₄Any of them, preferably NaCl and NaNO₃、Na₂SO₄、Na₃PO₄Any one of the above; the acid solution is selected from one or more of hydrochloric acid, nitric acid, sulfuric acid, phosphoric acid, formic acid, acetic acid, propionic acid, citric acid, carbolic acid, oxalic acid and benzoic acid.

6. The method of synthesis according to claim 4, characterized in that: and 4) the type of the ammonium salt is a mixture formed by mixing any one, two or more than two of ammonium chloride, ammonium sulfate, ammonium nitrate, ammonium carbonate and ammonium acetate in any proportion.

7. An SCR catalyst for denitration, characterized in that: the CHA-type molecular sieve of any one of claims 1 to 3 is subjected to ion exchange with a soluble copper salt solution, then forms a slurry with a solid content of 25.0-48.0 wt% with a binder and deionized water, and is coated on a proper coating formed on a carrier of a porous regular material or an integral filter substrate to obtain the SCR catalyst of the metal-promoted CHA molecular sieve.

8. The SCR catalyst of claim 7, wherein: the soluble metal salt is selected from one or a combination of more of soluble salts of copper, iron, cobalt, tungsten, nickel, zinc, molybdenum, vanadium, tin, titanium, zirconium, manganese, chromium, niobium, bismuth, antimony, ruthenium, germanium, palladium, indium, platinum, gold or silver, preferably any one or two of copper salt and iron salt, and further preferably copper salt; the copper salt is one or more of copper nitrate, copper chloride, copper acetate or copper sulfate; the concentration of copper ions in the water solution of the soluble salt of copper is 0.1-0.5 mol/L.

9. The catalyst of claim 7, wherein: the binder is selected from any one or mixture of silica sol, aluminum sol or pseudo-boehmite; the porous regular material or the monolithic filter base material is prepared from any one of cordierite, alpha-alumina, silicon carbide, aluminum titanate, silicon nitride, zirconia, mullite, spodumene, alumina-silica-magnesia or zirconium silicate.

10. Use of the SCR catalyst of any one of claims 7 to 9, characterized in that: the method is applied to the selective catalyst reduction process of nitrogen oxides in the tail gas of an internal combustion engine, the purification of gas containing nitrogen oxides generated in the industrial process of refining, and the purification treatment of gas containing nitrogen oxides from refining heaters and boilers, furnaces, chemical processing industry, coke ovens, municipal waste treatment devices and incinerators.