CN110474015A - A kind of automatic liquid supply prevents the battery of thermal runaway - Google Patents

A kind of automatic liquid supply prevents the battery of thermal runaway Download PDF

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Publication number
CN110474015A
CN110474015A CN201910796586.XA CN201910796586A CN110474015A CN 110474015 A CN110474015 A CN 110474015A CN 201910796586 A CN201910796586 A CN 201910796586A CN 110474015 A CN110474015 A CN 110474015A
Authority
CN
China
Prior art keywords
battery
thermal runaway
upper cover
fluid infusion
liquid supply
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910796586.XA
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Chinese (zh)
Inventor
张森
陈振富
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGXI XINWEI POWER ENERGY TECHNOLOGY CO LTD
Original Assignee
JIANGXI XINWEI POWER ENERGY TECHNOLOGY CO LTD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by JIANGXI XINWEI POWER ENERGY TECHNOLOGY CO LTD filed Critical JIANGXI XINWEI POWER ENERGY TECHNOLOGY CO LTD
Priority to CN201910796586.XA priority Critical patent/CN110474015A/en
Publication of CN110474015A publication Critical patent/CN110474015A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/12Construction or manufacture
    • H01M10/121Valve regulated lead acid batteries [VRLA]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/60Arrangements or processes for filling or topping-up with liquids; Arrangements or processes for draining liquids from casings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)

Abstract

The present invention relates to the batteries that a kind of automatic liquid supply prevents thermal runaway.The reason of Most current valve controlled sealed lead-acid accumulator pool-size declines, is all as caused by battery dehydration.It has been generally acknowledged that when dehydration is more than 15%, battery failure.Can all there be 10~30% thermal runaway failure return of goods phenomenon to summer 7~September part every year, company's lost revenue is huge.The present invention relates to the batteries that a kind of automatic liquid supply prevents thermal runaway, it is sequentially connected including single lattice, both ends are provided with busbar connector in each single lattice, fluid infusion bottle is provided among busbar connector, fluid infusion bottle includes upper cover and volumetric flask, overflow port is distributed in upper cover, and the sealing of upper cover overflow port is encapsulated using microwax.The advantages of present apparatus, is: being melted by the microwax at porous place, fluid infusion water in bottle flows out automatically carries out water supplement, adds battery internal resistance moment after water to decline, so that charger is quickly turned lamp and enter floating charge state, it avoids battery pack that thermal runaway phenomenon occurs, while extending the service life of battery pack.

Description

A kind of automatic liquid supply prevents the battery of thermal runaway
Technical field
The present invention relates to valve-regulated lead-acid battery technical fields, and in particular to a kind of automatic liquid supply prevents the electricity of thermal runaway Pond.
Background technique
Battery is 1859 by Pulan special (Plante) invention, has 160 years history so far.Lead-acid accumulator is certainly After invention, have overwhelming superiority always in electrochmical power source.It recycles, make this is because its is cheap, raw material are recyclable With securely and reliably.In recent years, Lead-acid Battery Technology continues to develop, and product is ripe day by day.Maintenance-free battery is widely used, It is still the vital power supply device of military, civilian traffic transportation equipment, walking-replacing tool.
The design principle of valve-regulated lead-acid battery is that the electrolyte of required deal is injected in pole plate and partition, is not dissociated Electrolyte, the ability for absorbing oxygen is improved by negative plate humidity, battery sealed to prevent electrolyte from reducing, therefore valve control Formula lead-acid accumulator is also known as " lean solution battery ".
The dehydration of valve control battery is to lead to the most common failure of battery malfunction.Gas-recombination efficiency is low, from battery case Water seepage, grid corrosion and self discharge can all cause battery dehydration.If overcharge current is big, float charge voltage is excessively high, environment temperature It is excessively high, Investigation on safety valve pressure is low etc. can accelerate battery dehydrating speed.Most current valve controlled sealed lead-acid accumulator group is held The reason of amount decline, be all as caused by battery dehydration.It has been generally acknowledged that when dehydration is more than 15%, battery failure.Every year to the summer Season, 7~September part can all have 10~30% thermal runaway failure return of goods phenomenon, and company's lost revenue is huge.Also as the logical of industry Disease.
It is closely assembled design since AGM sealed lead accumulator uses barren liquor type, about 10% hole must be kept in partition Inaccurate electrolyte enters, thus the poor thermal conductivity of inside battery, thermal capacity are small.The oxygen that anode generates when charging reaches cathode and bears Pole lead can generate heat when reacting, and such as guide not in time, then battery temperature can be made to increase;If without reducing charging electricity in time Pressure, then charging current will increase, and analysis oxygen speed increases, and increases battery temperature in turn.Such vicious circle is gone down, just It can cause thermal runaway phenomenon, if it will be huge for can effectively solve thermal runaway problem social benefit.
China Patent No. are as follows: the utility model of CN207473061U provides a kind of single battery thermal runaway test device, packet Include station, multiple single batteries, multiple fixation kits, heating component and multiple temperature acquisition components;Single battery passes through solid Determine component to be fixed on station;Heating component is set on station and between multiple single battery, and heating component is used In conducting heat to single battery;Temperature acquisition component is set on fixation kit and temperature acquisition component acquires and fixation kit The real time temperature signal of adjacent single battery.The single battery thermal runaway test device that the utility model provides, can not go The real thermal runaway problem of effective solution, practical value is high.
Summary of the invention
(1) the technical issues of solving
The purpose of the present invention is overcome the deficiencies in the prior art, and the present invention provides a kind of automatic liquid supplies to prevent thermal runaway Battery, effective solution thermal runaway problem.
(2) technical solution
Technical solution of the present invention: a kind of automatic liquid supply prevents the battery of thermal runaway, including single lattice, busbar connector, fluid infusion bottle; Wherein: single lattice is sequentially connected, and both ends are provided with busbar connector in each single lattice, and a fluid infusion bottle, fluid infusion are placed in busbar connector Bottle includes upper cover and volumetric flask, and upper cover is fixedly connected with volumetric flask, and overflow port is distributed in upper cover, and the sealing of upper cover overflow port is using micro- Crystalline substance is sealed with wax dress, and a fluid infusion bottle is placed in each single lattice of battery, and fluid infusion bottle uses the PP material of acid-resistant and heat-resistant, amount of capacity root Determine according to different battery sizes;Fluid infusion bottle includes upper cover and volumetric flask, fluid infusion water needed for battery is loaded in volumetric flask (or Dilute sulfuric acid), when temperature reaches close to 70 DEG C of thermal runaway in battery, the microwax at porous place melts, the fluid infusion water in bottle Automatic outflow carries out water supplement, adds battery internal resistance moment after water to decline, so that charger is quickly turned lamp and enter floating charge state, avoid Thermal runaway phenomenon occurs for battery pack, while extending the service life of battery pack.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
Fig. 2 is the structural schematic diagram of fluid infusion bottle of the invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Embodiment 1 please refers to Fig. 1-Fig. 2, and a kind of automatic liquid supply prevents the battery of thermal runaway, including busbar unit lattice, Fluid infusion bottle, fluid infusion bottle include upper cover 1 and volumetric flask 2;Wherein: 1 overflow port of upper cover uses cellular structures, improves microwax Leakproofness while, it is ensured that any plane of structure has enough overflow ports, once thermal runaway, which occurs, leads to overtemperature in battery, capacity Water energy in bottle 2 all releases.
Embodiment 2, referring to Fig. 2, volumetric flask 2 size meet battery compartment space allow under conditions of, can basis Different battery capacities designs, example: the battery design capacity of 20AH is 10ml, i.e. 0.5ml/AH.
Embodiment 3, referring to Fig. 2, the present invention including but not limited to by other sealing modes such as microwax using transfiniting Temperature as automatic liquid supply physical switch.
Working principle:
Thermal runaway refers to: the charging for valve controlled sealed lead-acid accumulator, is that certain electric energy is input to battery In.Energy is converted to chemical energy.The oxygen of formation flows to negative plate, weakens herein and is combined to water again.During this, release Heat out makes battery become a heat generator.
Battery latter stage of charging electric current and temperature of the phase (or floating charge state) due under constant-voltage charge mode, making battery after charging A kind of cumulative mutual humidification occurs for degree, and the temperature of battery steeply rises at this time, the lasting accumulation of heat, cell voltage Begin to decline, it will a kind of uncontrolled, temperature occurs and increases, leads to battery thermal runaway, so as to cause battery case dilatancy, Damage.
Microwax is a kind of synthetic wax, and according to different purposes fusing points at 45~90 DEG C, automatic liquid supply device utilizes microwax The principle of low melting point is carried out to bottle sealing, is fully sealed under normal operating conditions, when thermal runaway generation occurs in battery pack When high temperature, when the temperature of inside battery reaches 70 DEG C, microwax starts to melt, and bottleneck loses sealing, and the water in bottle flows out automatically To fluid infusion is implemented in single lattice, the microwax of different melting points is may be selected in different battery cell case heatproof degree.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that There is also other identical elements in process, method, article or equipment including the element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (3)

1. a kind of automatic liquid supply prevents the battery of thermal runaway, including single lattice, busbar connector, fluid infusion bottle;It is characterized by: single lattice is successively It is connected, both ends are provided with busbar connector in each single lattice, and fluid infusion bottle is provided among busbar connector, and fluid infusion bottle includes upper cover and capacity Bottle, upper cover are fixedly connected with volumetric flask, and overflow port is distributed in upper cover, and the sealing of upper cover overflow port is encapsulated using microwax.
2. the battery that a kind of automatic liquid supply according to claim 1 prevents thermal runaway, it is characterised in that: upper cover overflow port is adopted Use cellular structures.
3. the battery that a kind of automatic liquid supply according to claim 1 prevents thermal runaway, it is characterised in that: fluid infusion bottle is using resistance to The PP material of sour heatproof.
CN201910796586.XA 2019-08-27 2019-08-27 A kind of automatic liquid supply prevents the battery of thermal runaway Pending CN110474015A (en)

Priority Applications (1)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07183026A (en) * 1993-12-22 1995-07-21 Japan Storage Battery Co Ltd Sealed lead-acid battery
JP2006236905A (en) * 2005-02-28 2006-09-07 Furukawa Battery Co Ltd:The Lead-acid battery
CN201146212Y (en) * 2008-01-21 2008-11-05 浙江超威电源有限公司 Lead acid accumulator
CN201773875U (en) * 2010-07-02 2011-03-23 超威电源有限公司 Battery cover with electrolyte replenishing structure
CN202236979U (en) * 2011-09-28 2012-05-30 陕西坚瑞消防股份有限公司 Portable fire extinguishing apparatus
CN104409794A (en) * 2014-11-19 2015-03-11 奇瑞汽车股份有限公司 Temperature management device of power battery pack of electric automobile, as well as manufacture method and application method thereof
JP6409093B1 (en) * 2017-04-26 2018-10-17 張乃文 Lead-acid battery packaging method and structure thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07183026A (en) * 1993-12-22 1995-07-21 Japan Storage Battery Co Ltd Sealed lead-acid battery
JP2006236905A (en) * 2005-02-28 2006-09-07 Furukawa Battery Co Ltd:The Lead-acid battery
CN201146212Y (en) * 2008-01-21 2008-11-05 浙江超威电源有限公司 Lead acid accumulator
CN201773875U (en) * 2010-07-02 2011-03-23 超威电源有限公司 Battery cover with electrolyte replenishing structure
CN202236979U (en) * 2011-09-28 2012-05-30 陕西坚瑞消防股份有限公司 Portable fire extinguishing apparatus
CN104409794A (en) * 2014-11-19 2015-03-11 奇瑞汽车股份有限公司 Temperature management device of power battery pack of electric automobile, as well as manufacture method and application method thereof
JP6409093B1 (en) * 2017-04-26 2018-10-17 張乃文 Lead-acid battery packaging method and structure thereof

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Application publication date: 20191119