CN1103809C - Aqueous personal cleansing compositions comprising specific nonocclusive liquid polyol fatty acid polyester - Google Patents
Aqueous personal cleansing compositions comprising specific nonocclusive liquid polyol fatty acid polyester Download PDFInfo
- Publication number
- CN1103809C CN1103809C CN96195413A CN96195413A CN1103809C CN 1103809 C CN1103809 C CN 1103809C CN 96195413 A CN96195413 A CN 96195413A CN 96195413 A CN96195413 A CN 96195413A CN 1103809 C CN1103809 C CN 1103809C
- Authority
- CN
- China
- Prior art keywords
- oil
- composition
- acid
- alkyl
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/226—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Molecular Biology (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
A personal cleansing composition comprising: (a) from about 1 % to about 30 % by weight of a dispersed oil phase comprising at least one nonocclusive liquid polyol fatty acid polyester containing at least four fatty acid ester groups wherein the polyol moiety is selected from sugars and sugar alcohols containing from about 4 to about 8 hydroxyl groups, and wherein each carboxylic acid moiety has from about 8 to about 22 carbon atoms and wherein the liquid polyol fatty acid polyester has a complete melting point of less than about 30 DEG C; and (b) from about 5 % to about 30 % by weight of water-soluble surfactant selected from anionic, nonionic, zwitterionic and amphoteric surfactants and mixtures thereof. The products provide excellent in-use and efficacy benefits including excellent skin feel during and after use, good lather volume and stability characteristics, skin conditioning, mildness, stability, cleansing, good water-feel and appearance.
Description
The present invention relates to cleaning compositions.Particularly relate to gentle personal cleaning compositions, it has good skin sense feature and the foam characteristics that is suitable for cleaning simultaneously with conditioning skin and/or hair, and it can use in a variety of forms, for example, foam bathing preparation, shower articles for use, skin cleaner, hand, face and body sanitising agent, shampoo or the like.
Gentle cosmetic composition need satisfy many standards, comprises cleaning force, whipability and skin, hair and eye mucus are had gentleness/low irritant/feel good.Skin is by which floor cellularity, and it coats and shielding angle albumen and collegen filament albumen, and they have constituted the skeleton of skin texture.Be known as cuticular this which floor most external, known is to be made of 250 dust protein bundles that surrounded by the thick layer of 80 dusts.Hair has the outermost protection covering of similarly sealing hair fiber, and this covering is called epidermis.Anion surfactant can see through cutin tunic and epidermis, and destroys the integrity of film by degreasing.This effect to skin and hair protective membrane can cause the pachylosis sense and to the stimulation of eye, and tensio-active agent and Keratin sulfate and hair protein are interacted, and causes the afunction of stimulations, barrier loss and reservation moisture content.
Ideal cosmetic clean-out system should leniently clean skin or hair, and often use can degreasing and/or made hair and xerosis cutis, also can exciting eye mucus or make skin tight.Many foaming perfumed soaps, shower and bath in a tub product, shampoo and soap bar are unsatisfactory in this respect.
Known some synthetic surfactant is gentle.But, to compare with the highest shampoo and the standard of soap bar, a major defect of the gentleest most synthetic surfactants is, when being used to prepare shampoo or individual and cleaning product, their character that spumes is relatively poor.Therefore those belong to the gentleest tensio-active agent, and for example lauryl glyceryl ether sulfonic acid sodium (AGS) all is not good enough aspect foaming.On the other hand, use known high foaming anion surfactant and foaming promotor,, sacrificed the flexibility of skin though can obtain acceptable froth quality and volume.These two kinds of factors make the favourable compound method of selection, whipability and the mildness of tensio-active agent become a delicate balance.
Although cosmetic industry has been carried out years of researches perhaps to personal cleanliness's product, consumers in general are the mildness of dissatisfied current cleaning compositions still, they find, for example after using shower or body washing agent, for keeping the fat abstraction of skin elasticity and moisture content, counteracting sanitising agent, need re-use other skin lotion or soothing cream.
Known in this fieldly in bath composition, add the good skin sense of oil after can be useful.But, add oil with the concentration that is enough to provide the benefit that the human consumer can notice and still prove a challenge, particularly in the presence of oil, have simultaneously emulsion form, stablize good bubbling character and provide ideal with the soft skin sense in back in, avoid undesirable " sliding/greasy " talent for swimming or oily outward appearance.With a large amount of oil is combined another relevant difficult point with conventional cleaning system is to obtain stable system, this system between the usage period oil be deposited on the skin with non-cunning form.Have now found that, adopt special polyol polyester oil component, can form the use neutralization and use fabulous skin sense feature in back and good lather volume, stability reaches the personal cleaning compositions of the sensorial characteristics relevant with the product stability that improves.Also find have the combination of oil component of specific oil/surfactant soln interfacial tension characteristic valuable especially to product stability and skin deposits characteristic.
Therefore need a kind of personal cleaning compositions, it can not make the skin dehydration or cause the skin elasticity loss, it will possess to a certain degree skin condition and skin moisten performance, this performance could obtain after having only the cleaning back to use the cosmetic wetting agent in addition in the past, and this composition can produce lather volume and the high-quality stable foam of outward appearance, it is effective hair and skin cleaner, but it has aesthetic feeling and rinsing feature in the good use, it has stable product and viscosity characteristics simultaneously, and keeps complete stability under long-term and strict storage temperature.
Theme of the present invention is a kind of gentleness, produces the foamy cleaning product that it is suitable for the cleaning of individual's skin or hair and can be used as foam having a bath and shower product, skin cleaner and shampoo etc.An aspect of of the present present invention provides a kind of personal cleaning compositions, and it comprises:
(a) the dispersion oil phase of weight (wt) about 1% to about 30%, it comprise oil/surfactant soln interfacial tension (IFT) greater than first kind of oil component of about 1.0 dyne/cm and surfactant soln interfacial tension (IFT) scope at second kind of oil component of about 0.1 to about 1.0 dyne/cm;
(b) about 5% to about 30% (wt) water miscible tensio-active agent, it is selected from negatively charged ion, nonionic, zwitter-ion and amphoterics and composition thereof; With
(c) water;
And wherein first kind and second kind of dispersed oil components in proportions scope are from about 20: 1 to about 1: 20.
In preferred embodiments, first kind of oil component is selected from polyol fatty acid polyesters, the nonocclusive liquid polyol fatty acid polyester that at least 4 lipid acid ester groups are particularly arranged, and wherein polyol moiety is selected from and contains 4 sugar and the sugar alcohols to about 8 hydroxyls of having an appointment, and wherein each carboxylic moiety has an appointment 8 to about 22 carbon atoms, and wherein liquid polyol fatty acid polyesters has and is lower than about 30 ℃ complete fusing point.
Another aspect of the present invention provides a kind of aqueous personal cleansing composition, and it comprises:
(a) about 1% disperseed oil phase to about 30% (wt), it comprises at least a non-liquid polyol fatty acid polyesters that 4 lipid acid ester groups are arranged that contains, wherein polyol moiety is selected from 4 sugar and the sugar alcohols to about 8 hydroxyls of having an appointment, and each carboxylic moiety has an appointment 8 to about 22 carbon atoms, and wherein the liquid polyol fatty acid polyester has one to be lower than about 30 ℃ complete fusing point; With
(b) about 5% to about 30% (wt) water miscible tensio-active agent, it is selected from negatively charged ion, nonionic, zwitter-ion and amphoterics and composition thereof.
In highly preferred embodiment, the present invention adopts and produces foamy cleaning compositions form, and it has superior foaming and stabilising characteristic, fabulous skin sense characteristic, the perceptible dry sensation that improves and the dry sensation of tight sense and expert's level, good cleaning power and conditioning performance.
Unless specialize, concentration that this paper is all and ratio are all in cleaning compositions weight.Unless specialize, the chain length of tensio-active agent is also based on the weighted average chain length.
Cleaning compositions of the present invention is based on the combination of a dispersible oil phase and a water soluble surfactant active system.In the preferred compositions, surfactant system comprises oily dispersive nonionogenic tenside and gentle cosurfactant, and the latter generally can be selected from other nonionic, negatively charged ion, both sexes and zwitterionics and composition thereof.The total amount of tensio-active agent comprises negatively charged ion, nonionic, zwitter-ion, both sexes and other tensio-active agent composition, is preferably about 5% to about 25%, more preferably from about 7% to 20%, preferred especially about 8% to about 16% (wt).Said composition preferably includes a mixture, and this mixture is by oily dispersive nonionic and anion surfactant is optional and auxiliary nonionic, zwitter-ion and/or amphoterics are formed.The total amount of cosurfactant is about 0.5% to about 15%, preferred about 1% to about 10%, more preferably from about 2% to about 6%, and the content preferably about 1% to about 25% of the diffusing nonionogenic tenside of oil content, preferred about 2% to about 15%, more preferably from about 3% arrive about 12%, preferred especially about 4% to about 8% (wt).The weight ratio of anion surfactant and auxiliary nonionic, zwitter-ion and/or amphoterics is about 8: 1 to about 1: 2.Cosurfactant and oil content loose the ratio of nonionogenic tenside preferably at 1: 10 to about 10: 1, and more preferably from about 1: 5 to about 5: 1, most preferably from about 1: 2 to about 2: 1.Preferred composition in the scope of the invention comprises nonionogenic tenside, oily and auxiliary negatively charged ion, zwitter-ion and/or amphoterics, wherein the content of dispersible oil phase is about 3% to about 25%, preferred about 8% to about 20%, more preferably from about 10% to about 15 (with composition weight meters), and diffusing nonionogenic tenside of oil content and dispersible oil phase weight ratio are about 1: 20 to about 3: 2, preferred about 1: 6 to about 1: 2, more preferably from about 1: 4 to about 1: 3.
Disperse the oil phase preferred package to contain the mixture of first and second oil components of the oil/surfactant soln interfacial tension characteristic according to them, this combination is optimum for transmitting the heavy characteristic of ideal emulsion stabilization and skin.
The measurement of oil/surfactant interface tension force (IFT) shows that surfactant soln can be the degree of the minimizing of the IFT between oil component and water.The IFT measurement is to drip (drop) interfacial tension survey meter and spend the Clark water hardness (428ppm CaCO at 40-50 ℃ and 21 with spin
3) and the aqueous tenside concentration of 75ppm under carry out.In this test, preferably the surfactant system of usefulness is the surfactant system of final cleaning compositions.At the place that goes wrong, or in order to shield (screening) purpose, can adopt the standard aqueous surfactant soln, it comprises a mixture, and this mixture is formed with about 4: 1 weight ratio by ethoxyquin alkyl sulfuric ester that 2 ethoxylation groups are arranged and alkyl N-methyl glucose amide.Measurement is carried out under pH7 and is provided with the mean value of 2,5 and 10 minutes interfacial tension reading.
" interfacial tension " herein (IFT) refers to the tension force that oil/water termination records, the measurement of IFT is to drip (drop) technology with spin, by Cafas, Schechter and Wade are in " dripping the commercial measurement low interfacial tension by spin ", ACS (American Chemical Society) symposium Series No.8 (1975), start from 234 pages absorption at the interface, in disclosed.
Be suitable for adding the mixture that dispersion oil phase preferred package of the present invention contains first kind and second kind oil component, wherein in preferred embodiments, first kind of oil component comprises a kind of polyol polyester and second kind of oil component and comprises and be selected from hydrocarbon, one or more oils of lanolin and lanolin derivative and animal and plant triglyceride level.Use the mixing oil system for effectively oil being emulsifiable in the product matrix and they all are valuable in skin surface sedimentation subsequently during the product dilution in using.The applicant finds to have the composition of oil component in the blended the first/the second and the product that only contains first kind or second kind oil component to compare, and the former in use with after using can improve the skin sense.
The total content of first kind and second kind dispersive oil component about 1% to about 30%, preferred about 3% to about 25%, more preferably from about 8% to about 20%, most preferably from about 10% arrive about 15% (wt), wherein the weight ratio scope of first kind of oil component and second kind of oil component is about 20: 1 to about 1: 20, preferred about 8: 1 to about 1: 8, more preferably from about 4: 1 to about 1: 4.
In composition very preferably, dispersible oil phase comprises non-liquid that contains or liquable polyol fatty acid polyesters, the special liquid polyol fatty acid polyesters that at least 4 lipid acid ester groups are preferably arranged, and wherein polyol moiety is selected from and has an appointment 4 to the sugar or the sugar alcohols of about 8 hydroxyls, and wherein each carboxy moiety have an appointment 8 to about 22 carbon atoms and wherein the complete fusing point of liquid polyol fatty acid polyesters be lower than about 30 ℃.
Polyester also preferably has oil/tensio-active agent IFT greater than about 1.0dynes/cm, preferred about 1.1 to about 4.0, more preferably from about 1.2 to about 3.0 and particularly about 1.3 to about 2.0dynes/cm (under above-mentioned standard conditions, measuring), and its content about 1% to about 10%, preferred about 1% to about 5%, and more preferably from about 2% to about 4% (wt).
The liquid polyol polyester that is preferred for this composition comprises some polyvalent alcohol, particularly uses the sugar or the sugar alcohol of at least 4 fatty acid-based esterifications.Correspondingly, but the preferred polyhydric alcohols initial feed should have the hydroxyl of at least 4 esterifications, and the preferred polyhydric alcohols example is a sugar, comprises monose and disaccharides and sugar alcohol.The monose example that 4 hydroxyls are arranged is wood sugar and arabinose, and sugar alcohol is derived from wood sugar, and it has 5 hydroxyls, i.e. Xylitols.This monose of erythrose is not preferred in use of the present invention, because of it only has 3 hydroxyls, still is derived from the sugar alcohol of erythrose, and tetrahydroxybutane has 4 hydroxyls therefore available.The suitable monose that contains 5 hydroxyls is semi-lactosi, and fructose and sorbose contain the sugar alcohol of the hydrolyzate that is derived from sucrose and glucose and sorbose of 6 hydroxyls, and for example Sorbitol Powder also is suitable.The example of available two sugar polyols comprises maltose, lactose and sucrose, and they all contain 8 hydroxyls.
The preferred polyol that preparation is used for polyester of the present invention is selected from tetrahydroxybutane, Xylitol, Sorbitol Powder, dextrose plus saccharose, special preferably sucrose.
Have the preferred polyol parent material of at least 4 hydroxyls with containing 8 lipid acid to about 22 carbon atoms of having an appointment its at least 4 hydroxyls to be carried out esterification, it is sad that the example of these lipid acid comprises, capric acid, lauric acid, tetradecanoic acid, palmitinic acid (Palmiticacid), palmitolic acid, stearic acid, oleic acid, ricinolic acid, linolic acid, linolenic acid, eleostearic acid, eicosanoic acid, arachidonic acid, mountain Yu acid and erucic acid.Lipid acid can be derived from natural existence or synthetic lipid acid; They are saturated or undersaturated, comprise positional isomers and geometrical isomer.But preferably be suitable for liquid polyester of the present invention in order to provide, the lipid acid that joins in the polyester molecule should be undersaturated at least about 50% weight, preferred especially oleic acid and linolic acid, and their mixture.
Be used for polyol fatty acid polyesters of the present invention and preferably have at least 4 lipid acid ester groups, and all hydroxyls that needn't polyvalent alcohol are all by fatty acid esterification, but preferred polyester contains only 2 nonesterified hydroxyls.Most preferably, all hydroxyls of polyvalent alcohol are all by the esterification of lipid acid institute basically, and promptly polyol moiety is by basic thoroughly esterification.The lipid acid of esterification polyol molecule is of the same race or blended, but as above indicated, must have a large amount of unsaturated acid ester groups to exist to provide mobile.
For illustrating above viewpoint, sucrose four fatty acid esters are suitable of the present invention, but it is not preferred, because it has more than 2 nonesterified hydroxyls.Sucrose six fatty acid esters are preferred, because it only has 2 nonesterified hydroxyls, to compound very preferably, its all hydroxyls comprise liquid sugar eight substituted fatty acid esters all by fatty acid esterification.
Be the nonrestrictive example that is preferred for specific polyol fatty acid polyesters of the present invention that contains at least 4 lipid acid ester groups below: glucose four oleic acid esters, glucose four soybean fat acid esters (undersaturated), seminose four mixing soya beans fatty acid oil esters, semi-lactosi four oleic acid esters, arabinose four linoleate, wood sugar four linoleate, semi-lactosi five oleic acid esters, sorbyl alcohol four oleic acid esters, sorbyl alcohol six unsaturated soya fatty acid esters, Xylitol five oleic acid esters, sucrose four oleic acid esters, sucrose five oleic acid esters, sucrose six oleic acid esters, sucrose seven oleic acid esters, sucrose eight oleic acid esters, and their mixture.
As above indicated, polyhydric alcohol fatty acid ester very preferably is those 14 lipid acid to about 18 carbon atoms of wherein having an appointment.
Preferred be fit to liquid polyol polyester of the present invention and be lower than about 30 ℃, preferably be lower than about 27.5 ℃, fusing point is completely arranged more preferably less than about 25 ℃, Bao Dao complete fusing point is measured by differential thermal analysis (DSC) herein.
Available those prepared in various methods well-known in the art are suitable for polyol fatty acid polyesters of the present invention, and these methods comprise: use methyl, ethyl or the glycerol fatty acid ester transesterification to polyvalent alcohol under various catalyzer; The lipid acid acyl chlorides is to the acidylate of polyvalent alcohol; Fatty acid anhydride is to the acidylate of polyvalent alcohol; With the acidylate of lipid acid itself to polyvalent alcohol.Referring to US-A-2,831,854; US-A-4,005,196, Jandacek, on January 25th, 1977; US-A-4,005,196, to Jandacek is published on January 25th, 1977.
The preferred first kind of oil component of said composition is liquid sugar eight substituted fatty acid esters according to the present invention.
Composition of the present invention also can further be included in the other oil component that disperses in the oil phase, and preferred oil component in addition is nonpolar oil.The IFT scope about 0.1 to about 1.0dynes/cm of second kind of oil component very preferably, preferred about 0.2 to about 0.9, more preferably from about 03 to about 0.7dynes/cm (measuring under the above-mentioned standard conditions) and its content about 1% to about 20%, preferred about 5% to about 15%, and more preferably from about 8% to about 15% (wt).
Be applicable to that the other oil component of oil phase that disperses of the present invention comprises hydrocarbon, lanolin and animal and vegetable triglyceride such as mineral oil, Vaseline and squalene, fat dehydration sorb ester is (referring to US-A-3988255, Seiden, on October 26th, 1976), the lanolin derivative of lanolin and class oil, the immiscible property of water siloxanes comprises non-volatile poly-alkyl and poly-aryl siloxanes natural gum and fluid, volatile cyclic and linear poly-alkylsiloxane, the siloxanes of poly-alkoxylation, the siloxanes of amino and quaternary ammonium modification, rigidity crosslinked with siloxanes that strengthen and their mixture, C
8-C
30The C of lipid acid
1-C
24Ester such as Isopropyl myristate and ricinolic acid cetyl ester, beeswax, the C of saturated and unsaturated fatty alcohol such as behenyl alcohol, Prunus amygdalus oil, peanut oil, wheat germ oil, Toenol 1140, simmondsia oil, Apricot kernel oil, walnut oil, palm-nut oil, pistachio oil, sesame seed oil, rapeseed oil, Du's pine nut oil, Semen Maydis oil, peach oil, poppy seed oil, pine nut oil, Viscotrol C, soybean oil, Lipoval A, Thistle oil, Oleum Cocois, hazelnut oil, sweet oil, raisin seed oil and sunflower oil and dimeracid and trimer acid
1-C
24Ester such as dimeracid diisopropyl ester, apple acid two isooctadecane base esters, dimeracid two isooctadecane base esters and trimer acid three isooctadecane base esters and their mixture.
Most preferred second kind of oil component is non-polar oil, and it is selected from mineral oil, Vaseline, and the immiscible property of water siloxanes, soya-bean oil and resemblance thereof and their mixture, being particularly suitable for of the present invention is mineral oil.
Preferred compositions comprises an oily dispersive nonionogenic tenside, and its content about 1% is to about 25%, preferred about 2% to about 15%, and more preferably from about 3% to about 12%, most preferably from about 4% to about 8% (wt).
The diffusing nonionogenic tenside of oil content that is fit to the adding present composition has the diffusing characteristic of fabulous oil content, and this can be confirmed by microscopic examination and dip test.
In order to confirm that nonionogenic tenside is suitable for adding in the composition of the present invention, prepared to comprise the test matrix of nonionogenic tenside to be measured and other composition composition.Use the part of the microscopic examination prototype of the NikonOptipot-2 little viewer of type image (Videomicrowatcher).Be suitable for adding the common evenly product matrix of (opaque) that generates of tensio-active agent of composition of the present invention, wherein the mean diameter of oil droplet is about 1 to about 30 microns, and preferred about 2 arrive about 20 microns.
But be fit to the dispersed oil system very preferably according to composition of the present invention, the mean oil droplet size of measuring with the little viewer of NikonOptipot-2 type image about 3 arrives about 10 microns.
In dip test the assessment former mold base use the time feature.In fact, 6 milliliters former mold base is scattered in 40 ℃ 20 premium on currency.Estimate the physical appearance of gained solution then.As long as desired skin sense can be provided in addition, the composition of the solution of the muddiness of the oil droplet that wherein is invisible to the naked eye (cloud) is called as and shows perfect performance.
The oil content that is suitable for adding the present composition nonionogenic tenside that looses is selected from C
12-C
18Polyhydroxy fatty amido tensio-active agent, preferred C
12-C
16Polyhydroxy fatty amido tensio-active agent, more preferably C
12-C
14Polyhydroxy fatty amido tensio-active agent, it has following general formula (I):
Preferred N-alkyl, N-alkoxyl group or N-aryloxy, polyhydroxy fatty amido tensio-active agent are those wherein R
8Be C
5-C
31Alkyl, C preferably
9-C
17Alkyl comprises alkyl and alkenyl or its mixture and the R of straight or branched
9C normally
1-C
8Alkyl or hydroxyalkyl, preferable methyl or formula-R
1-O-R
2Group, R wherein
1Be C
2-C
8Comprise straight chain, side chain or the ring-type alkyl of (comprising phenyl), be preferably C
2-C
4Alkenyl, R
2Be C
1-C
8Straight chain, side chain or cyclic alkyl, comprise aryl and oxygen base alkyl, and preferred C
1-C
4Alkyl, particularly methyl or phenyl.Z
2It is the polyhydroxy alkyl part, it has linear alkyl chain, wherein have two (when being Glycerose) at least or have at least three (when being other reducing sugar) hydroxyls to be directly connected on this hydrocarbon chain, or the derivative of its alkoxylate (preferred ethoxylation or propoxylation).Z
2The reducing sugar that is preferably in the reduction amination is derived, Z
2Most preferably be glycosyl (glycityl).Suitable reducing sugar comprises glucose, fructose, maltose, lactose, semi-lactosi, seminose and wood sugar and Glycerose etc.As starting material, each sugar that can utilize high glucose maize treacle, high-fructose corn syrup and high malt sugar maize treacle and list above.These maize treacle can produce a kind of sugared mixture of ingredients as Z
2Should be appreciated that and do not get rid of other proper raw material.Z
2Be preferably and be selected from-CH
2(CHOH)
n-CH
2OH ,-CH (CH
2OH)-(CHOH)
N-1-CH
2OH ,-CH
2-(CHOH)
2(CHOR ') (CHOH)-CH
2OH, wherein n is 1 to 5 integer (containing 1 and 5), and R ' is monose or polysaccharide and its oxyalkylated derivative of hydrogen or cyclic.Most preferred for n wherein is 4 glycosyl, particularly-CH
2(CHOH)
4-CH
2OH.
In the compound of following formula, R
8-CO-N＜can be for example cocoa amido, stearyl amino, oleoyl amino, lauroyl amino, mnyristoyl amino, certain herbaceous plants with big flowers amido, palmityl amino, butter amido or the like.
The preferred method for preparing following formula (I) compound comprises the polyhydroxy amine reaction of a kind of fatty acid triglycercide and N-replacement, reacts essentially no rudimentary (C
1-C
4) the alcoholic solvent existence, but preferably have oxyalkylated alcohol or alkoxylated alkyl group phenol, for example NEODOL, and use alkoxide catalyzer, temperature is 50～140 degrees centigrade, obtains the required product of high yield (90～98%) with this.The appropriate steps for preparing required polyhydroxy fatty acid amide material is outlined in US-A-5, and 194,639 and US-A-5,380,891.
The structural formula of most preferred polyhydroxy fatty amido is R
8(CO) N (CH
3) CH
2(CHOH)
4CH
2OH, wherein R
8Be C
11-C
17Straight chained alkyl or alkenyl.
Surfactant system comprises an oily dispersive nonionogenic tenside and a cosurfactant in preferred compositions, and wherein cosurfactant is selected from negatively charged ion, zwitter-ion, both sexes and auxiliary nonionogenic tenside and their mixture.The content of cosurfactant about 0.5% is to about 15%, preferred about 1% to about 10%, and more preferably from about 2% to about 6% (wt).
The anion surfactant that is suitable for adding the present composition is generally gentle synthesis of detergent tensio-active agent; the alkyl-sulphate that comprises ethoxylation; alkyl glycerol ether sulfonate; methyl-acyl taurine salt; fat acidyl glycine salt; the N-acyl glutamate; acyl isethinate; salts of alkyl sulfosuccinates salt; α-sulfonated lipid acid, their salt and/or ester, alkyl ethoxy carboxylate, alkyl phosphate; the alkyl phosphate of ethoxylation, acyl sarcosinate and lipid acid/protein condenses and their mixture.The alkyl of these tensio-active agents and/or acyl group chain length are C
8-C
22, be preferably C
10-C
18
From the mildness and the bubbling character viewpoint of the best, preferably being suitable for of the present invention is 1 mole high fatty alcohol and about 1 salt to the sulfuric ester of the reaction product of about 12 moles oxyethane, and its counter ion is preferably sodium and magnesium.Particularly preferably be and contain about 2 to 6, the alkyl-sulphate of preferred 2 to 4 moles oxyethane, for example dodecyl Soxylat A 25-7 2 (laureth-2) sodium sulfate, dodecyl Soxylat A 25-7 3 (laureth-3) sodium sulfate and dodecyl Soxylat A 25-7 3.6 (laureth-3.6) sal epsom sodium.In preferred embodiments, anion surfactant contains at least 50%, especially at least about the alkyl-sulphate of the ethoxylation of 75% (wt).
Composition of the present invention also is fit to comprise a kind of amphoterics.The amphoterics that is applicable to composition of the present invention comprises:
(a) imidazoline surfactant of formula (II):
R wherein
1Be C
7-C
22Alkyl or alkenyl, R
2Be hydrogen or CH
2Z, each Z is respectively CO
2M or CH
2CO
2M, and M is H, basic metal, alkaline-earth metal, ammonium or alkanol ammonium; And/or the derivative of the ammonium of formula (III):
R wherein
1, R
2Define as above with Z.
(b) the amino-alkane hydrochlorate of formula (IV):
R
1NH(CH
2)
nCO
2M
The iminodiacetic alkanoate of formula V:
R
1N[(CH
2)
mCO
2M]
2
Wherein n and m are 1 to 4 number, and R
1With M is independently to be selected from above-mentioned specified group; With
(c) their mixture.
(a) the suitable amphoterics of type is sold with trade(brand)name Miranol and Empigen, and thinks that they have comprised the complex mixture of each material.Think that traditionally Miranol has the structure of formula II, though the 4th edition of CTFA cosmetic ingredient dictionary shows that it is the structure of non-annularity formula III.In fact, may for the purpose of complete, provide two definition for the complex mixture of ring-type and non-annularity material.Even so, being preferred for of the present invention is acyclic material.
(a) example of the suitable amphoterics of type comprises the compound of formula II and/or formula III, R wherein
1Be C
8H
17(particularly iso-octyl), C
9H
19And C
11H
23Alkyl.Particularly preferably be wherein R
1Be C
9H
19, Z is CO
2M and R
2Compound for H; R wherein
1Be C
11H
23, Z is CO
2M and R
2Be CH
2CO
2The compound of M; And R wherein
1Be C
11H
23, Z is CO
2M and R
2Compound for H.
In CTFA name, the material that is preferred among the present invention comprises coconut both sexes carboxyl propionic ester, coconut both sexes carboxyl propionic acid, and particularly coconut both sexes acetic ester and coconut both sexes diacetate esters (can be described as coconut both sexes carboxyl glycinate in addition).Concrete commercially available prod comprises with following trade(brand)name product sold: Empigen CDL60 and CDR60 (Albright; Wilson), Miranol H2MConc.Miranol C2M Conc.N.P., Miranol C2M Conc.O.P., Miranol C2M SF, Miranol CM Special (Rhone-Poulenc); Alkateric 2CIB (Alkaril Chemicals); Amphoterge W-2 (Lonza, Inc.); Monateric CDX-38, Monateric CSH-32 (MonaIndustries); Rewoteric AM-2C (Rewo Chemical Group); With Schercotic MS-2 (Scher Chemicals).
Be to be understood that, the obtainable amphoterics in more such markets is with the form produce and market of electric neutrality mixture, they have for example hydroxide radical counter ion or anion sulfate acid ester (salt) or sulphonate (salt) tensio-active agent, particularly those Sulfated C
8-C
18Alcohol, C
8-C
18The alcohol of ethoxylation or C
8-C
18The acyl glyceride type.But from the viewpoint of mildness and product stability, preferred compositions is substantially free of (non-ethoxylatedization) Sulfated pure tensio-active agent.It should be noted the concentration and the surfactants based non-complexed forms formula of weight ratio of amphoterics simultaneously, the counter ion of any anion surfactant is all regarded the part of total anion surfactant component content as.
(b) example of the amphoterics that is fit to of type comprises salt, particularly tri ethanol ammonium salt and N-lauryl-β-An Jibingsuan salt and N-lauryl-imino--dipropionate.Such material is sold by Henkel with the Deriphat trade(brand)name and is sold by Rhone Poulenc with the Mirataine trade(brand)name.But the amphoterics that preferably uses is the material of formula II and/or formula III herein.
Composition of the present invention also can contain auxiliary nonionogenic tenside.Be applicable to that auxiliary nonionogenic tenside herein can be selected from C
12-C
14Lipid acid list and di-methylcarbinol acid amides and sucrose polyester tensio-active agent, come from the softener (oily deutero-) of water-soluble plant and animal, for example embed the triglyceride level of polyglycol chain; The mono and di-glycerides of ethoxylation, the lanolin of many ethoxylations and shea butter derivative and composition thereof.The auxiliary nonionogenic tenside of the preferred oily deutero-of one class has following general formula (VI):
Wherein n is about 5 to about 200, and preferred about 20 to about 100, and more preferably from about 30 to about 85, and wherein R comprises an aliphatic group, and it has average about 5 to about 20 carbon atoms, preferred about 9 to 18 carbon atoms.
The oil ﹠ fat of this suitable class ethoxylation comprises the polyethyleneglycol derivative of following material: glycerine coconut ester, caproin, glycerol caprylate, glycerine butter ester, palmitic acid glyceride, Vinlub, glycerol laurate, oleic acid glyceride, glycerine ricinoleate ester and the glycerol fatty acid ester that is derived from triglyceride level, for example plam oil, Prunus amygdalus oil and Semen Maydis oil, preferably glycerine butter ester and glycerine coconut ester.
The suitable auxiliary nonionogenic tenside of this class oil deutero-can be by Croda Inc. (NewYork, USA) obtain with its Crovol series material, for example, Crovol EP40 (PEG20 primrose in night glyceryl ester), Crovol EP70 (PEG60 primrose in night glyceryl ester), Crovol A-40 (PEG20 almond glyceryl ester), Crovol A-70 (PEG60 almond glyceryl ester), Crovol M-40 (PEG20 corn glyceryl ester), Crovol M-70 (PEG60 corn glyceryl ester), Crovol PK-40 (PEG12 palm nuclear glyceryl ester), and Crovol PK-70 (PEG45 palm nuclear glyceryl ester), also have Solan series material, for example Solan E, the ethylating wool grease of the polyoxy of E50 and X.Also preferred especially PEG (6) capric acid/caprylin (softigen 767).The suitable tensio-active agent of other this class can (Dublin, ohio USA) obtain, and sell with the form of Varonic LI series of surfactants by Sherex ChemicalCo..These comprise, for example, and Varonic LI 48 (polyoxyethylene glycol (n=80) glycerine butter ester is also referred to as PEG80 glycerine butter ester in addition), Varonic LI2 (PEG28 glycerine butter ester); Varonic LI420 (PEG200 glycerine butter ester) and Varonic LI63 and 67 (PEG30 and PEG80 glycerine coconut ester).The water-soluble plant deutero-softener that other is suitable for using be Semen Maydis oil, Lipoval A and babassu oil the PEG derivative.
The auxiliary nonionogenic tenside that is suitable for herein is derived from composite plant fat or derivatives thereof, refines in the fruit of this composite plant fat by Butyrospermum Parkii (Butyrospermum Karkii Kotschy).This vegetation fat that is referred to as shea butter in non-area widely use, soap system and make cold cream for example, it is sold by Sederma (78610 Le Perray En Yvelines, France).The also derivative of the ethoxylation of shea butter alternatively, by Karlshamn Chemical Co. (Columbos, Ohio, the U.S.) sell, be Lipex series chemical, Lipex 102E-75 (list of the ethoxylation of shea butter or double glyceride) and sell with its Crovol series material from Croda company (New York) for example is as Crovol SB70 (RTM) (shea butter of ethoxylation).Similarly, the derivative of the ethoxylation of mango oil, theobroma oil and Illipe fat also can be used in the composition of the present invention.Though the nonionogenic tenside that these classify as ethoxylation should be appreciated that the vegetables oil or the fat that still have certain proportion to be left non-ethoxylatedization.
Other suitable ionic surfactant pack derived from oil is drawn together the derivative of the ethoxyquin of following oil: Prunus amygdalus oil, peanut oil, wheat germ oil, Toenol 1140, simmondsia oil, apricot line oil, walnut oil, palm-nut oil, pistachio oil, sesame seed oil, rapeseed oil, Du's pine nut oil, Semen Maydis oil, peach oil, poppyseed oil, pine nut oil, Viscotrol C, soya-bean oil, Lipoval A, Thistle oil, Oleum Cocois, hazelnut oil, sweet oil, raisin seed oil and Sunflower Receptacle wet goods.
From the mildness of the best and the viewpoint of skin sense feature, the auxiliary nonionogenic tenside of oily deutero-very preferably used herein is PEG60 primrose in a night triglyceride level; The derivative of the derivative of PEG55 lanolin polyethoxylated and the ethoxylation of shea butter.
Composition of the present invention preferably also contains zwitterionics.
The beet alkali surface activator that is suitable for adding the present composition comprises formula R
5R
6R
7N
+(CH
2)
nThe amido betaines of the alkyl betaine of M (VII) and formula (VIII):
Wherein, R
5Be C
12-C
22Alkyl or alkenyl, R
6And R
7Be C independently
1-C
3Alkyl, M are H, basic metal, alkaline-earth metal, ammonium or alkanol ammonium, and n, and each is arbitrary numeral of 1 to 4 for m.Preferred trimethyl-glycine comprises coconut amido propyl-dimethyl carboxymethyl betaine, lauryl amido propyl-dimethyl carboxymethyl betaine and Tego trimethyl-glycine (RTM).
Water-soluble auxiliary sultaine (sultaine) tensio-active agent of the suitable adding present composition comprises the alkyl sultaine of formula (IX);
R wherein
1Be C
7-C
22Alkyl or alkenyl, R
2And R
3Be C independently
1-C
3Alkyl, M are H, basic metal, and alkaline-earth metal, ammonium or alkanol ammonium and m and n are 1 to 4 numerals, preferably being suitable for of the present invention is coconut amido third hydroxyl sulfo betaine.
The water-soluble assisted oxidation amine tensio-active agent of the suitable adding present composition comprises oxidation of alkyl amine R
5R
6R
7The amide group amine oxide of NO and formula (X)
R wherein
5Be C
11-C
22Alkyl or alkenyl, R
6And R
7Be C independently
1-C
3Alkyl, M are H, basic metal, and alkaline-earth metal, ammonium or alkanol ammonium and m are 1 to 4 numerals.Preferred amine oxide comprises oxidation coconut monoethanolamide base propylamine, oxidation lauryl dimethyl amine and oxidation myristyl dimethyl amine.
But composition of the present invention is cation or non-ionic polymeric skin or hair conditioner also, and content is about 0.01% to about 5%, preferred about 0.04% to about 2%, preferred especially about 0.05% to about 1% (wt).Find these polymkeric substance to improve slip and froth quality and hair is provided and skin conditioning extremely valuable.
Suitable polymers is high-molecular weight material (weight-average molecular weight is measured, and for example light scattering method generally arrives about 3,000,000, preferred about 5,000 to about 1,000,000 from about 2,000).
Useful polymkeric substance is those positively charged ions that are applied to cosmetic field, nonionic, both sexes and anionic polymkeric substance.Positively charged ion and the non-ionic polymers used of cosmetic field preferably as hair or skin conditioning agent.
The representative classification of polymkeric substance comprises positively charged ion and nonionic polysaccharide; The positively charged ion of derived from propylene acid and/or methacrylic acid and nonionic homopolymer and multipolymer; Positively charged ion and non-ionic cellulose resin; Dimethyl diallyl ammonium chloride and acrylic acid cationic copolymer; The cationic homopolymer of dimethyl diallyl ammonium chloride; Positively charged ion polyolefine and oxyethyl group polyalkylene imine; Quaternised siloxanes and their mixture.
By way of example, the cationic polymers that is suitable for herein using comprises cationic guar gum, Hydroxyproyl Trimethyl ammonium guar gum (substitution value (d.s) is 0.11 to 0.22) for example, with trade(brand)name Jaguar C-14-S (RTM), Jaguar C-17 (RTM) and Jaguar C-16 (RTM) in market sale, it is except that containing above-mentioned cation group, also contain hydroxypropyl substituting group (d.s.0.8-1.1), and the quaternised ether of cellulose of selling with trade(brand)name UcarePolymer JR and Celquat.Other cationic polymers that is suitable for is that trade(brand)name is the multipolymer of multipolymer, dimethyl amino ethyl methacrylate and the acrylamido of the dimethyl diallyl ammonium chloride sold with Merquat100, the acrylate of the quaternised vinyl pyrrolidone of the multipolymer of the dimethyl diallyl ammonium chloride sold with trade(brand)name Merquat550 and Merquat S and acrylamido, the amino alcohol sold with trade(brand)name Gafquat or the multipolymer of methacrylic ester, and the polyalkylene imine polymine of polymine and ethoxylation for example.
The non-ionic polymers that is applicable to the present composition comprises any conventional non-ionic polymers that uses, and preferably those Pluronic that can buy by BASF and Synperonic bunch polyoxyethylene polyoxypropylene block copolymer, for example Pluronic L-121 and from ICI bought as Synperonic PE-F127.
The anionic polymer of Shi Yonging comprises the cross-linked polymer with amphipathic acrylic acid hydrophobically modified herein, and it is sold by BF Goodrich with trade(brand)name Pemulen TRI and Pemulen TR2; And the carboxy vinyl polymer of selling by BF Goodrich with trade mark Carbopol, it contains by vinylformic acid and polyene propyl group sugar or the crosslinked polymkeric substance of polyene propyl group tetramethylolmethane, for example, and Carbopol 934,940 and 950.
The viscosity of final composition (Helipath, Spindle A, 10rpm, 25 ℃, pure substance) is preferably at least about 500 centipoises (CPS), and more preferably from about 1,000 to about 10,000 centipoises, and preferred about 1,000 to about 5,000 centipoises especially.
This cleaning compositions can be chosen wantonly and contain hair or the skin moisturizing agent that is dissolved in the cleaning compositions matrix.Moisturizing agent content preferably about 0.5% to about 20% (wt).In preferred embodiments, moisturizing agent is selected from:
1. liquid water-soluble polyalcohols;
2. the naturally occurring indispensable amino acid compound of in keratoderma, finding; With
3. non-occlusions of water-soluble non-polyvalent alcohol and composition thereof.
Preferred non-some examples that contain moisturizing agent are: the protein and the protein derived protein of other collegen filament of the polyoxyethylene glycol of the polyoxyethylene glycol of glycerine, polyoxyethylene glycol, propylene glycol, sorbyl alcohol, methyl glucoside (as methyl gluceth-20) and the ether of propylene glycol, Wool wax alcohol (as Solulan-75) and the ether of propylene glycol, pyrrolidone sodium carboxylate, lactic acid, urea, L-proline(Pro), citrulline, pyrrolidone, hydrolysis, Aloe gel and acetate single ethanol amide (acetamide MEA) and composition thereof.In above-mentioned each material, glycerine is extremely preferred.
The other optional components of the present composition is the adducts by the vegetables oil preparation that contains unconjugated poly-unsaturated fatty acid ester, it is that conjugation and elaidic acid are reset, and passes through Diels-Alder (diels-alder) addition modification with a member in vinylformic acid, fumaric acid and the maleic anhydride group then.Preferred vegetables oil adducts has following general formula (X).
X wherein, Y is 3 to 9 integer, R
3And R
4Be independently selected from saturated and undersaturated C
7-C
22Alkyl, each Z is CO
2M and wherein M be H, or the positively charged ion of salt formation, preferred as alkali, ammonium or alkanol ammonium.US-A-4740367 has the description of adducts and preparation thereof, and adducts is sold with commodity Ceraphyl GA (Van Dyke) by name on market.The vegetables oil adducts adds preferably about 0.01% to about 5%, preferred about 0.05% to about 2%, and more preferably from about 0.1% to about 1% (composition weight).
Composition of the present invention also can comprise a stabiliser system, and the preferred stable system that is suitable for adding composition of the present invention comprises the main and secondary stablizer, and wherein main stabilizer is the clay or the argillaceous material of any modification, and inferior stablizer is a mixed polysaccharide glue.Use the blended stabiliser system to help providing foam, can improve the skin sense simultaneously with good volume, stability and external appearance characteristic.
The total content of main and secondary stablizer is about 0.01% to about 15% by weight, be preferably about 0.05% to about 12%, more preferably about 0.1% to about 10%, most preferably be about 0.5% to about 5%, wherein the ratio of main stabilizer and time stablizer is about 32: 1 to about 1: 1, be preferably about 16: 1 to about 1: 1, more preferably about 4: 1 to about 2: 1.
In preferred compositions of the present invention, main stabilizer is the clay-based material of modification.
Be suitable for main suspension agent of the present invention and comprise magnesium aluminum silicate (Al
2Mg
8Si
2), wilkinite, hectorite and their derivative.Natural terre verte material for example colemanite, talcum powder and the sapphire of being conigenous of magnesium aluminum silicate.The refining magnesium aluminum silicate of Shi Heing can be bought from R.T.Vanderbilt company herein, and commodity are called Veegum (RTM), buys from ECC America, and commodity are called Gelwhite MAS-H (RTM).The magnesium aluminum silicate material of modification for example magnesium aluminum silicate CMC can be bought from R.T.Vanderbilt company, and commodity are called Veegum Plus (RTM).The clay material of this modification contains the smectic clays with Xylo-Mucine and titanium dioxide.Wilkinite is the aluminum silicate clay of the colloidal of natural hydration, and it can buy the ECC in the U.S., and commodity are called Bentonite H (RTM), also can buy in Whittaker Clark; Daniels, commodity are called Mineral Colloid BP2430 (RTM).Hectorite is a kind of montmorillonite mineral, and it is the main component of POLARGEL NF.Hectorite can be bought the company in Rheox, commodity Bentone EW (RTM) by name and Macaloid (RTM).
Preferred main stabilizer is magnesium aluminum silicate/CMC, and it can be bought from R.T.Vanderbilt company, and commodity are called Veegum Plus (RTM).
Preferred stablizer of the present composition is xanthan gum (xanthan/corn carbohydrate gum), and it is the molecular weight that formed by carbohydrate and campestris xanthomonas (Xanthomonas campestris) pure culture fermentation greater than about 1,000,000 mixed polysaccharide glue.It is considered to contain molar ratio is 2.8: 2.0: 2.0 D-glucose, D-seminose and D-Glucoronate.Polysaccharide carries out partial acetylation with 4.7% ethanoyl.This biosynthetic sizing material can be bought from Calgon company, and commodity are called Kelgum CG (RTM), from Kelko (Merck; Co. the branch of company), Meer and R.T.Vanderbilt company buy, and trade(brand)name is respectively Keltrol (RTM), and Merezan 8 (RTM) and Rhodigel (RTM) also can be from other source acquisitions.Xanthan gum mixtures can be bought in Calgon, Alban Muller or the like, and also be fit to add in the composition of the present invention.Further information about xanthan gum can be referring to industrial glue-polysaccharide and the derivative thereof of Whistler.RoyL (editor), New York, and the academic press, 1973 (
Industrial Gums-Polysaccharides and Their Derivatives, New York:Academic Press, 1973).
Composition of the present invention also can contain the hydrotropic agent that the cryostatic stabilization of improvement characteristic is provided, and the suitable low temperature hydrotropic agent of the present composition is C
8Sodium alkyl sulfate.
Some other optional materials can add in this cleaning compositions.These materials comprise protein and polypeptide with and derivative; First, the second of water dissolvable sanitas such as DMDM Hydantoin, Germall 115, hydroxy-benzoic acid, third and butyl ester, EDTA, Euxyl (RTM) K400, Bronopol (2-bromo-2-nitro the third-1,3-glycol), Sodium Benzoate, potassium sorbate and 2-phenoxyethyl alcohol; Other moisturizing agent such as hyaluronic acid, chitin, starch-grafted sodium polyacrylate such as Sanwet (RTM) IM-1000, IM-1500 and IM-2500 are by Celanese Superabsorbent Materials, Portsmith, VA, US-A-4 is sold and be disclosed in the U.S., in 076,663; Solvent such as hexylene glycol and propylene glycol; Antiseptic-germicide such as Oxeco (phenoxy group Virahol); Low temperature adjust mutually agent for example ammonium ion source (as NH
4Cl); Viscosity control agent such as sal epsom, Citrate trianion and other ionogen; Tinting material; Perlite and opalizer such as vinylbenzene polyvinylpyrrolidone (PVP) are as Lytron631 (RTM), TiO
2And TiO
2The mica of coating; Spices and spices solubility promoter; With zeolite such as Valfour BV400 and derivative thereof, Ca
2+/ Mg
2+Sequestrant such as multi-carboxylate, aminopolycanboxylic acid's salt, polyphosphate, polyphosphonic acid salt, aminopolyphosphonic acid salt and gluconate etc. and pH regulator agent such as citric acid and salt thereof.Also contain simultaneously water, its content is preferably about 40% to about 94%, preferably at least about 50% in present composition weight.
The pH value of this composition preferred about 4 to about 8.
The present invention is by following non-limiting example explanation.
In an embodiment, all concentration are all in 100% activity, and abbreviation has following appointment implication:
Oil 1 complete fusing point be lower than 30 ℃ and the about 1.45dynes/cm of IFT (based on 4: 1 the moon from
The son: the liquid sugar eight oleic acid esters GA aqueous solution), wherein the mensuration of IFT as
Describe herein.
The mineral oil of Oil 2 IFT about 0.38 (mensuration) as describing in detail among the Oil 1.
The polyhydroxy fatty acid amide of GA formula I, wherein R
8Be C
11-C
17Alkyl, R
9Be first
Base, and Z
2Be CH
2(CHOH)
4CH
2OH
Anionic lauryl polyoxyethylene (2) ether (laureth-2) sodium sulfate
Amphoteric Empigen CDL60, it is by 23.5% coconut both sexes acetate (R wherein
1
Be coconut alkyl, R
2Be H, and Z is CO
2Na) and 1.35% coconut two
Property diacetin (R wherein
1Be coconut alkyl, R
2Be CH
2CO
2Na and Z are
CO
2Na) aqueous mixture of Zu Chenging.
Betaine coconut amido propyl-dimethyl carboxymethyl betaine
Solan Solan (RTM) E (PEG55 lanolin)
The water-soluble shea butter of Shea (PEG75)
Sanitas DMDM Hydantoin
Stablizer magnesium aluminum silicate CMC (Veegum Plus RTM)/xanthan gum
Hydrotrope C
8Sodium alkyl sulfate
Example I is to VII
Below be the personal cleaning compositions of the shower glue or the froth product form of having a bath, they are representatives of the present invention:
I II III IV V VI VII
GA 2.0 5.0 6.0 4.0 1.5 6.0 5.0
Anionic 4.0 2.0 1.0 2.5 6.0 0.5 1.5
Amphoteric - 2.0 - - - - 0.5
Betaine 0.5 0.5 1.0 - - 0.5 0.5
Oil?1 4.0 1.0 5.0 4.0 3.0 1.0 2.0
Oil?2 8.0 9.0 8.0 12.0 10.0 12.0 8.0
Solan 0.5 0.5 - - - - -
Shea - - - 0.5 - - -
Stablizer 0.8 1.6 4.0 0.3 1.6 2.0 0.2
Hyolrotrope 0.1 - - 1.0 2.0 0.5 0.2
Spices 1.5 1.5 1.5 1.5 1.5 1.5 1.5
Sanitas 0.15 0.15 0.15 0.15 0.15 0.2 0.2
-----------------Jia entry is to 100------------------for water
At first the material of any Veegum kind of aquation prepares composition I to VII as pre-composition, and blunging in envrionment temperature then mixes all oil plants down.If there is xanthan gum section bar material, stir into slurry with this mixture.Tensio-active agent and any other skin sense agent in addition, sanitas and water-based growth substance mix with water together and be heated to about 20 ℃ to about 90 ℃ and hydration.At last, oil mixt joins the Veegum pre-composition (if existence) of hydration, and then the tensio-active agent that stirred is joined in the mixture of merging, and this final mixture stirs and is cooled to envrionment temperature, and adding remainder water, sanitas, spices and other materials.
At last, the range of viscosities of composition (Helipath .Spindle A, 10rpm, 25 ℃, pure substance) is 1,000 to 10,000 centipoise.
This product provides the good use effective benefit that neutralizes, and comprises the skin sense after fabulous use neutralization is used, good lather volume and invariant feature, skin condition, mildness, stability, cleaning power, good talent for swimming and outward appearance.
Claims (27)
1. aqueous personal cleansing composition, it comprises:
(a) the dispersive oil phase of 1% to 30% weight, it comprises at least a non-liquid polyol fatty acid polyesters that contains that contains at least 4 lipid acid ester groups, wherein polyol moiety is selected from sugar and the sugar alcohol that contains 4 to 8 hydroxyls, and wherein each carboxylic moiety has 8 to 22 carbon atoms, and wherein liquid polyol fatty acid polyesters has and is lower than 30 ℃ complete fusing point; With
(b) water soluble surfactant active's system of 5% to 30% weight comprise 1% to 25% the diffusing nonionogenic tenside of oil content, and randomly, cosurfactant is selected from negatively charged ion, zwitter-ion and amphoterics and their mixture,
Described composition also comprises the stabiliser system of 0.01% to 15% weight, comprises the clay-based material main stabilizer and the mixed polysaccharide glue time stablizer of optional modification, and wherein the weight ratio of main stabilizer and time stablizer is 32: 1 to 1: 1.
2. the composition of claim 1, wherein the oil of nonocclusive liquid polyol fatty acid polyester/surfactant soln interfacial tension is greater than 1.0 dynes per centimeter.
3. the composition of claim 1, wherein the viscosity of composition is 1,000 to 10,000 centipoise.
4. the composition of claim 1, wherein liquid polyol fatty acid polyesters is selected from glucose four oleic acid esters, glucose four soybean fat acid esters, seminose four mixing soya beans fatty acid oil esters, semi-lactosi four oleic acid esters, arabinose four linoleate, wood sugar four linoleate, semi-lactosi five oleic acid esters, sorbyl alcohol four oleic acid esters, sorbyl alcohol six unsaturated soya fatty acid esters, Xylitol five oleic acid esters, sucrose four oleic acid esters, sucrose five oleic acid esters, sucrose six oleic acid acid, sucrose seven oleic acid esters, sucrose eight oleic acid acid, and their mixture.
5. the composition of claim 1, wherein liquid polyol fatty acid polyesters is sucrose eight oleic acid esters.
6. the composition of claim 1, wherein the content of liquid polyol fatty acid polyesters is 1% to 10% weight.
7. the composition of claim 1, wherein the dispersive oil phase comprises one or more additional oil components in addition, comprise one or more and be selected from following oil, be selected from hydrocarbon, animal and vegetable triglyceride, lanolin and lanolin derivative, the water-insoluble siloxanes comprise siloxanes, the rigidity of siloxanes, amino and quaternary ammonium modification of non-volatile poly-alkyl and poly-aryl siloxanes natural gum and fluid, volatile cyclic and linear poly-alkylsiloxane, poly-alkoxylation crosslinked with the siloxanes of reinforcement and their mixture, C
8-C
30The C of lipid acid
1-C
24Ester, beeswax, saturated and unsaturated fatty alcohol, Prunus amygdalus oil, peanut oil, wheat germ oil, Toenol 1140, Jojoba oil, Apricot kernel oil, walnut oil, palm-nut oil, pistachio oil, sesame seed oil, rapeseed oil, Du's pine nut oil, Semen Maydis oil, peach oil, poppyseed oil, pine nut oil, Viscotrol C, soybean oil, Lipoval A, Thistle oil, Oleum Cocois, hazelnut oil, sweet oil, raisin seed oil and sunflower seed oil, the C of dimeracid and trimer acid
1-C
24Ester, and their mixture.
8. the composition of claim 7, wherein additional oil component comprises one or more oil, is selected from mineral oil, Vaseline, water-insoluble siloxanes, soybean oil and their mixture.
9. the composition of claim 7, wherein the content of additional oil component is 1% to 20% weight.
10. the composition of claim 7, wherein the total content of oil component is 3% to 25% weight.
11. the composition of claim 7, wherein the ratio of liquid polyol fatty acid polyesters and additional oil component is 8: 1 to 1: 8.
12. the composition of claim 1, wherein the amount of the diffusing nonionogenic tenside of oil content is 2% to 15% weight.
13. the composition of claim 1, wherein the oil content nonionogenic tenside that looses is selected from the have general formula C of (I)
12-C
18Polyhydroxy fatty acyl ammonia tensio-active agent:
R wherein
9Be C
1-4Alkyl, R
8Be C
7-C
19Alkyl or alkenyl or its mixture; And Z
2Be polyhydroxy alkyl, wherein have at least 3 hydroxyls to be directly connected on this hydrocarbon chain with linear alkyl chain, or its oxyalkylated derivative.
14. the composition of claim 13, wherein the diffusing ionic surfactant pack of oil content contains formula R
8(CO) N (CH
3) CH
2(CHOH)
4CH
2The polyhydroxy fatty acid amide of OH, wherein R
8Be C
11-C
17Straight chained alkyl or alkenyl.
15. the composition of claim 14, wherein the diffusing ionic surfactant pack of oil content contains C
12-C
14Polyhydroxy fatty acid amide.
16. the composition of claim 1 comprises the cosurfactant of 1% to 10% weight.
17. the composition of claim 1, wherein the weight ratio scope of diffusing nonionogenic tenside of oil content and dispersive oil phase is 1: 20 to 3: 2.
18. the composition of claim 1, wherein the diffusing proportional range with nonionogenic tenside of cosurfactant and oil content is 1: 10 to 10: 1.
19. the composition of claim 1; wherein water soluble surfactant active's system comprises anion surfactant; be selected from the alkyl-sulphate of ethoxylation; alkyl glycerol ether sulfonate; methyl-acyl taurine salt; fat acidyl glycine salt; alkyl ethoxy carboxylate, N-acyl glutamate, acyl isethinate; salts of alkyl sulfosuccinates salt; α-sulfonated lipid acid, their salt and/or ester, alkyl phosphate, the alkyl phosphate of ethoxylation; acyl sarcosinate and lipid acid/albumen condenses, and their mixture.
20. the composition of claim 1, wherein anion surfactant comprises the C of ethoxylation
8-C
22Alkyl-sulphate.
21. the composition of claim 1, wherein amphoterics is selected from:
(a) imidazolidine derivatives of formula (II):
R wherein
1Be C
7-C
22Alkyl or alkenyl, R
2Be hydrogen or CH
2Z, each Z are CO independently
2M or CH
2CO
2M, and M is H, basic metal, alkaline-earth metal, ammonium or alkanol ammonium; And/or the derivative of the ammonium of formula (III).
R wherein
1, R
2Define as above or their mixture with Z;
(b) the amino-alkane acid or the salt of formula (IV):
R
1NH(CH
2)
nCO
2M
Imino-diacetic paraffinic acid or salt with formula V;
R
1N[(CH
2)
mCO
2M]
2
Wherein n and m are 1 to 4 number, and R
1Be independently selected from specified group in above-mentioned (a) with M; With
(c) their mixture.
22. the composition of claim 21, wherein amphoterics is selected from the imidazolidine derivatives of formula II, the ammonium derivative of formula III and their mixture.
23. the composition of claim 1, wherein zwitterionics is selected from alkyl betaine, amido betaines, alkyl sultaine and their mixture.
24. the composition of claim 19, wherein the weight ratio of anion surfactant and zwitter-ion and/or amphoterics is 8: 1 to 1: 2.
25. the composition of claim 1 comprises positively charged ion or the non-ionic polymeric skin or the hair conditioner of 0.01% to 5% weight in addition, it is selected from positively charged ion and nonionic polysaccharide; The positively charged ion of derived from propylene acid or methacrylic acid and nonionic homopolymer and multipolymer; Positively charged ion and non-ionic cellulose resin; Dimethyl diallyl ammonium chloride and acrylic acid cationic copolymer; The cationic homopolymer of dimethyl diallyl ammonium chloride; Positively charged ion polyolefine and oxyethyl group poly (alkylenimines); Quaternised siloxanes and their mixture.
26. the composition of claim 1 also comprises moisturizing agent, it is selected from glycerine, polyoxyethylene glycol, propylene glycol, sorbyl alcohol, the polyoxyethylene glycol of methyl glucoside and the ether of propylene glycol, pyrrolidone sodium carboxylate, lactic acid, L-proline(Pro) and composition thereof.
27. the composition of claim 1, also comprise adducts by the vegetables oil preparation that contains unconjugated poly-unsaturated fatty acid ester, it is that conjugation and elaidic acid are reset, and passes through the Diels-Alder addition modification with a member that vinylformic acid, fumaric acid and maleic anhydride are arranged then.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9510832.0 | 1995-05-27 | ||
| GBGB9510832.0A GB9510832D0 (en) | 1995-05-27 | 1995-05-27 | Cleansing compositions |
| GBGB9513404.5A GB9513404D0 (en) | 1995-06-30 | 1995-06-30 | Cleansing compositions |
| GB9513404.5 | 1995-06-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1190432A CN1190432A (en) | 1998-08-12 |
| CN1103809C true CN1103809C (en) | 2003-03-26 |
Family
ID=26307102
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96195413A Expired - Fee Related CN1103809C (en) | 1995-05-27 | 1996-05-23 | Aqueous personal cleansing compositions comprising specific nonocclusive liquid polyol fatty acid polyester |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0828813A4 (en) |
| CN (1) | CN1103809C (en) |
| WO (1) | WO1996037595A1 (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9415452D0 (en) * | 1994-07-30 | 1994-09-21 | Procter & Gamble | Cleansing compositions |
| GB9615631D0 (en) * | 1996-07-25 | 1996-09-04 | Procter & Gamble | Shampoo compositions |
| US5916575A (en) * | 1997-01-27 | 1999-06-29 | The Procter & Gamble Company | Cleaning products |
| US20010055599A1 (en) * | 1997-05-23 | 2001-12-27 | Paul Joseph Drzewiecki | Compositions containing select liquid polyol fatty acid polyesters |
| AU9556898A (en) * | 1997-11-10 | 1999-05-31 | Procter & Gamble Company, The | Compositions containing combinations of solid polyol fatty acid polyesters and asolid oil |
| EP1032355A1 (en) * | 1997-11-10 | 2000-09-06 | The Procter & Gamble Company | Compositions containing combinations of liquid polyol fatty acid polyesters and a liquid oil |
| GB9814706D0 (en) * | 1998-07-08 | 1998-09-02 | Procter & Gamble | Cleansing apparatus |
| US6627586B1 (en) | 1998-07-08 | 2003-09-30 | The Procter & Gamble Company | Cleansing compositions |
| GB9911437D0 (en) * | 1999-05-17 | 1999-07-14 | Unilever Plc | Fabric softening compositions |
| DE10318526A1 (en) * | 2003-04-24 | 2004-11-11 | Beiersdorf Ag | High fat cleaning emulsion |
| DE102007029241A1 (en) * | 2007-06-20 | 2008-12-24 | Beiersdorf Ag | New emulsion-shaped shower preparation |
| US9376648B2 (en) | 2008-04-07 | 2016-06-28 | The Procter & Gamble Company | Foam manipulation compositions containing fine particles |
| US20110166370A1 (en) | 2010-01-12 | 2011-07-07 | Charles Winston Saunders | Scattered Branched-Chain Fatty Acids And Biological Production Thereof |
| WO2012112828A1 (en) | 2011-02-17 | 2012-08-23 | The Procter & Gamble Company | Bio-based linear alkylphenyl sulfonates |
| BR112013019685A2 (en) | 2011-02-17 | 2016-10-18 | Procter & Gamble | compositions comprising mixtures of c10 -C13 alkyl phenyl sulfonates |
| MX2015011690A (en) | 2013-03-05 | 2015-12-07 | Procter & Gamble | Mixed sugar compositions. |
| MX2019000344A (en) * | 2016-07-14 | 2019-06-17 | Unilever Nv | A foaming cleansing composition for topical application. |
| BR112019014914B1 (en) * | 2017-02-08 | 2022-10-04 | Unilever Ip Holdings B.V. | COMPOSITION AND PROCESSES FOR PRODUCING A COMPOSITION |
| CN106905945A (en) * | 2017-03-04 | 2017-06-30 | 东北石油大学 | A kind of preparation method of the sulfonate oligomerization surfactant based on polyalcohol |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4368213A (en) * | 1981-06-23 | 1983-01-11 | The Procter & Gamble Company | Emulsion concentrate for palatable polyester beverage |
| US4446165A (en) * | 1979-06-08 | 1984-05-01 | The Procter & Gamble Company | Oleaginous compositions |
| US5160738A (en) * | 1990-07-09 | 1992-11-03 | Chesebrough-Pond's U.S.A. Co., Division Of Conopco Inc. | Cosmetic composition |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9113484D0 (en) * | 1991-06-21 | 1991-08-07 | Unilever Plc | Cosmetic composition |
| AU3136593A (en) * | 1991-11-22 | 1993-06-15 | Richardson-Vicks Inc. | Combined personal cleansing and moisturizing compositions |
| WO1993019149A1 (en) * | 1992-03-25 | 1993-09-30 | The Procter & Gamble Company | Cleansing compositions |
| JP2736486B2 (en) * | 1992-07-03 | 1998-04-02 | 花王株式会社 | Cleansing composition |
-
1996
- 1996-05-23 CN CN96195413A patent/CN1103809C/en not_active Expired - Fee Related
- 1996-05-23 WO PCT/US1996/007510 patent/WO1996037595A1/en not_active Application Discontinuation
- 1996-05-23 EP EP96916564A patent/EP0828813A4/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4446165A (en) * | 1979-06-08 | 1984-05-01 | The Procter & Gamble Company | Oleaginous compositions |
| US4368213A (en) * | 1981-06-23 | 1983-01-11 | The Procter & Gamble Company | Emulsion concentrate for palatable polyester beverage |
| US5160738A (en) * | 1990-07-09 | 1992-11-03 | Chesebrough-Pond's U.S.A. Co., Division Of Conopco Inc. | Cosmetic composition |
Also Published As
| Publication number | Publication date |
|---|---|
| MX9709176A (en) | 1998-07-31 |
| WO1996037595A1 (en) | 1996-11-28 |
| EP0828813A1 (en) | 1998-03-18 |
| EP0828813A4 (en) | 1999-09-15 |
| CN1190432A (en) | 1998-08-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1080558C (en) | Cleansing compositions | |
| CN1103809C (en) | Aqueous personal cleansing compositions comprising specific nonocclusive liquid polyol fatty acid polyester | |
| CN1047620C (en) | Cleansing compositions | |
| CN1092041C (en) | Cleansing compositions | |
| CN1080557C (en) | Cleansing compositions | |
| CN1057327C (en) | Cleansing compositions | |
| CN1190986A (en) | Liquid personal cleansing composition containing cationic polymeric skin conditioning agent | |
| US5942479A (en) | Aqueous personal cleansing composition with a dispersed oil phase comprising two specifically defined oil components | |
| CN1076049C (en) | Cleansing composition containing polyhydroxy fatty acid amide surfactants | |
| CN1116858A (en) | Cleansing compossitions | |
| CN1061432A (en) | composition for cleaning | |
| US5985809A (en) | Aqueous personal cleansing compositions comprising specific nonocclusive liquid polyol fatty acid polyester | |
| JP2004514653A5 (en) | ||
| CN1092043C (en) | Cleansing compositions | |
| CN1341012A (en) | Cleaning compositions | |
| CN1061151A (en) | Cleaning compositions | |
| CN1100862C (en) | Aqueous personal cleansing composition with dispersed oil phase comprising two specifically defined oil component | |
| CN1174567A (en) | Cleansing compositions | |
| CN1174501A (en) | Cleaning composition | |
| CN1227597A (en) | Cleaning compositions | |
| CN1113645C (en) | Cleansing compositions | |
| CN1092042C (en) | Cleansing compositions | |
| CN1166855A (en) | Detergent composition comprising clay and polysaccharide gum stabilizing agents | |
| CN1227592A (en) | Cleaning compositions | |
| CN1227596A (en) | Cleaning compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |