CN110373154A - A kind of antifog spray and preparation method thereof - Google Patents
A kind of antifog spray and preparation method thereof Download PDFInfo
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- CN110373154A CN110373154A CN201910674980.6A CN201910674980A CN110373154A CN 110373154 A CN110373154 A CN 110373154A CN 201910674980 A CN201910674980 A CN 201910674980A CN 110373154 A CN110373154 A CN 110373154A
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- antifoggant
- antifog
- antifog spray
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- antistatic agent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
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Abstract
The present invention relates to glass protecting liquid fields, more particularly to a kind of antifog spray and preparation method thereof, it include by mass percentage antifoggant 0.1% ~ 10%, antibacterial agent 0.1% ~ 10%, stabilizer 0.1% ~ 10%, antistatic agent 0.5 ~ 10%, solvent 80% ~ 98%, wherein the antifoggant includes one of fatty alcohol polyoxyethylene ether, sodium sulfate of polyethenoxy ether of fatty alcohol, octyl phenol polyoxyethylene ether, coconut acid diethanolamine condensates or a variety of;The antibacterial agent includes one of Bravo, Hinokitiol, hexamethylene or a variety of;The antistatic agent includes one of N- cetyl pyridinium nitrate, sodium alkyl benzene sulfonate.It using molecules surfactant, is preferably combined with the silica of glass, there is good persistence and stability;The addition of antistatic agent can eliminate the charge of glass surface, so that glass surface is not easy to adsorb dust, performance safety is stablized;The addition of antibacterial agent does not have any corrosiveness to various metals, can antibacterial and mouldproof, it is nontoxic, it is widely used.
Description
Technical field
The present invention relates to glass protecting liquid fields, and in particular to a kind of antifog spray and preparation method thereof.
Technical background
In the hot summer, people are often empty in a specific space, such as indoor and automobile for comfort level
Between, temperature is transferred to the comfort standard of oneself.In cold winter, since the temperature in indoor or automobile is high, internal-external temperature difference is larger,
When cold air is met, hot-air is easy in window-glass, vehicle glass, there are also the surfaces such as the glasses of people to form fumulus,
It makes troubles to people's lives and safety, or even jeopardizes the safety of people.In order to avoid the appearance of this problem, Ren Menkai
How begin largely to study prevents this mist from generating.
Antifoggant can be widely applied to a variety of glass such as glass housing, automobile, steamer, glasses, prevent the formation of fog, protect
Hold that glass transparent is limpid, the current most common method is exactly the antifoggant using surfactant types, affordable, user
Just, while also there is good anti-fog effect, but since glass surface easily condenses moisture, surfactant is easy to run off, and group
The defects of dividing is small-molecule substance, cannot form a film, exist intolerant to wiping, antifog persistence, easily decomposes difference in a short time, and it is existing
Glass antidimmer performance it is single, do not have the function of lubricating antistatic, anticorrosion antibacterial, be not able to satisfy people to automobile use
Demand.
Summary of the invention
It is an object of the invention to overcome the problems of the prior art, a kind of antifog spray and its preparation side newly is provided
Method.
The purpose of the present invention is achieved by the following technical programs:
A kind of antifog spray, by mass percentage include antifoggant 0.1% ~ 10%, antibacterial agent 0.1% ~ 10%, stabilizer 0.1% ~
10%, antistatic agent 0.5 ~ 10%, solvent 90% ~ 98%, wherein the antifoggant includes fatty alcohol polyoxyethylene ether, fatty alcohol polyoxy
One of ethylene ether sodium sulfate, octyl phenol polyoxyethylene ether, coconut acid diethanolamine condensates are a variety of;The antibacterial agent packet
Include one of Bravo, Hinokitiol, hexamethylene or a variety of;The antistatic agent includes N- cetyl
Pyridine nitrate or sodium alkyl benzene sulfonate.
A kind of antifog spray is preferably combined with the silica of glass, is had using molecules surfactant
Good persistence and stability.Simultaneously in order to which glass surface is cleaner, it is not easy dust suction, a certain amount of antistatic agent is added, subtracts
Few buildup of static electricity and dust suction quantity.
Preferably, the antifoggant is sodium sulfate of polyethenoxy ether of fatty alcohol or coconut acid diethanolamine condensates.
Preferably, the antibacterial agent is hexamethylene.
Preferably, the antistatic agent is N- cetyl pyridinium nitrate.
Preferably, the stabilizer is modified acrylic polymer or silicone oil.
Preferably, the solvent is one of dehydrated alcohol, propyl alcohol, water or a variety of.
A kind of preparation method of the antifog spray, comprising the following steps: S1 will be by antifoggant, antibacterial agent and 1/3 ~ 1/2
Solvent mixing, stirs 800 ~ 1200rpm, 3 ~ 8min, obtains mixture A;S2 mixes the solvent of antistatic agent and 1/4 ~ 1/3, stirs
800 ~ 1200rpm, 3 ~ 8min are mixed, mixture B is obtained;Mixture A and mixing is added when stirring remaining solvent in S3 thereto
Object B;S4 keeps system temperature at 30 ~ 60 DEG C, and stabilizer is added dropwise while stirring until system becomes transparency liquid.
Preferably, mixing speed is 1000rpm in the step S1 and S2.
Preferably, S1 mixing time is 5min.
Preferably, S2 mixing time is 3min.
The present invention has following technical effect that
1. antifog spray provided by the invention, using molecules surfactant, can preferably with the silica of glass into
Row combines, and has good persistence and stability;
2. the addition of antistatic agent can eliminate the charge of glass surface in antifog spray of the invention, so that glass surface is not easy to inhale
Attached dust, performance safety are stablized;The addition of antibacterial agent does not have any corrosiveness to various metals, can antibacterial and mouldproof, it is nontoxic
It is harmless, it is widely used, and the retention period of glass transparent degree can be extended;
3. the present invention uses unique preparation process, propyl alcohol and ethyl alcohol are as solvent therein, when cleaning, on the one hand can dissolve pole
Property stronger macromolecular grease type greasy dirt, on the other hand can form protective film in glass surface, there is foam-inhibiting effect, antifoggant
The generation of glass surface fog can be slowed down, keep glass transparent degree, the antifog spray being prepared has better anti-fog effect,
So that the stability of antifoggant is more preferably.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, combined with specific embodiments below with comparative example pair
Technical solution of the present invention is described in detail.Obviously, described embodiments are only a part of the embodiments of the present invention, and
The embodiment being not all of.Based on the embodiments of the present invention, those of ordinary skill in the art are not making creative work
Under the premise of obtained all other embodiment, belong to the range protected of the present invention.
Except specified otherwise, equipment used in the present embodiment, comparative example and experimental example is routine experiment equipment, used
Reagent it is commercially available.
Embodiment 1
A kind of antifog spray, includes antifoggant as mass fraction: sodium sulfate of polyethenoxy ether of fatty alcohol 1%, antibacterial agent: poly- six
Di-2-ethylhexylphosphine oxide guanidine hydrochloride 0.5%, antistatic agent: N- cetyl pyridinium nitrate 1%, stabilizer: modified acrylic polymer
0.5%, solvent A: ethyl alcohol 10%, solvent B: water 87%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Antistatic agent and part water are mixed, 1000rpm, 3min is stirred, obtains mixture B;Remaining water is opened
Begin to stir, mixture A and mixture B is slowly added in 800rpm thereto, and keeps 50 DEG C of water temperatures simultaneously, dropwise by stabilizer
It is added, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
Embodiment 2
A kind of antifog spray, includes antifoggant as mass fraction: fatty alcohol polyoxyethylene ether 1%, antibacterial agent: polyhexamethylene
Biguanide hydrochloride 1%, antistatic agent: N- cetyl pyridinium nitrate 1.5%, stabilizer: modified acrylic polymer 1.5%, it is molten
Agent A: ethyl alcohol 10%, solvent B: water 85%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Antistatic agent and part water are mixed, 1000rpm, 3min is stirred, obtains mixture B;Remaining water is opened
Begin to stir, mixture A and mixture B is slowly added in 800rpm thereto, and keeps 50 DEG C of water temperatures simultaneously, dropwise by stabilizer
It is added, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
Embodiment 3
A kind of antifog spray, includes antifoggant as mass fraction: fatty alcohol polyoxyethylene ether 1%, antibacterial agent: polyhexamethylene
Biguanide hydrochloride 2%, antistatic agent: N- cetyl pyridinium nitrate 2%, stabilizer: modified acrylic polymer 2%, solvent A:
Ethyl alcohol 10%, solvent B: water 83%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Antistatic agent and part water are mixed, 1000rpm, 3min is stirred, obtains mixture B;Remaining water is opened
Begin to stir, mixture A and mixture B is slowly added in 800rpm thereto, and keeps 50 DEG C of water temperatures simultaneously, dropwise by stabilizer
It is added, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
Embodiment 4
A kind of antifog spray, includes antifoggant as mass fraction: octyl phenol polyoxyethylene ether 1.5%, antibacterial agent: poly- six methylene
Base biguanide hydrochloride 0.5%, antistatic agent: N- cetyl pyridinium nitrate 1.5%, stabilizer: modified acrylic polymer 2%,
Solvent A: ethyl alcohol 10%, solvent B: water 84.5%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Antistatic agent and part water are mixed, 1000rpm, 3min is stirred, obtains mixture B;Remaining water is opened
Begin to stir, mixture A and mixture B is slowly added in 800rpm thereto, and keeps 50 DEG C of water temperatures simultaneously, dropwise by stabilizer
It is added, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
Embodiment 5
A kind of antifog spray, includes antifoggant as mass fraction: sodium sulfate of polyethenoxy ether of fatty alcohol 1.5%, antibacterial agent: poly-
Hexamethylene bis guanidine hydrochloride 1%, antistatic agent: N- cetyl pyridinium nitrate 1%, stabilizer: modified acrylic polymer
1%, solvent A: ethyl alcohol 10%, solvent B: water 85.5%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Antistatic agent and part water are mixed, 1000rpm, 3min is stirred, obtains mixture B;Remaining water is opened
Begin to stir, mixture A and mixture B is slowly added in 800rpm thereto, and keeps 50 DEG C of water temperatures simultaneously, dropwise by stabilizer
It is added, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
Embodiment 6
A kind of antifog spray, includes antifoggant as mass fraction: mixture (sodium sulfate of polyethenoxy ether of fatty alcohol: coconut acid
Diethanolamine condensates=1:1) 1.5%, antibacterial agent: hexamethylene 2%, antistatic agent: N- cetyl pyridinium
Nitrate 2%, stabilizer: modified acrylic polymer 0.5%, solvent A: ethyl alcohol 10%, solvent B: water 83%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Antistatic agent and part water are mixed, 1000rpm, 3min is stirred, obtains mixture B;Remaining water is opened
Begin to stir, mixture A and mixture B is slowly added in 800rpm thereto, and keeps 50 DEG C of water temperatures simultaneously, dropwise by stabilizer
It is added, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
Embodiment 7
A kind of antifog spray, includes antifoggant as mass fraction: sodium sulfate of polyethenoxy ether of fatty alcohol 2%, antibacterial agent: hundred bacterium
Clear 0.5%, antistatic agent: N- cetyl pyridinium nitrate 2%, stabilizer: modified acrylic polymer 1%, solvent A: ethyl alcohol
10%, solvent B: water 94.5%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Antistatic agent and part water are mixed, 1000rpm, 3min is stirred, obtains mixture B;Remaining water is opened
Begin to stir, mixture A and mixture B is slowly added in 800rpm thereto, and keeps 50 DEG C of water temperatures simultaneously, dropwise by stabilizer
It is added, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
Embodiment 8
A kind of antifog spray, includes antifoggant as mass fraction: sodium sulfate of polyethenoxy ether of fatty alcohol 2%, antibacterial agent: Chinese juniper wood
Alcohol 1%, antistatic agent: N- cetyl pyridinium nitrate 1%, stabilizer: modified acrylic polymer 2%, solvent A: ethyl alcohol 10%,
Solvent B: water 84%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Antistatic agent and part water are mixed, 1000rpm, 3min is stirred, obtains mixture B;Remaining water is opened
Begin to stir, mixture A and mixture B is slowly added in 800rpm thereto, and keeps 50 DEG C of water temperatures simultaneously, dropwise by stabilizer
It is added, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
Embodiment 9
A kind of antifog spray, includes antifoggant as mass fraction: sodium sulfate of polyethenoxy ether of fatty alcohol 2%, antibacterial agent: poly- six
Di-2-ethylhexylphosphine oxide guanidine hydrochloride 2%, antistatic agent: sodium alkyl benzene sulfonate 1.5%, stabilizer: modified acrylic polymer 0.5%, solvent
A: ethyl alcohol 10%, solvent B: water 83%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Antistatic agent and part water are mixed, 1000rpm, 3min is stirred, obtains mixture B;Remaining water is opened
Begin to stir, 800rpm slowly enters mixture A and mixture B thereto, and keeps 50 DEG C of water temperatures simultaneously, and stabilizer is added dropwise
Enter, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
Embodiment 10
A kind of antifog spray, includes antifoggant as mass fraction: sodium sulfate of polyethenoxy ether of fatty alcohol 10%, antibacterial agent: poly-
Hexamethylene bis guanidine hydrochloride 3%, antistatic agent: N- cetyl pyridinium nitrate 3%, stabilizer: modified acrylic polymer
3%, solvent A: ethyl alcohol 10%, solvent B: water 72%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Antistatic agent and part water are mixed, 1000rpm, 3min is stirred, obtains mixture B;Remaining water is opened
Begin to stir, mixture A and mixture B is slowly added in 800rpm thereto, and keeps 50 DEG C of water temperatures simultaneously, dropwise by stabilizer
It is added, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
Embodiment 11
A kind of antifog spray, includes antifoggant as mass fraction: sodium sulfate of polyethenoxy ether of fatty alcohol 5%, antibacterial agent: poly- six
Di-2-ethylhexylphosphine oxide guanidine hydrochloride 1.5%, antistatic agent: N- cetyl pyridinium nitrate 1%, stabilizer: modified acrylic polymer
1.5%, solvent A: ethyl alcohol 10%, solvent B: water 81%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Antistatic agent and part water are mixed, 1000rpm, 2min is stirred, obtains mixture B;Remaining water is opened
Begin to stir, mixture A and mixture B is slowly added in 800rpm thereto, and keeps 50 DEG C of water temperatures simultaneously, dropwise by stabilizer
It is added, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
Comparative example 1
A kind of antifog spray, includes antifoggant as mass fraction: sodium sulfate of polyethenoxy ether of fatty alcohol 5%, antistatic agent: N-
Cetyl pyridinium nitrate 1%, stabilizer: modified acrylic polymer 1.5%, solvent A: ethyl alcohol 10%, solvent B: water 81%.
A kind of preparation method of antifog spray first mixes antifoggant and dehydrated alcohol, stirs 1000rpm, 5min, obtains mixed
Close object A;Antistatic agent and part water are mixed, 1000rpm, 2min is stirred, obtains mixture B;Remaining water is started to stir,
Mixture A and mixture B is slowly added in 800rpm thereto, and keeps 50 DEG C of water temperatures simultaneously, stabilizer is added dropwise, directly
To as transparency liquid, the as antistatic antifog spray of novel antibacterial.
Comparative example 2
A kind of antifog spray, includes antifoggant as mass fraction: sodium sulfate of polyethenoxy ether of fatty alcohol 5%, antibacterial agent: poly- six
Di-2-ethylhexylphosphine oxide guanidine hydrochloride 1.5%, stabilizer: modified acrylic polymer 1.5%, solvent A: ethyl alcohol 10%, solvent B: water 81%.
A kind of preparation method of antifog spray first mixes antifoggant, antibacterial agent and dehydrated alcohol, stirs 1000rpm,
5min obtains mixture A;Under 50 DEG C of water temperatures, 800rpm stirring condition, mixture A is slowly added thereto, then will be by stabilizer
It is added dropwise, until becoming transparency liquid, the as antistatic antifog spray of novel antibacterial.
The usage mode of the antifog spray of antibacterial antistatic:
First by glass to be processed or plastic film wiped clean, keeps glass dry, then open configured bottled antibacterial
Antistatic antifog spray spray head, squirts clean towel, uniform cleaning glass window or Plastic film surface, dries or naturally dry
It can reach the anti-fog effect of good antibacterial antistatic.
Antifog evaluation criterion:
Antibacterial evaluation criterion: GB/T31402-2015(national standard is referred to) frosting Anti-microbial Performance Tests method.
Antistatic evaluation criterion:
Animal toxicity test: using acute oral toxicity test, and with specific reference to Ministry of Health of the People's Republic of China, " disinfection technology is advised
Model " acute oral toxicity test method as defined in (2006) 4.1 carries out.
The test of skin animal toxicity: Skin Irritation Test is used, with specific reference to Ministry of Health of the People's Republic of China's " disinfection technology
Specification " repeatedly intact skin Irritation Test Method carries out as defined in (2006) 4.4.3.3.
Eye irritation test: using acute eye irritation test, with specific reference to Ministry of Health of the People's Republic of China's " disinfection skill
Art specification " acute eye irritation test method as defined in (2006) 4.5 carries out.
The functional test results of table 1 embodiment 1-11 and comparative example 1-2
According to the evaluation criterion of the above various indexs, correlation function test is carried out to other mould inhibitor of embodiment 1-11, by table 1
Functional test results can be seen that in the antifog grade of antifoggant that the preferred embodiment of the present invention is prepared on C grades,
90% or more at D grades, and 50% or more can reach E grades, and antibiotic rate can reach 90%, and antistatic grade 85%, at 1 grade, effect is good
It is good;Due to having lacked antibacterial agent in comparative example 1, so antibiotic rate test result shows that its antibiotic rate less than 30%, and then influences anti-
Electrostatic grade, antistatic grade is also reduced to 2 grades under the conditions of, ineffective;And due to having lacked antistatic agent in comparative example 3,
Although Kang Jun Shuai≤92%, antistatic grade is only 4 grades, and large area dust is adhered to glass surface, and perspective is fuzzy, effect
It is poor.In addition, carrying out toxotest to the antifoggant of embodiment 5, animal toxicity test result is LD5 > 5000mg/kg, skin
Animal toxicity test result be it is non-stimulated, eye irritation test result be it is non-stimulated, show antifoggant prepared by the present invention peace
Completely without toxic side effect.
Claims (10)
1. a kind of antifog spray, which is characterized in that by mass percentage include antifoggant 0.1% ~ 10%, antibacterial agent 0.1% ~
10%, stabilizer 0.1% ~ 10%, antistatic agent 0.5 ~ 10%, solvent 80% ~ 98%, wherein the antifoggant includes fatty alcohol polyoxy second
One of alkene ether, sodium sulfate of polyethenoxy ether of fatty alcohol, octyl phenol polyoxyethylene ether, coconut acid diethanolamine condensates are more
Kind;The antibacterial agent includes one of Bravo, Hinokitiol, hexamethylene or a variety of;It is described antistatic
Agent includes N- cetyl pyridinium nitrate or sodium alkyl benzene sulfonate.
2. antifog spray according to claim 1, which is characterized in that the antifoggant is sodium sulfate of polyethenoxy ether of fatty alcohol
Or coconut acid diethanolamine condensates.
3. antifog spray according to claim 1, which is characterized in that the antibacterial agent is hexamethylene.
4. antifog spray according to claim 1, which is characterized in that the antistatic agent is N- cetyl pyridinium nitric acid
Salt.
5. antifog spray according to claim 1, which is characterized in that the stabilizer is modified acrylic polymer or silicon
Oil.
6. antifog spray according to claim 1, which is characterized in that the solvent is one of dehydrated alcohol, propyl alcohol, water
Or it is a variety of.
7. a kind of preparation method of any one of claim 1 to 6 antifog spray, which is characterized in that include the following steps S1
Antifoggant, antibacterial agent and 1/3 ~ 1/2 solvent are mixed, 800 ~ 1200rpm, 3 ~ 8min is stirred, obtains mixture A;S2 will be antistatic
Agent and 1/4 ~ 1/3 solvent mixing, stir 800 ~ 1200rpm, 3 ~ 8min, obtain mixture B;S3 stirs remaining solvent, together
When mixture A and mixture B are added thereto;S4 keeps system temperature at 30 ~ 60 DEG C, and it is straight that stabilizer is added dropwise while stirring
Become transparency liquid to system.
8. the preparation method of antifog spray according to claim 7, which is characterized in that mixing speed in the step S1 and S2
For 1000rpm.
9. the preparation method of antifog spray according to claim 7, which is characterized in that S1 mixing time is 5min.
10. the preparation method of antifog spray according to claim 7, which is characterized in that S2 mixing time is 3min.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111574962A (en) * | 2020-06-23 | 2020-08-25 | 贵州省材料技术创新基地 | Antibacterial antifogging agent and preparation method thereof |
CN112457922A (en) * | 2021-01-14 | 2021-03-09 | 南昌迈进科技有限公司 | Formula and using method of antifogging wet tissue for lenses |
CN112760175A (en) * | 2020-12-31 | 2021-05-07 | 茂名张氏科技发展有限公司 | Antifogging wet tissue for glass and preparation method thereof |
CN114686173A (en) * | 2020-12-28 | 2022-07-01 | 广东三和化工科技有限公司 | Antifogging aerosol and preparation method thereof |
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CN103694958A (en) * | 2012-09-28 | 2014-04-02 | 中国石油化工股份有限公司 | Glass antifogging agent and preparation method thereof |
CN106753847A (en) * | 2016-11-17 | 2017-05-31 | 维尼健康(深圳)股份有限公司 | A kind of wiping optical lenses wet tissue |
CN109306289A (en) * | 2017-07-26 | 2019-02-05 | 深圳市康雅实业有限公司 | A kind of wet tissue for cleaning glass window mirror surface |
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CN1107173A (en) * | 1994-02-21 | 1995-08-23 | 赵邦君 | Glass dirt removing and fogging-proof agent |
CN1557904A (en) * | 2004-01-18 | 2004-12-29 | 上海师范大学 | Composition for prevention of vapor fogging on the surface of glass |
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CN111574962A (en) * | 2020-06-23 | 2020-08-25 | 贵州省材料技术创新基地 | Antibacterial antifogging agent and preparation method thereof |
CN111574962B (en) * | 2020-06-23 | 2023-01-31 | 贵州省材料技术创新基地 | Antibacterial antifogging agent and preparation method thereof |
CN114686173A (en) * | 2020-12-28 | 2022-07-01 | 广东三和化工科技有限公司 | Antifogging aerosol and preparation method thereof |
CN112760175A (en) * | 2020-12-31 | 2021-05-07 | 茂名张氏科技发展有限公司 | Antifogging wet tissue for glass and preparation method thereof |
CN112457922A (en) * | 2021-01-14 | 2021-03-09 | 南昌迈进科技有限公司 | Formula and using method of antifogging wet tissue for lenses |
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