The objective of the invention is farthest to eliminate above-mentioned shortcoming, and provide the base material of the wallpaper that a kind of body paper of novelty, this body paper be suitable for use as plastic-coated and available for example PVC to carry out good coating.In order to realize this purpose, described body paper is characterised in that, is made up of at least two fibrages.
By with bilayer or multi-ply paper body paper as wallpaper, the problem that body paper occurred that is made by the individual layer paper web is significantly reduced, eliminate fully even.In addition, can make bilayer or multi-layer web have following layer component, promptly in forming the layer on surface, contain the fiber of suitable grade, in forming the layer at the back side, contain the fiber of suitable grade.
Another object of the present invention is, a kind of wallpaper of plastic-coated is provided, and in the time of on being bonded to wall, this wallpaper existing shortcoming can not occur.For realizing this purpose, the principal character of the wallpaper of this plastic-coated is that its body paper is made up of two fibrages at least.When this bilayer or multilayer body paper were moistening, it was more even to become on mutually perpendicular direction.
Double-deck body paper is previous as the body paper that directly prints the wallpaper that does not promptly have plastic coating.Because directly the corresponding problem as the wallpaper of plastic-coated can not appear to equal extent in these wallpapers of printing, therefore, before never notices the advantageous property of duplex paper.In addition, duplex paper is as according to the body paper of the extrusion coated wallpaper of German utility model 8600174 usefulness polyethylene, so that improve its visual effect, this body paper quantitatively relatively large is about 180-230g/m
2Scope in.Since the contraction when cooling, therefore, the most about 30g/m
2The thin extruding coating of polyethylene may produce some problems.
The present invention will be described in more detail below with reference to the accompanying drawings, wherein:
That Fig. 1 shows is that the wallpaper of wanting coat plastics is used, according to body paper 1 of the present invention.This body paper is by two fibrage 1a, and 1b forms, and described 1a and 1b form by cellulose fibre used in preparation paper or the cardboard, and their other replacement scheme will be described below further.Body paper 1 is a uniform paper, and it does not certainly have the interface of tangible layer structure and interlayer, and it is that already known processes by the double-deck paper web for preparing in paper machine or board machine forms.Layer 1a forms the surface accept the wallpaper coating, and layer 1b forms reverse side, and the back side of this reverse side layer will be by using paste to be bonded in known manner on the wall or by on the topped other structure of wallpaper.In a known manner, also can when the preparation wallpaper, carry out pre-gluing, before bonding, only need get wet thus, maybe when boning, only need gluing this back side.
Fig. 2 shows a wallpaper of making, and therefore, it is included in the plastic coating 2 on body paper 1 top, and described coating is made up of the plastics of topped body paper closely.Particularly, described basic plastic construction is the synthetic polymer of some heat deformables, as PVC (polyvinyl chloride).PVC or PVC base are also represented the copolymer of polyvinyl chloride in addition.Dotted line 3 is illustrated in the possible pre-gluing on the back side.With the dispersion form be applied on the body paper and heat-treat after coating 2 form waterproof plastic layer at the in-plane of body paper and on homogeneous texture perpendicular to the direction of this direction.
Can carry out known post processing in the various wallpaper process to plastic layer 2.
Body paper among Fig. 1 and 2 is made up of the two-layer of equal thickness.Fig. 3 shows the embodiment of the body paper that wherein has different-thickness, and therefore, they are quantitatively different.Form surface to be coated superficial layer 1a quantitatively less than the reverse side layer 1b that forms the body paper back side quantitatively.Therefore, can be according to surface property, the accurately fibre blend of option table surface layer 1a and the additive that may use and the preparation method of paper, the fiber costliness that use at the comparable back side of the fiber in the superficial layer.When selecting to be used for the fiber of reverse side layer 1b, what also should consider is, this fiber will be by moistening and possibly pre-gluing is applied on it when using wallpaper.
In superficial layer 1a, can use for example chemical pulp, utilize the IGT surface strength of this chemical pulp of half viscous oil measurement to be about 1.5m/s.Among the layer 1b, can use mechanical pulp overleaf with corresponding about 0.5m/s surface strength.One of if this is two-layer or two-layer be fibre blend, can select the mixing ratio of fiber, with the fiber share that causes better surface strength performance in superficial layer more than back layer.The share of chemical pulp can be greater than the share at the back of the remainder that forms body paper in superficial layer 1a, and correspondingly in the back share of mechanical pulp and/or broken greater than superficial layer.In addition, the share of chemical pulp can be greater than the share in the adjacent with it layer among the back layer 1b.
The example of nonrestrictive, possible composition comprises as follows: body paper A
--quantitatively be 20g/m
2The chemical pulp superficial layer
--quantitatively be 70g/m
2The back layer body paper B of mechanical pulp, broken and chemical pulp mixture
--quantitatively be 30g/m
2The superficial layer of mechanical pulp, broken and chemical pulp mixture
--quantitatively be 60g/m
2The back layer of mechanical pulp, broken and chemical pulp mixture.
In the latter case, the component of fiber can be that identical, two-layer difference is quantitatively different.
With regard to above-mentioned surface strength performance, the most useful fibre structure is, in superficial layer the share of chemical pulp greater than back layer, and correspondingly overleaf in the layer share of mechanical pulp and/or broken greater than superficial layer.Yet, when selecting fiber or fibre blend, also can use other standard, and, consider the material that is applied on the fibrage, even may need to provide surface strength by the fibrolaminar maximum of the back side of paper bonding, in this occasion, the component of each layer may be with above-mentioned opposite.
Fig. 4 shows the replacement scheme that body paper 1 wherein includes superficial layer 1a and back layer 1b, and different is that an intermediate layer 1c is arranged between this is two-layer, and promptly this body paper is three layers of product.In addition, in this case, the chemical pulp that is comprised among the superficial layer 1a can be more than the chemical pulp in the paper of forming intermediate layer 1c and back layer 1b (being the back side).When intermediate layer 1c and back layer 1b were selected, what should consider was, intermediate layer 1c plays body layer, and back layer 1b will contact with water with paste.Therefore, also possible in addition is that the chemical pulp among the back layer 1b is more than the chemical pulp in intermediate layer.
Similarly, the quantitative ratio between the fibrage can change.Particularly, under the situation below, promptly because its special performances, when fiber that uses among the superficial layer 1a or fibre blend are more expensive, what form surperficial superficial layer 1a can be quantitatively (being back layer 1b in double-decker, then is intermediate layer 1c and back layer 1b in three-decker) at the back side less than the remainder that forms paper quantitatively.Particularly in duplex paper, these quantitatively also can equate, perhaps also can be back layer 1b quantitatively less than superficial layer 1a quantitatively.
Above-mentioned body paper B is carried out tensile strength, the test of percentage elongation and hygroexpansivity, and to the coated paper test of curling, and the result that they and following paper obtain compared, described paper is made up of single layer fibre, but fibrous and quantitatively identical.The results are shown in the following table.
Table
Body paper | Duplex paper 90g/m
2 | Single-part stationery, reference coupon 1 | Single-part stationery, reference coupon 2 |
Quantitative (g/m
2)
| 90.2 | 89.4 | 89.5 |
Thickness (micron) | 140 | 140 | 138 |
Tensile strength md (kN/m) tensile strength cd (kN/m) tensile strength ratio | 3.7 1.8 2.0 | 3.9 1.8 2.3 | 4.1 1.9 2.2 |
Percentage elongation md (%) percentage elongation cd (%) | 1.3 2.9 | 1.2 3.0 | 1.2 3.3 |
AMBERTEC shaping dispersed (%) | 6.0 | 7.4-8.0 | 8.0-9.9 |
Hygroexpansivity (%) in the middle of paper web | 1.1 | 1.3 | 1.5 |
Behind the moistening 2min, the edge of the paper of plastics (PVC) coatings is from curl (mm) of horizontal plane, | 6 | 13 | 11 |
Annotate: md=is vertical, and cd=is horizontal, and the result that single-part stationery (reference coupon 1 and 2) obtains is final mean value.
The DIMENSIONAL STABILITY that resulting low tensile strength is better than value representation, this is also relevant with low hygroexpansivity.This also can test by hygral expansion and prove.Vertically bigger percentage elongation and good formability (shaping uniformity) when processing when promptly for example being coated with, can give body paper better processing characteristics.The dispersiveness (small-scale quantitative fluctuation) that is shaped is low, shows that the material technology performance of paper is even, correspondingly has good processability and low damageability.
Irrelevant with the factor that is shaped, total advantage of bilayer or multi-ply paper is: because the better rigidity due to the layer structure.
Quantitatively can changing of body paper, this quantitatively can be different from the 90g/m that provides in the foregoing description
2Each layer always quantitatively can be from 80-180g/m
2Between change, preferably from 80-120g/m
2
By preparing bilayer or multi-layer web method commonly used, independently starch stream in conjunction with two-layer or multilayer, in board machine, make body paper.
In fact, for example available multilayer flow box is prepared, wherein each slurry stream combination when low concentration, but preferably two strands or the quite rare slurry stream of multiply are passed on its former that independently dewaters from its flow box individually, and before press section, be lower than 25% at dry matter content and preferably be lower than at 20% o'clock, to combine by the fibrage that these slurry stream forms, known to using bigger water content relatively, can more easily obtain good shaping is little shaping deviation, and low fiber orientation rate.
Resulting body paper also can be processed with known coating machine further, in coating machine, uses the waterproof plastic layer, the most frequently used is quantitative 80g/m at least usually
2, usually about 100g/m
2The PVC layer, body paper is coated with.Therefore, obtained the wallpaper of Fig. 2 of being used to print.