CN109545981A - A kind of organic solar batteries and preparation method thereof - Google Patents
A kind of organic solar batteries and preparation method thereof Download PDFInfo
- Publication number
- CN109545981A CN109545981A CN201811428777.2A CN201811428777A CN109545981A CN 109545981 A CN109545981 A CN 109545981A CN 201811428777 A CN201811428777 A CN 201811428777A CN 109545981 A CN109545981 A CN 109545981A
- Authority
- CN
- China
- Prior art keywords
- preparation
- organic solar
- solar batteries
- parts
- solid product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/80—Constructional details
- H10K30/88—Passivation; Containers; Encapsulations
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Landscapes
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Photovoltaic Devices (AREA)
Abstract
The invention discloses a kind of organic solar batteries and preparation method thereof, it is described the preparation method is as follows: by copper chloride, thiocarbamide, gallium chloride is dissolved in ethylene glycol, stirring dissolves it sufficiently, body of material is three diazosulfide structural motifs, both ends have identical alkylthrophene class formation primitive, solvent hot obtained above is spent into ionized water and dehydrated alcohol washing, solid product is obtained after centrifugal filtration separation, by obtained solid product in vacuum oven, obtain organic solar batteries, a kind of organic solar batteries preparation method of the present invention, preparation process is simple, it is reproducible, it is low in cost, raw material availability is high, without vulcanizing treatment, synthesis temperature is low, it is environmentally protective, improve the weatherability of solar battery, and it is able to maintain that in the keeping of solar battery or in the improvement effect of its generating efficiency.
Description
Technical field
The present invention relates to a kind of organic solar batteries and preparation method thereof, are related to a kind of manufacture of solar cells technology neck
Domain.
Background technique
Solar energy because having reproducibility, pollution-free, the features such as reserves are big and favored by people.There is provided low cost and
The solar cell of high performance-price ratio is the key that photovoltaic power generation application.The primary approach for realizing high conversion efficiency is to improve as far as possible too
The utilization rate of sunlight.
When sun energy battery is substantially free of ultraviolet absorbing agent with sealing film in the prior art, even if containing fluorescence
Matter, the weatherability of solar battery is also referred to as not upper abundant, and being especially easy to happen is caused by the xanthochromia of the backboard of solar battery
Bad order etc., the improvement effect drop of the keeping of solar battery or the generating efficiency also brought along in by fluorescent material
Low situation.
Summary of the invention
The technical problem to be solved by the present invention is in view of the deficiencies of the prior art, the present invention provides a kind of organic solar
Battery and preparation method thereof, preparation process is simple, reproducible, low in cost, raw material availability is high, is not necessarily to vulcanizing treatment, closes
It is low at temperature, it is environmentally protective, the weatherability of solar battery is improved, and can tie up in the keeping or use of solar battery
Hold the improvement effect of its generating efficiency.
Further, a kind of organic solar batteries, raw material component by weight are made up of: 13~23 parts of copper chloride,
5.5~7.5 parts of ethylene glycol, 11~13 parts of thiocarbamide, 22~25 parts of gallium chloride.
A kind of preparation method of organic solar batteries, it is described the preparation method is as follows:
(1) copper chloride, thiocarbamide, gallium chloride are dissolved in ethylene glycol, stirring dissolves it sufficiently；
(2) solar cell device is sealed between surface side transparent protection member and back side protection component and is constituted
The sealing films for solar cell of two panels a pair of solar battery；
(3) body of material is three diazosulfide structural motifs, and both ends have identical alkylthrophene class formation primitive；
(4) solvent hot obtained above is spent into ionized water and dehydrated alcohol washs, obtained after centrifugal filtration separation
Solid product；
(5) obtained solid product is obtained into organic solar batteries in vacuum oven.
Further deionized water and dehydrated alcohol washing times are 5 times.
Further solid product is 15~18 hours dry under 85~95 DEG C of vacuum drying.
The utility model has the advantages that preparation process of the present invention is simple, reproducible, low in cost, raw material availability is high, without at vulcanization
Reason, synthesis temperature is low, environmentally protective, improves the weatherability of solar battery, and in the keeping or use of solar battery
It is able to maintain that the improvement effect of its generating efficiency.
Specific embodiment
The present invention is described in further details below by embodiment.
Embodiment 1
A kind of organic solar batteries, raw material component by weight are made up of: 13 parts of copper chloride, 5.5 parts of ethylene glycol, sulphur
11 parts of urea, 22 parts of gallium chloride.
A kind of organic solar batteries the preparation method is as follows:
(1) copper chloride, thiocarbamide, gallium chloride are dissolved in ethylene glycol, stirring dissolves it sufficiently；
(2) solar cell device is sealed between surface side transparent protection member and back side protection component and is constituted
The sealing films for solar cell of two panels a pair of solar battery；
(3) body of material is three diazosulfide structural motifs, and both ends have identical alkylthrophene class formation primitive；
(4) solvent hot obtained above is spent into ionized water and dehydrated alcohol washs, obtained after centrifugal filtration separation
Solid product；
(5) obtained solid product is obtained into organic solar batteries in vacuum oven.
The deionized water and dehydrated alcohol washing times is 5 times.
The solid product is 15 hours dry under 85 DEG C of vacuum drying.
Embodiment 2
A kind of organic solar batteries, raw material component by weight are made up of: 18 parts of copper chloride, 6.5 parts of ethylene glycol, sulphur
12 parts of urea, 23 parts of gallium chloride.
A kind of organic solar batteries the preparation method is as follows:
(1) copper chloride, thiocarbamide, gallium chloride are dissolved in ethylene glycol, stirring dissolves it sufficiently；
(2) solar cell device is sealed between surface side transparent protection member and back side protection component and is constituted
The sealing films for solar cell of two panels a pair of solar battery；
(3) body of material is three diazosulfide structural motifs, and both ends have identical alkylthrophene class formation primitive；
(4) solvent hot obtained above is spent into ionized water and dehydrated alcohol washs, obtained after centrifugal filtration separation
Solid product；
(5) obtained solid product is obtained into organic solar batteries in vacuum oven.
The deionized water and dehydrated alcohol washing times is 5 times.
The solid product is 16 hours dry under 90 DEG C of vacuum drying.
Embodiment 3
A kind of organic solar batteries, raw material component by weight are made up of: 23 parts of copper chloride, 7.5 parts of ethylene glycol, sulphur
13 parts of urea, 25 parts of gallium chloride.
A kind of organic solar batteries the preparation method is as follows:
(1) copper chloride, thiocarbamide, gallium chloride are dissolved in ethylene glycol, stirring dissolves it sufficiently；
(2) solar cell device is sealed between surface side transparent protection member and back side protection component and is constituted
The sealing films for solar cell of two panels a pair of solar battery；
(3) body of material is three diazosulfide structural motifs, and both ends have identical alkylthrophene class formation primitive；
(4) solvent hot obtained above is spent into ionized water and dehydrated alcohol washs, obtained after centrifugal filtration separation
Solid product；
(5) obtained solid product is obtained into organic solar batteries in vacuum oven.
The deionized water and dehydrated alcohol washing times is 5 times.
The solid product is 18 hours dry under 95 DEG C of vacuum drying.
Claims (4)
1. a kind of organic solar batteries, which is characterized in that raw material component by weight is made up of: 13~23 parts of copper chloride,
5.5~7.5 parts of ethylene glycol, 11~13 parts of thiocarbamide, 22~25 parts of gallium chloride.
2. a kind of preparation method of organic solar batteries as described in claim 1, which is characterized in that the preparation method is such as
Under:
(1) copper chloride, thiocarbamide, gallium chloride are dissolved in ethylene glycol, stirring dissolves it sufficiently；
(2) solar cell device is sealed between surface side transparent protection member and back side protection component and constitutes the sun
The sealing films for solar cell of two panels a pair of energy battery；
(3) body of material is three diazosulfide structural motifs, and both ends have identical alkylthrophene class formation primitive；
(4) solvent hot obtained above is spent into ionized water and dehydrated alcohol washs, obtain solid after centrifugal filtration separation
Product；
(5) obtained solid product is obtained into organic solar batteries in vacuum oven.
3. a kind of preparation method of organic solar batteries as claimed in claim 2, which is characterized in that the step (4) is gone
Ionized water and dehydrated alcohol washing times are 5 times.
4. a kind of preparation method of organic solar batteries as claimed in claim 2, which is characterized in that the step (5) is solid
Body product is 15~18 hours dry under 85~95 DEG C of vacuum drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811428777.2A CN109545981A (en) | 2018-11-27 | 2018-11-27 | A kind of organic solar batteries and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811428777.2A CN109545981A (en) | 2018-11-27 | 2018-11-27 | A kind of organic solar batteries and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109545981A true CN109545981A (en) | 2019-03-29 |
Family
ID=65851088
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811428777.2A Pending CN109545981A (en) | 2018-11-27 | 2018-11-27 | A kind of organic solar batteries and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109545981A (en) |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101479853A (en) * | 2006-06-22 | 2009-07-08 | 依索沃尔塔股份公司 | Method for producing photoactive layers and components comprising said layer(s) |
| US20090235987A1 (en) * | 2008-03-24 | 2009-09-24 | Epv Solar, Inc. | Chemical Treatments to Enhance Photovoltaic Performance of CIGS |
| CN102473774A (en) * | 2009-07-30 | 2012-05-23 | 三菱树脂株式会社 | Solar cell module |
| JP2012151399A (en) * | 2011-01-21 | 2012-08-09 | Bridgestone Corp | Sealing film integrating rear side protection member for solar cell and production method therefor, solar cell using it and manufacturing method therefor |
| US20130102746A1 (en) * | 2010-06-25 | 2013-04-25 | Mingjie Zhou | Conjugated polymer based on benzodithiophene and thienopyrazine, preparation method thereof and application thereof |
| CN103288143A (en) * | 2013-05-22 | 2013-09-11 | 济南大学 | Synthetic method of forbidden bandwidth-adjustable nanometer chalcopyrite |
| CN103880834A (en) * | 2014-03-05 | 2014-06-25 | 南京邮电大学 | Organic solar cell material and preparation method thereof |
| CN104692450A (en) * | 2015-03-24 | 2015-06-10 | 湘潭大学 | Preparation method for solar battery materials with three-zone gap tin doped with copper, gallium and sulphur |
| CN105580143A (en) * | 2013-09-26 | 2016-05-11 | 株式会社普利司通 | Sealing film for solar cells, and solar cell using same |
| CN106024976A (en) * | 2016-06-15 | 2016-10-12 | 山东建筑大学 | Method for preparing copper gallium sulfide photoelectric thin film from copper chloride |
| CN107055591A (en) * | 2017-04-29 | 2017-08-18 | 复旦大学 | A kind of semiconductor CuGaS2The preparation method of hexagon nano-sheet crystals |
| CN108293284A (en) * | 2015-11-30 | 2018-07-17 | 日本化学工业株式会社 | The luminescent layer ionic compound of electrochemical luminescence unit, the luminescent layer formation composition of electrochemical luminescence unit and electrochemical luminescence unit |
-
2018
- 2018-11-27 CN CN201811428777.2A patent/CN109545981A/en active Pending
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101479853A (en) * | 2006-06-22 | 2009-07-08 | 依索沃尔塔股份公司 | Method for producing photoactive layers and components comprising said layer(s) |
| US20090235987A1 (en) * | 2008-03-24 | 2009-09-24 | Epv Solar, Inc. | Chemical Treatments to Enhance Photovoltaic Performance of CIGS |
| CN102473774A (en) * | 2009-07-30 | 2012-05-23 | 三菱树脂株式会社 | Solar cell module |
| US20130102746A1 (en) * | 2010-06-25 | 2013-04-25 | Mingjie Zhou | Conjugated polymer based on benzodithiophene and thienopyrazine, preparation method thereof and application thereof |
| JP2012151399A (en) * | 2011-01-21 | 2012-08-09 | Bridgestone Corp | Sealing film integrating rear side protection member for solar cell and production method therefor, solar cell using it and manufacturing method therefor |
| CN103288143A (en) * | 2013-05-22 | 2013-09-11 | 济南大学 | Synthetic method of forbidden bandwidth-adjustable nanometer chalcopyrite |
| CN105580143A (en) * | 2013-09-26 | 2016-05-11 | 株式会社普利司通 | Sealing film for solar cells, and solar cell using same |
| CN103880834A (en) * | 2014-03-05 | 2014-06-25 | 南京邮电大学 | Organic solar cell material and preparation method thereof |
| CN104692450A (en) * | 2015-03-24 | 2015-06-10 | 湘潭大学 | Preparation method for solar battery materials with three-zone gap tin doped with copper, gallium and sulphur |
| CN108293284A (en) * | 2015-11-30 | 2018-07-17 | 日本化学工业株式会社 | The luminescent layer ionic compound of electrochemical luminescence unit, the luminescent layer formation composition of electrochemical luminescence unit and electrochemical luminescence unit |
| CN106024976A (en) * | 2016-06-15 | 2016-10-12 | 山东建筑大学 | Method for preparing copper gallium sulfide photoelectric thin film from copper chloride |
| CN107055591A (en) * | 2017-04-29 | 2017-08-18 | 复旦大学 | A kind of semiconductor CuGaS2The preparation method of hexagon nano-sheet crystals |
Non-Patent Citations (1)
| Title |
|---|
| 齐云霞: "Ⅰ-Ⅲ-Ⅵ_2族硫化物亚稳结构的溶剂热合成与表征", 《工程科技Ⅰ辑》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN203942493U (en) | A kind of photovoltaic and photothermal assembly | |
| CN102632611B (en) | Solar cell packaging glue film | |
| CN104529988A (en) | A chemical modification method for a highland natural dye sensitizer | |
| CN203562435U (en) | Two-side film photovoltaic solar power generation panel | |
| CN204303839U (en) | Solar cell backboard | |
| CN204206103U (en) | A kind of solar panel with cooling system | |
| Chen et al. | Environmental friendly PV power plant | |
| CN104403240B (en) | High light-shading solar battery back membrane material and preparation method thereof | |
| CN109545981A (en) | A kind of organic solar batteries and preparation method thereof | |
| CN204303837U (en) | Solar cell backboard | |
| CN102174241B (en) | Silver paste for photovoltaic assembly | |
| CN101976689B (en) | Five-junction semiconductor solar photovoltaic cell chip | |
| CN105449021A (en) | High-performance solar module packaged through reliable durable EVA | |
| CN204303834U (en) | Solar cell backboard | |
| CN102155078B (en) | Nanometer solar fabric photovoltaic surface skin | |
| CN205194710U (en) | Four knot solar cell with reflection stratum | |
| CN204303840U (en) | Solar cell backboard | |
| CN204045605U (en) | A kind of Synergistic type solar cell backboard | |
| CN105448707A (en) | Method for preparing polycrystalline silicon thin film by using ceramic substrate | |
| CN202328875U (en) | Solar vacuum tube with inner tube capable of accommodating working medium based on flexible solar cell | |
| CN206225377U (en) | Photovoltaic module | |
| CN204303841U (en) | Solar cell backboard | |
| CN104992994A (en) | Solar cell | |
| CN205944102U (en) | Polycrystalline silicon chip with double layers of antireflection films | |
| CN206023662U (en) | A kind of high-efficiency solar plate of waterproof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190329 |