CN109362746A - A kind of Herbicidal combinations of the humulone containing dichloroquinoline - Google Patents

A kind of Herbicidal combinations of the humulone containing dichloroquinoline Download PDF

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Publication number
CN109362746A
CN109362746A CN201811389523.4A CN201811389523A CN109362746A CN 109362746 A CN109362746 A CN 109362746A CN 201811389523 A CN201811389523 A CN 201811389523A CN 109362746 A CN109362746 A CN 109362746A
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component
herbicidal combinations
humulone
dichloroquinoline
barnyard grass
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CN201811389523.4A
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Chinese (zh)
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黄自云
吴电亮
张建邦
陈金红
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ANHUI ZHONGBANG BIOLOGICAL ENGINEERING Co Ltd
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ANHUI ZHONGBANG BIOLOGICAL ENGINEERING Co Ltd
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Priority to CN201811389523.4A priority Critical patent/CN109362746A/en
Publication of CN109362746A publication Critical patent/CN109362746A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/761,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention discloses a kind of Herbicidal combinations of humulone containing dichloroquinoline, and the effective component of the Herbicidal combinations is made of component A and component B, and the component A is dichloroquinoline humulone, and the component B is fenoxapropPethyl;The mass ratio of the component A and component B is 10~50:1~20.Herbicidal combinations of the invention have synergistic effect, it is mainly used for rice direct seeding field or transplant field annual grassy weeds, effectively preventing and kill off annual gramineous weed mainly has barnyard grass, west to come barnyard grass, bald barnyard, hard bran barnyard grass, herba digitariae, Eclipta prostrata, Procumbent Falsepimpernel, false loosestrife, difformed galingale herb, cyperus iria, wild avena sativa, amur foxtail, herba setariae viridis, oat, rye grass, annual bluegrass, barnyard grass, spontaneous corn, herba digitariae etc.;Have the characteristics that activity of weeding is high, synergistic effect is obvious, broad weed-killing spectrum, be easy to use, reduce cost, and to rice safety, belongs to environmentally friendly herbicide.

Description

A kind of Herbicidal combinations of the humulone containing dichloroquinoline
Technical field
The invention belongs to pesticide herbicide technical field more particularly to a kind of Herbicidal combinations of humulone containing dichloroquinoline.
Background technique
Rice is one of the staple food crop in China, and rice is the staple food of national about 60% population, and sown area is about The 18.5% of national total sown area is accounted for, rice yield accounts for the 39.23% of total grain output, therefore the increase and decrease of the yield of rice has act The influence of sufficient weight.But all the time, all kinds of weeds affect the yield of rice, according to investigations, its rice of the field of weed encroachment Production loss is generally in 10-20%, serious loss 40-50%.In recent years, water is broadcast live in a kind of saving of labor, water-saving planting patterns Rice is risen rapidly, and management of weeds, which more seems, to be even more important, wherein be affected and it is more difficult it is anti-be the standing grain such as barnyard grass, semen euphorbiae The broadleaf weeds such as undergraduate course weeds, followed by Monochoria vaginalis, mexicana, potamogeton grass.Lag is compared in herbicide for paddy field development, and kind is not More, the wider of application is bensulfuron-methyl, Acetochlor, dimethyl tetrachloride etc., but since these service life of the products are longer, and weeds produce Drug resistance is given birth to, the effect is unsatisfactory.
Dichloroquinoline humulone also known as 2- (3,7- dichloroquinoline -8- base)-carbonyl-cyclohexane -1,3- diketone, are two chloroquines The derivative of quinoline acid.Dichloro quinolinic acid can effectively prevent and kill off barnyard grass in paddy field, but decline year by year to above the average age for marriage barnyard grass preventive effect;To rice field broad-leaved Weed-control effect is poor, invalid to sedge weed, and meets high temperature and be also easy to produce phytotoxicity.And dichloroquinoline humulone is to above the average age for marriage barnyard grass preventive effect It is excellent, while also can effectively prevent and kill off rice field broadleaf weeds such as Monochoria vaginalis, ear leaf water amaranth etc..
FenoxapropPethyl category heterocyclic oxy group phenoxy propionic acid class herbicide, the mainly pass by inhibiting fatty acid synthesis One acetyl-CoA carboxylase of key enzyme, to inhibit the synthesis of fatty acid.Medicament by cauline leaf Assimilation and conductivity to separate living tissue and The growing point of root, effect rapidly, stop growing for 2-3 days after application, 5-6 days lobus cardiacus chlorosis purpling colors, separate living tissue browning color, leaf Piece is gradually withered, is the extremely strong cauline leaf process agent of selectivity.
Summary of the invention
The purpose of the present invention is to provide a kind of synergistic effects significantly, the weeding group of the humulone containing dichloroquinoline of broad weed-killing spectrum Close object.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of Herbicidal combinations of the humulone containing dichloroquinoline, the effective component of the Herbicidal combinations are by component A and group Divide B composition, the component A is dichloroquinoline humulone, and the component B is fenoxapropPethyl;The matter of the component A and component B Amount is than being 10~50:1~20.
Further scheme further includes synergist, the mass ratio of the component A, component B and synergist be 10~50:1~ 20:1~5.
Further scheme, the synergist are that organosilicon, cyclohexanedione, pyrrolidones, alkyl polyglycoside or tallow amine are poly- Ethylene oxide ether.
The mass ratio of further scheme, the component A, component B and synergist is 15:3:2.
Further scheme, the Herbicidal combinations also contain agriculturally acceptable auxiliary agent and carrier.
Further scheme, the dosage forms of the Herbicidal combinations be dispersible oil-suspending agent, missible oil, aqueous emulsion, microemulsion or Wettable powder.
Active component is dichloroquinoline humulone, fenoxapropPethyl in Herbicidal combinations of the present invention, and dosage depends on single Respective amount of application and the two portfolio ratio and synergy degree when solely using, special protection of the present invention Herbicidal combinations are effective Ingredient A dichloroquinoline humulone 10~50% and effective component B fenoxapropPethyl 1~20%, synergist and its can agriculturally connect The auxiliary agent and carrier received, are made dispersible oil-suspending agent, missible oil, aqueous emulsion, microemulsion or wettable powder.
Herbicidal combinations of the invention can add agriculturally acceptable synergist, auxiliary agent and carrier, be made into dispersible Oil-suspending agent, missible oil, microemulsion, wettable powder or water dispersible granules.
The synergist is in organosilicon, cyclohexanedione, pyrrolidones, alkyl polyglycoside and tallow amine polyoxyethylene ether One or more.
The auxiliary agent includes dispersing agent, disintegrating agent, wetting agent, thickener, emulsifier, preservative, antifreezing agent and defoaming One or more of agent.
The dispersing agent is APES formaldehyde condensation product, naphthalenesulfonate formaldehyde condensation compound, to methoxyl group rouge Fat amide groups benzene sulfonic acid, calcium lignosulfonate, polycarboxylate, alkyl phenol polyoxyethylene ether sulfate, sodium methylene bis-naphthalene sulfonate, One of alkyl benzene calcium sulfonate, aliphatic ester sulfate, alkyl phenol polyoxyethylene ether and fatty alcohol polyoxyethylene ether are several Kind.
The disintegrating agent is sodium carboxymethyl starch, low-substituted hydroxypropyl cellulose, croscarmellose sodium, is crosslinked and gathers Tie up one of ketone, chitosan, sodium alginate sodium bicarbonate, magnesium chloride, aluminium chloride, sodium chloride, urea and ammonium sulfate or several Kind.
The wetting agent be lauryl sodium sulfate, neopelex, sodium butylnaphthalenesulfonate, sodium alkyl sulfonate, One or more of tea seed cake powder, spaonin powder and spaonin powder.
The thickener be polyvinyl acetate, organobentonite, xanthan gum, gelatin, gum arabic, aluminium-magnesium silicate, One or more of phenolic resin, hydroxymethyl cellulose and sodium alginate.
The emulsifier is alkyl phenol polyoxyethylene ether, triphenylethylene polyoxyethylene ether, Ben-zylphenol Polyoxyethyl Ether, benzene second Base phenol polyethenoxy ether, fatty alcohol polyoxyethylene ether, phenethyl phenol polyethenoxy ether polyethenoxy ether, aliphatic amine polyoxyethylene One or more of ether, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate and styryl phenyl polyoxyethylene ether.
The preservative is one or more of sodium benzoate and Kathon CG.
The antifreezing agent is one or more of calcium chloride, methanol, ethyl alcohol, ethylene glycol, propylene glycol and glycerine.
The defoaming agent is in dimethyl silicone polymer, dimethyl silicone polymer and polyoxypropylene ethylene oxide glycerin ether It is one or more of.
The carrier is divided into solid carrier and solvent, solid carrier organobentonite, White Carbon black, kaolin, lightweight carbonic acid One or more of calcium, sodium sulphate, ammonium sulfate, diatomite, starch and clay etc.;Solvent have deionized water, methyl oleate, Toluene, dimethylbenzene, chlorobenzene, solvent naphtha, α-methyl naphthalene, turpentine oil, methylene chloride, chloroform, methanol, ethyl alcohol, glycerine, Ethylene glycol, butanol, isoamyl alcohol, propylene glycol, cyclohexanone, isophorone, acetophenone, ethyl acetate, propyl acetate, butyl acetate, One or more of n,N-Dimethylformamide (DMF), dimethyl sulfoxide (DMSO) and cellosolve etc., it is above-mentioned individually to make With, can also two kinds or more be used in combination.
The above various auxiliary agents or carrier are commercially available.
Herbicidal combinations of the invention have synergistic effect, are mainly used for rice direct seeding field or transplant field annual grassy weeds, Effectively preventing and kill off annual gramineous weed mainly has barnyard grass, west to come barnyard grass, bald barnyard, hard bran barnyard grass, herba digitariae, Eclipta prostrata, Procumbent Falsepimpernel, cloves Knotweed, difformed galingale herb, cyperus iria, wild avena sativa, amur foxtail, herba setariae viridis, oat, rye grass, annual bluegrass, barnyard grass, spontaneous corn, horse Tang etc.;Have the characteristics that activity of weeding is high, synergistic effect is obvious, broad weed-killing spectrum, be easy to use, reducing cost, and rice is pacified Entirely, belong to environmentally friendly herbicide.
Specific embodiment
The present invention is further illustrated with the specific embodiments of several different dosage forms below.But the present invention is only limitted to absolutely not this A little examples.Percentage is weight fraction in all formulas.
One, form formula example:
Embodiment 1,20% wettable powder:
Embodiment 2,21% microemulsion:
Embodiment 3,15% dispersible oil-suspending agent:
Embodiment 4,18% dispersible oil-suspending agent
Embodiment 5,13% missible oil
Embodiment 6,17% aqueous emulsion
Example 7,15% missible oil
Example 8,30% wettable powder
Two, indoor biological activity assay:
Below by way of dichloroquinoline humulone, fenoxapropPethyl composition herbicide to paddy field weed indoor biological activity It measures to verify the reasonability of formula.
In the present composition, dichloroquinoline humulone (98% raw medicine) is by Dingyuan County Jiahe plant protection product Limited Liability public affairs Department's production, fenoxapropPethyl (93% raw medicine) are produced by Anhui Hua Xing Chemical Co., Ltd..
Test method is that quantitative weeds (40 plants of every basin) and rice paddy seed are sowed in basin using greenhouse pot culture method, to After weeds are unearthed when length to the 2-4 leaf phase, cauline leaf spraying treatment is carried out with spraying machine, is placed in greenhouse and continues after 6 hours after processing Culture observation, investigates the preventive effect to weeds and the safety to rice after 15 days.Investigation method uses absolute value investigation method, The fresh weight of every basin remaining weeds is first investigated, then the fresh weight preventive effect of each processing: E=(C-T)/C × 100% is calculated according to the following formula, E is fresh weight preventive effect in formula, and C is control weeds fresh weight, and T is processing weeds fresh weight.Then weeds activity is examined with Colby method It surveys and the co-toxicity of weeds is acted on, by Colby method, work as E0- E > 10% is synergistic effect;Work as E0- E < -10% is antagonism; As -10%≤E0- E≤10% is addition.
Table 1: herbicidal composition acts on (spray-on process) to the co-toxicity of barnyard grass.
It can be seen that from upper table 1, when dichloroquinoline humulone, fenoxapropPethyl (or fenoxapropPethyl) compound, to barnyard grass The E of grass0For-E value between 9.14-20.27, synergy type is synergistic effect, with dichloroquinoline humulone, smart oxazole dogstail The weight ratio of spirit is that the effect of 15:3:2 is most obvious, E0- E value is 20.27.
Three, test examples:
1, trial crops and object: for studying object as live streaming water in field rice, subjects are annual based on barnyard grass etc. Weeds.
Test medicine: 1 Chinese medicine of embodiment: 20% wettable powder (dichloroquinoline humulone 16%, fenoxapropPethyl 4%) (our company's production);
Comparison medicament: it is (limited by Tao benefit agriculture agricultural science and technology (China) that oil-suspending agent can be dispersed in 20% dichloroquinoline humulone Company's production)
10% fenoxapropPethyl missible oil (is produced) by Hangzhou, Zhejiang province Yu Long Chemical Co., Ltd.
Spraying time and method: test is then administered (application drained water in field before two days) on May 08th, 2018, at that time water Direct sowing of rice is 20 days existing, and barnyard grass, one heart stage of 2~4 leaf of semen euphorbiae, routinely preparating liquid 45KG is sprayed per acre, 6 after application Rainfall is had no in hour, paddy field normal irrigation after 1 day.
Control time and number: investigating weeds radix before application, 3,5 days observation treatment region rice shoot leaf colors after application, Upgrowth situation records in detail if any abnormal.(on May 15th, 2018), 10 days (on May 18th, 2018) point 7 days after application It Tiao Cha not strain preventive effect and weeds overground part fresh weight.
Investigation method: 5 point samplings, each cell random selection 5 points of investigation, every area 0.25m2, application 7 are used The strain number for investigating two kinds of main weeds and total weed after it respectively, after 10 days simultaneously investigate the strain number of all kinds of weeds and total weed with And overground part fresh weight, calculate decline rate and anti-efficiency.It is specific as shown in table 2.
Drug effect calculation method is as follows:
CK indicates clear water control in above formula.
Table 2: direct seading rice field weed is prevented and kill off to total weed preventive effect table
Interpretation of result: 20% wettable powder of the invention prevents and kill off direct seading rice field to the preventive effect of total weed, medication After 10 days, average decline rate is up to 93.50%, and averagely preventing and kill off rate is 95.37%.The dispersible oil of 20% dichloroquinoline humulone suspends The average decline rate of agent and 10% fenoxapropPethyl missible oil is only 77.50% and 75.00%, and the two averagely rate of preventing and kill off is respectively 84.38%, 82.22%.Illustrate that 20% wettable powder of the invention is apparently higher than the control efficiency of direct seading rice field weed Dichloroquinoline humulone, fenoxapropPethyl single dose effect, therefore there is preferable popularization and application foreground.
2, trial crops and object: for studying object as live streaming water in field rice, subjects are based on barnyard grass, semen euphorbiae etc. Annual grassy weeds.
Test medicine: 4 Chinese medicine of embodiment: 18% dispersible oil-suspending agent (dichloroquinoline humulone 15%, smart oxazole dogstail Clever 3%, alkyl polyglycoside 2%) (our company's production);
Comparison medicament: it is (limited by Tao benefit agriculture agricultural science and technology (China) that oil-suspending agent can be dispersed in 20% dichloroquinoline humulone Company's production)
10% fenoxapropPethyl missible oil (is produced) by Hangzhou, Zhejiang province Yu Long Chemical Co., Ltd.
Spraying time and method: test is then administered (application drained water in field before two days) on May 08th, 2018, at that time water Direct sowing of rice is 20 days existing, and barnyard grass, one heart stage of 2~4 leaf of semen euphorbiae, routinely preparating liquid 45KG is sprayed per acre, 6 after application Rainfall is had no in hour, paddy field normal irrigation after 1 day.
Control time and number: investigating weeds radix before application, 3,5 days observation treatment region rice shoot leaf colors after application, Upgrowth situation records in detail if any abnormal.(on May 15th, 2018), 10 days (on May 18th, 2018) point 7 days after application It Tiao Cha not strain preventive effect and weeds overground part fresh weight.
Investigation method: 5 point samplings, each cell random selection 5 points of investigation, every area 0.25m are used2, application 7 The strain number for investigating two kinds of main weeds and total weed after it respectively, after 10 days simultaneously investigate the strain number of all kinds of weeds and total weed with And overground part fresh weight, calculate decline rate and anti-efficiency.It is specific as shown in table 3.
Drug effect calculation method is as follows:
CK indicates clear water control in above formula.
Table 3: direct seading rice field weed is prevented and kill off to total weed preventive effect table
Interpretation of result: 18% dispersible oil-suspending agent prevents and kill off direct seading rice field to the preventive effect of total weed, and medication 10 days Preventive effect highest afterwards, average decline rate are up to 95.50%, and averagely preventing and kill off rate is 96.68%.The dispersible oil of 20% dichloroquinoline humulone The average decline rate of suspending agent and 10% fenoxapropPethyl missible oil is only 77.50% and 75.00%, and the two averagely prevents and kill off rate point It Wei 84.38%, 82.22%.Illustrate that 18% dispersible oil-suspending agent is apparently higher than the control efficiency of direct seading rice field weed Dichloroquinoline humulone, fenoxapropPethyl single dose effect, therefore there is preferable popularization and application foreground.
3, trial crops and object: for studying object as live streaming water in field rice, subjects are based on barnyard grass, semen euphorbiae etc. Annual grassy weeds.
Test medicine: 7 Chinese medicine of embodiment: 15% missible oil (dichloroquinoline humulone 8%, fenoxapropPethyl 7%) (this public affairs Department's production);
Comparison medicament: it is (limited by Tao benefit agriculture agricultural science and technology (China) that oil-suspending agent can be dispersed in 20% dichloroquinoline humulone Company's production)
10% fenoxapropPethyl missible oil (is produced) by Hangzhou, Zhejiang province Yu Long Chemical Co., Ltd.
Spraying time and method: test is then administered (application drained water in field before two days) on May 08th, 2018, at that time water Direct sowing of rice is 20 days existing, and barnyard grass, one heart stage of 2~4 leaf of semen euphorbiae, routinely preparating liquid 45KG is sprayed per acre, 6 after application Rainfall is had no in hour, paddy field normal irrigation after 1 day.
Control time and number: investigating weeds radix before application, 3,5 days observation treatment region rice shoot leaf colors after application, Upgrowth situation records in detail if any abnormal.(on May 15th, 2018), 10 days (on May 18th, 2018) point 7 days after application It Tiao Cha not strain preventive effect and weeds overground part fresh weight.
Investigation method: 5 point samplings, each cell random selection 5 points of investigation, every area 0.25m are used2, application 7 The strain number for investigating two kinds of main weeds and total weed after it respectively, after 10 days simultaneously investigate the strain number of all kinds of weeds and total weed with And overground part fresh weight, calculate decline rate and anti-efficiency.It is specific as shown in table 4.
Drug effect calculation method is as follows:
CK indicates clear water control in above formula.
Table 4: direct seading rice field weed is prevented and kill off to total weed preventive effect table
Interpretation of result: 15% missible oil prevents and kill off direct seading rice field to the preventive effect of total weed, preventive effect highest after medication 10 days, Average decline rate is up to 88.50%, and averagely preventing and kill off rate is 91.61%.20% dichloroquinoline humulone can be dispersed oil-suspending agent with The average decline rate of 10% fenoxapropPethyl missible oil is only 77.50% and 75.00%, and the two averagely rate of preventing and kill off is respectively 84.38%, 82.22%.Illustrate that 15% missible oil is apparently higher than dichloroquinoline humulone, essence to the control efficiency of direct seading rice field weed Fenoxaprop-P single dose effect, therefore there is preferable popularization and application foreground.
This hair can be understood and applied the above description of the embodiments is intended to facilitate those skilled in the art It is bright.Person skilled in the art obviously easily can make various modifications to case study on implementation, and described herein one As principle be applied in other embodiments without having to go through creative labor.Therefore, the present invention is not limited to implementation cases here Example, those skilled in the art's announcement according to the present invention, improvement and modification made without departing from the scope of the present invention all should be Within protection scope of the present invention.

Claims (6)

1. a kind of Herbicidal combinations of humulone containing dichloroquinoline, it is characterised in that: the effective component of the Herbicidal combinations be by Component A and component B composition, the component A are dichloroquinoline humulone, and the component B is fenoxapropPethyl;The component A and The mass ratio of component B is 10~50:1~20.
2. the Herbicidal combinations of the humulone according to claim 1 containing dichloroquinoline, it is characterised in that: it further include synergist, The mass ratio of the component A, component B and synergist is 10~50:1~20:1~5.
3. the Herbicidal combinations of the humulone according to claim 2 containing dichloroquinoline, it is characterised in that: the synergist is to have Machine silicon, cyclohexanedione, pyrrolidones, alkyl polyglycoside or tallow amine polyoxyethylene ether.
4. the Herbicidal combinations of the humulone according to claim 2 containing dichloroquinoline, it is characterised in that: the component A, component The mass ratio of B and synergist is 15:3:2.
5. the Herbicidal combinations of the humulone according to claim 1 or 2 containing dichloroquinoline, it is characterised in that: the weeding group It closes object and also contains agriculturally acceptable auxiliary agent and carrier.
6. the Herbicidal combinations of the humulone according to claim 1 containing dichloroquinoline, it is characterised in that: the Herbicidal combinations Dosage form be dispersible oil-suspending agent, missible oil, aqueous emulsion, microemulsion or wettable powder.
CN201811389523.4A 2018-11-21 2018-11-21 A kind of Herbicidal combinations of the humulone containing dichloroquinoline Pending CN109362746A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110074121A (en) * 2019-05-31 2019-08-02 江西鑫邦科技有限责任公司 A kind of quinolines Herbicidal combinations of brassinolide-containing class compound
CN111202080A (en) * 2019-12-27 2020-05-29 安徽众邦生物工程有限公司 Weeding composition containing triafamone and quinclorac

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CN103155923A (en) * 2013-03-27 2013-06-19 北京法盖银科技有限公司 Weedicide composition containing aryloxyphenoxypropionate compound and application thereof
CN103621507A (en) * 2013-03-27 2014-03-12 北京法盖银科技有限公司 Weeding compositions containing 2-(quinoline-8-yl)carbonyl-cyclohexane-1,3-dione compounds and application of weeding compositions
CN104222130A (en) * 2014-09-26 2014-12-24 安徽众邦生物工程有限公司 Ternary weeding composition for paddy rice direct-seeding field
CN108739839A (en) * 2018-06-13 2018-11-06 安徽众邦生物工程有限公司 A kind of Herbicidal composition for rice field of fluorinated ketones contained sulphur grass amine

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102249996A (en) * 2011-05-10 2011-11-23 北京法盖银科技有限公司 2-(quinoline-8-yl)carbonyl-cyclohexane-1,3-dione compounds
CN103155923A (en) * 2013-03-27 2013-06-19 北京法盖银科技有限公司 Weedicide composition containing aryloxyphenoxypropionate compound and application thereof
CN103621507A (en) * 2013-03-27 2014-03-12 北京法盖银科技有限公司 Weeding compositions containing 2-(quinoline-8-yl)carbonyl-cyclohexane-1,3-dione compounds and application of weeding compositions
CN104222130A (en) * 2014-09-26 2014-12-24 安徽众邦生物工程有限公司 Ternary weeding composition for paddy rice direct-seeding field
CN108739839A (en) * 2018-06-13 2018-11-06 安徽众邦生物工程有限公司 A kind of Herbicidal composition for rice field of fluorinated ketones contained sulphur grass amine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110074121A (en) * 2019-05-31 2019-08-02 江西鑫邦科技有限责任公司 A kind of quinolines Herbicidal combinations of brassinolide-containing class compound
CN111202080A (en) * 2019-12-27 2020-05-29 安徽众邦生物工程有限公司 Weeding composition containing triafamone and quinclorac

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Application publication date: 20190222