CN109326818A - The application of battery module and this battery module - Google Patents

The application of battery module and this battery module Download PDF

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Publication number
CN109326818A
CN109326818A CN201810859597.3A CN201810859597A CN109326818A CN 109326818 A CN109326818 A CN 109326818A CN 201810859597 A CN201810859597 A CN 201810859597A CN 109326818 A CN109326818 A CN 109326818A
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CN
China
Prior art keywords
battery module
battery
phase
coldplate
battery cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810859597.3A
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Chinese (zh)
Inventor
A·鲁尔勒
C·G·普夫鲁格
J·塞布
T·克勒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Robert Bosch GmbH
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Robert Bosch GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Robert Bosch GmbH filed Critical Robert Bosch GmbH
Publication of CN109326818A publication Critical patent/CN109326818A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/613Cooling or keeping cold
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/617Types of temperature control for achieving uniformity or desired distribution of temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/62Heating or cooling; Temperature control specially adapted for specific applications
    • H01M10/625Vehicles
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/653Means for temperature control structurally associated with the cells characterised by electrically insulating or thermally conductive materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6552Closed pipes transferring heat by thermal conductivity or phase transition, e.g. heat pipes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6554Rods or plates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/656Means for temperature control structurally associated with the cells characterised by the type of heat-exchange fluid
    • H01M10/6569Fluids undergoing a liquid-gas phase change or transition, e.g. evaporation or condensation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/659Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

The present invention relates to a kind of battery modules, the battery module includes: at least one battery cell (2), especially Li-ion batteries piles battery, hot linked coldplate (3) are led with at least one described battery cell (2), wherein, it there also is provided the thermal balance layer (4) for being configured to improve the capacity of heat transmission between at least one battery cell (2) and the coldplate (3) between at least one described battery cell (2) and the coldplate (3), wherein, the thermal balance layer (4) is constructed by basic material (5) and further includes at least one phase-change material (6), at least one described polymer actuator has the inversion temperature higher than 20 DEG C of temperature.

Description

The application of battery module and this battery module
Technical field
The present invention is from the battery module of the type according to independent claims.In addition, the present invention also relates to institute State the application of battery module.
Background technique
It is known from the state of the art, battery module can be made of multiple single battery cells, the battery Group battery can be connected in series and/or in parallel mutual conductive connection.
Especially in the vehicle of electricity operation (EV), hybrid vehicle (HEV) or plug-in hybrid vehicle (PHEV) In the case of, using including plentiful and the strong Li-ion batteries piles battery of power or lithium polymer battery group battery the battery of energy Group module, wherein the battery module preferably has about 100 battery cells, so as to meet be enhanced to row Sail the expection of power.
Based on chemical conversion process, Li-ion batteries piles battery or lithium polymer battery group battery are especially being discharged or are being absorbed Heating when electric flux, thus in order to run battery cell high-power in this way in preferred temperature range, it is also known that, Battery module may include thermoregulating system, and the thermoregulating system should especially cause, and the battery cell is without departing from predetermined Temperature.
It should be noted here that the preferred temperature range of Li-ion batteries piles battery is substantially between 5 DEG C and 35 DEG C.In addition, Service life continues to decline from substantially 40 DEG C of running temperature, should be by temperature adjustment system thus in order to meet the requirement to enough service life Battery cell is maintained in the state of thermally not critical (the thermisch unkritisch) under 40 DEG C by system.This Outside, the temperature difference between different battery cells should not also exceed 5 Kelvins.
In this regard, by for example known thermoregulating system using the fluid for flowing through coldplate of the prior art, wherein the fluid is all Water/ethylene glycol mixture in this way.
In addition, being known from the state of the art, heat is arranged between such coldplate and the battery cell of battery module Equalizing layer, the thermal balance layer are expressed as " Thermal Interface Material (thermal interfacial material) " (TIM) in English.
Summary of the invention
The battery module of feature with independent claims is provided the advantage that can be extremely by reliable way Few one forms hot line road between battery cell and coldplate
In this regard, providing a kind of battery module, the battery module includes at least one battery cell and coldplate. Battery cell especially Li-ion batteries piles battery herein.In addition, coldplate connects with heat conduction at least one battery cell It connects.
Here, there also is provided thermal balance layer, the heat between at least one described battery cell and the coldplate Equalizing layer is configured to improve the capacity of heat transmission between at least one described battery cell and the coldplate.
Here, thermal balance layer is constructed by basic material (Grundmaterial) and further includes at least one phase-change material. At least one described phase-change material has the inversion temperature on 20 DEG C of temperature herein.Preferably, at least one phase transformation material Material has the inversion temperature on 30 DEG C of temperature herein.At least one phase-change material especially has the temperature at 40 DEG C herein On inversion temperature.
By the measure enumerated in the dependent claims, the advantageous extension of the equipment illustrated in the independent claim Scheme and improvement project are possible.
Here it should be noted that phase-change material is interpreted as following material, the feelings that the material changes in ambient temperature It can be converted back and forth between different phases under condition.Such transformation is exceeding or the feelings of not up to so-called inversion temperature herein It is carried out under condition.
Phase transformation described herein especially can be expanded or or be shunk.
Herein, it is particularly possible to be limited by selection phase-change material and by the desirably adjustment direction converted back and forth And temperature.
This convert back and forth between different phases is especially configured to reversible process.
Therefore phase-change material converts back and forth especially between the first phase and the second phase, wherein the first phase inversion temperature it Exist in the case where lower and the second phase is on inversion temperature in the case that exists.
For example, the first phase, which can be solid and the second phase, can be liquid;Or first phase can be it is solid And the second phase can be gaseous;Or first phase can be liquid and the second phase can be it is gaseous.
In addition, thought according to the present invention is it is also possible that the first phase describes the first shape of so-called polymer actuator Shape (erste Form) and the second phase describe the second shape (zweite Form) of so-called polymer actuator.Therefore, make Solid-state is obtained for the first phase and the second phase structure and phase transformation is configured to shape change
It is advantageously carried out as a result, using battery module according to the present invention: to the electricity of an at least battery pack caused by tolerance The surface irregularity in pond and expansion and contraction process due at least one battery cell and in the electricity of battery module The surface modification occurred during operation compensates, so that the hot line road between at least one battery cell and coldplate is logical The equalizing layer holding for crossing calorifics is maintained.Herein can by the shape of phase-change material change make thermal balance layer and it is described extremely The surface irregularity of a few battery cell and the surface modification of at least one battery cell are adapted.
Advantageously, the basic material of the thermal balance layer is constructed by electrically insulating material.Thus it is possible that at least One constructs the electric insulation part (elektrische Isolation) of restriction between battery cell and coldplate.In addition, heat is The basic material of weighing apparatus layer can select as follows, so that additionally can also be at least one battery cell and coldplate Between construct the enough capacity of heat transmission.The basic material of thermal balance layer especially can for example be constructed by polymeric material or by paste Or full-bodied material construction.
It here should be it is once again noted that in order to improve the capacity of heat transmission at least one described battery cell and cold But thermal balance layer is constructed between plate, so that the basic material can have the capacity of heat transmission of raising.
Meet purpose, the basic material of the thermal balance layer is deformable in a manner of elastically and/or plastically.Base Plinth material especially can be deformable in reversible mode.Thus exist it is possible that being compensated during battery module operation At least one battery cell relative to coldplate arrangement in terms of inhomogeneities.
An advantageous aspect according to the present invention, at least one described phase-change material are disposed in the basis of thermal balance layer In material.This have the advantage that exceed at least one phase-change material inversion temperature in the case where, at least one described phase Become material to change its shape and preferably also expand (expandieren), it is possible thereby to reduce at least one battery pack electricity Spacing between pond and coldplate.Thus, it is possible to preferably avoid between at least one described battery cell and coldplate The air gap of formation.
Especially because the air with 0.026 Watt per meter Kelvin has the relatively smaller capacity of heat transmission, it is possible to Avoid the thermal barrier (thermische of the part with high thermal resistance)。
Advantageously, at least one described phase-change material is arranged at least one described battery cell and the basic material Between material and/or at least one described phase-change material is arranged between the coldplate and the basic material.This is with following Advantage: exceed at least one phase-change material inversion temperature in the case where, at least one phase-change material change its shape and It preferably also expands, it is possible thereby to reduce the spacing between at least one battery cell and coldplate.Thus, it is possible to it is preferred that Ground avoids the air gap preferably constructed between at least one battery cell and coldplate.
Especially because the air with 0.026 Watt per meter Kelvin has the lesser capacity of heat transmission, it is possible to avoid The thermal barrier of part with high thermal resistance.
According to a kind of preferred embodiment, thermal balance layer includes multiple phase-change materials.Thus it is possible that providing reliable Hot line road.
One according to the present invention meets the aspect of purpose, at least one described phase-change material constructs in the following manner, makes Obtaining at least one described phase-change material has first shape on the inversion temperature and has under the inversion temperature There is the second shape.
Here, the volume at least twice of the volume of first shape especially the second shape is big.Thus it is possible that providing Reliable hot line road between at least one described battery cell and coldplate.
In addition, the present invention also relates to the use of battery module according to the present invention, for the operation in battery module Period improves the capacity of heat transmission between at least one described battery cell and coldplate.
In addition, the present invention also relates to the use of battery module according to the present invention, for prevent heat from least one Battery cell is transferred on coldplate.
Especially, the phase-change material has this on 50 DEG C, on preferably 65 DEG C and further preferred Inversion temperature on 80 DEG C.
Battery module according to the present invention can be not only used in electric vehicle, hybrid vehicle and plug-in mixing Power car and battery pack in mobile amusement equipment and communication equipment and can apply fixed memory (Speicher it) neutralizes in the memory for goals of medicine, such as intracorporal battery pack.
Detailed description of the invention
It is shown in the accompanying drawings and elaborates the embodiment of the present invention in the following description.Wherein:
Fig. 1 schematically shows a kind of implementation of the battery module according to the present invention at least one phase-change material Mode;
Fig. 2 schematically shows a kind of embodiment of phase-change material.
Specific embodiment
Fig. 1 schematically shows a kind of embodiment of battery module 1.
Battery module 1 includes at least one battery cell 2, at least one described battery cell especially lithium herein Ion battery cell.
In addition, battery module 1 includes coldplate 3.Here, coldplate 3 and at least one thermally conductive company of battery cell 2 It connects.
In order to improve the capacity of heat transmission between at least one described battery cell 2 and the coldplate 3, here, in institute State arrangement thermal balance layer 4 between at least one battery cell 2 and the coldplate 3.
Here, thermal balance layer 4 is constructed by basic material 5.The basic material 5 of thermal balance layer 4 is herein preferably by being electrically insulated Material 7 constructs.For example, basic material 5 can be constructed by silicone or epoxides and additionally include the thermally conductive filling of energy Material (F ü llstoff), for improving the capacity of heat transmission.
In addition, basic material can be constructed by paste or full-bodied material.
In addition, the basic material 5 of the thermal balance layer 4 is preferably constructed in a manner of elastically and/or plastically deformable.
In addition, thermal balance layer 4 includes phase-change material 6.The phase-change material 6 has herein to be turned on 20 DEG C of temperature Change temperature.Phase-change material 6 preferably has the inversion temperature on 30 DEG C of temperature herein.Phase-change material 6 especially has herein Inversion temperature on 40 DEG C of temperature.Thermal balance layer 4 especially may include multiple phase-change materials 6 herein.
Phase-change material 6 so constructs herein, has in the case where so that the phase-change material is on the inversion temperature First shape 61 and there is the second shape 62 in the case where under the inversion temperature.Here, the diagram on the right side of Fig. 1 shows The following state of phase-change material 6 out: in this state, phase-change material forms first shape 61, and the diagram on the left side of Fig. 1 shows The following state of phase-change material 6 out: in this state, phase-change material forms the second shape 62.
It should especially find out compared with the diagram on the left side of Fig. 1 from the diagram on the right side of Fig. 1, the volume of first shape 61 is At least twice of the volume of second shape 62 is big.
Therefore, the diagram on the left side especially shows following state: in this state, temperature is located under inversion temperature, and The diagram on the right side shows following state: in this state, temperature is located on inversion temperature.
Here, Fig. 1 shows a kind of embodiment of battery module 1, wherein at least one described phase-change material 6 is by cloth It sets within the basic material 5 of thermal balance layer 4.
Obviously herein it is also possible that at least one described phase-change material 6 is disposed in coldplate 3 and thermal balance layer 4 Between basic material 5.
Obviously herein it is also possible that at least one described phase-change material 6 is disposed at least one battery pack electricity Between pond 2 and the basic material 5 of the thermal balance layer 4.
It, can be between thermal balance layer 4 and at least one battery cell 2 here, should find out from the diagram on the left side of Fig. 1 Form the air gap 8.
Beyond the inversion temperature of at least one phase-change material 6, the phase-change material changes its shape simultaneously And it especially expands, thermal balance layer 4 is thus allow generally to adapt at least one described battery cell 2 and can use The material of thermal balance layer 4 fills the air gap 8, it is possible thereby to improve the capacity of heat transmission.
Fig. 2 shows a kind of embodiments of phase-change material 6.
Here, showing the phase-change material 6 with the second shape 62 in the diagram on the left side and on the right side in Fig. 2 Phase-change material with first shape 61 is shown in diagram.
Here it should be noted that in the case where the diagram on the left side, temperature is under inversion temperature and showing on the right side In the case where figure, temperature is on inversion temperature.
Here, should will become apparent from again from Fig. 2: especially body of the volume of first shape 61 greater than the second shape 62 Product, and at least twice of the volume of preferably the second shape is big.

Claims (9)

1. a kind of battery module, the battery module include:
At least one battery cell (2), especially Li-ion batteries piles battery, and
Hot linked coldplate (3) are led at least one described battery cell (2), wherein at least one described battery pack It there also is provided between battery (2) and the coldplate (3) thermal balance layer (4), the thermal balance layer is configured to described in raising The capacity of heat transmission between at least one battery cell (2) and the coldplate (3),
It is characterized in that,
The thermal balance layer (4) is constructed by basic material (5) and further includes at least one phase-change material (6), and described at least one A phase-change material has the inversion temperature on 20 DEG C of temperature, it is therefore preferred to have the inversion temperature on 30 DEG C of temperature And especially there is the inversion temperature on 40 DEG C of temperature.
2. according to battery module described in preceding claims 1, which is characterized in that the basis of the thermal balance layer (4) Material (5) is constructed by electrically insulating material (7).
3. the battery module according to one of preceding claims 1 or 2, which is characterized in that the institute of the thermal balance layer (4) It is deformable in a manner of elastically and/or plastically for stating basic material (5).
4. the battery module according to one of preceding claims 1 to 3, which is characterized in that at least one described phase transformation material Material (6) is arranged within the basic material (5).
5. the battery module according to one of preceding claims 1 to 5, which is characterized in that at least one described phase transformation material Material (6) is arranged between at least one battery cell (2) and the basic material (5);And/or at least one described phase Become material (6) to be arranged between the coldplate (3) and the basic material (5).
6. the battery module according to one of preceding claims 1 to 5, which is characterized in that the thermal balance layer (4) includes Multiple phase-change materials (6).
7. the battery module according to one of preceding claims 1 to 6, which is characterized in that at least one described phase transformation material Material (6) is constructed in the following manner, so that at least one described phase-change material (6) has first shape on the inversion temperature (61) there are the second shape (62) and under the inversion temperature, wherein the volume of the especially described first shape (61) is At least twice of the volume of second shape (62) is big.
8. according to claim 1 to battery module described in one of 7 according to the application of such as under type, so that described at least one The capacity of heat transmission between a battery cell (2) and the coldplate (3) is enhanced during the operation of battery module (1).
9. the application to battery module described in one of 7 as follows according to claim 1, so that preventing heat from described At least one battery cell (2) is transferred on the coldplate (3).
CN201810859597.3A 2017-08-01 2018-07-31 The application of battery module and this battery module Pending CN109326818A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102017213272.8 2017-08-01
DE102017213272.8A DE102017213272A1 (en) 2017-08-01 2017-08-01 Battery module and use of such a battery module

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CN109326818A true CN109326818A (en) 2019-02-12

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Cited By (1)

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CN112713354A (en) * 2019-10-08 2021-04-27 通用汽车环球科技运作有限责任公司 Thermal insulation layer incorporating phase change material for power module assembly

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Publication number Priority date Publication date Assignee Title
CN112713354A (en) * 2019-10-08 2021-04-27 通用汽车环球科技运作有限责任公司 Thermal insulation layer incorporating phase change material for power module assembly

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