CN108634482A - A kind of football insole - Google Patents
A kind of football insole Download PDFInfo
- Publication number
- CN108634482A CN108634482A CN201810485162.7A CN201810485162A CN108634482A CN 108634482 A CN108634482 A CN 108634482A CN 201810485162 A CN201810485162 A CN 201810485162A CN 108634482 A CN108634482 A CN 108634482A
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- Prior art keywords
- layer
- polyurethane
- insole
- thickness
- cushioning piece
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/003—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material
- A43B17/006—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material multilayered
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/02—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined wedge-like or resilient
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/08—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined ventilated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
- C08J2203/144—Perhalogenated saturated hydrocarbons, e.g. F3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of football insoles, are related to insole technical field.The present invention includes insole body, insole body includes nanometer bamboo carbon fiber layer, the first layer of polyurethane, the second layer of polyurethane and third layer of polyurethane successively from top to bottom, correspond to the position of person's toe on the downside of the front end of third layer of polyurethane, be both provided with cushioning piece corresponding to the position for corresponding to human body heel portion on the downside of the position of vola before human body and the rear end of third layer of polyurethane, flexible shield foot is arranged corresponding to the position of human body arch portion in the downside of third layer of polyurethane；It is evenly distributed with multiple hexagon protrusions on the upside of nanometer bamboo carbon fiber layer, multiple perforative holes up and down are arranged on third layer of polyurethane.The present invention can allow wearer's dress comfortable, can cater to foot protruding parts and be deformed, and damping, shield foot effect are strong, and can effective protection wearer toe, half sole, arch of foot and heel, good permeability and have mould proof, antibacterial, perspire, deodorization and other effects.
Description
Technical field
The present invention relates to a kind of insole, more particularly to a kind of football insole.
Background technology
Many people enjoy a lot to play soccer, play soccer enough stimulations, all passion, can allow people's waving wantonly on court
Spill the sweat of oneself.But simultaneously, it is also a very fierce movement to play soccer, and during playing football, if protected
Shield measure do not enough in place, can be very easy to damage itself, especially in terms of wear shoes, because playing soccer makes
It is exactly our foot with most, so wearing which type of shoes is impacted to playing soccer.
But people often only focus on requirement of the football to wear shoes, but have ignored insole itself and are risen to the protection of foot
The important function arrived.Insole is to apply very universal articles for daily use, and by effect point, insole can be divided into health insoles, functional shoe
Pad and conventional insole.
In football, the health care of foot needs to realize by insole cooperation, and the structure of traditional sock is laminates
Material sewing is suppressed into either multilayer leather, with certain pliability and shock absorbing effect, is substantially conformed to general
Logical people takes a walk, moves the demands of wear shoes usually, but for football, because the special motion mode of football needs
It wears that good damping effect, gas permeability are relatively high, and has the insole of special protection function to toe, sole, arch of foot, heel.
Traditional sock then has as a drawback that：One, the upper layer of traditional sock and the nonhomogeneous hardness of vola skin are larger, meeting
Football crowd is enabled to feel that foot is uncomfortable；Secondly, the material of main part of traditional sock be not easy to deform, or after deformation
The problems such as being difficult to restore, easily aggravating blue foot numbness of football crowd, pain, thrombosis, nigrescence, oedema；Thirdly,
Traditional sock damping, shield foot effect it is poor, foot's half sole of football crowd crowd and followed by bottom be easier impacted,
Easily aggravation vola bone, ankle-joint and kneed disease problems；Five, traditional sock poor air permeability is easy to grow bacterium, true
Bacterium easily aggravates pedal edema, the problem of interdigit erosion.
Invention content
The technical problem to be solved by the present invention is in view of the above shortcomings of the prior art, provide a kind of football insole,
The insole can allow wearer's dress comfortable, can cater to foot protruding parts and be deformed, can be restored automatically after deformation, damping,
Shield foot effect is strong, and can effective protection wearer toe, half sole, arch of foot and heel, good permeability and have mould proof, antibacterial, perspire,
Deodorization and other effects.
In order to solve the above technical problems, the technical scheme is that：A kind of football insole, including insole body,
It is characterized in that：The insole body includes nanometer bamboo carbon fiber layer, the first layer of polyurethane, the second polyurethane successively from top to bottom
Layer and third layer of polyurethane, the front end downside of the third layer of polyurethane are provided with first corresponding to the position of person's toe and subtract
Gasket is shaken, the front end downside of the third layer of polyurethane is provided with the second cushioning piece corresponding to the position of vola before human body,
The position for corresponding to human body heel portion on the downside of the rear end of the third layer of polyurethane is provided with third cushioning piece, the third
Flexible shield foot is arranged in the position that the downside of layer of polyurethane corresponds to human body arch portion；From the front end of insole body to rear end,
30~120 hexagon protrusions are evenly distributed on the upside of the nanometer bamboo carbon fiber layer, are arranged on the third layer of polyurethane
About 50~150 perforative holes.
As being expanded on further for the present invention：
Preferably, the shape of first cushioning piece is torch-shaped, and first cushioning piece is corresponding with person's toe, is used
In protection person's toe；The shape of second cushioning piece is in tongue type, and second cushioning piece is opposite with vola before human body
It answers, for protecting vola before human body；The shape of the third cushioning piece is rounded, the third cushioning piece and human body heel
Portion is corresponding, for protecting human body heel portion；The shape of the elasticity shield foot is in half-moon-shaped, and the elasticity shield foot package is whole
A human body arch portion.
Preferably, the thickness of the nanometer bamboo carbon fiber layer is 0.4~0.9 mm, and the thickness of first layer of polyurethane is
3.0~7.0mm, the thickness of second layer of polyurethane are 3.5~9.5mm, the thickness of the third layer of polyurethane is 3.5~
10.0mm, the thickness of first cushioning piece are 5.5~15.0mm, the thickness of second cushioning piece is 4.0~
The thickness of 8.0mm, the third cushioning piece are 3.5~6.0mm, and the thickness of the elasticity shield foot is 4.0~7.5mm.
Preferably, the thickness of the nanometer bamboo carbon fiber layer is 0.5~0.8 mm, and the thickness of first layer of polyurethane is
3.9~6.5mm, the thickness of second layer of polyurethane are 3.8~8.5mm, the thickness of the third layer of polyurethane is 4.5~
The thickness of 9.0mm, first cushioning piece are 6.5~13.0mm, and the thickness of second cushioning piece is 5.0~7.0mm,
The thickness of the third cushioning piece is 4.5~5.5mm, and the thickness of the elasticity shield foot is 4.5~7.0mm.
Preferably, include waist and insole heel in insole half sole, insole successively from the front end of insole body to rear end,
In, waist and insole heel are both provided with the outer rim up tilted in the insole, and the tilting height of the insole heel is less than shoes
The tilting height of waist both sides in pad.
Preferably, the nanometer bamboo carbon fiber layer is by bamboo charcoal fiber, nano silver fibre, polyester fiber and viscose rayon group
At；Ceramic powders and coupling agent containing 2%-5% in viscose rayon, coupling agent are the 0.1%-0.3% of ceramic powders weight；Ceramics
Powder is made of following weight percent composition：Maifanite powder 30%-60%, manganese dioxide 10%-15%, tungstic acid 5%-8%,
Zinc oxide 10%-15%, zirconium dioxide 30%-60%, silica 35%-40%, silver oxide 10%-15%, titanium dioxide 5%-15%, cunning
Mountain flour 0.3%-0.4%；Coupling agent be ethyl orthosilicate, titanate esters one or two.
Preferably, the preparation method of the viscose rayon is：（1）, by maifanite powder, manganese dioxide, tungstic acid, oxygen
Change zinc, zirconium dioxide, silica, silver oxide, titanium dioxide, talcum powder mixing, it is 1-2 to be crushed to average grain diameter after sintering
μm ceramic powders；（2）, coupling agent mixed with the ceramic powders, obtain modified ceramic powder；（3）, modified make pottery described
Porcelain powder and viscose glue blending squeeze out, slice, and viscose glue slice is made；（4）, by the viscose glue be sliced heating melting, squeeze, spinneret
Molding, you can viscose rayon is made.
Preferably, the preparation method of the nanometer bamboo carbon fiber layer is：
（1）, bamboo charcoal fiber, nano silver fibre, polyester fiber and viscose rayon be uniformly mixed, dispersant, binder, soft is added
Soft dose is stirred, and dries processing；
（2）, step will be passed through（1）The fiber of processing is handled through rove, spun yarn, automatic winding, yarn steaming, high speed doubling, double twisting
To spun yarn；
（3）, weaved using cassimere twill；
（4）, to fabric carry out washing process, water temperature control at 35-38 DEG C, wash 5-8min；
（5）, adjustment pH value to 5-7, be warming up to 80 DEG C, then impregnate 50 minutes, dry, cut the obtained nanometer bamboo carbon fiber
Layer.
Preferably, first cushioning piece is made of the following raw material reaction foaming：100 parts of polyether polyol, six is sub-
Methyl 1,25~30 parts of 6- isocyanates, 15~25 parts of lysine diisocyanate, 1,25~30 parts of hexamethylene-diisocyanate, two
5~15 parts of methylenebis phenyl isocyanate, 1,5- 5~10 parts of pentamethylene diisocyanate, isophorone diisocyanate 5~
10 parts, 5~15 parts of m-xylylene diisocyanate, 2~3 parts of camellia pollen, 12~13 parts of water, 0.5~3 part of silicone oil, catalysis
0.2~1 part of agent, 0.5~1 part of foaming agent, 2~5 parts of crosslinking agent；
Preferably, the preparation method of first cushioning piece is：By the polyether polyol of corresponding parts by weight, hexa-methylene 1,
6- isocyanates, lysine diisocyanate, 1, hexamethylene-diisocyanate, methyl diphenylene diisocyanate, 1,5- five methylene
Group diisocyanate, isophorone diisocyanate, m-xylylene diisocyanate are added in mixer and stir evenly, add
Heat is warming up to 35~38 degrees Celsius, and other raw materials of corresponding number are added in mixer, and high-speed stirred is fallen after 6~8 seconds
Enter after mold foams and cure, obtains corresponding first cushioning piece；
The hydroxyl value of the polyether polyol is 55~85 mgKOH/g, and molecular weight is 800~2000, and the silicone oil is BF-2370
It is 1.5 with two kinds of mass ratioes of B-4900：1 mixture；The catalyst is stannous octoate；The foaming agent is trichlorine fluorine first
Alkane；Crosslinking agent is ethylenediamine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol.
The beneficial effects of the invention are as follows：One, due to insole body upper layer be nanometer bamboo carbon fiber layer and vola skin
Nonhomogeneous hardness it is smaller, football crowd can be enabled to feel that foot is very comfortable；Secondly, due to being arranged under nanometer bamboo carbon fiber layer
Three layers of layer of polyurethane can cater to foot protruding parts and be deformed, can be restored automatically after deformation, realize to football crowd
Foot health-care；Thirdly, elasticity shield foot is equipped with due to the medial end portions of third layer of polyurethane, can arch upward in the middle part of insole body, patch
The arch portion for closing wearer plays the role of pressing arch of foot acupuncture point, promotes blood circulation；Four, due to third layer of polyurethane
Front end on the downside of correspond to the position of person's toe and be provided with the first cushioning piece, it is right on the downside of the front end of third layer of polyurethane
It should be provided with the second cushioning piece in the position of vola before human body, correspond to human body heel on the downside of the rear end of third layer of polyurethane
The position in portion is provided with third cushioning piece, and flexible shield foot is arranged in the position that downside corresponds on the inside of human body arch portion, because
This, insole elasticity is good, can effectively absorb the foot bones impact force of football crowd, protection vola bone, ankle-joint and knee
Joint has outstanding damping shield foot effect；Five, nanometer bamboo carbon fiber layer has moisture absorption ventilative, bacteriostasis antibiosis, environmentally protective
The characteristics of, therefore this insole is mould proof, antibacterial, perspire, deodorization, air permeability effect are good；Six, nanometer bamboo carbon fiber layer is by bamboo charcoal fibre
Dimension, nano silver fibre, polyester fiber and viscose rayon form, and ceramic powders are contained in viscose rayon, wheat is added in ceramic powders
Meal stone powder, can discharge the infrared ray beneficial to human body, and medical stone can also utilize method of the self component by absorbing, decomposing
Noxious material, released mineral matter and balanced human's minerals quantity are ionized, when football foot perspires, medical stone can dissipate
Send out the essential various minerals of human body；Talcum powder has antibacterial action；Its special preparation method can meet human body to micro-
The primary demand of secondary element, and can moisture absorption to a certain extent, keep insole drying；Seventh, the first cushioning piece subtracts higher than second
Shaking gasket and third cushioning piece, football is played football with toe portion, especially when shooting, this mode meeting
Cause very big injury, the preparation method of the first special cushioning piece that can protect football crowd on the toe of oneself
Toe do not come to harm, the 1 of addition, hexamethylene-diisocyanate can prevent xanthochromia, and camellia pollen, which can play, enables football crowd
The effect refreshed oneself, energy is kept to concentrate；Eighth, 30~120 hexagon protrusions are evenly distributed on the upside of nanometer bamboo carbon fiber layer,
Can increase football crowd swerve, pause and accelerator in frictional force, be arranged on third layer of polyurethane
About 50~150 perforative holes further enhance the gas permeability of this insole.
Description of the drawings
Fig. 1 is one of the dispersed structure schematic diagram of the present invention.
Fig. 2 is the two of the dispersed structure schematic diagram of the present invention.
In figure：1. nanometer bamboo carbon fiber layer；2. the first layer of polyurethane；3. the second layer of polyurethane；4. third layer of polyurethane；5.
First cushioning piece；6. the second cushioning piece；7. third cushioning piece；8. elasticity shield foot；9. hexagon is raised；10. hole.
Specific implementation mode
Xia Mianjiehefutuduibenfamingjiegouyuanlihegongzuoyuanlizuojinyibuxiangxishuoming.
As shown in Fig. 1~Fig. 2, the present invention is a kind of football insole, including insole body, it is characterised in that：It is described
Insole body includes nanometer bamboo carbon fiber layer 1, the first layer of polyurethane 2, the second layer of polyurethane 3 and the poly- ammonia of third successively from top to bottom
The front end downside of ester layer 4, the third layer of polyurethane 4 is provided with the first cushioning piece 5, institute corresponding to the position of person's toe
The position for stating vola before corresponding to human body on the downside of the front end of third layer of polyurethane 4 is provided with the second cushioning piece 6, the third
The position for corresponding to human body heel portion on the downside of the rear end of layer of polyurethane 4 is provided with third cushioning piece 7, the third polyurethane
Flexible shield foot 8 is arranged in the position that the downside of layer 4 corresponds to human body arch portion；It is described from the front end of insole body to rear end
1 upside of nanometer bamboo carbon fiber layer is evenly distributed with 30~120 hexagon protrusions 9, and 50 are arranged on the third layer of polyurethane 4
About~150 perforative holes 10.Nanometer bamboo carbon fiber layer 1 has the characteristics that moisture absorption ventilative, bacteriostasis antibiosis, environmentally protective,
Therefore this insole is mould proof, antibacterial, perspire, deodorization, air permeability effect are good；First layer of polyurethane 2, the second layer of polyurethane 3 and third are poly-
Urethane layer 4 is degradable, ventilative with environmental protection, deodorization, perspires effect.
As shown in Fig. 1~Fig. 2, the shape of first cushioning piece 5 is torch-shaped, first cushioning piece 5 and people
Body toe is corresponding, for protecting person's toe；The shape of second cushioning piece 6 is in tongue type, second cushioning piece 6
It is corresponding with vola before human body, for protecting vola before human body；The shape of the third cushioning piece 7 is rounded, the third
Cushioning piece 7 is corresponding with human body heel portion, for protecting human body heel portion；The shape of the elasticity shield foot 8 in half-moon-shaped,
The elasticity shield foot 8 wraps up entire human body arch portion.
As shown in Fig. 1~Fig. 2, the thickness of the nanometer bamboo carbon fiber layer 1 is 0.4~0.9 mm, first polyurethane
The thickness of layer 2 is 3.0~7.0mm, and the thickness of second layer of polyurethane 3 is 3.5~9.5mm, the third layer of polyurethane 4
Thickness be 3.5~10.0mm, the thickness of first cushioning piece 5 is 5.5~15.0mm, second cushioning piece 6
Thickness is 4.0~8.0mm, and the thickness of the third cushioning piece 7 is 3.5~6.0mm, and the thickness of the elasticity shield foot 8 is
4.0~7.5mm.
Preferably, the thickness of the nanometer bamboo carbon fiber layer 1 is 0.5~0.8 mm, the thickness of first layer of polyurethane 2
Thickness for 3.9~6.5mm, second layer of polyurethane 3 is 3.8~8.5mm, and the thickness of the third layer of polyurethane 4 is
The thickness of 4.5~9.0mm, first cushioning piece 5 are 6.5~13.0mm, and the thickness of second cushioning piece 6 is 5.0
~7.0mm, the thickness of the third cushioning piece 7 are 4.5~5.5mm, the thickness of the elasticity shield foot 8 is 4.5~
7.0mm。
Include waist and insole in insole half sole, insole successively from the front end of insole body to rear end as shown in Fig. 1~Fig. 2
Heel, wherein waist and insole heel are both provided with the outer rim up tilted, the tilting height of the insole heel in the insole
Less than the tilting height of waist both sides in insole.
It is material prescription and process example below.
Embodiment 1：
The nanometer bamboo carbon fiber layer 1 is made of bamboo charcoal fiber, nano silver fibre, polyester fiber and viscose rayon；Viscose rayon
In containing 2% ceramic powders and coupling agent, coupling agent is the 0.1% of ceramic powders weight；Ceramic powders are by following weight percent
It is made than ingredient：Maifanite powder 30%, manganese dioxide 10%, tungstic acid 5%, zinc oxide 10%, zirconium dioxide 30%, titanium dioxide
Silicon 35%, silver oxide 10%, titanium dioxide 5%, talcum powder 0.3%；Coupling agent be ethyl orthosilicate, titanate esters one or two.
The preparation method of the viscose rayon is：
（1）, by maifanite powder, manganese dioxide, tungstic acid, zinc oxide, zirconium dioxide, silica, silver oxide, titanium dioxide
Titanium, talcum powder mixing, are crushed to the ceramic powders that average grain diameter is 1-2 μm after sintering；（2）, by coupling agent and the ceramics
Powder mixes, and obtains modified ceramic powder；（3）, by the modified ceramic powder and viscose glue blending, squeeze out, slice, viscose glue be made
Slice；（4）, by the viscose glue be sliced heating melting, squeeze, spinneret molding, you can be made viscose rayon.
The preparation method of the nanometer bamboo carbon fiber layer 1 is：
（1）, bamboo charcoal fiber, nano silver fibre, polyester fiber and viscose rayon be uniformly mixed, dispersant, binder, soft is added
Soft dose is stirred, and dries processing；
（2）, step will be passed through（1）The fiber of processing is handled through rove, spun yarn, automatic winding, yarn steaming, high speed doubling, double twisting
To spun yarn；
（3）, weaved using cassimere twill；
（4）, to fabric carry out washing process, water temperature control at 35-38 DEG C, wash 5-8min；
（5）, adjustment pH value to 5-7, be warming up to 80 DEG C, then impregnate 50 minutes, dry, cut the obtained nanometer bamboo carbon fiber
Layer 1.
First cushioning piece 5 is made of the following raw material reaction foaming：100 parts of polyether polyol, hexa-methylene 1,
25 parts of 6- isocyanates, 15 parts of lysine diisocyanate, 1,25 parts of hexamethylene-diisocyanate, methyl diphenylene diisocyanate
5 parts, 1,5- 5 parts of pentamethylene diisocyanate, 5 parts of isophorone diisocyanate, m-xylylene diisocyanate 5
Part, 2 parts of camellia pollen, 12 parts of water, 0.5 part of silicone oil, 0.2 part of catalyst, 0.5 part of foaming agent, 2 parts of crosslinking agent；
The preparation method of first cushioning piece 5 is：By the polyether polyol of corresponding parts by weight, hexa-methylene 1,6- isocyanides
Acid esters, lysine diisocyanate, 1, hexamethylene-diisocyanate, methyl diphenylene diisocyanate, 1,5- pentamethylene two is different
Cyanate, isophorone diisocyanate, m-xylylene diisocyanate are added in mixer and stir evenly, heat temperature raising
To 35~38 degrees Celsius, other raw materials of corresponding number are added in mixer, high-speed stirred pours into mold after 6~8 seconds
After foaming and curing, corresponding first cushioning piece 5 is obtained；
The hydroxyl value of the polyether polyol is 55~85 mgKOH/g, and molecular weight is 800~2000, and the silicone oil is BF-2370
It is 1.5 with two kinds of mass ratioes of B-4900：1 mixture；The catalyst is stannous octoate；The foaming agent is trichlorine fluorine first
Alkane；Crosslinking agent is ethylenediamine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol.
The other structures component of insole is that current material is obtained by commonsense method.
Embodiment 2：
The nanometer bamboo carbon fiber layer 1 is made of bamboo charcoal fiber, nano silver fibre, polyester fiber and viscose rayon；Viscose rayon
In containing 5% ceramic powders and coupling agent, coupling agent is the 0.3% of ceramic powders weight；Ceramic powders are by following weight percent
It is made than ingredient：Maifanite powder 60%, manganese dioxide 15%, tungstic acid 8%, zinc oxide 15%, zirconium dioxide 60%, titanium dioxide
Silicon 40%, silver oxide 15%, titanium dioxide 15%, talcum powder 0.4%；Coupling agent be ethyl orthosilicate, titanate esters one or two.
The preparation method of the viscose rayon is：
（1）, by maifanite powder, manganese dioxide, tungstic acid, zinc oxide, zirconium dioxide, silica, silver oxide, titanium dioxide
Titanium, talcum powder mixing, are crushed to the ceramic powders that average grain diameter is 1-2 μm after sintering；（2）, by coupling agent and the ceramics
Powder mixes, and obtains modified ceramic powder；（3）, by the modified ceramic powder and viscose glue blending, squeeze out, slice, viscose glue be made
Slice；（4）, by the viscose glue be sliced heating melting, squeeze, spinneret molding, you can be made viscose rayon.
The preparation method of the nanometer bamboo carbon fiber layer 1 is：
（1）, bamboo charcoal fiber, nano silver fibre, polyester fiber and viscose rayon be uniformly mixed, dispersant, binder, soft is added
Soft dose is stirred, and dries processing；
（2）, step will be passed through（1）The fiber of processing is handled through rove, spun yarn, automatic winding, yarn steaming, high speed doubling, double twisting
To spun yarn；
（3）, weaved using cassimere twill；
（4）, to fabric carry out washing process, water temperature control at 35-38 DEG C, wash 5-8min；
（5）, adjustment pH value to 5-7, be warming up to 80 DEG C, then impregnate 50 minutes, dry, cut the obtained nanometer bamboo carbon fiber
Layer 1.
First cushioning piece 5 is made of the following raw material reaction foaming：100 parts of polyether polyol, hexa-methylene 1,
30 parts of 6- isocyanates, 25 parts of lysine diisocyanate, 1,30 parts of hexamethylene-diisocyanate, methyl diphenylene diisocyanate
15 parts, 1,5- 10 parts of pentamethylene diisocyanate, 10 parts of isophorone diisocyanate, m-xylylene diisocyanate
15 parts, 3 parts of camellia pollen, 13 parts of water, 3 parts of silicone oil, 1 part of catalyst, 1 part of foaming agent, 5 parts of crosslinking agent；
The preparation method of first cushioning piece 5 is：By the polyether polyol of corresponding parts by weight, hexa-methylene 1,6- isocyanides
Acid esters, lysine diisocyanate, 1, hexamethylene-diisocyanate, methyl diphenylene diisocyanate, 1,5- pentamethylene two is different
Cyanate, isophorone diisocyanate, m-xylylene diisocyanate are added in mixer and stir evenly, heat temperature raising
To 35~38 degrees Celsius, other raw materials of corresponding number are added in mixer, high-speed stirred pours into mold after 6~8 seconds
After foaming and curing, corresponding first cushioning piece 5 is obtained；
The hydroxyl value of the polyether polyol is 55~85 mgKOH/g, and molecular weight is 800~2000, and the silicone oil is BF-2370
It is 1.5 with two kinds of mass ratioes of B-4900：1 mixture；The catalyst is stannous octoate；The foaming agent is trichlorine fluorine first
Alkane；Crosslinking agent is ethylenediamine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol.
The other structures component of insole is that current material is obtained by commonsense method.
Embodiment 3：
The nanometer bamboo carbon fiber layer 1 is made of bamboo charcoal fiber, nano silver fibre, polyester fiber and viscose rayon；Viscose rayon
In containing 3% ceramic powders and coupling agent, coupling agent is the 0.25% of ceramic powders weight；Ceramic powders are by following weight percent
It is made than ingredient：Maifanite powder 40%, manganese dioxide 11%, tungstic acid 6%, zinc oxide 13%, zirconium dioxide 35%, titanium dioxide
Silicon 38%, silver oxide 14%, titanium dioxide 13%, talcum powder 0.34%；Coupling agent is ethyl orthosilicate, one kind of titanate esters or two
Kind.
The preparation method of the viscose rayon is：
（1）, by maifanite powder, manganese dioxide, tungstic acid, zinc oxide, zirconium dioxide, silica, silver oxide, titanium dioxide
Titanium, talcum powder mixing, are crushed to the ceramic powders that average grain diameter is 1-2 μm after sintering；（2）, by coupling agent and the ceramics
Powder mixes, and obtains modified ceramic powder；（3）, by the modified ceramic powder and viscose glue blending, squeeze out, slice, viscose glue be made
Slice；（4）, by the viscose glue be sliced heating melting, squeeze, spinneret molding, you can be made viscose rayon.
The preparation method of the nanometer bamboo carbon fiber layer 1 is：
（1）, bamboo charcoal fiber, nano silver fibre, polyester fiber and viscose rayon be uniformly mixed, dispersant, binder, soft is added
Soft dose is stirred, and dries processing；
（2）, step will be passed through（1）The fiber of processing is handled through rove, spun yarn, automatic winding, yarn steaming, high speed doubling, double twisting
To spun yarn；
（3）, weaved using cassimere twill；
（4）, to fabric carry out washing process, water temperature control at 35-38 DEG C, wash 5-8min；
（5）, adjustment pH value to 5-7, be warming up to 80 DEG C, then impregnate 50 minutes, dry, cut the obtained nanometer bamboo carbon fiber
Layer 1.
The other structures component of insole is that current material is obtained by commonsense method.
Embodiment 4
First cushioning piece 5 is made of the following raw material reaction foaming：100 parts of polyether polyol, hexa-methylene 1,6- is different
28 parts of cyanate, 20 parts of lysine diisocyanate, 1,26 parts of hexamethylene-diisocyanate, methyl diphenylene diisocyanate 12
Part, 1,5- 8 parts of pentamethylene diisocyanate, 7 parts of isophorone diisocyanate, m-xylylene diisocyanate 11
Part, 2.5 parts of camellia pollen, 12 parts of water, 2 parts of silicone oil, 0.8 part of catalyst, 0.8 part of foaming agent, 4 parts of crosslinking agent；
The preparation method of first cushioning piece 5 is：By the polyether polyol of corresponding parts by weight, hexa-methylene 1,6- isocyanides
Acid esters, lysine diisocyanate, 1, hexamethylene-diisocyanate, methyl diphenylene diisocyanate, 1,5- pentamethylene two is different
Cyanate, isophorone diisocyanate, m-xylylene diisocyanate are added in mixer and stir evenly, heat temperature raising
To 35~38 degrees Celsius, other raw materials of corresponding number are added in mixer, high-speed stirred pours into mold after 6~8 seconds
After foaming and curing, corresponding first cushioning piece 5 is obtained；
The hydroxyl value of the polyether polyol is 55~85 mgKOH/g, and molecular weight is 800~2000, and the silicone oil is BF-2370
It is 1.5 with two kinds of mass ratioes of B-4900：1 mixture；The catalyst is stannous octoate；The foaming agent is trichlorine fluorine first
Alkane；Crosslinking agent is ethylenediamine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol.
The other structures component of insole is that current material is obtained by commonsense method.
All it is that current material is carried out by the insole that commonsense method obtains by the embodiment 1-4 insoles prepared and all components
Comparison finds that the insole of embodiment 1-4 makes wearer's dress comfortable, can cater to foot protruding parts and be deformed, after deformation
Can restore automatically, damping, shield foot effect are strong, and can effective protection wearer toe, half sole, arch of foot and heel, good permeability and
There is mould proof, antibacterial, perspire, deodorization and other effects.The especially insole of Examples 1 and 2, comfort highest, and gas permeability, it is mould proof,
Antibacterial, perspire, deodorization and other effects it is best；Embodiment 3 protects the effect that toe does not come to harm compared to Examples 1 and 2, prevents shoes
Pad xanthochromia and the effect for enabling wearer refresh oneself, energy being kept to concentrate are slightly worse；Embodiment 4 is ventilative compared to Examples 1 and 2 moisture absorption to be kept
Insole is dried, and the effect of bacteriostasis antibiosis is slightly worse.
The above is only better embodiment of the present invention, and every technical solution according to the present invention is to above implementation
Any subtle modifications, equivalent variations and modifications, belong in the range of technical solution of the present invention made by mode.
Claims (10)
1. a kind of football insole, including insole body, it is characterised in that：The insole body includes receiving successively from top to bottom
Rice bamboo, the first layer of polyurethane, the second layer of polyurethane and third layer of polyurethane, the front end of the third layer of polyurethane
The position that downside corresponds to person's toe is provided with the first cushioning piece, corresponds on the downside of the front end of the third layer of polyurethane
The position of vola is provided with the second cushioning piece before human body, corresponds to human body heel on the downside of the rear end of the third layer of polyurethane
The position in portion is provided with third cushioning piece, and the downside of the third layer of polyurethane is provided with corresponding to the position of human body arch portion
Elasticity shield foot；From the front end of insole body to rear end, 30~120 six are evenly distributed on the upside of the nanometer bamboo carbon fiber layer
Side shape is raised, and about 50~150 perforative holes are arranged on the third layer of polyurethane.
2. football insole according to claim 1, it is characterised in that：The shape of first cushioning piece is torch
Type, first cushioning piece is corresponding with person's toe, for protecting person's toe；The shape of second cushioning piece is in
Tongue type, second cushioning piece is corresponding with vola before human body, for protecting vola before human body；The third cushioning piece
Shape is rounded, and the third cushioning piece is corresponding with human body heel portion, for protecting human body heel portion；The elasticity shield foot
The shape in portion is in half-moon-shaped, the entire human body arch portion of the elasticity shield foot package.
3. football insole according to claim 1, it is characterised in that：The thickness of the nanometer bamboo carbon fiber layer is
0.4~0.9 mm, the thickness of first layer of polyurethane are 3.0~7.0mm, the thickness of second layer of polyurethane is 3.5~
9.5mm, the thickness of the third layer of polyurethane are 3.5~10.0mm, the thickness of first cushioning piece is 5.5~
The thickness of 15.0mm, second cushioning piece are 4.0~8.0mm, and the thickness of the third cushioning piece is 3.5~6.0mm,
The thickness of the elasticity shield foot is 4.0~7.5mm.
4. football insole according to claim 3, it is characterised in that：The thickness of the nanometer bamboo carbon fiber layer is
0.5~0.8 mm, the thickness of first layer of polyurethane are 3.9~6.5mm, the thickness of second layer of polyurethane is 3.8~
8.5mm, the thickness of the third layer of polyurethane are 4.5~9.0mm, the thickness of first cushioning piece is 6.5~
The thickness of 13.0mm, second cushioning piece are 5.0~7.0mm, and the thickness of the third cushioning piece is 4.5~5.5mm,
The thickness of the elasticity shield foot is 4.5~7.0mm.
5. the football insole according to any one of Claims 1 to 4, it is characterised in that：Before insole body
End includes waist and insole heel in insole half sole, insole successively, wherein waist and insole heel are all provided in the insole to rear end
It is equipped with the outer rim up tilted, the tilting height of the insole heel is less than the tilting height of waist both sides in insole.
6. football insole according to claim 1, it is characterised in that：The nanometer bamboo carbon fiber layer is by bamboo charcoal fibre
Dimension, nano silver fibre, polyester fiber and viscose rayon composition；Ceramic powders and coupling agent containing 2%-5% in viscose rayon, it is even
Join the 0.1%-0.3% that agent is ceramic powders weight；Ceramic powders are made of following weight percent composition：Maifanite powder 30%-
60%, manganese dioxide 10%-15%, tungstic acid 5%-8%, zinc oxide 10%-15%, zirconium dioxide 30%-60%, silica 35%-
40%, silver oxide 10%-15%, titanium dioxide 5%-15%, talcum powder 0.3%-0.4%；Coupling agent is ethyl orthosilicate, titanate esters
It is one or two kinds of.
7. football insole according to claim 6, it is characterised in that：The preparation method of the viscose rayon is：
（1）, by maifanite powder, manganese dioxide, tungstic acid, zinc oxide, zirconium dioxide, silica, silver oxide, titanium dioxide,
Talcum powder mixes, and is crushed to the ceramic powders that average grain diameter is 1-2 μm after sintering；（2）, by coupling agent and the ceramic powders
Mixing, obtains modified ceramic powder；（3）, by the modified ceramic powder and viscose glue blending, squeeze out, slice, obtained viscose glue is cut
Piece；（4）, by the viscose glue be sliced heating melting, squeeze, spinneret molding, you can be made viscose rayon.
8. football insole according to claim 6, it is characterised in that：The preparation method of the nanometer bamboo carbon fiber layer
For：
（1）, bamboo charcoal fiber, nano silver fibre, polyester fiber and viscose rayon be uniformly mixed, dispersant, binder, soft is added
Soft dose is stirred, and dries processing；
（2）, step will be passed through（1）The fiber of processing is handled through rove, spun yarn, automatic winding, yarn steaming, high speed doubling, double twisting
To spun yarn；
（3）, weaved using cassimere twill；
（4）, to fabric carry out washing process, water temperature control at 35-38 DEG C, wash 5-8min；
（5）, adjustment pH value to 5-7, be warming up to 80 DEG C, then impregnate 50 minutes, dry, cut the obtained nanometer bamboo carbon fiber
Layer.
9. football insole according to claim 1, it is characterised in that：First cushioning piece is anti-by the following raw material
Made of should foaming：100 parts of polyether polyol, hexa-methylene 1,25~30 parts of 6- isocyanates, lysine diisocyanate 15
~25 parts, 1,25~30 parts of hexamethylene-diisocyanate, 5~15 parts of methyl diphenylene diisocyanate, 1,5- pentamethylene two is different
5~10 parts of cyanate, 5~10 parts of isophorone diisocyanate, 5~15 parts of m-xylylene diisocyanate, camellia pollen 2
~3 parts, 12~13 parts of water, 0.5~3 part of silicone oil, 0.2~1 part of catalyst, 0.5~1 part of foaming agent, 2~5 parts of crosslinking agent.
10. football insole according to claim 9, it is characterised in that：The preparation method of first cushioning piece
For：By the polyether polyol of corresponding parts by weight, hexa-methylene 1,6- isocyanates, lysine diisocyanate, 1,6- oneself two
Isocyanates, methyl diphenylene diisocyanate, 1,5- pentamethylene diisocyanate, isophorone diisocyanate, isophthalic
Dimethylene diisocyanate is added in mixer and stirs evenly, and 35~38 degrees Celsius is heated to, by its of corresponding number
Its raw material is added in mixer, and high-speed stirred is poured into after 6~8 seconds after mold foams and cure, and is obtained corresponding first and is subtracted
Shake gasket；
The hydroxyl value of the polyether polyol is 55~85 mgKOH/g, and molecular weight is 800~2000, and the silicone oil is BF-2370
It is 1.5 with two kinds of mass ratioes of B-4900：1 mixture；The catalyst is stannous octoate；The foaming agent is trichlorine fluorine first
Alkane；Crosslinking agent is ethylenediamine, triethylene glycol and dipropyl（Support）Three kinds of mixtures of glycol.
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| CN201810485162.7A CN108634482B (en) | 2018-05-21 | 2018-05-21 | Football insole |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810485162.7A CN108634482B (en) | 2018-05-21 | 2018-05-21 | Football insole |
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| CN108634482B CN108634482B (en) | 2020-12-25 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110037382A (en) * | 2019-04-01 | 2019-07-23 | 章国雄 | A kind of functional polyurethane insole |
| USD903268S1 (en) | 2019-02-06 | 2020-12-01 | S. C. Johnson & Son, Inc. | Insole |
| USD906658S1 (en) | 2019-02-19 | 2021-01-05 | S. C. Johnson & Son, Inc. | Insole |
| CN113662328A (en) * | 2021-09-01 | 2021-11-19 | 东莞尊荣鞋业有限公司 | Antibacterial insole |
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| CN107136641A (en) * | 2017-07-12 | 2017-09-08 | 东莞市顺风运动器材有限公司 | A kind of fire-fighting operational training shoe-pad |
| CN107440231A (en) * | 2017-07-04 | 2017-12-08 | 东莞市顺风运动器材有限公司 | A kind of strenuous exercise protects shoe-pad |
| US20180000196A1 (en) * | 2016-06-30 | 2018-01-04 | Boot Royalty Company, L.P. | Comfort system for boots |
| US20180084865A1 (en) * | 2016-09-28 | 2018-03-29 | Te-Wei TANG | Insole |
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| US20180000196A1 (en) * | 2016-06-30 | 2018-01-04 | Boot Royalty Company, L.P. | Comfort system for boots |
| US20180084865A1 (en) * | 2016-09-28 | 2018-03-29 | Te-Wei TANG | Insole |
| CN107095392A (en) * | 2017-07-04 | 2017-08-29 | 东莞市顺风运动器材有限公司 | A kind of the elderly's Special shoe pad |
| CN107440231A (en) * | 2017-07-04 | 2017-12-08 | 东莞市顺风运动器材有限公司 | A kind of strenuous exercise protects shoe-pad |
| CN107136641A (en) * | 2017-07-12 | 2017-09-08 | 东莞市顺风运动器材有限公司 | A kind of fire-fighting operational training shoe-pad |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USD903268S1 (en) | 2019-02-06 | 2020-12-01 | S. C. Johnson & Son, Inc. | Insole |
| USD906658S1 (en) | 2019-02-19 | 2021-01-05 | S. C. Johnson & Son, Inc. | Insole |
| USD935758S1 (en) | 2019-02-19 | 2021-11-16 | S. C. Johnson & Son, Inc. | Insole |
| CN110037382A (en) * | 2019-04-01 | 2019-07-23 | 章国雄 | A kind of functional polyurethane insole |
| CN113662328A (en) * | 2021-09-01 | 2021-11-19 | 东莞尊荣鞋业有限公司 | Antibacterial insole |
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|---|---|
| CN108634482B (en) | 2020-12-25 |
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