CN108586907A - A kind of CABLE MATERIALS containing the stink agent of triggering property - Google Patents
A kind of CABLE MATERIALS containing the stink agent of triggering property Download PDFInfo
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- CN108586907A CN108586907A CN201810447476.8A CN201810447476A CN108586907A CN 108586907 A CN108586907 A CN 108586907A CN 201810447476 A CN201810447476 A CN 201810447476A CN 108586907 A CN108586907 A CN 108586907A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Physics & Mathematics (AREA)
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Abstract
The present invention relates to technical field of electric wires and cables, and in particular to a kind of CABLE MATERIALS containing the stink agent of triggering property.Contain following components in CABLE MATERIALS：Vistanex, composite flame-retardant agent, the agent of triggering property stink, heat stabilizer, antioxidant, coupling agent and lubricant.Wherein, the stink agent of triggering property is to be adsorbed the stink substances such as dimethylamine, diethylamine, n-butyl mercaptan, thiophane and β cyclocitrals completely by atlapulgite, and the compound substance that last layer resin material obtains then is coated by special process on the carclazyte surface of stench type.The heat stabilizer used in raw material is organic tin heat stabilizer；Antioxidant is poly- hydroxyl pentaerythritol ester；Lubricant is PE waxes or magnesium stearate.The stink substance added in the CABLE MATERIALS has the characteristics that triggering property, stink only can be just produced when mouse baits, the term of validity of stink nearly reaches the total life cycle of CABLE MATERIALS, and mouse bite preventing performance is very superior.
Description
Technical field
The present invention relates to technical field of electric wires and cables, and in particular to a kind of CABLE MATERIALS containing the stink agent of triggering property.
Background technology
CABLE MATERIALS is a kind of insulating materials being used to prepare electric wire and cable jacket, mainly by polyvinyl chloride, polyethylene, poly- third
The high-molecular organic materials such as alkene, fluoroplastics, chlorinated polyether and polyamide form, these high molecular materials have light weight, insulation
Performance is good, resistant to chemical etching, easy processing, excellent mechanics and anti-fatigue performance the features such as.It can be used for power cable, control electricity
It is prepared by the insulating sheath of the variety classes cable such as cable, compensating cable, shielded cable, signal cable.
Conventional cable is easy to bait destruction, the cable protection of these cables by mouse and insect during embedded underground
After cover material is destroyed, it is easy to happen short circuit, causes great economic loss.In order to improve the mouse bite preventing ability of cable, people
Stink, bitter taste or spicy substance can be added in the cable, these substances can carry out physiology detest to biozones such as mouse, to reduce
The probability that cable is destroyed by mouse, the CABLE MATERIALS that patent announcement CN104109305A and CN103965542A are provided pass through
This mode improves the mouse bite preventing performance of cable.What wherein Taste and odor compounds generated is that experience, conventional CABLE MATERIALS are detested in smell
The stink substance of middle addition can directly stink substance, and this volatile malodor not only impacts mouse, also can be to dimension
Shield line work personnel cause physiology to detest experience.In addition, since the volatilization of these stink substances has certain timeliness, with
The degree of the growth of usage time, stink also can gradually weaken, and finally lose mouse bite preventing effect.
Invention content
For problems of the prior art, the present invention provides a kind of CABLE MATERIALSs containing the stink agent of triggering property, should
The stink substance added in CABLE MATERIALS passes through special processing, has the characteristics that triggering property, only can just be produced when mouse baits smelly
The term of validity of taste, stink nearly reaches the total life cycle of CABLE MATERIALS, and mouse bite preventing performance is very superior.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
It is a kind of containing triggering property stink agent CABLE MATERIALS contain following components in the CABLE MATERIALS according to mass fraction：Polyene
70-80 parts of hydrocarbon resin, 10-15 parts of composite flame-retardant agent, 6-8 parts of the stink agent of triggering property, 2-5 parts of heat stabilizer, antioxidant 1.5-2
Part, 1-3 parts of coupling agent, 1.3-1.7 parts of lubricant；
Wherein, the preparation method of triggering property stink agent includes the following steps：
(1) according to mass fraction, by 3-5 parts of dimethylamine, 15-18 parts of diethylamine, 10-13 parts of n-butyl mercaptans, 4-6 parts of tetrahydrochysenes
Thiophene and 1-2 parts of β-cyclocitrals are added in 30-40 parts of methanol and fully dissolve, and obtain required stink substance solution；
(2) by stink substance solution and atlapulgite according to 7:3 mass ratio mixing, is added in reaction kettle, heating is anti-
It answers the temperature of kettle to 40-45 DEG C, and 1-2h is sufficiently stirred with the rotating speed of 150-180r/min, then mixture is with 65-68 DEG C
The processing of temperature low temperature distillation by mixture drying and is ground to 350-500 mesh after methanol solvate volatilization completely；Needed for obtaining
Stink substance pulvis；
(3) organic resin material is dissolved in organic solvent, stink substance pulvis is then added into obtained solution,
Stink substance pulvis is stirred well to the rotating speed of 700-800r/min to be uniformly dispersed, wherein stink substance pulvis and organic tree
The mass ratio of fat material addition is 1:6-10 obtains required composite diffusion system；
(4) deionized water of 1.5-2 times of organic solvent volume is added in the composite diffusion system of step upwards, mixes to
It is uniformly dispersed, converts composite diffusion system to water phase solution；
(5) it is dried after filtering water phase solution, the solid content after drying is ground to 200-250 mesh, obtains required
The stink agent of triggering property.
Preferably, it is polycarbonate resin or poly- methyl-prop to trigger the organic resin material used in stink agent preparation process
E pioic acid methyl ester resin.
Preferably, it is tetrahydrofuran to trigger the organic solvent used in stink agent preparation process.
Preferably, according to mass fraction, contain following components in the CABLE MATERIALS：75-78 parts of vistanex, compound resistance
Fire 12-13 parts of agent, 6-7 parts of the stink agent of triggering property, 3-4 parts of heat stabilizer, 1.7-1.8 parts of antioxidant, 1-2 parts of coupling agent, lubrication
1.5-1.6 parts of agent.
Preferably, vistanex is selected from linear low density polyethylene, medium density polyethylene, high density polyethylene (HDPE), ethylene-
It is one or more in octene copolymer and ethylene-vinyl acetate copolymer.
Preferably, aluminium hydroxide, magnesium hydroxide and antimony oxide are contained in composite flame-retardant agent, the matter of three in mixture
Amount is than being 2:2:3.
Preferably, heat stabilizer is organic tin heat stabilizer；Antioxidant is poly- hydroxyl pentaerythritol ester；Coupling agent is silicon
Alkane coupling agent；Lubricant is PE waxes or magnesium stearate.
The preparation method of CABLE MATERIALS provided by the invention is：According to mass fraction, by vistanex, triggering property stink
Agent, heat stabilizer, coupling agent, antioxidant and lubricant are added in mixer, are mixed with 100-125 DEG C of temperature mixing, so
Composite flame-retardant agent is added to continuation batch mixing 5-8min in mixer afterwards, then puts into mixture in double screw extruder altogether
Mixed extrusion, cooling granulation, obtain required CABLE MATERIALS.
The present invention has following advantageous effect：
A kind of stink agent of triggering property is added in the type CABLE MATERIALS, this stink agent will have strong by atlapulgite
A variety of chemical substances of stink are effectively adsorbed, and then coat the stench type carclazyte after absorption completely by resin material, to
The stink substance avoided arbitrarily volatilizees, and after this triggering property stink substance is added in CABLE MATERIALS, mouse baits CABLE MATERIALS
It is that the resin packet particle damage for coating foul smelling type carclazyte can quickly be volatilized so as to cause internal stink substance so that old
Mouse moment generates smell and detests, and to avoid mouse from further destroying cable, achievees the purpose that mouse bite preventing.Due to making in the cable
Stink agent is coated by resin, as long as mouse does not destroy cable, the cable would not spontaneous generation stink,
Therefore it will not cause physiological effect, resin clad that can also be carried out to internal stink substance to cable maintenance or service personnel
Protection, improves the term of validity of stink substance.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
It is a kind of containing triggering property stink agent CABLE MATERIALS contain following components in the CABLE MATERIALS according to mass fraction：Polyene
70 parts of hydrocarbon resin, 10 parts of composite flame-retardant agent, 6 parts of triggering property stink agent, 2 parts of heat stabilizer, 1.5 parts of antioxidant, 1 part of coupling agent,
1.3 parts of lubricant；
Wherein, the preparation method of triggering property stink agent includes the following steps：
(1) according to mass fraction, by 3 parts of dimethylamine, 15 parts of diethylamine, 10 parts of n-butyl mercaptans, 4 parts of thiophanes and 1 part
β-cyclocitral, which is added in 30 parts of methanol, fully to be dissolved, and required stink substance solution is obtained；
(2) by stink substance solution and atlapulgite according to 7:3 mass ratio mixing, is added in reaction kettle, heating is anti-
The temperature of kettle is answered to be sufficiently stirred 1h to 40 DEG C, and with the rotating speed of 150r/min, then mixture is with 65 DEG C of temperature low temperature distillation
Processing by mixture drying and is ground to 350 mesh after methanol solvate volatilization completely；Obtain required stink substance pulvis；
(3) organic resin material is dissolved in organic solvent, stink substance pulvis is then added into obtained solution,
Stink substance pulvis is stirred well to the rotating speed of 700r/min to be uniformly dispersed, wherein stink substance pulvis and organic resin material
The mass ratio of material addition is 1:6, obtain required composite diffusion system；Organic resin material is polycarbonate resin or polymethyl
Sour late resin；Organic solvent is tetrahydrofuran.
(4) deionized water of 1.5 times of organic solvent volumes is added in the composite diffusion system of step upwards, mixes to point
It dissipates uniformly, converts composite diffusion system to water phase solution；
(5) it is dried after filtering water phase solution, the solid content after drying is ground to 200 mesh, obtains required triggering
Property stink agent.
Wherein, the vistanex used in raw material is linear density polyethylene.Contain hydroxide in composite flame-retardant agent
Aluminium, magnesium hydroxide and antimony oxide, the mass ratio of three is 2 in mixture:2:3.Heat stabilizer is organic tin thermostabilization
Agent；Antioxidant is poly- hydroxyl pentaerythritol ester；Coupling agent is silane coupling agent；Lubricant is PE waxes.
The preparation method of CABLE MATERIALS provided in this embodiment is：According to mass fraction, by vistanex, triggering property stink
Agent, heat stabilizer, coupling agent, antioxidant and lubricant are added in mixer, are mixed with 100 DEG C of temperature mixing, then will
Composite flame-retardant agent is added to continuation batch mixing 5min in mixer, then puts into be blended in double screw extruder by mixture and squeeze
Go out, cooling granulation, obtains required CABLE MATERIALS.
Embodiment 2
It is a kind of containing triggering property stink agent CABLE MATERIALS contain following components in the CABLE MATERIALS according to mass fraction：Polyene
80 parts of hydrocarbon resin, 15 parts of composite flame-retardant agent, 8 parts of triggering property stink agent, 5 parts of heat stabilizer, 2 parts of antioxidant, 3 parts of coupling agent, profit
1.7 parts of lubrication prescription；
Wherein, the preparation method of triggering property stink agent includes the following steps：
(1) according to mass fraction, by 5 parts of dimethylamine, 18 parts of diethylamine, 13 parts of n-butyl mercaptans, 6 parts of thiophanes and 2 parts
β-cyclocitral, which is added in 40 parts of methanol, fully to be dissolved, and required stink substance solution is obtained；
(2) by stink substance solution and atlapulgite according to 7:3 mass ratio mixing, is added in reaction kettle, heating is anti-
The temperature of kettle is answered to be sufficiently stirred 2h to 45 DEG C, and with the rotating speed of 180r/min, then mixture is with 68 DEG C of temperature low temperature distillation
Processing by mixture drying and is ground to 500 mesh after methanol solvate volatilization completely；Obtain required stink substance pulvis；
(3) organic resin material is dissolved in organic solvent, stink substance pulvis is then added into obtained solution,
Stink substance pulvis is stirred well to the rotating speed of 800r/min to be uniformly dispersed, wherein stink substance pulvis and organic resin material
The mass ratio of material addition is 1:10, obtain required composite diffusion system；Organic resin material is plexiglass；Have
Solvent is tetrahydrofuran.
(4) deionized water of 2 times of organic solvent volumes is added in the composite diffusion system of step upwards, mixes to dispersion
Uniformly, composite diffusion system is converted to water phase solution；
(5) it is dried after filtering water phase solution, the solid content after drying is ground to 250 mesh, obtains required triggering
Property stink agent.
Wherein, the vistanex used in raw material includes that linear low density polyethylene, medium density polyethylene and ethylene-are pungent
The mixture of alkene copolymer.Contain aluminium hydroxide, magnesium hydroxide and antimony oxide in composite flame-retardant agent, three in mixture
Mass ratio is 2:2:3.Heat stabilizer is organic tin heat stabilizer；Antioxidant is poly- hydroxyl pentaerythritol ester；Coupling agent is silicon
Alkane coupling agent；Lubricant is magnesium stearate.
The preparation method of CABLE MATERIALS provided in this embodiment is：According to mass fraction, by vistanex, triggering property stink
Agent, heat stabilizer, coupling agent, antioxidant and lubricant are added in mixer, are mixed with 125 DEG C of temperature mixing, then will
Composite flame-retardant agent is added to continuation batch mixing 8min in mixer, then puts into be blended in double screw extruder by mixture and squeeze
Go out, cooling granulation, obtains required CABLE MATERIALS.
Embodiment 3
It is a kind of containing triggering property stink agent CABLE MATERIALS contain following components in the CABLE MATERIALS according to mass fraction：Polyene
75 parts of hydrocarbon resin, 13 parts of composite flame-retardant agent, 7 parts of triggering property stink agent, 4 parts of heat stabilizer, 1.8 parts of antioxidant, 2 parts of coupling agent,
1.5 parts of lubricant；
Wherein, the preparation method of triggering property stink agent includes the following steps：
(1) according to mass fraction, by 4 parts of dimethylamine, 17 parts of diethylamine, 12 parts of n-butyl mercaptans, 5 parts of thiophanes and 1.5
Part β-cyclocitral, which is added in 35 parts of methanol, fully to be dissolved, and required stink substance solution is obtained；
(2) by stink substance solution and atlapulgite according to 7:3 mass ratio mixing, is added in reaction kettle, heating is anti-
The temperature of kettle is answered to be sufficiently stirred 1.5h to 43 DEG C, and with the rotating speed of 170r/min, then mixture is steamed with 67 DEG C of temperature low temperature
Processing is evaporated, after methanol solvate volatilization completely, by mixture drying and is ground to 400 mesh；Obtain required stink substance pulvis；
(3) organic resin material is dissolved in organic solvent, stink substance pulvis is then added into obtained solution,
Stink substance pulvis is stirred well to the rotating speed of 750r/min to be uniformly dispersed, wherein stink substance pulvis and organic resin material
The mass ratio of material addition is 1:8, obtain required composite diffusion system；Organic resin material is plexiglass；Have
Solvent is tetrahydrofuran.
(4) deionized water of 1.8 times of organic solvent volumes is added in the composite diffusion system of step upwards, mixes to point
It dissipates uniformly, converts composite diffusion system to water phase solution；
(5) it is dried after filtering water phase solution, the solid content after drying is ground to 230 mesh, obtains required triggering
Property stink agent.
Wherein, the vistanex used in raw material is selected from linear low density polyethylene, ethylene-octene copolymer and second
The mixture of alkene-vinyl acetate.Contain aluminium hydroxide, magnesium hydroxide and antimony oxide in composite flame-retardant agent, three in mixture
The mass ratio of person is 2:2:3.Heat stabilizer is organic tin heat stabilizer；Antioxidant is poly- hydroxyl pentaerythritol ester；Coupling agent
For silane coupling agent；Lubricant is PE waxes.
The preparation method of CABLE MATERIALS provided in this embodiment is：According to mass fraction, by vistanex, triggering property stink
Agent, heat stabilizer, coupling agent, antioxidant and lubricant are added in mixer, are mixed with 110 DEG C of temperature mixing, then will
Composite flame-retardant agent is added to continuation batch mixing 7min in mixer, then puts into be blended in double screw extruder by mixture and squeeze
Go out, cooling granulation, obtains required CABLE MATERIALS.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (8)
1. a kind of CABLE MATERIALS containing the stink agent of triggering property, it is characterised in that：According to mass fraction, in the CABLE MATERIALS containing with
Lower component：70-80 parts of vistanex, 10-15 parts of composite flame-retardant agent, 6-8 parts of the stink agent of triggering property, 2-5 parts of heat stabilizer resist
1.5-2 parts of oxygen agent, 1-3 parts of coupling agent, 1.3-1.7 parts of lubricant；
Wherein, the preparation method of the triggering property stink agent includes the following steps：
（1）According to mass fraction, by 3-5 parts of dimethylamine, 15-18 parts of diethylamine, 10-13 parts of n-butyl mercaptans, 4-6 parts of thiophanes
It is added in 30-40 parts of methanol with 1-2 parts of β-cyclocitrals and fully dissolves, obtain required stink substance solution；
（2）By stink substance solution and atlapulgite according to 7:3 mass ratio mixing, is added in reaction kettle, heats reaction kettle
Temperature be sufficiently stirred 1-2h to 40-45 DEG C, and with the rotating speed of 150-180r/min, then mixture is with 65-68 DEG C of temperature
Low temperature distillation processing by mixture drying and is ground to 350-500 mesh after methanol solvate volatilization completely；Obtain required stink
Substance pulvis；
（3）Organic resin material is dissolved in organic solvent, stink substance pulvis is then added into obtained solution, with
The rotating speed of 700-800r/min is stirred well to stink substance pulvis and is uniformly dispersed, wherein stink substance pulvis and organic resin
The mass ratio of material addition is 1:6-10 obtains required composite diffusion system；
（4）The deionized water of 1.5-2 times of organic solvent volume is added in the composite diffusion system of upward step, mixes to dispersion
Uniformly, composite diffusion system is converted to water phase solution；
（5）It is dried after water phase solution is filtered, the solid content after drying is ground to 200-250 mesh, obtains required triggering
Property stink agent.
2. a kind of CABLE MATERIALS containing the stink agent of triggering property according to claim 1, it is characterised in that：The triggering stink
The organic resin material used in agent preparation process is polycarbonate resin or plexiglass.
3. a kind of CABLE MATERIALS containing the stink agent of triggering property according to claim 1, it is characterised in that：The triggering stink
The organic solvent used in agent preparation process is tetrahydrofuran.
4. a kind of CABLE MATERIALS containing the stink agent of triggering property according to claim 1, it is characterised in that：According to mass parts
It counts, contains following components in the CABLE MATERIALS：75-78 parts of vistanex, 12-13 parts of composite flame-retardant agent, the stink agent of triggering property
6-7 parts, 3-4 parts of heat stabilizer, 1.7-1.8 parts of antioxidant, 1-2 parts of coupling agent, 1.5-1.6 parts of lubricant.
5. a kind of CABLE MATERIALS containing the stink agent of triggering property according to claim 4, it is characterised in that：The polyolefin tree
Fat is selected from linear low density polyethylene, medium density polyethylene, high density polyethylene (HDPE), ethylene-octene copolymer and ethyl vinyl acetate second
It is one or more in alkene copolymer.
6. a kind of CABLE MATERIALS containing the stink agent of triggering property according to claim 4, it is characterised in that：The composite flame-proof
Contain aluminium hydroxide, magnesium hydroxide and antimony oxide in agent, the mass ratio of three is 2 in mixture:2:3.
7. a kind of CABLE MATERIALS containing the stink agent of triggering property according to claim 4, it is characterised in that：Heat stabilizer is to have
Machine tin type thermal stabilizing agent；Antioxidant is poly- hydroxyl pentaerythritol ester；Coupling agent is silane coupling agent；Lubricant is PE waxes or tristearin
Sour magnesium.
8. a kind of CABLE MATERIALS containing the stink agent of triggering property according to claim 1, which is characterized in that the CABLE MATERIALS
Preparation method is：According to mass fraction, by vistanex, the agent of triggering property stink, heat stabilizer, coupling agent, antioxidant and profit
Lubrication prescription is added in mixer, is mixed with 100-125 DEG C of temperature mixing, and composite flame-retardant agent is then added to mixer relaying
Continuous batch mixing 5-8min, then puts into blending extrusion in double screw extruder, cooling granulation by mixture, obtains required cable
Material.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115287039A (en) * | 2022-01-28 | 2022-11-04 | 延边群益科技发展有限责任公司 | Odor agent and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101327653A (en) * | 2007-06-22 | 2008-12-24 | 日精树脂工业株式会社 | Method for manufacturing resin-coated carbon nanomaterial and method for manufacturing carbon nanocomposite resin molded article |
| CN101407092A (en) * | 2007-08-01 | 2009-04-15 | 日精树脂工业株式会社 | Method for manufacturing resin-coated carbon nanomaterial, resin material containing nano-carbon and carbon nano compound resin moldings |
| CN106979725A (en) * | 2017-03-20 | 2017-07-25 | 西安科技大学 | The preparation method of the agent of composite fluid stink, the agent of solid stink and solid stink agent |
| CN107090142A (en) * | 2017-05-10 | 2017-08-25 | 天长市通联焊业有限公司 | A kind of protection against rodents bird repellent aerial optical cable CABLE MATERIALS and preparation method thereof |
| CN107936418A (en) * | 2017-12-27 | 2018-04-20 | 成都新柯力化工科技有限公司 | A kind of long-acting type gopher protected cable material and preparation method |
-
2018
- 2018-05-11 CN CN201810447476.8A patent/CN108586907A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101327653A (en) * | 2007-06-22 | 2008-12-24 | 日精树脂工业株式会社 | Method for manufacturing resin-coated carbon nanomaterial and method for manufacturing carbon nanocomposite resin molded article |
| CN101407092A (en) * | 2007-08-01 | 2009-04-15 | 日精树脂工业株式会社 | Method for manufacturing resin-coated carbon nanomaterial, resin material containing nano-carbon and carbon nano compound resin moldings |
| CN106979725A (en) * | 2017-03-20 | 2017-07-25 | 西安科技大学 | The preparation method of the agent of composite fluid stink, the agent of solid stink and solid stink agent |
| CN107090142A (en) * | 2017-05-10 | 2017-08-25 | 天长市通联焊业有限公司 | A kind of protection against rodents bird repellent aerial optical cable CABLE MATERIALS and preparation method thereof |
| CN107936418A (en) * | 2017-12-27 | 2018-04-20 | 成都新柯力化工科技有限公司 | A kind of long-acting type gopher protected cable material and preparation method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115287039A (en) * | 2022-01-28 | 2022-11-04 | 延边群益科技发展有限责任公司 | Odor agent and preparation method and application thereof |
| CN115287039B (en) * | 2022-01-28 | 2024-04-05 | 延边群益科技发展有限责任公司 | Odor agent and preparation method and application thereof |
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