CN108101191A - Floating stuffing built in a kind of biofilm reactor - Google Patents

Floating stuffing built in a kind of biofilm reactor Download PDF

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Publication number
CN108101191A
CN108101191A CN201711378331.9A CN201711378331A CN108101191A CN 108101191 A CN108101191 A CN 108101191A CN 201711378331 A CN201711378331 A CN 201711378331A CN 108101191 A CN108101191 A CN 108101191A
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CN
China
Prior art keywords
filler
built
blade
biofilm reactor
hdpe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711378331.9A
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Chinese (zh)
Inventor
李培根
谢孟伟
张灿伟
董坤
陈彤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANDONG LUKANG ZHONGHE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Original Assignee
SHANDONG LUKANG ZHONGHE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Application filed by SHANDONG LUKANG ZHONGHE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd filed Critical SHANDONG LUKANG ZHONGHE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Priority to CN201711378331.9A priority Critical patent/CN108101191A/en
Publication of CN108101191A publication Critical patent/CN108101191A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

The invention discloses floating stuffings built in a kind of biofilm reactor.Filler uses high density polyethylene (HDPE) (HDPE) material, material surface is embedded with Powdered Activated Carbon, iron powder, starch, potassium dihydrogen phosphate, ammonium carbonate, the solid granule of manganese iron axinite powder composition, so that microorganism can quickly adhere to simultaneously growth and breeding on these nutrition points.Solve biofilm reactor difficulty biofilm, the caducous problem of biomembrane.This filler has large specific surface area, and good hydrophilic property, bioactivity is high, hangs the characteristics of mould is fast, and high treating effect, impact resistance is good, and service life is long.

Description

Floating stuffing built in a kind of biofilm reactor
Technical field
The present invention relates to biofilm reactor packing technique field, more particularly to suspension built in a kind of biofilm reactor Filler.
Background technology
Biofilm is born at the end of the 19th century, due to the characteristics of its biomass is high, and operating cost is low, is applied at sewage In the practical application of reason, but since filler dehydration is easily hardened, the characteristics of biomembrane is easy to fall off, biofilm is difficult, reality With being somewhat limited.Therefore, it is necessary to a kind of new fillers to solve biofilm reactor difficulty biofilm, biomembrane Caducous problem.
The content of the invention
The present invention provides floating stuffing built in a kind of biofilm reactor aiming at above-mentioned defect.This filler With large specific surface area, good hydrophilic property, bioactivity is high, and extension mould is fast, and high treating effect, impact resistance is good, and service life is long The characteristics of.
Floating stuffing technical solution built in a kind of biofilm reactor of the present invention is that filler uses high density polyethylene (HDPE) (HDPE) material, material surface are embedded with Powdered Activated Carbon, iron powder, starch, potassium dihydrogen phosphate, ammonium carbonate, manganese iron axinite powder The solid granule of composition, so that microorganism can quickly adhere to simultaneously growth and breeding on these nutrition points.
The iron and manganese oxides of the present invention are purchased from Shanghai Venus chemical engineering industry Co., Ltd.
0.95 ± 0.2g/cm of packing density3, it is ensured that it is at suspended state in water.
Floating stuffing built in a kind of biofilm reactor includes the following component of percentage by weight:
The filler includes the blade that multilayer is in tower-like arrangement, and every layer of blade is 2-10 pieces, and the bottom of every layer of blade is in The heart is gathered, and vane tip radially distributes obliquely, and adjacent two layers blade is in be spaced apart.Filler maximum gauge is 45mm, Width of blade is that the distance between 4-7mm, levels blade is 2-5mm, and every blade back has one directly by bottom to top Footpath is the vertical bars of 0.5mm.
High temperature using 180 DEG C -230 DEG C melts high density polyethylene (HDPE), by active carbon powder, iron powder, starch, carbonic acid Ammonium, potassium dihydrogen phosphate, iron and manganese oxides powder are added in the high density polyethylene (HDPE) of molten state, are then fixed filler by being molded Shaping.
Filler is placed in the sewage treatment structure containing activated sludge, the microorganism in water quickly lives with filler surface Property basic point is combined, and is firmly attached to filler surface, and fast-growth breeds to form biomembrane.The filler of biomembrane is attached with, It in the case of aeration or stirring, rotates freely, fills the matrix such as the organic matter in microorganism and water in biomembrane, ammonia nitrogen Tap is touched, and is adsorbed and is carried out metabolic breakdown.In addition, filler has a substantial amounts of cavity, microorganism growth and breeding inside it can be with Strong current or air stream shear forces is avoided to wash away biomembrane.Filler has certain shearing for the air-flow in aeration tank Effect improves the utilization rate of oxygen to a certain extent.And it can realize hydraulic detention time and sludge retention time Separation ensures the quantity of active mud content in structures, so as to fulfill the efficient removal of pollutant.
Beneficial effects of the present invention are:The purpose that active carbon powder is added in filler is exactly to strengthen filler to microorganism and water The suction-operated of nutriment and oxygen in body, in order to which microorganism can quickly realize biofilm;The purpose for adding in iron powder is one Aspect regulates and controls the proportion of filler, contains iron and carbon component in another aspect iron powder, can be formed in waste water numerous small Primary battery, organic matter is under the action of electric field, further Quick Oxidation reduction, so as to increase the biodegradability of waste water;It adds in and forms sediment The purpose of powder, ammonium carbonate and potassium dihydrogen phosphate is that microbial growth provides nutritional ingredient, makes microbial film not easily to fall off, this Also there is to adjust carbon, nitrogen in water outside, phosphorus ratio is unbalance;It is for microbial cell external respiration to add in iron and manganese oxides powder Metabolism provides electron acceptor, enhancement microbiological metabolism.The appearance and internal structure design of this filler uniqueness can be adjusted with facilitating Sluicing of the whole current to filler surface microorganism film, microorganism that on the other hand can also be on filler have huge with sewage Contact area.
This filler has large specific surface area, and good hydrophilic property, bioactivity is high, and extension mould is fast, high treating effect, impact resistance It is good, the characteristics of service life is long.
Description of the drawings:
Fig. 1 show the filling-material structure schematic diagram of the present invention;
Fig. 2 show the injection pictorial diagram of filler of the present invention;
Wherein, 1- blades, 2- vertical bars.
Specific embodiment:
For a better understanding of the present invention, below with specific example come the technical solution that the present invention will be described in detail, but this Invention is not limited thereto.
Embodiment 1-3:A kind of floating stuffing for microorganism rapid biofilm, component is as shown in table 1 (used in the present invention Iron and manganese oxides be purchased from Shanghai Venus chemical engineering industry Co., Ltd):
Table 1
High temperature using 180 DEG C -230 DEG C melts high density polyethylene (HDPE), is matched according to above by active carbon powder, iron Powder, starch, ammonium carbonate, potassium dihydrogen phosphate, iron and manganese oxides powder are added in the high density polyethylene (HDPE) of molten state, then pass through note Modeling is fixed-type by filler.
The filler includes the blade 1 that multilayer is in tower-like arrangement, and every layer of blade 1 is 2-10 pieces, the bottom of every layer of blade 1 to Center is gathered, and 1 top of blade radially distributes obliquely, and adjacent two layers blade 1 is in be spaced apart.Filler maximum gauge is 45mm, 1 width of blade are that the distance between 4-7mm, levels blade is 2-5mm, and every 11 back of blade is by bottom to top There are the vertical bars 2 of an a diameter of 0.5mm.
Embodiment 1
Using identical preparation process, difference exists:Active carbon powder is added without in filler, obtained filler A is close It spends for 0.95g/cm3
Embodiment 2
Using identical preparation process, the difference is that:Starch is added without in filler, obtained filler B, density is 0.97g/cm3
Embodiment 3
Using identical preparation process, the difference is that:Starch, ammonium carbonate and potassium dihydrogen phosphate are added without in filler, Its density is 0.96g/cm3
Three of the above filler is separately added into the beaker that 500ml fills clear water, after impregnating 10min, is surveyed using contact angle Determine instrument to be measured, the contact angle of tri- kinds of fillers of A, B, C is respectively 65 °, 73 °, 84 °.The result shows that microbe carrier of the present invention The clear water of filler is improved significantly.
The filler of identical quantity is taken, is marked using the cotton rope of different colours (red A, Huang B, green C), it is anti-to be placed in same biology It answers in device, pH is in the range of 7.5-9.0, and temperature control is at 25-30 DEG C, BOD5/COD=0.3 or so, DO=1-2mg/l, COD For 300mg/l, ammonia nitrogen 100mg/l, HRT=8h.The results are shown in Table 2:The biofilm time of such new packing is significantly lower than General filler, COD and ammonia nitrogen removal frank are obviously improved.
Table 2

Claims (6)

1. a kind of floating stuffing built in biofilm reactor, which is characterized in that filler uses high density polyethylene (HDPE) (HDPE) material, Material surface is embedded in manganese iron axinite powder and Powdered Activated Carbon, iron powder, starch, potassium dihydrogen phosphate, ammonium carbonate at least A kind of solid granule of composition, so that microorganism can quickly adhere to simultaneously growth and breeding on these nutrition points.
2. floating stuffing built in a kind of biofilm reactor according to claim 1, which is characterized in that packing density 0.95 ±0.2g/cm3
3. floating stuffing built in a kind of biofilm reactor according to claim 1, which is characterized in that including by weight hundred The following component divided:
High density polyethylene (HDPE) 70-85%
Powdered active carbon 10-20%
Iron powder 5-10%
Starch 2-5%
Ammonium carbonate 0.5-1%
Potassium dihydrogen phosphate 0.2-0.5%
Manganese iron axinite powder 0.1-0.3%.
4. floating stuffing built in a kind of biofilm reactor according to claim 1, which is characterized in that the filler includes Multilayer is in the blade of tower-like arrangement, and every layer of blade is 2-10 pieces, and the bottom of every layer of blade is gathered to center, and vane tip is obliquely It radially distributes, adjacent two layers blade is in be spaced apart.
5. floating stuffing built in a kind of biofilm reactor according to claim 1, which is characterized in that filler maximum gauge It is 2-5mm for the distance between 45mm, width of blade 4-7mm, levels blade, every blade back is had by bottom to top The vertical bars of one a diameter of 0.5mm.
6. floating stuffing built in a kind of biofilm reactor according to claim 1, which is characterized in that using 180 DEG C- 230 DEG C of high temperature melts high density polyethylene (HDPE), by active carbon powder, iron powder, starch, ammonium carbonate, potassium dihydrogen phosphate, ferrimanganic oxygen Compound powder is added in the high density polyethylene (HDPE) of molten state, then by being molded that filler is fixed-type.
CN201711378331.9A 2017-12-19 2017-12-19 Floating stuffing built in a kind of biofilm reactor Pending CN108101191A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711378331.9A CN108101191A (en) 2017-12-19 2017-12-19 Floating stuffing built in a kind of biofilm reactor

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Application Number Priority Date Filing Date Title
CN201711378331.9A CN108101191A (en) 2017-12-19 2017-12-19 Floating stuffing built in a kind of biofilm reactor

Publications (1)

Publication Number Publication Date
CN108101191A true CN108101191A (en) 2018-06-01

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108946933A (en) * 2018-08-03 2018-12-07 南京高新工大生物技术研究院有限公司 A kind of modified poly ethylene microbe carrier stuffing
CN110591205A (en) * 2019-09-29 2019-12-20 北交源生态环境科技(北京)有限公司 Composite polymer material with oxygen enrichment function
CN110980934A (en) * 2019-12-19 2020-04-10 内蒙古圣清科技有限公司 Suspended filler and preparation method thereof
CN114671515A (en) * 2022-04-26 2022-06-28 国网河北省电力有限公司电力科学研究院 Aerobic pool floating filler and preparation method and application thereof
CN114772870A (en) * 2022-05-24 2022-07-22 湖南五方环境科技研究院有限公司 Sewage treatment device and method for continuous flow sludge particles with controllable particle sizes
CN114835255A (en) * 2022-05-24 2022-08-02 湖南五方环境科技研究院有限公司 Composite bioreactor based on iron-carbon carrier and preparation and sewage treatment method thereof

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WO2002072486A1 (en) * 2001-03-09 2002-09-19 Council Of Scientific And Industrial Research Process and reverse fluidised loop reactor for wastewater purification
CN1569684A (en) * 2004-05-13 2005-01-26 上海大学 Process for preparing bio-catalytic combined filling for biological fluidized bed
CN100999361A (en) * 2007-01-05 2007-07-18 华南理工大学 Nutrition slow-release type biofiller for water treatment and its preparation method
CN102491495A (en) * 2011-11-28 2012-06-13 邱树兴 Novel biofilm carrier and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002072486A1 (en) * 2001-03-09 2002-09-19 Council Of Scientific And Industrial Research Process and reverse fluidised loop reactor for wastewater purification
CN1569684A (en) * 2004-05-13 2005-01-26 上海大学 Process for preparing bio-catalytic combined filling for biological fluidized bed
CN100999361A (en) * 2007-01-05 2007-07-18 华南理工大学 Nutrition slow-release type biofiller for water treatment and its preparation method
CN102491495A (en) * 2011-11-28 2012-06-13 邱树兴 Novel biofilm carrier and preparation method thereof

Non-Patent Citations (1)

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Title
李家洲: "《生物制药工艺学》", 31 August 2007, 中国轻工业出版社 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108946933A (en) * 2018-08-03 2018-12-07 南京高新工大生物技术研究院有限公司 A kind of modified poly ethylene microbe carrier stuffing
CN110591205A (en) * 2019-09-29 2019-12-20 北交源生态环境科技(北京)有限公司 Composite polymer material with oxygen enrichment function
CN110980934A (en) * 2019-12-19 2020-04-10 内蒙古圣清科技有限公司 Suspended filler and preparation method thereof
CN114671515A (en) * 2022-04-26 2022-06-28 国网河北省电力有限公司电力科学研究院 Aerobic pool floating filler and preparation method and application thereof
CN114671515B (en) * 2022-04-26 2023-09-26 国网河北省电力有限公司电力科学研究院 Floating filler for aerobic tank and preparation method and application thereof
CN114772870A (en) * 2022-05-24 2022-07-22 湖南五方环境科技研究院有限公司 Sewage treatment device and method for continuous flow sludge particles with controllable particle sizes
CN114835255A (en) * 2022-05-24 2022-08-02 湖南五方环境科技研究院有限公司 Composite bioreactor based on iron-carbon carrier and preparation and sewage treatment method thereof
CN114772870B (en) * 2022-05-24 2023-10-31 湖南五方环境科技研究院有限公司 Sewage treatment device and method for continuous flow particle size controllable sludge particles

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Application publication date: 20180601

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