CN108023106A - Bipolar plate of vanadium cell and preparation method thereof - Google Patents
Bipolar plate of vanadium cell and preparation method thereof Download PDFInfo
- Publication number
- CN108023106A CN108023106A CN201610958797.5A CN201610958797A CN108023106A CN 108023106 A CN108023106 A CN 108023106A CN 201610958797 A CN201610958797 A CN 201610958797A CN 108023106 A CN108023106 A CN 108023106A
- Authority
- CN
- China
- Prior art keywords
- vanadium cell
- bipolar plate
- powder
- resin
- cell described
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052720 vanadium Inorganic materials 0.000 title claims abstract description 44
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 44
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000007921 spray Substances 0.000 claims abstract description 15
- 239000007769 metal material Substances 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 9
- 238000007751 thermal spraying Methods 0.000 claims abstract description 4
- 238000007731 hot pressing Methods 0.000 claims description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- -1 polypropylene Polymers 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 239000010959 steel Substances 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 239000011342 resin composition Substances 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920005992 thermoplastic resin Polymers 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- 210000000988 bone and bone Anatomy 0.000 claims 1
- 229920001568 phenolic resin Polymers 0.000 claims 1
- 239000005011 phenolic resin Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000007789 sealing Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 11
- 239000011247 coating layer Substances 0.000 description 7
- 238000007599 discharging Methods 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 229910002114 biscuit porcelain Inorganic materials 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 230000001172 regenerating effect Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 230000023402 cell communication Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0223—Composites
- H01M8/0228—Composites in the form of layered or coated products
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Fuel Cell (AREA)
Abstract
The present invention relates to vanadium cell manufacturing field, is specially a kind of bipolar plate of vanadium cell and preparation method thereof.Metal material is used as framework material, selects the mode of thermal spraying, sprays one layer of mixture being made of conducting powder and resin respectively in metal material both sides first, sprays one layer of conductive powder body after curing respectively in both sides, then on hot press it is hot-forming.The problems such as present invention solves in the prior art that its mechanical strength of bipolar plates is low, poorly conductive, in vertical direction poorly conductive, and the contact resistance between battery component is larger.Compared with prior art, the bipolar plate of vanadium cell that prepared by the present invention, as framework material, substantially increases the mechanical strength of bipolar plates, under the effect of a variety of sealing means, performance is stablized, and substantially increases the service life of bipolar plates using metal material.
Description
Technical field
The present invention relates to vanadium cell manufacturing field, is specially a kind of bipolar plate of vanadium cell and preparation method thereof.
Background technology
With the profit of the regenerative resources such as the increasingly exhausted and corresponding environmental problem of traditional energy, wind energy, solar energy
With causing people widely to pay close attention to and be rapidly developed, while in order to ensure the stable power-supplying of regenerative resource, overcome it solid
Problematic, more and more electric power storage energy storage technologies are developed and used, wherein vanadium cell as extensive energy storage technology one
Kind solution, also obtains remarkable progress in recent years.Wherein, bipolar plates be used to separate each monocell, while in circuit
On by two adjacent sections cell communication, it is desirable to bipolar plates must have high conductivity and the stability in strong acid medium, together
When can be attached between electrode material with relatively low contact resistance.Bipolar plates are moulded using carbon mostly in the prior art, its
Mechanical strength is low, poorly conductive, and the contact resistance between battery component is larger, it is necessary to reduces the resistance of bipolar plates, improves
The voltage efficiency of battery, so as to lift battery performance, as above problems demand solves.
The content of the invention
For overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of bipolar plate of vanadium cell and its preparation
Method, solves in the prior art that its mechanical strength of bipolar plates is low, poorly conductive, in vertical direction poorly conductive, and with electricity
The problems such as contact resistance of pond inter-module is larger.
To reach above-mentioned purpose, the technical scheme is that：
A kind of bipolar plate of vanadium cell, uses metal material the mode of thermal spraying to be selected, first in metal for framework material
One layer of mixture being made of conducting powder and resin is sprayed in material both sides respectively, sprays one layer of conductive powder body after curing respectively in both sides,
It is hot-forming on hot press again.
The bipolar plate of vanadium cell, spraying use the external air pump of spray gun, and powder is loaded in spray gun, passes through air pressure
Mode spraying powder.
The bipolar plate of vanadium cell, metal material are metallic plate or metal mesh, and thickness is in 0.5mm~30mm, material
Matter is copper, steel, iron, titanium or silver.
In the mixture of the bipolar plate of vanadium cell, conducting powder and resin composition, the mass ratio of conducting powder and resin
For (1：1)~(1：10).
The bipolar plate of vanadium cell, conducting powder are one kind in carbon black, graphite and carbon fiber powder；Resin is thermoplasticity
Resin or thermosetting resin, thermoplastic resin is polypropylene, one kind in polyethylene, polyvinyl chloride, and thermosetting resin is phenolic aldehyde
One kind in resin, epoxy resin.
The bipolar plate of vanadium cell, the particle diameter of powder particle is 0.01mm~3mm, preferably 0.01mm~0.1mm.
The bipolar plate of vanadium cell, positioned at outermost conductive powder body thickness in 0.02mm~0.10mm, conducting powder
Mixture thickness with resin composition is in 0.5mm~30mm.
The bipolar plate of vanadium cell, the thickness of bipolar plate of vanadium cell is in 1.0mm~40mm.
The preparation method of the bipolar plate of vanadium cell, comprises the following steps that：
1) metallic plate or metal mesh are placed in incubator, temperature control is at 150~300 DEG C；
2) conducting powder and resin powder mixture are loaded in spray gun and metallic plate or metal mesh both sides work is got to by air pressure
For casing play；
3) after casing play curing, one layer of conductive powder body is sprayed respectively in its both sides；
4) put it into it is hot-forming on hot press be made bipolar plate of vanadium cell, hot pressing temperature is 100~300 DEG C, heat
The pressure time is 5~200min, and hot pressing pressure is 1~25MPa.
Advantages of the present invention and beneficial effect are：
1st, compared with prior art, the bipolar plate of vanadium cell for preparing of the present invention using metal material as framework material,
The mechanical strength of bipolar plates is substantially increased, under the effect of a variety of sealing means, performance is stablized, and substantially increases making for bipolar plates
Use the service life.
2nd, bipolar plate of vanadium cell prepared by the present invention is using the processing method of thermal spraying and hot pressing, and technique is simple, equipment
Cost is low.
3rd, the bipolar plate of vanadium cell framework material for preparing of the present invention is metal, by the use of conducting powder and resin as bonding agent,
Superficies are pure conductive powder bodies, and due to the isotropism of metal material, overall electrical resistance is very small, substantially reduces bipolar
Contact resistance between plate and battery component, improves the voltage efficiency of battery, and voltage efficiency can improve 3~5%.
Brief description of the drawings
Fig. 1 is the structure diagram of bipolar plate of vanadium cell.Wherein, 1 metallic plate or metal mesh；2 conducting powders and resin
Mixture layer；3 conductive bisques.
Embodiment
The embodiment of the present invention is further described below in conjunction with the accompanying drawings.
As shown in Figure 1, bipolar plate of vanadium cell of the present invention includes metallic plate or metal mesh 1, conducting powder and resin mixing
Nitride layer 2, conductive bisque 3, metallic plate or 1 both sides of metal mesh be followed successively by respectively conductive layer 2, conducting powder and resin mixture layer 2,
Conductive bisque 3.
Embodiment 1
2mm steel plates are placed in incubator, temperature control is at 200 DEG C, by the graphite powder and grain that particle diameter is 0.02mm
The polypropylene powder that footpath is 0.04mm presses 1：1 mass ratio, which is uniformly mixed, to be loaded in spray gun, and mixture is sprayed on steel plate both sides table
On face, coating layer thickness 0.5mm, then particle diameter is sprayed in mixture layer both side surface for 0.02mm graphite powders, coating layer thickness is
0.05mm, then put it into mould and bipolar plate of vanadium cell is made after hot pressing on hot press, hot pressing temperature is 170 DEG C, heat
The pressure time is 50min, hot pressing pressure 18MPa.
Bipolar plates manufactured in the present embodiment assemble 2KW vanadium cells, and battery charging and discharging performance parameter is：Coulombic efficiency
95.5%, voltage efficiency 86.5%, energy efficiency 82.6%, compared with existing carbon moulds bipolar plates, voltage efficiency improves 5%.
Embodiment 2
1mm thickness copper mesh is placed in incubator, temperature control is at 250 DEG C, by the carbon powder and grain that particle diameter is 0.02mm
The polypropylene powder that footpath is 0.05mm presses 1：2 mass ratio, which is uniformly mixed, to be loaded in spray gun, and mixture is sprayed on copper mesh both sides table
On face, coating layer thickness 1.0mm, then particle diameter is sprayed in mixture layer both side surface for 0.02mm carbon powders, coating layer thickness is
0.1mm, then put it into mould and bipolar plate of vanadium cell is made after hot pressing on hot press, hot pressing temperature is 180 DEG C, hot pressing
Time is 20min, hot pressing pressure 25MPa.
Bipolar plates manufactured in the present embodiment assemble 2KW vanadium cells, and battery charging and discharging performance parameter is：Coulombic efficiency
95.2%, voltage efficiency 85.5%, energy efficiency 81.4%, compared with existing carbon moulds bipolar plates, voltage efficiency improves 4%.
Embodiment 3
1.5mm thickness copper coins are placed in incubator, temperature control is at 210 DEG C, by the carbon fiber powder that particle diameter is 0.10mm
With particle diameter 1 is pressed for the polyethylene powder of 0.06mm：3 mass ratio, which is uniformly mixed, to be loaded in spray gun, and mixture is sprayed on copper coin two
On side surface, coating layer thickness 0.9mm, then particle diameter is sprayed in mixture layer both side surface for 0.10mm carbon fiber powders, coating
Thickness is 0.13mm, then puts it into mould and bipolar plate of vanadium cell, hot pressing temperature 150 is made after hot pressing on hot press
DEG C, hot pressing time 30min, hot pressing pressure 20MPa.
Bipolar plates manufactured in the present embodiment assemble 2KW vanadium cells, and battery charging and discharging performance parameter is：Coulombic efficiency
96.0%, voltage efficiency 86.0%, energy efficiency 82.6%, compared with existing carbon moulds bipolar plates, voltage efficiency improves 5%.
Embodiment 4
2mm thickness iron nets are placed in incubator, temperature control is at 200 DEG C, by the graphite powder and grain that particle diameter is 0.04mm
The polypropylene powder that footpath is 0.05mm presses 1：4 mass ratio, which is uniformly mixed, to be loaded in spray gun, and mixture is sprayed on steel plate both sides table
On face, coating layer thickness 1.2mm, then particle diameter is sprayed in mixture layer both side surface for 0.04mm graphite powders, coating layer thickness is
0.08mm, then put it into mould and bipolar plate of vanadium cell is made after hot pressing on hot press, hot pressing temperature is 180 DEG C, heat
The pressure time is 25min, hot pressing pressure 24MPa.
Bipolar plates manufactured in the present embodiment assemble 2KW vanadium cells, and battery charging and discharging performance parameter is：Coulombic efficiency
95.9%, voltage efficiency 85.8%, energy efficiency 82.3%, compared with existing carbon moulds bipolar plates, voltage efficiency improves
4.3%.
Claims (9)
- A kind of 1. bipolar plate of vanadium cell, it is characterised in that：Metal material is used to select the mode of thermal spraying for framework material, Spray one layer of mixture being made of conducting powder and resin respectively in metal material both sides first, spray one layer respectively in both sides after curing Conductive powder body, then on hot press it is hot-forming.
- 2. bipolar plate of vanadium cell described in accordance with the claim 1, it is characterised in that：Spraying uses the external air pump of spray gun, by powder Body loads in spray gun, the spraying powder by way of air pressure.
- 3. bipolar plate of vanadium cell described in accordance with the claim 1, it is characterised in that：Metal material is metallic plate or metal Net, for thickness in 0.5mm~30mm, material is copper, steel, iron, titanium or silver.
- 4. bipolar plate of vanadium cell described in accordance with the claim 1, it is characterised in that：The mixture of conducting powder and resin composition In, the mass ratio of conducting powder and resin is (1：1)~(1：10).
- 5. according to the bipolar plate of vanadium cell described in claim 1 or 4, it is characterised in that：Conducting powder is carbon black, graphite and carbon are fine Tie up one kind in powder；Resin is thermoplastic resin or thermosetting resin, and thermoplastic resin is polypropylene, polyethylene, polyvinyl chloride In one kind, the one kind of thermosetting resin for phenolic resin, in epoxy resin.
- 6. bipolar plate of vanadium cell described in accordance with the claim 1, it is characterised in that：The particle diameter of powder particle for 0.01mm~ 3mm, preferably 0.01mm~0.1mm.
- 7. bipolar plate of vanadium cell described in accordance with the claim 1, it is characterised in that：Exist positioned at outermost conductive powder body thickness The mixture thickness of 0.02mm~0.10mm, conducting powder and resin composition is in 0.5mm~30mm.
- 8. bipolar plate of vanadium cell described in accordance with the claim 1, it is characterised in that：The thickness of bipolar plate of vanadium cell exists 1.0mm~40mm.
- 9. the preparation method of the bipolar plate of vanadium cell described in a kind of one of claim 1 to 8, it is characterised in that specific steps It is as follows：1) metallic plate or metal mesh are placed in incubator, temperature control is at 150~300 DEG C；2) metallic plate will be got to by air pressure in conducting powder and resin powder mixture loading spray gun or bone is used as in metal mesh both sides Rack-layer；3) after casing play curing, one layer of conductive powder body is sprayed respectively in its both sides；4) put it into it is hot-forming on hot press be made bipolar plate of vanadium cell, hot pressing temperature is 100~300 DEG C, during hot pressing Between be 5~200min, hot pressing pressure is 1~25MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610958797.5A CN108023106B (en) | 2016-11-03 | 2016-11-03 | Bipolar plate for vanadium battery and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610958797.5A CN108023106B (en) | 2016-11-03 | 2016-11-03 | Bipolar plate for vanadium battery and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108023106A true CN108023106A (en) | 2018-05-11 |
| CN108023106B CN108023106B (en) | 2020-07-10 |
Family
ID=62083915
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610958797.5A Expired - Fee Related CN108023106B (en) | 2016-11-03 | 2016-11-03 | Bipolar plate for vanadium battery and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108023106B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110289428A (en) * | 2019-06-19 | 2019-09-27 | 北京科技大学 | A kind of preparation of fuel cell stainless steel bi-polar plate and surface modifying method |
| CN110828841A (en) * | 2019-11-19 | 2020-02-21 | 深圳市雄韬电源科技股份有限公司 | Fuel cell bipolar plate and preparation method and used equipment thereof |
| CN111370719A (en) * | 2020-03-19 | 2020-07-03 | 辽宁科京新材料科技有限公司 | High-conductivity bipolar plate for flow battery and continuous processing device and method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102637881A (en) * | 2012-04-11 | 2012-08-15 | 朝阳华鼎储能技术有限公司 | Method for preparing electroconductive plastic bipolar plate for vanadium cell |
| CN102891324A (en) * | 2012-09-25 | 2013-01-23 | 中国科学院金属研究所 | Bipolar plate for vanadium battery and preparation method for bipolar plate |
| CN103633336A (en) * | 2012-08-29 | 2014-03-12 | 中国科学院大连化学物理研究所 | Bipolar plate for liquid flow energy storage battery and preparation method |
| US20140272571A1 (en) * | 2013-03-15 | 2014-09-18 | Physical Sciences, Inc. | Electroactive Polymer Coating for Improved Battery Safety |
-
2016
- 2016-11-03 CN CN201610958797.5A patent/CN108023106B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102637881A (en) * | 2012-04-11 | 2012-08-15 | 朝阳华鼎储能技术有限公司 | Method for preparing electroconductive plastic bipolar plate for vanadium cell |
| CN103633336A (en) * | 2012-08-29 | 2014-03-12 | 中国科学院大连化学物理研究所 | Bipolar plate for liquid flow energy storage battery and preparation method |
| CN102891324A (en) * | 2012-09-25 | 2013-01-23 | 中国科学院金属研究所 | Bipolar plate for vanadium battery and preparation method for bipolar plate |
| US20140272571A1 (en) * | 2013-03-15 | 2014-09-18 | Physical Sciences, Inc. | Electroactive Polymer Coating for Improved Battery Safety |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110289428A (en) * | 2019-06-19 | 2019-09-27 | 北京科技大学 | A kind of preparation of fuel cell stainless steel bi-polar plate and surface modifying method |
| CN110828841A (en) * | 2019-11-19 | 2020-02-21 | 深圳市雄韬电源科技股份有限公司 | Fuel cell bipolar plate and preparation method and used equipment thereof |
| CN111370719A (en) * | 2020-03-19 | 2020-07-03 | 辽宁科京新材料科技有限公司 | High-conductivity bipolar plate for flow battery and continuous processing device and method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108023106B (en) | 2020-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108023104B (en) | Bipolar plate for vanadium battery and preparation method thereof | |
| CN103187551B (en) | Lithium ion liquid flow battery | |
| CN101969120B (en) | Technology for manufacturing lead-acid battery pole plate | |
| CN102891324B (en) | Bipolar plate for vanadium battery and preparation method for bipolar plate | |
| CN109004234A (en) | A kind of lithium ion secondary battery | |
| CN106299514A (en) | A kind of compound method for lithium ion battery | |
| CN105609703A (en) | Integrated electrode and fabrication method | |
| CN104409740B (en) | A kind of Novel vanadium battery bipolar plates and preparation method thereof | |
| CN108023106A (en) | Bipolar plate of vanadium cell and preparation method thereof | |
| CN109950556B (en) | Preparation method of carbon fiber bipolar plate with three-dimensional porous structure | |
| CN112159634A (en) | Carbon powder conductive adhesive, flow battery electrode prepared by using carbon powder conductive adhesive and galvanic pile | |
| CN102208629A (en) | Preparation method of bipolar electrode plate for battery | |
| CN109732943A (en) | Bipolar plate for fuel cell and preparation method thereof | |
| CN104882630B (en) | A kind of preparation method of the naked battery core of lithium ion battery and the lithium ion battery containing the naked battery core | |
| CN103035928B (en) | Integrated electrode for vanadium cell and preparation method thereof | |
| CN106410268A (en) | Multi-coating intelligent high-safety polymer lithium ion secondary battery | |
| CN207459090U (en) | A kind of lithium ion battery | |
| CN102623756A (en) | Bipolar battery made from thin film composite material and bipolar plate base of bipolar battery | |
| CN106486631A (en) | A kind of high voltage fills lithium ion battery and preparation method thereof soon | |
| CN106025383B (en) | Valve-regulated lead-acid storage battery and preparation method thereof | |
| CN109411779A (en) | A kind of preparation method of vanadium cell soft graphite bipolar plates | |
| CN114024037A (en) | Solid-state battery cell, preparation method thereof and energy storage device | |
| CN111600057B (en) | Composite material structure battery with curved surface structure and preparation method and application thereof | |
| CN101794887A (en) | Vanadium battery bi-polar plate, preparation method and application thereof | |
| CN103531820A (en) | Carbon-based bipolar plate used for lead-acid storage battery and preparation method of the carbon-based bipolar plate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20200710 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |