CN107810963A - A kind of Herbicidal combinations of the fluorine of pyrrole containing ring humulone and its application - Google Patents

A kind of Herbicidal combinations of the fluorine of pyrrole containing ring humulone and its application Download PDF

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Publication number
CN107810963A
CN107810963A CN201711095778.5A CN201711095778A CN107810963A CN 107810963 A CN107810963 A CN 107810963A CN 201711095778 A CN201711095778 A CN 201711095778A CN 107810963 A CN107810963 A CN 107810963A
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humulone
ring pyrrole
pyrrole fluorine
fluorine
accession number
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彭学岗
赵德
金涛
刘娜
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Qingdao Qing Yuan Compound Co Ltd
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Qingdao Qing Yuan Compound Co Ltd
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Priority to CN202110317652.8A priority Critical patent/CN113057169B/en
Priority to CN201711095778.5A priority patent/CN107810963A/en
Priority to PCT/CN2017/112017 priority patent/WO2019090815A1/en
Publication of CN107810963A publication Critical patent/CN107810963A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
    • A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A—HUMAN NECESSITIES
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
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    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
    • A—HUMAN NECESSITIES
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
    • A—HUMAN NECESSITIES
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • A—HUMAN NECESSITIES
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    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
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    • A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals

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Abstract

The invention belongs to pesticide field, and in particular to a kind of Herbicidal combinations of the fluorine of pyrrole containing ring humulone and its application.It is ring pyrrole fluorine humulone that the composition, which includes the active components A of herbicidally effective amount and B, A, and B may be selected from the one or more of following compound：VLCFA, PPO, PSII, ALS, microtubules, HPPD, PDS, DOXP, lipid synthesis, EPSPS, GS, PSI, DHP inhibitor class and synthetic hormone class etc..Said composition can effectively prevent and kill off the weed problems such as Alopecurus in the crop fields, Descurainia sophia, shepherd's purse, ox chickweed, Veronica, clearvers, amur foxtail, annual bluegrass, have the characteristics that to expand herbicide controlling spectrum, reduce amount of application, to crop safety, synergistic effect can be produced and solve resistant weed.

Description

A kind of Herbicidal combinations of the fluorine of pyrrole containing ring humulone and its application
Technical field
The invention belongs to pesticide field, and in particular to a kind of Herbicidal combinations of the fluorine of pyrrole containing ring humulone and its application.
Background technology
Chemical weed control is means the most economical and effective during farmland weed is prevented and kill off, but uses list for a long time continuous high dose The chemical herbicide of one kind or the single mode of action, the problems such as easily causing weeds resistance and resistance evolution.
Ring pyrrole fluorine humulone chemical structural formula isBelong to HPPD inhibitor, pass through suppression The activity of HPPD enzymes, make to be converted into oxypyroracemic acid alcapton process and be obstructed, so as to cause tocopherol and plastoquinone can not be just Often synthesis, influence carotenogenesis in target body, cause blade to turn white, influence it is photosynthetic in plant be normally carried out, It is final thoroughly dead.
The reasonable compounding or mixture of herbicidal compounds, which have, to be expanded weeds spectrum, improves preventive effect, delays weeds resistance Property and it is drug-fast generation with development the advantages that, be one of maximally efficient method to solve the above problems.Therefore in production urgently Safe, broad weed-killing spectrum need to be developed, synergistic effect can be produced and solves the problems, such as the Herbicidal combinations kind of resistant weed.
The content of the invention
To solve the above-mentioned problems in the prior art, the present invention provides a kind of Herbicidal combinations of the fluorine of pyrrole containing ring humulone And its application.Said composition can effectively prevent and kill off Alopecurus in the crop fields, Descurainia sophia, shepherd's purse, ox chickweed, Veronica, pig Bring disaster to calamity, amur foxtail, the weed problem such as annual bluegrass, have expand herbicide controlling spectrum, reduction amount of application, to crop safety, increasing can be produced Effect acts on and solves the features such as resistant weed.
A kind of Herbicidal combinations of the fluorine of pyrrole containing ring humulone, including the active components A of herbicidally effective amount and active component B, its In, active components A is ring pyrrole fluorine humulone, and active component B may be selected from the one or more of following compound:
1) VLCFA inhibitor class:Butachlor (CAS accession number:23184-66-9), anilofos (CAS accession number:64249- 01-0), xylenol grass amine (CAS accession number:87674-68-8), fentrazamide (CAS accession number:158237-07-1), triazole Acyl grass amine (CAS accession number:212201-70-2), cafenstrole (CAS accession number:125306-83-4), piperophos (CAS accession number: 24151-93-7), metazachlor (CAS accession number:67129-08-2), propachlor (CAS accession number:1918-16-7), pethoxamid (CAS accession number:106700-29-2)；
2) PPO inhibitor class:Oxyfluorfen (CAS accession number:42874-03-3), fomesafen (CAS accession number: 72178-02-0), Evil humulones (CAS accession number:19666-30-9), oxadiargyl (CAS accession number:39807-15-3), first Sulphur grass amine (CAS accession number:122836-35-5), pyraclonil (CAS accession number:158353-15-2), flumioxazin (CAS Accession number:103361-09-7), Huan Wu Evil humulones (CAS accession number:110956-75-7), tiafenacil (CAS accession number: 1220411-29-9), benzene flumetsulam (CAS accession number:372137-35-4)；
3) PSII inhibitor class:Atrazine (CAS accession number:102029-43-6), Garagard (CAS accession number:5915- 41-3), ametryn (CAS accession number:834-12-8), dipropetryn (CAS accession number:4147-51-7), net (the CAS logins of evil grass Number:845-52-3), desmetryn (CAS accession number:1014-69-3), Simanex (CAS accession number:122-34-9), cyanazine (CAS accession number:21725-46-2), fluometuron (CAS accession number:2164-17-2), linuron (CAS accession number:330-55- 2), tebuthiuron (CAS accession number:34014-18-1), Sha flutters grand (CAS accession number:42609-52-9), (CAS is logged in afesin Number:1746-81-2), metobromuron (CAS accession number:3060-89-7), neburea (CAS accession number:555-37-3), alcohol pyridazines (CAS accession number:40020-01-7), hexazinone (CAS accession number:51235-04-2), dimethametryn (CAS accession number:22936- 75-0), trietazine (CAS accession number:1912-26-1), bromacil (CAS accession number:314-40-9), (CAS is logged in lenacil Number:2164-08-1), terbacil (CAS accession number:5902-51-2), methabenzthiazuron (CAS accession number:18691-97-9), ring Grand (the CAS accession number of grass:1982-49-6) grand (the CAS accession number of, Yi Evil:55861-78-4), metoxuron (CAS accession number: 19937-59-8), chloroxifenidium (CAS accession number:1982-47-4), Cyclopyrimorate (CAS accession number:499231-24- 2), pyridate (CAS accession number:55512-33-9), desmedipham (CAS accession number:13684-56-5), (CAS is logged in phenmedipham Number:13684-63-4), symetryne (CAS accession number:1014-70-6), diuron (CAS accession number:330-54-1), ammonia azoles grass Ketone (CAS accession number:129909-90-6), metamitron (CAS accession number:41394-05-2), ethiozin (CAS accession number: 64529-56-2)；
4) ALS inhibitor class:Pyrazosulfuron (CAS accession number:93697-74-6), grand (the CAS accession number of thiophene ketone sulphur: 317815-83-1), promazine Sulfometuron Methyl (CAS accession number:570415-88-2), piperazine pyrazosulfuron (CAS accession number:868680- 84-6), rimsulfuron (CAS accession number:122931-48-0), ethoxysulfuron (CAS accession number:126801-58-9), phonetic aniline Grand (the CAS accession number of sulphur:213464-77-8), nicosulfuron (CAS accession number:111991-09-4), (CAS is stepped on foramsulfuron Record number:173159-57-4), fluorine ketone sulphur grass amine (CAS accession number:96525-23-4) penoxsuam (CAS accession number: 219714-96-2), cloransulammethyl (CAS accession number:147150-35-4)), imazamox (CAS accession number:114311- 32-9), AC 263222 (CAS accession number:104098-48-8), imazethapyr (CAS accession number:81385-77-5), weed eradication Cigarette (CAS accession number:81334-34-1), KIH 6127 (CAS accession number:147411-69-6)；
5) microtubules inhibitor class:Trefanocide (CAS accession number:1582-09-8), butralin (CAS accession number: 33629-47-9), pendimethalin (CAS accession number:40487-42-1), Amex820 (CAS accession number:33629-47-9), fluorine sulphur Fixed (the CAS accession number of grass:97886-45-8), ethalfluralin (CAS accession number:55283-68-6), (CAS is logged in oryzalin Number:19044-88-3), benfluralin (CAS accession number:1861-40-1), thiazopyr (CAS accession number:117718-60-2), by grass Special (CAS accession number:23950-58-5), chlorthal (CAS accession number:1861-32-1), butamifos (CAS accession number:36335- 67-8)；
6) HPPD inhibitor class:Sulphur humulone (CAS accession number:99105-77-8), mesotrione (CAS accession number: 104206-82-8), ring sulphur ketone (CAS accession number:335104-84-2), furans sulphur humulone (CAS accession number:473278-76-1)、 Benzobicylon (CAS accession number:156963-66-5), lancotrione (CAS accession number:1486617-21-3), sulphonyl grass Pyrazoles (CAS accession number:365400-11-9), pyrazolate (CAS accession number:58011-68-0), benzofenap (CAS accession number: 82692-44-2), tolpyralate (CAS accession number:1101132-67-5), fenquinotrione (CAS accession number: 1342891-70-6), isoxaflutoles (CAS accession number:141112-29-0)；
7) PDS inhibitor class:Fluorochloridone (CAS accession number:61213-25-0), flurtamone (CAS accession number:96525- 23-4), beflubutamid (CAS accession number:113614-08-7), norflurazon (CAS accession number:27314-13-2), fluridone (CAS accession number:59756-60-4)；
8) DOXP inhibitor class:Clomazone (CAS accession number:81777-89-1)；
9) lipid synthesis (non-acetyl-CoA carboxylase) inhibitor class:Molinate (CAS accession number:2212-67-1), standing grain Careless pellet (CAS accession number:28249-77-6), benfuresate (CAS accession number:68505-69-1), ethofumesate (CAS accession number: 26225-79-6), tri-allate (CAS accession number:2303-17-5), benthiocarb (CAS accession number:28249-77-6), vernolate (CAS accession number:1929-77-7), Ding Caote (CAS accession number:2008-41-5), cycloate (CAS accession number:1134-23- 2), dimepiperate (CAS accession number:61432-55-1), esprocarb (CAS accession number:85785-20-2)；
10) synthetic hormone class:Dichloro quinolinic acid (CAS accession number:84087-01-4), quinmerac (CAS accession number: 90717-03-6), Thistrol (CAS accession number:94-81-5), 2,4- Embutoxs (CAS accession number:94-82-6)；
11) EPSPS inhibitor class:Sulphosate (CAS accession number:81591-81-3)；
12) GS inhibitor class:Bialaphos (CAS accession number:35597-43-4), smart glufosinate-ammonium (CAS accession number: 35597-44-5)；
13) PSI inhibitor class:Paraquat (CAS accession number:1910-42-5), diquat dibromide (CAS accession number:6385-62- 2)；
14) DHP inhibitor class:Clever (the CAS accession number of sulphur grass:3337-71-1)；
15) other:Oxaziclomefone (CAS accession number:153197-14-9), cinmethylin (CAS accession number:87818-31- 3)。
Wherein, A and B weight ratio is 1:200-200:1, preferably 1:150-150:1, more preferably 1:120-120:1；Enter one Step ground, A and B weight ratio are 1:100-100:1, preferably 1:80-80:1, more preferably 1:50-50:1；Further, A and B Weight ratio be 1:30-30:1, preferably 1:10-10:1, more preferably 1:5-5:1.
A, B weight/mass percentage composition account for the 1-95% of total amount, preferably 10-80% in the Herbicidal combinations.
Conven-tional adjuvants are also included in the Herbicidal combinations, the conven-tional adjuvants include carrier, surfactant.
Term " carrier " herein represents a kind of organic or inorganic, natural or synthetic material.They contribute to activity The administration of composition, the carrier are usually inert and must be agriculturally acceptable, and particularly processed plant is received. Carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer；Or liquid Body, such as water, alcohols, ketone, petroleum distillate, aromatic hydrocarbons or wax hydrocarbon, chlorohydrocarbon, liquefied gas.
Surfactant may include emulsifying agent, dispersant or wetting agent, and it can be ionic or nonionic.It can carry And example be the salt of polyacrylic acid, lignosulfonates, phenolsulfonic acid or naphthalene sulfonic acids salt, oxirane and aliphatic alcohol or Polymer, sulfosuccinic acid with aliphatic acid or with aliphatic amine and fortified phenol (particularly alkylphenol or aryl phenol) Phosphate, the alkyl of salt, taurine derivatives (particularly taurine alkane fat) and the phenol of alcohol phosphate or multi-hydroxy ethyl Sulfonate, alkylaryl sulfonates, alkyl sulfate, lauryl ether sulfate, aliphatic alcohol sulfate, and sulphation 16-, 17-and octadecanol and sulphated fatty alcohol glycol ether, in addition with the condensation of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde Thing, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol or nonyl phenol, alkyl phenyl polyglycol ether, three fourths Base phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, alcohol and fatty alcohol/ethylene oxide contracting Compound, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation polyoxypropylene, laruyl alcohol polyglycol ether acetal, sorb Alcohol ester, lignin sulfite waste liquor, and protein, albuminate, polysaccharide (such as methylcellulose), Hydrophobic Modified Starch, Polyvinyl alcohol, polycarboxylate, poly-alkoxyl compound, polyvinylamine, polyvinylpyrrolidone and its copolymer.At least need one kind Surfactant is present, to be advantageous to scattered in water of active component and be advantageous to enable them to correctly be applied to plant.
Above-mentioned composition also contains various other components, such as protecting colloid, adhesive, thickener, thixotropic agent, infiltration Agent, stabilizer, chelating agent, dyestuff, colouring agent and polymer.
The composition of the present invention can be used by user before use through dilution or directly.It, which is prepared, to be added by common Work method prepare, i.e., after active material is mixed with liquid flux or solid carrier, add surfactant such as dispersant, surely Determine the one or more in agent, wetting agent, adhesive, defoamer etc..
The specific preparation of the Herbicidal combinations be dispersible oil-suspending agent, aqueous suspension agent, suspension emulsion, wettable powder, Missible oil, water dispersible granules (dry suspending agent), aqueous emulsion, microemulsion.
In brief, composition of the invention can be with conventional use of solid and liquid addition in the formula of prior art Agent mixes.
In addition, compound A and B composition can mix with following active material, such as《World pesticide new varieties technology It is complete works of》, Scientia Agricultura Sinica technology publishing house, 2010.9 and document incorporated herein in known substance.It is such as mentioned below Herbicidal activity material, (remarks:The title of compound, or be the common name according to International Organization for standardization (ISO), Or be chemical name, have code name when appropriate):Acetochlor, butachlor, alachlor, propisochlor, isopropyl methoxalamine, essence The left-handed naphthalene propionyl grass amine of isopropyl methoxalamine, pretilachlor, propachlor, kecaoan, naphthalene propionyl grass amine, R-, propanil, mefenacet, Diphenamide, diflufenican, N-alpha-chloroacetyl-N-isopropyl-o ethylaniline, beflubutamid, bromobutide, dimethenamid, dimethenamidP, Ethobenzanid, flufenacet, thenylchlor, metazachlor, isoxaben, flampropMmethyl, flampropMisopropyl, Allidochlor, pethoxamid, chloranocryl, ring pretilachlor, mefluidide, monalide, delachlor, prynachlor, spy Butachlor, xylachlor, dimethachlor, amine of taking to the greenwood, front three ring grass amine, clomeprop, propyzamide, valeryl benzene grass Amine, the careless amine of card, suffer, three rings match careless amine, butenachlor, tebutam, benzyl grass amine, quinone duckweed amine, dichlofluanid, naproanilide, second Acyl alachlor, quinclorac, fenacet, pyrrole cyanogen grass amine, more grams of benzene grass are dead, chlorothiamid, chlorine phthalimide, fourth amidine amine, fluorine metazachlor, green bristlegrass Go Tianjin, Simanex, prometryn, cyanatryn, symetryne, ametryn, propazine, dipropetryn, SSH-108, terbutryn, Garagard, three Piperazine benfluralin, cyprazine, proglinazine, trietazine, prometon, Gesadrual, nitrine are net, desmetryn, dimethametryn, third blue or green Tianjin of ring, Green bristlegrass of going out Tianjin, another Ding Jin, Zhong Dingtong, Te Dingtong, methoxy third are net, cyanatryn, ipazine, chlorazine, atraton, weed eradication are logical, radix glycyrrhizae Tianjin, cyanuric acid, Indaziflam, green sulphur are grand, metsulfuron-methyl, bensulfuron-methyl, chlorimuron, tribenuron-methyl, thifensulfuron methyl, the phonetic Huang of pyrrole Grand, mesosulfuron, iodosulfuron-methyl-sodium, formamido group Sulfometuron Methyl, cinosulfuron, triasulfuron, sulfometuronmethyl, the phonetic sulphur of cigarette Grand, ethametsulfuron, amidosulfuron, ethoxysulfuron, AC322140, rimsulfuron, azimsulfuron, pyridine ethyl methyl, list are phonetic Sulphur is grand, single phonetic sulphur ester, flucarbazone, flupyrsulfuron-methyl-sodium, fluorine pyrazosulfuron, oxasulfuron, imazosulfuron, primisulfuronmethyl, Procarbazone, prosulfuron, Sulfosulfuron, trifloxysulfuron, triflusulfuronmethyl, tritosulfuron, metsulfuron-methyl sodium salt, fluorine pyrrole sulphur Grand, Sulfonylurea, orthosulfamuron, Propyrisulfuron (promazine Sulfometuron Methyl), piperazine pyrazosulfuron, acifluorfen, fluorine Sulfanilamide (SN) grass ether, lactofen, fluoroglycofen-ethyl, Oxyfluorfen, Mo 9 granular, aclonifen, ethoxyfen-ethyl, first carboxylic weeding Ether, fluoroform grass ether, chlomethoxyfen, fluorodifen, fluorination nitrofen, fluorine furan grass ether, nitrofen, first grass ether, diformazan grass Ether, fluorine lactazone grass ether, AKH7088 ester, Halosafen, chlortoluron, isoproturon, linuron, diuron, Sha flutter grand, fluometuron, benzene Thiophene is grand, methabenzthiazuron, cumyluron, ethidimuron, isouron, terbufos benzthiazuron, buturon, bromax, methyldymron, acyl grass Grand, methoxy daimuron, metobromuron, metoxuron, afesin, telvar, Tupersan, fenuron, fluorine sulphur are grand, neburea, chloroxifenidium, It is herban, isonoruron, Alipur-O, thiazfluron, tebuthiuron, difenoxuron, different to fluon, methylamine methabenz thiazuron, Long Caote, front three Urea, dimefuron, Monisouron, Anisuron, Methiuron, Chloreturon, four fluon, phenmedipham, phenmedipham-second The careless spirit of ester, desmedipham, sulphur, terbucarb, oatax, Chem hoe, chlorpropham, benzyl dichloride grass ester, swep, chlorbufam, Carboxazole, Chlorprocarb, Fenasulam, BCPC, CPPC, Carbasulam, Ding Caote, benthiocarb, vernolate, The careless spy of molinate, tri-allate, dimepiperate, esprocarb, pyributicarb, cycloate, Avadex, bactericide, second sulphur, orbencarb, gram grass Suddenly, prosulfocarb, tiocarbazil, sulfuric acid, dimexan, Isopolinate, Methiobencarb, 2,4- d butyl ester, the chlorine of 2 first 4 Sodium, the different monooctyl ester of 2,4- drops, the different monooctyl ester of the chlorine of 2 first 4,2,4- drops sodium salt, 2,4- drops dimethylamine salt, the chloroethene thioesters of 2 first 4, the chlorine of 2 first 4,2, 4- drops propionic acid, high 2,4- drops propionate, 2,4- Embutoxs, Vi par, Vi par salt, Thistrol, 2,4,5- Tears, 2,4,5- tears propionic acid, 2,4,5- tears butyric acid, the chloramines salt of 2 first 4, Mediben, erbon, Fenac, match pine, trichlorobenzoic acid, ammonia Dichloro benzoic acid, methoxy trichlorobenzoic acid, diclofop-methyl, fluazifop, efficient fluazifop, haloxyfop-P-methyl, efficient pyrrole fluorine chlorine standing grain Spirit, quizalofop-ethyl, Quizalotop-ethyl, fenoxaprop-P, fenoxapropPethyl, propaquizafop, cyhalofop-butyl, metamifop, clodinafop-propargyl, Diclofop-methyl thiazole, chloroazifoppropynyl, the spirit of the standing grain of hydroxyl penta, trifluoro dogstail oxime, isoxapyrifop, paraquat, diquat dibromide, oryzalin, second butylene fluorine Spirit, isopropalin, nitralin, profluralin, prodiamine, benfluralin, fluchloraline, the spirit of amino second fluorine, dipropalin, Chloroethene dipropalin, Methalpropalin, the third nitre phenol, glyphosate, Sha barnyard grass phosphine, glufosinate-ammonium, amiprophos-methyl, sulphosate, piperazine grass Phosphine, bialaphos, bensulide, butamifos, creeping weed phosphorus, cut down ridge phosphorus, double first amiprophos, dow crabgrass killer, imazapyr, imidazoles second cigarette Acid, imazaquin, imazamox, imazamox ammonium salt, AC 263222, miaow grass ester, fluroxypyr, chlorine fluorine pyrrole The different monooctyl ester of fluoroacetic acid, clopyralid, picloram, trichlopyr, dithiopyr, halogen grass are fixed, phenolate trichloropyridine, thiophene Careless pyridine, fluridone, chlorine Fampridine acid, diflufenzopyr, triclopyr butoxyethyl ester, Cliodinate, sethoxydim, alkene Humulone, cycloxydim, alloxydimsodium, clefoxidim, butroxydim, tralkoxydim, tepraloxydim, Buthidazole, metribuzin, ring piperazine Ketone, metamitron, ethiozin, Ametridione, Amibuzin, Brominal, bromoxynil octanoate, ioxynil octanoate, iodobenzene Nitrile, dichlobenil, diphenatril, pyraclonil, chloroxynil, Iodobonil, Flumetsulam, florasulam, penoxsulam Amine, metosulam, cloransulammethyl, diclosulam, pyroxsulam, fluorine straw colour, bispyribac-sodium, pyribenzoxim, pyriftalid, KIH 6127, pyrithiobacsodium, benzobicylon, mesotrione, sulphur humulone, Tembotrione, Tefuryltrione, It is Bicyclopyrone, Ketodpiradox, isoxaflutole, isoxachlorotole, Fenoxasulfone, Methiozolin, different Third pyrrole grass ester, pyraflufen-ethyl, pyrazolate, difenzoquat, pyrazoxyfen, benzofenap, pyrrole chlorine grass amine, Pyrasulfotole, topramezone, Pyroxasulfone, cafenstrole, flupoxam, Amrol, amicarbazone, azafenidin, profluazone, sulfentrazone, Bencarbazone, benzfendizone, butafenacil, bromacil, isoprocil, lenacil, terbacil, Flupropacil, Yin Diindyl ketone grass ester, Flumiclorac pentyl, flumioxazin, alkynes grass amine, phthalein benzyl oxide, Flumezin, pentachlorophenol (sodium), dinoseb, dinoterb, Dinoterb acetate, dinosam, Chemox PE, chlorine nitre phenol, medinoterb acetate, Di Lete, oxadiargyl, oxadiazon, pentoxazone, fluorine azoles grass Amine, fluthiacet, fentrazamide, flufenpyrethyl, pyrazon, brompyrazon, diformazan reach careless volt, Kusakira, careless pyridazone, grass Rattle away pine, norflurazon, Pyridafol, dichloro quinolinic acid, quinmerac, Bentazon, pyridate, oxaziclomefone, benazolin, different Oxadiazon, cinmethylin, iso-propyl-ester nitrofen, propyl-ester nitorfen, indanofan, sodium chlorate, Dalapon, trichloroacetic acid, monochloroacetic acid, six Chlroacetone, tetrafluoro propionic acid, herbage are fast, bromofenoxim, triazole sulphur, kill azoles, flurtamone, benfuresate, ethofumesate, phonetic careless amine, chlorine Phthalandione, fluorochloridone, barnyard grass, methacrylaldehyde, bentranil, tridiphane, Bidisin, thiadiazoles grass amine, phenisopham, hydroxyl humulone, first Oxybenzone, benzene flumetsulam, chlorine acyl grass phosphine, chloropon, Alorac, Diethamquat, Etnipromid, Iprymidam, Ipfencarbazone、Thiencarbazone-methyl、Pyrimisulfan、Chlorflurazole、 Tripropindan, Sulglycapin, first sulphur nitralin, Cambendichlor, the pyrimidine acid of ring third, rodethanii, benoxacor, Fenclorim, flurazole, fenchlorazole, the careless quinoline of solution, oxabetrinil, MG191, cyometrinil, DKA_24, mefenpyrdiethyl, furans solution grass Azoles, fluxofenim, isoxadifen, allyl dichloride amine, fluorine chloropyridine ester, DOW chlorine fluorine pyridine ester, UBH-509, D489, LS 82- 556、KPP-300、NC-324、NC-330、KH-218、DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、 PP-600, MBH-001, KIH-9201, ET-751, KIH-6127 and KIH-2023.
The Herbicidal combinations further comprise safener, and it is selected from isoxadifen (CAS accession number:163520-33- 0), cyprosulfamide (CAS accession number:221667-31-8), mefenpyrdiethyl (CAS accession number:135590-91-9), solve Malicious quinoline (CAS accession number:99607-70-2), gibberellic acid (CAS accession number:77-06-5), furilazole (CAS accession number: 121776-33-8), metcamifen (CAS accession number:One or more in 129531-12-0).
The composition of the present invention can be applied on pending plant leaf blade by the method for spraying, that is, is applied to weeds, On the surface that the weed infestation or easy invasion being particularly harmful on plant growth influence.
When applying the Herbicidal combinations of the present invention, unexpected synergistic effect is obtained, and activity of weeding ratio makes It is individually active more notable with the expected summation of the activity of single herbicide, and single herbicide.Synergistic effect shows as applying Measure reduction, broader weeds distribution spectrum, herbicide effect faster, it is more longlasting, these characteristics are needed for Weeds distribution practice process Want.For described characteristic, these new compositions are significantly superior to existing herbicide.
The Herbicidal combinations of the present invention, which also have, to be had the advantage that:
(1) composition of the invention is environmentally friendly to be easy to degrade in the environment, suitable for various crop field.
(2) Herbicidal combinations cost of the invention is low, easy to use, and its popularization and application has huge economic benefit and society Benefit.
Embodiment
The following example not limits the present invention, and is used only to how the explanation present invention realizes.For some miscellaneous Grass, these embodiments show especially significant validity.It is exemplified below:
A) embodiment
1st, the 28% ring pyrrole dispersible oil-suspending agent of fluorine humulone butachlor (3+25)
The NPE+4% of 3%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+25% butachlor of humulone+6% Fumed silica+5%150# the solvent naphthas of the organobentonite of castor oil polyoxyethylene ether+3.0%+2.5%+methyl oleate is mended Foot.
2nd, 30% ring pyrrole fluorine humulone ethiozin suspending agent (6+24)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 6%+24% ethiozin of ring pyrrole fluorine humulone+5% disperses + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the AEO of agent+2%+1.6%+water is supplied.
3rd, 32% ring pyrrole fluorine humulone anilofos suspension emulsion (12+20)
The phenethyl phenol polyethenoxy ether phosphate of 12%+20% anilofos+10%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans+5% third of+2% castor oil polyoxyethylene ether of+3% phenethyl phenol polyethenoxy ether of triethanolamine dipersant+0.1% Triol+water is supplied.4th, the 18% ring pyrrole fluorine humulone dispersible oil-suspending agent of xylenol grass amine (3+15)
The NPE of+15%+5% calcium dodecyl benzene sulfonate of xylenol grass amine of 3% ring pyrrole fluorine humulone+6%+ + 10% soybean oil of fumed silica of+1.8% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+methyl oleate is mended Foot.
5th, 27% ring pyrrole fluorine humulone fentrazamide suspending agent (12+15)
The AEO of 12%+5% polycarboxylate salt dispersant of ring pyrrole fluorine+15% fentrazamide of humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of 0.16% xanthans+1.6%+water is supplied.
6th, the azole amide suspending agent (12+17) of 29% ring pyrrole fluorine humulone three
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+17% three azole amide of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of the AEO of powder+2%+1.6%+water is supplied.
7th, 27% ring pyrrole fluorine humulone cafenstrole suspending agent (12+15)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+15% cafenstrole of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of+2% AEO+1.8%+water is supplied.
8th, the 28% ring pyrrole dispersible oil-suspending agent of fluorine humulone piperophos (3+25)
The NPE+4% of 3%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+25% piperophos of humulone+6% Fumed silica+10%150# the solvent naphthas of the organobentonite of castor oil polyoxyethylene ether+1.2%+1.2%+methyl oleate Supply.
9th, 31% ring pyrrole fluorine humulone metazachlor suspension emulsion (6+25)
The phenethyl phenol polyethenoxy ether phosphate of 6%+25% metazachlor+20%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans+5% third of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of triethanolamine dipersant+0.1% Triol+water is supplied.
10th, 41% ring pyrrole fluorine humulone propachlor suspension emulsion (3+38)
The phenethyl phenol polyethenoxy ether phosphate three of 3%+38% propachlor+10%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.08% the third three Alcohol+water is supplied.
11st, 43% ring pyrrole fluorine humulone pethoxamid suspension emulsion (3+40)
The phenethyl phenol polyethenoxy ether phosphate three of 3%+40% pethoxamid+15%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans+5% of+2% castor oil polyoxyethylene ether of+3% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.04% the third three Alcohol+water is supplied.
12nd, the 24% ring pyrrole dispersible oil-suspending agent of fluorine humulone Oxyfluorfen (12+12)
The NPE of 12%+6% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+12% Oxyfluorfen of humulone+6% + 5% soybean oil of fumed silica of+1.4% organobentonite of+4% AEO+1.0%+methyl oleate is mended Foot.
13rd, 9% ring pyrrole fluorine humulone fomesafen aqua (3+6)
+ 15% AEO of dimethylamine of 3%+6% fomesafen of ring pyrrole fluorine humulone+4%+water is supplied.
14th, 52% ring pyrrole fluorine Cao Tong Evil humulones suspending agents (12+40)
The fat of 12%+2% naphthalenesulfonate dispersant of ring pyrrole fluorine humulone+5% polycarboxylate salt dispersant of+40% Evil humulones+2% + 5% glycerine of aluminium-magnesium silicate of+0.08% xanthans of fat alcohol APEO+1.0%+water is supplied.
15th, 18% ring pyrrole fluorine humulone oxadiargyl suspending agent (12+6)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+6% oxadiargyl of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.22% xanthans of the AEO of powder+2%+2.0%+water is supplied.
16th, 48% ring pyrrole fluorine humulone sulfentrazone suspending agent (12+36)
The AEO of 12%+4% polycarboxylic acid salt's dispersant of ring pyrrole fluorine+36% sulfentrazone of humulone+1%+ + 5% glycerine of aluminium-magnesium silicate of 0.1% xanthans+1.0%+water is supplied.
17th, 27% ring pyrrole fluorine humulone pyraclonil suspending agent (12+15)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 12%+15% pyraclonil of ring pyrrole fluorine humulone+5% disperses + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of the AEO of agent+2%+1.6%+water is supplied.
18th, the 18% ring pyrrole dispersible oil-suspending agent of fluorine humulone flumioxazin (12+6)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+6% flumioxazin of humulone+7%+ Fumed silica+10%150# the solvent naphthas of+1.5% organobentonite of 3% castor oil polyoxyethylene ether+1.2%+oleic acid first Ester is supplied.
19th, 39% ring pyrrole fluorine humulone Huan Wu Evil humulones suspending agents (12+27)
The AEO of+27%+5% polycarboxylate salt dispersant of Huan Wu Evil humulones of 12% ring pyrrole fluorine humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of 0.1% xanthans+1.0%+water is supplied.
20th, 28% ring pyrrole fluorine humulone tiafenacil suspending agents (24+4)
24% ring pyrrole fluorine humulone+4%tiafenacil+5% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinities + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the AEO of powder+2%+1.6%+water is supplied.
21st, the 12% ring pyrrole fluorine dispersible oil-suspending agent of humulone benzene flumetsulam (9+3)
The NPE of 9%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+3% benzene flumetsulam of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+3.0% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
22nd, 50% ring pyrrole fluorine humulone atrazine suspending agent (12+38)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+38% atrazine of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.07% xanthans of+2% AEO+0.8%+water is supplied.
23rd, 36% ring pyrrole fluorine humulone Garagard suspending agent (6+30)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+30% Garagard of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 2% AEO+1.5%+water is supplied.
24th, 43% ring pyrrole fluorine humulone ametryn suspending agent (3+40)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+40% ametryn of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 2% AEO+1.6%+water is supplied.
25th, 53% ring pyrrole fluorine humulone dipropetryn suspending agent (3+50)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+50% dipropetryn of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.06% xanthans of 2% AEO+0.6%+water is supplied.
26th, 53% ring pyrrole fluorine humulone does harm to careless net suspension agent (3+50)
Net+5% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3% ring pyrrole fluorine humulone+50% evil grass+ + 5% glycerine of aluminium-magnesium silicate of+0.07% xanthans of 2% AEO+0.6%+water is supplied.
27th, 44% ring pyrrole fluorine humulone desmetryn suspending agent (6+38)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+38% desmetryn of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 2% AEO+1.0%+water is supplied.
28th, 33% ring pyrrole fluorine humulone Simanex suspending agent (3+30)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+30% Simanex of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.17% xanthans of 2% AEO+1.6%+water is supplied.
29th, 28% ring pyrrole fluorine humulone cyanazine suspending agent (3+25)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+25% cyanazine of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of 2% AEO+1.6%+water is supplied.
30th, 46% ring pyrrole fluorine humulone fluometuron suspending agent (6+40)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+40% fluometuron of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 2% AEO+1.0%+water is supplied.
31st, 28% ring pyrrole fluorine humulone linuron suspending agent (3+25)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+25% linuron of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 2% AEO+1.6%+water is supplied.
32nd, 33% ring pyrrole fluorine humulone tebuthiuron suspending agent (3+30)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+30% tebuthiuron of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 2% AEO+1.6%+water is supplied.
33rd, 28% ring pyrrole fluorine humulone Sha flutters grand suspending agent (3+25)
The Sha of 3% ring pyrrole fluorine humulone+25% flutter grand+5% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant+ + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of 2% AEO+1.6%+water is supplied.
34th, 53% ring pyrrole fluorine humulone afesin suspending agent (3+50)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+50% afesin of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.06% xanthans of 2% AEO+0.6%+water is supplied.
35th, 39% ring pyrrole fluorine humulone metobromuron suspending agent (6+33)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+33% metobromuron of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of 2% AEO+1.2%+water is supplied.
36th, 67% ring pyrrole fluorine humulone neburea water dispersible granules (3+64)
The poly- second of disintegrant of 3%+6% pull open powder of ring pyrrole fluorine humulone+8% polycarboxylic acid salt's dispersant of+64% neburea+1% The precipitated silica of enol+5%+filler diatomite is supplied.
37th, 39% ring pyrrole fluorine humulone alcohol pyridazines suspending agent (6+33)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+33% alcohol pyridazines of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 2% AEO+1.6%+water is supplied.
38th, 41% ring pyrrole fluorine humulone hexazinone suspending agent (3+38)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+38% hexazinone of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of 2% AEO+1.2%+water is supplied.
39th, 45% ring pyrrole fluorine humulone dimethametryn suspending agent (3+42)
The AEO of 3%+5% polycarboxylate salt dispersant of ring pyrrole fluorine+42% dimethametryn of humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of 0.1% xanthans+0.8%+water is supplied.
40th, 43% ring pyrrole fluorine humulone trietazine suspending agent (3+40)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+40% trietazine of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.13% xanthans of 2% AEO+1.5%+water is supplied.
41st, 60% ring pyrrole fluorine humulone bromacil suspending agent (2.25+57.75)
The aliphatic alcohol polyethenoxy of 2.25%+3% polycarboxylate salt dispersant of ring pyrrole fluorine+57.75% bromacil of humulone+1.5% + 5% glycerine of aluminium-magnesium silicate of the xanthans of ether+0.04%+0.4%+water is supplied.
42nd, 46% ring pyrrole fluorine humulone lenacil suspending agent (6+40)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+40% lenacil of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 2% AEO+0.8%+water is supplied.
43rd, 63% ring pyrrole fluorine humulone terbacil suspending agent (3+60)
The AEO+0.16% of 3%+4% polycarboxylate salt dispersant of ring pyrrole fluorine+60% terbacil of humulone+2% + 5% glycerine of the aluminium-magnesium silicate of xanthans+1.6%+water is supplied.
44th, 26% ring pyrrole fluorine humulone methabenzthiazuron suspending agent (12+14)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+14% methabenzthiazuron of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of the AEO of powder+2%+1.8%+water is supplied.
45th, 63% ring pyrrole fluorine humulone Tupersan suspending agent (3+60)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 3%+60% Tupersan of ring pyrrole fluorine humulone+1.5% disperses + 5% glycerine of aluminium-magnesium silicate of+0.04% xanthans of the polycarboxylic acid salt of agent+2% dispersant+0.4%+water is supplied.
46th, the 33% ring pyrrole fluorine grand suspending agents of humulone Yi Evil (3+33)
+ 33% different grand+5% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersants of Evil of 3% ring pyrrole fluorine humulone+ + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of 2% AEO+1.6%+water is supplied.
47th, 70% ring pyrrole fluorine humulone metoxuron water dispersible granules (3+67)
The poly- second of disintegrant of 3%+6% pull open powder of ring pyrrole fluorine humulone+8% polycarboxylic acid salt's dispersant of+67% metoxuron+1% The precipitated silica of enol+5%+filler bentonite is supplied.
48th, 70% ring pyrrole fluorine humulone chloroxifenidium water dispersible granules (3+67)
The poly- second of disintegrant of 3%+6% pull open powder of ring pyrrole fluorine humulone+8% polycarboxylic acid salt's dispersant of+67% chloroxifenidium+1% The precipitated silica of enol+5%+filler diatomite is supplied.
49th, the 14% ring pyrrole dispersible oil-suspending agent of fluorine humulone pyrazosulfuron (12+2)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+2% pyrazosulfuron of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.2% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
50th, the 14% grand dispersible oil-suspending agent (12+2) of ring pyrrole fluorine humulone thiophene ketone sulphur
The grand NPE of+5% calcium dodecyl benzene sulfonate+7% of thiophene ketone sulphur of 12% ring pyrrole fluorine humulone+2%+ Fumed silica+5%150# the solvent naphthas of+2.6% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
51st, the 18% ring pyrrole fluorine dispersible oil-suspending agent of humulone promazine Sulfometuron Methyl (12+6)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+6% promazine Sulfometuron Methyl of humulone+6%+ Fumed silica+5%150# the solvent naphthas of+2.6% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
52nd, the 19% ring pyrrole fluorine dispersible oil-suspending agent of humulone piperazine pyrazosulfuron (12+7)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+7% piperazine pyrazosulfuron of humulone+6%+ Fumed silica+5%150# the solvent naphthas of+1.8% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
53rd, the 27% ring pyrrole dispersible oil-suspending agent of fluorine humulone rimsulfuron (24+3)
The NPE of 24%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+3% rimsulfuron of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+1.2% organobentonite of 4% castor oil polyoxyethylene ether+0.5%+oleic acid first Ester is supplied.
54th, the 27% ring pyrrole dispersible oil-suspending agent of fluorine humulone ethoxysulfuron (24+3)
The NPE of 24%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+3% ethoxysulfuron of humulone+6%+ Fumed silica+5%150# the solvent naphthas of+1.0% organobentonite of 4% castor oil polyoxyethylene ether+0.5%+oleic acid first Ester is supplied.
55th, the 17% ring pyrrole dispersible oil-suspending agent of fluorine humulone orthosulfamuron (12+5)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+5% orthosulfamuron of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+1.5% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
56th, the 16% ring pyrrole dispersible oil-suspending agent of fluorine humulone nicosulfuron (12+4)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+4% nicosulfuron of humulone+6%+ Fumed silica+5%150# the solvent naphthas of+1.5% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
57th, the 15% ring pyrrole dispersible oil-suspending agent of fluorine humulone foramsulfuron (12+3)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+3% foramsulfuron of humulone+6%+ Fumed silica+5%150# the solvent naphthas of+1.5% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
58th, the 29% ring pyrrole fluorine humulone fluorine ketone dispersible oil-suspending agent of sulphur grass amine (24+5)
The NPE of+5%+5% calcium dodecyl benzene sulfonate of fluorine ketone sulphur grass amine of 24% ring pyrrole fluorine humulone+6%+ Organobentonite+10%150# the solvent naphthas of 4% castor oil polyoxyethylene ether+0.8%+methyl oleate is supplied.
59th, the 14% ring pyrrole dispersible oil-suspending agent of fluorine humulone penoxsuam (12+2)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+2% penoxsuam of humulone+6%+ Fumed silica+5%150# the solvent naphthas of+1.8% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
60th, the 14% ring pyrrole dispersible oil-suspending agent of fluorine humulone cloransulammethyl (12+2)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+2% cloransulammethyl of humulone+6%+ Fumed silica+5%150# the solvent naphthas of+1.8% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
61st, the 15% ring pyrrole dispersible oil-suspending agent of fluorine humulone imazamox (12+3)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+3% imazamox of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+1.8% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
62nd, the 22% ring pyrrole dispersible oil-suspending agent of fluorine humulone AC 263222 (12+10)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+10% AC 263222 of humulone+6% Fumed silica+5%150# the solvent naphthas of+1.2% organobentonite of+4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
63rd, the 19% ring pyrrole dispersible oil-suspending agent of fluorine humulone imazethapyr (12+7)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine humulone+7%+ imazethapyrs+6% Fumed silica+5%150# the solvent naphthas of+3.0% organobentonite of+4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
64th, 28% ring pyrrole fluorine humulone Arsenal aqua (3+25)
+ 10% AEO of dimethylamine of 3%+25% Arsenal of ring pyrrole fluorine humulone+12%+water is supplied.
65th, the 15% ring pyrrole dispersible oil-suspending agent of fluorine humulone KIH 6127 (12+3)
The NPE+4% of 12%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+3% KIH 6127 of humulone+6% Fumed silica+5%150# the solvent naphthas of the organobentonite of castor oil polyoxyethylene ether+2.0%+1.5%+methyl oleate is mended Foot.
66th, 42% ring pyrrole fluorine humulone trefanocide suspending agent (6+36)
The propylene glycol block polyether dispersant of 6%+5% polycarboxylate dipersant of ring pyrrole fluorine+36% trefanocide of humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of+0.08% xanthans of 1.5% AEO+1.0%+water is supplied.
67th, 33% ring pyrrole fluorine humulone butralin suspending agent (3+30)
The propylene glycol block polyether dispersant of 3%+5% polycarboxylate dipersant of ring pyrrole fluorine+30% butralin of humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of+0.08% xanthans of 1.5% AEO+1.0%+water is supplied.
68th, 46% ring pyrrole fluorine humulone pendimethalin suspension (6+40)
The propylene glycol block polyether of 6%+5% polycarboxylate dipersant of ring pyrrole fluorine+40% pendimethalin of humulone+2% disperses + 5% glycerine of aluminium-magnesium silicate of+0.08% xanthans of the AEO of agent+1.5%+0.8%+water is supplied.
69th, 39% ring pyrrole fluorine humulone Amex820 suspending agent (3+36)
The propylene glycol block polyether dispersant of 3%+5% polycarboxylate dipersant of ring pyrrole fluorine+36% Amex820 of humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 1.5% AEO+1.0%+water is supplied.
70th, 39% ring pyrrole fluorine humulone dithiopyr suspending agent (6+33)
The propylene glycol block polyether of 6%+5% polycarboxylate dipersant of ring pyrrole fluorine+33% dithiopyr of humulone+2% disperses + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of the AEO of agent+1.5%+1.2%+water is supplied.
71st, 38% ring pyrrole fluorine humulone ethalfluralin suspending agent (3+35)
The propylene glycol block polyether point of 3%+5% polycarboxylate dipersant of ring pyrrole fluorine+35% ethalfluralin of humulone+2% + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of the AEO of powder+1.5%+1.2%+water is supplied.
72nd, 28% ring pyrrole fluorine humulone oryzalin suspending agent (3+25)
The propylene glycol block polyether of 3%+5% polycarboxylate dipersant of ring pyrrole fluorine+25% oryzalin of humulone+2% disperses + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the AEO of agent+1.5%+1.6%+water is supplied.
73rd, 35% ring pyrrole fluorine humulone benfluralin suspending agent (6+29)
The propylene glycol block polyether dispersant of 6%+5% polycarboxylate dipersant of ring pyrrole fluorine+29% benfluralin of humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 1.5% AEO+1.6%+water is supplied.
74th, 39% ring pyrrole fluorine humulone thiazopyr suspending agent (6+33)
The propylene glycol block polyether dispersant of 6%+5% polycarboxylate dipersant of ring pyrrole fluorine+33% thiazopyr of humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of 2% AEO+1.6%+water is supplied.
75th, 39% ring pyrrole fluorine humulone pronamide suspending agent (6+33)
The propylene glycol block polyether dispersant of 6%+5% polycarboxylate dipersant of ring pyrrole fluorine+33% pronamide of humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 2% AEO+1.2%+water is supplied.
76th, 53% ring pyrrole fluorine humulone Chlorthal suspension agent (3+50)
The propylene glycol block polyether dispersant of 3%+5% polycarboxylate dipersant of ring pyrrole fluorine+50% chlorthal of humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of+0.05% xanthans of 2% AEO+0.6%+water is supplied.
77th, 58% ring pyrrole fluorine humulone butamifos suspending agent (3+55)
The propylene glycol block polyether dispersant of 3%+5% polycarboxylate dipersant of ring pyrrole fluorine+55% butamifos of humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of+0.04% xanthans of 2% AEO+0.6%+water is supplied.
78th, 36% ring pyrrole fluorine humulone sulphur humulone suspending agent (6+30)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+30% sulphur humulone of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 2% AEO+1.6%+water is supplied.
79th, 21% ring pyrrole fluorine humulone mesotrione suspending agent (12+9)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 12%+9% mesotrione of ring pyrrole fluorine humulone+5% disperses + 5% glycerine of aluminium-magnesium silicate of+0.2% xanthans of the AEO of agent+2%+2.0%+water is supplied.
80th, 18% ring pyrrole fluorine humulone ring sulphur ketone suspending agent (12+6)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+6% ring sulphur ketone of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of 2% AEO+2.0%+water is supplied.
81st, 17% ring pyrrole fluorine humulone furans sulphur humulone suspending agent (12+5)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+5% furans sulphur humulone of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of the AEO of powder+2%+2.0%+water is supplied.
82nd, 29% ring pyrrole fluorine humulone benzobicylon suspending agent (12+17)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+17% benzobicylon of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of powder+2%+1.6%+water is supplied.
83rd, 32% ring pyrrole fluorine humulone lancotrione suspending agents (24+8)
24% ring pyrrole fluorine humulone+8%lancotrione+5% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinities + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of powder+2%+1.6%+water is supplied.
84th, the 11% ring pyrrole fluorine humulone dispersible oil-suspending agent of sulphonyl grass pyrazoles (9+2)
The NPE of+2%+5% calcium dodecyl benzene sulfonate of sulphonyl grass pyrazoles of 9% ring pyrrole fluorine humulone+6%+ Fumed silica+5%150# the solvent naphthas of+2.8% organobentonite of 4% castor oil polyoxyethylene ether+2.8%+oleic acid first Ester is supplied.
85th, 36% ring pyrrole fluorine humulone pyrazolate suspending agent (3+33)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+33% pyrazolate of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 2% AEO+1.5%+water is supplied.
86th, 33% ring pyrrole fluorine humulone benzofenap suspending agent (3+30)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+30% benzofenap of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of 2% AEO+1.5%+water is supplied.
87th, 32% ring pyrrole fluorine humulone tolpyralate suspending agents (12+20)
12% ring pyrrole fluorine humulone+20%tolpyralate+5% phenethyl phenol polyethenoxy ether phosphate triethanolamine salts + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the AEO of dispersant+2%+1.6%+water is supplied.
88th, 32% ring pyrrole fluorine humulone fenquinotrione suspending agents (12+20)
12% ring pyrrole fluorine humulone+20%fenquinotrione+5% phenethyl phenol polyethenoxy ether phosphate triethanolamines + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of dipersant+2%+1.6%+water is supplied.
89th, 18% ring pyrrole fluorine humulone isoxaflutole suspending agent (12+6)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+6% isoxaflutole of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.2% xanthans of the AEO of powder+2%+1.8%+water is supplied.
90th, 31% ring pyrrole fluorine humulone fluorochloridone suspending agent (6+25)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 6%+25% fluorochloridone of ring pyrrole fluorine humulone+5% disperses + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the AEO of agent+2%+1.6%+water is supplied.
91st, 22% ring pyrrole fluorine humulone flurtamone suspending agent (12+10)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+10% flurtamone of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of+2% AEO+2.0%+water is supplied.
92nd, 29% ring pyrrole fluorine humulone beflubutamid suspending agent (12+17)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+17% beflubutamid of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of the AEO of powder+2%+1.5%+water is supplied.
93rd, 40% ring pyrrole fluorine humulone norflurazon suspending agent (3+37)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+37% norflurazon of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of 2% AEO+1.2%+water is supplied.
94th, 52% ring pyrrole fluorine humulone fluridone water dispersible granules (2+50)
The disintegrant of 2%+4% pull open powder of ring pyrrole fluorine humulone+10% polycarboxylic acid salt's dispersant of+50% fluridone+1% gathers The precipitated silica of vinyl alcohol+30%+filler diatomite is supplied.
95th, 49% ring pyrrole fluorine humulone clomazone suspension emulsion (6+43)
The phenethyl phenol polyethenoxy ether phosphate of 6%+43% clomazone+5%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+1.5% phenethyl phenol polyethenoxy ether of triethanolamine dipersant+0.1% Glycerine+water is supplied.96th, 53% ring pyrrole fluorine humulone molinate suspension emulsion (3+50)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+50% molinate of ring pyrrole fluorine humulone+3%+ + 5% glycerine of xanthans of+3% castor oil polyoxyethylene ether of 2% phenethyl phenol polyethenoxy ether+0.06%+water is supplied.
97th, 53% ring pyrrole fluorine humulone benthiocarb suspension emulsion (3+50)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+50% benthiocarb of ring pyrrole fluorine humulone+3%+ + 5% glycerine of xanthans of+3% castor oil polyoxyethylene ether of 1.5% phenethyl phenol polyethenoxy ether+0.05%+water is supplied.
98th, 50% ring pyrrole fluorine humulone benfuresate suspension emulsion (3+47)
The phenethyl phenol polyethenoxy ether phosphate three of 3%+47% benfuresate+8%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+1% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.07% the third three Alcohol+water is supplied.
99th, 30% ring pyrrole fluorine humulone ethofumesate suspension emulsion (3+27)
The phenethyl phenol polyethenoxy ether phosphoric acid of 3%+27% ethofumesate+10%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans of+3% castor oil polyoxyethylene ether of ester triethanolamine+1.5% phenethyl phenol polyethenoxy ether of dipersant+0.1%+ 5% glycerine+water is supplied.
100th, 28% ring pyrrole fluorine humulone tri-allate suspension emulsion (3+25)
The phenethyl phenol polyethenoxy ether phosphate three of 3%+25% tri-allate+10%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+1% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.1% the third three Alcohol+water is supplied.
101st, 35% ring pyrrole fluorine humulone benthiocarb suspension emulsion (3+32)
The phenethyl phenol polyethenoxy ether phosphate three of 3%+32% benthiocarb+8%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.1% the third three Alcohol+water is supplied.
102nd, 61% ring pyrrole fluorine humulone vernolate suspension emulsion (3+58)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+58% vernolate of ring pyrrole fluorine humulone+3%+ + 5% glycerine of xanthans of+3% castor oil polyoxyethylene ether of 1% phenethyl phenol polyethenoxy ether+0.04%+water is supplied.
103rd, the special suspension emulsion (12+20) of 32% ring pyrrole fluorine humulone fourth grass
The phenethyl phenol polyethenoxy ether phosphate of+20% fourth grass spy+10%150# solvent naphthas of 12% ring pyrrole fluorine humulone+3% The xanthans+5% third of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of triethanolamine dipersant+0.12% Triol+water is supplied.
104th, 32% ring pyrrole fluorine humulone cycloate suspension emulsion (12+20)
The phenethyl phenol polyethenoxy ether phosphate of 12%+20% cycloate+10%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans+5% third of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of triethanolamine dipersant+0.12% Triol+water is supplied.105th, 36% ring pyrrole fluorine humulone dimepiperate suspension emulsion (3+33)
The phenethyl phenol polyethenoxy ether phosphate three of 3%+33% dimepiperate+6%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.1% the third three Alcohol+water is supplied.
106th, 35% ring pyrrole fluorine humulone esprocarb suspension emulsion (1.5+33.5)
The phenethyl phenol polyethenoxy ether phosphoric acid of 1.5%+33.5% esprocarb+6%150# solvent naphthas of ring pyrrole fluorine humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of ester triethanolamine+2% phenethyl phenol polyethenoxy ether of dipersant+0.1% Glycerine+water is supplied.107th, 21% ring pyrrole fluorine humulone dichloro quinolinic acid aqua (6+15)
The second of 6%+10% AEO of ring pyrrole fluorine humulone+15% Mono Isopropylamine of+15% dichloro quinolinic acid+20% Glycol+water is supplied.
108th, 30% ring pyrrole fluorine humulone quinmerac aqueous suspension agent (12+18)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+18% quinmerac of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of powder+2%+1.5%+water is supplied.
109th, 13% ring pyrrole fluorine Cao Tong oxaziclomefones suspending agents (9+4)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 9%+4% oxaziclomefone of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.22% xanthans of+2% AEO+1.8%+water is supplied.
110th, 28% ring pyrrole fluorine humulone cinmethylin suspending agent (24+4)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 24%+4% cinmethylin of ring pyrrole fluorine humulone+5% disperses + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of agent+2%+1.4%+water is supplied.
111st, 38% ring pyrrole fluorine humulone sulphosate aqua (1.5+36.5)
+ 15% APG of dimethylamine of 1.5%+36.5% sulphosate of ring pyrrole fluorine humulone+0.5%+water is supplied.
112nd, 30% ring pyrrole fluorine humulone bialaphos aqua (2.25+27.75)
+ 15% AEO of dimethylamine of 2.25%+27.75% bialaphos of ring pyrrole fluorine humulone+1.2%+water Supply.
113rd, 35% ring pyrrole fluorine humulone essence glufosinate-ammoniumaqua aqua (4.5+30.5)
+ 15% APG of the smart dimethylamine of glufosinate-ammonium+5% of 4.5% ring pyrrole fluorine humulone+30.5%+water is supplied.
114th, 45% ring pyrrole fluorine humulone paraquat aqua (4.5+40.5)
+ 15% APG of dimethylamine of 4.5%+40.5% paraquat of ring pyrrole fluorine humulone+5%+water is supplied.
115th, 40% ring pyrrole fluorine humulone diquat dibromide aqua (4.5+35.5)
+ 15% APG of dimethylamine of 4.5%+35.5% diquat dibromide of ring pyrrole fluorine humulone+5%+water is supplied.
116th, 55% ring pyrrole fluorine humulone sulphur grass Lingshui Spring agent (2.25+52.75)
Clever+1.5%+10% AEO of the dimethylamine+water of the sulphur of 2.25% ring pyrrole fluorine humulone+52.75% grass is mended Foot.
117th, 37% ring pyrrole fluorine humulone symetryne suspending agent (6+31)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+31% symetryne of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of 2% AEO+1.4%+water is supplied.
118th, 33% ring pyrrole fluorine humulone amicarbazone suspending agent (12+21)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 12%+21% amicarbazone of ring pyrrole fluorine humulone+5% disperses + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of the AEO of agent+2%+1.5%+water is supplied.
119th, 60% ring pyrrole fluorine humulone metamitron water dispersible granules (2+58)
The disintegrant of 2%+4% pull open powder of ring pyrrole fluorine humulone+10% polycarboxylic acid salt's dispersant of+58% metamitron+1% gathers The precipitated silica of vinyl alcohol+30%+filler diatomite is supplied.
120th, 36% ring pyrrole fluorine humulone diuron suspending agent (6+30)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+30% diuron of ring pyrrole fluorine humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of 2% AEO+1.4%+water is supplied.
121st, 26% ring pyrrole fluorine humulone cyclopyrimorate suspending agents (9+17)
9% ring pyrrole fluorine humulone+17%cyclopyrimorate+5% phenethyl phenol polyethenoxy ether phosphate triethanolamines + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of dipersant+2%+1.6%+water is supplied.
122nd, the 50% ring pyrrole dispersible oil-suspending agent of fluorine humulone pyridate (4.5+44.5)
The NPE of 4.5%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+44.5% pyridate of humulone+8%+ Fumed silica+15%150# the solvent naphthas of+2.8% organobentonite of 6% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
123rd, 36% ring pyrrole fluorine humulone desmedipham suspending agent (4.5+31.5)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 4.5%+31.5% desmedipham of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of the AEO of powder+2%+1.2%+water is supplied.
124th, 36% ring pyrrole fluorine humulone phenmedipham suspending agent (4.5+31.5)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 4.5%+31.5% phenmedipham of ring pyrrole fluorine humulone+5% + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of the AEO of powder+2%+1.2%+water is supplied.
125th, the 26% ring pyrrole dispersible oil-suspending agent of fluorine humulone Thistrol (3+23)
The NPE of 3%+5% calcium dodecyl benzene sulfonate of ring pyrrole fluorine+23%2 mcpb 2 of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.8% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
126th, 20% ring pyrrole fluorine humulone 2, the dispersible oil-suspending agent of 4- Embutoxs (4.5+15.5)
4.5% ring pyrrole fluorine humulone+15.5%2, the polyoxyethylene nonyl phenyl second of+5% calcium dodecyl benzene sulfonate of 4- Embutoxs+6% Fumed silica+10%150# the solvent naphthas of+2.8% organobentonite of+4% castor oil polyoxyethylene ether of alkene ether+2.5%+ Methyl oleate is supplied.
Above-mentioned aqueous suspension agent process equipment:Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned aqueous suspension agent process:By all materials put into mixing kettle in, after being stirred cross colloid mill, it is laggard Enter sand mill three-level sanding, finally sheared in cutter uniformly, after chemical examination is qualified, it is filling to be transferred to storage tank.
Above-mentioned dispersible oil-suspending agent process equipment:Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned dispersible oil-suspending agent process:All materials are put into mixing kettle, colloid mill is crossed after being stirred, Enter sand mill three-level sanding afterwards, finally sheared in cutter uniformly, after chemical examination is qualified, it is filling to be transferred to storage tank.
Above-mentioned aqua process equipment:Mixing kettle, cutter etc..
Above-mentioned aqua process:All materials are put into mixing kettle, are stirred, are sheared afterwards in cutter equal It is even transparent, after chemical examination is qualified, it is filling to be transferred to storage tank.
Above-mentioned water dispersible granules process equipment:Airslide disintegrating mill, coulter type mixer, basket comminutor, drying box, screening Machine etc..
Above-mentioned water dispersible granules process:Above-mentioned material was well mixed air-flow crushing, adds water to enter to mediate granulation, it After dry, final sizing obtains finished product.
Above-mentioned suspension emulsion process equipment:Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned suspension emulsion process:Aqueous phase material is put into mixing kettle, colloid mill is crossed after being stirred, is entered afterwards Sand mill three-level sanding, finally sheared in cutter uniformly, it is standby to chemically examine qualified rear transfer；Oil phase material is put into mixing kettle In, add solvent naphtha and emulsifying agent, stirring and dissolving are uniform；Aqueous phase material is added in cutting kettle afterwards, and under shearing condition, Oil phase material is slowly pumped into cutting kettle, sheared in Chou Liao, continues shearing uniformly, after chemical examination is qualified, is transferred to storage tank filling Dress.B) the test of pesticide effectiveness
After seedling cauline leaf spraying treatment:
1) experimental condition
1.1), for trying target
Alopecurus picks up from Jiangsu Xinghua, and Descurainia sophia picks up from Taian Shandong, and above-mentioned weeds use pot-culture method culture, uses 180 х 140mm plastic nutrition bowls, are placed in enamel tray, built-in that the topsoil (4/5 for backing through and air-drying sieving is adopted from farmland Place), soil moisture controls 20% initial stage, selects the homogeneous weed seed of full seed, is soaked 6 hours with 25 DEG C of warm water, The vernalization in 28 DEG C of biochemical cultivation cases (dark), the weed seed just to have showed money or valuables one carries unintentionally is uniformly placed in soil surface, according to seed Particle size and then earthing 0.5-1cm.
1.2), condition of culture
Carried out in controllable heliogreenhouse, 20~30 DEG C of temperature, natural lighting, relative humidity 57%~72%.Soil class Type is loam, the content of organic matter 1.63%, pH=7.1, alkali-hydrolyzable nitrogen 84.3mg/kg, rapid available phosphorus 38.5mg/kg, available potassium 82.1mg/kg。
1.3), instrument and equipment
3WP-2000 type walking spray towers, Nanjing Agricultural Machinery Inst., Ministry of Agriculture.GA10 type a ten thousandth electronics day Flat (Germany)；ZDR2000 intelligent datas recorder (Hangzhou Ze great Instrument Ltd.)；SPX type Intelligent biochemistry incubators (Ningbo South of the River instrument plant).
2) experimental design
2.1), reagent
Required active component B is bought by Reagent Company, and A produces for our company.
Active compound uses acetone as solvent, is diluted with the aqueous solution of 0.1% emulsifier tween of content -80, current existing dilution.
2.2), test process
2.2.1), dosage is set
It is determined that A and active component B are matched or during contents, should be weighed from the action character of two kinds of medicaments and its virulence etc., It is also contemplated that the main application target of the formula.This research is on the basis of prerun early stage, if A, B activity composition are alone and mix Dosage is shown in Table lattice respectively.Blank control is used as using the water without medicament, containing same solvent and emulsifying agent.
2.2.2), experiment repeats
Often processing is repeated 4 times, and often handles 3 basins every time, and per basin, sowing weed seed 20, often handles totally 60 plants.
2.3), processing mode
2.3.1), processing time and number
Experiment shares medicine 1 time.Treat the leaf phase of weeds 2, thinning, keep 15 plants of weeds in per basin, often processing retains 45 plants, then Continue culture to the heart of 3 leaf of Alopecurus 1, the leaf of Descurainia sophia 3 to be handled.
2.3.2), using apparatus and administrated method
Cultured examination material is uniformly placed in area 0.5m2Platform on, with 3WP-2000 type walking spray tower stems Foliar spray mist, spouting liquid is based on 30 kilograms/hectare.Atomisation pressure 0.3MPa.After whole liquid medicine jets are complete, air valve is closed, after 30 seconds, Spraying pyller is opened, takes out nutritive cube.Then air valve is opened, sprays clear water 50mL, cleans sparge pipe.
3) test method
Using pot-culture method.Weeds culture is shown in 1.1, reference《Farm-chemical indoor determination test rule herbicide》Carry out.With Prescription method is shown in 2.3.2, using cauline leaf process method.Greenhouse cellar culture is moved into after processing, 1-2cm water is remained during experiment Layer.
4) data survey and statistical analysis
4.1), investigation method
Using absolute number investigation method, the survival whole strain seedling of weeds is cut off along soil surface with blade, is weighed with assay balance Weeds fresh weight.It is based on zero by fresh weight for dead weeds.
4.2), control time and number
Investigate within 20 days after processing, investigate 1 time altogether.
4.3), data statistic analysis
The theoretical fresh weight inhibition (E0=X+Y-X*Y/100) of each processing hybrid combining, Ran Houyu are calculated with Gowing methods Actual measurement inhibiting rate (E) compares, the two mixed synergy type to weeds of evaluation, is that synergy is made when E-E0 values are more than 10% With, less than -10% be antagonism, be addition between -10%~10%.It is and special according to actual preventive effect and herbicide The factors such as point, the balance being formulated determine optimum proportioning.X is fresh weight inhibition when active components A dosage is P in formula；Y is work Fresh weight inhibition when property composition B dosages are Q.
Closed soil treatment:
1) experimental condition
1.1), for trying target
Alopecurus, ox chickweed pick up from Jiangsu Xinghua, and Descurainia sophia picks up from Taian Shandong.
1.2), condition of culture
Carried out in controllable heliogreenhouse, 20~30 DEG C of temperature, natural lighting, relative humidity 57%~72%.Soil class Type is loam, the content of organic matter 1.63%, pH=7.1, alkali-hydrolyzable nitrogen 84.3mg/kg, rapid available phosphorus 38.5mg/kg, available potassium 82.1mg/kg.Experiment soil is quantitatively filled at the 3/4 of basin alms bowl, is then poured from basin alms bowl bottom, soil is moistened completely to saturation State.Pretreatment is broadcasted sowing into surface for examination weed seed, equal and quantitative, according to seed size earthing 0.5-2cm, after planting 24 Hour is standby.
1.3), instrument and equipment
GA10 type a ten thousandth electronic balances (Germany)；ZDR2000 intelligent datas recorder (the limited public affairs of the big instrument in Hangzhou pool Department)；SPX type Intelligent biochemistries incubator (Ningbo south of the River instrument plant), pipettor etc..
2) experimental design
2.1), reagent
Required active component B is commercially available active compound, and A produces for our company.
Active compound uses acetone as solvent, is diluted with the emulsifying agent T-80 aqueous solution of content 0.1%, current existing dilution.
2.2), test process
2.2.1), dosage is set
, should be from the action character of two kinds of medicaments and its virulence etc. it is determined that when A and active component B each groups distribution ratio or content Weigh, it is also contemplated that the main application target of the formula.This research is on the basis of prerun early stage, if A, B activity composition are alone And mixing dosage is shown in Table lattice respectively.Blank control is used as using the water without medicament, containing same solvent and emulsifying agent.
2.2.2), experiment repeats
Often processing is repeated 4 times, and often handles 3 basins every time, the sowing weed seed 30 per basin.
2) test method
Before processing is poured, and keeps 1-2cm water layers.Quantitative liquid medicine is taken with pipettor, according to experimental design from low dosage to height Dosage carries out pouring processing, 4 repetitions per treatment respectively；Greenhouse cellar culture is moved into after processing, is remained during experiment 1-2cm water layers.
3) data survey and statistical analysis
It is identical with after seedling cauline leaf spraying treatment, therefore repeat no more.
Statistical result see the table below 1-125.
The A of table 1 is with butachlor mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 2 is with ethiozin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 3 is with anilofos mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 4 is with xylenol grass amine mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 5 is with fentrazamide mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 6 and three azole amide mixtures are to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 7 is with cafenstrole mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 8 is with piperophos mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 9 is with metazachlor mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 10 is with propachlor mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 11 is with pethoxamid mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 12 is with Oxyfluorfen mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 13 is with fomesafen mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A Yu Evil humulones mixtures of table 14 are to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 15 is with oxadiargyl mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 16 is with sulfentrazone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 17 is with pyraclonil mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 18 is with flumioxazin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 19 is with Huan Wu Evil humulones mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 20 is with tiafenacil mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 21 is with benzene flumetsulam mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 22 is with atrazine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 23 is with Garagard mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 24 is with ametryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 25 is with dipropetryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 26 is with the net mixture of evil grass to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 27 is with desmetryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 28 is with Simanex mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 29 is with cyanazine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 30 is with fluometuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 31 is with linuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 32 is with tebuthiuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 33 flutters grand mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment) with Sha
The A of table 34 is with afesin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 35 is with metobromuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 36 is with neburea mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 37 is with alcohol pyridazines mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 38 is with hexazinone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 39 is with dimethametryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 40 is with trietazine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 41 is with bromacil mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 42 is with lenacil mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 43 is with terbacil mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 44 is with methabenzthiazuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 45 is with Tupersan mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A grand mixtures of Yu Yi Evil of table 46 are to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 47 is with metoxuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 48 is with chloroxifenidium mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 49 is with pyrazosulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 50 is with the grand mixture of thiophene ketone sulphur to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 51 is with promazine Sulfometuron Methyl mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 52 is with piperazine pyrazosulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 53 is with rimsulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 54 is with ethoxysulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 55 is with orthosulfamuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 56 is with nicosulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 57 is with foramsulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 58 is with fluorine ketone sulphur grass amine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 59 is with penoxsuam mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 60 is with cloransulammethyl mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 61 is with imazamox mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 62 is with AC 263222 mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 63 is with imazethapyr mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 64 is with Arsenal mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 65 is with KIH 6127 mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 66 is with trefanocide mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 67 is with butralin mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 68 is with pendimethalin mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 69 is with Amex820 mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 70 is with dithiopyr mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 71 is with ethalfluralin mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 72 is with oryzalin mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 73 is with benfluralin mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 74 is with thiazopyr mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 75 is with pronamide mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 76 is with chlorthal mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 77 is with butamifos mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 78 is with sulphur humulone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 79 is with mesotrione mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 80 is with ring sulphur ketone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 81 is with furans sulphur humulone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 82 is with benzobicylon mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 83 is with lancotrione mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 84 is with sulphonyl grass pyrazoles mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 85 is with pyrazolate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 86 is with benzofenap mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 87 is with tolpyralate mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 88 is with fenquinotrione mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A Yu isoxaflutoles mixtures of table 89 are to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 90 is with fluorochloridone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 91 is with flurtamone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 92 is with beflubutamid mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 93 is with norflurazon mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 94 is with fluridone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A Yu clomazones mixtures of table 95 are to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 96 is with molinate mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 97 is with benthiocarb mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 98 is with benfuresate mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 99 is with ethofumesate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 100 is with tri-allate mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 101 is with benthiocarb mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 102 is with vernolate mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 103 is with the special mixture of fourth grass to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 104 is with cycloate mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 105 is with dimepiperate mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 106 is with esprocarb mixture to the actual preventive effect of Alopecurus and synergy evaluation (soil treatment)
The A of table 107 is with dichloro quinolinic acid mixture to the actual preventive effect of ox chickweed and synergy evaluation (soil treatment)
The A of table 108 is with quinmerac mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A Yu oxaziclomefones mixtures of table 109 are to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 110 is with cinmethylin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 111 is with sulphosate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 112 is with bialaphos mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 113 is with smart glufosinate-ammonium mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 114 is with paraquat mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 115 is with diquat dibromide mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 116 is with the clever mixture of sulphur grass to the actual preventive effect of Alopecurus and synergy evaluation (cauline leaf process)
The A of table 117 is with symetryne mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 118 is with amicarbazone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 119 is with metamitron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 120 is with diuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The A of table 121 is with cyclopyrimorate mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 122 is with pyridate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 123 is with desmedipham mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 124 is with phenmedipham mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 125 is with Thistrol mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
The A of table 126 is with 2,4- Embutoxs mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
C) field demonstration
Utilize embodiment 1) -126) made from herbicidal composition carry out weeds in field effect test.
Exemplary promote is carried out in Jiangsu Xinghua testing site within 2016 to test.The weeds that field occurs mainly have:Shepherd's purse, ox Chickweed, Veronica, clearvers, Alopecurus, amur foxtail, Wang grass etc..
Test method:
Soil treatment:Before weeds germinate, hand sprayer, 45 kilograms/667m of the amount of being watered2, it is uniform using soil surface Spraying.
Cauline leaf process:Treat that weeds are in 3-4 leaf phases, hand sprayer, 30 kilograms/667m of the amount of being watered2, sprayed using cauline leaf Even spraying.
Specific test medicine and dosage refer to table 127,50 square metres of plot area, and often processing is repeated 4 times.45 days after dispenser Investigation preventive effect is shown in Table 127.
By lot of experiments and exploration, it is an unexpected discovery of the invention that the composition is used to prevent and kill off shepherd's purse, ox chickweed, mother-in-law The weeds such as procumbent speedwell, clearvers, Alopecurus, amur foxtail, Wang grass, Descurainia sophia, there is surprising, unexpected synergy Effect, this synergistic effect show more notable under low dosage, can reduce dosage, reduce the pollution to environment, and rationally Compounding reduces agricultural cost, efficient to ALS, ACCase inhibitor resistant weed, has good application prospect.Pass through simultaneously Test is in wheat paddock, corn field, rice terrace, peanut, sugarcane, sorghum, millet, potato, rape, soybean, cotton, vegetables, morning The lawns such as ripe standing grain, Festuca Arundinacea, Korea lawn grass and crop show good selectivity and excellent synergistic effect, can develop into extensive The herbicide combination product of market value.
The field demonstration effect situation of complex composition described in table 127

Claims (10)

1. a kind of Herbicidal combinations of the fluorine of pyrrole containing ring humulone, it is characterised in that active components A and activity including herbicidally effective amount Composition B, wherein, active components A is ring pyrrole fluorine humulone, and active component B may be selected from the one or more of following compound：
1) VLCFA inhibitor class：Butachlor, anilofos, xylenol grass amine, fentrazamide, three azole amides, cafenstrole, piperazine Careless phosphorus, metazachlor, propachlor, pethoxamid；
2) PPO inhibitor class：Oxyfluorfen, fomesafen, Evil humulones, oxadiargyl, sulfentrazone, pyraclonil, Flumioxazin, Huan Wu Evil humulones, tiafenacil, benzene flumetsulam；
3) PSII inhibitor class：Atrazine, Garagard, ametryn, dipropetryn, evil grass are net, desmetryn, Simanex, cyanazine, fluorine The grand, linuron of grass, tebuthiuron, Sha flutter grand, afesin, metobromuron, neburea, alcohol pyridazines, hexazinone, dimethametryn, trietazine, Bromacil, lenacil, terbacil, methabenzthiazuron, Tupersan, Yi Evil are grand, metoxuron, chloroxifenidium, cyclopyrimorate, Pyridate, desmedipham, phenmedipham, symetryne, diuron, amicarbazone, metamitron, ethiozin；
4) ALS inhibitor class：Pyrazosulfuron, thiophene ketone sulphur are grand, promazine Sulfometuron Methyl, piperazine pyrazosulfuron, rimsulfuron, ethoxysulfuron, Orthosulfamuron, nicosulfuron, foramsulfuron, fluorine ketone sulphur grass amine, penoxsuam, cloransulammethyl, imazamox, first Imazapyr, imazethapyr, Arsenal, KIH 6127；
5) microtubules inhibitor class：Trefanocide, butralin, pendimethalin, Amex820, dithiopyr, ethalfluralin, ammonia sulphur Happy spirit, benfluralin, thiazopyr, pronamide, chlorthal, butamifos；
6) HPPD inhibitor class：Sulphur humulone, mesotrione, ring sulphur ketone, furans sulphur humulone, benzobicylon, lancotrione, Sulphonyl grass pyrazoles, pyrazolate, benzofenap, tolpyralate, fenquinotrione, isoxaflutoles；
7) PDS inhibitor class：Fluorochloridone, flurtamone, beflubutamid, norflurazon, fluridone；
8) DOXP inhibitor class：Clomazone；
9) lipid synthesis (non-acetyl-CoA carboxylase) inhibitor class：Molinate, benthiocarb, benfuresate, ethofumesate, open country Mai Wei, benthiocarb, vernolate, Ding Caote, cycloate, dimepiperate, esprocarb；
10) synthetic hormone class：Dichloro quinolinic acid, quinmerac, Thistrol, 2,4- Embutoxs；
11) EPSPS inhibitor class：Sulphosate；
12) GS inhibitor class：Bialaphos, smart glufosinate-ammonium；
13) PSI inhibitor class：Paraquat, diquat dibromide；
14) DHP inhibitor class：Sulphur grass spirit；
15) other：Oxaziclomefone, cinmethylin.
A kind of 2. Herbicidal combinations of the fluorine of pyrrole containing ring humulone according to claim 1, it is characterised in that A and B weight ratio For 1:200-200:1, preferably 1:150-150:1.
A kind of 3. Herbicidal combinations of the fluorine of pyrrole containing ring humulone according to claim 2, it is characterised in that A and B weight ratio For 1:100-100:1, preferably 1:50-50:1.
A kind of 4. Herbicidal combinations of the fluorine of pyrrole containing ring humulone according to claim 3, it is characterised in that A and B weight ratio For 1:30-30:1, preferably 1:10-10:1.
A kind of 5. Herbicidal combinations of the fluorine of pyrrole containing ring humulone according to Claims 1-4 any one, it is characterised in that A and B weight/mass percentage composition accounts for the 1-95% of total amount in the Herbicidal combinations.
A kind of 6. Herbicidal combinations of the fluorine of pyrrole containing ring humulone according to claim 5, it is characterised in that the Herbicidal combination A and B weight/mass percentage composition accounts for the 10-80% of total amount in thing.
A kind of 7. Herbicidal combinations of the fluorine of pyrrole containing ring humulone according to claim 1 to 6 any one, it is characterised in that Also include carrier, surfactant in the Herbicidal combinations.
A kind of 8. Herbicidal combinations of the fluorine of pyrrole containing ring humulone according to claim 1 to 6 any one, it is characterised in that The specific preparation of the Herbicidal combinations is dispersible oil-suspending agent, aqueous suspension agent, suspension emulsion, wettable powder, missible oil, moisture Shot agent, aqueous emulsion or microemulsion.
A kind of 9. Herbicidal combinations of the fluorine of pyrrole containing ring humulone according to claim 1 to 6 any one, it is characterised in that The Herbicidal combinations further comprise safener, and it is selected from isoxadifen, cyprosulfamide, mefenpyrdiethyl, solution One or more in malicious quinoline, gibberellic acid, furilazole, metcamifen.
10. the Herbicidal combinations of the fluorine of pyrrole containing ring humulone injurious weed in crop is prevented and treated as described in claim 1 to 9 any one On application.
CN201711095778.5A 2017-11-09 2017-11-09 A kind of Herbicidal combinations of the fluorine of pyrrole containing ring humulone and its application Pending CN107810963A (en)

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CN111362919B (en) * 2018-12-25 2021-03-12 青岛清原化合物有限公司 Cyclopyraflutole dimethylamine salt D crystal form and preparation method and application thereof
CN111362909B (en) * 2018-12-25 2021-03-12 青岛清原化合物有限公司 Cypridinafulone dimethylamine salt C crystal form and preparation method and application thereof
CN111362912B (en) * 2018-12-25 2021-03-12 青岛清原化合物有限公司 Cyclopyraflutole triethanolamine salt and preparation method and application thereof
CN111362915B (en) * 2018-12-25 2021-03-12 青岛清原化合物有限公司 Cyclopyraflutole-isopropylamine salt and preparation method and application thereof
CN111362914B (en) * 2018-12-25 2021-03-12 青岛清原化合物有限公司 Cyclopyraflutole triethanolamine salt crystal form B and preparation method and application thereof
WO2020133020A1 (en) * 2018-12-25 2020-07-02 青岛清原化合物有限公司 Cypyrafluone dimethylamine salt c crystal form, preparation method therefor and use thereof
WO2020133012A1 (en) * 2018-12-25 2020-07-02 青岛清原化合物有限公司 Cypyrafluone monoisopropylamine salt and preparation method and use thereof
WO2022068377A1 (en) * 2020-09-30 2022-04-07 青岛清原化合物有限公司 Binary herbicidal composition and use thereof

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