CN107311539A - Building waste baking-free brick and preparation method thereof - Google Patents

Building waste baking-free brick and preparation method thereof Download PDF

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Publication number
CN107311539A
CN107311539A CN201710544179.0A CN201710544179A CN107311539A CN 107311539 A CN107311539 A CN 107311539A CN 201710544179 A CN201710544179 A CN 201710544179A CN 107311539 A CN107311539 A CN 107311539A
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Prior art keywords
parts
building waste
burning brick
waste
building
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710544179.0A
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Chinese (zh)
Inventor
汪知明
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Hefei Yipianmei Environmental Protection Technology Co ltd
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Hefei Yipianmei Environmental Protection Technology Co ltd
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Priority to CN201710544179.0A priority Critical patent/CN107311539A/en
Publication of CN107311539A publication Critical patent/CN107311539A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/245Curing concrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C5/00Apparatus or methods for producing mixtures of cement with other substances, e.g. slurries, mortars, porous or fibrous compositions
    • B28C5/08Apparatus or methods for producing mixtures of cement with other substances, e.g. slurries, mortars, porous or fibrous compositions using driven mechanical means affecting the mixing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention belongs to the technical field of energy-saving building materials, and provides a building garbage baking-free brick and a preparation method thereof, wherein the building garbage baking-free brick comprises the following raw materials in parts by weight: 20-25 parts of basalt powder, 16-29 parts of glass powder, 25-46 parts of arsenopyrite, 15-28 parts of construction waste, 1-3 parts of activated clay waste residue, 5-11 parts of vermiculite, 9-14 parts of bauxite fine powder, 11-15 parts of cement, 1-6 parts of calcium oxide, 2-5 parts of a stabilizer and 1-2 parts of a gelling agent. The invention aims to provide a building garbage baking-free brick and a preparation method thereof, and the building garbage baking-free brick solves the problem that the strength, heat preservation, energy conservation and other properties of the existing baking-free brick can not meet the requirements of modern industrial development.

Description

A kind of building waste is non-burning brick and preparation method thereof
Technical field
The invention belongs to energy saving building material technical field, specifically, a kind of building waste is non-burning brick and preparation method thereof.
Background technology
A kind of novel wall material manufactured through high-temperature calcination is referred to as non-burning brick.The product meets China's " protection
Farmland, save the energy, suit measures to local conditions, gather materials on the spot " development building materials general policy.With the continuous depth of policies of reform and opening to the outside world Change, market economy is continued to develop, and urban construction is developed rapidly, all kinds of municipal works, public utility, skyscraper is civilian to build Build, Comfortable Housing Project is rised sheer from level ground, it would be desirable to a large amount of novel wall materials.But the property such as existing non-burning brick intensity, insulation, energy-conservation It can not all meet the demand of development of modern industry.
The content of the invention
For defect of the prior art, it is an object of the invention to provide a kind of building waste is non-burning brick and preparation method. The non-burning brick performances such as current non-burning brick intensity, insulation, energy-conservation that overcome of the building waste can not all meet development of modern industry Demand the problem of.
A kind of building waste provided according to an aspect of the present invention is non-burning brick, and described building waste is non-burning brick including as follows The raw material of parts by weight:20-25 parts of basalt powder, 16-29 parts of glass dust, 25-46 parts of feldspathic sandstone, 15-28 parts of building waste, work 1-3 parts of carclazyte waste residue of property, 5-11 parts of vermiculite, 9-14 parts of alumine fine powder, 11-15 parts of cement, 1-6 parts of calcium oxide, stabilizer 2-5 parts, 1-2 parts of gelling agent.
Preferably, the building waste be yellow ground, stone, block stone, dregs, steel scrap muscle, waste iron wire, various steel scrap accessories, Metal pipe line waste material, useless bamboo wood, wood chip, the mixture of wood shavings.
Preferably, the building waste acidified processing in advance.
Preferably, the specific method of the acidification is:
(1)First building waste is input in mixer and stirred, then the sulfuric acid solution that concentration is 10-15% is slowly added to building Immersion 2-4h is carried out in rubbish;
(2)Building waste mixture after acidification is squeezed into building waste particle by twin rollers so that building waste Particle diameter≤1mm of particle;
(3)Building waste particle is transported in swinging drying oven and is calcined, roasting time is 1-3h, sintering temperature control exists 260-320 DEG C, building waste particle water content≤3% after roasting, you can.
Preferably, the step(1)The percentage by weight of middle building waste and sulfuric acid solution is respectively:Building waste 85- 94% and dilute sulfuric acid 6-15%.
Preferably, the gelling agent includes the composition of following percentage by weight:Portland cement 25-40%, lime 23-30%, magnesium sulfate 18-30%, sodium metasilicate 15-20%.
Preferably, the lime composition is made up of calcium oxide and calcium hydroxide.
According to another aspect of the present invention there is provided a kind of non-burning brick preparation method of building waste, methods described includes as follows Step:
(1)It is thin that basalt powder, glass dust, feldspathic sandstone, building waste, active white clay waste slag, vermiculite, alumine are weighed in proportion The mixed-powder of 210-240 mesh is ground into after powder, cement, calcium oxide, mixing, appropriate water is then added, with 260r/min speed Degree stirring 30min;
(2)To(1)Middle addition stabilizer, gelling agent mixing, add suitable quantity of water and mixed slurry are made, be then fed into block machine Middle to be suppressed, briquetting pressure control is for 18MPa;
(3)Watering maintenance 3-6 days under the conditions of product after shaping is placed at 28 DEG C, you can.
Compared with prior art, the present invention has following beneficial effect:
(1)A kind of building waste that the present invention is provided is non-burning brick, using building waste as primary raw material, adds gelling agent and other are auxiliary Co-ingredients, and by the preparation method of the present invention so for preparing is non-burning brick with stronger compression strength, and relatively low leads Hot coefficient, and substantial amounts of building waste is recycled, environmental pollution and the wasting of resources are reduced, energy-saving ring is realized Protect production;
(2)Gelling agent used in the present invention, cementation is strong, have a wide range of application, and uses it for manufacture non-burning brick so that non-burning brick Compression strength, wearability, frost resistance be all improved, the cement usage amount of concrete reduces percent than normal concrete More than 20, positive effect is served to environmental protection, and because the incorporation of cement is few, significantly reduce labour cost with And production cost, and save great lot of water resources;Non-burning brick, the daily people without traditional approach being made of the gelling agent Work watering maintenance, you can reach the hardness of general concrete, save maintenance cost and human cost;And use the multipurpose Concrete gelling agent, after addition building waste, you can turn waste into wealth, environmental protection;
(3)After the acidified calcination process of building waste of the present invention, pH value is controlled in 5.5-7.0, can improve building waste Utilization rate, can not only bring good economic benefit, environmental benefit and social benefit, and can realize and turn waste into wealth.After acidifying The preferable laxity of building waste, adsorptivity, thixotropy, plasticity and the characteristics of caking property.Building waste after acidifying is also Suitable for production Nutrition Soil, environment-friendly materials and Landscape Material.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention Rather than limitation the scope of the present invention.
Embodiment 1
A kind of building waste that the present embodiment is provided is non-burning brick, and described building waste is non-burning brick to include the original of following parts by weight Material:23 parts of basalt powder, 18 parts of glass dust, 28 parts of feldspathic sandstone, 23 parts of building waste, 2 parts of active white clay waste slag, 7 parts of vermiculite, height 12 parts of bauxite fine powder, 14 parts of cement, 3 parts of calcium oxide, 4 parts of stabilizer, 1 part of gelling agent.Wherein, the gelling agent includes as follows The composition of percentage by weight:Portland cement 30%, lime 26%, magnesium sulfate 21%, sodium metasilicate 170%.Wherein, it is described Lime composition is made up of calcium oxide and calcium hydroxide.
Wherein, the building waste is yellow ground, stone, block stone, dregs, steel scrap muscle, waste iron wire, various steel scrap accessories, gold Belong to pipeline waste material, useless bamboo wood, wood chip, the mixture of wood shavings.The building waste acidified processing in advance.The acidification Specific method be:
(1)First building waste is input in mixer and stirred, then the sulfuric acid solution that concentration is 13% is slowly added to building waste Middle progress immersion 3h, the percentage by weight of middle building waste and sulfuric acid solution is respectively:Building waste 88% and dilute sulfuric acid 7%;
(2)Building waste mixture after acidification is squeezed into building waste particle by twin rollers so that building waste Particle diameter≤1mm of particle;
(3)Building waste particle is transported in swinging drying oven and is calcined, roasting time is 2h, sintering temperature is controlled 290 DEG C, building waste particle water content≤3% after roasting, you can.
According to another aspect of the present invention there is provided a kind of non-burning brick preparation method of building waste, methods described includes as follows Step:
(1)It is thin that basalt powder, glass dust, feldspathic sandstone, building waste, active white clay waste slag, vermiculite, alumine are weighed in proportion The mixed-powder of 230 mesh is ground into after powder, cement, calcium oxide, mixing, appropriate water is then added, is stirred with 260r/min speed Mix 30min;
(2)To(1)Middle addition stabilizer, gelling agent mixing, add suitable quantity of water and mixed slurry are made, be then fed into block machine Middle to be suppressed, briquetting pressure control is for 18MPa;
(3)Watering maintenance 5 days under the conditions of product after shaping is placed at 28 DEG C, you can.
Embodiment 2
A kind of building waste that the present embodiment is provided is non-burning brick, and described building waste is non-burning brick to include the original of following parts by weight Material:25 parts of basalt powder, 16 parts of glass dust, 46 parts of feldspathic sandstone, 15 parts of building waste, 3 parts of active white clay waste slag, 5 parts of vermiculite, height 14 parts of bauxite fine powder, 11 parts of cement, 6 parts of calcium oxide, 2 parts of stabilizer, 2 parts of gelling agent.Wherein, the gelling agent includes as follows The composition of percentage by weight:Portland cement 25%, lime 30%, magnesium sulfate 18%, sodium metasilicate 20%.Wherein, the stone Ash component is made up of calcium oxide and calcium hydroxide.
Wherein, the building waste is yellow ground, stone, block stone, dregs, steel scrap muscle, waste iron wire, various steel scrap accessories, gold Belong to pipeline waste material, useless bamboo wood, wood chip, the mixture of wood shavings.The building waste acidified processing in advance.The acidification Specific method be:
(1)First building waste is input in mixer and stirred, then the sulfuric acid solution that concentration is 15% is slowly added to building waste Middle progress immersion 2h, the percentage by weight of middle building waste and sulfuric acid solution is respectively:Building waste 94% and dilute sulfuric acid 6%;
(2)Building waste mixture after acidification is squeezed into building waste particle by twin rollers so that building waste Particle diameter≤1mm of particle;
(3)Building waste particle is transported in swinging drying oven and is calcined, roasting time is 3h, sintering temperature is controlled 260 DEG C, building waste particle water content≤3% after roasting, you can.
According to another aspect of the present invention there is provided a kind of non-burning brick preparation method of building waste, methods described includes as follows Step:
(1)It is thin that basalt powder, glass dust, feldspathic sandstone, building waste, active white clay waste slag, vermiculite, alumine are weighed in proportion The mixed-powder of 240 mesh is ground into after powder, cement, calcium oxide, mixing, appropriate water is then added, is stirred with 260r/min speed Mix 30min;
(2)To(1)Middle addition stabilizer, gelling agent mixing, add suitable quantity of water and mixed slurry are made, be then fed into block machine Middle to be suppressed, briquetting pressure control is for 18MPa;
(3)Watering maintenance 3 days under the conditions of product after shaping is placed at 28 DEG C, you can.
Embodiment 3
A kind of building waste that the present embodiment is provided is non-burning brick, and described building waste is non-burning brick to include the original of following parts by weight Material:20 parts of basalt powder, 29 parts of glass dust, 25 parts of feldspathic sandstone, 28 parts of building waste, 1 part of active white clay waste slag, 11 parts of vermiculite, 9 parts of alumine fine powder, 15 parts of cement, 1 part of calcium oxide, 5 parts of stabilizer, 1 part of gelling agent.Wherein, the gelling agent is included such as The composition of lower percentage by weight:Portland cement 40%, lime 23%, magnesium sulfate 30%, sodium metasilicate 15%.Wherein, it is described Lime composition is made up of calcium oxide and calcium hydroxide.
Wherein, the building waste is yellow ground, stone, block stone, dregs, steel scrap muscle, waste iron wire, various steel scrap accessories, gold Belong to pipeline waste material, useless bamboo wood, wood chip, the mixture of wood shavings.The building waste acidified processing in advance.The acidification Specific method be:
(1)First building waste is input in mixer and stirred, then the sulfuric acid solution that concentration is 10% is slowly added to building waste Middle progress immersion 4h, the percentage by weight of middle building waste and sulfuric acid solution is respectively:Building waste 85% and dilute sulfuric acid 15%;
(2)Building waste mixture after acidification is squeezed into building waste particle by twin rollers so that building waste Particle diameter≤1mm of particle;
(3)Building waste particle is transported in swinging drying oven and is calcined, roasting time is 1h, sintering temperature is controlled 320 DEG C, building waste particle water content≤3% after roasting, you can.
According to another aspect of the present invention there is provided a kind of non-burning brick preparation method of building waste, methods described includes as follows Step:
(1)It is thin that basalt powder, glass dust, feldspathic sandstone, building waste, active white clay waste slag, vermiculite, alumine are weighed in proportion The mixed-powder of 210 mesh is ground into after powder, cement, calcium oxide, mixing, appropriate water is then added, is stirred with 260r/min speed Mix 30min;
(2)To(1)Middle addition stabilizer, gelling agent mixing, add suitable quantity of water and mixed slurry are made, be then fed into block machine Middle to be suppressed, briquetting pressure control is for 18MPa;
(3)Watering maintenance 6 days under the conditions of product after shaping is placed at 28 DEG C, you can.
Experiment test:
According to the raw material and proportioning described in embodiment 1-3, it is non-burning brick to prepare building waste, is divided into 1 group, 2 groups, 3 groups, takes commercially available general It is logical it is non-burning brick be control group, test the performance of above-mentioned each group, test result is shown in Table 1.
The test result list of table 1
Index 1 group 2 groups 3 groups Control group
Compression strength(28d)MPa 32.7 34.1 33.9 17.3
Thermal conductivity factor(W/m ﹒ k) 0.021 0.022 0.024 0.036
Consumption of raw materials slip(%) 42 40 37 0
Use water slip(%) 51 54 57 0
As can be seen here, the building waste that the present invention is provided is non-burning brick, with preferable intensity, insulation, the performance such as energy-conservation.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow Ring the substantive content of the present invention.

Claims (8)

1. a kind of building waste is non-burning brick, it is characterised in that:Described building waste is non-burning brick to include the original of following parts by weight Material:20-25 parts of basalt powder, 16-29 parts of glass dust, 25-46 parts of feldspathic sandstone, 15-28 parts of building waste, active white clay waste slag 1- 3 parts, 5-11 parts of vermiculite, 9-14 parts of alumine fine powder, 11-15 parts of cement, 1-6 parts of calcium oxide, 2-5 parts of stabilizer, gelling agent 1-2 parts.
2. a kind of building waste according to claim 1 is non-burning brick, it is characterised in that:The building waste is yellow ground, stone Son, block stone, dregs, steel scrap muscle, waste iron wire, various steel scrap accessories, metal pipe line waste material, useless bamboo wood, wood chip, the mixing of wood shavings Thing.
3. a kind of building waste according to claim 2 is non-burning brick, it is characterised in that:The building waste first passes through acid in advance Change is handled.
4. a kind of building waste according to claim 3 is non-burning brick, it is characterised in that:The specific method of the acidification For:
(1)First building waste is input in mixer and stirred, then the sulfuric acid solution that concentration is 10-15% is slowly added to building Immersion 2-4h is carried out in rubbish;
(2)Building waste mixture after acidification is squeezed into building waste particle by twin rollers so that building waste Particle diameter≤1mm of particle;
(3)Building waste particle is transported in swinging drying oven and is calcined, roasting time is 1-3h, sintering temperature control exists 260-320 DEG C, building waste particle water content≤3% after roasting, you can.
5. a kind of building waste according to claim 4 is non-burning brick, it is characterised in that:The step(1)Middle building waste Percentage by weight with sulfuric acid solution is respectively:Building waste 85-94% and dilute sulfuric acid 6-15%.
6. a kind of building waste according to claim 1 is non-burning brick, it is characterised in that:The gelling agent includes following weight The composition of percentage:Portland cement 25-40%, lime 23-30%, magnesium sulfate 18-30%, sodium metasilicate 15-20%.
7. a kind of building waste according to claim 6 is non-burning brick, it is characterised in that:The lime composition by calcium oxide and Calcium hydroxide is constituted.
8. a kind of non-burning brick preparation method of building waste as described in claim any one of 1-7, it is characterised in that:Including such as Lower step:
(1)It is thin that basalt powder, glass dust, feldspathic sandstone, building waste, active white clay waste slag, vermiculite, alumine are weighed in proportion The mixed-powder of 210-240 mesh is ground into after powder, cement, calcium oxide, mixing, appropriate water is then added, with 260r/min speed Degree stirring 30min;
(2)To(1)Middle addition stabilizer, gelling agent mixing, add suitable quantity of water and mixed slurry are made, be then fed into block machine Middle to be suppressed, briquetting pressure control is for 18MPa;
(3)Watering maintenance 3-6 days under the conditions of product after shaping is placed at 28 DEG C, you can.
CN201710544179.0A 2017-07-05 2017-07-05 Building waste baking-free brick and preparation method thereof Withdrawn CN107311539A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108383462A (en) * 2018-04-18 2018-08-10 肥西县碧涛建材有限公司 A kind of building material and preparation method thereof handled using microbial mineralization
CN108395166A (en) * 2018-05-18 2018-08-14 李志科 A kind of building waste is non-burning brick and its manufacturing method
CN108975844A (en) * 2018-07-17 2018-12-11 定远县双远新型建筑材料厂 A kind of environmentally protective non-burning brick and its manufacturing process
CN111847945A (en) * 2020-07-29 2020-10-30 广东通兴再生资源科技有限公司 Construction waste recycling method
CN111875350A (en) * 2020-07-28 2020-11-03 安徽恒创环保建材有限公司 Building brick prepared from building garbage and manufacturing method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101088958A (en) * 2006-06-12 2007-12-19 刘贵堂 Heat insulating brick and its production process
CN101747007A (en) * 2009-12-24 2010-06-23 刘兆 Baking-free brick made from renewable material of building waste
CN105461248A (en) * 2015-11-20 2016-04-06 广西壮族自治区水利科学研究院 A modifying method of a recycled aggregate and modified-recycled-aggregate concrete

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101088958A (en) * 2006-06-12 2007-12-19 刘贵堂 Heat insulating brick and its production process
CN101747007A (en) * 2009-12-24 2010-06-23 刘兆 Baking-free brick made from renewable material of building waste
CN105461248A (en) * 2015-11-20 2016-04-06 广西壮族自治区水利科学研究院 A modifying method of a recycled aggregate and modified-recycled-aggregate concrete

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108383462A (en) * 2018-04-18 2018-08-10 肥西县碧涛建材有限公司 A kind of building material and preparation method thereof handled using microbial mineralization
CN108395166A (en) * 2018-05-18 2018-08-14 李志科 A kind of building waste is non-burning brick and its manufacturing method
CN108975844A (en) * 2018-07-17 2018-12-11 定远县双远新型建筑材料厂 A kind of environmentally protective non-burning brick and its manufacturing process
CN111875350A (en) * 2020-07-28 2020-11-03 安徽恒创环保建材有限公司 Building brick prepared from building garbage and manufacturing method thereof
CN111847945A (en) * 2020-07-29 2020-10-30 广东通兴再生资源科技有限公司 Construction waste recycling method

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Application publication date: 20171103