CN107117909A - It is a kind of mixed with RPC of flyash and preparation method thereof - Google Patents

It is a kind of mixed with RPC of flyash and preparation method thereof Download PDF

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Publication number
CN107117909A
CN107117909A CN201710527271.6A CN201710527271A CN107117909A CN 107117909 A CN107117909 A CN 107117909A CN 201710527271 A CN201710527271 A CN 201710527271A CN 107117909 A CN107117909 A CN 107117909A
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flyash
water
cement
rpc
steel fibre
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CN201710527271.6A
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CN107117909B (en
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付强
万冬伟
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Guilin University of Technology
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Guilin University of Technology
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/02Selection of the hardening environment
    • C04B40/0263Hardening promoted by a rise in temperature
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • C04B2201/52High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of mixed with RPC of flyash and preparation method thereof.It is made up of mixed with the RPC of flyash the material of following mass parts:0.015 part of 1 part of cement, 1.1 parts of quartz sand, 0.21~0.28 part of silicon ash, 0.07~0.14 part of flyash, 0.1 part of steel fibre, 0.1 part of small component, 0.2 part of water and water reducer;Pass through stir, vibrate shaping, form removal and High Temperature Curing.It is characteristic of the invention that incorporation industrial residue flyash is used as a kind of active component, a kind of On New Reactive Powder Concrete being made through High Temperature Curing, have the advantages that intensity is high, workability is good, cost is low, environmentally friendly and preparation method is simple, it is adapted to the popularization and application in Practical Project, meets the Strategic Concept of China's Green Sustainable.

Description

It is a kind of mixed with RPC of flyash and preparation method thereof
Technical field
The present invention relates to building material technical field, more particularly to a kind of RPC mixed with flyash and Its preparation method.
Background technology
RPC is a kind of high intensity, high tenacity, high-durability, the ultra-high performance concrete of low porosity. It is by rejecting coarse aggregate, improving composition activity and fineness, make the internal flaw (microcrack and hole) of material that it, which configures principle, It is reduced to a minimum, so as to obtain higher mechanical property and high-durability.Its basic composition material has:Cement, fine quartz Sand, levigate silica flour, silicon ash, high efficiency water reducing agent, steel fibre etc..Because part composition material cost is higher, to a certain extent Constrain popularization and application of the RPC in Practical Project.And on the other hand, the clinker such as flyash is current discharge Measure one of maximum industrial residue, China's annual emissions are up to more than 1.5 hundred million tons at this stage, processing to clinkers such as flyash and Utilizing question has caused the extensive concern of people.Since 21 century, with the development of technology of high performance concrete, people It was found that when preparing high performance concrete, it is necessary to mix appropriate admixture, and in many admixtures, flyash has reduction water Consumption, improve the workability of concrete, improve concrete pumpability, reduce the creeping of concrete, reduce the heat of hydration, save Many advantages, such as about substantial amounts of cement and fine aggregate.
The content of the invention
It is an object of the invention to provide a kind of mixed with RPC of flyash and preparation method thereof, reduction activity While powder concrete production cost, the problem of environmental pollution that flyash is brought is solved.
In order to realize above-mentioned target, the present invention is adopted the following technical scheme that:
A kind of RPC mixed with flyash, is made up of the material of following mass parts:1 part of cement, quartz sand 1.1 Part, 0.21~0.28 part of silicon ash, 0.07~0.14 part of flyash, 0.1 part of steel fibre, 0.1 part of small component, 0.2 part of water and diminishing 0.015 part of agent.
The cement is the portland cement of label 52.5, the m of fineness 10 of cement2/ kg, the presetting period >=45min, eventually Solidifying time≤600min.
The quartz sand particle size is in 0.4mm~0.6mm, SiO2Content more than 99.6%.
0.1~0.2 μm of the silicon ash average grain diameter, specific surface area>20 m2/ g, water demand ratio<120%, loss on ignition 1.45.
The steel fibre is the straight steel fibre of copper facing smooth surface, and diameter 0.22mm, 12~15mm of length, tensile strength exists More than 2300MPa.
The flyash is gray powdery, 6.34 μm of particle mean size, loss on ignition 0.4.
The group is divided into gray powder end, and main component is polyester fiber, swelling agent and latex protein.
The water reducer is sepia pulvis, water-reducing rate >=25%.
The invention also discloses a kind of method for preparing a kind of described RPC mixed with flyash, specifically Comprise the following steps:
(1)Stirring:After each raw material are weighed by match ratio, cement, quartz sand, silicon ash, flyash are first poured into mixer In, then steel fibre is uniformly sieved into mixer through steel sieve, stirring 4 minutes is done, finally by water and high efficiency water reducing agent and group Divide mixing, uniformly pour into mixer, stirring discharges after 6~8 minutes.
(2)Vibrate shaping:RPC material is once loaded into punching block, omited during charging with spatula along mould inner wall Plus vibrate, and it is suitable for reading mix is higher by mould, and mould is placed in into shake table vibration moulding, continues to concrete surface pulp.
(3)Form removal:Test specimen is poured finish after immediately with moistening wood chip cover, be put into mark support room conserve 36 hours after tear open Mould.
(4)High Temperature Curing:The test specimen removed after mould is put into the constant temperature cement concrete curing boxes of HW -30, constant temperature After 75 DEG C conserve 48 hours, take out test specimen and be put into the foster room of mark.
Compared with prior art, using a kind of formula of RPC mixed with flyash of the present invention, due to mixing Enter flyash, will have the advantages that:
Further improve the mobility and workability of slurry, so as to reduce viscosity, reduce because viscosity is high and is stirring and is vibrating When the bubble that introduces, improve the compactness of matrix;
Flyash is not involved in aquation in early stage, so in whole bonding component, although water-cement ratio very little, considering in early stage To flyash not aquation, the ratio between water/cement is not low, be conducive to cement early stage aquation;
When matrix has been formed using sand, the unhydrated cement granules of fly ash grain and part as skeleton, the knot of hydrated product is wrapped up Structure, the top layer aquation of subsequent fly ash grain further fills closely knit effect with regard to that can play;
Flyash is mixed, totle drilling cost can also be reduced by substituting part silicon ash, improve the ratio of performance to price;
Industrial waste residue resource is applied in concrete, effectively solves the problem of flyash is largely stored up, and reduces environmental pollution, has Beneficial to realizing China's Green Sustainable.
Preparation method preparation technology of the present invention is simple, improves multi-component dispersed problem, especially stirs Steel fibre is uniformly sieved into mixer through steel sieve when mixing, steel fibre can be avoided to form " conglomeration " phenomenon in mixture well.
Under the conditions of High Temperature Curing, the volcano ash effect of active material is excited, and Ca (OH) is reduced to a certain extent2's Content, generates C-S-H gels, improves the microstructure in interface area, improves the density of slurry, improves RPC Compression strength and rupture strength.
It is characteristic of the invention that incorporation industrial residue flyash is as a kind of active component, one be made through High Temperature Curing On New Reactive Powder Concrete is planted, has the advantages that intensity is high, workability is good, cost is low, environmentally friendly and preparation method is simple, is adapted to The popularization and application in Practical Project, meet the Strategic Concept of China's Green Sustainable.
Embodiment
Illustrate the specific embodiment of the invention with reference to example.
Embodiment 1:
A kind of RPC mixed with flyash, is made up of the material of following mass parts:1 part of cement, quartz sand 1.1 Part, 0.28 part of silicon ash, 0.07 part of flyash, 0.1 part of steel fibre, 0.1 part of small component, 0.2 part of water, 0.015 part of water reducer;
The cement is the portland cement of label 52.5, the m of fineness 10 of cement2/ kg, presetting period >=45min, during final set Between≤600min.
The quartz sand particle size is in 0.4mm, SiO2Content more than 99.6%.
0.1 μm of the silicon ash average grain diameter, specific surface area>20 m2/ g, water demand ratio<120%, loss on ignition 1.45.
The steel fibre is the straight steel fibre of copper facing smooth surface, and diameter 0.22mm, 12~15mm of length, tensile strength exists More than 2300MPa.
The flyash is gray powdery, 6.34 μm of particle mean size, loss on ignition 0.4.
The group is divided into gray powder end, and main component is polyester fiber, swelling agent and latex protein.
The water reducer is sepia pulvis, water-reducing rate >=25%.
The method of the above-mentioned RPC mixed with flyash is concretely comprised the following steps:
(1)Stirring:After each raw material are weighed by match ratio, cement, quartz sand, silicon ash, flyash are first poured into mixer In, then steel fibre is uniformly sieved into mixer through steel sieve, stirring 4 minutes is done, finally by water and high efficiency water reducing agent and group Divide mixing, uniformly pour into mixer, stirring discharges after 6 minutes.
(2)Vibrate shaping:RPC material is once loaded into punching block, omited during charging with spatula along mould inner wall Plus vibrate, and it is suitable for reading mix is higher by mould, and mould is placed in into shake table vibration moulding, continues to concrete surface pulp.
(3)Form removal:Test specimen is poured finish after immediately with moistening wood chip cover, be put into mark support room conserve 36 hours after tear open Mould.
(4)High Temperature Curing:The test specimen removed after mould is put into the constant temperature cement concrete curing boxes of HW -30, constant temperature After 75 DEG C conserve 48 hours, take out test specimen and be put into the foster room of mark.
Gained flyash activity powder concrete compression strength is 131.8Mpa, and rupture strength is 25.43Mpa.
Embodiment 2:
A kind of RPC mixed with flyash, is made up of the material of following mass parts:1 part of cement, quartz sand 1.1 Part, 0.21 part of silicon ash, 0.14 part of flyash, 0.1 part of steel fibre, 0.1 part of small component, 0.2 part of water, 0.015 part of water reducer;
The cement is the portland cement of label 52.5, the m of fineness 10 of cement2/ kg, presetting period >=45min, during final set Between≤600min.
The quartz sand particle size is in 0.6mm, SiO2Content more than 99.6%.
0.2 μm of the silicon ash average grain diameter, specific surface area>20 m2/ g, water demand ratio<120%, loss on ignition 1.45.
The steel fibre is the straight steel fibre of copper facing smooth surface, and diameter 0.22mm, 12~15mm of length, tensile strength exists More than 2300MPa.
The flyash is gray powdery, 6.34 μm of particle mean size, loss on ignition 0.4.
The group is divided into gray powder end, and main component is polyester fiber, swelling agent and latex protein.
The water reducer is sepia pulvis, water-reducing rate >=25%.
The method of the above-mentioned RPC mixed with flyash is concretely comprised the following steps:
(1)Stirring:After each raw material are weighed by match ratio, cement, quartz sand, silicon ash, flyash are first poured into mixer In, then steel fibre is uniformly sieved into mixer through steel sieve, stirring 4 minutes is done, finally by water and high efficiency water reducing agent and group Divide mixing, uniformly pour into mixer, stirring discharges after 8 minutes.
(2)Vibrate shaping:RPC material is once loaded into punching block, omited during charging with spatula along mould inner wall Plus vibrate, and it is suitable for reading mix is higher by mould, and mould is placed in into shake table vibration moulding, continues to concrete surface pulp.
(3)Form removal:Test specimen is poured finish after immediately with moistening wood chip cover, be put into mark support room conserve 36 hours after tear open Mould.
(4)High Temperature Curing:The test specimen removed after mould is put into the constant temperature cement concrete curing boxes of HW -30, constant temperature After 75 DEG C conserve 48 hours, take out test specimen and be put into the foster room of mark.
Gained flyash activity powder concrete compression strength is 142.7Mpa, and rupture strength is 23.58Mpa.
Above-described embodiment only illustrates the basic principles, principal features and advantages of the present invention, does not limit in any form The present invention.Every spirit in present inventive concept is with principle, and those skilled in the art use equivalent substitution and equivalence replacement The technical scheme obtained etc. mode, within protection scope of the present invention.

Claims (2)

1. a kind of RPC mixed with flyash, it is characterised in that be made up of the material of following mass parts:1 part of water Mud, 1.1 parts of quartz sand, 0.21~0.28 part of silicon ash, 0.07~0.14 part of flyash, 0.1 part of steel fibre, 0.1 part of small component, 0.2 part of water and 0.015 part of water reducer;
The cement is the portland cement of label 52.5, the m of fineness 10 of cement2/ kg, presetting period >=45min, final setting time ≤600min;
The quartz sand particle size is in 0.4mm~0.6mm, SiO2Content more than 99.6%;
0.1~0.2 μm of the silicon ash average grain diameter, specific surface area>20 m2/ g, water demand ratio<120%, loss on ignition 1.45;
The steel fibre be the straight steel fibre of copper facing smooth surface, diameter 0.22mm, 12~15mm of length, tensile strength is in 2300MPa More than;
The flyash is gray powdery, 6.34 μm of particle mean size, loss on ignition 0.4;
The group is divided into gray powder end, and main component is polyester fiber, swelling agent and latex protein;
The water reducer is sepia pulvis, water-reducing rate >=25%.
2. the preparation method of the RPC according to claim 1 mixed with flyash, it is characterised in that specific Step is:
(1)Each raw material are weighed by mass parts:1 part of cement, 1.1 parts of quartz sands, 0.21~0.28 part of silicon ash, 0.07~0.14 Part flyash, 0.1 part of steel fibre, 0.1 part of small component, 0.2 part of water and 0.015 part of water reducer;
(2)By step(1)After match ratio is weighed, first cement, quartz sand, silicon ash, flyash are poured into mixer, then will Steel fibre is uniformly sieved into mixer through steel sieve, is done stirring 4 minutes, is finally mixed water with high efficiency water reducing agent and small component, Even pours into mixer, and stirring discharges after 6~8 minutes;
(3)By step(2)Gained RPC material once loads punching block, during charging with spatula along mould inner wall slightly Vibrate, and it is suitable for reading mix is higher by mould, and mould is placed in into shake table vibration moulding, continues to concrete surface pulp;
(4)Test specimen is poured finish after immediately with moistening wood chip cover, be put into mark support room conserve 36 hours after form removal;
(5)The test specimen removed after mould is put into the constant temperature cement concrete curing boxes of HW -30,75 DEG C of constant temperature is conserved 48 hours Afterwards, take out test specimen and be put into the foster room of mark.
CN201710527271.6A 2017-07-01 2017-07-01 Active powder concrete doped with fly ash and preparation method thereof Active CN107117909B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107721277A (en) * 2017-11-13 2018-02-23 杭州幽若科技有限公司 A kind of preparation method of high ferro Line for Passenger Transportation RPC trench covers
CN109138310A (en) * 2018-10-23 2019-01-04 黄贺明 A kind of superhigh tenacity concrete inorganic decorating board and preparation method thereof of the surface containing pattern
CN111620662A (en) * 2020-06-16 2020-09-04 湘潭大学 Concrete doped with modified zeolite
CN112909875A (en) * 2021-02-03 2021-06-04 江西龙正科技发展有限公司 Novel super-strength RPC tunnel cable trench cover plate
CN112944057A (en) * 2021-02-03 2021-06-11 江西龙正科技发展有限公司 Novel super-strength RPC air duct pipe
CN114436596A (en) * 2022-02-25 2022-05-06 中铁大桥局集团有限公司 Ultra-high performance concrete suitable for use in vibration environment and application thereof
CN116354657A (en) * 2023-03-23 2023-06-30 桂林理工大学 Preparation method of high-strength UHPC hollow thin-wall structured curbstone

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6858075B1 (en) * 2004-02-10 2005-02-22 The United States Of America As Represented By The Department Of The Interior, Bureau Of Reclamation Thin concrete repair composition for alkali-aggregate reaction affected concrete
CN102775099A (en) * 2012-07-30 2012-11-14 北京工业大学 Economic active powder concrete mixed superfine cement

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6858075B1 (en) * 2004-02-10 2005-02-22 The United States Of America As Represented By The Department Of The Interior, Bureau Of Reclamation Thin concrete repair composition for alkali-aggregate reaction affected concrete
CN102775099A (en) * 2012-07-30 2012-11-14 北京工业大学 Economic active powder concrete mixed superfine cement

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107721277A (en) * 2017-11-13 2018-02-23 杭州幽若科技有限公司 A kind of preparation method of high ferro Line for Passenger Transportation RPC trench covers
CN109138310A (en) * 2018-10-23 2019-01-04 黄贺明 A kind of superhigh tenacity concrete inorganic decorating board and preparation method thereof of the surface containing pattern
CN111620662A (en) * 2020-06-16 2020-09-04 湘潭大学 Concrete doped with modified zeolite
CN112909875A (en) * 2021-02-03 2021-06-04 江西龙正科技发展有限公司 Novel super-strength RPC tunnel cable trench cover plate
CN112944057A (en) * 2021-02-03 2021-06-11 江西龙正科技发展有限公司 Novel super-strength RPC air duct pipe
CN114436596A (en) * 2022-02-25 2022-05-06 中铁大桥局集团有限公司 Ultra-high performance concrete suitable for use in vibration environment and application thereof
CN116354657A (en) * 2023-03-23 2023-06-30 桂林理工大学 Preparation method of high-strength UHPC hollow thin-wall structured curbstone

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Inventor after: Jin Lingzhi

Inventor after: Fu Qiang

Inventor after: Li Yuexia

Inventor after: Wan Dongwei

Inventor before: Fu Qiang

Inventor before: Wan Dongwei

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Application publication date: 20170901

Assignee: Zhongxiang Design Co.,Ltd. Guilin Branch

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Contract record no.: X2023980044215

Denomination of invention: A reactive powder concrete mixed with fly ash and its preparation method

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Record date: 20231023