CN107042477A - Metal material composite electrodeposition diamond disk and its manufacture method - Google Patents
Metal material composite electrodeposition diamond disk and its manufacture method Download PDFInfo
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- CN107042477A CN107042477A CN201710220069.9A CN201710220069A CN107042477A CN 107042477 A CN107042477 A CN 107042477A CN 201710220069 A CN201710220069 A CN 201710220069A CN 107042477 A CN107042477 A CN 107042477A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/0018—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for by electrolytic deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/04—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
- B24D3/06—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/34—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Abstract
It is to be electrodeposited in one or more kinds of metals and diamond jointly by the way of plating to have on the conducting base of property that the present invention, which provides a kind of metal material composite electrodeposition diamond disk, and metallic diamond composite bed is formed on matrix.These metal or alloy are wrapped in diamond and anchored on matrix, so that grinding function is formed, in the another side of matrix, hair side or hook face with bonding agent one layer of velcro of bonding, to be connected with corresponding using equipment.The metal material composite electrodeposition diamond disk of the present invention, high polymer material bonding agent is replaced as bonding agent with metal material, not only increase intensity, wearability, heat resistance and the thermal diffusivity of bonding agent in itself, directly reduce grinding temperature, overcome high polymer material and burn the fatal defects such as plate, dyeing, it can be used for water mill and can be used for dry grinding again, while also drastically increasing the service life and grinding efficiency of grinding.
Description
Technical field
The present invention relates to a kind of metal material composite electrodeposition diamond disk and its manufacture method.
Background technology
Nonmetallic materials are applied more and more extensively, such as from cement flooring to granite, marble, pottery in production and life
Porcelain floor tile, the appearance of glass, the extensive use of silicon wafer, and Sapphire mobile phone panel.Many fields are to crudy
It is required that also more and more higher, therefore more and more to grinding and the demand of polishing tool, to grinding performance more and more higher.It is initially golden
Hard rock grinding is using high polymer material as bonding agent, due to high polymer material poor heat resistance, so having to add during grinding
Water cooling, here it is so-called water mill piece.Because being limited by machined material and processing environment, many grindings are not suitable for
Cooled down with coolant, it is necessary to which required suface processing quality is reached using dry grinding, the dry processing method thrown.So go out again
Existing another question, grinding is carried out under conditions of being cooled down without coolant, grinding surface temperature certainly will be caused to greatly improve.
Due to high polymer material non-refractory, it is impossible to bear too high grinding temperature, occur in grinding process and burnt phenomenon, burn
Burnt high polymer material, which stays in be processed, shows that to form one of color marks dye, while surface to be machined is sent out not because heat is spread
Go out, having become color by high temperature burning burns plate.Ultimately result in grinding and can not proceed, be ground and process workpiece and be damaged report
Useless adverse consequences.In order to overcome this phenomenon, people add metal dust as radiating in high polymer material bonding agent
Agent, adds ice crystal as heat absorbent, to reduce grinding temperature, but these methods all can not fundamentally change bonding agent
The problem of non-refractory, radiating effect are poor.
The existing diamond dry grinding disc for material skivings such as stone material, ceramics, can only carry out the grinding of short time, to protect
Card dry grinding heating will not be too high, and these diamond dry grinding discs can not be met for processing stock removal is big, quick heating, temperature are high, mill
Cut the requirement of the work such as time length.
Notification number diamond dry grinding disc disclosed in CN201807975U utility model patent is uniform on grinding layer
Multiple projections are placed with, projection cross section is hollow positive 3-10 sides shape, and the hollow intracavity section of projection is circle；Notification number
A kind of diamond dry grinding disc disclosed in CN201799940U utility model patent, its skiving layer is by being evenly spaced in basic unit
Body upper annular projection is constituted.Two above patented technology is that the skiving Rotating fields of dry grinding disc are improved, and adds it
Thermal diffusivity, does not change the heat resistance of dry grinding disc in itself, and also the combination agent material and production technology of dry grinding disc are not carried out
Improve.
Notification number is CN101722478A patent application, discloses a kind of diamond dry grinding disc and its manufacture method, should
The abrasive material of dry grinding disc is mixed by fire resistant resin, diamond particles and wear-resisting radiating additive, and the technical scheme is led to
Crossing increase wear heat-resistant material additive improves the heat resistance of abrasive material resin, and technique is improved, and takes and first closes
Mould hot pressing, the mode of solidify afterwards are molded, and thicker dry grinding disc can be made, although the diamond dry grinding disc of invention manufacture is in heatproof
Increased in property, but equally also can not thoroughly change the heat resistance of high polymer material bonding agent in itself, also not to skiving
Temperature is reduced.The molding mode of other matched moulds hot pressing is higher to equipment dynamic and thermal requirements, is unfavorable for energy-conservation；Produced
Volatile organic matter is produced in journey, is unfavorable for environmental protection.
The content of the invention
It is an object of the invention to provide a kind of most of heat that can be absorbed and be produced in grinding, directly reduction grinding temperature
Degree, is not easily blocked, does not dye, and the metal material composite electrodeposition diamond of the surface to be machined that will not burn, service life length
Grinding and its manufacture method.
The metal material composite electrodeposition diamond disk of the present invention, is made up of abrasive material working lining, matrix and hair side, and it is special
Levy and be, the material of the abrasive material working lining is made up of the raw material of volumes below number：
Diamond abrasive 5-50%
Auxiliary abrasive 0-30%
Metallic bond 20-95%；
Described matrix is for the thin plate of 0.01-5 mm of thickness, preferably steel, copper material, zinc material, aluminium, the thin plate of tin material and to lead
The nonmetallic materials after one kind or activated, quick China's processing in electric cloth.
Described hair side is the hair side in nylon adherent buckle with hooking face.
The auxiliary abrasive be metal oxide or carbide, preferably：Aluminum oxide, zinc oxide, strontium oxide strontia, chromium oxide, carbon
One kind or any several in SiClx and tungsten carbide.
The metallic bond is：One kind or any several alloy in iron, nickel, cobalt, tungsten, copper, zinc, tin, aluminium.
The metal material composite electrodeposition diamond disk manufacture method of the present invention, it is characterised in that including with following step
Suddenly：
1st, plating solution is configured：All types of electroplate liquid constituents
2nd, matrix is cut：By above-mentioned matrix, it is machined into method and cuts shaping；
3rd, oil removing：Remove matrix surface grease；
4th, derust：Matrix is placed on and filled in one kind in hydrochloric acid, sulfuric acid, nitric acid or any several container, matrix is removed
Surface film oxide；
5th, die-filling insulation：The one side of matrix is covered in insulating materials mould according to the tooth form of diamond disk, insulating materials is used
The region of plating is not needed to be covered remaining；
6th, empty plating：Matrix enters after groove, in 20-70 degrees Celsius of plating solution, with 1-10 amperes/every square decimeter of current density,
Plating 5-30 minutes；
7th, upper sand：Abrasive material working lining is covered in matrix surface, in 20-70 degrees Celsius of plating solution, with 0.5-5 amperes/often put down
Under the current density of square decimetre, the technique of plating 10-50 minutes, make metal deposit in matrix surface, while diamond is swept along
Stick to matrix surface；
8th, sand removal：The nonadherent diamond abrasive on matrix is rinsed out with current；
9th, thicken：In 20-70 degrees Celsius of plating solution, with 1-10 amperes/every square decimeter of current density, 30-250 points of plating
Under the technique of clock, continue to thicken metal deposition layer, abrasive material working lining is wrapped up and is attached on matrix；
10th, brightness：Metal deposition layer reaches to be taken out after thickness requirement, is placed into existing conventional brightness groove, is taken the photograph in 20-70
In the plating solution of family name's degree, with 1-2 amperes/every square decimeter of current density, decorative cover is spent under the technique of plating 5-30 minutes, makes it
Surface-brightening is attractive in appearance；
11st, adhesive hair face：Take out, clear water is rinsed well, dried, be bonded in the hair side of nylon adherent buckle or hook face afterwards with bonding agent
The one side of the non-plating diamond of matrix, it is neat along edge pruning, obtain finished product.
The metal material composite electrodeposition diamond disk of the present invention, is using metal or alloy as bonding agent, with superhard material
Expect for abrasive material, the materials such as auxiliary abrasive are added in addition, with electro-deposition（Plating）Method diamond and auxiliary abrasive are attached to
Conductive material or non-conducting material is activated, on the matrix made of thin plate after sensitization, then brush coating pastes one layer of Buddhist nun on matrix
The method manufacture of imperial thread gluing.It has abandoned traditional production technology and has combined agent material, made compared with existing diamond disk
With new electro-deposition（Plating）Technique and metal material bonding agent.New bonding agent not only improve only grinding itself intensity,
Wearability, heat resistance, while the thermal diffusivity of metal material is far superior to high polymer material, can absorb the big portion produced in grinding
Divide heat, directly reduce grinding temperature.So that the diamond disk of the present invention is not easily blocked, not dyed, will not burn is added
Work surface, it is sharp, all it is remote super existing gold no matter on service life or on grinding efficiency, and on grinding quality
Hard rock is ground.
Embodiment
A kind of metal material composite electrodeposition diamond disk, is made up of abrasive material working lining, matrix and hair side, and its feature exists
In the material of the abrasive material working lining is by the material composition of volumes below number：Diamond abrasive 50%；Auxiliary abrasive：
30%；Metallic bond：20%；
Wherein, the granularity of the diamond abrasive is：The mesh of coarse grain 35/40 is to 270/325 mesh, and micro powder grade is W40 to W0.1；Institute
Super hard abrasive is stated for diamond, the model of coarseness is included listed by GB/T 6405-94：RVD、MBD、SCD；It is required that grain
Scale standard meets GB/T 6406-1996；And it is fine-grained including each principal series of MP-SD listed by GB6966.1-86 and benefit
Fill serial diadust.
The auxiliary abrasive is：One kind in aluminum oxide, zinc oxide, strontium oxide strontia, chromium oxide, carborundum and tungsten carbide is appointed
Meaning is several.
The metallic bond is：One kind or any several alloy in iron, nickel, cobalt, tungsten, copper, zinc, tin, aluminium.
Described matrix is in the various model steel of metal, copper material, zinc material, aluminium, the thin plate of tin material and conductive fabric
Nonmetallic materials thin plate after a kind of or activated, quick China's processing, lamella thickness is 0.1-5 millimeters；
Example 1：A kind of metal material composite electrodeposition diamond disk manufacture method, it is characterised in that comprise the following steps：
（1）Configure plating solution：
Nickel sulfate 300g/L, nickel chloride 50g/L, boric acid 36g/L, lauryl sodium sulfate 0.1g/L；
（2）Cut matrix：0.1mm sheet irons are chosen, Φ 80mm disks is cut into, is fabricated to matrix；
（3）Oil removing：Matrix is placed in the container for fill degreaser and is heated to 80 DEG C, oil removing is carried out within 30 minutes；
（4）Derusting：Matrix is placed in the container for filling hydrochloric acid, in the case of not heating, soaked 1 hour, except descale；
（5）Die-filling insulation：Mould is covered in the one side of matrix, with insulating materials do not need plating place covered；
（6）Sky plating：Matrix enters after groove, in 40 DEG C of plating solution, with 2 amperes/every square decimeter of current density, electroplates 5 minutes；
（7）Upper sand：Diamond is gently floated in the air in a liquid with small spoon, diamond is fallen in matrix surface；Diamond covers base
Behind body surface face, in 40 DEG C of plating solution, with 0.5 ampere/every square decimeter of current density, under the technique for electroplating 50 minutes, make
Metal deposit sticks to matrix surface in matrix surface while diamond is swept along；
（8）Sand removal：As the nonadherent diamond on matrix is gently washed with current；
（9）Thicken：After sand removal, in 40 DEG C of plating solution, with 5 amperes/every square decimeter of current density, electroplate 180 minutes
Under technique, continue to thicken metal deposition layer, diamond is wrapped up and is attached on matrix；
（10）Brightness：Metal deposition layer reaches to be taken out after thickness requirement, special brightness groove is placed into, in 40 DEG C of plating solution
In, with 1 ampere/every square decimeter of current density, decorative cover is spent under the technique of plating 30 minutes, makes its surface-brightening attractive in appearance；
（11）Adhesive hair face：Taken out after light, clear water is rinsed well, dried, with bonding agent is by the hair side of nylon adherent buckle or hooks face
The one side of the non-plating diamond of matrix is bonded in, hooks or hair is outside, it is neat along edge pruning, obtain finished product.
Example 2：A kind of metal material composite electrodeposition diamond disk manufacture method, it is characterised in that including following step
Suddenly：
（1）Configure plating solution：
Nickel chloride 250g/L, boric acid 25g/L, lauryl sodium sulfate 0.1g/L；
（2）Cut matrix：0.02mm sheet coppers are chosen, Φ 100mm disks is cut into, is fabricated to matrix；
（3）Oil removing：Matrix is placed in the container for fill degreaser and is heated to 100 DEG C, oil removing is carried out within 30 minutes；
（4）Derusting：Matrix is placed in the container for filling sulfuric acid, in the case of not heating, soaked 1 hour, except descale；
（5）Die-filling insulation：Mould is covered in the one side of matrix, with insulating materials not needing plating elsewhere to be hidden
Lid；
（6）Sky plating：Matrix enters after groove, in 40 DEG C of plating solution, with 1 ampere/every square decimeter of current density, electroplates 20 points
Clock；
（7）Upper sand：Matrix is embedded in diamond, diamond is covered after matrix surface, diamond covering matrix surface, 40
DEG C plating solution in, with 0.5 ampere/every square decimeter of current density, under the technique of plating 50 minutes, make metal deposit in matrix
Surface, matrix surface is sticked to while diamond is swept along；
（8）Sand removal：As the nonadherent diamond on matrix is gently washed with current；
（9）Thicken：After sand removal, in 40 DEG C of plating solution, with 5 amperes/every square decimeter of current density, electroplate 180 minutes
Under technique, continue to thicken metal deposition layer, diamond is wrapped up and is attached on matrix；
（10）Brightness：Metal deposition layer reaches to be taken out after thickness requirement, special brightness groove is placed into, in 40 DEG C of plating solution
In, with 1 ampere/every square decimeter of current density, decorative cover is spent under the technique of plating 30 minutes, makes its surface-brightening attractive in appearance；
（11）Adhesive hair face：Take out, clear water is rinsed well, dry after light.With bonding agent is by the hair side of nylon adherent buckle or hooks face
The one side of the non-plating diamond of matrix is bonded in, hooks or hair is outside, it is neat along edge pruning, obtain finished product.
Example 3：A kind of metal material composite electrodeposition diamond disk manufacture method, it is characterised in that including following step
Suddenly：
（1）Configure plating solution：
Nickel sulfamic acid 300g/L, nickel chloride 50g/L, boric acid 36g/L, lauryl sodium sulfate 0.1g/L；
（2）Cut matrix：Conductive fabric is chosen, Φ 80mm disks is cut into, is fabricated to matrix；
（3）Oil removing：Matrix is placed in the container for fill degreaser and is heated to 40 DEG C, oil removing is carried out within 30 minutes；
（4）Derusting：Conductive fabric can not derust, or slightly be soaked in very dilute hydrochloric acid solution, clean up；
（5）Die-filling insulation：Insulating materials is covered in the one side of matrix, with insulating materials not needing plating elsewhere to enter
Row is covered；
（6）Sky plating：Matrix enters after groove, in 40 DEG C of plating solution, with 2 amperes/every square decimeter of current density, electroplates 5 minutes；
（7）Upper sand：Diamond is gently floated in the air in a liquid with small spoon, diamond is fallen in matrix surface, diamond covering base
Behind body surface face, in 40 DEG C of plating solution, with 0.5 ampere/every square decimeter of current density, under the technique for electroplating 50 minutes, make
Metal deposit sticks to matrix surface in matrix surface while diamond is swept along；
（8）Sand removal：As the nonadherent diamond on matrix is gently washed with current；
（9）Thicken：After sand removal, in 40 DEG C of plating solution, with 5 amperes/every square decimeter of current density, electroplate 180 minutes
Under technique, continue to thicken metal deposition layer, diamond is wrapped up and is attached on matrix；
（10）Brightness：Conductive fabric does matrix and does not need brightness；
（11）Adhesive hair face：Rinsed well, dried with clear water after the completion of adding thickness.With bonding agent is by the hair side of nylon adherent buckle or hooks face
The one side of the non-plating diamond of matrix is bonded in, hooks or hair is outside, it is neat along edge pruning, obtain finished product.
Example 4：A kind of metal material composite electrodeposition diamond disk manufacture method, it is characterised in that including following step
Suddenly：
（1）Configure plating solution：
Nickel sulfamic acid 300g/L, nickel chloride 50g/L, boric acid 36g/L, lauryl sodium sulfate 0.1g/L；
（2）Cut matrix：2mm single-side coated copper plates, are cut into Φ 125mm disks, are fabricated to matrix；
（3）Oil removing：Matrix is placed in the container for fill degreaser and is heated to 40 DEG C, oil removing is carried out within 30 minutes；
（4）Derusting：Slightly soak, clean up in very dilute hydrochloric acid solution；
（5）Die-filling insulation：Insulating materials is covered in the one side that matrix is covered with copper coin, need not be covered elsewhere；
（6）Sky plating：Matrix enters after groove, in 50 DEG C of plating solution, with 3 amperes/every square decimeter of current density, electroplates 5 minutes；
（7）Upper sand：Diamond is gently floated in the air in a liquid with small spoon, diamond is fallen in matrix surface, diamond covering base
Behind body surface face, in 50 DEG C of plating solution, with 1 ampere/every square decimeter of current density, under the technique for electroplating 20 minutes, make gold
Category is deposited on matrix surface, and matrix surface is sticked to while diamond is swept along；
（8）Sand removal：As the nonadherent diamond on matrix is gently washed with current；
（9）Thicken：After sand removal, in 50 DEG C of plating solution, with 5 amperes/every square decimeter of current density, electroplate 120 minutes
Under technique, continue to thicken metal deposition layer, diamond is wrapped up and is attached on matrix；
（10）Brightness：Copper-clad plate does matrix and does not need brightness；
（11）Adhesive hair face：Rinsed well, dried with clear water after the completion of adding thickness, with bonding agent is by the hair side of nylon adherent buckle or hooks face
The one side of the non-plating diamond of matrix is bonded in, hooks or hair is outside, it is neat along edge pruning, obtain finished product.
The dry grinding disc finished product prepared in four embodiments of the above is as follows by detection properties：
| Project | This Project Product | Existing product | This product advantage |
| It is molded energy consumption（Kilowatt-hour/piece） | 0.5 | 2 | Energy-conservation 75% |
| Production efficiency（Piece/minute） | 1 | 5/30 | Improve 6 times |
| Service life（Hour） | 3 | 0.3 | 10 times of extension |
| Grinding efficiency（Kg/hr） | 2.57 | 1.89 | Improve 35.97% |
| Production environment（Chemical dust pollutes） | Nothing | Have | Environmental protection |
Claims (3)
1. a kind of metal material composite electrodeposition diamond disk, is made up of abrasive material working lining, matrix and hair side, its feature exists
In：The material of the abrasive material working lining is made up of the raw material of volumes below number：
Diamond abrasive 5-50%
Auxiliary abrasive 0-30%
Metallic bond 20-95%；
The auxiliary abrasive is：One kind or any several in aluminum oxide, zinc oxide, strontium oxide strontia, chromium oxide, carborundum and tungsten carbide
Kind；
The metallic bond is：One kind or any several alloy in iron, nickel, cobalt, tungsten, copper, zinc, tin, aluminium.
2. metal material composite electrodeposition diamond disk according to claim 1, it is characterised in that：Described matrix is
One kind in the thin plate of 0.01-5 mm of thickness, preferably steel, copper material, zinc material, aluminium, the thin plate of tin material and conductive fabric, or
It is the nonmetallic materials after activated, quick China's processing.
3. metal material composite electrodeposition diamond disk manufacture method as claimed in claim 1, it is characterised in that：Including with
Lower step：
(1) plating solution is configured：All types of electroplate liquid constituents
(2) matrix, is cut：By above-mentioned matrix, it is machined into method and cuts shaping；
(3), oil removing：Remove matrix surface grease；
(4), derust：Matrix is placed on and filled in one kind in hydrochloric acid, sulfuric acid, nitric acid or any several container, base is removed
Body surface surface oxidation film；
(5), die-filling insulation：The one side of matrix is covered in insulating materials mould according to the tooth form of diamond disk, insulation material is used
Remaining is expected not need the region of plating to be covered；
(6), empty plating：Matrix enters after groove, in 20-70 degrees Celsius of plating solution, close with 1-10 amperes/every square decimeter of electric current
Degree, is electroplated 5-30 minutes；
(7), upper sand：Abrasive material working lining is covered in matrix surface, in 20-70 degrees Celsius of plating solution, with 0.5-5 amperes/it is every
Under the current density of square decimeter, the technique of plating 10-50 minutes, make metal deposit in matrix surface, while diamond is wrapped up in
Hold under the arm and stick to matrix surface；
(8), sand removal：The nonadherent diamond abrasive on matrix is rinsed out with current；
(9), thicken：In 20-70 degrees Celsius of plating solution, with 1-10 amperes/every square decimeter of current density, 30-250 is electroplated
Under the technique of minute, continue to thicken metal deposition layer, abrasive material working lining is wrapped up and is attached on matrix；
(10), brightness：Metal deposition layer reaches to be taken out after thickness requirement, existing conventional brightness groove is placed into, in 20-70
Degree Celsius plating solution in, with 1-2 amperes/every square decimeter of current density, spend decorative cover under the technique of plating 5-30 minutes, make
Its surface-brightening is attractive in appearance；
(11), adhesive hair face：Take out afterwards, clear water is rinsed well, dried, with bonding agent is by the hair side of nylon adherent buckle or hooks face bonding
In the one side of the non-plating diamond of matrix, obtain finished product along edge pruning neatly.
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| CN201710220069.9A CN107042477A (en) | 2017-04-06 | 2017-04-06 | Metal material composite electrodeposition diamond disk and its manufacture method |
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| CN201710220069.9A CN107042477A (en) | 2017-04-06 | 2017-04-06 | Metal material composite electrodeposition diamond disk and its manufacture method |
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| CN107553357A (en) * | 2017-09-28 | 2018-01-09 | 苏州远东砂轮有限公司 | Fiberboard dedicated ceramic microcrystal fused alumina coated abrasive tool and its manufacture method |
| CN107866756A (en) * | 2017-12-05 | 2018-04-03 | 长沙理工大学 | A kind of micro groove structure multi-player super-hard abrasive material electroplating abrasion wheel and preparation method thereof in order |
| CN108296995A (en) * | 2018-02-05 | 2018-07-20 | 湖北小蚂蚁金刚石工具有限公司 | A kind of diamond disk and preparation method thereof |
| CN109352542A (en) * | 2018-11-15 | 2019-02-19 | 娄底市安地亚斯电子陶瓷有限公司 | Diamond abrasive tool and preparation method thereof |
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Application publication date: 20170815 |