CN106928956A - Neutral hard scale softener for ternary combination drive screw pump well - Google Patents

Neutral hard scale softener for ternary combination drive screw pump well Download PDF

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Publication number
CN106928956A
CN106928956A CN201710120199.5A CN201710120199A CN106928956A CN 106928956 A CN106928956 A CN 106928956A CN 201710120199 A CN201710120199 A CN 201710120199A CN 106928956 A CN106928956 A CN 106928956A
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CN
China
Prior art keywords
sodium
hard scale
screw pump
screw bolt
alkali
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710120199.5A
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Chinese (zh)
Inventor
程杰成
周万富
孔衔霄
管公帅
韩露
黄小会
随大伟
余瀚森
杨海洋
王鑫
王庆国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Petrochina Co Ltd
Daqing Oilfield Co Ltd
Original Assignee
Petrochina Co Ltd
Daqing Oilfield Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petrochina Co Ltd, Daqing Oilfield Co Ltd filed Critical Petrochina Co Ltd
Priority to CN201710120199.5A priority Critical patent/CN106928956A/en
Publication of CN106928956A publication Critical patent/CN106928956A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/52Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
    • C09K8/528Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning inorganic depositions, e.g. sulfates or carbonates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F14/00Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes
    • C23F14/02Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes by chemical means

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Lubricants (AREA)

Abstract

The invention belongs to the technical field of oilfield chemistry, and particularly belongs to a neutral hard scale softener for a ternary combination flooding screw pump well. The invention solves the problem that the screw pump well cannot be acid-washed after scaling due to excessive corrosion of the scale remover. The invention consists of organic phosphate, organic phosphonate, dispersant, alkali and water, and the weight percentages are as follows: 10-40% of organic phosphate, 2-10% of organic phosphate, 1-5% of dispersing agent, 1-3% of alkali and 50-80% of water. The invention can be applied to scale removal and blockage removal of the ternary composite drive screw pump well, completely softens and drops the scale substances attached to the parts such as the screw pump rotor and the like, and thoroughly removes the scale substances.

Description

A kind of neutral hard scale softening agent for ternary composite driving screw bolt well
Technical field
The invention belongs to technical field of oilfield chemistry, a kind of neutrality for ternary composite driving screw bolt well is particularly belonged to hard Dirty softening agent.
Background technology
During water flooding, the generation of inorganic scale is the FAQs run into producing, due to reservoir The presence of anisotropism, causes the difference of fluid properties in underground different layers position rock forming mineral composition and reservoir, when oil well is adopted The underground fluid of several different layers position for going out mix in the wellbore or the temperature of various fluids, pressure and fluid in into dirt When ion concentration etc. is varied widely, it is easy to produce inorganic scale, these dirty matter can be attached to screw bolt well pump barrel, rotor, The positions such as sucker rod, cause the problems such as screw bolt well frequently occurs leakage, bar is disconnected, pump efficiency declines, and have a strong impact on production time efficiency, and And increased production cost.
At present, the oil well for ternary composite driving fouling takes pickling measure scale removal, has preferable snaking to oil well Effect, but the hydrogen ion in these pickling medicaments can occur fast reaction with screw pump rotor chrome plating coating, cause screw pump Rotor chrome plating coating comes off, and space increases between stator, rotor, and pump efficiency declines after causing pickling snaking, has a strong impact on extraction effect Rate, or even also result in the phenomenon of holddown.
The content of the invention
Soften it is an object of the invention to provide the dirty matter that can effectively make to be attached to the positions such as rotor, sucker rod, pump barrel, Come off, remove, reduce screw bolt well because of the operations number of leakage, holddown etc., a kind of use of rate when extending the operation of screw bolt well In the neutral hard scale softening agent of ternary composite driving screw bolt well.
The present invention is made up of organophosphorus ester, organic phosphonate, dispersant, alkali and water, and their percentage by weight is:Have Machine phosphate 10~40%, organic phosphate 2~10%, dispersant 1~5%, alkali 1~3%, water 50~80%.
Described organophosphorus ester can be AA-E alcohol phosphoric acid ester copolymer, maleic acid-vinyl alcohol phosphate or Any one in polyvinyl alcohol phosphate.
Described organic phosphonate can be the sodium of ATMP four, ATMP potassium, 2- phosphonobutanes- Any one in the sodium of 1,2,4- tricarboxylic acids four or the sodium of ethylene diamine tetra methylene phosphonic acid five.
Described dispersant can be any one in Sodium Polyacrylate, poly sodium or HPMA.
Described alkali can be any one in NaOH, potassium hydroxide, sodium carbonate or potassium carbonate.
Wherein, above-mentioned organophosphate molecules formula is following molecular formula:
AA-E alcohol phosphate copolymer molecule formula:
.
Maleic acid-vinyl alcohol phosphate molecular formula:
Polyvinyl alcohol phosphate molecular formula:
Molten dirty mechanism of the invention is:Phosphate group in organic phosphate or organophosphorus ester can in neutral conditions with Calcium ion is complexed, and improves the hydrophily of dirty matter, improves permeability so that in dispersant substantial amounts of carboxyl can further with Calcium is complexed, and improves the dispersiveness of calcium dirt, and final induction inorganic crystal salt occurs crystal transfer, makes the calcium carbonate in dirty matter brilliant Body is the aragonite crystal form of short texture by piling up fine and close calcite crystal transfer, so that dirty matter is loose, expansion, from extraction Equipment surface comes off, and realizes snaking purpose.
Compared with the prior art the present invention has the following advantages:
1) and stratum compatibility is strong, the temperature, salinity, pH value accommodation to stratum are big, without wadding after mixing with formation fluid Solidifying and precipitation;
2) do not reacted with the reservoir rock mineral of different blocks, static immersing under formation temperature
48 hours, produced without any corrosion and expansion;
3) more than 10 times of former dirty sample volume, are reached to the dispersion expansion multiple of Ternary composite drive well dirt sample;
4), soaked 48 hours under formation temperature, to screw pump rotor chrome plating coating not damaged, rotor coating does not fall off, and pump efficiency is not Change, normal production is not influenceed, the onsite application requirement of screw bolt well snaking can be met;
5), corrosion rate is low, and the corrosion rate at 45 DEG C to N80 test pieces is less than 1g/ (m2·h)。
Specific embodiment:With reference to example, the present invention is further illustrated:It is by organophosphorus ester, organic phosphine Hydrochlorate, dispersant, alkali and water are constituted, and their percentage by weight is:Organophosphorus ester 10~40%, organic phosphate 2~10%, Dispersant 1~5%, alkali 1~3%, water 50~80%.
Described organophosphorus ester can be AA-E alcohol phosphoric acid ester copolymer, maleic acid-vinyl alcohol phosphate or Any one in polyvinyl alcohol phosphate.
Described organic phosphonate can be the sodium of ATMP four, ATMP potassium, 2- phosphonobutanes- Any one in the sodium of 1,2,4- tricarboxylic acids four or the sodium of ethylene diamine tetra methylene phosphonic acid five.
Described dispersant can be any one in Sodium Polyacrylate, poly sodium or HPMA.
Described alkali can be any one in NaOH, potassium hydroxide, sodium carbonate or potassium carbonate.
Preparation method of the invention is:
A, take organophosphorus ester in beaker, add water, stirring and dissolving.
B, take dispersant and be added to the water, stirring and dissolving.
C, two kinds of solution of the above a and b are mixed, organic phosphonate is added thereto to after stirring, stirred.
D, take alkali and be added to the water, using the solution obtained in aqueous slkali regulating step c after dissolving, regulation solution ph is 7.
Embodiment 1:It by AA-E alcohol phosphoric acid ester copolymer, the sodium of ATMP four, poly sodium, NaOH, water are constituted, and their percentage by weight is:AA-E alcohol phosphoric acid ester copolymer 25%, the methene phosphine of amino three Sour four sodium 5%, poly sodium 2%, NaOH 2%, water 66% are imitated this gives neutral hard scale softening agent field test Really.
The present embodiment returns block screw bolt well C271-SP12 in the class of Daqing oil field West two and uses, and the well is because of dirt deposition Screw bolt well electric current is caused to rise to 63A from 51A, oil well electric current recovers normal drop after onsite application neutrality hard scale softening agent treatment To 52A, oil well is normally produced, and is occurred without leakage situation;Block screw bolt well N4-10- is returned on Daqing oil field Nan Si areas east P3039 is used, and electric current drops to 37A by 48A after treatment, and oil well returns to normal production, and is occurred without leakage situation.Neutral hard scale is soft Agent can make the dirty soft of the positions such as pump and oil pipe come off in the case where screw pump rotor chrome plating coating is not corroded, and meet spiral shell The onsite application requirement of bar pump sump snaking.
Embodiment 2:It is by the maleic acid-vinyl alcohol phosphoric acid ester copolymer, sodium of 2- phosphonobutane -1,2,4- tricarboxylic acids four, poly- PAA, potassium hydroxide, water are constituted, and their percentage by weight is:Maleic acid-vinyl alcohol phosphoric acid ester copolymer 25%, 2- phosphines The sour sodium 5% of butane -1,2,4- tricarboxylic acids four, Sodium Polyacrylate 2%, potassium hydroxide 3%, water 65%.
Embodiment 3:It by polyvinyl alcohol phosphoric acid ester copolymer, HPMA, the sodium of ethylene diamine tetra methylene phosphonic acid five, Sodium carbonate, water are constituted, and their percentage by weight is:Polyvinyl alcohol phosphate copolymer 1 5%, HPMA 1.5%, The sodium 4% of ethylene diamine tetra methylene phosphonic acid five, sodium carbonate 2%, water 77.5%.
Embodiment 4:It by polyvinyl alcohol phosphoric acid ester copolymer, HPMA, the sodium of ethylene diamine tetra methylene phosphonic acid five, Sodium carbonate, water are constituted, and their percentage by weight is:Polyvinyl alcohol phosphoric acid ester copolymer 40%, HPMA 3%, second The sodium 8% of four methylenephosphonic acid of diamines five, NaOH 3%, water 46%.

Claims (5)

1. a kind of neutral hard scale softening agent for ternary composite driving screw bolt well, it is characterised in that:It by organophosphorus ester, have Organic phosphonates, dispersant, alkali and water are constituted, and their percentage by weight is:Organophosphorus ester 10~40%, organic phosphate 2~ 10%, dispersant 1~5%, alkali 1~3%, water 50~80%.
2. a kind of neutral hard scale softening agent for ternary composite driving screw bolt well according to claim 1, its feature exists In:Described organophosphorus ester can be AA-E alcohol phosphoric acid ester copolymer, maleic acid-vinyl alcohol phosphate or poly- second Any one in enol phosphate.
3. a kind of neutral hard scale softening agent for ternary composite driving screw bolt well according to claim 1, its feature exists In:Described organic phosphonate can be the sodium of ATMP four, ATMP potassium, 2- phosphonobutane -1,2, Any one in the sodium of 4- tricarboxylic acids four or the sodium of ethylene diamine tetra methylene phosphonic acid five.
4. a kind of neutral hard scale softening agent for ternary composite driving screw bolt well according to claim 1, its feature exists In:Described dispersant can be any one in Sodium Polyacrylate, poly sodium or HPMA.
5. a kind of neutral hard scale softening agent for ternary composite driving screw bolt well according to claim 1, its feature exists In:Described alkali can be any one in NaOH, potassium hydroxide, sodium carbonate or potassium carbonate.
CN201710120199.5A 2017-03-02 2017-03-02 Neutral hard scale softener for ternary combination drive screw pump well Pending CN106928956A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108641694A (en) * 2018-04-27 2018-10-12 长江大学 A kind of oil well descaling agent and preparation method thereof
CN109339741A (en) * 2018-09-12 2019-02-15 中国石油天然气股份有限公司 Neutral non-return circulation descaling process flow applicable to ASP flooding pumping well

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103319010A (en) * 2012-03-19 2013-09-25 常州市排水管理处 Scale and corrosion inhibitor
US20150184061A1 (en) * 2013-03-14 2015-07-02 Cesi Chemical, Inc. Methods and compositions for use in oil and/or gas wells
CN105502704A (en) * 2016-01-04 2016-04-20 河北农业大学 Composite corrosion and scale inhibitor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103319010A (en) * 2012-03-19 2013-09-25 常州市排水管理处 Scale and corrosion inhibitor
US20150184061A1 (en) * 2013-03-14 2015-07-02 Cesi Chemical, Inc. Methods and compositions for use in oil and/or gas wells
CN105502704A (en) * 2016-01-04 2016-04-20 河北农业大学 Composite corrosion and scale inhibitor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
梁涛: "固体缓释性防腐阻垢剂的研制及应用", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108641694A (en) * 2018-04-27 2018-10-12 长江大学 A kind of oil well descaling agent and preparation method thereof
CN109339741A (en) * 2018-09-12 2019-02-15 中国石油天然气股份有限公司 Neutral non-return circulation descaling process flow applicable to ASP flooding pumping well
CN109339741B (en) * 2018-09-12 2021-03-19 中国石油天然气股份有限公司 Neutral non-return circulation descaling process flow applicable to ASP flooding pumping well

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Application publication date: 20170707

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