CN106833815A - A kind of punching oil antioxidant additive - Google Patents
A kind of punching oil antioxidant additive Download PDFInfo
- Publication number
- CN106833815A CN106833815A CN201611140963.7A CN201611140963A CN106833815A CN 106833815 A CN106833815 A CN 106833815A CN 201611140963 A CN201611140963 A CN 201611140963A CN 106833815 A CN106833815 A CN 106833815A
- Authority
- CN
- China
- Prior art keywords
- parts
- thio
- ester
- antioxidant additive
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention discloses a kind of punching oil antioxidant additive, it is constituted according to the parts by weight of following raw material：10 25 parts of secondary diarylamine, 20 40 parts of styrenated phenol, thio-2 acid double 10 50 parts of octadecyl ester, 10 20 parts of thio-2 acid dibasic acid esters, 18 parts of three monooctyl ester, 3 10 parts of three last of the ten Heavenly stems esters.Punching oil of the present invention with antioxidant additive from as light color, low toxicity have oxidation resistance and resin higher compatibility is good, processing characteristics is good.
Description
Technical field
The present invention relates to a kind of punching oil antioxidant additive.
Background technology
Most of punching oils are made up of oil extract in the market, due to being extracted from oil, there is certain
Paraffin component, paraffin cannot volatilize in the application, because being applied to refrigeration compressor motor is not allowed containing paraffin component,
So, cannot be used in punching silicon steel sheet.Some other punching oils, volatilization is too fast, and this can cause production on-site environment tight
Heavily contaminated, and because volatilization is too fast, cause High_Speed Die in punching punching, the stress concentration of punching, punching burr is larger,
The coating of local punching can be damaged, and to motor performance, especially electric efficiency causes very big influence.
Existing punching oil with antioxidant additive it is resistance to extract that shape is poor out, high cost, oxidisability it is poor.
The content of the invention
The purpose of the present invention is that and provides a kind of with oxidation resistance higher and tree in order to solve the above problems
The punching oil antioxidant additive that the compatibility of fat is good, processing characteristics is good.
To achieve these goals, the present invention is achieved by the following technical solutions：A kind of punching oil is added with antioxygen
Agent, it is constituted according to the parts by weight of following raw material：Secondary diarylamine 10-25 parts, styrenated phenol 20-40 parts, thio two
Propionic acid double 10-50 parts of octadecyl ester, 10-20 parts of thio-2 acid dibasic acid esters, three monooctyl ester 1-8 parts, ester 3-10 parts of three last of the ten Heavenly stems.
Further, a kind of punching oil antioxidant additive, it is constituted according to the parts by weight of following raw material：Diaryl is secondary
Amine 15-20 parts, styrenated phenol 25-30 parts, thio-2 acid double 20-40 parts of octadecyl ester, thio-2 acid dibasic acid esters 10-15
Part, three monooctyl ester 3-6 parts, ester 5-8 parts of three last of the ten Heavenly stems.
Further, a kind of punching oil antioxidant additive, it is constituted according to the parts by weight of following raw material：Diaryl
18 parts of secondary amine, 26 parts of styrenated phenol, thio-2 acid double 30 parts of octadecyl ester, 13 parts of thio-2 acid dibasic acid esters, three monooctyl esters 5
Part, 6 parts of three last of the ten Heavenly stems ester.
In sum the invention has the advantages that：Punching oil of the present invention antioxidant additive is from as light, low
Compatibility of the poison with oxidation resistance and resin higher is good, processing characteristics is good.
Specific embodiment
Specific embodiment 1：A kind of punching oil antioxidant additive, it is constituted according to the parts by weight of following raw material：Two virtues
10 parts of base secondary amine, 20 parts of styrenated phenol, thio-2 acid double 10 parts of octadecyl ester, 10 parts of thio-2 acid dibasic acid esters, three monooctyl esters 1
Part, 3 parts of three last of the ten Heavenly stems ester.
Specific embodiment 2：A kind of punching oil antioxidant additive, it is constituted according to the parts by weight of following raw material：Two virtues
18 parts of base secondary amine, 26 parts of styrenated phenol, thio-2 acid double 30 parts of octadecyl ester, 13 parts of thio-2 acid dibasic acid esters, three monooctyl esters 5
Part, 6 parts of three last of the ten Heavenly stems ester.
Specific embodiment 3：A kind of punching oil antioxidant additive, it is constituted according to the parts by weight of following raw material：Two virtues
25 parts of base secondary amine, 40 parts of styrenated phenol, thio-2 acid double 50 parts of octadecyl ester, 20 parts of thio-2 acid dibasic acid esters, three monooctyl esters 8
Part, 10 parts of three last of the ten Heavenly stems ester.
Embodiment provided above is better embodiment of the invention, only for the convenient explanation present invention, not to this hair
It is bright to make any formal limitation, any those of ordinary skill in the art, if putting forward skill the present invention is not departed from
In the range of art feature, using the Equivalent embodiments for locally being changed done by disclosed technology contents or modify, and
Without departing from technical characteristic content of the invention, still fall within the range of the technology of the present invention feature.
Claims (3)
1. a kind of punching oil antioxidant additive, it is characterised in that：Parts by weight according to following raw material are constituted：Secondary diarylamine
10-25 parts, styrenated phenol 20-40 parts, double 10-50 parts of the octadecyl esters of thio-2 acid, 10-20 parts of thio-2 acid dibasic acid esters,
Three monooctyl ester 1-8 parts, ester 3-10 parts of three last of the ten Heavenly stems.
2. a kind of punching oil antioxidant additive, it is characterised in that：Parts by weight according to following raw material are constituted：Secondary diarylamine
15-20 parts, styrenated phenol 25-30 parts, double 20-40 parts of the octadecyl esters of thio-2 acid, 10-15 parts of thio-2 acid dibasic acid esters,
Three monooctyl ester 3-6 parts, ester 5-8 parts of three last of the ten Heavenly stems.
3. a kind of punching oil antioxidant additive, it is characterised in that：Parts by weight according to following raw material are constituted：Secondary diarylamine
18 parts, 26 parts of styrenated phenol, thio-2 acid double 30 parts of octadecyl ester, 13 parts of thio-2 acid dibasic acid esters, 5 parts of three monooctyl ester, three
6 parts of last of the ten Heavenly stems ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611140963.7A CN106833815A (en) | 2016-12-12 | 2016-12-12 | A kind of punching oil antioxidant additive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611140963.7A CN106833815A (en) | 2016-12-12 | 2016-12-12 | A kind of punching oil antioxidant additive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106833815A true CN106833815A (en) | 2017-06-13 |
Family
ID=59140895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611140963.7A Withdrawn CN106833815A (en) | 2016-12-12 | 2016-12-12 | A kind of punching oil antioxidant additive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106833815A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102167991A (en) * | 2010-02-26 | 2011-08-31 | 中国石油化工股份有限公司 | Lubricating grease composition applicable to high-temperature, high-speed and heavy-load conditions and preparation method thereof |
| CN103756254A (en) * | 2013-12-14 | 2014-04-30 | 大连理工大学 | Epoxy resin used for liquid oxygen environment, preparation method and application thereof |
| CN103789066A (en) * | 2014-01-14 | 2014-05-14 | 黄志华 | Fully-washable textile sewing machine oil |
| CN104342228A (en) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | Antioxidant composition and use thereof |
| CN104450020A (en) * | 2014-10-28 | 2015-03-25 | 宁波春蕊润滑油有限公司 | Extreme-pressure-resisting wear-resisting type long-acting lubricating oil composition and preparation method thereof |
-
2016
- 2016-12-12 CN CN201611140963.7A patent/CN106833815A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102167991A (en) * | 2010-02-26 | 2011-08-31 | 中国石油化工股份有限公司 | Lubricating grease composition applicable to high-temperature, high-speed and heavy-load conditions and preparation method thereof |
| CN103756254A (en) * | 2013-12-14 | 2014-04-30 | 大连理工大学 | Epoxy resin used for liquid oxygen environment, preparation method and application thereof |
| CN103789066A (en) * | 2014-01-14 | 2014-05-14 | 黄志华 | Fully-washable textile sewing machine oil |
| CN104342228A (en) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | Antioxidant composition and use thereof |
| CN104450020A (en) * | 2014-10-28 | 2015-03-25 | 宁波春蕊润滑油有限公司 | Extreme-pressure-resisting wear-resisting type long-acting lubricating oil composition and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 吴绍祖等: "《实用精细化工》", 31 January 1993, 兰州大学出版社 * |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170613 |
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| WW01 | Invention patent application withdrawn after publication |